KR20080102332A - A method to make roast meat with the lacquer tree extraction which extracted a lacquer tree ingredient with deep-ocean water - Google Patents
A method to make roast meat with the lacquer tree extraction which extracted a lacquer tree ingredient with deep-ocean water Download PDFInfo
- Publication number
- KR20080102332A KR20080102332A KR1020070048953A KR20070048953A KR20080102332A KR 20080102332 A KR20080102332 A KR 20080102332A KR 1020070048953 A KR1020070048953 A KR 1020070048953A KR 20070048953 A KR20070048953 A KR 20070048953A KR 20080102332 A KR20080102332 A KR 20080102332A
- Authority
- KR
- South Korea
- Prior art keywords
- parts
- lacquer
- bulgogi
- extract
- water
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L13/00—Meat products; Meat meal; Preparation or treatment thereof
- A23L13/40—Meat products; Meat meal; Preparation or treatment thereof containing additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2200/00—Function of food ingredients
- A23V2200/15—Flavour affecting agent
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2250/00—Food ingredients
- A23V2250/15—Inorganic Compounds
- A23V2250/156—Mineral combination
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2250/00—Food ingredients
- A23V2250/20—Natural extracts
- A23V2250/21—Plant extracts
Landscapes
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Seasonings (AREA)
Abstract
Description
본 발명은 불고기를 만드는 방법에 관한 것으로, 더욱 상세하게는 수심 200m 이하의 해양 심층수를 이용하여 옻나무나 옻나무의 수피를 가열로에서 150∼200℃ 범위로 2∼6시간 동안 열처리한 것을 물과 함께 가마솥에 넣고. 95∼100℃로 15∼30시간 동안 가열하여 독성이 없는 옻 추출물을 추출하는 단계, 상기 독성이 없는 옻 추출물로 불고기용 양념장을 만드는 단계와 상기의 불고기용 양념장과 쇠고기나 돼지고기로 불고기를 만드는 단계에 의해서 불고기를 만드는 방법에 관한 것이다.The present invention relates to a method for making bulgogi, and more specifically, heat treatment of lacquer or bark of bark with a depth of 200 m or less in a heating furnace for 2 to 6 hours in a heating furnace for 2 to 6 hours together with water. Put in the cauldron. Extracting non-toxic lacquer extract by heating to 95-100 ° C. for 15-30 hours, making bulgogi sauce with the non-toxic lacquer extract and making bulgogi with the bulgogi sauce and beef or pork It is about how to make bulgogi by step.
불고기는 한국을 대표하는 구이요리의 상징으로, 고구려 시대의 고기구이인 "맥적(貊炙)"에서 그 유래를 찾을 수 있으며, "맥적"이란 꼬챙이에 끼워 미리 조미해둔 고기를 직화(直火)에 굽는 것으로 석쇠가 나온 다음에는 꼬챙이에 꿸 필요가 없어져서 지금과 같은 불고기가 되었다. 소 불고기는 안심이나 등심 등의 부위를 얇게 섬유를 끊어 저며서 가로세로로 잔칼질을 한 다음, 배즙이나 청주·설탕 등에 버무려서 잠시 놓아 두어 효소작용이 활발해져서 고기가 연해지면 진간장에 다진 파·마늘·깨소금·생강즙·후춧가루·참기름 등을 넣고 잘 주물러 약 30분간 쟁여 두었다가 먹을 때 중불에서 천천히 구워서 만들었다.Bulgogi is a symbol of Korea's most famous grilled dish, and its origin can be found in the Koguryo era yakiniku, which is a type of grilled meat. After grilling on the grill, there was no need to fry it on a skewer, and it became the same bulgogi as it is now. Beef Bulgogi is thinly sliced and sliced in pieces of tenderloin or sirloin, and finely chopped in length and length. · Ginger juice, pepper powder, sesame oil and so on, knead well for about 30 minutes, then slowly baked over medium heat when made.
해양 심층수(海洋深層水)는 통상 200m이하 심층의 해수를 해양 심층수라고 부르며, 표층해수와는 달리 햇빛이 닿지 않아 플랑크톤(Plankton) 및 생명체가 증식하지 못하기 때문에 영양염류의 농도가 높으면서 수온에 따른 밀도차이로 표층해수와 혼합되지 않아 표층해수에 존재하는 오염물질이 없으며, 표층해수와 비교하였을 때 저온안정성(低溫安定性), 오염물질과 유해세균이나 유기물이 매우 적은 청정성(淸淨性), 식물의 성장에 매우 중요한 무기영양염류가 풍부한 부영양성(富營養性)과 다양한 미네랄성분이 균형있게 존재하는 미네랄밸런스(Mineral balance) 특성과 고압 저온상태에서 긴 세월동안 물 분자의 집단(Cluster)이 소집단화(小集團化) 되어 표면장력이 적어 침투성이 좋은 소집단수(小集團水: Microclustered water)로 숙성된 숙성성(熟成性) 등의 특성이 있으며, 구체적인 내용은 표1의 내용과 같다.Deep sea water is generally called deep sea water of less than 200m deep, and unlike surface water, sunlight does not reach, so plankton and life cannot proliferate. There is no contaminant present in surface seawater because it is not mixed with surface seawater due to the difference in density, and it has low temperature stability compared to surface seawater, cleanliness with very few pollutants, harmful bacteria and organics, Mineral balance, which is rich in inorganic nutrients, which are very important for plant growth, and the balance of various minerals, and the cluster of water molecules for a long time under high pressure and low temperature Characteristics of ripening matured with small group water (Microclustered water) due to small grouping and low surface tension , And specific content is the same as the contents shown in Table 1.
표1 해양 심층수의 특성Table 1 Characteristics of deep sea water
해양 심층수는 표층해수에 비해서 오염물질 및 유해세균이 전혀 함유되어 있 지 않으면서 표2의 "해양 심층수와 표층해수의 성분 분석 치"에서 보는 바와 같이 발효미생물의 생육에 필요한 칼슘(Ca), 마그네슘(Mg), 철(Fe), 아연(Zn), 나트륨(Na) 등 70종류를 넘는 다종다양한 미네랄성분이 포함되어 있으면서 영양염류, 생균 수, 수온은 상당한 차이가 있는 특성이 있다.Deep sea water contains no contaminants or harmful bacteria compared to surface sea water, and calcium (Ca) and magnesium required for the growth of fermented microorganisms, as shown in Table 2, "Analysis Value of Deep Sea Water and Surface Water". It contains more than 70 different minerals such as (Mg), iron (Fe), zinc (Zn), sodium (Na), and nutrients, viable bacteria and water temperature have significant differences.
표2 해양 심층수와 표층해수의 성분 분석 치 Table 2 Depth analysis of deep sea and surface seawater
해양 심층수(海洋深層水) 이용의 역사는 짧고, 지금까지 수산분야(水産分野)를 시작으로 식품(食品)이나 의료(醫療), 건강산업(健康産業), 음료수(飮料水), 화장품(化粧品) 등의 비수산분야(非水産分野)에 있어도, 다양한 연구를 하고 있다.The history of deep sea water use has been short, and it has been a long time since the field of fisheries, food, medicine, health industry, beverages, and cosmetics. Even in the field of non-fishery fisheries, etc.), various studies have been conducted.
해양 심층수에 함유된 미네랄성분으로 인한 금속 맛을 마스킹(Masking)하여 맛을 향상하기 위해 비환원성당류(非還元性糖類)인 자당(蔗糖; Sucrose), 트레할로스(Trehalose), 라피노오스(Raffinose), 비환원성 당알코올(Nonreducing sugar alcohol)인 말티톨(Maltitol), 자일리톨(Xylitol), 솔비톨(Sorbitol), 에리쓰리톨(Erythitol), 락티톨(Lactitol), 만니톨(Mannitol) 중에서 한 종류 또는 2종류 이상을 혼합한 첨가제(添加劑)를 첨가할 필요가 있다.Non-reducing sugars (Sucrose), Trehalose, and Raffinose to enhance the taste by masking the taste of metals due to minerals contained in deep sea water , One or two or more of non-reducing sugar alcohols maltitol, xylitol, Xylitol, sorbitol, erythritol, erythitol, lactitol, and mannitol It is necessary to add the additive which mixed these.
옻나무(Rhus Verniciflua Stokes)는 중앙아시아 고원지대인 티벳(Tibet) 및 히말라야(Himalaya) 지방이 원산지로 알려져 있으며 옻나무과(Anacardiaceae)에 속하는 낙엽활엽교목(落葉闊葉喬木)으로 수고(樹高)가 20m, 직경(直徑)이 60㎝에 이르고, 옻나무의 수피에서 채취되는 수액(樹液)인 칠액(漆液)은 식물생리상 일종의 분비물로써 금방 채취한 칠 액(생 옻)은 회백색의 유상(乳狀)의 액으로 단맛과 떫은맛이 나며 공기와 접촉하면 갈색으로 변한다. 칠 액의 주성분인 옻 산(Urushiol)은 공기 중의 산소와 접촉되면 효소반응에 의해 견고하게 굳어지면서 다른 도료와는 특이하게 3차원 구조의 고분자인 훌륭한 도막을 형성하여 엿 날부터 칠로 널리 이용되어 왔다.The Rhus Verniciflua Stokes is a deciduous broad-leaved arborescent tree belonging to the Anacardiaceae family, which is known as Tibet and Himalayas, the central Asian highlands. The lacquer, which is a sap collected from the bark of lacquer trees, is 60 cm in diameter and is a plant physiological secretion. The lacquer that has just been collected is an off-white oily substance. The solution is sweet and astringent, and turns brown when in contact with air. Urushiol, the main component of the lacquer, is solidified by enzymatic reaction when it comes into contact with oxygen in the air, and has been widely used as a lacquer since it forms an excellent coating film which is a polymer of three-dimensional structure uniquely with other paints. .
옻나무과의 식물은 세계적으로 약 70속, 600여 종 정도 있으며, 우리나라에는 참옻나무, 개옻나무, 덩굴옻나무, 붉나무, 검양옻나무 및 산검양옻나무 등의 6 종이 생육하고 있다.There are about 70 genus and 600 species of lacquer plants in the world, and 6 species, such as oak tree, dog lacquer tree, vine lacquer tree, red tree, bark lacquer tree, and mountain bark tree, are grown in Korea.
한국(韓國). 중국(中國). 일본(日本)에 자생(自生)하는 옻나무 수액(樹液)에는 우루시올(Urushiol)이 주성분이자만, 타이완(Taiwan)과 베트남(Vietnam)의 더운 날씨의 옻나무에는 카테콜(Catechol)에 탄소 수 17개의 곁가지(Side chain)가 결합한 라콜(Laccol)이 주성분이며, 태국(泰國)과 미얀마(Myanmar)의 옻나무 수액에는 탄소 수 17개의 곁가지가 우루시올 및 라콜과는 달리 다른 위치에 결합하는 팃시올(Thitsiol)이 보고되어 있다. 이와 같이 옻나무 자생지에 따라 주성분의 구조가 약간씩 다르며 독성도 다르다. 즉 태국과 미얀마의 카테콜은, 포이죤 아이비(Poison ivy), 포이죤 오크(Poison Oak), 포이죤 수맥(Poison Sumac) 등 여러 가지 나무에 공통으로 들어 있는 카테콜(Catechols)이 원인물질로서 병변은 일직선으로 잘 나타나는데 접촉부위에 물집이 생겨 가렵고 벌게지며, 시간이 지남에 따라 병변(病變)이 번지는 것처럼 보이지만 실제로는 시간이 어느 정도 지나 피부 중심에 자극이 직접 전달되어야 발진(發疹)이 나타나며 옻나무에 직접 접촉했던 부위가 접촉이 적었던 부위보다 증상이 심하게 나타난다.Korea. China. Urushiol is the main ingredient in lacquer sap native to Japan, but in the hot weather lacquer of Taiwan and Vietnam, catechol has 17 carbon atoms. The main ingredient is Laccol, which is a side chain, and Tsisiol, which has 17 carbon atoms in its lacquer sap in Thailand and Myanmar, unlike Urushiol and Lacol. Is reported. Thus, the structure of the main components of the lacquer native habitat is slightly different and the toxicity is also different. In other words, catechols in Thailand and Myanmar are caused by catechols commonly found in various trees such as Poison ivy, Poison Oak and Poison Sumac. The lesions appear well in a straight line, with blisters on the contact area, itchy and widening, and the lesions appear to bleed over time, but in reality the rash must be delivered directly to the skin center after some time. It appears that the area that was in direct contact with the lacquer is more severe than the area where the contact was less.
한국에서 나는 옻의 성분은 우루시올이 60∼80wt%, 수분이 10∼30wt%, 고무 질이 7∼8wt%과 미량의 함질소화합물과 옻 닭, 옻 오리, 옻 수육, 옻 불고기와 같은 옻 요리를 하였을 때 맛과 향을 좋게 하는 비환원당(Nonreducing sugar)인 트레할로스(Trehalose)와 같은 물질이 함유되어 있는 것으로 밝혀져 있다.The components of lacquer from Korea are 60 ~ 80wt% of urushiol, 10 ~ 30wt% of moisture, 7 ~ 8wt% of rubber and trace nitrogen compounds, lacquer such as lacquer chicken, lacquer duck, lacquer meat, lacquer bulgogi It is found to contain substances such as trehalose (Nonreducing sugar), which improves the taste and aroma.
옻은 독성(毒性)과 약성(藥性)을 동시에 지닌 신비로운 약재(藥材)로, 동양에서는 옛날부터 옻이 식용과 약용으로 이용되어 왔고 어혈제거(瘀血除去), 구충 (驅蟲), 위장질환(胃腸疾患), 여성의 생리불순(生理不順) 등 민간요법(民間療法)에 이를 이용하는 처방이 전래 되고 있으며, 동의보감(東醫寶鑑)에서도 위장병(胃腸病)과 변비, 어혈(瘀血)을 치료하는 약재로 소개되고 있으며 예로부터 다양하게 민간요법(民間療法)으로 활용되어 왔다. Lacquer is a mysterious herb that has both toxicity and weakness. In ancient times, lacquer has been used for food and medicinal purposes. (胃腸 疾患), women's physiological impurity (生理 처방), such as folk remedies that have been used for the prescription has been introduced, and in Dongbobogam (醫 寶 鑑), gastrointestinal diseases, constipation, blood It has been introduced as a medicinal herb and has been used as a folk remedy since ancient times.
우리나라에서는 여름철 보신용(保身用)으로 옻나무의 수피와 가지를 옻 닭, 옻 오리 등으로 식용하고 있다. 최근에 이루어진 연구결과를 보면 옻 액의 주성분이며 알레르기(Allergy)를 유발하는 옻 산 성분이 강한 항암(抗癌), 항산화(抗酸化) 및 항균활성(抗菌活性)이 있는 것으로 보고되었으며, 옻나무의 수피(樹皮) 및 목부(木部)에서 추출된 플라보노이드(Flavonoids)성분이 혈관형성 억제작용을 나타내어 암세포의 증식 및 전이를 억제하고 암세포를 정상세포로의 분화를 유도하는 항암효과(抗癌效果)가 확인되었고 또한 항산화(抗酸化), 숙취해소(熟醉解消) 및 위염억제효과(胃炎抑制效果)도 있는 것이 밝혀졌다.In Korea, the bark and eggplant of lacquer trees is used as a summer boshinyong (保身 用) as lacquer chicken, lacquer duck, etc. Recent studies have shown that lactate, the main component of lacquer fluid and allergy-inducing lactate, has strong anticancer, antioxidant and antimicrobial activity. Flavonoids extracted from bark and wood show anti-angiogenic effects, inhibiting proliferation and metastasis of cancer cells and inducing differentiation of cancer cells into normal cells In addition, it has been found that there are antioxidant, hangover relief and gastritis suppressing effect.
칠 액이 고화된 것을 분쇄하여 분말로 만든 것을 건칠(乾漆)이라 하는데 한방 및 민간에서는 혈액촉진(血液促進), 위산과다증(Hyperacidity), 여성의 생리통(生理痛), 어혈제거(瘀血除去), 편도선염(扁桃腺炎), 구충제(驅蟲劑) 등에 쓰이고 있다.The powdered solid of the lacquer is made from powder, and it is called dry chil. In oriental medicine and private medicine, blood promotion, hyperacidity, women's menstrual cramps, and blood removal , Tonsillitis (선), insect repellent (驅蟲 劑) is used.
옻의 주성분(主成分)은 폴리페놀(Polyphenol) 유도체(誘導體)인 우루시올(Urushiol)이며 처음에는 무색투명하나 공기에 접촉하면 산화효소(Oxidase)의 작용으로 검게 변하면서 도막(塗膜)을 이루는 물질로, 화학식은 C21H34O2이며, 점성(粘 性)이 있는 무색액체이고, 끓는점은 210∼222℃(0.4∼0.6㎜ Hg)이다. 공기 중에서는 검게 변하며, 진득하게 되어 응고한다. 1종류의 화합물이 아니라, 2가(價)페놀의 혼합물이며, 주요 성분인 우루시올(Urushiol)의 구조식(構造式)은 다음과 같다.The main component of lacquer is Urushiol, a polyphenol derivative. It is colorless and transparent at first. As a substance, the chemical formula is C 21 H 34 O 2 , a viscous colorless liquid, and a boiling point of 210 to 222 ° C. (0.4 to 0.6 mm Hg). It turns black in the air and becomes solid and solidifies. The structural formula of Urushiol, which is a mixture of dihydric phenols, not one type of compound, and is a main component is as follows.
상기 우루시올의 구조식에서 곁 사슬(Side chain) R는 (CH2)14CH3 , (CH2)7CH=CH(CH2)6CH2, (CH2)7CH=CHCH2CH=CH(CH2)2CH3 , (CH2)7CH=CHCH2CH=CHCH2CH=CH2로 표시 되는 4종류의 혼합물로 알려져 있다.Side chain R in the structural formula of the urushiol is (CH 2 ) 14 CH 3 , (CH 2 ) 7 CH = CH (CH 2 ) 6 CH 2, (CH 2 ) 7 CH = CHCH 2 CH = CH ( CH 2 ) 2 CH 3 , (CH 2 ) 7 CH = CHCH 2 CH = CHCH 2 It is known to four kinds of mixtures represented by CH = CH 2 .
옻나무로부터 채취한 생칠(生漆)의 지질성분(脂質成分)인 우루시올(Urushiol)은 우선 옻나무 수액(樹液) 중의 탈수소효소(脫水素酵素)인 라카아제(Laccase)에 의해서 효소산화(酵素酸化)가 진행된다. 다음에, 우루시올 중의 불포화측쇄(不飽和側鎖)는 습한 공기 중의 산소(O2)에 의해서 퀴논 화합물(Quinone compounds)로 전환되면서 과산화물(過酸化物)이 생성하여, 자동산화(自動酸化)가 일어나, 복잡한 망목구조(網目構造)를 형성한다. 우루시올은 상기의 구조식에서와 같이 2개의 수산기(水酸基: -OH)를 가진 항산화성(抗酸化性)을 나타낸다. 옻나무는 효소중합(酵素重合)을 하면 수산기가 감소하기 때문에, 항산화성도 감소한다. 따라 서 옻나무가 중합하는 것에 따라 2단계로 일어나는 자동 산화가 촉진하게 되며, 이는 항산화성과 수산기가(水酸基價)를 측정하는 것으로 확인할 수 있다.Urushiol, a lipid component of raw lacquer, extracted from lacquer trees, is first subjected to enzymatic oxidation by laccase, a dehydrogenase in lacquer sap. Proceed. Next, the unsaturated side chain in urushiol is converted into a quinone compound by oxygen (O 2 ) in humid air, producing peroxides, and automatic oxidation is carried out. Rise to form a complex network structure. Urushiol exhibits antioxidant properties with two hydroxyl groups (OH) as in the above structural formula. Sucrose decreases its hydroxyl value when it is enzymatically polymerized, thus reducing its antioxidant activity. Therefore, as the polymerization of the lacquer tree, automatic oxidation occurs in two stages, which can be confirmed by measuring the antioxidant activity and hydroxyl value (水 酸 基價).
Urushiol(Phenolic Compounds) + 공기(O2) ――Laccase(Oxidase)→ Quinone compounds + H2O2 ……………………………………………………………………①Urushiol (Phenolic Compounds) + Air (O 2 ) ――Laccase (Oxidase) → Quinone compounds + H 2 O 2 . … … … … … … … … … … … … … … … … … … … … … … … … … ①
Quinone compounds + Protein, Amino acid, 기타 유기산 등 → 망목구조(網目構造)의 거대고분자화합물(巨大高分子化合物) + H2O ………………………②Quinone compounds + Protein, Amino acid, and other organic acids → macromolecular compounds of network structure + H 2 O… … … … … … … … … ②
옻이 피부를 헐게 하는 것은, 옻의 성분인 우루시올과 라카아제가 피부를 묻으면, 우루시올이 공기 중에서 라카아제의 산화촉매작용에 의해서 산화되면서 피부 단백질과 반응하여 생기는 알레르기성 피부염을 야기되어 피부가 약한 사람은 옻오름 현상이 나타나게 된다.When lacquer breaks down the skin, urushiol and laccase, which are the components of lacquer, bury the skin, causes allergic dermatitis caused by the reaction of skin protein with uricol being oxidized by the oxidation catalyst of laccase in air. Weak people will develop lacquer phenomenon.
상기와 같은 옻의 독성(옻오름)을 감소 내지는 무독화하는 방법을 고려하면 다음과 같다.Considering the method of reducing or detoxifying the toxicity of the lacquer as described above is as follows.
1) 옻 추출물은 공기 중에서 완전산화를 하면 무독화된다.1) The lacquer extract is detoxified by complete oxidation in air.
옻 추출물을 가구 등에 옻칠을 하여 공기 중에서 완전산화를 한 옻칠 가구에서는 옻오름 현상이 야기되지 않는다.Lacquer furniture does not cause lacquer phenomena in the lacquered furniture where the lacquer extract is lacquered into furniture and completely oxidized in the air.
옻 추출물을 가구나 공예품 등에 옻칠을 하여 상기 반응식 ①과 ②의 반응이 완료되어 옻칠이 된 경우는 독성물질인 우루시올과 라카아제의 반응이 없게 되어 무독화된다.When lacquer is lacquered with furniture or crafts, the reaction of reaction formulas ① and ② is completed and the lacquer is detoxified due to the absence of the reaction of toxic substances urushiol and laccase.
2) 고온에서 가열하면 독성이 감소 내지는 무독화된다.2) When heated at high temperatures, toxicity is reduced or non-toxic.
옻나무나 수피를 가열로에서 150∼200℃ 범위로 2∼6시간 동안 열처리를 하면 산화효소인 라카아제가 분해되어 무독화된다.Heat treatment of lacquer or bark in a heating furnace at a temperature of 150-200 ° C. for 2-6 hours decomposes and detoxifies the oxidase laccase.
한방에서는 옻나무의 수피를 고온에서 법제(法製)처리를 하여 약재로 사용하고 있다.In oriental medicine, bark of lacquer trees is used as a medicinal herb after high temperature treatment.
3) 수용액 중에서도 고온으로 장시간 동안 가열하면 독성이 감소 된다.3) Toxicity is reduced when heated to high temperature in aqueous solution for a long time.
옻나무 토막이나 수피를 물과 함께 가마솥에 넣고 95∼100℃에서 15∼30시간 동안 가열하면 독성이 감소 된다.Toxins are reduced by placing the sumac or bark with water in a cauldron and heating at 95-100 ℃ for 15-30 hours.
옻 추출물에 함유되어 있는 산화효소(Oxidase)인 라카아제(Laccase)는 45℃ 이상에서 장시간 가열하면 활성이 떨어지면서 독성은 급격히 감소한다.Lacase, an oxidase (Oxidase) contained in lacquer extract, decreases its activity and rapidly decreases toxicity when heated at 45 ° C. or longer.
옻칠용의 옻 수지(Urushi lacquer)를 만드는 경우에 45℃ 이상에서 장시간 가열하면 품질이 떨어지기 때문에 45℃ 이하에서 농축하게 된다. 그러나 독성이 감소한 옻 추출물을 얻고자 하는 경우는 45℃ 이상의 고온에서 장시간 가열하는 것이 바람직하다.In case of making lacquer for lacquer (Urushi lacquer), if it is heated at 45 ℃ or more for a long time, the quality is deteriorated. However, in order to obtain a lacquer extract with reduced toxicity, it is preferable to heat at a high temperature of 45 ° C. or more for a long time.
그리고 옻 닭이나 옻 오리의 요리에서와 같이 단백질(蛋白質) 성분을 함께 넣고 고온으로 가열하면 우루시올 성분이 단백질과 반응하게 되어 독성은 더욱 감소하게 된다.And as in the cooking of lacquer chicken or lacquer duck protein (단백질 白 質) put together and heated to a high temperature when urushiol components react with the protein will further reduce the toxicity.
또한, 타닌(Tannin)성분이 함유된 밤, 감나무 잎, 느릅나무, 등롱과(燈籠果: 까마귀밥여름나무) 등과 함께 가열하면 우루시올성분이 타닌과 반응하여 독성이 더욱더 감소하는 것으로 밝혀져 있다.In addition, when heated together with the tannin (Tannin), chestnut, persimmon leaves, elm, lanterns (燈籠 果: Summer Crow) and the urushiol component is found to further reduce the toxicity by reacting with tannin.
4) 산소농도가 높은 수용액에서 고온으로 가열하면 독성의 거의 없는 옻 추 출물을 얻을 수 있다.4) When heated to high temperature in aqueous solution with high oxygen concentration, almost no poisonous lacquer extract can be obtained.
옻나무 토막이나 수피(樹皮)를 물과 함께 가마솥에 넣고 95∼100℃로 가열을 하면서 산소(O2)나 공기를 주입하여 폭기를 하거나, 옻나무 토막이나 수피를 물과 함께 고압 가마솥에 넣고 산소의 분압(分壓)을 1∼2㎏/㎠a으로 유지하면서 95∼100℃로 가열을 하면 상기의 ①과 ②의 반응이 일어나 무독성의 옻 추출물을 얻을 수 있다.Put the sumac or bark into the cauldron with water and heat it at 95 ~ 100 ℃ while injecting oxygen (O 2 ) or air to aeration, or put the sumac or bark with water into the high pressure cauldron with oxygen When heating at 95-100 ° C. while maintaining partial pressure at 1 to 2 kg / cm 2 a, the reaction of ① and ② occurs, thereby obtaining a non-toxic lacquer extract.
5) 발효처리하는 방법5) Fermentation Process
옻나무 토막이나 수피, 옻 순을 된장이나 고추장과 같이 발효식품을 만드는 경우에 함께 주입하여 발효처리를 하면 발효미생물에 의해서 옻의 독성성분을 무독화할 수 있다.Fermented microorganisms can be detoxified by fermentation microorganisms when fermented foods are added together when making fermented foods such as miso or red pepper paste.
옻나무 토막이나 수피, 옻 순만을 국균(麴菌), 고초균(枯草菌), 나도균(納豆菌: Bacillus natto)과 같은 발효미생물을 이용하여 발효처리를 하면 발효미생물이 옻 성분을 섭취하여 무독성의 대사산물(代謝産物)을 배설(排泄)하여 독성이 없는 옻 성분을 추출할 수 있다.Fermentation microorganisms such as succulents, bark, and lacquer sprouts using fermentation microorganisms such as Bacillus, Bacillus natto, and Bacillus natto are used to ferment microorganisms. Excretion of metabolites (代謝 産物) (排泄) can be extracted non-toxic lacquer components.
그러나 발효방법에 의한 옻 성분의 추출은 추출시간이 길어 시설비와 경비가 많이 들어가는 문제점이 있다.However, the extraction of the lacquer component by the fermentation method has a problem that a lot of facility costs and expenses go into the extraction time is long.
6) 가열 추출한 옻 추출물을 전해환원처리(電解還元處理)를 하면 무독성으로 처리된다.6) Heat-extracted lacquer extract is non-toxic if electrolytic reduction treatment (電解 還 元 處理).
옻나무 토막이나 수피를 물과 함께 가마솥에 넣고 95∼100℃에서 15∼30시간 동안 가열하여 추출한 옻 추출물을 전기분해장치의 음극실로 공급하여 산화환원전위(酸化還元電位: Oxidation-reduction potential, ORP) 값을 -100㎷ 이하로 전해환원처리를 하면 옻의 독성이 무독화될 수 있다.Oxidation-reduction potential (ORP) was obtained by placing the lacquered wood or bark with water in a cauldron and heating it at 95-100 ° C for 15-30 hours to supply the extracted lacquer extract to the cathode chamber of the electrolysis device. If the electrolytic reduction treatment is carried out below -100㎷, lacquer toxicity can be detoxified.
종래의 불고기를 만드는 방법은, 주로 쇠고기를 양념하여 불에 구운 것을 말하며, 등심이나 안심의 연한 부위를 사용하여, 0.5㎝ 두께로 넓적하고 얇게 저미거나 가늘게 썰어 양념에 재웠다가 구워서 만들었는데, 고기를 굽기 30분 전쯤에 파와 마늘을 곱게 다지고, 배를 갈아서 간장, 설탕, 참기름, 깨소금, 후춧가루를 혼합하여 만든 구이 양념장을 고기에 붓고 손으로 주물러 장이 고기에 고루 스며들게 한 것을 숯불에 뜨겁게 달군 석쇠에 얹어서 양면을 고루 익혀서 불고기를 만들었다.The traditional method of making bulgogi is roasted beef, seasoned with beef, and using a light portion of sirloin or tenderloin, sliced into thin, thinly sliced or thinly sliced and seasoned and grilled. About 30 minutes before baking, chop the green onions and garlic finely, grind the pears, and pour the grilled marinade made with the mixture of soy sauce, sugar, sesame oil, sesame salt, and pepper powder to the meat, and rub the meat with your hands and put it on the char-grilled grill. Both sides were cooked to make bulgogi.
본 발명은 종래의 불고기를 만드는 방법에서 독성이 없는 옻 추출물을 첨가하여 맛과 향미가 향상된 불고기를 만드는 방법을 제공하는 데 본 발명의 목적이 있는 것이다.The present invention has an object of the present invention to provide a method for making bulgogi improved taste and flavor by adding a non-toxic lacquer extract in the conventional method of making bulgogi.
이와 같은 목적을 달성하기 위한 본 발명은, 수심 200m 이하의 해양 심층수로 옻나무나 옻나무의 수피로부터 독성이 없는 옻 추출물을 추출하는 단계, 불고기용 양념장을 만드는 단계와 불고기를 만드는 단계로 이루어진 것에 특징이 있다.The present invention for achieving the above object is characterized by consisting of extracting non-toxic lacquer extract from the bark of the lacquer or lacquer with deep sea water of 200 m or less, making a marinade for bulgogi and making a bulgogi have.
본 발명에서 사용하는 해양 심층수는, 수심 200m 이하의 해양 심층수를 사용하며, 해양 심층수의 취수방법은 선상(船上)에서 해저 200m이하에 배관을 내려 취 수하던가, 해저 수심 200m 이하까지 배관을 설치하여 펌프(Pump)로 취수하던가, 해저 수심 200m 이하까지 배관을 설치하여 취수정을 해수면 이하로 설치하여 사이펀(siphon) 원리에 의해서 취수를 한다.The deep sea water used in the present invention uses a deep sea water of 200 m or less in depth, and the deep sea water intake method is piped down to 200 m or less from the seabed, or a pipe is installed up to 200 m or less. The water is pumped or the pipe is installed up to the sea level 200m or less, and the intake well is installed below the sea level to take water according to the siphon principle.
집수조에 취수된 해양 심층수는 모래여과(Sand filter)나 정밀여과(Micro filter)를 단독 또는 2가지를 조합한 여과를 하여 부유고형물질(SS: Suspended solid)을 제거한다.The deep ocean water collected in the sump is filtered through a sand filter or a micro filter alone or a combination of both to remove suspended solids (SS).
이때 여과압력은 운전조건에 따른 여과기의 압력손실과 배관의 압력손실을 고려하여 결정하며, 모래여과의 여과속도는 6∼10m/시간으로 하고, 여과사(濾過砂)의 유효경(有效徑)은 0.3∼0.45㎜, 균등계수(均等係數)는 2.0 이하로 하며, 여층(濾層)의 두께는 0.5∼1.0m로 한다.At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.The filtration speed of sand filtration is 6-10 m / hour, and the effective diameter of the filter sand is 0.3-0.45 mm, the uniformity coefficient shall be 2.0 or less, and the thickness of the filtrate layer shall be 0.5-1.0 m.
이때 취수된 해양 심층수의 탁도(濁度)가 2㎎/ℓ이하인 경우는 여과공정은 생략하고, 취수된 해양 심층수를 그대로 사용한다.At this time, when the turbidity of the deep sea water taken is 2 mg / l or less, the filtration step is omitted, and the deep sea water taken out is used as it is.
그리고 옻 성분의 추출은 7년생 이상 되는 옻나무(Rhus verniciflua)를 5∼10㎝ 크기로 토막낸 것이나 옻나무의 수피(樹皮)를 사용하며, 옻나무의 잎이나 순을 이용할 수도 있다.Extraction of the lacquer component is made by cutting the lacquer tree (Rhus verniciflua), which is more than 7 years old, into 5-10cm in size, or by using the bark of lacquer tree.
이하 본 발명에서 혼합의 비율을 나타내는 "부"는 중량 부를 의미하며, 독성(毒性)이 없으면서 미네랄성분이 다량 함유된 불고기를 만드는 방법을 상세히 설명하면 다음과 같다. Hereinafter, "parts" representing the mixing ratio in the present invention means parts by weight, and the method of making bulgogi containing a large amount of minerals without toxicity is described in detail as follows.
1. 독성이 없는 옻 성분의 추출물을 추출하는 단계1. Extraction of non-toxic lacquer extract
해양 심층수 100부, 7년생 이상 되는 옻나무를 5∼20㎝ 크기로 토막낸 것이나 옻나무의 수피(樹皮)를 가열로에서 150∼200℃ 범위로 2∼6시간 동안 열처리하여 독성을 무독화한 옻 10∼30부, 한약재인 감초(甘草) 1∼2부, 당귀(當歸) 1∼2부 느릅나무껍질 1∼2부를 가마솥에 넣고 95∼100℃에서 15∼30시간 동안 가열하여 독성이 없는 옻 성분을 추출한 다음, 채반이나 스크린(Screen) 망으로 걸러 고형물질을 제거한 독성이 없는 옻 추출물을 만든다.100 parts of deep sea water, 7 years old lacquer, cut into pieces of 5-20cm or bark of lacquer tree heated to 150-200 ℃ in a heating furnace for 2-6 hours to poison poison. -30 parts, 1-2 parts of licorice, a Chinese herb, 1 to 2 parts of Angelica, 1 to 2 parts of elm bark in a cauldron and heated at 95-100 ° C for 15 to 30 hours After extracting, filter or filter out the screen (Screen) to remove the non-toxic lacquer to remove the solid material.
그리고 상기의 독성이 없는 옻 성분의 추출물을 추출하는 단계에서 한약 성분이 함유된 독성이 없는 옻 성분의 추출물을 추출하는 경우에는 갈근(葛根), 오가피(五加皮), 애엽(艾葉), 천궁(川芎), 밤나무, 구기자(枸杞子), 작약(芍藥), 둥굴레, 계피(桂皮), 감잎 중에서 한 종류나 2종류 이상을 2∼4부를 추가로 첨가하여 한약재 성분이 함유된 독성이 없는 옻 추출물을 만든다.And in the step of extracting the non-toxic lacquer extract in the step of extracting the non-toxic lacquer extract containing the Chinese herbal medicine ingredient (갈 根), Ogapi (五加皮), Ae-yeop (艾葉), Cheongung Non-toxic lacquer containing Chinese medicine ingredients by adding 2 to 4 parts of one or two or more kinds of 川芎, chestnut, goji berry, peony, roundworm, cinnamon, and persimmon leaf Make an extract.
[실시 예1]Example 1
수심 650m에서 취수한 해양 심층수 20㎏, 8년생 옻나무를 10㎝ 크기로 토막낸 것 3㎏를 전기로에서 160∼180℃ 범위로 2시간 동안 열처리하여 독성을 무독화한 옻과 한약재인 감초 300g, 당귀 300g, 오가피 100g, 느릅나무뿌리껍질 200g, 자당 400g을 가마솥에 넣고 98∼100℃에서 24시간 동안 가열하여 독성이 없는 옻 성분을 추출한 다음, 채반으로 걸러 고형물질을 제거한 독성이 없는 옻 추출물을 15.2㎏를 만들었다. (4.8㎏의 해양 심층수는 옻나무, 감초, 당귀 … 등에 흡착 및 증발되었다.)20 kg of deep-sea water, 8 years old lacquer tree, taken at a depth of 650 m, cut into 10 cm pieces, 3 kg of heat treated at 160-180 ° C in an electric furnace for 2 hours. 300g, 100g of Ogapi, 200g of Elm Root Bark and 400g of Sucrose are added to a cauldron and heated at 98-100 ℃ for 24 hours to extract nontoxic poisonous lacquer. Kg was made. (4.8 kg of deep sea water was adsorbed and evaporated to sumac, licorice, angii, etc.)
표 2에서 보는 바와 같이 해양 심층수에는 염분의 농도가 3.3∼3.4wt% 함유 되어 있으며, 이와 같은 해양 심층수를 이용하여 옻 성분의 추출물을 추출하는 단계에서 수분이 증발하여 독성이 없는 옻 추출물에 염분의 농도는 4.3∼4.6wt%로 된다.As shown in Table 2, the deep seawater contains 3.3 to 3.4 wt% of salt, and the water is evaporated in the step of extracting the lacquer extract using such deep sea water to remove the salt from the non-toxic lacquer extract. The concentration becomes 4.3 to 4.6 wt%.
2. 불고기용 양념장을 만드는 단계2. Steps to Make a Bulgogi Marinade
독성이 없는 옻 추출물 15∼30부에 물엿 15∼20부, 캐러멜(Caramel) 0.3∼0.8부, 글루탐산모노나트륨(Monosodium glutamate)이나 핵산계 조미료 중에서 한 종류 0.1∼0.2부, 후추 0.1∼1.5부, 마늘 1.5∼6부, 파 1∼5부, 양파 1∼5부, 산탄검(Xanthan gum) 0.2∼0.7부, 참기름 2∼6부, 대두유(Soybean oil) 0.2∼2부, 참깨 0.1∼1부, 구연산 0.05∼0.5부, 설탕 5∼15부, 꿀 0.2∼0.3부, 파인애플(Pineapple)농축액 또는 배 과즙 농축액 1∼6부, 비환원성당류(非還元性糖類)인 자당(蔗糖; Sucrose), 트레할로스(Trehalose), 라피노오스(Raffinose), 비환원성 당알코올(Nonreducing sugar alcohol)인 말티톨(Maltitol), 자일리톨(Xylitol), 솔비톨(Sorbitol), 에리쓰리톨(Erythitol), 락티톨(Lactitol), 만니톨(Mannitol) 중에서 한 종류 또는 2종류 이상을 혼합한 것을 4∼10부를 혼합한 것에 용수를 염분의 농도가 0.8∼1.0wt% 되게 혼합하여 불고기용 양념장을 만든다.15 to 30 parts of non-toxic lacquer extract, 15 to 20 parts of starch syrup, 0.3 to 0.8 parts of caramel, 0.1 to 0.2 parts of one kind of monosodium glutamate or nucleic acid seasoning, 0.1 to 1.5 parts of pepper, 1.5 to 6 parts of garlic, 1 to 5 parts of onion, 1 to 5 parts of onion, 0.2 to 0.7 parts of Xanthan gum, 2 to 6 parts of sesame oil, 0.2 to 2 parts of soybean oil, 0.1 to 1 part of sesame oil , 0.05 to 0.5 parts citric acid, 5 to 15 parts sugar, 0.2 to 0.3 parts honey, 1 to 6 parts pineapple concentrate or pear juice concentrate, sucrose, which is a non-reducing sugar, Trehalose, Raffinose, Nonreducing Sugar Alcohol Maltitol, Xylitol, Sobitol, Erythitol, Lactitol, Lactitol, Bulgogi is mixed with 4-10 parts of a mixture of one or two or more kinds of mannitol, so that the salt concentration is 0.8-1.0 wt%. Make a dragon sauce.
상기의 독성이 없는 옻 성분의 추출물을 추출하는 단계에서 해양 심층수를 구입하기 어려운 경우는, 해양 심층수 대신에 수돗물이나 광천수를 사용하고, 불고기용 양념장을 만드는 단계에서는 용수로 희석하여 염분의 농도가 0.8∼1.0wt% 되게 혼합하는 대신에 간장을 주입하여 염분의 농도가 0.8∼1.0wt% 되게 혼합하여 불 고기용 양념장을 만든다.If it is difficult to purchase deep sea water in the step of extracting the non-toxic lacquer extract, use tap water or mineral water instead of deep sea water, and in the step of making bulgogi marinade, dilute with water to make salt concentration 0.8 to Instead of mixing 1.0wt%, inject soy sauce to mix the salt to 0.8 ~ 1.0wt% to make bulgogi sauce.
그리고 해양 심층수의 특성만 이용하고, 옻 성분추출과정을 생략하는 경우는, 상기의 독성이 없는 옻 성분의 추출물을 추출하는 단계를 생략하고, 불고기용 양념장을 만드는 단계에서 독성이 없는 옻 성분의 추출물 대신에 해양 심층수를 사용하여 불고기용 양념장을 만든다.And when using only the characteristics of the deep sea water, and omission of the lacquer extraction process, the step of extracting the extract of the non-toxic lacquer component is omitted, the extract of the non-toxic lacquer component in the step of making a marinade sauce for bulgogi Instead, deep ocean water is used to make bulgogi sauce.
[실시 예2]Example 2
독성이 없는 옻 추출물 2㎏에 물엿 1.5㎏, 캐러멜 40g, 글루탐산모노나트륨 15g, 후추 10g, 다진 마늘 300g, 파 200g, 양파 200g, 산탄검 20g, 참기름 200g, 대두유(Soybean oil) 40g, 참깨 40g, 구연산 10g, 설탕 500g, 꿀 50g, 배 과즙 농축액 50g, 자당 200g, 트레할로스 200g, 솔비톨 200g을 혼합한 것에 광천수 4㎏을 혼합하여 불고기용 양념장을 만들었다. Nontoxic poisonous lacquer extract 2kg, starch syrup 1.5kg, caramel 40g, monosodium glutamate 15g, pepper 10g, minced garlic 300g, green onion 200g, onion 200g, xanthan gum 20g, sesame oil 200g, soybean oil 40g, sesame 40g, 10 kg of citric acid, 500 g of sugar, 50 g of honey, 50 g of pear juice concentrate, 200 g of sucrose, 200 g of trehalose, and 200 g of sorbitol were mixed with 4 kg of mineral water to make a marinade for bulgogi.
3. 불고기를 만드는 단계3. Steps to Make Bulgogi
불고기를 굽기 30∼40분 전에 쇠고기나 돼지고기 100부에 상기의 불고기용 양념장을 만드는 단계에서 생산된 불고기용 양념장 50∼80부를 붓고 손으로 주물러 옻 성분과 양념성분이 고기에 고루 스며들게 한 다음, 송이버섯, 팽이버섯, 팽이버섯 표고버섯, 느타리버섯과 같은 버섯을 50∼100부를 혼합하여 숯불에 뜨겁게 달군 석쇠나 번철에 얹어서 양면을 고루 익혀서 불고기를 만든다.30 to 40 minutes before roasting the bulgogi, pour 50 to 80 parts of the bulgogi marinade produced in the step of making the above bulgogi marinade in 100 parts of beef or pork, and rub it by hand so that the lacquer and seasoning ingredients are evenly mixed with the meat. 50-100 parts of mushrooms such as matsutake mushrooms, oyster mushrooms, shiitake mushrooms and oyster mushrooms are mixed and cooked on a charcoal-heated grill or griddle to cook both sides evenly to make bulgogi.
[실시 예3]Example 3
M-불고기 식당에서, 안심부분 쇠고기 4㎏을 불고기용으로 썰어, 상기 실시 예2에서 만든 불고기용 양념장 3㎏를 붓고 손으로 주물러 옻 성분과 양념성분이 고기에 고루 스며들게 한 다음 30분 후에 양송이 버섯 1㎏와 팽이버섯 1㎏을 혼합한 것을 숯불에 뜨겁게 달군 8개의 번철에서 불고기를 만들었다.In M-Bulgogi restaurant, slice 4kg beef tenderloin for bulgogi, pour 3kg of bulgogi sauce made in Example 2, and rub it by hand so that the lacquer and seasoning ingredients are evenly infused with meat. A mixture of 1kg and 1kg of mushrooms was made on 8 griddles hot with charcoal.
실시 예3에서 만든 불고기와 M-불고기 식당에서 종래의 방식대로 만든 불고기를 옻오름의 경험이 있는 10인과 옻오름의 경험이 없는 10인에 공급하여 시식하도록 한 결과 모두가 실시 예2에서 만든 불고기의 맛과 향미가 우수하다는 평가를 하였다. 그리고 옻오름 현상은 전혀 야기되지 않았다. Bulgogi made in Example 2 by tasting Bulgogi made in Example 3 and 10 persons with experience in lacquer and 10 having no experience in lacquer The taste and flavor of the evaluation was excellent. And lacquer phenomenon did not occur at all.
이상에서 상술한 바와 같이 본 발명은, 해양 심층수로 옻나무나 옻나무의 수피로부터 독성이 없는 옻 성분을 추출한 옻 추출물로 만든 불고기용 양념장으로 불고기를 만들었을 때 맛과 향미가 향상되는 효과가 있기 때문에 불고기요리에 널리 보급될 것으로 기대된다. As described above, the present invention is a barbecue because the taste and flavor is improved when the barbecue is made with a barbecue seasoning made of lacquer extract, which is extracted from lacquer or bark of lacquer with deep sea water. It is expected to be widely used in cooking.
Claims (4)
Priority Applications (1)
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103005482A (en) * | 2012-12-03 | 2013-04-03 | 安徽光正食品有限公司 | Processing method of mushroom fragrance pork and mushroom fragrance pork |
CN110062584A (en) * | 2016-10-07 | 2019-07-26 | 尹后男 | The preparation method of non-toxic paint solution and using its ferment rice bran powder and powder cereal nutriment preparation method |
KR102291343B1 (en) * | 2020-10-07 | 2021-08-18 | 백승욱 | Method of manufacturing pork ribs |
KR20210106934A (en) * | 2015-08-18 | 2021-08-31 | 윤종철 | Method for preparing a Lacquer extract and Manufacturing apparatus using the same |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20030025652A (en) * | 2001-09-21 | 2003-03-29 | 최인순 | Processed seasoned beef ribs with pine needle fermented extract for bulgogi |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103005482A (en) * | 2012-12-03 | 2013-04-03 | 安徽光正食品有限公司 | Processing method of mushroom fragrance pork and mushroom fragrance pork |
KR20210106934A (en) * | 2015-08-18 | 2021-08-31 | 윤종철 | Method for preparing a Lacquer extract and Manufacturing apparatus using the same |
CN110062584A (en) * | 2016-10-07 | 2019-07-26 | 尹后男 | The preparation method of non-toxic paint solution and using its ferment rice bran powder and powder cereal nutriment preparation method |
KR102291343B1 (en) * | 2020-10-07 | 2021-08-18 | 백승욱 | Method of manufacturing pork ribs |
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