KR20090041072A - A water oil, an system and a method for manufacturing the same - Google Patents

Abstract

Water oil using brown gas, a system and a method for producing the same are provided to use oil remained on earth effectively and to decrease emission quantity of carbon dioxide, oxides of sulfur. A system for producing water oil using Brown Gas includes a brown gas-dissolved water manufacturing unit(200) and a water oil manufacturing unit(400). The water oil manufacturing unit chemically binds the brown gas-dissolved water(250). The brown gas-dissolved water is supplied to the water oil manufacturing unit through a first pipe(410) from the brown gas-dissolved water manufacturing unit. Oil(350) is supplied to the water oil manufacturing unit through a second pipe(420) from an oil tank(300). The first pipe and the second pipe include each first metering pump(415) and second metering pump(425).

Description

Water oil, manufacturing system and manufacturing method using water oil {{A Water Oil, An System and A Method for manufacturing the same}

An embodiment relates to a water oil using Brown's Gas, a manufacturing system thereof, and a manufacturing method thereof. Water oil is named by the inventor of the present application and refers to a compound in which water and oil are chemically mixed.

The energy of coal, oil, etc. existing on the earth is limited in the amount of remaining, and it is expected that the energy supply and demand imbalance in the next 20 years and almost exhausted in 50 years.

The development of alternative energy is even more urgent, with the situation that energy supply and demand imbalance in the next 20 years, and almost 50 years later, is almost depleted.

In particular, the development of alternative energy is more urgent as energy shortages such as the recent surge in oil prices are appearing in reality.

Alternative energy is classified into solar energy, biomass, wind power, small hydropower, fuel cell, coal liquefaction, gasification, marine energy, waste energy and other than coal, petroleum, nuclear power and natural gas. It means the flowable fuel mixed with the material by. However, the actual alternative energy, in a broad sense, refers to an energy source that replaces petroleum, and in a narrow sense it refers to a renewable energy source.

Korea has designated 11 fields as alternative energy to be used in the future, not petroleum, coal, nuclear power, or natural gas (Article 2 of the Alternative Energy Development and Utilization and Distribution Promotion Act). Eight renewable energy fields include solar heat, photovoltaic power generation, biomass, wind power, hydropower, geothermal, marine energy, and waste energy. The three new energy fields are fuel cells, coal liquefaction and gasification, and hydrogen energy.

In the last 10 years, Korea's energy consumption has recorded the world's highest growth rate of 10% annually, and the greenhouse gas emission growth rate also ranks first in the world. Fortunately, the implementation of the World Climate Convention has been delayed, but soon we are forced to participate in it, so the need for alternative energy development is increasing.

Currently, advanced technologies are actively developed in advanced countries, and solar energy and wind energy are mainly used as alternative energy, and alternative energy using biomass, geothermal energy, wave power, and tidal power is being actively developed. According to 'US Future Technology' announced at George Washington University in 1998, the US will cover 10% of energy consumption by 2010, and the EU's 'Energy White Paper' published in 1997. 'Plans to increase the share of alternative energy by 12% by 2010. In Denmark, the wind power mecca, 1,135 MW of electricity is generated from 4,900 wind turbines, accounting for 7% of electricity consumption. According to the "Energy 21" plan, 10% in 2000 and 50% by 2030. Is replacing wind with wind ".

On the other hand, Korea still has not escaped from nuclear energy-oriented energy policy. Rather, it plans to increase the share of nuclear power by 2015 from 27.5% in 1998 to 34.2%. The 10-year plan for energy technology development will only increase the rate of alternative energy, which is currently 0.82%, to 2%.

Water oil using Brown's Gas according to the embodiment, a manufacturing system thereof, and a manufacturing method thereof have the following contents.

First, in general, water (H ₂ O) and oil (Oil) can be simply mixed (physical), but does not produce a compound by a chemical bond.

A mixture is a substance in which two or more kinds of substances are physically simply mixed without causing a chemical reaction. The mixture is classified into a homogeneous mixture and a heterogeneous mixture according to whether the components are evenly mixed. And a method using chromatography.

For example, iron powder is a black substance and has a property of attaching to a magnet. Yellow powder is a yellowish substance that smells like piercing. If iron powder and sulfur powder are mixed and heated, the two chemicals combine to form a new substance called iron sulfide. This substance does not adhere to the magnet and does not smell. The two substances created an entirely new substance through chemical bonding. These substances are called compounds.

However, if iron powder and yellow powder are simply mixed together, the iron powder will stick to the magnet when the magnet is touched. It also smells like poking your nose. In other words, the two materials are mixed but iron powder and yellow powder have their own properties. Such chemical substances that do not cause chemical reactions and are simply mixed with each other are called mixtures.

That is, in general, pure water (H ₂ O) and oil (Oil) can be simply mixed (physical), but does not produce a compound (chemical compound, compound) by a chemical bond.

The reason is that water molecules are polar molecules with little + and little-because the ions in the molecule are little by little. Oil molecule is a polar nonpolar component with perfect symmetry in molecular structure. Because polar molecules and nonpolar compounds do not chemically mix with each other, water and oil do not form compounds. In this simple mixture, the gravity of the earth goes down by the gravity of the water, and the gravity of the low oil rises up, so that water and oil are separated.

However, if water and oil are chemically mixed and water oil mixed with these oils generates more calories than burned oil alone, the oil remaining on the earth can be used more efficiently. This will solve some of the problems of energy resources.

In addition, according to the embodiment, when a large amount of sulfur (S) or carbon (C) is present in the oil to burn the oil, a large amount of sulfur oxides (sulfur oxides) or carbon dioxide (CO ₂ ) is generated, and such carbon dioxide is a greenhouse. As the main culprit of gas, it has recently been pointed out as the culprit of extreme weather. In addition, sulfur oxides are a major air pollutant that causes acid rain or the gas itself acts on the mucous membranes of the human body causing respiratory diseases. However, if oil and water are chemically mixed, water (H ₂ O) is composed of hydrogen and oxygen and does not contain sulfur or carbon. Therefore, the amount of sulfur or carbon dioxide is reduced by the amount of water to reduce environmental pollution. Could be.

Water oil using a brown's gas according to the embodiment (water oil) is characterized in that the water (oil) and the oil (oil) in which the brown's gas is chemically combined.

In addition, a water oil manufacturing system using Brown's Gas is a water production apparatus in which Brown's Gas is dissolved; And a water oil production apparatus for chemically combining oil and water in which Brown's Gas is dissolved.

In addition, a method of producing water oil using Brown's Gas includes preparing water in which Brown's Gas is dissolved; And mixing water in which brown's gas is dissolved in oil to prepare water oil.

According to the water oil using Brown's Gas according to the embodiment, a manufacturing system thereof, and a method for manufacturing the same, only oil when water water, which is a compound of water and oil, is made, and water oil, which is a new compound, is burned Since more calories can be obtained than when it is burned, the oil remaining on the earth can be used more efficiently, so it can be used as an alternative energy to solve the problem of energy resources.

In addition, according to the embodiment, it is possible to make a water oil which is a compound of water and oil. At this time, when a large amount of carbon (C) or sulfur (S) is present in the oil to burn the oil, a large amount of carbon dioxide (CO ₂ ) or sulfur oxides are generated, and these are the main causes of greenhouse gases or environmental pollution. When burning the chemically mixed water oil, oil and water according to the embodiment, since water (H ₂ O) is hydrogen and oxygen and does not contain carbon or sulfur, the amount of carbon dioxide or sulfur oxides is reduced by the amount of water. Environmental pollution can also be reduced.

Hereinafter, water oil using Brown's Gas according to an embodiment, a manufacturing system thereof, and a manufacturing method thereof will be described.

Water oil is named by the inventor and refers to a compound in which water and oil are chemically mixed.

(Example)

Water oil according to the embodiment (water oil) is characterized in that Brown's Gas is a compound (compound) in which water (water) and oil (oil) is dissolved chemically combined.

In the embodiment, Brown's Gas is a gas obtained by electrolysis of water, and refers to a mixed gas having an equivalent ratio of hydrogen and oxygen of 2: 1. Normally, electrolysis of water yields hydrogen at the cathode and oxygen at the anode. Brown's Gas was collected at once without collecting these gases, named after Dr. Yull Brown from Bulgaria.

Many companies around the world use aqua gas and water gas instead of the name Brown's Gas.

Oils employed in the examples include kerosene, heavy oil, light oil and the like.

Water oil according to the embodiment is characterized in that the compound of the chemically bonded water (oil) and water (oil) in which Brown's Gas is dissolved.

In other words, water and oil typically have different polarities and are not chemically bound. However, in the embodiment, the water in which Brown's Gas is dissolved has a large amount of hydrogen ions (H ⁺ ), and the hydrogen ions may enable chemical bonding of oil and water. For example, although water is a polar molecule as H ₂ O, when the hydrogen ion (H ⁺ ) is closer to the nonpolar nature, it may be possible to chemically bond with the nonpolar oil.

At this time, water in which Brown's Gas is dissolved is a compound having a redox potential of less than -300mV due to the presence of a large amount of hydrogen ions (H ⁺ ). The phosphorus oil can be obtained in a stable state. For example, water in which Brown's Gas is melted may have an ORP of -300 mV, -400 mV, or -500 mV.

ORP is a measure of oxidizing or reducing power. ORP originally expresses the electrode potential inherent in metals. Therefore, ORP meters, which measure metal ORP, are often used in materials analysis laboratories and electrochemical industries (battery, photographic film, plating, and electrolysis) plants. Recently, however, it has been used as an analysis means for various aqueous solutions and biophysiologically active substances of inorganic compounds or semiconductor composite electrolytes.

The unit of measurement of ORP is mV, which means that the greater the negative (-) absolute value, the greater the reducing power.

Next, in the embodiment, the volume ratio of water and oil in which Brown's Gas is dissolved may be 10 to 30: 90 to 70.

For example, 10 liters (L) of melted water and 90 liters (L) of brown's gas may be mixed, or 30 liters (L) of melted water and 70 liters (L) of brown's gas may be mixed.

1 is a test report for the calorific value and sulfur content received by the Korea Petroleum Quality Management Institute research center for water oil according to the embodiment. Sulfur means sulfur oxides.

There are three materials submitted to the Korea Petroleum Quality Management Research Center. Sample name "heavy oil 0" is the case of 100% heavy oil, "heavy oil 1" is the volume ratio of water dissolved in heavy oil: Brown's Gas is 90:10, "heavy oil 2" is the volume ratio of water dissolved in heavy oil: Brown's Gas is 80: 20 is the case. Heavy oil was used in the test, but the oil is not limited thereto.

Using this sample, the experiment was secretly authorized in the Korea Petroleum Quality Control Research Center. In the case of the control sample "heavy oil 0", the calorific value was 41,450J / g and the sulfur content was 0.36wt%.

However, in the case of the sample name "heavy oil 1" according to the first embodiment, the calorific value was 38,860 J / g, and the sulfur content was 0.35 wt%, and in the case of the sample name "heavy oil 2" according to the second embodiment, the calorific value was 36,480 J / g, sulfur content was 0.32wt%.

When the data of the calorific value is analyzed, it is shown in Table 1.

Sample Name Actual calorific value Theoretical calorific value Difference between actual calorific value and expected value Heavy oil 0 41,450 Heavy oil 1 38,860 41,450 × 90/100 = 37,050 1,810 ( 5% excess heat ) Heavy oil 2 36,480 41,450 × 80/100 = 33,160 3320 ( more than 10% fever )

Table 1 is an analysis table for the estimated value of the actual calorific value and the theoretical calorific value and the difference.

That is, the actual calorific value 41,450J / g of the control sample "heavy oil 0" was 38,860 J / g in the case of the sample name "heavy oil 1", which is a theoretical calorific value (90% of heavy oil 0) of 37,050 J / g. More calories were generated as much as 1,810 J / g compared to g. This is about 5% more heat than the expected calorific value of 37,050 J / g.

In addition, the actual calorific value 41,450J / g of the control sample "heavy oil 0" was 33,160 J / g in the case of the sample name "heavy oil 2", which is 33,160 J / g which is a theoretical calorific value (80% of heavy oil 0). More calories were generated by the difference of 3,320 J / g compared to g. This is about 10% more than the expected heat of 33,160 J / g.

That is, according to the water oil using Brown's Gas according to the embodiment, water oil, which is a compound of water and oil, is made, and the amount of heat when only the oil is burned when the new oil is burned. Since a large amount of calories can be obtained, the oil remaining on the earth can be used more efficiently, and thus can be used as an alternative energy to solve the problem of energy resources.

In addition, it is an unexpected effect that the water oil can obtain a significantly higher calorific value than when only oil is burned.

Next, according to FIG. 1, 0.35 wt% of sulfur (sulfur oxide) is generated in the first embodiment of "heavy oil 1", and "heavy oil 2" of 0.32 wt% of sulfur in comparison with the control "heavy oil 0". It can be seen that (sulfur oxide) is generated and sulfur oxide is significantly reduced. However, this is also effective in preventing environmental pollution than conventional oil by reducing sulfur oxides in a situation where the calorific value of water oil according to the embodiment is secured.

That is, according to the embodiment, a water oil which is a compound of water and oil can be made. At this time, when a large amount of carbon (C) or sulfur (S) is present in the oil to burn the oil, a large amount of carbon dioxide (CO ₂ ) or sulfur oxides are generated, and these are the main causes of greenhouse gases or environmental pollution. When burning the chemically mixed water oil, oil and water according to the embodiment, since water (H ₂ O) is hydrogen and oxygen and does not contain carbon or sulfur, the amount of carbon dioxide or sulfur oxides is reduced by the amount of water. Environmental pollution can also be reduced.

Hereinafter, a water oil production system using Brown's Gas and a method of manufacturing the same will be described with reference to FIGS. 2 to 3.

Water oil production system using Brown's Gas according to the embodiment is a water manufacturing apparatus 200 in which Brown's Gas is dissolved; And a water oil manufacturing apparatus 400 for chemically combining oil and water in which Brown's Gas is dissolved.

First, water 250 in which Brown's Gas is melted is supplied to the water oil manufacturing apparatus 400 through the first pipe 410 from the water manufacturing apparatus 200 in which Brown's Gas is dissolved, and oil (350) from the oil tank 300. ) Is supplied to the water oil production apparatus 400 through the second pipe (420). In this case, each of the first pipe 410 and the second pipe 420 is provided with a first metering pump 415 and a second metering pump 425, respectively, to adjust the amount supplied.

 In an embodiment, the volume ratio of water and oil in which Brown's Gas is dissolved may be 10 to 30: 90 to 70. For example, 10 liters (L) of melted water and 90 liters (L) of Brown's Gas may be mixed, or 30 liters (L) of melted water and 70 liters (L) of Brown's Gas may be mixed. It is not.

The supplied brown's gas is dissolved in water 250 and oil 350 by an agitator to form a water oil 450 that is a chemically uniform compound.

In an embodiment, an agitator is a mechanism for stirring and mixing a liquid and a liquid, and the propeller type is illustrated in FIG. 2, but is not limited thereto. That is, the stirrer may be in addition to the propeller type, or the other type, the turbine type, the spiral shaft type, etc., depending on the type of the blade for stirring.

According to a water oil production system using Brown's Gas and a method for manufacturing the same, a water oil which is a compound of water and oil is made, and only the oil when the new oil is combusted is burned. Since more calories can be obtained than in the case, oil remaining on the earth can be used more efficiently, so it can be used as an alternative energy to solve the problem of energy resources.

In addition, when the chemically mixed water oil of oil and water according to the embodiment is combusted, since the water (H ₂ O) is hydrogen and oxygen and does not contain carbon or sulfur, the amount of carbon dioxide or sulfur oxides is reduced by the amount of water. It can also reduce environmental pollution.

Next, an apparatus 200 for manufacturing water in which Brown's Gas is dissolved will be described.

As shown in FIG. 2, the water manufacturing apparatus 200 in which Brown's Gas is melted may include a Brown's Gas manufacturing apparatus 100 and a water supply device 50.

Water may be supplied from the water supply device 50 to the water production apparatus 200 in which Brown's Gas is melted through the third pipe 220 using the water pump 55.

Thereafter, Brown's Gas (not shown) is injected into the supplied water through the fourth pipe 46 from the Brown's Gas manufacturing apparatus 100 to prepare water 250 in which Brown's Gas is dissolved.

In the embodiment, Brown's Gas (Brown Gas) is a gas obtained by electrolysis of water, which is called by any name, and includes both mixed gas having an equivalent ratio of hydrogen and oxygen of 2: 1, and Brown's Gas manufacturing apparatus described later ( 100 is only an example, and includes all devices capable of producing Brown's Gas and all methods capable of producing Brown's Gas.

Brown's Gas melted water 250 according to the embodiment is characterized in that the reduced hydrogen water is close to about alkali while increasing the negative (-) absolute value of the ORP.

Specifically, the water 250 in which Brown's Gas is melted is characterized in that the redox potential (ORP) is -400 mV to -500 mV and the pH is 6.0 to 8.4. In other words, alkaline electrolyzed water according to the prior art increases the amount of hydrogen in the water when the electrolysis is increased, and when the ORP value is increased to the negative (-) absolute value, the pH value becomes higher as the hydrogen ion concentration [H +] is relatively lowered. There was a problem. Accordingly, according to the electrolytic reduced water according to the prior art, there is a problem of corroding the pump, piping and the like in contact with the electrolytic reduced water.

The embodiment is characterized by little change in the pH value of the water before the Brown's Gas is injected ORP is negative (-), the absolute value is large, but is not strongly alkaline.

In the embodiment, Brown's Gas is a gas obtained by electrolysis of water and is a mixed gas having a hydrogen and oxygen equivalent ratio of 2: 1. When Brown's Gas, which is a mixed gas, is added to water, some hydrogen may be adsorbed onto the metal nanocolloid and may be present in a stable state without being a gas. Hydrogen and oxygen not dissolved in water may be released to the outside.

Next, Brown's Gas manufacturing apparatus 100 will be described with reference to FIG. 3.

In an embodiment, the Brown's Gas manufacturing apparatus 100 is filled with an electrolyte 44 composed of water and an electrolyte (KOH or NaOH, etc.), and heat exchanges the electrolyte 44 with an electrolyzer 14 for generating Brown's Gas. It may include an electrolyte control unit (not shown) to replenish the insufficient electrolyte, and a cooling unit (not shown) for automatically cooling the temperature of the electrolyte.

Hereinafter, the configuration of the electrolytic cell 14 will be described in more detail.

Referring to FIG. 3, the electrolytic cell 14 is provided with an upper and fixed plate 34 which fixes the pole tube 20 and the pole tube 20 and maintains a constant gap therebetween, and the gas collecting unit (above the upper portion of the electrolytic cell 14). 30) and the gas-stove outlet (fourth pipe) 46. In addition, the electric drawing device 40 is installed on the top and side of the electrolytic cell.

Hereinafter, the operation of the Brown's Gas generator in the embodiment will be described in more detail.

In the embodiment Brown's Gas manufacturing apparatus 100 is composed of an upper fixing plate 34 and the lower fixing plate 34, the pole tube 20 functions as an electrode. Each pole tube 20 is fastened at equal intervals. Eventually, the cathode tube 20 and the upper and lower fixing plates 34 maintained at regular intervals form one unit for generating gas, thereby independently generating Brown's Gas.

In detail, the cathode tube 20 is alternately set to a positive electrode (+) and a negative electrode (−) by a voltage applied to the upper and side electric drawing devices 40, and the electrolyte is filled between the electrodes. It decomposes to produce Brown's Gas.

The cathode tube 20 corresponding to the applied voltage is capable of efficiently generating Brown's Gas by electrolyzing the electrolyte solution present between the cathode electrodes 20 corresponding to the electrode without any electrical loss.

In addition, a cooling unit (not shown) is configured on one side of the electrolytic cell 14, and the electrolyte in the electrolytic cell 14 is circulated to a heat exchanger (not shown) to cool the heat exchanger by the cooling unit, resulting in the electrolyte solution. The temperature of 44 is cooled to maintain the temperature in the electrolytic cell 14 at a constant state at all times.

According to the water oil using Brown's Gas according to the embodiment, a manufacturing system thereof, and a method for manufacturing the same, only oil when water water, which is a compound of water and oil, is made, and water oil, which is a new compound, is burned Since more calories can be obtained than when it is combusted, oil remaining on the earth can be used more efficiently, so it can be used as an alternative energy to solve the problem of energy resources.

In addition, according to the embodiment, it is possible to make a water oil which is a compound of water and oil. At this time, when a large amount of carbon (C) or sulfur (S) is present in the oil to burn the oil, a large amount of carbon dioxide (CO ₂ ) or sulfur oxides are generated, and these are the main causes of greenhouse gases or environmental pollution. When burning the chemically mixed water oil, oil and water according to the embodiment, since water (H ₂ O) is hydrogen and oxygen and does not contain carbon or sulfur, the amount of carbon dioxide or sulfur oxides is reduced by the amount of water. Environmental pollution can also be reduced.

4 is a schematic diagram of a water oil production system using Brown's Gas according to a further embodiment.

That is, according to a further embodiment, in the case where Brown's Gas is added to the melted water and oil and directly mixed with Brown's Gas into the water oil production apparatus 400 by the second gas outlet 47, the negative (-) of the ORP is mixed. Higher absolute values make the compounds of the water oil more effective.

This further embodiment may employ the technical features of the water oil production system and the method for producing the water oil is a compound of water and oil in which Brown's Gas is dissolved.

This, further embodiment can be produced more efficiently by injecting and stirring additional Brown's Gas in the water oil production apparatus. This is because the greater the -absolute value of ORP, the greater the presence of hydrogen ions and thus the greater the chemical reaction.

The present invention is not limited to the described embodiments and drawings, and various other embodiments are possible within the scope of the claims.

For example, in the above embodiment, the compound of water and oil in which Brown's Gas is dissolved is described. In another embodiment, a new compound in which Brown's Gas is directly dissolved in oil may be possible.

1 is a test report for the water oil (water oil) using Brown's Gas according to the embodiment.

2 is a schematic view of a water oil production system using Brown's Gas according to an embodiment.

Figure 3 is a schematic diagram of a Brown's Gas production apparatus in a water oil (water oil) production system using Brown's Gas according to the embodiment.

4 is a schematic view of a water oil production system using Brown's Gas in accordance with a further embodiment.

Claims (11)

Water oil using brown's gas, characterized by chemically combining water and oil in which brown's gas is dissolved. According to claim 1, The water in which Brown's Gas is dissolved, Water oil using Brown's Gas, characterized in that the ORP is -300mV or less. The method according to claim 1 or 2, Water ratio using brown's gas, characterized in that the volume ratio of water and oil in which the brown's gas is dissolved is 10 to 30:90 to 70. Brown's Gas melted water production equipment; And Water oil production system using Brown's Gas, characterized in that it comprises a; water oil production apparatus for chemically combining the water and the melted brown's gas. The method of claim 4, wherein The water in which Brown's Gas is dissolved, Water oil production system using Brown's Gas, characterized in that the ORP is less than -300mV. The method according to claim 4 or 5, Water volume production system using Brown's Gas, characterized in that the volume ratio of water and oil in which Brown's Gas is dissolved is 10 to 30: 90 to 70. The method of claim 4, wherein The water oil production device Water oil production system using Brown's Gas characterized in that it further comprises a stirrer for mixing the oil and the water melted Brown's Gas. Preparing molten water by Brown's Gas; And Mixing water in which the Brown's Gas is dissolved in oil to produce a water oil; Water oil manufacturing method using Brown's Gas comprising a. The method of claim 8, The water in which Brown's Gas is dissolved Water oil production method using Brown's Gas, characterized in that the ORP is -300mV or less. The method according to claim 8 or 9, The mixing volume ratio of the water and oil in which the Brown's Gas is dissolved is 10 to 30: 90 to 70, wherein the water oil manufacturing method using Brown's Gas. Brown's Gas melted water production equipment; Water oil production apparatus for chemically combining oil and water in which Brown's Gas is dissolved; And Brown's Gas supply device for supplying Brown's Gas to the water oil production apparatus; Water oil production system using Brown's Gas comprising a.

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