KR20090095342A - Personal cleansing composition comprising self emulsified silicone copolymer - Google Patents

Abstract

A composition for body cleansing, which contains a self emulsified silicon copolymer is provided to ensure moisturization and elasticity of hair and enhance the conditioning effect. A composition for body cleansing comprises anionic surfactant, level four ammonium cationic surfactant, further contains a self emulsified silicon copolymer. The self emulsified silicon copolymer comprises a main chain by polymerizing the level four cationic monomer of the chemical formula 1 and non-ionic soluble polymer monomer and a side chain of silicone macromer of the chemical formula 2. The self emulsified silicon copolymer forms copolymerization further comprising a polyalkyleneglycol macromer of the chemical formula 3.

Description

Personal cleansing composition comprising self emulsified silicone copolymer

The present invention relates to a human cleansing composition comprising a self-emulsifying silicone copolymer, and more particularly, to a human cleansing composition that protects hair and skin, has an excellent moisturizing and softening effect, and changes physical properties of coacetate.

Recently, skin and hair are not only damaged by wind, heat, sun, pollution and many other factors, but as the standard of living improves, interest in beauty is increasing.

Accordingly, there has been a continuous research on detergents or cosmetics that improve the softness of skin or hair and have a moisturizing and softening effect during or after cleaning. In particular, as various products are commercialized, they have excellent feelings for cleaning agents that emphasized only the cleaning function in the past, and in order to prevent moisturizing and damage of skin and hair and to impart conditioning effects, they exhibit various effects in addition to the cleaning surfactant which is the main ingredient. Products with added ingredients have been introduced and their use is on the rise.

Among them, the quaternary cationic polymer is a component that absorbs hair and skin and provides conditioning effect. Among the cosmetic ingredients that are widely used for softness, softening effect, moisturizing, thickening, and bubble stabilizing effect in various hair and skin products. One. Generally, synthetic polymers cationicly polymerized using monomers such as cationic cellulose, cationic guar gum, vinylpyrrolidone, vinyl acetate, methacrylate, and vinylimidazolinium are used.

However, when these cationic polymers are used alone, hair or skin tenderness can be provided, but other characteristics such as smoothness and gloss cannot be provided, and the hygroscopicity of the polymer while the hair or skin is dried There is a problem that the feeling of use is degraded by showing a feeling of damp and sticky.

To solve these problems, hair and skin products are being used with oily ingredients such as silicones, oils and waxes to protect hair and skin, prevent damage and impart conditioning effects. It is a trend.

In this regard, Korean Patent Laid-Open Publication No. 10-0316976 discloses a silicone compound such as water insoluble nonvolatile dimethicone, cyclomethicone, amino silicone, amodimethicone, trimethylsilyl amodimethicone, and the like as a hair conditioning component. Disclosed is a technique using a derivative of.

In addition, US Patent Nos. 5,104,646 and 6,930,078 have attempted to increase the conditioning effect by increasing the adsorption of hair conditioning components such as silicone to the hair using coacetate produced by anionic surfactants and cationic polymers.

However, these oily components have the disadvantage of using additional stabilizing materials such as thickeners and surfactants in order to be able to be present stably in the composition. Further, by simply adding these conditioning components or by providing a coacervate by a simple combination of an anionic detergent and a cationic polymer, it imparts a conditioning effect, and there is a disadvantage in that the amount of coacetate is not generated much and the conditioning effect is weak.

Therefore, the problem to be solved by the present invention is excellent in the feeling of use, it can impart excellent protection, moisturizing, softness, suppleness, smoothness and shine effect to the hair and skin, and change the physical properties of coacervate to feel the use of coacervate To improve and increase the adsorption of the conditioning component to provide a composition for cleaning the human body that can optimize the conditioning effect.

In order to solve the above problems, the composition for washing human body of the present invention, in the composition for washing human body comprising an anionic surfactant, quaternary ammonium cation surfactant, N-vinyl-2-pyrrolidone, acrylic acid, methacrylic acid, maleic acid, acrylamide, methacrylamide, N, N-dimethyl acrylamide, hydroxy ethyl acrylate, hydroxy ethyl methacrylate, hydroxy propyl acrylic Nonionic water-soluble polymer monomers, which are any one or a mixture of two or more selected from the group consisting of latex and hydroxy propyl methacrylate; And

It is represented by the following formula (1),

R ₁ in formula is hydrogen or an alkyl group having 1 ~ 3, R ₂ is -C _n H _2n - is represented by n is an integer of 1-5, X represents -COO-, -CONH-, or -OCO- And Y is a halogen ion or methyl sulfate ion, and R ₃ , R ₄ and R ₅ are each independently a quaternary cationic monomer which is an alkyl group having 1 to 3 carbon atoms;

Is polymerized to form a main chain,

It is represented by the formula (2)

Wherein R ₁ is hydrogen or an alkyl group of 1 to 3 carbon atoms, R ₂ is a hydroxy group, an alkyl group of 1 to 3 carbon atoms or a vinyl group capable of addition polymerization, m is an integer of 1 to 5, n is 10 to 1,000 It is characterized in that it further comprises a self-emulsifying silicone copolymer formed by forming a side chain is an integer silicone macromer.

In addition, the above-mentioned self-emulsifying silicone copolymer may be copolymerized by further including a polyalkylene glycol macromer represented by the following Chemical Formula 3 as a side chain.

In formula, R <_1> , R <_2> is hydrogen or a C1-C3 alkyl group, m and n are the integers of 0-1,000 each independently.

In the human body cleaning composition of the present invention, the quaternary ammonium cationic surfactant may be represented by the following formula (4).

Wherein R is any one selected from the group consisting of a straight alkyl group having 12 to 22 carbon atoms, a branched alkyl group and an alkenyl group, n is an integer of 0 to 10, and X is a halogen group element, a sulfate group and an acetate group Any one selected from the group.

The composition for washing the human body of the present invention has excellent feeling and can show excellent protection, moisturizing, softness, softness, smoothness and shine effect on hair and skin, and can increase the adsorption of conditioning ingredients to optimize the conditioning effect. have.

Hereinafter, the composition for washing human body of the present invention will be described in detail. The terms or words used in this specification and claims are not to be construed as being limited to the common or dictionary meanings, and the inventors may appropriately define the concept of terms in order to best describe their inventions. It should be interpreted as meaning and concept corresponding to the technical idea of the present invention based on the principle that the present invention.

In order to solve the above-mentioned conventional problems, the composition for cleaning human body of the present invention is an anionic surfactant quaternary ammonium cationic surfactant and a specific water-soluble monomer, a quaternary cationic monomer represented by a specific formula and a silicone represented by a specific formula It is characterized in that it comprises a self-emulsifiable silicone copolymer formed by copolymerizing the macromer.

As the nonionic water soluble monomer used to form the self-emulsifying silicone copolymer according to the present invention, a monomer of a nonionic water soluble polymer including a vinyl group capable of addition polymerization may be used. For example, N-vinyl-2-pyrrolidone, acrylic acid, methacrylic acid, maleic acid, acrylic and methacrylic amides, N, N-dimethyl acrylamide, hydroxy ethyl acrylate and methacrylate, hydroxy propyl acrylic One or more nonionic water soluble monomers selected from the group consisting of rate and methacrylate may be used for the copolymerization.

The content of the water-soluble monomer is preferably 1 to 90% by weight relative to the total weight of the copolymer. When the water-soluble monomer according to the present invention is in the above content range, it is possible to form a self-emulsifying silicone copolymer with a stable phase.

Used to form the self-emulsifying silicone copolymer according to the present invention, the content of the quaternary cationic monomer represented by Formula 1 is preferably 1 to 60% by weight based on the total weight of the copolymer. In the above content range, the silicone can be adsorbed to the hair very efficiently.

Used to form a self-emulsifying silicone copolymer according to the present invention, the content of the silicone macromer represented by Formula 2 is preferably 5 to 90% by weight, and 20 to 70% by weight based on the total weight of the copolymer. More preferred. If the content is less than 5% by weight, the softness, smoothness and luster of the hair are less likely to appear. If the content is more than 90% by weight, the self-emulsifying silicone copolymer does not form a stable phase in the water phase, and the hair stiffness and feeling of use are poor. You may not.

In the preparation of the self-emulsifying silicone copolymer according to the present invention, the monomer content of the polyalkylene glycol macromer represented by Formula 3, which may be further included as necessary, is 1 to 50% by weight based on the total weight of the copolymer. It is preferable. In the above content range, the moisture and volume of the hair may be very excellent.

In addition, when a polyalkylene glycol macromer is used as a monomer, in the self-emulsifying silicone copolymer according to the present invention, the water-soluble monomer, the quaternary cationic monomer and the polyalkylene glycol macromer The copolymer may be formed to 10 to 95% by weight, preferably 20 to 80% by weight. When the total content of the nonionic water-soluble polymer monomer, the quaternary cationic monomer and the polyalkylene glycol macromer is less than 10% of the total weight of the copolymer, the self-emulsifying silicone copolymer does not form a stable phase in the aqueous phase, and is not less than 95%. In this case, the content of silicone is relatively small, and it is difficult to show softness, smoothness, and gloss of hair. In this case, only the quaternary cationic monomer and the polyalkylene glycol macromer may be included in an amount of 10 to 95 wt% based on the total weight of the copolymer, in which case the polyalkylene glycol macromer is not included. 3-40 wt% of the total weight of the copolymer may be included. At this time, when the polyalkylene glycol macromer is in the above content range, the phase stability of the copolymer is excellent.

As an initiator for synthesizing the self-emulsifying silicone copolymer according to the present invention using the above-mentioned monomer, an initiator for radical polymerization used in the art may be used without limitation. For example, 2,2'-azobisnitrile (AIBN), 2,2'-azobis- (2,4-dimethylvalenonitrile), dimethyl 2,2'-azobis- (2-methylpropio Azo compounds such as nate), 2,2'-azobis- (4-methoxy-2,4-dimethylvalenonitrile), benzoyl peroxide, laurolei peroxide, t-butylperoxy pivalate, 1, Organic peroxides such as 1′-bis- (bis-t-butylperoxy) cyclohexane and redox initiators such as ammonium persulfate and potassium persulfate may be used, but are not limited thereto.

In the composition for washing human body of the present invention, the content of the self-emulsifying silicone copolymer may be variously selected according to the use of the composition, for example, 0.001 to 10% by weight, preferably 0.01 to the total weight of the composition. It may be 5% by weight. It can be excellent in the protection, moisturizing and softening effect on the hair and skin in the content range.

The quaternary ammonium cation surfactant included in the human cleansing composition of the present invention is used to increase the amount of coacetate produced, and may be used without limitation as long as it is used in the art. For example, quaternary ammonium cationic surfactants represented by Formula 4 may be used.

Referring to Formula 4, one of the substituents of the ammonium ion is a structure consisting essentially of an alkylamidopropyl group, the other is a structure in which a glyceryl group having a repeating unit of 1 to 11 is condensed with a hydrophilic group, and the other two Substituents consist of a methyl group.

The quaternary ammonium cationic surfactant contains at least one hydrophilic group glyceryl group, and is dissolved in an aqueous solution commonly called pseudo-nonionic complex surfactant through interaction with an anionic surfactant. Mixed micelles can be formed. Since the pseudo-nonionic complex surfactant improves problems such as high viscosity and precipitation occurring when the cationic polymer and the anionic surfactant are used at the same time, the amount of the cationic polymer can be increased even in the presence of the anionic surfactant.

In addition, the quaternary ammonium cation surfactant of Formula 4 includes an alkylamido group having a relatively hydrophilic property instead of a long chain fatty acid group, so that the mixed micelle formation ability of a pseudo-nonionic complex surfactant is better. In the presence of an anionic surfactant, the amount of the cationic polymer can be further increased, and as a result, more coacervate, which is a complex of the anionic surfactant and the cationic polymer, can be produced.

The quaternary ammonium cationic surfactant may be included in the composition in an appropriate amount according to the specific use of the composition of the present invention. For example, it may be 0.001 to 10% by weight relative to the total weight of the composition. If the content is less than 0.001% by weight, it is difficult to achieve conditioning and stability improvement effect by increasing coacetate formation by quaternary ammonium cationic surfactant, and when it exceeds 10% by weight, it gives a damp feeling to hair and precipitates and phase stability. There is a risk of inhibition and may not be suitable for use.

The anionic surfactant used in the present invention is used to exhibit cleaning and foaming properties, and may be used without particular limitation as long as it can be used in a conventional human cleansing composition. For example, sodium lauryl sulfate, lauryl ammonium sulfate, lauryl magnesium sulfate, lauryl sulfate triethanolamine, sodium polyoxyethylene lauryl sulfate, polyoxyethylene lauryl sulfate, sulfonate type surfactant, sulfosuccinate type It may be any one or a mixture of two or more selected from the group consisting of surfactants, sulfate-based surfactants, carboxylate-based surfactants and amino acid-based surfactants, but is not limited thereto.

In the present invention, the anionic surfactant may be included in the composition in an appropriate amount according to the specific use of the composition of the present invention. For example, it is preferably 1 to 50% by weight based on the total weight of the composition. If the content is less than 1% by weight, the washing function is not properly exerted, and when the content exceeds 50% by weight, the washing power is excessive, which may give a rough feeling to the hair.

The human cleansing composition of the present invention may further include a natural or synthetic cationic polymer in addition to the self-emulsifying silicone copolymer. The cationic polymer is not particularly limited as long as it can be generally used in the composition for washing human body, for example, at least one selected from the group consisting of natural cationic polymer, synthetic cationic polymer and mixtures thereof. Can be.

As the natural cationic polymer that can be included in the cleaning composition of the present invention, for example, cationic guar such as guarhydroxypropyltrimonium chloride, hydroxypropyl guarhydroxypropyltrimonium chloride, cellulose (polyquaternium-10) ) May be used one or more, but is not limited thereto.

In addition, as the synthetic cationic polymer that can be used in the human cleansing composition of the present invention, for example, dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, polyvinylpyrrolidone (PVP)- Any one or two selected from the group consisting of dimethylaminoethyl methacrylate copolymer, acrylic acid-dimethyldiallylammonium chloride copolymer, acrylamide-dimethylamino ethylmethacrylate methyl chloride copolymer, trimethylaminoethyl methacrylate polymer Mixtures of more than one species may be used, but are not limited thereto.

The composition for washing human body of the present invention may further contain nonionic surfactants and / or amphoteric surfactants in addition to the above-mentioned anionic surfactants within the scope of not impairing the object of the present invention for the purpose of increasing cleaning power. .

Nonionic surfactants that can be used in the present invention can be used without limitation as long as they are used in the art. For example, lauryl acid diethanolamide, palm oil fatty acid diethanolamide, palm oil fatty acid monoethanolamide may be any one or a mixture of two or more selected from the group consisting of, but is not limited thereto.

In addition, the amphoteric surfactant that can be used in the present invention can be used without limitation so long as it is used in the art. For example, it may be any one or a mixture of two or more selected from the group consisting of betaine, amido propyl betaine, coco amppocarboxy glycinate, sacosinate, but is not limited thereto.

Additional aids used in the art may be further included in the human cleansing composition of the present invention to further enhance the conditioning properties. For example, water-insoluble non-volatile dimethicone, cyclomethicone, aminated silicon, trimethylsilyl amodimethicone, components such as silicone, and derivatives thereof, vegetable oils, vegetable oils, animal oils or Animal fats, hydrocarbon oils, synthetic ester oils and the like can be used. Hydrocarbon oils may include liquid paraffin, isoparaffin, hydrogenated polydecene, and the like, and ester oils include isopropyl myristin, isopropyl palmitate, isostearic acid isostearyl, and C _12-15 alkyl. Benzoate and the like may be used, but is not limited thereto.

In addition, the composition for washing human body of the present invention may further include an additive that provides beneficial properties to the human body. For example, washing, volume, trimming, protection, blocking, moisturizing, dyeing, coloring, bleaching, limiting, deodorization, antiseptic, refreshing, depilation, hair growth, anti dandruff, anti hair loss, wool, anti-inflammatory, fragrance, aroma, whitening Benefits to human body such as anti-aging, wrinkle improvement, convergence, relaxation, contraction, sebum control, exfoliation, antiseptic, anti-inflammatory, yangyang, deodorant, antihistamine, anti seborrhea, blood circulation, UV protection, skin metabolism It may further include additives.

Examples of such additives include for the purpose of moisturizing, thickening, or forming a surfactant used for the purpose of emulsifying or solubilizing oil or oil raw materials such as silicones, fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, and ester oils, or High-molecular compounds used as powders by themselves UV absorbers Antioxidants Metal ion sequestrants Colorants such as dyes, pigments, vitamins, animal and plant extracts, hormones, enzymes, amino acids, peptides, proteins, etc. Combined forms can be used.

In addition, the human cleansing composition according to the present invention may further contain preservatives, thickeners, viscosity adjusting agents, pH bath tablets, fragrances, dyes, conditioning agents, etc., which can be commonly used as a component of the cleansing composition. It can be easily purchased and used commercially. Examples of the preservative include a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methylisothiazolinone (trade name: Kathon CG, manufactured by Rohm & Haas, USA). Examples of the thickener and viscosity regulator include hydroxypropyl methyl cellulose, hydroxymethyl cellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol, and the like. Citric acid, sodium hydroxide, triethanolamine, etc. are mentioned as a pH adjuster. Examples of the dyes include water-soluble tar dyes. Conditioning agents include animal and vegetable extracts, proteins and protein variants, and Fatty Acid.

Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, and the scope of the present invention should not be construed as being limited to the embodiments described below. The embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.

Examples 1-8 and Comparative Examples 1-4

<Synthesis of self-emulsifying silicone copolymer>

Into a covered reactor equipped with a stirrer, a condenser, a thermometer and a nitrogen gas inlet, the silicone macromers and / or polyalkylene glycol macromers, water-soluble monomers, quaternary cationic monomers, initiators and solvents shown in Table 1 While stirring, the inside of the reactor was made into a nitrogen environment and reacted at 75 ° C. for 12 hours. After completion of the reaction, the reaction mixture was removed by distillation of the solvent isopropyl alcohol using a rotary depressurizer, and the obtained copolymer was added with water at a concentration suitable for use to form a self-emulsifying silicone copolymer aqueous solution. Got.

In Table 1, the silicone macromer ⁽¹⁾ has a molecular weight of 10,000, and in Formula 2, R ₁ is a methyl group.

In addition, the molecular weight of polyethyleneglycol methacrylate ⁽²⁾ is 1,100, R ₁ and R ₂ in the general formula (3) are each a methyl group, m is 23, n is 0.

2-acryloyl ethyl trimethyl ammonium chloride ⁽³⁾ in the formula 1 R ₁ is hydrogen, R ₂ is -C ₂ H _4- , R ₃ , R ₄ , R ₅ is a methyl group, X is -COO- , Y is chloride ion.

V601 ⁽⁴⁾ used as initiator was supplied from Waco Chem. As dimethyl 2,2'-azobis- (2-methylpropionate).

Synthesis of Quaternary Ammonium Cationic Surfactant

Synthesis of N, N-dimethyl-N-glyceryl Stearyl Amidopropyl Ammonium Chloride

As a cationic surfactant in the form of quaternary ammonium, mono-type N, N-dimethyl-N-glyceryl stearyl amidopropyl ammonium chloride containing one quaternary ammonium group is prepared as follows. Synthesized.

In a three-necked flask, isopropyl alcohol, alkylamidopropylamine, and an equivalent of 1-chloro-2,3-propanediol were added, and sodium iodide was added as a catalyst and then refluxed. The reaction progress was checked by measuring the amine%. The reaction proceeded 95% by raising the temperature of the reactor to 120 ° C. and reacting for 10 hours. The reaction product was poured into acetone, cooled and recrystallized. The result was hygroscopic, and the result obtained through the manure after recrystallization was immediately dried in vacuo.

N, N-dimethyl-N- Diglyceryl Stearyl Amidopropyl  Synthesis of Ammonium Chloride

In order to synthesize the diglyceryl compound in which two glyceryl groups were substituted, the glyceryl group was further introduced in the monoglyceryl compound. Isopropyl alcohol, a monoglyceryl compound, and glycidol were added to a three-necked flask, followed by stirring at a temperature of 50 ° C. for 1 hour to complete the reaction. Isopropyl alcohol was removed from the mixture by distillation under reduced pressure. Since the result was hygroscopic, the result was stored as a distilled water 50% solution.

<Synthesis of human cleansing composition (conditioning shampoo composition)>

Conditioning shampoo compositions of Comparative Examples 1 to 4 and Examples 1 to 8 were prepared in the compositions and contents shown in Table 2 below. Specifically, after dissolving and dissolving polyquaternium-10 and copolymers 1-4 most widely used in conditioning shampoos as distilled water in distilled water, EDTA 4Na, a metal ion blocking agent, and citric acid, a pH adjusting agent, are added thereto. It was confirmed. Next, cocamidopropyl betaine which is an amphoteric surfactant was added. Sodium lauryl sulfate and polyoxyethylene sodium lauryl sulfate were added as anionic surfactant, and a quaternary ammonium cationic surfactant of Formula 5 or Formula 6 was added at 60 ° C., followed by stirring for 10 minutes to confirm dissolution of the components. Thereafter, the composition was cooled, dimethicone was added at 40 ° C., and stirred for 30 minutes to disperse. Then, the fragrance and preservatives were added and stirred for 20 minutes to prepare the compositions of Comparative Examples 1-4 and Examples 1-8.

(1) N, N-dimethyl-N-diglyceryl stearylamidopropyl ammonium chloride.

(2) N, N-dimethyl-N-diglyceryl stearyl ammonium chloride.

<Evaluation of coacervate production amount>

In order to measure the amount of coacervate produced to enhance hair adsorption of the conditioning component, the concentration using the actual shampoo was determined to be 10% by weight of shampoo, and 10 g of the sample was diluted in 90 g of water to measure the amount of coacervate at this concentration. The resulting coacervate was centrifuged (3,000 rpm, 30 minutes), the supernatant was discarded, and the precipitated portion was taken to determine the coacervate production amount, and the results are shown in Table 3 below.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Coacervate production amount (g) 0.25 0.23 0.20 0.23 1.23 1.26 1.06 1.03 1.13 1.10 1.09 1.11

<Silicone adsorption amount evaluation>

The degree of hair adsorption of the conditioning silicone components was measured as the amount of coacetate produced increased. After treating the composition shampoo to the hairdresser and drying the hair, silicon was extracted from the hair, and the silicon content (microgram) adsorbed to 1 g of hair was measured using GPC, and the results are shown in Table 4 below.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Silicon adsorption amount (micrograms / hair 1 gram) 180 200 185 196 1260 1230 1160 1180 1150 1120 1160 1130

<Evaluation of Conditioning Effect of Shampoo>

120 females with experience in sensory evaluation of hair products were evaluated using a shampoo prepared in Examples 1 to 8 and Comparative Examples 1 to 4, respectively, in a normal shampoo method to evaluate the hair conditioning effect on a 5-point scale. It was. In the evaluation method, the hair conditioning effect is very bad, 1 point, bad case 2 points, normal case 3 points, good case 4 points, 5 points if very good, the results are shown in Table 5 below.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Conditioning effect 3.5 3.6 3.5 3.5 4.1 4.1 3.9 4.0 3.9 3.9 4.0 4.1

As can be seen in Tables 3 to 5, the conditioning shampoo composition of Examples 1 to 8 including the alkylamidoglyceryl quaternary ammonium cation surfactant of Formulas 5 and 6 uses quaternary ammonium cation surfactant Compared with Comparative Examples 1 to 4, the amount of coacetate produced is large, and thus, the amount of silicon adsorbed is also increased, thereby confirming that the conditioning effect is excellent.

Claims (11)

In the composition for human washing comprising an anionic surfactant, quaternary ammonium cationic surfactant, N-vinyl-2-pyrrolidone, acrylic acid, methacrylic acid, maleic acid, acrylamide, methacrylamide, N, N-dimethyl acrylamide, hydroxy ethyl acrylate, hydroxy ethyl methacrylate, hydroxy propyl acrylic Nonionic water-soluble polymer monomers, which are any one or a mixture of two or more selected from the group consisting of latex and hydroxy propyl methacrylate; And It is represented by the following formula (1),  [Formula 1]

R ₁ in formula is hydrogen or an alkyl group having 1 ~ 3, R ₂ is -C _n H _2n - is represented by n is an integer of 1-5, X represents -COO-, -CONH-, or -OCO- And Y is a halogen ion or methyl sulfate ion, and R ₃ , R ₄ and R ₅ are each independently a quaternary cationic monomer which is an alkyl group having 1 to 3 carbon atoms; Is polymerized to form a main chain, It is represented by the formula (2) [Formula 2]

Wherein R ₁ is hydrogen or an alkyl group of 1 to 3 carbon atoms, R ₂ is a hydroxy group, an alkyl group of 1 to 3 carbon atoms or a vinyl group capable of addition polymerization, m is an integer of 1 to 5, n is 10 to 1,000 The composition for human body cleaning, characterized in that it further comprises a self-emulsifying silicone copolymer formed by forming a side chain is an integral silicone macromer. The method of claim 1, The water-soluble monomer is a composition for washing human body, characterized in that 1 to 90% by weight relative to the total weight of the copolymer. The method of claim 1, The quaternary cationic monomer is 1 to 60% by weight relative to the total weight of the copolymer composition for human washing. The method of claim 1, The silicone macromer is 5 to 90% by weight relative to the total weight of the copolymer composition for human cleaning. The method of claim 1, The self-emulsifying silicone copolymer is a side chain comprising a polyalkylene glycol macromer of the general formula (3) as a side chain copolymer for cleaning human body, characterized in that the copolymerization: [Formula 3]

In formula, R <_1> , R <_2> is hydrogen or a C1-C3 alkyl group, m and n are the integers of 0-1,000 each independently. The method of claim 5, The polyalkylene glycol macromer is 1 to 50% by weight relative to the total weight of the copolymer composition for human washing. The method according to claim 1 or 5, The self-emulsifying silicone copolymer composition for human body, characterized in that it comprises 0.001 to 10% by weight relative to the total weight of the composition. The method of claim 1, The quaternary ammonium cationic surfactant is a human cleansing composition, characterized in that represented by the following formula (4): [Formula 4]

Wherein R is any one selected from the group consisting of a straight alkyl group having 12 to 22 carbon atoms, a branched alkyl group and an alkenyl group, n is an integer of 0 to 10, and X is a halogen group element, a sulfate group and an acetate group Any one selected from the group. The method of claim 1, The quaternary ammonium cationic surfactant is a composition for human washing, characterized in that it comprises 0.001 to 10% by weight relative to the total weight of the composition. The method of claim 1, The anionic surfactants include sodium lauryl sulfate, lauryl ammonium sulfate, lauryl magnesium sulfate, lauryl triethanolamine, sodium polyoxyethylene lauryl sulfate, polyoxyethylene lauryl sulfate, sulfonate-based surfactant, sulfosuccisine A composition for washing human body, characterized in that any one or a mixture of two or more selected from the group consisting of a nate-based surfactant, a sulfate-based surfactant, a carboxylate-based surfactant and an amino acid-based surfactant. The method of claim 1, The anionic surfactant is a composition for cleaning human body, characterized in that 1 to 50% by weight based on the total weight of the composition.