KR20070069412A - Hair roll maker compositions - Google Patents

Abstract

Pump type hair roll maker compositions are provided to maintain hair style with wave or curl formed by an iron for a long period of time, protect the hair from heat of the iron, and improve smoothness and combing feeling of the hair when the composition is applied to the hair prior to wave or curl making with the iron. The pump type hair roll maker composition comprises 0.1-5.0 wt.% of metacryloyl ethylbetaine metacrylate copolymer represented by the formula(1), 0.000005-0.0001 wt.% of poly(ethylene oxide) represented by the formula(2) of (-CH2CH2O-)n and 0.1-5.0 wt.% of provitamin B(panthenol or (R)-2,4-dihydroxy-3,3-dimethylbutyric 3-hydroxypropylamide) represented by the formula(3) of C9H19NO4, and is applied to the hair prior to wave or curl making with the iron.

Description

Hair Roll Maker Compositions

The present invention relates to a pump-type hair roll maker (Roll Maker) composition for injecting fine particles.

More specifically, the present invention is a methacryloyl acetylbetaine methacrylate copolymer having the physical properties of the mass average molecular weight 10,000 ~ 75,000, viscosity (20 ℃) 20,000 ~ 55,000cps and Tm: 110 ~ 290 ℃ (Formula 1 Mass average molecular weight: 100,000 to 8,000,000, Tm: 57 to 77 ° C and viscosity (25 ° C, 1% Aqueous Solution): poly (ethylene oxide) with properties of 600 to 5500 cps (see formula 2) and mass average It relates to a pump type hair roll maker (Roll Maker) composition containing Provitamin B (see Formula 3) having a molecular weight of 100 to 2,000 and a density (20 ° C) of 1.0 to 1.8 g / mL. After spraying the hair roll maker of the present invention to the hair to make a hair wave or curl using a heated iron, the hairstyle is not only maintained for a long time, but also protects the hair from the heat of the curling iron, Helps to smooth and comb your hair.

The present invention provides a pump-type hair roll that keeps a hair wave or curl made by using a heated iron and provides hair protection and smoothness from the heat of the iron. It relates to a roll maker composition.

Humans feel satisfied by dyeing their hair, perm and dryer to pursue beauty.

In addition, women with long straight hair have a strong desire to have a changed hairstyle by temporarily creating a natural wave or curl. To meet these needs, women with long straight hair generally use heated iron to make curls of the desired hair. However, the curled hair is released in a very short time and has a fatal problem that the hair is damaged by hot iron heat. Humans want to keep their hair curled for a long time, and are looking for products for hair treatment before using curling irons to make hair smooth and combed well. In general, when hair is damaged from heat, smoothness and luster are lost, and the surface of the hair is rough, so that combing is poor. Therefore, human hair recognizes it as healthy hair when it is smooth and combed well.

Hair styling agents that facilitate hair preparation and styling include aerosol hairdressing agents by the method of being discharged with aerosol fillers (see Bilek, Doris., “Aerosol Foam and Mousse Preparation in Europe”, Cosmetics & Toiletries, Vol. 99 (September 1984), 57-60, 62-67) and oil-based hair dressing agents such as emulsion type hair creams, hair lotions, pomades (US Pat. Nos. 6,244,770, 4,938,954, 5,993,832), etc. There is this. The styling effects and glossiness of these formulations vary depending on the formulation.

In the prior art, hair products such as an aerosol-type hairspray, a pump-type hairspray, or a hair mousse, which have good hair holding power and a hairstyle holding power, are applied to the hair and then curled using a heated curling iron to maintain curling power. It is excellent, but the hair is hard and smooth, and there is a problem that it cannot be combed. If a hair product such as hair gel or hair wax is applied to the hair and curled using heated curling iron, the hair has a smoothness but the curl holding power I have a problem with this falling. In particular, viscous products such as hair gels do not provide a consistent quality for long straight hair because they are very poor in application and do not coat evenly on the surface of the hair.

In the prior art, high molecular weight polyethylene glycol and polyvinylpyrrolidone (PVP) have been used as hair fixatives in the composition of hair gels or hair waxes to improve curl retention and spreadability in hair. There was a limit to lasting hair retention because of its characteristics. (Japanese Patent No. 2515149, Japanese Patent Application No. 63-504461, Korean Patent Application No. 10-2001-0033749, Publication No. 2002-0095593, European Patent Application No. 01125978, Publication No. 1308150)

Conventional hair lotion or pump type treatment products have excellent hair smoothing and combing effects but have little ability to make or maintain hair curls.

The present invention is to solve the above problems, an object of the present invention is a methacryloyl ethyl beta having a mass average molecular weight of 10,000 ~ 75,000, viscosity (20 ℃) 20,000 ~ 55,000cps and Tm: 110 ~ 290 ℃ Phosphate methacrylate copolymer (Formula 1), mass average molecular weight: 100,000-8,000,000, Tm: 57-77 ° C and viscosity (25 ° C, 1% Aqueous Solution): Poly (ethylene oxide) having physical properties of 600-5500 cps After spraying the hair roll maker composition containing Provitamin B (Formula 3) having a mass average molecular weight of 100 to 2,000 and a density (20 ° C.) of 1.0 to 1.8 g / mL in an optimal ratio, to the hair By forming curl using heated iron, curl is kept longer than conventional technology, and hair protection function from iron heat and hair smoothness are very high quality. Pump type hair roll maker composition having a It is in the air.

The present invention is 0.1 to 5.0% by weight of methacryloyl acetylbetaine methacrylate copolymer as in Formula 1, 0.000005 to 0.0001% by weight of Poly (ethylene oxide) as in Formula 2, 0.1 to 5.0 Provitamin B as in Formula 3. A pump-type hair roll maker composition containing a mixture by weight in an optimum content ratio.

Hereinafter, the present invention will be described in more detail.

The present invention optimizes methacryloylethylbetaine methacrylate copolymer, Poly (ethylene oxide) and Provitamin B as a component in a pump-type hair roll maker composition that sprays fine particles. By mixing in the content ratio of to form a very low viscosity solution phase and has a uniform spray pattern (Spray Pattern). When the composition of the present invention is sprayed on the hair, fine particles are evenly coated on the hair, and the hair curling function is made by using a heated iron, having excellent hair protection and smoothness from iron heat. It is characterized by long life.

The methacryloyl ethylbetaine methacrylate copolymer used in the present invention is represented by the formula (1), and has a mass average molecular weight of 10,000 to 75,000, a viscosity (20 ° C) of 20,000 to 55,000 cps, and a Tm of 110 to 290 ° C. Poly (ethylene oxide) has physical properties of mass average molecular weight: 100,000 ~ 8,000,000, Tm: 57 ~ 77 ℃ and viscosity (25 ℃, 1% Aqueous Solution): 600 ~ 5500 cps. In addition, Provitamin B has physical properties of a mass average molecular weight of 100 to 2,000 and a density (20 ° C.) of 1.0 to 1.8 g / mL.

When the methacryloyl ethyl beta methacrylate copolymer is used alone, it is very effective in improving hair curl retention, but has a problem that the hair is hard and not combed.

In addition, when Poly (ethylene oxide) or Provitamin B is used alone, it is very effective for the smoothness and combing of the hair, but it does not improve hair curl retention and increases the amount of hair curling. If it is high, the viscosity of the content rises rapidly, causing a problem of clogging the pump.

Excessive use of the methacryloyl acetyl beta methacrylate copolymer of the composition of the present invention has a problem that the hair curling (Curl) retention ability is good but sticky, but not combing, Poly (ethylene oxide) or Excessive use of Provitamin B improves smoothness and combing, but it is difficult to maintain hair curls.

In the present invention, by mixing the methacryloyl ethyl methacrylate copolymer, Poly (ethylene oxide) and Provitamin B in an optimum content ratio, the hair protection from iron heat and smoothness is very excellent, Hair curls made using heated irons provide the long lasting feature.

As described above, when curling hair is made of heated iron, the hair is severely damaged by heat, and curling of hair is loosened in a short time.

After spraying the pump-type hair roll maker composition of the present invention to the hair, curl produced using iron is a hair protection function from heat than the composition according to the prior art, Not only is it smooth and combed, it also offers excellent curl retention.

Moisturizers, styling polymers, solvents such as ethanol, hair protecting agents such as hydrolyzed proteins and animal and vegetable extracts, and metal ion sequestering agents such as ethylene glycol tetrasodium acetate, which are generally used in hair styling products, in addition to the essential components in the composition of the present invention PH adjusting agents such as citric acid, preservatives such as para-benzoic acid esters, colorants, and flavors may be used within the range not impairing the characteristics of the formulation.

  [Chemical Name] Methacryloyl Echibetaine Methacrylate Copolymer

            Methacryloyl Ethyl Betaine / Metacrylate Copolymer

 [Chemical name] Poly (ethylene oxide)

(-CH ₂ CH ₂ O-) _n

  [Chemical Name] Provitamin B

(Panthenol or ( R ) -2,4-Dihydroxy-3,3-dimethylbutyric 3-hydroxypropylamide)

C ₉ H ₁₉ NO ₄

Hereinafter, the present invention will be described in more detail with reference to Comparative Examples and Examples, but the present invention is not limited thereto.

Comparative Examples 1-7 and Examples 1-8

The hair roll maker composition of Table 1 and Table 2 was prepared by the following method.

After mixing the purified water and the raw materials 2, 3 in the beaker and completely dissolved by stirring, the ethanol and the raw materials 4,5,6,7,8,9 (10,11) are mixed with another beaker and stirred sufficiently. The composition of the present invention was obtained by stirring the contents of the two beakers to mix thoroughly after mixing.

The evaluation method used in each Example and Comparative Example was evaluated by the mechanical method and the sensory method, each evaluator was evaluated by the evaluation criteria for each evaluation item.

Experimental Example 1: Mechanical evaluation of the setting force (hair curl holding force)

Hair Roll Maker (Roll Maker) Wind the hair evenly coated on the spiral and dry. The curled hair was placed in a thermo-hygrostat (25 ° C, 40% RH) and the setting effect was calculated using the Curl Retention (%) equation at 30 minute intervals for 12 hours. In this evaluation, the higher the curl percent retention (%), the better the hair curl retention.

Lo = Hair Tress Length

Lt = Hair Tress length after t hours

Ls = length of first curled hair tress (t = 0)

Albert L. Micchelli, B.A., and F. Theodore Koehler, B.S. Polymer Properties Influencing Curl Retention at High Humidity J. Soc.Cosmetic Chemists. 19,863-880 (Dec 9,1968).

Experimental Example 2: Sensual evaluation of the feeling of combing

The evaluator sprays the hair-type hair roll maker pump 10 times onto the hair 10 times, and then curls using a heated iron to naturally dry for 30 minutes. . The hair curls were combed three times and the degree of combing was recorded on a five-point scale. Each evaluator score was added and then divided by the number of evaluators (n = 100) to obtain an average value.

(Test conditions: constant temperature and humidity room / 25 ℃, 40% RH)

1 point | piece: A feeling of combing is very bad (it cannot comb).

2 points | pieces: A feeling of combing is slightly bad (combing is stiff).

3 points | pieces: The combing is normal.

4 points | pieces: A feeling of combing is slightly good (combing is smooth).

5 points | pieces: Very good combing (combing is very smooth).

Experimental Example 3: Sensational Evaluation of Smoothness

The evaluator sprays the hair-type hair roll maker pump 10 times onto the hair 10 times, and then curls using a heated iron to naturally dry for 30 minutes. . The degree of smoothness was recorded on a five-point scale while touching the made hair curl with a finger. Each evaluator score was added and then divided by the number of evaluators (n = 100) to obtain an average value.

(Test conditions: constant temperature and humidity room / 25 ℃, 40% RH)

1 point | piece: The smoothness is very bad (hair is very fluffy).

2 points | pieces: Smoothness is a little bad (hair is not glossy and fluffy)

3 points | pieces: smoothness is normal.

4 points | pieces: Slightly smooth (the hair is shiny and soft)

5 points | pieces: Very smooth (hair is shiny and very soft.)

                                                            (Unit: weight%) No Ingredient Name Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 One Purified water to100 to100 to100 to100 to100 to100 to100 2 Moisturizer 5.0 5.0 5.0 5.0 5.0 5.0 5.0 3 Provitamin B - - - - 1.0 1.0 0.5 4 Ethanol (95%) 15 15 15 15 15 15 15 5 Emulsifier 1.0 1.0 1.0 1.0 1.0 1.0 1.0 6 Setting first 1.0 - 1.0 - 1.0 - - 7 Setting second - 1.0 - 1.0 - 1.0 - 8 Setting third - - - - - - 1.0 9 Setting fourth - - 0.02 0.02 0.02 0.02 0.02 10 Spices 0.2 0.2 0.2 0.2 0.2 0.2 0.2 11 antiseptic 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Setting force (%) 30 40 35 45 37 50 60 Combing (5-point scale) 3.5 3.3 3.9 3.5 4.2 3.8 4.5 Softness (five points scale) 3.5 3.1 3.7 3.3 3.9 3.6 3.9

※ In Table 1, 1. Moisturizing agent: Propylene Glycol 2. Provitamin B (Formula 3) 3. Emulsifier: Glyceryl Stearate (and) PEG-100 Stearate 4. Setting agent 1: PVP 5. Setting agent 2: PVP / VA Copolymer 6. Setting 3: Methacryloyl Ethyl Betaine / Metacrylate Copolymer (Formula 1) 7. Setting 4: Poly (ethylene oxide) (0.2% in Water, Formula 2) 8.Preservative: Paraoxybenzoic acid ester

                                                           (Unit: weight%) No Ingredient Name Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 One Purified water to100 to100 to100 to100 to100 to100 to100 to100 2 Moisturizer 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 3 Provitamin B 1.0 1.0 1.0 1.0 1.0 4.0 2.0 1.0 4 Ethanol (95%) 15 15 15 15 15 15 15 15 5 Emulsifier 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 6 Setting first 1.0 1.0 1.0 2 0.5 1.0 1.0 1.0 7 Setting second 0.04 0.03 0.01 0.02 0.02 0.02 0.02 0.02 8 Spices 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 9 antiseptic 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Setting force (%) 68 64 59 80 45 68 65 60 Combing (5-point scale) 4.1 4.3 4.1 3.8 4.8 4.1 4.3 4.5 Softness (five points scale) 4.7 4.4 3.9 3.1 4.5 4.6 4.5 4.2

※ Table 2 above 1. Moisturizing agent: Propylene Glycol 2. Provitamin B (Formula 3) 3. Emulsifier: Glyceryl Stearate (and) PEG-100 Stearate 4. Setting 1: Methacryloyl Ethyl Betaine / Metacrylate Copolymer (Methacryloyl to Cylbetaine methacrylate copolymer) (Formula 1) 5. Setting agent 2: Poly (ethylene oxide) (0.2% in Water, Formula 2) 6.Preservative: Paraoxybenzoic acid ester

As shown in Table 2, the hair roll maker composition of the Example containing Provitamin B, Setting 1 (Methacryloyl Ethyl Betaine / Metacrylate Copolymer) and Setting 2 (Poly (ethylene oxide)) was set in the hair. (Hair curl holding power), combing and smoothness were excellent, and in Example 8, setting power, combing, and smoothness were suitably harmonized.

Wave- or curl-type hairs made using heated iron are not maintained for a long time, and the hair is damaged due to the heat of the curling iron, thereby eliminating the smoothness and smoothness.

The present invention is a methacryloyl acetylbetaine methacrylate copolymer (formula 1) having a mass average molecular weight of 10,000 ~ 75,000, viscosity (20 ℃) 20,000 ~ 55,000cps and Tm: 110 ~ 290 ℃ physical properties, mass average Molecular weight: 100,000 to 8,000,000, Tm: 57 to 77 ° C and viscosity (25 ° C, 1% Aqueous Solution): Poly (ethylene oxide) having physical properties of 600 to 5500 cps (Formula 2), mass average molecular weight 100 to 2,000, density It relates to a pump-type hair roll maker composition containing Provitamin B (formula 3) having a physical property of 1.0 to 1.8 g / mL (20 ° C) as appropriate. After spraying the hair roll maker of the present invention to the hair to make a hair wave or curl using a heated iron, the hair style is not only maintained for a long time, but also protects the hair from the heat of the curling iron, Helps to smooth and comb your hair.

Claims (3)

As an essential ingredient, 0.1 to 5.0% by weight of methacryloylethylbetaine methacrylate copolymer of Formula 1, 0.000005 to 0.0001% by weight of Poly (ethylene oxide) of Formula 2 and 0.1 to 5.0% by weight of Provitamin B of Formula 3 A hair roll maker composition of a pump type for hair treatment, which is used before making a hair curl form by using a heated iron. According to claim 1, 0.5 to 3.0% by weight of the methacryloyl ethyl beta methacrylate copolymer of Formula 1, 0.00001 to 0.0001% by weight of Poly (ethylene oxide) of Formula 2 and 0.5 to 5.0 Provitamin B of Formula 3 A pump-type hair roll maker composition comprising a weight percent as an essential ingredient. The pump-type hair roll maker according to claim 1 or 2, further comprising at least one of a humectant, a styling polymer, a fragrance, and a solvent used in the hair styling product. Composition.