KR20090118556A - Photo radiate fragrance and press-photo and method for preparing the sameof - Google Patents

Abstract

PURPOSE: A photograph for emitting fragrance and a preparation method thereof are provided to emit fragrance for a long time without additional fragrance-emitting processes. CONSTITUTION: A photograph for emitting fragrance comprises: a photographic paper layer(20); an image layer(30) where various images are shown; and an UV coating layer(40). The UV coating layer is composed of: an UV-curable oligomer which forms a thin layer; an UV-curable monomer which reacts to the oligomer; a photoinitiator to induce polymerization reaction of the monomer and oligomer; and an additive for improving abrasion-resistance and slip-resistance.

Description

Photo radiate fragrance and press-photo and method for preparing the sameof}

The present invention relates to a photo scented fragrance photographs and compressed photographs and to a method of manufacturing the same, and more particularly to forming a UV coating layer formed to prevent discoloration of the photo from ultraviolet rays, and to maintain color as it is stored for a long time. Along with this, a scratch-resistant coating layer having excellent scratch resistance and slip resistance is formed, and natural fragrance or synthetic fragrance is included therein so that the fragrance can be smelled for a long time, so that visual enjoyment and olfactory pleasure can be enjoyed when viewing photos. The present invention relates to a photograph, a compressed photograph, and a manufacturing method thereof, in which a fragrance capable of producing a pleasant environment when stored in an arbitrary place by effectively removing an unpleasant odor such as a chemical agent.

In general, after photographing a subject by a camera, a photograph expresses an image through a method of photosensitive photographic paper and a method of directly printing, and the image expressed on photo paper or the like can be viewed. Therefore, such photographs are widely used for various purposes in the home and industrial fields.

These pictures are used in accordance with various purposes in recent years, according to the expansion and expansion of general cameras, digital cameras, etc., many people are interested in photography to take a variety of images, such as a group having a hobby of shooting and collecting these images, etc. This is active. In line with the trend of the times, not only the photography but also a lot of attention is focused on the printing and storage of photos, and various photo technologies are being disclosed.

Such a photo is formed to be stored for a long time by expressing and printing the image on the first photo paper or the like, by coating a coating on the surface of the image for long time storage without deterioration of color due to the characteristics of the photo. In addition, during printing, the coating material is included in the photo printing ink so that it can be stored for a long time. However, the coating for photo storage used up to now has a problem that an unpleasant odor such as an industrial chemical smell is emitted from the photo after the printing is completed. In addition, when a large number of photographs are stored in a place where such an unpleasant smell is smelled, or when a large number of photographs are displayed at a place such as a photo exhibition, an unpleasant smell such as an industrial chemical smell gives more unpleasant feelings to people, Exposure can cause headaches and the like, and has a problem of causing an uncomfortable environment.

In addition, these photos are produced in the form of albums are widely used in the form of commemorative albums such as weddings, children's growth album. Such a commemorative album is advantageous in storage for a long time, and a compression album method using a compression method is used as a method recently used to be resistant to external contact.

When briefly describing the compressed album method, a plurality of commemorative photographs are placed on the album body each containing a plurality of album sheets, so that the album sheets and the commemorative photos are maintained in a high pressure state by compressing them at high pressure. City, as mentioned above, can be stored for a long time without fear of discoloration, and due to the nature of the commemorative album, many people's hands are in contact with a separate synthetic resin coating to be resistant to scratches due to external contact.

Such a synthetic resin coating also exhibits a high molecular chemical composition, so that when the user first opens the first page to enjoy the album after the first album is produced, unpleasant odors such as chemical chemicals are directly exposed to the user. It is quite unpleasant during photo viewing, and the unpleasant odor makes the surrounding environment uncomfortable, and eventually stops watching the photos. Expensive commemorative albums are simply used for archival purposes. have.

In addition, unpleasant odors such as chemical chemicals are smelled continuously during storage, and eventually the album is stored in a sealed storage space where unpleasant odors do not come out, and the unpleasant odor disappears only when the album is left for a long time. There is a problem that can not watch the album in the desired period.

Therefore, various efforts have been made to remove unpleasant odors from conventional photographs or albums, and in the case of photographs, the fragrance is included in the photo paper so that the scent is smelled separately from the album. It is used to decorate a sachet or fragrance stick. However, photos containing simply sprinkled with fragrance ingredients on the photo paper have a problem that the fragrance period is very short, and when the sachet or fragrance stick is used to decorate the album, the photo is fragile only outside of the album. Poetry is diluted with the unpleasant odor smelled from the compressed photograph of each page, and still has a problem that is quite difficult to solve the above-mentioned problems, and a fundamental solution is desired.

Therefore, the present invention was created to solve the problems described above, by mixing the natural or artificial fragrance with the coating liquid applied to the surface of the photo, without the need to perform a separate fragrance coating only photo coating process It is simple and easy to work with, and thus the fragrance is continuously extracted for a long time from the photo and the album using the same. The purpose is to provide.

Therefore, to solve the object as described above, the photograph of the fragrance in accordance with the present invention is a photo paper layer 20 to form the photo paper; An image layer 30 having various images developed on an upper surface of the photo paper layer 20; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture to the top surface of the image layer 30, the fragrance added to the UV coating agent was formed by mixing an additive that improves the wear resistance or slip resistance of the photograph surface; Characterized in that formed.

Here, the UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimetalol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE 5-15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% of silicone acrylate as an additive %, Dimethyl polysiloxane is composed of 0.1 to 1% by weight, the UV fragrance coating layer 40 is characterized by being prepared by adding 1 to 5% by weight of fragrance with respect to the UV coating agent.

On the other hand, the production method of the photo scented fragrance according to the present invention is a photo paper layer 20 to form the photo paper; An image layer 30 having various images developed on an upper surface of the photo paper layer 20; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture to the top surface of the image layer 30, the fragrance added to the UV coating composition formed by mixing an additive that improves the wear resistance and slip resistance of the photograph surface; Characterized in that formed.

Here, the UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimetalol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE 5-15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% of silicone acrylate as an additive %, Dimethyl polysiloxane is composed of 0.1 to 1% by weight, the UV fragrance coating layer 40 is characterized by being prepared by adding 1 to 5% by weight of fragrance with respect to the UV coating agent.

Further, the flavor is apple flavor, strawberry flavor, grape flavor, vanilla flavor, quince flavor, jasmine flavor, rosemary flavor, acacia flavor, herbal flavor, fruit flavor, hazelnut flavor, mocha flavor, juniper flavor, lilac flavor, lavender flavor, etc. It is preferable to selectively use any one of the fragrance such as natural fragrance or artificial fragrance for fragrance.

On the other hand, the compressed photo fragrance according to the present invention is placed on the surface of the compressed paper and compressed paper compressed by a high pressure by the press to adhere the compressed paper and the photo and the color of the photo on the surface of the photo In the compressed photograph (P) is formed by applying a coating agent for improving the durability against alteration and external contact of the, the compressed paper layer (10) constituting the lowest layer through the compression molding process by pressing; A photo paper layer 20 corresponding to the upper surface of the compressed paper layer 10 and adhered by compression by a press; An image layer 30 on which various images provided on an upper surface of the photo paper layer 20 are printed; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture of the fragrance added to the UV coating agent formed by combining an additive that improves the wear resistance and slip resistance of the photo surface by combining to the upper surface of the image layer 30; Characterized in that formed.

Here, the fragrance coating layer 40 may be formed between the compressed paper layer 20 and the photo paper layer 30 so that the fragrance may be emitted from the photo paper forming the photo paper layer 20 before the first photograph is developed, and the UV coating agent Is 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate (GDA; TRI PROPYLENE) as monomer GLYCOL DI ACRYLATE) 15-25 wt%, Hexane Diol Diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, Trimethylol Propane Triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5-15 % By weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, dimeth Polysiloxanes consist of 0.1 to 1% by weight, the smell diffusion UV coating layer 40 is characterized by being prepared by adding a perfume 1-5% by weight relative to the UV coating.

Furthermore, it is preferable to form a plurality of compressed photos (P) in which the fragrance is smelled in one bundle to form a photo album (A), wherein different fragrances are smelled for each page of the photo album (A), and each By selecting the scent that the consumer wants on each page, the user can see the different scent whenever the user turns the page.

On the other hand, the method for producing a compressed photograph according to the present invention is to place the photograph on the surface of the compressed paper and the compressed paper and compress the film with a high pressure by pressing the compressed paper and the photograph together with the color of the ultraviolet light on the surface of the photograph. Claims [1] A method for manufacturing a compressed photograph formed by applying a coating agent to improve durability against deterioration and external contact, the method comprising: a compressed paper layer (10) constituting a lowermost layer through compression molding by a press; A photo paper layer 20 corresponding to the upper surface of the compressed paper layer 10 and adhered by compression by a press; An image layer 30 on which various images provided on an upper surface of the photo paper layer 20 are printed; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers that are diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and coating films formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture added to the top surface of the image layer 30 by combining the additive to improve the wear resistance and slip resistance of the photo surface by combining with the fragrance; Characterized in that formed.

Here, the fragrance coating layer 40 may be formed between the compressed paper layer 20 and the photo paper layer 30 so that the fragrance may be emitted from the photo paper forming the photo paper layer 20 before the first photograph is developed. 25 to 35 weight percent of epoxy acrylate (EPOXY ACRYLATE RESIN) as oligomer, 3 to 10 weight percent of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as monomer (GDA; TRI PROPYLENE GLYCOL DI) ACRYLATE) 15-25 wt%, hexanediol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimetalol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5-15 wt%, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, dimethyl polysil It is composed of 0.1 to 1% by weight of oxane, the UV odor coating layer 40 is characterized in that it is prepared by adding 1 to 5% by weight of fragrance with respect to the UV coating agent.

In addition, the flavor is apple flavor, strawberry flavor, grape flavor, vanilla flavor, quince flavor, jasmine flavor, rosemary flavor, acacia flavor, herbal flavor, fruit flavor, hazelnut flavor, mocha flavor, juniper flavor, lilac flavor, lavender flavor It is preferable to selectively use a natural or artificial fragrance for fragrance of any one.

The present invention is a natural fragrance or artificial fragrance mixed with the coating liquid and applied to the surface of the photo, it is possible to simply and easily work only by the photo coating coating process without performing a separate fragrance work, accordingly the photo and using the same Since the fragrance is continuously extracted from the album for a long time, there is an effect that can always give the user a fresh feeling of comfort and enjoyment of photographs.

Hereinafter, with reference to the accompanying drawings will be described in detail the configuration and operation of the fragrance-flavored photographs and compressed photographs and manufacturing methods thereof according to the present invention.

1 is a cross-sectional view showing a layer structure of a photo fragrance and a manufacturing method according to the present invention, as shown, the photo paper layer 20, the image layer prepared by applying a UV coating fragrant fragrance on the photo surface On the surface of the image layer (30) of the photo composed of 30 improves the durability of the color change and external contact due to ultraviolet rays, as well as forming a UV-scented coating layer 40 to smell the fragrance when photographing enjoy the user It is prepared to double.

Here, the fragrance-flavored UV coating agent as an oligomer is UV curable oligomer introduced in 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN), 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), and as a monomer 15-25 wt% propylene glycol diacrylate (TPGDA; TRI PROPYLENE GLYCOL DI ACRYLATE), 10-20 wt% hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE), trimetholpropane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5-15% by weight, UV-curable monomer added in 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), the UV-curable oligomer and UV-curable monomer 5-10% by weight of a photo initiator, 0.1-1% by weight of silicone acrylate (SILICONE ACRYLATE), dimethyl polysil Acid (DIMETHYL POLYSILOXANE) the mixture was added the perfume 1-5% by weight relative to the total weight of the UV coating by mixing an additive for improving the surface is added to 0.1 to 1% by weight.

Here, the oligomer is the most important component that determines the overall physical properties of the UV coating agent, the epoxy acrylate (EPOXY ACRYLATE RESIN) is an ultraviolet curing oligomer, the main element required to form a coating film on the surface of the photo to form a coating film It is the main element that becomes the basic skeleton to determine the characteristics of. In addition, it is excellent in heat resistance according to the external temperature change, and excellent in water resistance and chemical resistance.

The polyester acrylate (POLYESTER ACRYLATE RESIN) is an ultraviolet curable oligomer, such as epoxy acrylate, is an element that improves the glossiness and the drying speed while forming the entire coating film of the photo surface.

On the other hand, a monomer called a reactive diluent is added. Such monomers are monofunctional to 6 functional and generally 1 to 4 functional groups. Here, the more functional groups of monomers, the better sclerosis | hardenability and the coating film physical property also improves. The monofunctional monomers in monomo are not frequently used for general hard coatings applied to the surface of the photo due to severe skin irritation and low curing density when in contact with the human body. The bifunctional monomers include hexane diol diacrylate and tripropylene glycol diacrylate, trimethol propane triacrylate as a trifunctional monomer, and PETA as a tetrafunctional monomer. In general, monomers used as reactive diluents are mainly bifunctional monomoth hexane diol diacrylate and trimethol propane triacrylate, and acrylate and trimethol propane triacrylate are well adhered.

Therefore, among the monomers which are reactive diluents in the present invention, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATETPGDA), tripropylene glycol diacrylate (TPGDA; TRI PROPYLENE GLYCOL DI ACRYLATE), and trimetholol Propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) and polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE) are added.

Here, hexane diol diacrylate forms the coating film properties and viscosity and the whole coating film, and imparts dissolution and flexibility of various components. In addition, the tripropylene glycol diacrylate forms a coating film, a viscosity control and a total coating film, and improves flexibility and drying speed.

In addition, the trimethol propane triacrylate is to control the coating properties and viscosity and form a full coating film and improve the hardness and drying speed of the coating film. In addition, the polyethylene glycol 400 diacrylate forms a coating film, a viscosity control, and a whole coating film, and gives flexibility.

The photo initiator (PHOTO INITIATOR) absorbs the ultraviolet energy emitted from the ultraviolet lamp and is added as an initiator to start the polymerization reaction of the oligomer of the epoxy acrylate, polyester acrylate and each monomer.

On the other hand, when the UV odor coating layer 40 is formed on the photographic surface, an additive is added to chemically bond with the coating film formed by the oligomer and the monomer to have excellent wear resistance or slip resistance. Here, as an additive, silicone acrylate and dimethyl polysiloxane are added.

The silicone acrylate (SILICONE ACRYLATE) is to remove the bubbles generated during the production of the compressed photograph and the coating of the UV coating on the surface, and improve the scratch resistance of the photo surface, thereby increasing the wear resistance.

The dimethyl polysiloxane (DIMETHYL POLYSILOXANE) improves the material wettability of the UV coating agent and provides slip property to the photo surface and prevents blocking between the coated film or the coating film during storage and loading of the photo.

1 to 5% by weight of the fragrance is added to the total weight of the oligomer, monomer, initiator and additives into the UV coating agent. Here, the flavor is apple flavor, strawberry flavor, grape flavor, vanilla flavor, quince flavor, jasmine flavor, rosemary flavor, acacia flavor, herbal flavor, fruit flavor, hazelnut flavor, mocha flavor, juniper flavor, lilac flavor, lavender flavor, etc. It is preferably used selectively to smell any one of natural flavors, artificial flavors and the like.

On the other hand, the fragrance is added to the liquid in accordance with the thermal stability, intrinsic fragrance strength and persistence according to the fragrance, as described above, 1 to 5% by weight relative to the total weight of the oligomer, monomer and initiator, UV coating agent as an additive Preference is given to adding%. That is, when added to the UV coating agent in less than 1.0% by weight when forming the UV fragrance coating layer 40 on the photo surface, the persistence of the fragrance is reduced. And, if the content exceeds 5.0% by weight, the persistence of the fragrance is greatly improved. However, the fragrance of the fragrance is too strong, causing headaches and the like, and thus the picture can not be sustained for a long time.

Therefore, the method for producing a fragrance-flavored photo according to the present invention using the fragrance-added UV coating mixture is applied by coating on the surface of the image layer 30 in which the image of the image is developed, thereby producing a fragrance of the fragrance. Can be achieved. On the other hand, it may be used more widely by applying to a printed matter in which an image such as a magazine, a catalog, or the like is developed through a method of manufacturing a photo in which the fragrance is smelled.

On the other hand, Figure 2 is a cross-sectional view showing a layer structure according to the production method and the compressed photo scented fragrance according to the present invention, as shown is produced by applying a UV coating agent for the fragrance scent to the photo surface is produced by compression molding, processing Compressed paper layer 10, photo paper layer 20, the image layer 30 to be composed of the compressed paper and the compressed paper so that the photo is placed on the surface of the compressed paper by compressing with a high pressure by pressing the photo with the compressed paper It is manufactured to enhance the user's enjoyment by forming the UV odor coating layer 40 so as to smell the fragrance when photographing as well as improve the durability of the color change and external contact due to ultraviolet rays on the surface of the above, The UV fragrance coating layer 40 is formed by the UV coating mixture to which the fragrance applied to the photo paper layer 30 of the photograph is added.

Therefore, the method for producing a fragrance-flavored compressed photo according to the present invention using the fragrance-added UV coating mixture by compressing by pressing the image is placed on the photo paper on the surface of the compressed paper produced by the size of the photo In accordance with the conventional compressed photographic production method for adhering photographs printed with images to compressed paper and photo paper.

At this time, after compressing the photograph with a compressed paper, by applying a UV coating agent for smell fragrance on the surface of the photo to form a fragrance UV fragrance coating layer 40, as shown in Figures 2 and 3, the compressed paper layer 10, the photo paper layer 20, the image layer 30, the UV odor coating layer 40 can be formed to obtain a compressed picture of the fragrance according to the present invention.

Here, the adhesion of the compressed paper and the photo by the press is adhered according to the close contact between the pores of the compressed paper and the photo by the compression, rather than by a separate adhesive, such as industrial chemicals of the adhesive according to the use of a conventional adhesive Unpleasant odors do not emanate and do not affect the fragrance of the fragrance by fragrance, and the fragrance of the fragrance can be fragrant for a long time.

In addition, as shown in Figure 4, by binding a plurality of compressed photos by a method of manufacturing a compressed photo fragrance scent according to the present invention in one bundle, it is possible to produce an album that smells fragrance, UV fragrance coating layer 40 formed on the compressed photograph constituting each page, apple flavor, strawberry flavor, grape flavor, vanilla flavor, quince flavor, jasmine flavor, rosemary flavor, acacia flavor, herbal flavor, fruit flavor, hazelnut flavor By using various natural or artificial fragrances such as mocha, juniper, lilac, lavender, and other fragrances, different fragrances are generated on each page of the album. You can enjoy the pictures.

In other words, when producing an album using a compressed picture that smells like this, it is obvious that it is also possible to produce an album that smells its own fragrance by implementing various scents according to the taste of the consumer requesting the album.

On the other hand, as shown in Figure 5, by forming a compressed paper layer 10-UV fragrance coating layer 40-photo paper layer 20-image layer 30, when producing an album, a picture of a separate fragrance is smelled during the album production Even if it is not produced, it is preferable to attach the photo to the compressed paper layer 10 which smells scents continuously, so that the production of an album smells scents is possible. In other words, the present invention is not limited to photographs and albums, and can be used for printed materials requiring fragrance of fragrance in general.

In addition, the compressed paper layer 10 is selected from any one of paper, polypropylene, acrylic and can be changed depending on the use, and by using a variety of materials, it is formed to exhibit high quality.

The fragrance of the present invention according to the configuration as described above, the photograph and the compressed photo and the manufacturing method thereof will be described in detail through the embodiment.

[Examples 1 to 5] A UV coating mixture was prepared in which a fragrance was scented so that the lilac flavor selected from natural or artificial flavors was 1.0 to 5.0% by weight based on 100% by weight of the UV coating agent of the oligomer, monomer, initiator, and additive mixture. Afterwards, the UV coating mixture was coated on the surface of the image layer 30 of the developed image to obtain a photo of fragrance. The photographic specimens with fragrant fragrance thus obtained were exposed to room temperature and left for 3 months, and then 10 panelists with well developed sense of smell were subjected to sensory evaluation on a five-point scale. In addition, the sensory test was performed on the appearance of the fragrance, the fragrance persistence, the appearance of bubbles, and the surface defects. The results are shown in Table 1 below.

[Comparative Examples 1 to 3] Compared with Examples, 0.1 and 10 parts by weight of the perfume were added to the total weight% of the UV coating agent of the oligomer, monomer, initiator, and additive mixture, and the same as in Example. The results of the sensory tests are shown in Table 1 together.

division UV coating material composition with fragrance Fragrance Persistence Exterior Example 1 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 1.0 wt%  △  △  ● Example 2 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 2.0 wt%  △  △  ● Example 3 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 3.0 wt%  ○  △  ● Example 4 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 4.0 wt%  ○  ○  ● Example 5 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 5.0 wt%  ●  ○  ● Comparative Example 1 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 0.1 wt%  △  X  ● Comparative Example 2 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 10.0 wt%  ●  ●  ● Comparative Example 3 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lilac flavor 0.0 wt%  X  X  ●

※ ●: Very good, ○: Good, △: Normal, X: Poor

As shown in Table 1, the fragrance scented from the photo coated with the UV coating agent mixed with the fragrance according to the present invention is controlled by the coating film by the UV coating agent, the fragrance and persistence of the fragrance is significantly controlled, so that the sensory test for 3 months Through the exposure to the air in the room through the normal smell was able to confirm that the soft fragrance emanates. In addition, as shown in Table 1, no special damage to the appearance was observed by the surface improvement additive added to the UV coating agent, and despite being continually drawn into the air due to the characteristics of being exposed to air for 3 months, The odor of the subject was excellent, and the persistence was slightly lower. And the appearance damage of the photograph was very good.

In addition, the persistence of the fragrance was found to be more than the average result except when not added at all and 0.1% by weight. Here, after the initial fragrance of fragrance persistence, the subject continuously judged the persistence of taking the fragrance, and the addition of 10% by weight of fragrance was excellent in the persistence of fragrance. The fragrance of the scent was too strong, causing headaches or dizziness.

Therefore, as shown in Table 1, by adding a fragrance 1.0 to 5.0% by weight to the UV coating agent and applied to the photo, it was confirmed that the fragrance and the persistence of the fragrance excellent.

[Examples 6 to 10] A UV coating mixture was prepared in which a fragrance was scented so that the selected lavender flavor among natural or artificial flavors was 1.0 to 5.0% by weight based on 100% by weight of the UV coating agent of the oligomer, monomer, initiator, and additive mixture. Thereafter, it was applied to a photograph placed on the surface of the compressed paper and compression molded by a press to obtain a compressed photograph in which the fragrance was smelled. The fragrance-produced compressed photographic specimens were left at room temperature for 10 months, and 10 panelists with well developed sense of smell were subjected to sensory evaluation on a five-point scale. In addition, the sensory test was performed on the appearance of the fragrance, the persistence of the fragrance, the appearance of bubbles, and the surface defects. The results are shown in Table 2 below.

[Comparative Examples 4 to 6] Compared with Examples, 0.1 and 10 parts by weight of the perfume were added to the total weight% of the UV coating agent of the oligomer, monomer, initiator, and additive mixture, and the same as in Example. The results of the sensory tests are shown in Table 1 together.

division UV coating material composition with fragrance Fragrance Persistence Exterior Example 6 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 1.0% by weight  △  △  ● Example 7 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 2.0 wt%  ○  ○  ● Example 8 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 3.0 wt%  ●  ○  ● Example 9 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 4.0% by weight  ●  ●  ● Example 10 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 5.0 wt%  ●  ●  ● Comparative Example 4 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 0.1 wt%  △  X  ● Comparative Example 5 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 10.0% by weight  ●  ●  ● Comparative Example 6 Total weight of UV coating agent of oligomer, monomer, initiator, and additive mixture Lavender Flavor 0.0 wt%  X  X  ●

※ ●: Very good, ○: Good, △: Normal, X: Poor

Currently, the fragrance mixture or fragrance preserved in the sachet of the gel is generally released in about 1 to 2 months, almost no fragrance, as shown in Table 2 coated with a UV coating mixed with the fragrance according to the present invention The fragrance that is smelled by making album from the compressed photos of the fragrance is controlled by the coating film by UV coating, and the fragrance and persistence of the fragrance are greatly controlled. there was. That is, as shown in Table 2, no damage to the appearance was observed by the surface improvement additive added to the UV coating agent, and despite the 10 months of standing, damage of the appearance was very good.

In addition, the persistence of the fragrance was found to be more than the average result except when not added at all and 0.1% by weight. Here, the normality of fragrance persistence was based on 3 months. The addition of 10% by weight of the fragrance is excellent in the persistence of the fragrance, but when the user views the album or keeps the album indoors, the fragrance of the fragrance is so strong that only the user living in the room has a headache or dizziness. Evoking results were shown.

Therefore, as shown in Table 2, it was confirmed that the fragrance and the persistence of the fragrance were excellent by adding 1.0 to 5.0% by weight of perfume to the UV coating agent.

On the other hand, in the detailed description of the present invention has been described with respect to specific embodiments, to those skilled in the art that various modifications are possible without departing from the scope of the invention, such modifications are claimed It is within the scope of the description.

1 is a cross-sectional view showing a layer structure in the photo fragrance and a manufacturing method according to the present invention.

Figure 2 is a cross-sectional view showing a layered structure of the compressed photo according to the invention and the compressed photo fragrance according to the present invention.

Figure 3 is a perspective view showing the layered structure of the compressed photograph according to the invention and the compressed photograph fragrant fragrance according to the present invention.

4 is a view showing an album according to the fragrance-flavored pictures and compressed photos and a method for producing the same according to the present invention.

Figure 5 is a cross-sectional view showing a layer structure of another embodiment according to the photograph and the compressed photograph and the manufacturing method thereof for the fragrance according to the present invention.

* Explanation of the major symbols in the drawings *

10: compressed layer 20: photo layer

30: image layer 40: UV odor coating layer

P: Compressed Pictures A: Album

Claims (13)

In photographs with developed images on photo paper, A photo paper layer 20 forming the photo paper; An image layer 30 having various images developed on an upper surface of the photo paper layer 20; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture to the top surface of the image layer 30, the fragrance added to the UV coating agent was formed by mixing an additive that improves the wear resistance or slip resistance of the photograph surface; The fragrance is characterized by the fragrance photo formed. The method of claim 1, The UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA) ; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimethylol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5 ~ 15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, Dimethyl polysiloxane is composed of 0.1 to 1% by weight, the UV fragrance coating layer 40 is a fragrance-flavored picture, characterized in that is prepared by adding 1 to 5% by weight fragrance with respect to the UV coating agent. In the manufacturing method of a photo in which an image is developed on a photo paper, A photo paper layer 20 forming the photo paper; An image layer 30 having various images developed on an upper surface of the photo paper layer 20; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture to the top surface of the image layer 30, the fragrance added to the UV coating composition formed by mixing an additive that improves the wear resistance and slip resistance of the photograph surface; Method of producing a photo of the fragrance is characterized in that it is formed into. The method of claim 3, wherein The UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA) ; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimethylol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5 ~ 15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, Dimethyl polysiloxane is composed of 0.1 to 1% by weight, the UV fragrance coating layer 40 is produced by adding a fragrance 1 to 5% by weight with respect to the UV coating agent, the fragrance of the fragrance of the photo production room . The method according to claim 3 or 4, The flavor is apple flavor, strawberry flavor, grape flavor, vanilla flavor, quince flavor, jasmine flavor, rosemary flavor, acacia flavor, herbal flavor, fruit flavor, hazelnut flavor, mocha flavor, juniper flavor, lilac flavor, lavender flavor, etc. Photograph fragrance is characterized by using any one of the fragrance, such as natural fragrance or artificial fragrance selectively. A coating agent for placing the photograph on the surface of the compressed paper and the compressed paper and compressing it with a high pressure by a press to bond the compressed paper with the photo, and to improve the durability of the color change and external contact caused by UV on the surface of the photo. In the compressed photograph P formed by applying A compressed paper layer 10 constituting the lowermost layer by compression molding by pressing; A photo paper layer 20 corresponding to the upper surface of the compressed paper layer 10 and adhered by compression by a press; An image layer 30 on which various images provided on an upper surface of the photo paper layer 20 are printed; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture of the fragrance added to the UV coating agent formed by combining an additive that improves the wear resistance and slip resistance of the photo surface by combining to the upper surface of the image layer 30; Compressed photos that are fragrant, characterized in that formed as. The method of claim 6, The fragrance coating layer 40 is formed between the compressed paper layer 20 and the photo paper layer 30 so that the fragrance is smelled from the photo paper constituting the photo paper layer 20 before the first photograph is developed, the compressed fragrance is smelled Picture. The method of claim 6, The UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA) ; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexanediol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimethylol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5 ~ 15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, Composed of 0.1 to 1% by weight of dimethyl polysiloxane, the UV odor coating layer 40 is a fragrance-flavored compressed picture, characterized in that is prepared by adding 1 to 5% by weight of fragrance with respect to the UV coating agent. The method of claim 6, Form a plurality of compressed photos (P) in which the fragrance is smelled in one bundle to constitute a photo album (A), but different fragrance is selected for each page of the photo album (A) according to the user's taste Compressed photograph, characterized in that formed as. A coating agent for placing the photograph on the surface of the compressed paper and the compressed paper and compressing it with a high pressure by a press to bond the compressed paper with the photo, and to improve the durability of the color change and external contact caused by UV on the surface of the photo. In the method for producing a compressed photograph formed by applying a, A compressed paper layer 10 constituting the lowermost layer by compression molding by pressing; A photo paper layer 20 corresponding to the upper surface of the compressed paper layer 10 and adhered by compression by a press; An image layer 30 on which various images provided on an upper surface of the photo paper layer 20 are printed; UV-curable oligomers that form a film on the photo surface depending on their overall physical properties, UV-curable monomers as diluents that react with the oligomers, photoinitiators that induce polymerization of the oligomers and monomers, and chemically formulated coatings formed by oligomers and monomers UV fragrance coating layer 40 formed by applying a mixture of the fragrance added to the UV coating agent formed by combining an additive that improves the wear resistance and slip resistance of the photo surface by combining to the upper surface of the image layer 30; Method for producing a compressed photograph fragrant fragrance, characterized in that formed in. The method of claim 10, The fragrance coating layer 40 is formed between the compressed paper layer 20 and the photo paper layer 30 so that the fragrance is smelled from the photo paper constituting the photo paper layer 20 before the first photograph is developed, the compressed fragrance is smelled How to make a photo. The method of claim 10, The UV coating agent based on the total weight of 25 to 35% by weight of epoxy acrylate (EPOXY ACRYLATE RESIN) as an oligomer, 3 to 10% by weight of polyester acrylate (POLYESTER ACRYLATE RESIN), tripropylene glycol diacrylate as a monomer (GDA) ; TRI PROPYLENE GLYCOL DI ACRYLATE) 15-25 wt%, hexane diol diacrylate (HDDA; 1.6 HEXAN DIOL DI ACRYLATE) 10-20 wt%, trimethylol propane triacrylate (TMPTA; TRI METHYLOL PROPANE TRI ACRYLATE) 5 ~ 15% by weight, 5-10% by weight of polyethylene glycol 400 diacrylate (PEG400DA; POLY ETHYLENE GLYCOL 400 DI ACRYLATE), 5-10% by weight of photo initiator, 0.1-1% by weight of silicone acrylate as an additive, Dimethyl polysiloxane is composed of 0.1 to 1% by weight, the UV fragrance coating layer 40 is a fragrance-flavored compressed photograph of the fragrance, characterized in that manufactured by adding 1 to 5% by weight of fragrance with respect to the UV coating agent Method. The method according to any one of claims 10 to 12, The flavor is apple, strawberry, grape, vanilla, quince, jasmine, rosemary, acacia, herb, fruit, hazelnut, mocha, juniper, lilac, lavender Method of producing a compressed scented fragrance, characterized in that the natural fragrance or artificial fragrance that uses the fragrance selectively.

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