KR20070078573A - Self-molding permanent agent having storage stability - Google Patents

Abstract

A self-molding permanent agent having improved storage stability is provided to perform shaping to the desired hair without hair-shaping apparatus due to self-molding properties, and inhibit deterioration of the permanent agent by preventing phase separation through addition of locust bean gum as a stabilizer. The self-molding permanent agent having improved storage stability comprises (a) a reducing composition containing a reducing agent and a sugar compound selected from algine, carrageenan and sugar derivatives thereof, (b) a molding composition containing a divalent metal element capable of inducing molding by combining with the sugar compound, and inducing molding by combining with the divalent metal element, and (c) a softening composition containing a softening agent selected from inorganic acid, organic acid and acid salt thereof, and mineral, and dissociating the combination of sugar compound with divalent metal element, and further comprises locust bean gum as a stabilizer.

Description

Self-molding permanent agent having storage stability

FIG. 1 is an infrared (IR) spectroscopy result of a sculpture formed by reacting 2 wt% of algin as a sugar compound and 3 wt% of propylene glycol as a reactive substance with a metal element of valence 2. FIG.

Figure 2 is a graph showing the viscosity change according to the mixed weight ratio of algin as the sugar compound and propylene glycol as the reactive material.

3 is a ¹ H-NMR (500 MHz) analysis spectrum of the reducing composition prepared in Example 1 of the present invention.

4 is a SEM photograph of a coating film obtained by mixing a reducing composition and a molding composition prepared in Example 2 of the present invention and then coating the substrate.

The present invention relates to a self-forming hair forming agent having excellent storage stability, and more particularly, to a reducing agent used to reduce disulfide bonds in cystine of hair and a sugar compound having a property of self-forming and immobilizing hair. A hair forming agent comprising a reducing composition (a), a molding composition (b) which binds to the sugar compound to induce molding, and a softening composition (c) which releases the molding of the sugar compound, When the hair forming agent is provided with its own molding property, the hair can be formed as intended even when the hair forming apparatus is removed, and when the above-mentioned composition further contains a locust gum as a stabilizer, phase separation can occur during long-term storage. Existing hair forming room which can prevent the possibility of product quality deterioration by not happening A new concept of self break the will of the Formative shaping the hair.

Hair forming agents of the present invention are one of the compositions used to imprint long-lasting hair forms. Commonly referred to as perming agents are applied to the hair to reduce disulfide bonds in the cystine and to oxidize the rearranged disulfide bonds to reshape the hair in the desired shape after use of the reducing agent and to maintain the shape of the reshaped hair. It comprises an oxidizing agent.

Generally, as a reducing agent constituting the permant, a substance containing thiol, sulfide, bisulfide, or the like is used. More specifically exemplifying such a reducing agent may include cysteine and its derivatives, cysteamine and its derivatives, thiolactic acid, thioglycolic acid and its esters or alkaline salts, glyceryl thioglycolate, and the like. Among the reducing agents described above, thioglycolic acid alkali salts are known to be particularly effective and are one of the reducing agents components most commonly included in the permeant product.

Looking at the prior art associated with the perm agent, the following techniques are known.

A keratin fiber hair treatment agent [Korea Patent Publication No. 2001-0033091] used by encapsulating with polyvinyl alcohol in order to stably maintain various components used to suppress hair damage is disclosed. Manufacturing method of mixing components such as polyvinylpyrrolidone, surfactants, thickeners and the like into the permeant components in order to have the function of setting the hair styling agent such as glaze, glaze, and the like to perm hair at the same time. [Korea Patent Registration No. 0167487 Is disclosed.

Permalinks and straighteners, which are stable in both reducing and oxidizing agents in both perming and straight formulations, which disperse beads containing a substance that acts as a nourishing agent to reduce hair damage and scalp irritation, use heat and improve sustainability And a method for producing the same [Korea Patent Registration No.0405955], a composition for perm containing ceramide, cysteine, and phospholipid, and a method for perm in combination with a shampoo, treatment, oxidizing agent, rinse and cuticle adjusting agent [Korea] Published Patent Publication No. 2002-0021141] and the like are known. In addition, there is a known perm method including a method of washing the hair with a ceramide-containing shampoo, a method of providing the hair with a ceramide-containing treatment, a step of shaping the hair with a composition for perm, and a step of treating with an oxidizing agent. have. In addition, it is known to have multiple systems using at least one of two aqueous formulations or rinses as suitable formulations for the reduction and permanent oxidation of keratinous fibers, limiting the oil and alcohol components and the conditioning agent. A method characterized by containing [Korean Patent Laid-Open No. 2002-0021392] is disclosed, and a stable form containing a solid composition and a liquid composition in powder form in a method of treating keratin for permanently reshaping hair. As a reducing agent of [Korean Patent Registration No. 0411960], the reducing agent used in the past is not safe and its function decreases over time, so it is possible to maintain the stability and effect of the reducing agent by mixing cysteine or cysteamine. My choice of silica, clay, carbohydrate and organic polymer It is disclosed.

A general perma method using these perm agents comprises the following steps:

In the first step, a reducing composition containing a reducing agent is used to break the disulfide bonds in the hair keratin (cystine),

In the second step, the hair with broken disulfide bonds is pre-tensioned by using a molding tool such as a perm rod, or the hair is formed by other means,

In the third step, an oxidizing composition, which may be referred to as a 'neutralizing agent', is added to the shaped hair to reconstruct the broken disulfide bonds to maintain the hair in the final desired form.

Through the perm method, curls may be formed on the hair, straightened, curls may be removed, or a soft shape may be provided. In the above-mentioned general perm method, a hair forming apparatus such as a pump rod and a rubber band is used to fix the hair in a desired shape, or a vinyl cap is used to prevent evaporation of water in the reducing composition or the oxidizing composition.

However, it has been pointed out that this general permanent method has the following common disadvantages.

First, by forcibly pulling and shaping the hair, weak hair roots not only have the fatal effect of the hair falling out or red spots on the skin, but also the length of the disulfide bond in the cystine of the hair, which leads to a decrease in the tensile strength of the hair. Doing so can cause hair damage.

Second, by using a molding mechanism such as a pump rod and a rubber band, the hair is pressed by the weight of the molding apparatus and the rod marks remain, and the pump rod is fixed by a rubber band, so that the rubber band passes through the rubber part of the hair. The band marks may cause breakage of the hair and damage to the hair, and thus may not be molded into a desirable shape.

Third, the forced perm by the molding mechanism such as the rod for the pump and the rubber band is artificial curl is formed can not control the shape of the wave.

Fourth, since the hair molding time takes at least 40 minutes, hair damage caused by the permanent agent is made more seriously, and there is an inconvenience of having to spend 40 minutes or more boring and painful time while wearing a molding apparatus.

Fifth, waves can never be formed without using rods.

The permeable agent and permer method described above have been in use since 80 years ago to the present, and despite the various problems described above, no technology has yet been developed to replace it. Some of the improved technologies include a straight permanent wave using a surfactant such as a straight permanent agent, but this method does not significantly deviate from the existing technology. Therefore, the currently developed permanent agent is essential to use a molding device such as a pump rod or a rubber band to fix the hair to obtain a desired shape wave.

On the other hand, Japanese Patent Application Laid-Open No. 2000-191478 discloses a molding material composed of one liquid containing polysaccharide and two liquids containing metal salts which react with and react with the polysaccharide. However, the above-described prior art merely discloses a technique for temporarily shaping hair or attaching a decoration to hair by forming a film by gelation of polysaccharides. In other words, Japanese Patent Application Laid-Open No. 2000-191478 discloses a styling product that induces hair setting or temporary reshaping that disappears during styling or shampoo cleaning, and is provided to the hair by the hair forming agent treatment of the present invention. Lasts several weeks and is clearly distinguished from perm, which is characterized by its morphology not being changed by water or scouring action.

The present invention has been obtained as a result of an effort to develop a new concept of hair molding agent that can solve various problems which have been pointed out in general hair molding agents and hair forming methods.

That is, according to the present invention, by using a sugar compound having physical and chemical properties of shaping the hair as it is molded by itself and re-released by the addition of a softener, mixed with various components used as a conventional reducing agent, the molding apparatus is removed. The present invention has been completed by developing a new concept of hair forming technology that enables hair molding in a desired form even in a state.

Accordingly, the present invention provides a new concept of self-molding permanent agent capable of shaping hair as intended with the self-molding property being removed and the hair forming apparatus removed. There is a purpose.

The present invention

(a) a reducing agent; A reducing composition containing a sugar compound selected from algin, carrageenan and sugar derivatives thereof,

(b) a molding composition containing a metal element component of valence 2 which binds to the sugar compound to induce molding, and

(c) a three-part hair forming agent containing a softening composition selected from an inorganic acid, an organic acid or an acid salt thereof, and minerals, the softening composition releasing the bond between the sugar compound and the valence 2 metal element.

The present invention is characterized by a self-forming hair forming agent containing locust gum in addition to any one or two or more compositions selected from the reducing composition, the molding composition, and the softening composition, and having excellent storage stability.

In addition, the present invention

(a) a reducing agent; A reducing composition containing a sugar compound selected from algin, carrageenan and sugar derivatives thereof,

(b) a molding composition containing a metal element component having a valence 2 in combination with the sugar compound to induce molding;

(c) a softening composition containing a softening agent selected from an inorganic acid, an organic acid or an acid salt thereof, and minerals, wherein the softening composition releases the bond between the sugar compound and the valence 2 metal element, and

(d) a four-part hair forming agent comprising an oxidizing composition containing an oxidizing agent,

Another feature is a self-forming hair forming agent having excellent storage stability in which any one or two or more compositions selected from the reducing composition, the molding composition, the softening composition, and the oxidizing composition further contain locust gum.

Referring to the present invention in more detail as follows.

The present invention selects and uses a sugar compound as a main component of a hair molding agent, which has the property of being molded into a molding having elasticity and a certain hardness, and having the property of being released from the use of a component that dissociates the chemical bond of the molding. Thus, the hair forming agent is given the characteristic that the molding itself is the biggest technical feature. This makes it possible to shape the hair as intended without using a separate hair forming apparatus. In addition, the sugar compound used in the present invention is a bio-friendly organic material that can nourish hair, and when formed, selects a material having the property of forming an organic / inorganic composite film having an internal structure of IPN (Interpenetrating Polymer Network). use. Since the molding reaction in which the organic / inorganic complex is formed proceeds basically to an exothermic reaction, it is possible to control the hair forming time by promoting hair formation by heat generated in itself without applying extra heat. Can be.

In addition, each composition constituting the hair forming agent according to the present invention is fragile due to its elasticity and lacks flexibility, so it is not lifted or broken according to the hair forming method to obtain sufficient cosmetic effect, and it is a gel produced using only alginic acid or carrageenan. The silver is unstable and, if left for a long time, phase separation occurs during storage for the reason that water containing the active ingredient is exuded, which may lead to product deterioration. Therefore, the present invention is characterized by further comprising locust gum as a stabilizer in any one or more of the above-mentioned compositions. The composition containing the locust gum does not undergo phase separation even if stored for a long period of time over months or years, thereby improving the storage stability of the hair forming agent according to the present invention.

In addition, the present invention may further include a reactive substance capable of reacting with the sugar compound as a component of the hair forming agent to control the pore size in the IPN internal structure and to control the viscosity of the hair forming agent. have. In the IPN internal structure in which the sugar compound is formed by forming, pores exist, and gas and liquid can be transported by using the pores as a transport passage. In the present invention, a reactive material capable of reacting with the sugar compound is added. By controlling the pore size by controlling the pore size, it is possible to supply the reducing agent and nutrients to the hair quickly, thereby controlling the hair forming time, thereby reducing the possibility of hair damage, and rather, smoothing the hair by supplying nutrients smoothly. In addition, it is possible to adjust the viscosity of the hair molding agent according to the type and content of the reactive material further contained, in the present invention may be used by adding a reactive material as a viscosity control agent to enable hair molding without using a separate molding apparatus. have.

In addition, the present invention further includes a nanometal catalyst component as a reduction catalyst and an oxidation catalyst for promoting a reduction reaction for breaking disulfide bonds in the cystine of the hair and an oxidation reaction for restoring the cleaved disulfide bond. It may be another technical feature of the invention. Metals are well known to exhibit markedly different physical and chemical properties depending on their particle size because the ratio of the number of atoms inside the particle to the number of atoms located on the exposed surface changes as the metal particle size changes. Thus, in the present invention, by using the metal catalyst contained in the hair forming agent in nano-sized powder or liquid phase, improved catalytic activity can be obtained by controlling the size of the metal particles, and of course, the nature of the nano-metal catalyst is applied to the hair. Additional effects of nourishing can be obtained.

As a form of such a nanometal catalyst, the present invention proposes to use it in the form of 'metal colloid', which is a form of a solution prepared by dispersing nano-sized metal particles in a solution. Methods of preparing metal colloids are generally well known, and in the present invention, they may be prepared and used by the following methods. The first method of preparing a metal colloid is to prepare a metal precursor solution and a reducing agent solution, respectively, and mix and stir the solution at room temperature to the boiling point of the solvent. The second method of preparing a metal colloid is a method of preparing a metal colloid by adding an aqueous hydrochloric acid solution to the metal precursor solution and stirring the solution to a boiling point temperature of the solvent. The size of the prepared metal colloidal particles may vary depending on the stirring temperature and the stirring speed. Metal particles suitable for use in the present invention range in size from several to several hundred nanometers, more preferably from 10 to 100 nanometers in size. In addition, it is also possible to produce a colloid in which the nano-sized metal particles are evenly dispersed using a high frequency generator, an ultrasonic vibrator, a nozzle sprayer, and the like. Precursors used to prepare metal colloids may be used in the form of nitrates, acetates, chlorides or oxides of metals. The solvent varies depending on the type of metal precursor used, but may be appropriately selected from solvents capable of dissolving the metal precursor. As the solvent, for example, water or a mixture of two or more kinds selected from alcohols having 1 to 10 carbon atoms, ketones, aldehydes, acids and the like can be used. The reducing agent can be selected from glucose, hydrazine, boron hydride compounds, dimethylamine borane, citrate, and the like. In addition, a dispersion stabilizer, a reduction stabilizer, etc. may be appropriately selected and used as necessary in order to easily disperse the solution or to assist in the reduction of the metal precursor. As the dispersion stabilizer, anionic, cationic, or nonionic surfactants commonly used in the art may be used, and there is no particular limitation on the selection thereof, and polyvinylpyrrolidone, which is a nonionic surfactant, is particularly preferable. Do. Reducing stabilizers include ethylene glycol, glycine, dextrose and the like as the components commonly used in the art, without particular limitation on the selection thereof, especially dextrose is preferred.

In addition, the molding formed by applying the hair forming agent of the present invention to the hair is a thin curable coating film having an internal structure of an interpenetrating polymer network (IPN), and the molding film formed on the surface of the hair serves as a film to block contact between the reducing agent and the outside air. Done. Therefore, in the conventional permer method, the plastic cap is covered after application of the reducing composition to prevent drying of the reducing composition, but the hair forming agent of the present invention does not need to cover the vinyl cap. However, it is also possible to wear a vinyl cap for the purpose of keeping warm and keeping out fresh air. In addition, since the molding membrane having the internal structure of IPN contains sufficient pores, it is possible to form the hair for a desired time by controlling the reduction reactivity by continuously delivering the reducing agent and the hair nutrient to the hair through the pores. In particular, the molded film has a range of viscosities, adhesive strength, and hardness, so that hair molding is easy and can be maintained in a molded state, thereby enabling hair molding without a separate molding apparatus.

The hair forming agent characterized by the present invention may be a three-part hair forming agent comprising a reducing composition (a), a shaping composition (b) and a softening composition (c), or further comprising an oxidizing agent composition comprising an oxidizing agent. It may be a four-component hair forming agent, including. That is, a reducing composition including a reducing agent and a curing accelerator, a molding composition reacting with the curing accelerator to form an organic / inorganic composite film, and a hair forming agent including a softening composition for releasing the molding as an essential composition are all of the present invention. It may be included in the scope of rights.

In the following, each component constituting the hair forming agent according to the present invention, and the principle to which the components used will be described in detail.

The reducing composition (a) is prepared by containing a reducing agent and a sugar compound as essential components.

Reducing agents constituting the above-mentioned reducing composition (a) are conventionally used components, and include sulfide groups, bisulfide groups, thiol groups, cyan groups, thiocyanate groups, hydroxyl groups, sulfite groups, bisulfite groups, and The component containing a functional group selected from bicarbonate groups etc. can be used. Specifically, for example, thioglycolic acid or a salt thereof, thioglycolic acid ester, thiolactic acid, thiolactic acid ester, cysteine, cysteamine, thiocyanate, sulfite, and derivatives thereof, and the like, or a mixture thereof. Can be used. As the derivative, salts usable for cosmetic use such as hydrochloride, bromate, citrate, acetate or sulfate of the above components can be used. The reducing agent may be contained in the reducing composition (a) of the present invention in the range of 1 to 25% by weight. When the content of the reducing agent is less than 1% by weight, there is a problem that reduction of hair to disulfide bonds in the cystine is not performed properly. In excess of 25% by weight, a problem occurs that causes hair damage. More preferably, the reducing agent is contained in the range of 2 to 20% by weight in the reducing composition (a) of the present invention.

As another essential component of the above-mentioned reducing composition (a), the present invention contains a sugar compound. The sugar compound is a material that is formed into an organic / inorganic composite membrane having a certain elasticity and hardness, and in the present invention, the effect of eliminating the use of the hair forming apparatus is obtained by immobilizing the hair using the molding property of the sugar compound. will be. In addition, the molded product formed by the formation of the sugar compound is formed on the surface of the hair as a coating film of the network structure is applied as a film to block the hair forming agent and the outside air to prevent evaporation of the reducing composition, and gas through the pores in the network structure Or, the liquid is easily penetrated, so oxygen gas, reducing agent or hair nutrients are delivered to the hair in a short time and continuously through the empty space in the network of the molding to control hair shaping time, suppress hair damage and rather The effect of nourishing is gained.

As a sugar compound which this invention contains in a reducing composition (a), as long as it is a substance which produces the molded object which has a fixed elasticity and hardness, all are applicable. In addition, the sugar compound may be more preferably used as long as it is chemically stable because it is not altered by the reducing agent among the components of the hair forming agent used together, and does not inhibit the hair forming effect of the hair. The sugar compound is selected from algin, carrageenan and sugar derivatives thereof, specifically, selected from algin, alginic acid, alginate, alginate, carrageenan, carrageenic acid, carrageate, carrageenan salt, derivatives thereof, and the like. Or mixtures may be used representatively. The derivative may include a functional group selected from monovalent or polyvalent hydroxyl group, aldehyde group, carboxylic acid group and ketone group. The sugar compound may be contained in the range of 0.1 to 15% by weight in the reducing composition (a) of the present invention. If the content of the sugar compound is less than 0.1% by weight, it may not impart molding characteristics to the hair forming agent itself. Excessive use in excess of% by weight causes a problem that the molding time is too short and hardens before the hair is formed into a desired shape. More preferably, the sugar compound is contained in the range of 0.5 to 10% by weight in the reducing composition (a) of the present invention.

In addition, in the reducing composition (a) of the present invention, a reactive substance containing a functional group reacting with a sugar compound may be further added. That is, as a functional group reacting with algin, alginic acid, alginate or alginate used as the sugar compound, for example, hydroxy group (-OH), carboxylic acid group (-COOH), ketone group (-CO-), carboxyl Reactive substances containing a rate group (-COOR) and an aldehyde group (-COH) can be further added. The reactive substance additionally added in the reducing composition (a) can adjust the pore size in the network structure of the molding to control the penetration rate of the gas or liquid, and act as a viscosity modifier to facilitate hair forming and It may also be easy to fix the hair in a state. It is preferable to use a substance having a molecular weight in the range of approximately 50 to 10,000 as the reactive substance. Reactive substances which are further added in the reducing composition (a) of the present invention to control the pore size in the network structure of the molded article include, specifically, polyols, chitin or chitin derivatives including glycol, polyalkylene glycol, and polyvinyl alcohol. , Chitosan or chitosan derivatives, maleic acid, aminopropyl-silicic acid, poly-L-lysine, cellulose, cellulose salts and derivatives thereof, adipic acid, gelatin, pectin, arginine and their Polymers, gluconic acid, lactones, sodium caseinate, vinyl acetate, starch and derivatives thereof, elastin, acrylamide, acrylamide polymers and derivatives thereof, gellan gum, carbopol, Glutaraldehyde, acrylate polymers, and the like, which may be used alone or as a mixture of two or more thereof. Can be. The reactive material may be contained in the range of 0 to 5% by weight in the reducing composition (a) of the present invention. When the content of the reactive material is excessively contained in excess of 5% by weight, it is rather difficult to control the viscosity of the sugar compound. The relatively low content causes a problem that is difficult to obtain a molding effect. More preferably, the reactive substance is contained in the range of 0.01 to 3% by weight in the reducing composition (a) of the present invention.

1 is an infrared (IR) spectral result of a molded product produced by reacting algin as a sugar compound and propylene glycol as a reactive substance. Referring to FIG. 1, a peak capable of confirming a conjugated ester bond formed by reaction of algin and propylene glycol in the region of 1600-1700 cm ⁻¹ is observed. Carbonyl group (C = O) bond of algin before reaction It can be seen that the binding energy after the reaction is lower than that of the energy, which is due to the change in the binding energy of the oxide group of the propylene glycol. The conjugated ester bond formed by the reaction of algin and propylene glycol is briefly represented by the following structural formula.

In the reducing composition (a) of the present invention, a reducing catalyst may be further added. In the present invention, a metal selected from gold, platinum, palladium, rhodium or the like or a metal compound thereof may be used alone or in combination as a reducing catalyst, and the metal or metal compound may be used in a nano-sized powder or liquid phase as a reducing catalyst. By incorporating the reducing catalyst of the nano-metal in the reducing composition, it is possible to control the reduction reaction rate so that the disulfide bonds can be quickly cut, thereby maximally inhibiting hair damage and controlling the hair forming time. In addition, in the reducing composition (a) of the present invention, a reducing catalyst such as hydride, hydroxide, oxalic acid, ascorbic acid, and the like may be further selected and used as the reducing catalyst. The reducing catalyst may be contained in the range of 0 to 5% by weight in the reducing composition (a) of the present invention, even if the content of the reactive substance exceeds 5% by weight, no further catalytic effect may be obtained. It is not desirable. More preferably, the reducing catalyst is contained in 0.0001 to 5% by weight in the reducing composition (a) of the present invention.

In addition, polymers, amino acids, alkalizing agents, acidifying agents, glycols, chelating compounds, surfactants and various treatment agents and the like that are commonly used in reducing compositions for permers and do not impair their reducing properties can be used. Specifically, the amino acid may be guanine, hydrolyzed keratin (PPT), or the like. The alkalizing agent is monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 2-methyl-2-amino-1-propanol, 1,3-propanediamine and ammonium, alkali metal carbonate, bicarbonate, guanidine carbonate, The same organic carbonate or alkali metal hydroxide may be used alone or in combination. The surfactant may be a component commonly used in the reducing composition for the permant, all anionic, nonionic, amphoteric or cationic surfactant can be used, specifically, for example, alkyl ammonium salt, alkyl sulfate , Alkyl benzenesulfates, alkyl ether sulfates, alkyl sulfonates, tetravalent ammonium salts, alkylbetaines, oxyethylenated alkylphenols, fatty acid alkanolamides, oxyethylenated fatty acid esters, and hydroxypropyl ether series nonionic surfactants. have. Various other treatment agents that may be used are volatile or nonvolatile, and polydimethylsiloxane-polyoxy such as linear or cyclic silicone or mixtures thereof, polydimethylsiloxane, tetravalent polyorganosiloxane, polyorganosiloxane, dimethicone copolyol Alkyl copolymers, polydimethylsiloxanes containing stearoxy- (steaoxydimethicone) end groups, polydimethylsiloxane dialkyl ammonium acetate copolymers or polydimethylsiloxane polyalkylbetaine copolymers, mercapto or mercapto alkyl groups Silanes such as organic modified polysiloxanes or stearoxytrimethylsilane, and the like. In addition, a wax, a swelling agent and a permeating agent which may enhance the efficacy of the reducing agent or assist in curing the sugar compound may be used. Specifically, for example, dimethylisosorbitol, urea and its derivatives, pyrrolidone, alkyl ethers of n-alkylpyrrolidone, thiamorpholine, alkylene glycol or dialkylene glycol such as propylene glycol monomethyl ether or dipropylene glycol monomethyl ether, and carbon atoms having 3 to 6 carbon atoms such as 1,2-propanediol Alkanediols, 2-imidazolidinones, fatty alcohols, lanolin derivatives, ceramides, especially compounds such as glycoseramides and pseudoceramides, active ingredients such as pantothenic acid, hair loss inhibitors, anti-dandruff agents, suspending agents, metal ion blockers, Various ingredients used as reducing agents in conventional perm agents such as opacifiers, colorants, sunscreens, fragrances and preservatives can be used. In addition, amino acids, polypeptides, ceramides, minerals and keratin may be used. The additives described above are components that have been used in a reducing composition included in a general permant, and those skilled in the art can easily and arbitrarily select and use them. The additive may be contained in the reducing composition (a) of the present invention in the range of 0 to 70% by weight. When the content of the additive is contained in excess of 70% by weight, the content of the reducing agent and the sugar compound is relatively decreased. A problem arises in which the self-forming hair forming agent desired by the present invention cannot be prepared. More preferably, the additive is contained in 0.01 to 60% by weight in the reducing composition (a) of the present invention.

Moreover, the reducing composition (a) of this invention can also be comprised by adding a sugar compound to the commercially available perm agent containing a reducing agent. Commercial permer 1 in the present invention is a processing solution that serves to break the bonds in the keratin (cystine) present as the main component of the hair for hair forming, and comprises a reducing agent or a reducing material.

The amount of the commercially available perm agent 1 is determined based on the content of the reducing agent, and the commercial perm 1 agent may be used within the content range of 10 to 98.9% by weight in the reducing composition (a) of the present invention. If the amount of the commercially available perm 1 agent contained in the reducing composition (a) is less than 10% by weight, the content of the reducing agent cannot be lowered to destroy the disulfide bonds of the hair, and when used excessively in excess of 98.9% by weight. Relatively low content of sugar compounds can not be obtained the effect of shaping. More preferably, the commercial perm agent is contained in 50 to 98% by weight in the reducing composition (a) of the present invention.

The reducing composition (a) of the present invention is prepared in the form of gel or sol by mixing each of the above-mentioned components with deionized water. The reducing composition is prepared by adjusting the pH in the range of 4 to 11, when the pH is less than 4 or above pH 11, the disulfide bonds of the hair are not broken, and thus the hair forming effect cannot be obtained and the hair may be damaged. More preferably, the reducing composition (a) of the present invention is prepared by adjusting the pH to 5.5 to 9.5.

The content ratio of each of the components used in the reducing composition (a) according to the present invention is as follows: 1 to 25% by weight reducing agent (preferably 2 to 20% by weight); 0.1-15% by weight of a sugar compound (preferably 0.5-10% by weight); 0-5% by weight of reactive material (preferably 0.01-3% by weight); 0-5% by weight of reduction catalyst (preferably 0.0001-5% by weight); 0 to 70% by weight of other additives (preferably 0.01 to 60% by weight); It consists of 1-98.9 weight% (preferably 30-90 weight%) of deionized water. Particularly preferred reducing composition (a) is 2 to 20% by weight of reducing agent, 0.5 to 10% by weight of sugar compound, 0.1 to 5% by weight of locust gum, 0.01 to 3% by weight of reactive substance, 0.0001 to 5% by weight of reducing catalyst, and usual additives 0.01 to 60 wt%, and 30 to 90 wt% of deionized water.

In addition, the reducing composition (a) according to the present invention may be a composition in which a reducing agent and other additives are replaced with a commercially available perm agent, and each of the components used may have the following composition ratio: commercial perm agent 10 to 98.9 weight % (Preferably 50 to 98% by weight); 0.1-15% by weight of a sugar compound (preferably 0.5-10% by weight); Locust gum 0.1-5% by weight (preferably 0.2-3% by weight); 0-5% by weight of reactive material (preferably 0.01-3% by weight); 0-5% by weight of reduction catalyst (preferably 0.0001-5% by weight); It consists of 1-89.9 weight% (preferably 1-70 weight%) of deionized water.

In addition, in the composition of the reducing composition (a) of the present invention, when maintaining the range of 0.01 to 1 part by weight of the sugar compound based on 1 part by weight of the reducing agent, the self-forming hair molding agent of the present invention can be obtained, and the content ratio Once obtained, the desired self-forming hair forming agent cannot be obtained. In particular, it is also possible to more easily control the physical properties such as viscosity, adhesion and hardness of the hair molding agent by containing a reactive substance as an essential component within the above range.

In addition, the viscosity control of the reducing composition (a) is important for the hair forming agent of the present invention to be molded by itself and to form hair. In order to obtain the self-forming hair forming agent desired by the present invention, the viscosity of the reducing composition (a) is approximately 1,000 to 60,000 cP, and preferably maintains a viscosity range of 10,000 to 50,000 cP. The viscosity control of the reducing composition (a) is mainly possible by the type and content ratio of the sugar compound and the reactive substance, and preferably, it is contained in the range of 0.1 to 5 parts by weight of the reactive substance based on 1 part by weight of the sugar compound. Figure 2 is a graph showing the viscosity change according to the change in the weight ratio of algin as a sugar compound and propylene glycol as a reactive material, the present invention is when the weight ratio of algin and propylene glycol is in the range of about 1: 0-5 It was confirmed that the reducing composition (a) having the desired viscosity range could be obtained.

The shaping composition (b), which is included as the second composition constituting the hair forming agent of the present invention, induces shaping by combining with a sugar compound included in the reducing composition (a).

As a component that reacts with a sugar compound to induce shaping, the shaping composition (b) is constituted by containing a metal element component having a valence 2 as an essential composition component. The metal element component of the valence 2 in the present invention may be applied as long as it can form M ²⁺ ions including a metal or metal compound or a water-soluble salt thereof. Forming effects can be obtained by using monovalent or trivalent elements as metal elements that induce the shaping of sugar compounds, but uranium (U ⁶⁺ ), cesium (Cs ⁺ ), rubidium (Rb ⁺ ) and iron M ⁺ , M ³⁺ , M ⁶⁺ metals represented by (III) (Fe ³⁺ ) are not suitable because they reduce the reducing power of the reducing composition and do not cause the hair to form properly, which may cause hair damage. . Therefore, in the present invention, as a component that induces the shaping of the sugar compound, it is represented by magnesium (Mg), calcium (Ca), barium (Ba), zinc (Zn), strontium (Sr), iron (II) (Fe) and the like. The metal element component of valence 2 to be used may be selected, and the use of such a metal element may be a technical feature of the present invention. The metal element component of the valence 2 may specifically include magnesium hydroxide, barium chloride, strontium chloride, calcium hydroxide, calcium chloride, calcium acetate, magnesium chloride, and the like, and may be used alone or in combination by selecting from all compounds derived from them. have. The metal element component of the valence 2 may be contained in the range of 0.1 to 25% by weight in the molding composition (b) of the present invention, if the content is less than 0.1% by weight can exhibit a sufficient effect of shaping the sugar compound If the excess is used in excess of 25% by weight, the softening to be carried out next is not easy and causes a reduction in reducing power. More preferably, the metal element component of the valence 2 is contained in the range of 1 to 20% by weight in the molding composition (b) of the present invention.

In addition, in the molding composition (b) of the present invention, various kinds of resins commonly used in the manufacture of permeants, including reducing aids, penetrants, wetting agents, swelling agents, curing aids, surfactants, alkalizing agents, acidifying agents, glycols, chelating compounds, and the like. An additive component may be further included, and in addition, hair nutrients such as amino acids, polypeptides, ceramides, minerals, keratins, and the like may be included. The reducing aid may be used alone or in a mixture selected from iron-based compounds, alcohols, glycols, glycol esters, urea and pyrrolidone. In addition, a penetrant, a humectant, which helps the curing agent to penetrate, may be used, and a curing aid may be used to promote molding. The additives described above are components included in a general permant, and those skilled in the art can be easily selected arbitrarily and used. The present invention does not have any particular limitation on the use of these additives. The additive may be contained in the molding composition (b) of the present invention in the range of 0 to 30% by weight. When the additive is contained in excess of 30% by weight, the content of the metal element component of valence 2 is relatively high. This reduction may cause a problem that the molded hair molding agent of the present invention cannot be prepared. More preferably, the additive is contained in 0.01 to 20% by weight in the molding composition (b) of the present invention.

The molding composition (b) of the present invention is prepared by mixing each of the components described above with deionized water. The shaping composition (b) is prepared by adjusting the pH in the range of 2 to 12. If the pH is less than 2 or exceeds pH 12, the reducing power may be reduced. More preferably, the molding composition (b) of the present invention is prepared by adjusting the pH to 5-11.

The content ratio of each used component constituting the molding composition (b) according to the present invention is as follows: 0.1 to 25% by weight (preferably 1 to 20% by weight) of the metal element component of valence 2; 0 to 30% by weight of other additives (preferably 0.01 to 20% by weight); It consists of 60-99.9 weight% (preferably 70-98 weight%) of deionized water. Particularly preferred molding composition (b) comprises 1 to 20% by weight of a metal element component of valence 2, 0.1 to 5% by weight of locust gum, 0.01 to 20% by weight of conventional additives, and 70 to 98% by weight of deionized water. .

In the constituting the molding composition (b) of the present invention, the metal element component of valence 2 is used in the range of 0.0001 to 5 parts by weight based on 1 part by weight of the sugar compound contained in the reducing composition (a). Bar, if the amount used is less than 0.0001 parts by weight, there is a problem in molding, and if the amount is used in excess of 5 parts by weight, the softening to be carried out next is not easy and causes a reduction in reducing power. More preferably, the metal element component of valence 2 is used in the range of 0.001 to 0.5 parts by weight based on 1 part by weight of the sugar compound.

The softening composition (c), which is included as the third composition constituting the hair forming agent of the present invention, is used to release the molding to soften the cured hair and to permanently reshape the hair. It consists of containing.

Sculptures formed by the reaction of the reducing composition (a) and the molding composition (b) are formed by dissociating the bonds by pH adjustment or addition of ions or compounds that can replace the bonds with the metal elements of valence 2. Can be released. In the present invention, it can be selected from organic acids, inorganic acids or acid salts and minerals as a softener for releasing the moldings. Examples of softeners include organic acids such as citric acid, succinic acid and acetic acid or salts thereof, mineral acids such as nitric acid, sulfuric acid, carbonic acid, bicarbonate, hydrochloric acid and phosphoric acid or salts thereof, ocher, illite, mavanite, bentonite and montmorillonite. Can be used. Salts of the acid may include alkali metal salts including sodium (Na ⁺ ), potassium (K ⁺ ), alkaline earth metal salts such as magnesium (Mg ²⁺ ), calcium (Ca ²⁺ ), and the like. The softener may be contained in the range of 0.1 to 25% by weight in the softening composition (c) of the present invention, when the content of the softener is less than 0.1% by weight, there is a problem that the molding is not released, excess exceeding 25% by weight Use causes problems with hair damage. More preferably, the softening agent is contained in the range of 1 to 20% by weight in the softening composition (c) of the present invention.

In addition, the softening composition (c) of the present invention may further contain an oxidizing agent. The oxidizing agent may be used alone or in a mixture selected from hydrogen peroxide solution, peroxides such as urea peroxide, bromates such as alkali metal-containing bromate, or persalts. The oxidizing agent may be contained in the softening composition (c) of the present invention in the range of 0 to 25% by weight, so that an excessive amount of the oxidizing agent exceeds 25% by weight causes hair damage. More preferably, the oxidizing agent is contained in the range of 1 to 20% by weight in the softening composition (c) of the present invention.

In addition, the softening composition (c) of the present invention may further contain an oxidation catalyst. The oxidation catalyst regenerates the hair by making the softening composition easy to penetrate into the hair and promotes oxidation of the disulfide bonds cleaved by the reducing composition (a) to induce recombination. As the oxidation catalyst, metals or metal compounds such as iron, zinc, copper, cobalt, zirconium, vanadium, manganese, and titanium may be used alone or in combination. Particularly, the above metals or metal compounds may be prepared in the form of nano-sized powder or liquid phase. It is more preferable in terms of catalytic activity. Specifically, the oxidation catalyst may be a metal oxide selected from iron oxide, zinc oxide, copper oxide, cobalt oxide, zirconium oxide, vanadium oxide, manganese dioxide, titanium oxide, and the like. The oxidation catalyst may be contained in the range of 0 to 5% by weight in the softening composition (c) of the present invention, even if the content of the oxidation catalyst exceeds 5% by weight, the catalytic effect is no longer improved, so economically Not desirable More preferably, the oxidation catalyst is contained in the range of 0.0001 to 5% by weight in the softening composition (c) of the present invention.

In addition, in the softening composition (c) of the present invention, various treating agents such as alkalizing agents, acidifying agents, metal ion sequestering agents, opacifying agents, amino acids, keratins, silicones, waxes, polymers, swelling agents, permeating agents, fatty alcohols, Lanolin derivatives, ceramides, glycols, collagen, active ingredients, hair loss inhibitors, anti-dandruff agents, suspending agents, colorants, sunscreens and preservatives, and the like. In addition, protein, amino acids, and the like may be included to supply nutrients to the hair, and surfactants may be added to impart shampoo and rinse function. The additives described above are components included in a general permant, and those skilled in the art can be easily selected arbitrarily and used. The present invention does not have any particular limitation on the use of these additives. The additive may be contained in the softening composition (c) of the present invention in the range of 0 to 30% by weight. When the content of the additive is contained in excess of 30% by weight, the content of the softener or the oxidant is relatively reduced, so that the hair A problem arises that cannot be softened and oxidized. More preferably, in the softening composition (c) of this invention, an additive is contained in 0.01 to 20weight% of a range.

The softening composition (c) of this invention is manufactured by mixing each use component demonstrated above with deionized water. The softening composition (c) is prepared by adjusting the pH in the range of 2 to 9, and there is a fear of hair damage when the pH is less than 2 or exceeds pH 9. More preferably, the softening composition (c) of this invention is manufactured by adjusting to the pH 3-8 range.

The content ratio of each component used in the softening composition (c) according to the present invention is as follows: 0.1 to 25% by weight (preferably 1 to 20% by weight); 0-25% by weight of oxidizing agent (preferably 1-20% by weight); 0-5% by weight of an oxidation catalyst (preferably 0.0001-5% by weight); 0 to 30% by weight of other additives (preferably 0.01 to 20% by weight); It consists of 50-99.9 weight% (preferably 70-98 weight%) of deionized water. Particularly preferred softening compositions (c) include 1 to 20% by weight softener, 0.1 to 5% by weight locust gum, 1 to 20% by weight oxidant, 0.0001 to 5% by weight oxidation catalyst, 0.01 to 20% by weight of conventional additives, and deionized water It consists of 70-98 weight%.

In addition, in constructing the softening composition (c) of the present invention, the softening agent is used in the range of 0.1 to 50 parts by weight (preferably 1 to 10 parts by weight) based on 1 part by weight of the molding accelerator, so that the amount of the softening agent is If it is less than 0.1 part by weight, softening is not good, and if it is used in excess of 50 parts by weight, there is a problem in economy.

In addition, since the oxidizing agent is used in the range of 0.1 to 10 parts by weight (preferably 0.5 to 2 parts by weight) based on 1 part by weight of the softener, the oxidizing power is decreased when the amount of the oxidizing agent is less than 0.1 part by weight, If used excessively, there is a problem of economic and hair peroxidation reaction.

In the above, the composition of the three-component hair molding agent which consists of a reducing composition (a), a shaping composition (b), and a softening composition (c), and the role of each using component were demonstrated in detail.

However, the four-component hair forming agent prepared by dividing the oxidant described in the composition of the softening composition (c) as a separate component, that is, as the oxidizing composition (d) is also included in the scope of the present invention. That is, the four-part hair forming agent according to the present invention is composed of a reducing composition (a), a molding composition (b), a softening composition (c) and an oxidizing composition (d).

In preparing the four-component hair forming agent of the present invention, the oxidizing agent is contained as an essential component in the oxidizing composition (d), and an oxidizing catalyst can be selected and used as necessary.In addition, the oxidizing agent or It may optionally contain an oxidizing agent and an oxidation catalyst.

In preparing the four-component hair forming agent according to the present invention, the oxidizing agent contained as an essential component in the oxidizing composition (d), a hydrogen peroxide solution as mentioned in the softening composition (c), peroxides such as urea peroxide, Bromates such as alkali metal-containing bromates or a single or mixture selected from over salts can be used. The oxidizing agent may be contained in the oxidizing composition (d) of the present invention in the range of 0.1 to 25% by weight. If the content of the oxidizing agent is less than 0.1% by weight, the oxidizing effect may not be obtained. The problem of damaging hair occurs. More preferably, the oxidizing agent is contained in the range of 1 to 20% by weight in the oxidizing composition (d) of the present invention.

In addition, the oxidation catalyst contained in the oxidizing composition (d) is a component mentioned in the softening composition (c), and may be a metal or metal compound such as iron, zinc, copper, cobalt, zirconium, vanadium, manganese or titanium. It can be used alone or in combination, and in particular, it is more preferable in view of catalytic activity to prepare and use the above-described metal or metal compound in a nano-sized powder or liquid phase. The oxidation catalyst may be contained in the range of 0 to 5% by weight in the oxidizing composition (d) of the present invention, even if the content of the oxidation catalyst exceeds 5% by weight, the catalytic effect is not improved anymore. Not desirable More preferably, the oxidation catalyst is contained in the range of 0.0001 to 5% by weight in the oxidizing composition (d) of the present invention.

In addition, the oxidizing composition (d) may be used as various additives such as alkalizing agents, acidifying agents, metal ion sequestering agents, opacifying agents, amino acids, keratins, silicones, waxes, polymers, swelling agents, permeating agents, fatty alcohols, lanolin, and the like. It may contain a treatment agent selected from derivatives, ceramides, glycols, cellulose-based, active ingredients, hair loss inhibitors, anti-dandruff agents, suspending agents, colorants, sunscreen agents and preservatives. When using a hydrogen peroxide oxidizing agent, it is more preferable to add phenacetin, acetaniline, mono- and trisodium phosphate, or 8-hydroxyquinoline sulfate to stabilize. The additives described above are components included in a general permant, and those skilled in the art can be easily selected arbitrarily and used. The present invention does not have any particular limitation on the use of these additives. The additive may be contained in the range of 0 to 30% by weight in the oxidizing composition (d) of the present invention. When the content of the additive is contained in excess of 30% by weight, the contents of the oxidizing agent and the oxidation catalyst are relatively decreased. It can reduce the oxidizing power. More preferably, the additive is contained in the range of 0.01 to 20% by weight in the oxidizing composition (d) of the present invention.

The oxidizing composition (d) of the present invention is prepared by mixing each used component described above with deionized water. Since the oxidizing composition (d) is prepared by adjusting the pH in the range of 2 to 7, when the pH is less than 2 or above pH 7, the oxidizing power may be too strong or reduced to maintain the shape of the shaped hair. More preferably, the oxidizing composition (d) of the present invention is prepared by adjusting the pH to 3-6 range.

The content ratio of each used component constituting the oxidizing composition (d) according to the present invention may be constituted as follows: for example, 0.1 to 25% by weight (preferably 1 to 20% by weight); 0-5% by weight of an oxidation catalyst (preferably 0.0001-5% by weight); 0 to 30% by weight of other additives (preferably 0.01 to 20% by weight); It consists of 60-99.9 weight% (preferably 70-98 weight%) of deionized water. Particularly preferred oxidizing composition (d) contains 1 to 20% by weight of oxidizing agent, 0.1 to 5% by weight of locust gum, 0.0001 to 5% by weight of oxidation catalyst, 0.01 to 20% by weight of conventional additives, and 70 to 98% by weight of deionized water. It is done by

In addition, the amount of the oxidizing agent used in the manufacture of the hair forming agent based on 1 part by weight of the softening agent contained in the softening agent composition (c) also in the manufacture of the four-component hair forming agent for the same reason as described in the preparation of the three-component hair forming agent. When used in the range of 10 parts by weight (preferably 0.5 to 2 parts by weight), the oxidizing power is reduced when the amount of the oxidizing agent is less than 0.1 part by weight, and when used in excess of 10 parts by weight, economic problems and hair peroxidation reactions are reduced. There is a problem that occurs.

Meanwhile, another object of the present invention is to provide a de-rod and de-band type hair forming method. The hair forming method of the present invention is a new hair forming method capable of forming semi-permanently in a state in which the hair forming apparatus is removed.

Hair forming method according to the present invention may comprise the following steps (three-component hair molding method): i) applying a reducing composition containing a reducing agent and a sugar compound to the hair; Ii) shaping the hair to which the reducing composition is applied; Iii) shaping by applying a molding composition to the molded hair in combination with the sugar compound to induce molding; Iii) releasing the molding by applying a softening composition to the shaped hair: and iii) washing the hair to which the softening composition is applied.

In addition, the hair shaping method according to the present invention may comprise the following steps (four-component hair shaping method): i) applying a reducing composition containing a reducing agent and a sugar compound to the hair; Ii) shaping the hair to which the reducing composition is applied; Iii) shaping by applying a molding composition to the molded hair in combination with the sugar compound to induce molding; Iii) applying an oxidizing composition to the shaped hair and then applying a softening composition to the oxidized hair to release the molding; And iii) washing the hair to which the softening composition has been applied.

That is, the hair forming method according to the present invention will be described in more detail. I) the step of evenly applying the reducing composition containing the sugar compound to the hair, ii) using a molding apparatus capable of producing a suitable shape directly or by hand. Shaping the hair into a shape, i) applying the molding composition to the hair to induce shaping, and maintaining the shaping apparatus used for shaping the hair for a predetermined time, i) shaping. It is based on a hair forming method using a three-part hair forming agent, which includes applying a softening composition to the prepared hair to release the softening and molding of the hair, and iii) washing the hair as an essential process.

In carrying out the hair forming method using the three-part type hair forming agent, an oxidizing agent and an oxidation catalyst may be selectively used. In this case, an oxidizing agent and an oxidation catalyst may be included in the softening composition.

The present invention also includes a hair forming method using a four-component hair forming agent as a right scope, and in the hair forming method using a four-component hair forming agent, a process of applying the oxidizing composition (d) is included as an essential step. That is, after the process of applying the oxidizing composition (d) to the molded hair, the step of applying a softening composition (c) to release the molding.

In carrying out the hair forming method described above, ii) in the process of molding the hair, since the reducing composition has a certain viscosity and adhesive strength, it is possible to form the hair in a desired shape using a hand. In addition, it is also possible to mold using an appropriate molding apparatus, if necessary, and when the molding composition (b) is applied to the molded hair, the hair forming agent has elasticity and appropriate hardness, so that the molding apparatus used at this time is removed. You can keep it for a while.

In the case of using the reducing composition and the shaping composition constituting the hair forming agent of the present invention, curling in a desired shape can be sufficiently obtained even if the treatment is performed at room temperature without heat treatment. Optionally, the hair coated with the reducing composition may be heat-treated to a temperature of 30 to 60 ° C. or to 180 to 200 ° C. when treated separately after marching, and the final curl degree of the hair may be selectively controlled by such heating. You can also adjust the time spent in the permanent. In practice, this operation can be performed using a hair dryer hood, hair dryer, infrared emitter or other conventional heating device.

According to the hair shaping method according to the present invention described above, the contact time of the hair forming agent and the hair is slightly different depending on the hair condition when no separate heat treatment is performed, but it is about 1 to 40 minutes, preferably 2 to 20 minutes is enough.

In summary, the hair forming method of the present invention is distinguished from the existing hair forming method in brief.

First, hair shaping is easy with the user's intention.

Second, the hair is molded with the molding rods and rubber bands removed.

 Third, a barrier film is formed on its own to prevent drying of the hair molding agent and to prevent external contact.

Fourth, it regulates existing hair forming time.

 Such the present invention will be described in more detail based on the following Examples and Experimental Examples, but the present invention is not limited thereto.

Example 1: Preparation of Reducing Compositions

Next, a reducing composition was prepared by mixing the composition ratios of Tables 1a to 1e.

Reducing composition (% by weight) Comparison 1 Reduction 1 Reduction 2 Reduction 3 Reduction 4 Ammonium Thioglycolate (50%) 10.0 10.0 10.0 0.3 0.3 Cysteine hydrochloride - - - 8.0 - Cysteine free bass - - - - 5.0 N-acetylcysteine - - - 0.1 - Monoethanolamine thioglycolate - - 1.0 - - Algin 5.0 5.0 2.0 3.0 2.0 Carrageenan 0.5 0.5 1.0 0.2 0.1 Sodium caseinate 0.1 0.1 0.1 0.1 0.1 Locust gum - 0.2 - 3.0 0.1 Poly-L-Lysine - - - - 3.1 Chitosan - - - 0.1 - Polyvinyl alcohol 0.1 0.1 - - - 1% gold nanoparticle solution (average 10 nm) 0.1 0.1 - - - 1% platinum nanoparticle solution (average 10 nm) - - 0.1 0.1 0.1 Monoethanolamine - - - 2.0 2.0 Ammonia Water (28%) 3.0 3.0 3.0 - - Sterimonium chloride 0.1 0.1 0.1 0.1 0.1 Polyethylene glycol - - - 5.0 5.0 Propylene glycol 5.0 5.0 5.0 - - EDTA 0.2 0.2 0.2 0.2 0.2 Pigment 0.1 0.1 0.1 - - Spices 0.5 0.5 0.5 0.1 0.1 Deionized water 75.3 75.1 76.9 77.7 81.8 Sum 100 100 100 100 100

Reducing composition (% by weight) Reduction 5 Reduction 6 Reduction 7 Reduction 8 Reduction 9 Reduction 10 Algin 1.0 2.0 4.0 0.5 2.0 2.5 Carrageenan 2.0 0.5 1.0 4.0 1.0 1.0 Cellulose acetate 1.5 - - - - - Locust gum - 0.5 - 4.0 0.5 - Adipic acid - - - - - 1.0 Lactone - - 3.0 - - - Arginine - - - - 1.0 - Polyvinyl alcohol - - - - - 4.0 1% gold nanoparticle solution (average 10 nm) - - 0.1 0.1 0.1 0.1 1% platinum nanoparticle solution (average 10 nm) 0.1 0.1 - 0.1 - - Butylene glycol - 0.5 - - - - Propylene glycol Collagen - 1.6 - - - - EDTA - - 0.1 0.1 0.1 0.1 Commercial Perm 1 91.4 91.3 86.9 86.9 86.4 86.9 Deionized water 4.0 3.5 4.9 4.3 8.9 4.4 Sum 100 100 100 100 100 100

Reducing composition (% by weight) Reduction 11 Reduction 12 Reduction 13 Reduction 14 Reduction 15 Potassium thiocyanate - - - - 0.5 Sodium bisulfite - - - - 0.5 Algin 3.0 - 1.0 2.0 0.5 Carrageenan - 3.0 2.0 1.0 0.5 Locust gum 0.2 1.0 0.5 0.1 1.5 Glutaraldehyde - 1.0 - - - starch - - 2.0 - - Gluconic Acid 1.0 - - - - 1% gold nanoparticle solution (average 10 nm) 0.1 - 0.1 - 0.1 1% platinum nanoparticle solution (average 10 nm) - 0.1 - 0.1 - Monoethanolamine - - - - Quantity glycerin - - - - 3.0 ethanol - - - - 3.0 Butylene glycol - - 3.0 5.0 - EDTA - - 0.1 0.1 - Stabilizer 4.9 4.9 - - - Commercial Perm 1 82.1 82.1 86.9 86.9 - Deionized water 8.7 7.9 4.4 4.8 90.4 Sum 100 100 100 100 100

Reducing composition (% by weight) Reduction 16 Reduction 17 Reduction 18 Reduction 19 Reduction 20 Reduction 21 Reduction 22 Ammonium Thioglycolate (50%) 2.0 - 10.0 1.5 10.0 10.0 8.0 Cysteine hydrochloride - - - 8.5 - - - Sodium sulfite 2.0 - - - - - - Monoethanolamine thioglycolate - - - 0.5 - - - Algin 2.5 2.0 1.5 2.0 1.0 0.5 1.0 Carrageenan 0.5 1.0 1.5 3.0 0.8 0.5 2.5 pectin - - 1.0 - - - - Locust gum 0.3 0.1 0.1 2.0 0.3 1.0 0.5 Polyvinyl alcohol - - 0.1 - 0.1 0.1 - 1% gold nanoparticle solution (average 10 nm) 0.1 0.1 - - - 0.1 - 1% rhodium nanoparticle solution (average 10 nm) - - - - 0.1 - - Monoethanolamine Quantity - - 8.5 - - 9.0 Ammonia Water (28%) - - 3.0 - 3.0 3.0 - Sterimonium chloride - - 0.1 - 0.1 0.1 - Nonionic surfactant - - - - - - 3.0 Cocamido Profile Betaine - - - - - - 1.0 Cetyl ammonium chloride - - - 1.0 - - - Polyethylene glycol - - - 0.5 - - - Hexadicanol - - - 2.0 - - - Stearic acid - - - 0.5 - - - Sorbitan - - - 1.5 - - - Squalene - - - 0.1 - - - glycerin 3.0 - - 1.0 - - - ethanol 3.0 - - - - - - Butylene glycol - - - - - - 0.1 Propylene glycol Collagen - - - 0.5 - - 2.0 Hydrolyzed keratin - - - 0.5 - - - EDTA - 0.1 0.2 0.4 0.2 0.2 0.2 Pigment - - 0.1 - 0.1 0.1 0.1 Spices - - 0.5 - 0.5 0.5 0.5 Commercial Perm 1 - 94.7 - - - - - Deionized water 86.6 2.0 81.9 66.0 83.8 83.9 72.1 Sum 100 100 100 100 100 100 100

Reducing composition (% by weight) Reduction 23 Reduction 24 Reduction 25 Reduction 26 Reduction 27 Reduction 28 Ammonium Thioglycolate (50%) 10.0 - 12.0 8.0 8.0 - Cysteine hydrochloride 8.0 - 1.0 - 1.0 - N-acetylcysteine 1.0 - - - - - Sodium sulfite 5.0 - - - - - Sodium bisulfite - - 0.5 - - N-tetramethylmecaptoacetamide - 12.0 - - - - Ammonium hydrogen carbonate - 2.0 - - - - Algin 0.5 1.0 0.5 3.5 - 0.5 Carrageenan 2.0 1.0 2.0 - 3.5 2.5 pectin - - - - 0.5 - Locust gum 0.1 0.1 0.8 0.2 2.0 0.1 Adipic acid - - - 5.3 - - Poly-L-Lysine - - - - 0.3 - Chitosan 1.0 - - - - - Arginine - - 0.5 - 0.7 - Polyvinyl alcohol 0.2 - - - - - 1% gold nanoparticle solution (average 10 nm) - - 3.1 - - 0.5 1% platinum nanoparticle solution (average 10 nm) 0.6 - - 0.1 - - 1% rhodium nanoparticle solution (average 10 nm) - 0.1 - - 5.5 - Monoethanolamine 2.0 - 3.0 3.5 2.0 - Ammonia Water (28%) 4.0 0.4 1.0 - 1.0 - Sodium hydrogen 2.0 - - - - - Sodium laureth sulfite - - - - 3.0 - Nonionic surfactant - - - 4.5 - - Cocamido Profile Betaine 0.5 - - - 0.5 - Polyethylene glycol - - - 7.0 - - Sorbitan - - - 2.5 0.5 - Squalene - - - 4.7 - - glycerin - - 2.0 8.5 - - ethanol - - - 5.8 - - Butylene glycol - - - 6.0 - - Propylene glycol Collagen 3.0 - 1.0 3.0 - - EDTA 0.1 0.1 0.4 - - - Stabilizer - - - - - - Pigment 0.1 - 0.1 0.1 - - Spices 0.5 - 0.5 0.5 - - Commercial Perm 1 - - - - 18.0 96.4 Deionized water 59.4 83.3 71.6 36.8 53.5 - Sum 100 100 100 100 100 100

Example 2: Preparation of Molding Composition

Next, the molding compositions were prepared by mixing the composition ratios of Tables 2a to 2d.

Molding composition (% by weight) Molding 1 Molding 2 Molding 3 Molding 4 Molding 5 Molding 6 Molding 7 Zinc nitrate 2.5 - 0.1 - - 7.5 - Calcium chloride 2.5 1.5 - 5.0 - - 2.0 Calcium sulfate - - 0.5 - 3.0 - - Magnesium chloride - 3.5 - - - - 8.0 Ammonia Water (28%) 1.0 0.9 1.0 0.9 1.0 0.9 1.0 Isopropylamine - - - 0.1 - - - Monoethanolamine - 0.1 - - - - - Methylethanolamine - - - - - 0.1 - Locust gum 1.0 0.2 0.5 0.3 0.1 0.1 1.0 Oleyl alcohol 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Propylene glycol 5.0 5.0 - - - - - Oxalic acid 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Spices 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Deionized water 87.5 88.3 97.4 93.2 95.4 90.9 87.5 Sum 100 100 100 100 100 100 100

Molding composition (% by weight) Molding 8 Molding 9 Molding 10 Molding 11 Molding 12 Molding 13 Molding 14 Calcium acetate - 2.0 0.5 1.5 - - 1.0 Calcium nitrate 1.5 - - - 0.5 0.5 - Barium chloride - 3.0 - 2.5 - - 2.0 Strontium chloride 2.0 - 3.0 - 0.5 3.0 - Ammonia Water (28%) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Methylethanolamine - - - 0.5 0.2 0.1 0.5 Locust gum 1.2 0.2 0.2 - - - - Oleyl alcohol 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Propylene glycol - 4.0 - 4.0 4.0 - - Oxalic acid 0.1 0.1 0.1 - - - - Spices 0.2 0.2 0.2 0.1 0.1 0.1 0.1 Deionized water 93.8 89.3 94.8 90.2 93.5 95.1 95.2 Sum 100 100 100 100 100 100 100

Molding composition (% by weight) Molding 15 Molding 16 Molding 17 Molding 18 Molding 19 Molding 20 Molding 21 Zinc nitrate 5.0 - 2.5 0.5 1.0 1.5 - Calcium chloride - 2.5 1.5 0.5 2.0 - 1.5 Calcium sulfate 5.0 - 0.5 2.0 - 1.5 - Magnesium chloride - 0.5 0.5 - 1.0 - 1.5 Ammonia Water (28%) 1.0 1.0 1.0 1.0 - 1.0 - DL-cysteine hydrochloride - - - 0.05 - - - Monoethanolamine thioglycolate - - - 0.05 - - - Monoethanolamine - - - - - - 2.0 Locust gum 0.5 1.0 3.0 1.5 0.1 0.4 0.5 Methylethanolamine - - - - - - - Oleyl alcohol 0.2 0.2 0.2 0.2 - 0.2 0.2 Propylene glycol 1.0 2.5 0.1 4.0 1.0 5.0 5.0 Butylene glycol - - 0.5 - - - - glycerin - - - - 1.0 - - Hydrolyzed keratin - - - - 0.5 - - Collagen - - - - 0.5 - - Oxalic acid 0.1 0.1 0.1 0.1 - 0.1 0.1 Spices 0.2 0.2 0.2 0.2 - 0.2 0.2 Deionized water 87.0 92.0 89.9 89.9 92.9 90.1 89.0 Sum 100 100 100 100 100 100 100

Molding composition (% by weight) Molding 22 Molding 23 Molding 24 Molding 25 Molding 26 Molding 27 Molding 28 Calcium acetate 0.1 2.0 0.5 2.0 - 1.5 2.0 Calcium nitrate - 1.0 0.5 - 3.0 - - Barium chloride 0.2 - 0.5 - - 2.5 1.5 Strontium chloride - - 0.5 3.0 2.0 - - Ammonia Water (28%) 1.0 - 0.5 1.0 1.5 0.5 - DL-cysteine hydrochloride - - - 3.0 2.0 - - Monoethanolamine thioglycolate - - - 2.0 - 1.5 - Isopropylamine - - - 0.5 - - 0.5 Monoethanolamine - - - 0.5 0.5 - - Locust gum 0.4 0.2 0.5 0.1 0.1 1.5 0.1 Methylethanolamine - - - 0.1 - 0.1 - Oleyl alcohol 0.2 - 3.0 2.0 2.5 4.0 - Propylene glycol - 2.0 - 3.0 22.0 - - Butylene glycol - - - 4.5 - 0.4 1.0 glycerin - - - 2.0 - - 0.5 Hydrolyzed keratin - - - 5.0 - 2.0 - Collagen - - - 2.0 1.5 1.0 - Oxalic acid 0.1 - 0.5 0.4 0.1 0.2 - Spices 0.2 - - 0.5 0.1 0.3 - Deionized water 97.8 94.8 93.5 68.4 64.7 84.5 94.4 Sum 100 100 100 100 100 100 100

Example 3: Preparation of Oxidizing Compositions

Next, the oxidation compositions were prepared by mixing the composition ratios of Tables 3a to 3c.

Oxidation Composition (% by weight) Oxidation 1 Oxidation 2 Oxidation 3 Oxidation 4 Oxidation 5 Oxidation 6 Oxidation 7 Sodium bromate 5.0 - 5.0 - 5.0 - 5.0 Hydrogen peroxide (35%) - 5.07 - 5.07 - 5.07 - Citric acid - 1.0 - - - - - Locust gum 0.4 0.5 0.2 0.1 0.8 1.5 0.4 Phenacetin - - - 1.0 - 1.0 - Deionized water 94.6 93.43 94.8 93.83 94.2 92.43 94.6 Sum 100 100 100 100 100 100 100

Oxidation Composition (% by weight) Oxidation 8 Oxidation 9 Oxidation 10 Oxidation 11 Oxidation 2 Oxidation 13 Oxidation 14 Sodium bromate - 5.0 - 5.0 - 5.0 - Hydrogen peroxide (35%) 5.07 - 5.07 - 5.07 - 5.07 Citric acid - - - - 1.0 - - Locust gum 0.1 - 0.5 0.1 0.1 0.2 0.5 Phenacetin 1.0 - 1.0 - - - 1.0 Deionized water 93.83 95.0 93.43 94.9 93.83 94.8 93.43 Sum 100 100 100 100 100 100 100

Oxidation Composition (% by weight) Oxidation 15 Oxidation 16 Oxidation 17 Oxidation 18 Oxidation 19 Oxidation 20 Oxidation 21 Sodium bromate - - 5.0 5.0 5.0 22.0 - Hydrogen peroxide (35%) 5.07 5.0 - - - - 8.0 Titanium dioxide - - - 0.001 0.001 4.0 0.5 Citric acid - 0.5 - - - - - Ceramide - - - - - 8.9 3.5 Silicone emulsion - - - - - - 3.0 Locust gum 0.5 1.0 0.2 0.1 0.1 0.5 0.1 glycerin - - - 2.0 - - 10.0 Hydrolyzed keratin - - - - - - 5.0 Polyquarium-10 - - - - - - 2.0 Phenacetin 1.0 0.1 - - - 0.1 - Deionized water 93.43 93.4 94.8 92.899 94.899 64.5 70.9 Sum 100 100 100 100 100 100 100

Oxidation Composition (% by weight) Oxidation 22 Oxidation 23 Oxidation 24 Oxidation 5 Oxidation 26 Sodium bromate - - 5.0 5.0 5.0 Hydrogen peroxide (35%) 5.07 5.0 - - - Titanium dioxide - 0.1 - 0.001 0.001 Citric acid - 0.5 - - - Ceramide - - 2.0 1.0 - Silicone emulsion - 0.1 - 1.0 - Locust gum 0.5 1.0 0.2 0.1 0.1 glycerin 2.0 - - - 0.1 Hydrolyzed keratin 1.0 - 0.7 - - Polyquarium-10 1.0 - - 1.0 - Phenacetin 1.0 0.1 - - 0.4 Deionized water 89.43 93.2 92.1 91.899 94.399 Sum 100 100 100 100 100

Example 4: Preparation of Softening Composition

Next, a softening composition was prepared by mixing at a composition ratio of Tables 4a to 4d.

Softening Composition (wt%) Softening 1 Softening 2 Softening 3 Softening 4 Softening 5 Softening 6 Softening 7 Sodium phosphate 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Potassium phosphate 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Sodium citrate 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Locust gum 1.0 0.5 0.4 0.1 0.2 0.1 0.5 1% zinc oxide nanoparticles (average 10 nm) 0.2 - - - - 0.2 0.2 1% titanium dioxide nanoparticles (average 10 nm) - 0.2 - - - - - 1% iron oxide nanoparticles (average 10 nm) - - 0.2 - - - - 1% zirconium oxide nanoparticles (average 10 nm) - - - 0.2 - - - 1% vanadium oxide nanoparticles (average 10 nm) - - - - 0.2 - - Silicone emulsion 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Hydrolyzed keratin 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Pigment 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Deionized water 94.9 95.4 95.5 95.8 95.7 95.8 95.4 Sum 100 100 100 100 100 100 100

Softening Composition (wt%) Softening 8 Softening 9 Softening 10 Softening 11 Softening 12 Softening 13 Softening 14 Sodium phosphate 0.3 0.3 0.3 0.3 0.3 - - Potassium phosphate 0.4 0.4 0.4 0.4 0.4 - - Citric acid 1.0 1.0 1.0 1.0 1.0 2.0 2.0 Sodium citrate 1.0 1.0 1.0 1.0 1.0 3.0 3.0 Potassium citrate - - - - - - - Bentonite - - - - - 3.0 3.0 Elvan - - - - - 3.0 3.0 Sodium carbonate - - - - - 1.0 1.0 Sodium bromate - - - - - - - Locust gum 0.4 - 0.2 1.0 0.4 0.6 0.1 1% zinc oxide nanoparticles (average 10 nm) 0.2 - 0.2 0.2 0.2 - - 1% titanium dioxide nanoparticles (average 10 nm) - 0.2 - - - - - Silicone emulsion 1.0 1.0 1.0 1.0 1.0 - - Hydrolyzed keratin 0.1 0.1 0.1 0.1 0.1 - - Pigment 0.1 0.1 0.1 0.1 0.1 - - Deionized water 95.5 95.9 95.7 94.9 95.5 87.4 87.9 Sum 100 100 100 100 100 100 100

Softening Composition (wt%) Softening 15 Softening 16 Softening 17 Softening 18 Softening 19 Softening 20 Softening 21 Sodium phosphate 0.3 0.3 0.3 0.3 - 0.3 1.0 Potassium phosphate 0.4 0.4 0.4 0.4 - 0.4 0.4 Citric acid 1.0 1.0 1.0 1.0 0.5 1.0 1.0 Sodium citrate 1.0 1.0 1.0 1.0 2.0 1.0 1.0 Potassium citrate - - - - 0.5 - - Locust gum 0.2 0.2 0.1 0.4 0.5 0.3 0.5 1% zinc oxide nanoparticles (average 10 nm) 0.2 0.2 0.2 - - 0.2 0.2 1% titanium dioxide nanoparticles (average 10 nm) - - - 0.2 0.1 0.001 - Silicone emulsion 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Hydrolyzed keratin 0.1 0.1 0.1 0.1 0.2 0.1 0.1 Pigment 0.1 0.1 0.1 0.1 - 0.1 0.1 Deionized water 95.7 95.7 95.8 95.5 95.2 95.5999 95.4 Sum 100 100 100 100 100 100 100

Softening Composition (wt%) Softening 22 Softening 23 Softening 24 Softening 25 Softening 26 Softening 27 Softening 28 Sodium phosphate 0.3 - 2.0 - 1.0 - 0.5 Potassium phosphate 0.4 - 1.0 - - 0.5 1.5 Citric acid 1.0 2.0 1.0 - - 1.5 2.0 Sodium citrate 1.0 - 2.0 2.0 3.0 2.0 - Potassium citrate - 1.0 5.0 2.0 1.0 - 0.5 Bentonite - - 3.0 - - 3.0 - Elvan - - 2.5 0.5 1.5 - - Sodium carbonate - 0.5 3.5 - 2.5 - 2.5 Sodium bromate - 22.0 1.0 0.5 - 8.0 - Locust gum 0.1 0.2 0.4 0.5 1.0 1.5 0.4 1% zinc oxide nanoparticles (average 10 nm) 0.2 - - - 0.5 2.0 - 1% titanium dioxide nanoparticles (average 10 nm) - - - 4.5 - - 2.0 1% iron oxide nanoparticles (average 10 nm) - - 0.5 - - 2.5 - 1% zirconium oxide nanoparticles (average 10 nm) - 0.5 - - - 0.5 - 1% vanadium oxide nanoparticles (average 10 nm) - - - 0.5 - - - Silicone emulsion 1.0 - - 2.0 2.5 0.5 1.5 Hydrolyzed keratin 0.1 0.5 - 2.0 0.8 - 0.5 Ceramide - 3.0 - 3.0 1.0 3.5 - glycerin - - - 3.0 - 2.0 - Propylene glycol - 2.5 - 10.0 1.5 - - Collagen - - - 5.0 - - - Pigment 0.1 - 0.1 - 0.2 0.2 - Deionized water 95.8 67.8 78.0 63.5 83.5 72.5 88.6 Sum 100 100 100 100 100 100 100

Experimental Example 1. Evaluation of Physical Properties of Hair Molding Agent

For each of the compositions prepared in Preparation Examples 1 to 4, a hair molding agent was prepared in the configuration shown in Table 5 below, and hair treatment was performed in the following manner.

30 strands of untreated hair with a length of 20 cm and a weight of 15 g were immersed in the reducing composition for 2 minutes, wound on a rod having a diameter of 14 mm, and the molding composition was sprayed with 3 mL. After 10 minutes, 5 mL of the oxidized composition was sprayed twice for 10 minutes, washed with water, and air dried to form curls.

In addition, the evaluation results for the following test clauses are summarized in Table 6 below. The evaluation results shown in Table 6 are symbolized according to the following criteria.

1) curling force

◎: When the curl diameter is less than 20 mm

○: When the curl diameter is 20 mm or more but less than 25 mm

(Triangle | delta): When the curl diameter is 25 mm or more and less than 30 mm

×: when the curl diameter is 30 mm or more

2) curl uniformity

◎: When the diameter error range is less than 4 mm in the curl of the beginning and the end of the hair

(Circle): When the diameter error range is 4 mm or more and less than 8 mm in the curl of the beginning and the end of hair.

(Triangle | delta): When the diameter error range is 8 mm or more and less than 12 mm in the curl of the beginning and end of a hair.

X: the diameter error range in the curl of the beginning and the end of the hair is 12 mm or more

3) Volume, gloss, health, moisture retention

Hair volume, shine, health and moisturizing are the results of sensory evaluation by 20 beauty technicians,

◎: When 15 or more beauty technicians rated excellent

(Circle): When 10 or more and less than 15 beauty technicians evaluate it as excellent

(Triangle | delta): When 5 or more and less than 10 beauty technicians evaluate as excellent

X: When less than 5 beauty technicians evaluated it as excellent

division Composition of hair forming agent and addition of logger's gum Reducing composition Molding composition Oxidation composition Softening composition Comparative Example 1 Comparison 1 Molding 11 Oxidation 9 Softening 9 Example 1 Reduction 1 Molding 1 Oxidation 1 Softening 1 Example 2 Reduction 2 Molding 2 Oxidation 2 Softening 2 Example 3 Reduction 3 Molding 3 Oxidation 3 Softening 3 Example 4 Reduction 4 Molding 4 Oxidation 4 Softening 4 Example 5 Reduction 5 Molding 5 Oxidation 5 Softening 5 Example 6 Reduction 6 Molding 6 Oxidation 6 Softening 6 Example 7 Reduction 7 Molding 7 Oxidation 7 Softening 7 Example 8 Reduction 8 Molding 8 Oxidation 8 Softening 8 Example 9 Reduction 9 Molding 9 Oxidation 9 Softening 9 Example 10 Reduction 10 Molding 10 Oxidation 10 Softening 10 Example 11 Reduction 11 Molding 11 Oxidation 11 Softening 11 Example 12 Reduction 12 Molding 12 Oxidation 12 Softening 12 Example 13 Reduction 13 Molding 13 Oxidation 13 Softening 13 Example 14 Reduction 14 Molding 14 Oxidation 14 Softening 14 Example 15 Reduction 15 Molding 15 - Softening 15 Example 16 Reduction 16 Molding 16 - Softening 16 Example 17 Reduction 17 Molding 17 Oxidation 15 Softening 17 Example 18 Reduction 18 Molding 18 Oxidation 16 Softening 18 Example 19 Reduction 19 Molding 19 Oxidation 17 Softening 19 Example 20 Reduction 20 Molding 20 Oxidation 18 Softening 20 Example 21 Reduction 21 Molding 21 Oxidation 19 Softening 21 Example 22 Reduction 22 Molding 22 Oxidation 20 Softening 22 Example 23 Reduction 23 Molding 23 Oxidation 21 Softening 23 Example 24 Reduction 24 Molding 24 Oxidation 22 Softening 24 Example 25 Reduction 25 Molding 25 Oxidation 23 Softening 25 Example 26 Reduction 26 Molding 26 Oxidation 24 Softening 26 Example 27 Reduction 27 Molding 27 Oxidation 25 Softening 27 Example 28 Reduction 28 Molding 28 Oxidation 26 Softening 28

division Measurement property Curl Curl uniformity Volume Gloss Health Moisturizing Comparative Example 1 ◎ ◎ ○ ◎ ○ ○ Example 1 ◎ ◎ ○ ◎ ○ ○ Example 2 ○ ◎ ◎ ○ △ △ Example 3 ○ ◎ ○ △ ◎ ○ Example 4 ◎ ○ ◎ ○ ○ ○ Example 5 ◎ ◎ ◎ ○ ◎ ○ Example 6 ○ ○ ○ ○ △ △ Example 7 ◎ ◎ ○ ◎ ○ ○ Example 8 ◎ ○ ◎ ○ ○ ○ Example 9 ○ ◎ ○ ○ ◎ ◎ Example 10 ◎ ◎ ◎ ○ ○ ○ Example 11 ◎ ◎ ○ ◎ ◎ ○ Example 12 ◎ ○ ◎ ◎ △ ◎ Example 13 ◎ ◎ ◎ ○ △ ◎ Example 14 ○ ◎ ○ ◎ ○ ○ Example 15 ○ ◎ ○ △ ○ ○ Example 16 ◎ ○ ○ ○ ○ △ Example 17 ◎ ○ ◎ ◎ ○ ○ Example 18 ◎ ◎ ◎ ○ ○ △ Example 19 ◎ ◎ ◎ △ ◎ ○ Example 20 ○ △ ○ ◎ ◎ ◎ Example 21 ○ ◎ ○ △ ○ ○ Example 22 ◎ △ ◎ ◎ ○ ○ Example 23 ○ ○ ○ △ ○ △ Example 24 ◎ ◎ ○ △ ○ ○ Example 25 ○ △ △ ○ ○ △ Example 26 ◎ ◎ ◎ ○ △ ◎ Example 27 ○ ◎ ○ △ ○ ○ Example 28 ◎ ○ ○ ◎ ○ ○

Experimental Example 2 Evaluation of Storage Stability for Hair Molding Agent

For each composition constituting the hair forming agent of the present invention, the long-term storage stability of the hair forming product according to the attachment of the locust gum was evaluated.

1) Leaching phenomenon of active ingredient

As a result of evaluating leaching separation for 6 months after sealing the hair treatment agent in a 100 mL beaker at 4 ℃ Celsius,

◎: When separated layer is 5 mm or less

(Circle): When the separated layer is 5-50 mm

(Triangle | delta): When the separated layer is 50-100 mm

×: when the separated layer is 100 mm or more

Leaching phenomenon of active ingredient Reducing composition Molding composition Oxidation composition Softening composition Comparison 1 × Molding 11 × Oxidation 9 × Softening 9 × Reduction 1 ○ Molding 1 ◎ Oxidation 1 ○ Softening 1 ◎ Reduction 2 × Molding 2 ○ Oxidation 2 ○ Softening 2 ○ Reduction 3 ◎ Molding 3 ○ Oxidation 3 ○ Softening 3 ○ Reduction 4 △ Molding 4 ○ Oxidation 4 △ Softening 4 △ Reduction 5 × Molding 5 △ Oxidation 5 ○ Softening 5 ○ Reduction 6 ○ Molding 6 △ Oxidation 6 ◎ Softening 6 △ Reduction 7 × Molding 7 ◎ Oxidation 7 ○ Softening 7 ○ Reduction 8 ◎ Molding 8 ◎ Oxidation 8 △ Softening 8 △ Reduction 9 ○ Molding 9 ○ Oxidation 9 × Softening 9 × Reduction 10 × Molding 10 ○ Oxidation 10 ○ Softening 10 ○ Reduction 11 ○ Molding 11 × Oxidation 11 △ Softening 11 ◎ Reduction 12 ◎ Molding 12 × Oxidation 12 △ Softening 12 ○ Reduction 13 ○ Molding 13 × Oxidation 13 ○ Softening 13 ○ Reduction 14 △ Molding 14 × Oxidation 14 ○ Softening 14 △ Reduction 15 ◎ Molding 15 ○ - - Softening 15 ○ Reduction 16 ○ Molding 16 ◎ - - Softening 16 ○ Reduction 17 △ Molding 17 ◎ Oxidation 15 ○ Softening 17 △ Reduction 18 ◎ Molding 18 ◎ Oxidation 16 ◎ Softening 18 ○ Reduction 19 ○ Molding 19 △ Oxidation 17 ○ Softening 19 ○ Reduction 20 ○ Molding 20 ○ Oxidation 18 △ Softening 20 ○ Reduction 21 ◎ Molding 21 ○ Oxidation 19 △ Softening 21 ○ Reduction 22 ○ Molding 22 ○ Oxidation 20 ○ Softening 22 ○ Reduction 23 △ Molding 23 ○ Oxidation 21 △ Softening 23 ○ Reduction 24 △ Molding 24 ○ Oxidation 22 ○ Softening 24 ○ Reduction 25 ○ Molding 25 △ Oxidation 23 ◎ Softening 25 ○ Reduction 26 ○ Molding 26 △ Oxidation 24 ○ Softening 26 ◎ Reduction 27 ◎ Molding 27 ◎ Oxidation 25 △ Softening 27 ◎ Reduction 28 △ Molding 28 △ Oxidation 26 △ Softening 28 ○

As confirmed from Table 7, the composition containing the locust gum as a stabilizer can be seen that almost no leaching phenomenon even during long-term storage of more than 6 months. Therefore, it is preferable to add locust gum to each composition which comprises the hair forming agent of this invention.

As described above, the hair forming agent of the present invention is a new concept hair forming agent and a hair forming method having an effect of forming itself, and is a hair forming method using a device such as a perm rod or a rubber band. It gives the effect of drastically improving the method.

In addition, the sugar compound used in the hair forming agent of the present invention is a conventional commercial perm, ie, acid perm, alkaline perm, no neutralizing perm, hot air perm, setting perm, straight perm, etc. Even if applied to the same hair reshaping effect, when using the hair molding agent of the present invention it can be seen that the curl of the reshaped hair is firmly formed and the tension is given to the hair.

In addition, the sugar compound used as a feature of the hair-forming agent of the present invention is a stable substance that can be combined with ingredients that can provide nutrition to the hair, so that various components are included in various composition ratios according to the hair condition of the subject. Molding agents can be provided.

In addition, in the case of using the hair forming agent of the present invention, even if the hair forming is performed by any method as described above, hair reshaping does not proceed while continuously wearing various hair forming tools such as a pump rod or a band. Because the subject may not feel at all uncomfortable, the operator gives the effect that can be easily performed.

Claims (40)

(a) a reducing agent; A reducing composition containing a sugar compound selected from algin, carrageenan and sugar derivatives thereof, (b) a molding composition containing a metal element component of valence 2 which binds to the sugar compound to induce molding, and (c) a three-part hair forming agent containing a softening composition selected from an inorganic acid, an organic acid or an acid salt thereof, and minerals, and comprising a softening composition which releases the bond between the sugar compound and the valence 2 metal element. The self-forming hair forming agent having improved storage stability, characterized in that the locust gum is further contained in any one or two or more compositions selected from the reducing composition, the molding composition, and the softening composition. (a) a reducing agent; A reducing composition containing a sugar compound selected from algin, carrageenan and sugar derivatives thereof, (b) a molding composition containing a metal element component having a valence 2 in combination with the sugar compound to induce molding; (c) a softening composition containing a softening agent selected from inorganic acids, organic acids or acid salts thereof, and minerals, wherein the softening composition releases the bond between the sugar compound and the valence 2 metal element; and (d) a four-part hair forming agent comprising an oxidizing composition containing an oxidizing agent, A self-forming hair forming agent having excellent storage stability, characterized in that a locust gum is further contained in any one or two or more compositions selected from the above reducing composition, molding composition, softening composition and oxidizing composition. The method of claim 1 or 2, wherein the reducing composition (a) is Hair forming agent, characterized in that in the range of pH 4-11. The method of claim 1 or 2, wherein the reducing composition (a) is A hair forming agent comprising a reducing agent containing a functional group selected from a sulfide group, a bisulfide group, a thiol group, a cyan group, a thiocyanate group, a hydroxyl group, a sulfite group, a bisulfite group, and a bicarbonate group. The method of claim 4, wherein the reducing agent A hair forming agent selected from the group consisting of thioglycolic acid or salts thereof, thioglycolic acid esters, thioxalic acid, thiolactic acid esters, cysteines, cysteamines, thiocyanates, sulfites and derivatives thereof. The method of claim 1 or 2, wherein the reducing composition (a) is A hair forming agent characterized in that an organic / inorganic composite film having an internal structure of an interpenetrating polymer network (IPN) is formed by reacting with a valence 2 metal element contained in the molding composition (b). The method of claim 1 or claim 2, wherein the sugar derivative is Hair-forming agent, characterized in that it has a functional group selected from monovalent or polyvalent hydroxyl group, aldehyde group, carboxylic acid group, ester group and ketone group. The method of claim 1 or 2, wherein the reducing composition (a) is A hair molding agent containing from 0.01 to 1 part by weight of a sugar compound, based on 1 part by weight of a reducing agent. The method of claim 1 or 2, wherein the reducing composition (a) is Hair forming agent, characterized in that the viscosity ranges from 1,000 to 60,000 cP. The method of claim 1 or 2, wherein the reducing composition (a) is It contains a reactive substance having a reactor selected from a hydroxyl group (-OH), carboxylic acid group (-COOH), carboxylate group (-COOR), ketone group (-CO-), and aldehyde group (-COH) Hair forming agent. The method of claim 10, wherein the reactive material Polyols, chitin or chitin derivatives, chitosan or chitosan derivatives, maleic acid, aminopropyl-silicic acid, poly-L-lysine, cellulose, cellulose salts including glycols, polyalkylene glycols, polyvinyl alcohols Or derivatives thereof, adipic acid, gelatin, pectin, arginine or polymers thereof, gluconic acid, lactones, sodium caseinate, vinyl acetate, starch or derivatives thereof, elastin, Hair forming agent, characterized in that it is selected from acrylamide, acrylamide polymer or derivatives thereof, gellan gum, carbopol, glutaraldehyde, and acrylate polymer. The method of claim 11, wherein the reactive material is Hair forming agent, characterized in that selected from polyalkylene glycol, chitosan and maleic acid. The method of claim 12, wherein the reducing composition (a) is A hair molding agent containing a reactive substance in the range of 0.1 to 5 parts by weight based on 1 part by weight of the sugar compound. The method of claim 1 or 2, wherein the reducing composition (a) is A hair forming agent comprising a reducing catalyst selected from gold, platinum, palladium, rhodium, hydrides, hydroxides, oxalic acid and ascorbic acid. The method of claim 14, wherein the reduction catalyst Hair forming agent, characterized in that the metal or metal compound selected from gold, platinum, palladium and rhodium is a powdery or liquid substance containing nano-size. The method according to claim 1 or 2, wherein the molding composition (b) is Hair forming agent, characterized in that the pH range from 2 to 12. The method according to claim 1 or 2, wherein the molding composition (b) is A hair forming agent comprising a metal having a valence 2 and a metal element selected from a metal compound and a water-soluble salt thereof. The hair forming agent according to claim 17, wherein the valence 2 metal is selected from magnesium, calcium, barium, strontium, zinc, and iron (II). The metal element component of claim 1 or 2, wherein the valence 2 Hair forming agent, characterized in that contained in 0.0001 to 5 parts by weight based on 1 part by weight of the sugar compound contained in the reducing composition (a). The method according to claim 1 or 2, wherein the softening composition (c) is Hair forming agent, characterized in that the pH range 2-9. The method according to claim 1 or 2, wherein the softener Inorganic acids and salts thereof selected from nitric acid, sulfuric acid, carbonic acid, bicarbonate, hydrochloric acid, and phosphoric acid; Organic acids selected from citric acid, succinic acid and acetic acid and salts thereof; And Minerals selected from ocher, illite, elvan, bentonite and montmorillonite; Hair forming agent, characterized in that one or a mixture of two or more selected from. The method according to claim 1 or 2, wherein the softener A hair forming agent, characterized in that contained in the range of 0.1 to 50 parts by weight based on 1 part by weight of the sugar compound contained in the reducing composition (a). The method of claim 1, wherein the softening composition (c) is A hair forming agent, further comprising an oxidizing agent selected from peroxides, bromates, and persalts, and an oxidation catalyst selected from iron, zinc, copper, cobalt, zirconium, vanadium, manganese, and titanium. The method of claim 2, wherein the oxidizing composition (d) is Hair forming agent, characterized in that pH 2-7 range. The method of claim 2, wherein the oxidizing composition (d) is A hair forming agent comprising an oxidizing agent selected from peroxides, bromates, and persalts. The method of claim 2, wherein the oxidizing composition (d) is A hair forming agent comprising an oxidation catalyst selected from iron, zinc, copper, cobalt, zirconium, vanadium, manganese and titanium. The method of claim 23 or 25, wherein the oxidizing agent A hair molding agent containing 0.1 to 10 parts by weight based on 1 part by weight of the softener contained in the softening composition (c). 27. The hair forming agent according to claim 23 or 26, wherein the oxidation catalyst is in powder form or liquid state containing a metal or metal compound in nano size. The method of claim 1 or 2, wherein the reducing composition (a) is A hair molding agent comprising 1 to 25% by weight of a reducing agent and 0.1 to 15% by weight of a sugar compound. The method of claim 29, wherein the reducing composition (a) is 2 to 20% by weight of reducing agent, 0.5 to 10% by weight of sugar compound, 0.01 to 3% by weight of reactive substance, 0.0001 to 5% by weight of reducing catalyst, 0.01 to 60% by weight of conventional additives, and 30 to 90% by weight of deionized water Hair forming agent, characterized in that consisting of. 31. The method of claim 1, 2 or 30, wherein the reducing composition (a) 2 to 20% by weight of reducing agent, 0.5 to 10% by weight of sugar compound, 0.1 to 5% by weight of locust gum, 0.01 to 3% by weight of reactive substance, 0.0001 to 5% by weight of reducing catalyst, 0.01 to 60% by weight of conventional additives, and deamination A hair molding agent comprising 30 to 90% by weight of deionized water. The method according to claim 1 or 2, wherein the molding composition (b) is A hair forming agent comprising 0.1 to 25 wt% of a valence 2 metal element component. 33. The method of claim 32, wherein the shaping composition (b) A hair forming agent comprising 1 to 20% by weight of a metal element component of valence 2, 0.01 to 20% by weight of an ordinary additive, and 70 to 98% by weight of deionized water. The method of claim 33, wherein the molding composition (b) is A hair forming agent comprising 1 to 20% by weight of a metal element component of valence 2, 0.1 to 5% by weight of locust gum, 0.01 to 20% by weight of conventional additives, and 70 to 98% by weight of deionized water. . The method according to claim 1 or 2, wherein the softening composition (c) is A hair forming agent comprising 0.1 to 25% by weight of a softening agent. 36. The method of claim 35, wherein the softening composition (c) Hair forming agent comprising 1 to 20% by weight of softener, 1 to 20% by weight of oxidizing agent, 0.0001 to 5% by weight of oxidation catalyst, 0.01 to 20% by weight of conventional additives, and 70 to 98% by weight of deionized water. . The method of claim 36, wherein the softening composition (c) is 1 to 20% by weight of softener, 0.1 to 5% by weight of locust gum, 1 to 20% by weight of oxidant, 0.0001 to 5% by weight of oxidation catalyst, 0.01 to 20% by weight of ordinary additives, and 70 to 98% by weight of deionized water. Hair forming agent, characterized in that made. The method of claim 2, wherein the oxidizing composition (d) is A hair forming agent comprising 0.1 to 25% by weight of an oxidizing agent. The method of claim 38, wherein the oxidizing composition (d) A hair forming agent comprising 1 to 20% by weight of an oxidizing agent, 0.0001 to 5% by weight of an oxidation catalyst, 0.01 to 20% by weight of ordinary additives, and 70 to 98% by weight of deionized water. 40. The composition of claim 39, wherein said oxidizing composition (d) 1 to 20% by weight of oxidizing agent, 0.1 to 5% by weight of locust gum, 0.0001 to 5% by weight of oxidation catalyst, 0.01 to 20% by weight of ordinary additives, and 70 to 98% by weight of deionized water. My.

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