JP2010515566A - Application method of composition - Google Patents

Abstract

In one specific embodiment, the method comprises the step of applying a composition comprising a general formula (1): MDM trisiloxane to the surface of a substrate, wherein M = R ^A R ^B R ^C SiO _1/2 D = R ^D R ^F SiO _1/2 , wherein R ^D and R ^F are each independently a monovalent, divalent or trivalent hydrocarbon having 2 to 8 carbon atoms A radical or a monovalent, divalent or trivalent hydrocarbon radical having 1 to 60 carbon atoms other than 2 to 8 carbon atoms, provided that at least one of R ^D and R ^F is from 2 It is a condition that it is a monovalent, divalent or trivalent hydrocarbon radical having 8 carbon atoms, and R ^A , R ^B and R ^C are each independently 1 other than 2 to 8 carbon atoms. Monovalent, divalent, if from 60 to 60 carbon atoms Is a trivalent hydrocarbon radical, a coating method to the surface of the substrate trisiloxane composition.
[Selection]
None

Description

  The present invention relates to a method for applying a composition.

Description of Related Art Many industries and markets have been successful in delivering multi-performance products based on a mixture of several components, where each component has a performance and compatibility profile. The ingredients are added depending on the properties that are important to and desired for the particular end product formulation. In the method of applying the composition, some desirable properties are derived from the use of cyclic siloxanes in the formulation. Cyclic siloxanes can provide some of these desirable properties, but they are low viscosity and highly flowable liquids. They are therefore not easily retained in the formulation, but rather separate and control the skin and / or other substrates when spilled from a given container or used for a particular application. There is a tendency to go through impossible.

  Cyclic siloxanes have limitations with respect to their performance and compatibility profiles. Desired performance and / or compatibility profiles with desirable properties are not always achieved by using cyclic siloxanes. Certain applications require other properties not met by the use of cyclic siloxanes.

  For example, one of the disadvantages in the current state of the art is that many sprayable formulations are uneven, with spray system clogging, poor or poor droplet formation, and too much spilling over non-horizontal surfaces. It is that you are suffering from a poor or poor covering. A run-off, for example, moves beneficial components to undesired locations and / or leads to an uneven distribution where they are desired, leading to an unfavorable distribution of beneficial components delivered on any substrate. . Also, the clogging of the spray nozzle places too much mechanical stress, leading to premature wear of the spray system. Uneven droplets lead to a non-uniform distribution of active ingredients. The resulting unevenness eventually leads to poor performance characteristics. Often ethanol is used as a dispersant, however, in certain applications, such as personal care, it suffers from the accompanying drying effects that can cause flaking of skin and inflammation. Therefore, a need exists for a sprayable formulation that does not have the disadvantages described above.

It is noted in this brief description that the present inventors have unexpectedly discovered a method for applying a trisiloxane-containing composition in one specific embodiment. Contains certain trisiloxanes that can provide significantly improved physical properties for siloxane-containing compositions. In one embodiment herein, a method for applying a trisiloxane-containing composition to a surface of a substrate is provided, the method comprising:
General formula (1):
MDM (1)
Applying a trisiloxane-containing composition to the surface of the substrate,
here,
M = R ^A R ^B R ^C SiO _1/2
D = R ^D R ^F SiO _1/2
Wherein R ^D and R ^F are each independently a monovalent, divalent or trivalent hydrocarbon radical having 2 to 8 carbon atoms, or 1 to 60 of other than 2 to 8 carbon atoms. A monovalent, divalent, or trivalent hydrocarbon radical having carbon atoms, provided that at least one of R ^D and R ^F is monovalent, divalent, or trivalent having 2 to 8 carbon atoms And R ^A , R ^B , and R ^C each independently have 1 to 60 carbon atoms other than 2 to 8 carbon atoms, monovalent, divalent, or trivalent Valent hydrocarbon radical.

FIG. 1 is a dry electrophotographic reproduction of a photograph of a pattern resulting from application of a composition within the scope of the disclosure herein (Examples I and II) and a composition outside of the scope (Comparative Examples I and II). The photographs were taken immediately after application of the composition (1-6 seconds). FIG. 2 is a dry electrophotographic reproduction of a photograph of a pattern resulting from application of a composition within the scope of the disclosure herein (Examples I and II) and a composition outside the scope (Comparative Examples I and II). The photographs were taken immediately after application of the composition (1-6 seconds). FIG. 3 is a dry electrophotographic reproduction of a photograph of a pattern resulting from application of a composition within the scope of the disclosure herein (Examples I and II) and a composition outside the scope (Comparative Examples I and II). The photographs were taken immediately after application of the composition (1-6 seconds). FIG. 4 is a dry electrophotographic reproduction of a photograph of a pattern resulting from application of a composition within the scope of the disclosure herein (Examples I and II) and a composition outside the scope (Comparative Examples I and II). The photographs were taken immediately after application of the composition (1-6 seconds).

  Surprisingly, the applicant has discovered, in one embodiment, a method for applying trisiloxane-containing compositions, wherein the trisiloxane-containing compositions exhibit better physical properties than those trisiloxane-containing compositions. The advantageous properties described herein, such as reduced run-off, for coating and / or compounding with specific trisiloxanes provided and having a trisiloxane-containing composition when sprayed onto a substrate surface. Lead.

  As used herein, the terms polyorganosiloxane and organopolysiloxane are interchangeable.

  As used herein, the terms formulation and application are interchangeable.

  Here it will be understood that all use of the term centistoke was measured at 25 ° C.

  It will be understood that all specific, more specific and most specific ranges cited herein include all sub-ranges in between.

  Unless stated otherwise, all percentage ranges are understood herein to be weight percentages based on the total weight of the formulation containing the trisiloxane-containing composition.

The expression “run-down” is to be understood here as the visually observed degree of downward flow of the trisiloxane-containing composition applied to the cellulose paper, Measured on a scale of 1 to 3:
0 = No downward extension of one spray.
1 = Slight downward extension of one spray.
2 = Downward extension of one spray is easily recognizable, but moderate.
3 = Downward extension of one spray is very obvious and large.

  In one specific embodiment herein, the trisiloxane-containing composition is specifically less than about 100 weight percent, more specifically less than about 10 weight percent, based on the total weight of the trisiloxane-containing composition. Less, most specifically less than 1 weight percent water. In one more specific embodiment, the trisiloxane-containing composition can be free of water, and thus the trisiloxane-containing composition is free of atmospheric water and / or additional water.

  In other specific embodiments herein, the substrate is skin, hair, nails, eyelashes, eyebrows, lips, plant leaves, paper, leather, metal, plastic, fiber, glass, cloth, wood, textile, non-woven fabric. And combinations thereof.

  In yet another more specific embodiment, the trisiloxane hydrocarbon radical of general formula (1) can be any hydrocarbon radical generally associated with such polymers, such as methyl, ethyl, propyl. Alkyl radicals of 1 to about 60 carbon atoms such as; cycloalkyl radicals such as cyclohexyl, cycloheptyl, cyclooctyl; monocyclic aryl radicals such as phenyl, methylphenyl, ethylphenyl; such as vinyl and allyl Alkenyl radicals; alkylene oxide radicals such as ethylene oxide, propylene oxide, and mixtures thereof; can generally be selected from non-limiting examples of haloalkyl radicals such as 3,3,3, trifluoropropyl. In a more specific embodiment, the hydrocarbon radical of the trisiloxane of general formula (1) is an alkyl radical of 1 to 8 carbon atoms, most specifically methyl or ethyl. In one embodiment, the trisiloxane of general formula (1) has several hydroxy groups in the polymer. In another specific embodiment, the trisiloxane hydrocarbon radical of general formula (1) is an organic functional group as described in US Pat. No. 6,531,540, the entire contents of which are hereby incorporated by reference. Can be any of the following. Nomenclature for hydrocarbon radicals used in US Pat. No. 6,531,540 because any hydrocarbon radical described in US Pat. No. 6,531,540 can be utilized as a hydrocarbon radical as described herein. Are considered equivalent to hydrocarbon radicals as described herein and are therefore utilized herein with the term hydrocarbon radicals described in US Pat. No. 6,531,540. It will be understood that the hydrocarbon radical is interchangeable. In one embodiment herein, any hydrocarbon radical described herein can be present on the trisiloxane of general formula (1) or, as a non-limiting example, an olefin, specifically an alpha-olefin. It will be appreciated that the trisiloxane can be bonded via reaction with organic compounds such as

In one specific embodiment herein, the trisiloxane of general formula (1) can be made by any known method. In one more specific embodiment, the trisiloxane-containing composition is an alkyl-substituted trisiloxane as described in general formula (1) above. In one embodiment, the term “alkyl” means a saturated linear or branched monovalent hydrocarbon radical, such as the hydrocarbon radicals described above. In a specific embodiment, the monovalent alkyl group is methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, hexyl, heptyl, decyl, and dodecyl. As exemplified, it is selected from linear or branched alkyl groups containing 1 to 60 carbon atoms per group.
In other specific embodiments,
The trisiloxane of the general formula (1) has the formula (A):
M ¹ D ² M ¹ (A)
A linear alkyltrisiloxane which is a high purity material resulting from alkylation of a polyorganosiloxane having
here,
M ¹ = R ^G R ^J R ^K SiO _1/2 ; and D ² = R ^L R ^M SiO _2/2 ;
Wherein R ^G , R ^J , R ^K , R ^L , and R ^M are independently a monovalent hydrocarbon radical or hydrogen having 1 to 60 carbon atoms, provided that R ^G , R ^J , The condition is that at least one of R ^K , R ^L , and R ^M is hydrogen. In a more specific embodiment, R ^L and / or R ^M is hydrogen. In one embodiment, the high purity material as described herein substantially contains an alkylated polyorganosiloxane of formula (A). In a specific embodiment herein, alkylation of the polyorganosiloxane having formula (A) comprises reacting the polyorganosiloxane having formula (A) with an alkene compound such as ethylene as a non-limiting example. Achieved by: In a more specific embodiment, the high purity material contains greater than about 90 weight percent of the alkylated polyorganosiloxane based on the total weight of the high purity material. In an even more specific embodiment, the high purity material contains greater than about 95 weight percent of the alkylated polyorganosiloxane of formula (A) based on the total weight of the high purity material. In the most specific embodiment, the high purity material contains greater than about 97 weight percent of the alkylated polyorganosiloxane based on the total weight of the high purity material. In another embodiment herein, the trisiloxane of general formula (1) is described in US patent application Ser. No. 11 / 274,450 filed Nov. 15, 2005, the entire contents of which are hereby incorporated by reference. As a result of alkylation of such polyorganosiloxanes. In other position embodiments herein, the trisiloxane of general formula (1) may be made by any known or conventional method known to those skilled in the art.

In a more specific embodiment here, the trisiloxane of the general formula (1) is monovalent, divalent or trivalent wherein R ^D and / or R ^F has 2 to 6 carbon atoms. The hydrocarbon radicals may be more specifically contained. In an even more specific embodiment here, the trisiloxane of general formula (1) is monovalent, divalent or trivalent wherein R ^D and / or R ^F have 2 to 4 carbon atoms. May be those that are valent hydrocarbon radicals. In an even more specific embodiment, the trisiloxane of general formula (1) may contain more specifically those in which R ^D and / or R ^F are ethyl. In the most specific embodiment, the trisiloxane of general formula (1) may contain those in which R ^D is ethyl and R ^F is methyl.

  In one specific embodiment herein, some non-limiting examples of trisiloxanes of general formula (1) include 1,1,1,3,5,5,5-heptamethyl-3-ethyltri A linear alkyltrisiloxane selected from the group consisting of ethyltrisiloxane, such as a non-limiting example of siloxane; of 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane Octylsiloxanes, such as non-limiting examples; hexyltrisiloxanes, such as non-limiting examples of 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane, and combinations thereof is there. In one specific embodiment herein, the trisiloxane of general formula (1) is at least one of the trisiloxanes such as those described in US Patent Publication No. 2004 / 0197284A1, which is hereby incorporated by reference in its entirety. possible. In other specific embodiments herein, the trisiloxane of general formula (1) is at least a trisiloxane such as those described in US Patent Publication 2005 / 0069564A1, the entire contents of which are hereby incorporated by reference. One. In an even more specific embodiment, the trisiloxane of general formula (1) is 3-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; for example by General Electric Company 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane sold under the name “Silsoft034”; 1,1,1,3,5,5,5-heptamethyl- 3-hexyltrisiloxane; 3- (1-ethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3 -(1-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) -1 1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 3- (3 3-dimethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methyl); Propyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyltrisiloxane; 3-isohexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl-1,1,1,3,5,5 , 5-heptamethyltrisiloxane; 3-neo-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3 -Dipropyltrisiloxane; 3,3-diethyl-1,1,1,5,5,5-hexamethyltrisiloxane; 3,3-dibutyl-1,1,1,5,5,5-hexamethyltrisiloxane Siloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,5,5,5-hexamethyl-3,3-diethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-butyltrisiloxane, and combinations thereof Can be selected.

  In one specific embodiment, the trisiloxane of general formula (1) may contain two or more trisiloxanes of general formula (1) as described herein.

  The amount of trisiloxane of the above general formula (1) used in the trisiloxane-containing composition will depend on the intended use of the trisiloxane-containing composition, other ingredients, the desired result, etc. Can be determined. In another embodiment, the trisiloxane of general formula (1) is in the trisiloxane-containing composition, specifically about 0.001 to about 99 weight percent, more specifically based on the total weight of the trisiloxane-containing composition. Typically about 0.01 to about 85 weight percent based on the total weight of the trisiloxane-containing composition, and even more specifically about 0.1 to about 50 weight percent based on the total weight of the trisiloxane-containing composition. Most specifically, it is present in an amount of about 0.2 to about 20 weight percent, based on the total weight of the trisiloxane-containing composition. In an even more specific embodiment, the trisiloxane of general formula (1) is in the trisiloxane-containing composition, specifically from about 10 to about 2 weight percent, based on the total weight of the trisiloxane-containing composition. Present in the amount of.

  The particular formulation containing the trisiloxane-containing composition described herein will vary depending on the industry and will be determined by those skilled in the industry. In still other specific embodiments herein, the trisiloxane-containing composition is specifically about 99 to about 0.001 weight percent, more specifically, based on the total weight of the trisiloxane-containing composition. Is about 85 to about 0.01 weight percent based on the total weight of the trisiloxane-containing composition, and even more specifically about 50 to about 0.1 weight percent based on the total weight of the trisiloxane-containing composition, Specifically, it further includes compounding ingredients in an amount of about 20 to about 2 weight percent based on the total weight of the trisiloxane-containing composition. In an even more specific embodiment, the trisiloxane-containing composition further contains the formulation ingredients, specifically in an amount of about 10 to about 2 weight percent, based on the total weight of the trisiloxane-containing composition. .

  In one embodiment, the ingredients can contain conventional and known ingredients as are known to those skilled in various industries. In an even more specific embodiment herein, the ingredients are propellants, surfactants, emulsifiers, solvents, emollients, moisture, moisturizers, pigments, colorants, fragrances, biocides, preservatives. , Antioxidants, antibacterial agents, antifungal agents, insecticides, paints, antiperspirants, spray propellants, exfoliants, alcohol, hormones, enzymes, pharmaceutical compounds, vitamins, alpha hydroxy acids, beta hydroxy acids And / or other hydroxy acids, retinol and its derivatives, niacinamide, skin lightening agents, salts, electrolytes, polyols, UV absorbers, herbal extracts and non-limiting examples of tea tree oils, organic Oil, wax, film forming element, thickener, fine particle filler, clay, plasticizer, sealant, sensory enhancer, ester, Jin and film-forming elements are selected spherical or other optically active particles comprising non-limiting examples of silicone spheres, and combinations thereof.

  In other specific embodiments, the trisiloxane of general formula (1) described above and a silicone oil, silicone rubber, silicone solid, silicone emulsion, silicone resin, silicone copolyol, alkyl silicone, silicone wax, silicone amine, Provided in combination with other types of silicones selected from the group consisting of silicone ammonium salts, quaternary silicone amines, spherical silicones, silicone gels, silicone cross-linked networks, polyether silicones, and combinations thereof. The relative amount of each silicone is optimized for industry-specific characteristics of trisiloxane-containing compositions, such as, but not limited to, reduced run-off, particularly for sprayable personal care compositions To be adjusted. In a more specific embodiment here, the trisiloxane-containing composition may further contain a silicone fluid other than the trisiloxane of general formula (1). In a more specific embodiment, the silicone fluid other than the trisiloxane of the general formula (1) is a cyclic siloxane and / or a linear chain such as a decamethylcyclopentasiloxane fluid and / or a high molecular weight polyorganosiloxane fluid, respectively. It can be a silicone fluid. In the most specific embodiment herein, the high molecular weight polyorganosiloxane fluid has a higher viscosity compared to the trisiloxane of general formula (1), and specifically from about 1 to about 400, more Specifically, an organopolydimethylsiloxane having a viscosity of about 3 to about 350, most specifically about 5 to about 300 centistokes, wherein the organo group is any of the hydrocarbon radicals described above. May be selected from the group consisting of In one specific embodiment, the organopolydimethylsiloxane can have a viscosity of about 1 to about 1000 centistokes, more specifically 2 to about 500 centistokes, most specifically 5 to about 10 centistokes. . In one very specific embodiment, the polydimethylsiloxane can have a viscosity of 5 centistokes. In one very specific embodiment, the polydimethylsiloxane can have a viscosity of 50 centistokes.

  In one embodiment herein, trisiloxane-containing compositions as described herein may be obtained from US Pat. Nos. 6,531,540, 6,060,546, the entire contents of which are hereby incorporated by reference. No. and 6,271,295 can be used as made or utilized as a silicone component in an emulsion.

  In a further embodiment herein, important metal catalysts suitable for making trisiloxanes of general formula (1) and other trisiloxanes of general formula (1) as described herein are Known in the art and includes complexes of rhodium, ruthenium, palladium, osmium, iridium, and / or platinum. For example, many types of platinum catalysts for this addition reaction of SiH to olefins are known and include Karlstedt catalysts, which are used to produce the compositions of the present invention. obtain. Further background on this area is Academic Press (New York, 1979), F.C. G. A. Stonen and R.W. West, Advances in Organometallic Chemistry Volume 17, pages 407-447. L. It can be found in Spier's “Homogeneous Catalysis of Hydrolysis by Transition Metals”. One skilled in the art can readily determine the effective amount of platinum catalyst. In general, an effective amount ranges from about 0.1 to about 50 parts per million total of the trisiloxane-containing composition. In more specific embodiments, the effective amount is more specifically about 1 to about 20 parts per million total trisiloxane-containing composition, most specifically 100 total trisiloxane-containing composition. It ranges from about 4 to about 15 parts per million.

  In a more specific embodiment herein, application of the trisiloxane-containing composition includes using a spray that takes at least one spraying, dispensing, diffusing or atomizing process. In a more specific embodiment, the pre-injection, dispensing, diffusing or atomizing process includes general and known processes including, but not limited to, flow rates, droplet sizes and pressure increases typical of industry. Can be any process.

  In an even more specific embodiment, the application of the trisiloxane-containing composition is a fragrance and lotion pump, a mist mist sprayer, a special pump, an anti-clogging pump, a spray-through to provide the spray spray application. Use a spray selected from the group consisting of a cap, nozzle, airless pump, double dispense pump, mist mist pump, trigger pump, foam pump, trigger sprayer, aerosol sprayer, squeeze foamer, and combinations thereof. contains.

  In one embodiment herein, the spraying, dispensing, diffusing or atomizing process can contain a rapid and sudden spill of the liquid or fluid that is released, which is a) the nebulization process, i.e. Microparticles such as fluids or emulsions are reduced and often particles pass through nozzles into a fine mist or mist; b) watering and sprinkling processes, including fire watering, ie water C) a jet stream process, i.e. a stream of fluid created by an orifice or small opening and / or discharge passing through a nozzle, where the nozzle Non-limiting mechanical device that controls the nature of the flow as it exits the enclosed chamber to a specific medium Including examples. Often, the kinetic energy of the flowing medium increases by consuming specific pressure energy of the fluid before passing through the nozzle.

  In a further embodiment, the application of the trisiloxane-containing composition is specifically from about 0.001 milliliter to about 50 milliliters per spray application, more specifically from about 0.01 milliliters per spray application. Spraying about 5 milliliters, more specifically about 0.1 milliliters to about 0.5 milliliters per spray application;

  In an even more specific embodiment, the application of the trisiloxane-containing composition is specifically from about 0.01 centimeters to about 10,000 centimeters from the surface of the substrate, more specifically from about 0 to the surface of the substrate. And further spraying at a distance of about 1 centimeter to about 100 centimeters, most specifically about 1 centimeter to about 50 centimeters from the surface of the substrate.

  In a further embodiment herein, the application method of the trisiloxane-containing composition further contains the trisiloxane-containing composition that contains something other than a release agent, a cosmetic spray, a gel, or an emulsion.

  In one specific embodiment herein, a method for applying a trisiloxane-containing composition is described in US patent application Ser. No. 11 / 274,450 filed Nov. 15, 2005, the entire contents of which are incorporated herein. The silicone gel can contain what the trisiloxane containing composition further contains.

  In another specific embodiment herein, the method of applying the trisiloxane-containing composition is improved over the sprayable composition wherein the trisiloxane-containing composition contains other than the composition of general formula (1). It further contains those exhibiting the above properties. In a more specific embodiment, application of a trisiloxane-containing composition wherein the trisiloxane-containing composition exhibits improved properties over sprayable compositions containing other than the composition of general formula (1) The method further includes those containing volatile siloxanes other than the composition of general formula (1), such as non-limiting examples of cyclic siloxanes. Cyclic siloxanes used as volatile siloxanes are well known in the prior art and will not be described in detail here. In an even more specific embodiment here, the improved properties over sprayable compositions containing other than the composition of general formula (1) are reduced run-off, better coating, improved activity. Component distribution and / or performance, quick drying, less excess wetting, simple formulation, no stickiness, improved extensibility, improved uniformity, improved organic compatibility, reduced skin From the group consisting of inflammation, improved active ingredient delivery, improved skin feel, improved SPF, less or more desired shine, smaller droplet size, and less mechanical stress in the employed spray system It is at least one selected. Any one or more improvements of the aforementioned properties are synergistic. For example, rapid drying can lead to less excessive wetting, which in some cases can lead to improved mechanical stability of the substrate, for example when wet paper is dried paper For the paper industry with less mechanical strength than, but not limited to. As another advantageous feature, the application method of the trisiloxane-containing composition here is sprayable, which is applied in many different industries, for example sprayable, cosmetic or personal care formulations. Formulation run-off is advantageously reduced by simply adding the trisiloxane-containing compositions described herein to such formulations.

  In one specific embodiment herein, the ingredients described above do not adversely affect or substantially counteract any of the properties specified above on the run-off reduction or trisiloxane-containing composition. Does not give adverse effects. In other specific embodiments herein, the improved properties described above include emulsifiers, preservatives, polymers, thixotropic and non-thixotropic film forming elements, sunscreens, sunscreens, colorants. Active ingredients such as pigments, fragrances, vitamins, alpha hydroxy acids, beta hydroxy acids and / or other hydroxy acids, non-limiting examples of retinol and derivatives thereof, niacinamide, tocopherol and / or derivatives thereof, skin lightening agents Humectants, sealants, sensory enhancers, esters, other resins and film-forming elements, spherical or other optically active particles including silicone spheres, and other silicones, emollients, surfactants, and their By using synergistic ingredients selected from the group consisting of combinations Are may be the result of a synergistic effect.

  In other specific embodiments, the method of applying the trisiloxane-containing composition herein includes aerospace industry, agriculture, food and beverage industry, textiles and nonwovens, automotive body panels, automotive energy management, automotive ceiling materials. Automobile headrests and armrests, automobile instrument panels, automobile seats, automobiles including non-limiting examples of handles, tires, paints, inks, paints, architectural sealants, discontinuous panels, flexible exterior panels, windows and doors, Architecture including non-limiting examples of pipes, consumer goods, footwear, furniture, bedding, consumption including non-limiting examples of carpets, electronics including automotive electronics, semiconductors, healthcare, hard surface cleaners, laundry and soft, Home care, factory assembly, factory cleaning, molding, packing and labeling, including non-limiting examples of polishing and processing Distribution and energization, Apparel and leather, Oil and gas, Pulp and paper, Processing industry including non-limiting examples of issuance, Insulation tanks, Transportation including non-limiting examples of shipping containers, Pools and hot springs, Motor scooters It can be used in a market or industry selected from the group consisting of motorcycles including limited examples, personal care, and combinations thereof.

  In yet another specific embodiment, the method of applying the trisiloxane-containing composition herein is a non-limiting form of the trisiloxane-containing composition that is applied by the personal care market and industry in the form of a spray, stick and spin coat. Deodorant, antiperspirant, antiperspirant / deodorant, shaving products, skin lotion, moisture, lotion, bath products, cleansing products, shampoo, conditioner, shampoo / conditioner combination, mousse, styling gel, hair spray , Hair dye, hair color products, hair decoloring, curling supplies, curling irons, nail polish, nail polish remover, nail cream and / or lotion, keratin softener, sunscreen, insect repellent, anti-aging products, lipstick, foundation, face Powder, eyeliner, Aisha C, blusher, cosmetics, mascara, moisturizing agent, body and hand agent, skin care agent, face and neck agent, tonic, makeup, hair styling aid, aerosol fixative, fragrance agent, after-shave preparation, cosmetic agent , Soft focus agent, day and night skin care agent, non-colored hair agent, tanning agent, synthetic and non-synthetic solid soap, hand liquid, pore pack, non-wovens for personal care, baby lotion, baby bath And / or shampoo products, baby conditioner, shaving agent, cucumber slice, skin pad, makeup remover, facial cleansing product, cold cream, sunscreen product, spritz, paste mask and / or mud, face mask, colon And lotion, hair cuticle , Shower gel, face and body detergent, personal care washout product, gel, bubble bath, cleanser, astringent, nail conditioner, eye shadow stick, facial or eye powder, lip balm, lip gloss, hair care pump spray and others Non-aerosol spray, hair curl control gel, hair leave in conditioner, hair pomade, tangle loosening product, hair fixative, hair bleach product, skin lotion, before shaving and before shaving, anhydrous cream and / or lotion, oil / Water, water / oil, multiple and macro and micro emulsions, pickering emulsions, multiphase emulsions, water-resistant creams and / or lotions, anti-acne agents, mouthwashes, Massage oils, toothpastes, clear gels and / or sticks, ointment bases, topical wound healing products, aerosol talc, barrier sprays, vitamins and anti-aging agents, herbal extract preparations, bath salts, bath and body milk, hair Styling aids, hair, eyes, nails, skin soft solid applications, controlled release personal care products, hair condition mist, skin care moisture mist, skin wipes, skin pore wipes, pore cleaners, stain removers, exfoliators ), Skin desquamation enhancer, skin wet tissue and / or cloth, hair removal agent, personal care lubricant, nail color agent, drug delivery system for local administration of pharmaceutical composition for application to skin, Further comprising that it contains be used in personal care applications selected from the group consisting of a rabbi.

  In other specific embodiments herein, the method of applying the trisiloxane-containing composition is such that the trisiloxane-containing composition is a sunscreen, hair color product, cosmetic product, anti-aging product, moisture, skin care product and combinations thereof. Including those used in applications where it is desired to have any advantageous properties associated with the coat, including but not limited to skin protection such as non-limiting examples.

  In still other specific embodiments herein, the method of applying the trisiloxane-containing composition includes a personal care product containing a UV blocking or UV absorbing sunscreen, and at least one of the aforementioned sunscreens. And a sun care formulation that can further contain a sunscreen selected from the group consisting of: In an even more specific embodiment, the sunscreen agent is generally silicone or other treated titanium dioxide, titanium dioxide, silicone or other treated zinc oxide, as non-limiting examples of zinc oxide. It is inorganic. In further specific embodiments, absorbing sunscreens, which are generally organic species, are in the 320 to 400 nm region of the ultraviolet spectrum, such as non-limiting examples of anthranilates, benzophenones, and dibenzoylmethanes. UV-A absorbers that generally absorb radiation, as well as radiation in the 280-320 nm region of the UV spectrum, such as non-limiting examples of paraaminobenzoic acid derivatives, camphor derivatives, cinnamic acid esters, salicylates Non-limiting examples of UV-B absorbers that absorb naturally. In one specific embodiment, non-limiting examples of some organic sunscreens include paraaminobenzoic acid, avobenzoncinoxate, dioxybenzone, homosalate, methyl anthranilate, octocrylene, octyl methoxycinnamate, octyl salicylate. , Oxybenzone, padimate, phenylbenzimidazolesulfonic acid, thrisobenzone, trolamine salicyl salt, aminobenzoic acid, p-aminobenzoic acid amyldimethyl, p-methoxycinnamic acid diethanolamine, digalloyl trioleate, 2-cyano- 2-ethylhexyl 3,3-diphenylacrylate, ethylhexyl p-methoxycinnamate, 2-ethylhexyl salicylate, glycerylaminobenzoate, homomenthyl salicylate , Homosalate, 3-imidazol-4-ylacrylic acid and its ethyl ester, methyl anthranilate, dimethyl PABA octyl, 2-phenylbenzimidazole-5-sulfonic acid and salt, soribenzone, triethanolamine salicylic acid, N, N, N-trimethyl-4- (2-oxoboron-3-ylidenemethyl) anilinium methyl sulfate, aminobenzoate, isopropylbenzyl salicylate, 2-methoxyhexyl 4-methoxycinnamate, methyl diisopropylcinnamate, 4-methoxycinnamic acid Isoamyl, 4-methoxycinnamic acid diethanolamine, 3- (4′trimethylammonium) -benzylidene-bornan-2-one methyl sulfate, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxyben Phenone-5-sulfonate, 2,4-dihydroxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2,2′-dihydroxy-4,4′dimethoxybenzophenone, 2-hydroxy-4-n Octoxybenzophenone, 2-hydroxy-4-methoxy-4'-methoxybenzophenone, ca- (2-oxoboron-3-ylidene) -tolyl-4-sulfonic acid and its soluble salts, 3- (4'- Sulfo) benzylidene-bornan-2-one and soluble salts thereof, 3- (4′-methylbenzylidene) -d, l-camphor, benzene-1,4-di (3-methylidene-10-camphosulfone ( camphosulfic)) acid and salts thereof, urocanic acid, 2,4,6-tris (2'-ethylhexyl-1) -Oxycarbonyl) -anilino 1,3,5-triazine, 2- (p- (tert-butylamido) anilino-4,6-bis- (p- (2'ethylhexyl 1'-oxycarbonyl) anilino 1,3 5-triazine, 2,4-bis {(1,4- (2-ethylhexyloxy) -2-hydroxyphenyl} -6- (4-methoxyphenyl) -1,3,5-triazine, N- (2 et 4)-(2-Oxoborn-3-ylidene) methylbenzylacrylamide polymer, 1,4-bisbenzimidazole-phenylene-3,3 ', 5,5'-tetrasulfonic acid and its salts, benzylidene Malonic acid-substituted polyorganosiloxane, benzotriazole-substituted polyorganosiloxane (drometrizole trisiloxane (Dr ometriazole Trisiloxane)), solubilized 2,2′-methylene-bis-1,6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol, 2 -Methyldibenzoylmethane, 4-methyldibenzoylmethane, 4-isopropyldibenzoylmethane, 4-tert-butyldibenzoylmethane, 2,4-dimethyldibenzoylmethane, 2,5-dimethyldibenzoylmethane, 4,4 '-Diisopropyldibenzoylmethane, 4,4'-dimethoxydibenzoylmethane, 4-tert-butyl-4'-methoxydibenzoylmethane, 2-methyl-5-isopropyl-4'methoxydibenzoylmethane, 2-methyl- 5-tert-butyl-4′-methoxydibenzoylmethane, 2, 4-dimethyl-4'-methoxydibenzoylmethane, 2,6-dimethyl-4-tert-butyl-4'-methoxydibenzoylmethane, and combinations comprising at least one of the aforementioned sunscreens. In one embodiment, a combination of at least three sunscreens has been found effective. In other embodiments, a combination of four sunscreens has been found to be particularly effective when a chemical sunscreen is used. In a further embodiment, a formulation comprising one or a combination of several sunscreens including one or several sunscreens is effective.

  In one embodiment herein, when the trisiloxane-containing composition is formulated into a sunscreen, the sunscreen formulation may be in the form of a thin layer emulsion, microemulsion, or nanoemulsion or pickering emulsion. Further, the emulsion can be a simple fluid emulsion, a multiple fluid emulsion, a simple solid emulsion, or a multiple solid emulsion. Simple emulsions or multiple emulsions comprise a continuous aqueous phase containing dispersed fat vesicles or oil droplets, or a continuous fat phase of dispersed fat vesicles or oil droplets. In one embodiment, sunscreen applications are emulsions with a continuous aqueous phase, usually in the form of sprayable compositions, simple phase, dual or multiphase emulsions, gels, lotions, and the like.

  In other specific embodiments herein, reduced “run-off” is such that the area wetted by the trisiloxane-containing composition sprayed onto the surface of the substrate is reduced or eliminated in shape or size. Including any phenomenon. This includes processes caused by gravity as well as processes caused by any other physical or mechanical force, such as but not limited to capillary forces.

  In an even more specific embodiment, the method for applying the trisiloxane-containing composition is such that the personal care application is sucrose palmitate (and) glyceryl stearate (and) glyceryl stearate citrate (and) sucrose (and) mannan. (And) xanthan gum, ie a non-ionic biopolymer mixture such as a non-limiting example from Uniquema (arlatone V-175); propylene glycol isoses-3 acetate, ie from Bernel (Hester PHA) or from Croda Steareth-2 or Steareth-10 (Volpo S2 and Volpo S1-), laureth-7, laureth-4 (Sepigel® 305 available from SEPPIC) Non-limiting examples of polyethoxylated emulsifiers; non-limiting examples of glycerin (and) glycerin polyacrylates, ie modified polyacrylates from Cognis (Hispagel 200); Oils such as bees; animal waxes and / or synthetic waxes such as beeswax, paraffin, rice bran wax, candelilla wax, carnauba wax, and their derivatives; Gel SS71, Gel EA2786, Quaterium-18 bentonite , 38CE, GelISDV or GElISD non-limiting examples of hydrocarbon gels or benton type gels; cetyl dimethicone copolyol-polyglyceryl-4-isostearic acid-hexyl laurate, ie Goldsc (ABIL® WE09), behenate dimethicone, cetyl dimethicone copolyol (ABIL® EM 90), (ABIL® EM 97), lauryl methicone copolyol from rnidt Chemical Corporation (5200), cyclomethicone and dimethicone copolyols, i.e. available from GE Silicones (DC5225C and DC3225C), cyclopentasiloxane and dimethicone copolyols (GE SF128 or GE1540), PEG-20 / PPG-23 dimethicone (GE Silsoft 440) A group of organosilicone emulsifiers such as, but not limited to, and combinations thereof It may further contain those further containing an emulsifier selected.

  In another specific embodiment herein, the method of applying the trisiloxane-containing composition comprises the trisiloxane-containing composition being used in the form of a product from hydrous to non-humidified. In a more specific embodiment, the product form may be a simple solid, particle, liquid, gel network stable phase, and combinations thereof. In an even more specific embodiment, the product form may be selected from the group consisting of gel, emulsion, dispersion, sludge, powder, rod, spray, spritz, mousse, stick, balm, foundation, and combinations thereof. In a more specific embodiment, the emulsion product form can be single phase, two phase, three phase, or multiple phase, lamellar phase, can be macroemulsion, microemulsion, or nanoemulsion, and water-in-oil-in-water (Water-in-oil-in-water) type emulsion oil-in-water-in-oil emulsion, water-in-silicone emulsion, or silicone-in-oil emulsion, anionic emulsion, It can be a cationic emulsion, an amphoteric emulsion, a neutral emulsion, or a pickering emulsion, as well as other physical forms.

  In still other specific embodiments herein, the method of applying the trisiloxane-containing composition includes: the trisiloxane-containing composition is lecithin, polysorbate, dimethicone copolyol, glycol, citrate ester, glycerin, dimethicone, and Further containing a plasticizer selected from the group of non-limiting examples consisting of

  In yet another specific embodiment herein, the method of making the trisiloxane-containing composition comprises any type of stirring at manual or mechanical stirring, high temperature, medium temperature, room temperature, low temperature. Shear including, but not limited to, other specific procedures to achieve small sized droplets in the emulsion, including but not limited to phase inversion including, but not limited to, homogenization or heating as well as any cooling process Through any process or combination of processes known to those skilled in the art, such as any technique that applies.

  In another embodiment, there is provided a method of manufacturing the aforementioned personal care application comprising a combination of trisiloxane-containing compositions with such personal care ingredients as known to those skilled in the art. Some non-limiting examples of personal care ingredients are described in US patent application Ser. No. 11 / 274,450 filed Nov. 15, 2005, the entire contents of which are incorporated herein.

  In still yet another embodiment, the disclosed personal care ingredients exhibit various advantages in personal care applications. Some such non-limiting advantages are reduced run-off and can be combined alone or with any active ingredient. Other performance of each personal care application includes considerations such as the type of hydrocarbyl radical present, the presence and type of any substitution on the silicone backbone or side chain, the molecular weight of trisiloxane, and sprayable personal care applications Depending on the nature of the particular trisiloxane selected, such as the remaining components of The desired properties of a particular personal care application can be specifically determined by those skilled in the art. Some specific examples of properties provided by using trisiloxanes here are reduced viscosity, improved extensibility, quick drying, reduced excessive wetting, improved uniformity, improved organics May include compatibility, improved skin feel, controlled active ingredient delivery, improved shine, and / or reduced skin irritation. A test panel may be used to objectively determine reduced viscosity, improved uniformity, improved organic compatibility, and improved skin feel. Improved extensibility can be determined by measuring the coefficient of friction in samples of personal care ingredients. Skin inflammation can be determined by measuring the development of erythema. Sunscreens are evaluated by their ability to delay erythema or sunburn resulting from exposure to ultraviolet radiation. The brightness will be determined by measuring the optical refractive index using a gloss meter.

  In yet a further embodiment herein, a silicone gel made by any process described in US patent application Ser. No. 11 / 274,450 filed Nov. 15, 2005, the entire contents of which are incorporated herein. A personal care formulation as described above is provided.

  The following examples are provided for purposes of illustrating the simple case invention. It is not provided for any purpose of setting a limitation on the embodiments described herein. All weights are weight percentages based on the total weight of the trisiloxane-containing composition unless otherwise stated.

  Preparation of the trisiloxane-containing composition of Table 1 below is accomplished by manual stirring and addition of the other listed ingredients with continued stirring during the addition of the next ingredient. .

  When Comparative Example I and Example I were sprayed onto the surface, the Comparative Example showed a clear trace of run-off, while Example I did not, as illustrated in the drawing section below. . Comparative Example I has a run-off of 2 on the scale shown above. Example I has zero run-off at the scale shown above.

  As can be clearly seen, the formulation with cyclopentasiloxane begins to run off, while the formulation with ETS remains in place. Here, a well-prepared spray system was used once in both cases and was applied 10.16 centimeters away from the surface of the notebook paper.

  In order to address the possibility that the ETS containing formulation simply would not run off due to the deposition of less material on the substrate surface, the following control experiment was performed to eliminate the effect of the difference between sprays.

  The above experiment was repeated on a pre-weighed notepad paper that was drawn 10.16 centimeters away. Five spray shots of each of the formulations of Comparative Example I and Example I were delivered and the mass of material delivered was obtained by a gravimeter.

  Comparative Example I: 0.581 grams (g) was deposited with 5 spray shots. 0.581 g / 5 = 0.162 g was deposited per spray. This result was calibrated with the density of the formulation, which was measured to be 0.9777 g / ml using a Mettler / Paar DMA46 digital densimeter, as the run-off reduction was also dependent on the volume deposited. 0.1162 g / 0.9777 g / ml = 0.189 ml was deposited per spray spray.

  Example I: 0.622 g was deposited with 5 spray shots. 0.622 g / 5 = 0.244 g was deposited per spray spray. With the density determined as described above, the following volume depositions were made. 0.1244g / 0.9107g / ml = 0.1366ml was deposited per spray spray.

  In addition, all experiments were performed with another spray pump of the same type (Qosmedix Corporation, Edgewood, New York, United States) transparent top cover white to eliminate any possible effects of the pump itself. Spray sprayer Model # 29717, spray pump made of polypropylene and bottle made of polyvinyl chloride).

  As can be seen from above, obviously the ETS formulation does not deposit less than the cyclopentasiloxane formulation, and therefore the effect of no run-off is truly due to the beneficial presence of ETS.

  Spraying Comparative Example I onto a hydrated vitro-skin and measuring the resulting sun protection index using a Labsphere UV7000 Light Simulator yielded a sun protection index of 11, while Example I Provides 13 sun protection indexes under the same conditions.

  This is exemplified by, but not limited to, 1,1,1,3,5,5,5-heptamethyl-3-ethyltrisiloxane, and the use of the trisiloxane described herein can be used in a variety of spray applications. Is an important example of providing measurable improved properties.

  FIGS. 3 and 4 in the drawing section below show that the run-off effect when using this ETS is not compound dependent but rather is a comprehensive advantage of ETS. 3 and 4 are included to show that the component ETS is the main factor responsible for the reduction in runoff in the example over the comparative example. Comparative Example II has a run-off of 3 on the scale shown above. Example II has zero run-off at the scale shown above. All examples and comparative examples here were sprayed using well prepared spray bottles. Comparative Example II and Example II were applied from the same distance as Example I and Comparative Example I. All data in Table 1 is weight percent data based on the total weight of the trisiloxane-containing composition in each corresponding example and comparative example. Example II and Comparative Example II were applied using the same number of spray sprays as shown in Example I and Comparative Example I.

  Here again, formulations containing cyclopentasiloxane showed significant run-off, while those containing ETS remained in place. FIGS. 1-4 show dry electrophotographic reproductions of photographs of patterns resulting from application of compositions within the scope of the disclosure (Examples I and II) and compositions outside of the scope (Comparative Examples I and II). The photographs were taken immediately after application of the composition (1-6 seconds).

  While the above description includes a number of specific examples, these specific examples should not be construed as limitations of the invention, but merely as exemplifications of preferred embodiments thereof. Those skilled in the art will envision many other embodiments within the scope and spirit of the invention as defined by the claims appended hereto.

Claims (34)

A method for applying a trisiloxane-containing composition to a surface of a substrate is provided, comprising:
General formula (1):
MDM (1)
Applying a trisiloxane-containing composition to the surface of the substrate,
here,
M = R ^A R ^B R ^C SiO _1/2
D = R ^D R ^F SiO _1/2
Wherein R ^D and R ^F are each independently a monovalent, divalent or trivalent hydrocarbon radical having 2 to 8 carbon atoms, or 1 to 60 of other than 2 to 8 carbon atoms. A monovalent, divalent, or trivalent hydrocarbon radical having carbon atoms, provided that at least one of R ^D and R ^F is monovalent, divalent, or trivalent having 2 to 8 carbon atoms And R ^A , R ^B , and R ^C each independently have 1 to 60 carbon atoms other than 2 to 8 carbon atoms, monovalent, divalent, or trivalent The method is a valent hydrocarbon radical. The process according to claim 1, wherein R ^D and / or R ^F is a monovalent, divalent or trivalent hydrocarbon radical having 2 to 6 carbon atoms. The process according to claim 1, wherein R ^D and / or R ^F is a monovalent, divalent or trivalent hydrocarbon radical having 2 to 4 carbon atoms. The method of claim 1, wherein R ^D and / or R ^F is ethyl. The process of claim 1 wherein ^RD is ethyl and ^RF is methyl.   The method of claim 1, wherein the trisiloxane is selected from the group consisting of ethyltrisiloxane, octyltrisiloxane, hexyltrisiloxane, and combinations thereof.   The trisiloxane is 3-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane, 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane, 3- (1-ethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane, , 1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane, 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) Trisiloxane, 3- (1,1-dimethylethyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane, 1,1,1,5,5,5-hexamethyl-3,3 -Bis (1-methylethyl) trisiloxane, 3- (3, -Dimethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane, 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane, 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane, 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) ) Trisiloxane, 1,1,1,3,5,5,5-heptamethyl-3-propyltrisiloxane, 3-isohexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 3 -Tert-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 3-neo-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, , 1,1,5,5,5-hexamethyl- , 3-dipropyltrisiloxane, 3,3-diethyl-1,1,1,5,5,5-hexamethyltrisiloxane, 3,3-dibutyl-1,1,1,5,5,5-hexa Methyltrisiloxane, 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 3-heptyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-diethyltrisiloxane, 1,1,1,3,5,5,5-heptamethyl-3-butyltrisiloxane, and combinations thereof The method of claim 1, wherein the method is selected from the group.   The method of claim 1, wherein the trisiloxane-containing composition may specifically contain less than about 100 percent water, based on the total weight of the trisiloxane-containing composition.   The method of claim 1, wherein the trisiloxane of the trisiloxane-containing composition is present in an amount of about 0.001 to about 99 weight percent.   The method of claim 1, wherein the trisiloxane-containing composition further comprises a formulation component in an amount of about 99 to about 0.001 weight percent.   The compounding ingredients are propellant, surfactant, emulsifier, solvent, emollient, moisture, moisturizer, pigment, colorant, fragrance, biocide, preservative, antioxidant, antibacterial agent, antifungal agent, Insecticides, paints, antiperspirants, spray propellants, exfoliants, alcohol, hormones, enzymes, pharmaceutical compounds, vitamins, alpha hydroxy acids, beta hydroxy acids and / or other hydroxy acids, retinol and its derivatives, niacinamide , Skin lightening agent, salt, electrolyte, polyol, UV absorber, plant extract, organic oil, wax, film-forming element, thickener, fine particle filler, clay, plasticizer, sealant, sensory enhancer, ester The resin and film-forming elements, spherical or other optically active particles, and combinations thereof, wherein The method of mounting.   The trisiloxane-containing composition includes the above-described trisiloxane of the general formula (1), silicone oil, silicone rubber, silicone solid, silicone emulsion, silicone resin, silicone copolyol, alkyl silicone, silicone wax, silicone amine, silicone ammonium. The method of claim 1, further comprising a combination with other types of silicones selected from the group consisting of salts, quaternary silicone amines, spherical silicones, silicone gels, silicone cross-linked networks, polyether silicones, and combinations thereof. The method described.   The method according to claim 1, wherein the trisiloxane-containing composition further contains a silicone fluid other than the trisiloxane of the general formula (1).   14. The method of claim 13, wherein a trisiloxane of a trisiloxane-containing composition and / or a silicone fluid other than the trisiloxane of general formula (1) can be made using a noble metal catalyst.   The method of claim 1, wherein applying the trisiloxane-containing composition comprises using a spray that employs at least one spraying, dispensing, diffusing or atomizing process.   Application of trisiloxane-containing composition is fragrance and lotion pump, mist mist sprayer, special pump, anti-clogging pump, spray through cap, nozzle, airless pump, double dispensing pump, mist mist pump, trigger pump, The method of claim 1, comprising using a spray selected from the group consisting of a foam pump, a trigger sprayer, an aerosol sprayer, a squeeze foamer, and combinations thereof to provide application by the spraying. .   The method of claim 16, wherein applying the trisiloxane-containing composition further comprises spraying from about 0.001 milliliter to about 50 milliliters per spray application.   17. The method of claim 16, wherein applying the trisiloxane-containing composition further comprises using the spray at a distance of about 0.01 to about 10,000 centimeters from the surface of the substrate.   The method according to claim 1, wherein the trisiloxane-containing composition contains other than a cosmetic spray, a gel, or an emulsion.   Reduced run-off, better coating, improved active ingredient distribution and / or performance of the applied trisiloxane-containing composition over sprayable compositions other than those of general formula (1) , Quick drying, less excessive wetting, simple formulation, no stickiness, improved extensibility, improved uniformity, improved organic compatibility, reduced skin irritation, improved active ingredients 2. The at least one of delivery, improved skin feel, improved SPF, less or more desired shine, smaller droplet size, less mechanical stress in the employed spray system. the method of.   21. The method of claim 20, wherein the sprayable composition containing other than the composition of general formula (1) is a volatile siloxane.   The method of claim 21, wherein the volatile siloxane is a cyclic siloxane.   21. The method of claim 20, wherein the flow-down exhibits less downward extension with a single spray on the surface of the substrate.   21. The method of claim 20, wherein the property improvement is synergistic.   Said properties are emulsifiers, preservatives, polymers, thixotropic and non-thixotropic film-forming elements, sunscreens, sunscreens, colorants, pigments, fragrances, active ingredients, retinol and its derivatives, niacinamide, Tocopherol and / or its derivatives, skin lightening agents, moisturizers, sealants, sensory enhancers, esters, other resins and film-forming elements, spherical or other optically active particles, other silicones, emollients, surface activity 21. The method of claim 20, wherein the method is the result of a synergistic effect obtained by using a synergistic component selected from the group consisting of agents and combinations thereof.   The method of claim 1, wherein the application of the trisiloxane-containing composition comprises being used in an application where it is desired that the trisiloxane-containing composition has advantageous properties associated with any coat.   Trisiloxane-containing compositions can be used in aerospace, agriculture, food and beverage, textiles and nonwovens, automobiles, tires, paints, inks, paints, consumption, electronics, semiconductors, healthcare, home care, factory assembly, factory The method of claim 1, which can be used in a market and industry selected from the group consisting of cleaning, molding, packaging and labeling, power distribution and energization, processing industry, transportation, pools and hot springs, motorcycles, personal care, and combinations thereof. the method of.   The personal care market and industry includes deodorants, antiperspirants, antiperspirants / deodorants, shaving products, skin lotions, moisture, lotions, bath products, cleansing products, shampoos, conditioners, shampoo / conditioner combinations, mousses , Styling gel, hair spray, hair dye, hair color product, hair bleaching, curling supplies, curling iron, nail polish, nail polish remover, nail cream and / or lotion, keratin softener, sunscreen, insect repellent, anti-aging product Lipstick, foundation, face powder, eyeliner, eye shadow, blusher, cosmetics, mascara, moisturizing agent, body and hand agent, skin care agent, face and neck agent, tonic, makeup, hair styling aid, aerosol fixative , Fragrance agent After-shave products, cosmetic agents, soft focus agents, day / night skincare agents, non-colored hair agents, tanning agents, synthetic and non-synthetic solid soaps, hand liquids, pore packs, non-fiber for personal care Products, baby lotions, baby bath and / or shampoo products, baby conditioners, shaving agents, cucumber slices, skin pads, makeup removers, facial cleansing products, cold creams, sunscreen products, spritz, paste masks and / or mud, Face mask, colon and lotion, hair cuticle film, shower gel, face and body detergent, personal care washout product, gel, bubble bath, cleanser, astringent, nail conditioner, eye shadow stick, facial skin Ophthalmic powder, lip balm, lip gloss, hair care pump spray and other non-aerosol sprays, curly hair control gel, hair leave conditioner, hair pomade, tangle loosening product, hair fixative, hair bleach product, skin lotion, shaving Before and before shaving, anhydrous creams and / or lotions, oil / water, water / oil, multiple and macro and micro emulsions, pickering emulsions, multiphase emulsions, water resistant creams and / or lotions, anti-acne agents, mouthwash , Massage oils, toothpastes, clear gels and / or sticks, ointment bases, topical wound healing products, aerosol talc, barrier sprays, vitamins and anti-aging agents, herbal extract preparations, bath salts, bath baths And body milk, hair styling aids, hair, eyes, nails, skin soft solid applications, controlled release personal care products, hair condition mist, skin care moisture mist, skin wipe, skin pore wipe, pore cleaner, stain remover, skin Exfoliators, skin desquamator enhancers, skin wet tissues and / or cloths, hair removal agents, personal care lubricants, nail color agents, drug delivery systems for topical administration of pharmaceutical compositions for application to the skin, and 28. The method of claim 27, comprising using a trisiloxane-containing composition in a personal care application selected from the group consisting of:   A personal care application is a sun care formulation that can further contain a sunscreen selected from the group consisting of UV blocking or UV absorbing sunscreens, and combinations containing at least one of the foregoing sunscreens 30. The method of claim 28.   Personal care applications from non-ionic biopolymer blends, polyethoxylated emulsifiers, modified polyacrylates, oils, animal waxes and / or synthetic waxes, hydrocarbon gels or benton type gels, organosilicone emulsifiers, and combinations thereof 30. The method of claim 28, further comprising an emulsifier selected from the group consisting of:   The method of claim 1, wherein the trisiloxane-containing composition can be used in the form of a product from hydrous to non-humidified.   32. The method of claim 31, wherein the product form can be a simple solid, a particle, a liquid, a gel network stable phase, and combinations thereof.   The trisiloxane-containing composition may be used in the form of a product selected from the group consisting of gels, emulsions, dispersions, sludges, powders, rods, sprays, spritz, mousses, sticks, balms, foundations, and combinations thereof. The method of claim 1. The trisiloxane-containing composition of claim 1, further comprising a plasticizer selected from the group consisting of lecithin, polysorbate, dimethicone copolyol, glycol, citrate, glycerin, dimethicone, and combinations thereof. Method.