KR20090085451A - Early-strength polymer cement paste composition, construction and repair method for pavement using the same - Google Patents

Abstract

An early-strength polymer cement paste composition and a constructing and repairing method for pavement using the same are provided to show excellent durability and to secure driving stability and amenities. An early-strength polymer cement paste composition is composed of 100wt% of polymeric admixture solution and 20-200wt% of early-strength admixture solution. The content of the early-strength admixture solution is 70-130wt%. The polymeric admixture solution consists of 40-100wt% of gypsum, 0-60wt% of cement and 20-120wt% of polymeric solution.

Description

High-strength rigid polymer cement paste composition, road pavement method, road pavement repair method using the same {EARLY-STRENGTH POLYMER CEMENT PASTE COMPOSITION, CONSTRUCTION AND REPAIR METHOD FOR PAVEMENT USING THE SAME}

The present invention relates to the construction field, and more particularly, to a material used for road pavement and a construction method using the same.

Conventionally, as a full road repair method, an old or damaged asphalt or concrete pavement is removed, and a method of re-spreading asphalt or concrete at the site is used.

Asphalt pavement is fast construction, low mechanical strength, low resistance to plastic deformation, shorten the pavement life, thereby increasing the maintenance cost of the road.

On the other hand, concrete pavement has excellent strength, but has a long construction and curing period, and is vulnerable to the occurrence of cracks caused by dry shrinkage, and has poor driving stability and comfort.

By improving the weak points of the concrete pavement and asphalt pavement, there is an urgent need for the development of road pavement and repair methods that can be quickly constructed, excellent in durability, and capable of securing driving safety and comfort.

The present invention has been made in order to solve the above problems, high-speed rigid polymer cement paste composition and road pavement method using the same, which is fast, the durability of the road paving, excellent durability, and ensures the driving safety and comfort, It aims to show repair method of road pavement.

The present invention, in order to achieve the object described above, 100% by weight aqueous polymer admixture; It presents a high-strength rigid polymer cement paste composition comprising; 20 to 200% by weight aqueous solution of the hard admixture.

It is preferable that 70-130 weight% of the said radical miscellaneous aqueous solution is contained.

The aqueous polymer admixture is 40 to 100% by weight of gypsum; 0-60% by weight of cement; 20-120 weight% of aqueous polymer solution; It is preferable to include.

The polymer aqueous solution is preferably contained 20 to 30% by weight.

The gypsum is preferably one or more of anhydrite (CaSO ₄ ), hemi-hydride (½H ₂ OCaSO ₄ ) and di-hydradine (2H ₂ OCaSO ₄ ).

It is preferable that the gypsum or gypsum-cement-based admixture has a blain value of 4,000 cm ² / g or more.

It is preferable that the said rapidly hardened admixture aqueous solution consists of mixing 20-200 weight% of water with a hardened admixture.

It is preferable that the said radical miscible material aqueous solution mixes 20-40 weight% of said waters with the said radical miscible material.

It is preferable to use one or two of the calcium admixture (Amorphous Calcium Aluminate), calcium sulfo aluminate (Calcium Sulfo-Aluminate).

It is preferable that the radically miscible material has a blain value of 4,000 cm ² / g or more.

It is preferable that 1-10 weight% (total weight weight) of a coloring pigment is further contained.

As another means for achieving the above object, the present invention comprises the steps of preparing the aqueous solution of the polymer admixture and the aqueous solution of the hard admixture in the high strength hard polymer cement paste composition; Mixing step of mixing 20 to 200% by weight of the aqueous solution of the sharp admixture with respect to the aqueous polymer admixture; Injecting the mixed high-strength rigid polymer cement paste composition in a porous road paving structure proposes a road pavement method comprising a.

In the mixing step, it is preferable to mix 70 to 130% by weight of the aqueous solution of the sharp admixture with respect to the aqueous polymer admixture.

The present invention proposes a high-strength rigid polymer cement paste composition, a road pavement method using the same, and a road pavement repair method, wherein the road pavement construction is quick, excellent in durability, and can ensure driving safety and comfort.

The high-strength rigid polymer cement paste composition according to the present invention is basically formed by mixing 20 to 200% by weight (preferably 70 to 130% by weight) of the aqueous solution of the polymer to the polymeric admixture.

Unlike general cemented carbide cements, the pot life can be controlled very long, eliminating the problems of construction machinery failure and construction delay caused by cemented mortar and cement hardening of concrete during emergency construction using cemented carbide cement. Can be.

In addition, the composition according to the present invention is excellent in early manifestation of strength and long-term strength performance after curing, suitable for the new construction and repair of existing concrete roads and asphalt roads, especially when applied to bridge pavement Can be obtained.

In general, for short time construction, construction is performed using cemented carbide cement mortar and concrete mixed with cemented carbide and aggregate with water.When construction is delayed due to problems with construction machinery or other problems during construction, Problems such as rapid cement mortar and concrete hardening in the mixer occur frequently.

This is because calcium aluminate or calcium sulfo aluminate, which is the main component of hard cement, comes into contact with water in the presence of gypsum and cement. .

The composition according to the present invention is separated from the hard admixture component, gypsum and cement, stirred in an agitator and prepared in an aqueous solution, and finally mixed in 1.5 shot (1.5 Shot) just before injection into porous asphalt or concrete. Can be adopted.

Therefore, even if the construction delay or interruption of construction occurs for a long time during the construction, it is possible to prevent the cement paste aqueous solution from curing. Therefore, the construction delay caused by the cement hardening inside the mixer or the construction equipment during the construction of the rigid cement as in the prior art The advantage is that the problem can be solved fundamentally.

In addition, the general cement hardening material has excellent compressive strength but low warpage and tensile strength, and has high rigidity, but has a limit of being vulnerable to cracking. The effect of improving strength and preventing cracks is added.

When the composition according to the present invention is applied to road pavement and repair methods, the rigidity of the cement hardened body having a compressive strength of 210 kgf / cm 2 or more is secured within 4 hours after installation, and the high strength of 400 kgf / cm 2 or more of the compressive strength is secured after 28 days. It can have excellent durability even in the long term.

EMBODIMENT OF THE INVENTION Hereinafter, the specific Example regarding the structure of the cement paste composition which concerns on this invention is described.

As described above, the high-strength rigid polymer cement paste composition according to the present invention basically consists of mixing 20 to 200% by weight (preferably 70 to 130% by weight) of the aqueous solution of the polymer to the polymeric admixture.

Here, the aqueous solution of the polymer admixture may be made by mixing 40-100% by weight of gypsum, 0-60% by weight of cement, 20-120% by weight of the aqueous polymer solution (preferably 20-30% by weight).

The added gypsum supplies sulfate ions (SO ₄ ^2- ), which are necessary for the hydration of calcium aluminate and calcium sulfo aluminate to secure the rigidity of the polymer cement paste, and anhydrite (CaSO ₄ ) and hemihydrate gypsum ( Hemi-Hydrate; ½H ₂ O · CaSO ₄ ) and Di-Hydrate; 2H ₂ O · CaSO ₄ are recommended to be used alone or in combination.

Considering the reactivity with the hard admixture, the physical properties such as the mechanical strength of the final cured product, and the long term stability, the powder level of the gypsum or gypsum-cement admixture (if gypsum and cement are mixed) is determined by the Blaine Value 4,000. Preference is given to using products of at least cm ² / g.

The polymer solution mixed with the above-described gypsum or gypsum-cement-based admixture may be a latex-based resin (Styrene-Butadiene Rubber Latex Polymer), an acrylic resin (Acrylic Polymer), a PVA-based resin (Poly-Vinyl Acetate Polymer), or an EVA-based resin (Ethylene-). It is recommended to use Vinyl Acetate Polymer) alone or in mixture of two or more kinds.

On the other hand, the aqueous solution of the hard admixture is made by mixing 20 to 100% by weight (preferably 20 to 40% by weight) of water in the hard admixture.

The hard admixture is used as the main raw material for securing the rigidity of the polymer cement paste, and calcium aluminate powder and calcium sulfo aluminate powder are used alone or in combination.

When the composition according to the present invention is used for urgent repair of concrete pavement, fast construction completion and traffic opening after pavement placement and repair are required. Is preferably at least 4,000 cm ² / g.

The cement paste composition according to the present invention can be constructed by the following method.

In the high strength rapid hard polymer cement paste composition described above, an aqueous polymer admixture solution and an aqueous rapid admixture solution are separately prepared and then mixed immediately before laying.

The mixed high strength rigid polymer cement paste composition is injected into the porous pavement structure (including both ascone and cement concrete), where the porous pavement is irrelevant before or after curing is completed.

That is, the cement paste composition according to the present invention can be applied to both a new paving method of roads or a repair method of existing roads.

On the other hand, the cement paste composition according to the present invention can be used by adding a coloring pigment 1 ~ 10% by weight (relative to the total weight), which can be said to be effective when color paving is required over long sections, such as the middle lane of the highway. .

That is, since it is possible to simply obtain the color pavement simply by mixing and injecting the color pigment into the cement paste composition according to the present invention without removing the existing asphalt or cement concrete pavement.

As a result of the test, even if the coloring pigment 1 ~ 10% by weight based on the total weight of the composition did not appear to adversely affect the physical properties.

Hereinafter, an experimental example for examining the effect of the composition according to the present invention will be described.

Tables 1 and 2 below relate to Example 1 of the composition according to the present invention.

Item Weight ratio Remarks Gypsum-Cement Admixtures 65% Polymer aqueous solution 35% SBR Latex Emulsion

Item Weight ratio Remarks Hard 75% water 25%

Table 1 shows a blending example of a polymer admixture in which a polymer aqueous solution is mixed into a gypsum-cement-based admixture, and Table 2 shows a blending example of an aqueous radical admixture in which a rapid admixture is mixed with water.

A cement paste composition was prepared by mixing the polymer admixture solution and the rapid admixture solution in a 1: 1 ratio.

The following Tables 3 to 4 relate to Example 2 of the compositions according to the invention.

Item Weight ratio Remarks Gypsum-Cement Admixtures 80% Polymer aqueous solution 20% Acrylic emulsion

Item Weight ratio Remarks Hard 50% water 50%

Table 3 shows the compounding ratio of the polymer admixture mixed with the polymer aqueous solution in the gypsum-cement-based admixture, and Table 4 shows the compounding ratio of the solution for the rapid admixture mixed with the water.

A cement paste composition was prepared by mixing the polymer admixture solution and the rapid admixture solution in a 1: 1 ratio.

Comparative Example 1 is a cement paste composition prepared by mixing 35% by weight of water in a mixture of 99.6% by weight of one type of ordinary portland cement (blow value of 3,400 cm ² / g) and 0.4% by weight of naphthalene sulfonate-based dispersant.

Comparative Example 2 is a cement paste composition prepared by mixing 35% by weight of water in a mixture of 99.6% by weight of ultrafine cement (Blain value 6000 cm ² / g) and 0.4% by weight of naphthalene sulfonate-based dispersant.

Comparative Example 3 is a cemented carbide polymer cement paste composition prepared by preparing cemented carbide using calcium sulfo aluminate, and then adding SBR latex emulsion shown in Table 1 to 50 wt% of the cemented carbide.

Comparative Example 4 is a cemented carbide polymer cement prepared by producing cemented carbide using amorphous calcium aluminate (blow value 5,500 cm ² / g), and then adding 50 wt% of the same SBR latex emulsion to the cemented carbide cement. Paste composition.

First, the free flow measurement experiment will be described.

Table 5 shows the results of a free flow measurement experiment in which each paste composition was placed in a cylindrical flow cone of Φ 50 mm × H 50 mm, and the diameter of the flow cone was raised as it was and spread.

(Unit: mm) Sample type Measurement time (minutes) 0 20 40 60 90 120 Example 1 Polymer mixed gypsum-cement admixture 280 275 270 260 250 240 Steep material admixture 280 270 270 265 255 245 Example 2 Mixed paste composition 280 250 150 - - - Polymer mixed gypsum-cement admixture 280 285 275 270 260 250 Steep material admixture 280 275 265 270 265 255 Mixed paste composition 280 250 160 - - -  Comparative Example 1 275 270 250 230 180 120  Comparative Example 2 260 230 200 150 80 -  Comparative Example 3 280 130 - - - -  Comparative Example 4 280 120 - - - -

In Comparative Examples 3 and 4, which are cemented carbide cement pastes, the pot life was completed within 30 minutes, but the paste compositions of Examples 1 and 2 of the present invention had fluidity after 2 hours or more in aqueous solution, respectively, so that condensation and curing occurred. Was not generated, and after mixing, it was found that condensation started after curing for 40 minutes.

Therefore, the cement paste composition according to the present invention can solve the problem of excessive premature condensation by the method of separately mixing the aqueous polymer admixture and the aqueous solution of the rapid admixture, and then mixing them just before being injected into the permeable asphalt and concrete pores. In addition, it is possible to fundamentally solve the problem of securing the pot life, which is a problem in construction of the cemented carbide, and the occurrence of hardening in the construction machine when the work is delayed.

Second, the strength measurement experiment will be described.

Each composition prepared according to Examples 1 and 2 and Comparative Examples 1 to 4 of the present invention was poured into a mold to prepare a specimen.

50 x 50 x 50 mm for compressive strength test, 60 x 60 x 240 mm for flexural strength test, 40 x 40 x 10 mm for adhesive strength test, 40 x 40 x 160 mm for dry shrinkage test The specimen was prepared by compacting and molding the composition.

The prepared specimens were demolded after air curing in an environment of 20 ° C. and a relative humidity of 50% by weight for 2 hours, and subjected to 20 ° C underwater curing until 28 days after air drying in an environment of 20 ° C. and 50% by relative humidity for 3 days. .

Each specimen manufactured under these conditions was tested by KS F 2477 (Method for testing the strength of polymer cement and mortar), and also JIS A 6916 (Wall coatings for thick textured finishes). Adhesion strength of the specimen was measured by).

Table 6 shows the results of the above test.

(Unit: kgf / cm ² ) Item Compressive strength Flexural strength Adhesive strength 4 hours 1 day 28 days 4 hours 1 day 28 days 4 hours 1 day 28 days Example 1 310 380 550 47 120 135 19 25 34 Example 2 320 380 580 48 123 134 20 24 35 Comparative Example 1 0 190 380 0 48 65 0 14 19 Comparative Example 2 0 175 370 0 39 60 0 13 17 Comparative Example 3 170 320 455 36 90 115 12 18 27 Comparative Example 4 160 315 445 32 85 110 10 17 23

As shown in Table 6, the general cement paste compositions of Comparative Examples 1 and 2 did not cure even after 4 hours did not harden, but the composition prepared by the examples of the present invention (Example 1, 2) is the compressive strength of 300kgf / cm ² for 4 hours As described above, very high strength expression performance was exhibited, and it was found that the strength was higher than the compressive strength after one day of the general cement paste compositions of Comparative Examples 1 and 2.

In addition, even when compared to the cemented carbide of Comparative Examples 3 and 4, it was confirmed that the compressive strength expression rate is very high at 4 hours and 28 days.

Also in the flexural strength and the adhesive strength, the compositions of Examples 1 and 2 of the present invention exhibited faster and higher strength development than the compositions of the comparative examples, and therefore, very high initial velocity than not only ordinary portland cement but also cemented carbide cement mixtures. It was confirmed that the light performance.

Since the above has been described only with respect to some of the preferred embodiments that can be implemented by the present invention, the scope of the present invention, as is well known, should not be construed as limited to the above embodiments, the present invention described above It will be said that both the technical idea and the technical idea which together with the base are included in the scope of the present invention.

Claims (13)

100% by weight of aqueous polymer admixture; 20-200% by weight aqueous solution of hard admixture; High strength hard rigid polymer cement paste composition comprising. The method of claim 1, High-strength rigid polymer cement paste composition, characterized in that the aqueous solution of the hard admixture is contained 70 ~ 130% by weight. The method of claim 1, The aqueous polymer admixture Gypsum 40-100% by weight; 0-60% by weight of cement; 20 to 120% by weight of aqueous polymer solution; High strength hard polymer cement paste composition comprising a. The method of claim 3, The high-strength rigid polymer cement paste composition, characterized in that the aqueous solution containing 20 to 30% by weight. The method of claim 3, The gypsum is characterized by the use of one or more of anhydrite (CaSO ₄ ), hemi-hydrate (½H ₂ OCaSO ₄ ) and di-hydrate (2H ₂ OCaSO ₄ ) Rapid polymer cement paste composition. The method of claim 3, The gypsum or gypsum-cement-based admixture has a high-strength rigid polymer cement paste composition, characterized in that the blain value is 4,000 cm ² / g or more. The method of claim 1, The high-strength rigid admixture aqueous solution is a high-strength rigid polymer cement paste composition, characterized in that by mixing 20 to 200% by weight of water in the rapid admixture. The method of claim 7, wherein The high-strength rigid polymer cement paste composition is characterized in that the aqueous solution of the sharp admixture is made by mixing 20 to 40% by weight of the water with the rapid admixture. The method of claim 7, wherein The rigid admixture is a high strength rigid polymer cement paste composition, characterized in that using one or two of calcium aluminate, calcium sulfo aluminate. The method of claim 9, High-strength rigid polymer cement paste composition characterized in that the radically miscible material has a blain value of 4,000 cm ² / g or more. The method of claim 1, High strength rigid polymer cement paste composition, characterized in that it further comprises 1 to 10% by weight (based on the total weight) of the colored pigment. Preparing the aqueous solution of the polymer admixture and the aqueous solution of the rapid admixture in the high strength rapid polymer cement paste composition according to any one of claims 1 to 11; Mixing step of mixing 20 to 200% by weight of the aqueous solution of the sharp admixture with respect to the aqueous polymer admixture; Injecting the mixed high-strength rigid polymer cement paste composition into the porous pavement structure; Including road pavement method. The method of claim 12, The mixing step is a road pavement repair method, characterized in that 70 to 130% by weight of the aqueous solution of the polymeric material mixed with the blended solution.