KR101314965B1 - Powder Type Hair Cosmetic Composition - Google Patents

Abstract

The present invention relates to a hair styling composition of powder form, which is a powder but changes to a liquid setting agent when rubbed by hand, and includes a powder type including purified water, silica sillate, vinylpyrrolidone / vinylacetate copolymer, and polyol. Regarding the hair setting cosmetics and a method of manufacturing the same, it is possible to produce a variety of hairstyles easily at the same time without giving a proper setting force to the hair at the fingertips.

Description

Powder Type Hair Cosmetic Composition

The present invention relates to a hair styling composition of powder form, which is a powder, but when changed by hand, it is changed into a liquid cream-type setting agent, and includes purified water, silica silylate, vinylpyrrolidone / vinylacetate copolymer, polyol, and the like. The present invention relates to a powder-type hair setting cosmetic and a method of manufacturing the same, and to a hair-type hair cosmetic composition which provides an effect of providing a proper setting force to the hair and at the same time easily producing various hairstyles without stickiness at the fingertips.

In general, hair plays an important role in decorating men as well as women in terms of decoration, and even the same person can give another impression depending on the hairstyle. Therefore, humans want to produce a variety of hairstyles, and are using the right products.

Hair styling agents that facilitate the preparation and styling of such hair include aerosol hairdressing agents such as hair foams, hair mousses and hair sprays (see Bilek, Doris., “Aerosol Foam and Mousse Preparation in Europe”, Cosmetics & Toiletries, Vol. , 99 (September 1984), 57-60, 62-67), oil-based hair dressing agents, such as emulsion type hair creams, hair lotions, pomades (US Pat. Nos. 6,244,770, 4,938,954, 5,993,832) And solubilization type hair gels and waxes. These products are different types of product families that can be selected by the consumer for their intended use.

Among them, transparent or translucent gel waxes can satisfy consumer psychology for a clean feeling as a hair dressing agent. However, such a hair gel wax contains a setting polymer and the like, leaving a slightly sticky texture on the hair and hands, and the setting polymer for the shape of the hair dries quickly and more often feels dry rather than moisturized.

In addition, the cream-type hair styling wax mainly used to make the latest hair styles, give the hair a proper shine and give natural setting power, it is possible to rearrange the hair by tidying up the hair. In particular, the emulsified hair styling wax is emulsified with a water-based component and an oil-based component using a surfactant, and the use of a water-soluble polymer compound, which is a hair fixative component, as an oil component, which is a component for gloss, and a setting agent, for a styling effect. It is essential. However, such an emulsified hair styling wax contains a lot of oily ingredients such as mineral oil, vegetable oil, silicone oil, etc., the setting effect is poor, and the hair looks dirty and has a fresh look and has a limit of oiliness. In addition, when an excessive amount of the water-soluble polymer compound is used to increase the styling effect, the stickiness in the hair is very high, and the restyling drops, giving a dull feeling, such that the user is reluctant to use it.

Therefore, the technical problem to be achieved by the present invention is to provide a new type of hair styling composition and a manufacturing method, unlike conventional hair-styling agents. It is a powder, but when rubbed by hand, it turns into a liquid setting agent to provide a hair cosmetic composition that can give a proper setting power to the hair and at the same time easily produce a variety of hairstyles without stickiness at the fingertips.

Other objects and advantages of the present invention will become apparent from the following detailed description and claims.

The present invention relates to a new type of hair styling composition comprising from 0.1 to 30.0% by weight of silica sillate, from 0.1 to 20.0% by weight of a setting agent, from 0.1 to 30.0% by weight of a polyol in a 100.0% by weight composition comprising purified water. It is composed of a hair cosmetic composition that turns into a liquid setting agent when rubbed with.

Preferably, the hair cosmetic composition, when rubbed by hand with a formulation of a form not previously available, can be used without sticky at the fingertips or palms, characterized in that the setting effect in the hair is excellent.

      In the case of the silica silicate, it is preferable to include 0.1 to 30.0 wt% in the total weight of the composition, more preferably 3.0 to 10.0 wt%. If the content is less than 0.1% by weight, the ability to contain water decreases as the water content increases, and the formulation stability is lowered. If the content exceeds 30.0%, the silica sillate alone exceeds the ability to support water. This causes the problem of blowing the formulation.

The setting agent is preferably included in 0.1 to 20.0% by weight of the total weight of the composition, more preferably comprises 0.1 to 5.0% by weight. If the content is less than 0.1% by weight, the setting power is insufficient to function as a hair styling agent. If the content exceeds 20.0% by weight, the hair may become entangled and cause an unpleasant feeling due to excessive setting power. It may remain on the hair and may not be removed. The powdery wax composition of the present invention may exhibit various functions aimed at by the present invention as a hair dressing agent by including silica sillate, a setting agent and a polyol in an optimal content ratio as described above.

The polyol is preferably used in an amount of 0.1 to 30% by weight based on the total weight of the above-described content range, and more preferably in 3.0 to 20.0% by weight to improve hair moisturizing. If the content is less than 0.1% by weight, the moisture retention is lowered, if it exceeds 30% by weight it is difficult to maintain the shape of the hair by excessive moisturizing.

As described above, according to the present invention, unlike conventional hair styling agents, a new type of hair styling composition is powder, but when it is rubbed by hand, it turns into a liquid setting agent and is easy to carry. It is to provide a hair cosmetic composition that can produce a variety of hairstyles easily without sticky at the same time giving the appropriate setting power.

The present invention relates to a new type of hair styling composition comprising 0.1 to 30.0 wt% of silica silyllate, 0.1 to 20.0 wt% of vinylpyrrolidone / vinylacetate copolymer, and 0.1 to polyol of 100.0 wt% of the composition including purified water. The phase comprising 30.0% by weight and the like provides a hair cosmetic composition which is a powder but which, when rubbed by hand, turns into a liquid setting agent.

Setting agents used in the present invention include polyvinylpyrrolidone, vinylpyrrolidone / vinylacetate copolymer, polyvinylpyrrolidone / vinylacetate copolymer, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer , Polyvinyl alcohol, polyethylene glycol, polyquaternium, methacryloylethylbetaine / methacrylate copolymer, acrylate / octylacrylamide copolymer, acrylate / t-butylacrylamide copolymer and octylacrylamide / And emulsified waxes such as acrylate / butylaminoethyl methacrylate, beeswax, carnauba wax, and the like, and these may be used alone or in combination of two or more thereof.

Polyvinylpyrrolidone, vinylpyrrolidone / vinylacetate copolymers and polyvinylpyrrolidone / vinylacetate copolymers are representative nonionic polymers that give strong setting in hair styling products, and vinylpyrrolidone / methacrylamide The / vinylimidazole copolymer exhibits high setting and sustaining power due to the rigid structure of vinylpyrrolidone and vinylimidazole, and soft applicability due to the flexible structure of methacrylamide. Polyvinyl alcohol and polyethylene glycol are water soluble polymers, methacryloylethylbetaine / acrylate copolymers are zwitterionic polymers that give excellent setting and sustainability in hair styling products, acrylate / octyl acrylamide copolymers, Acrylate / t-butylacrylamide copolymer and octylacrylamide / acrylate / butylaminoethylmethacrylate are representative anionic setting agents that give strong hair setting properties and have fast drying properties. These setting agents are used to adjust the strength of the feel and style, and can be included from 0.1 to 20.0% by weight relative to the total weight of the composition. If the content is less than 0.1% by weight, effective setting and sustaining power are not expressed. If the content is more than 20.0% by weight, it may be thickly applied to the hair to cause hair agglomeration and flaking.

In the case of the polyol used in the present invention, polyglycerols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerine, triglycerine, tetraglycerine and glucose, maltose, maltitol, sucrose, fructose Lactose, sorbitol, sugars derived from starch digests, and mixtures thereof.

In addition, water is used as a solvent of the hair composition according to the present invention, and a water protection agent such as hydrolyzed protein and animal or plant extract may be used in the aqueous phase, and a pH adjuster such as citric acid, a moisturizer, and a preservative in addition to the above components are selected. It may further comprise one or more other additives. The above components can be easily selected and used by those skilled in the art as materials included in conventional hair styling agents.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood that the scope of the present invention is not limited by these examples in accordance with the gist of the present invention, and it is to be understood by those skilled in the art that the present invention is not limited thereto It will be obvious.

Manufacturing example  One Solubilization  Type of clear gel wax

To prepare a hair gel composition having a component and content as shown in Table 1 below.

Raw ingredient Production Example 1 One Purified water To 100 2 Acrylate / C10-30 alkyl acrylate crosspolymer 1.00 3 Triethanolamine 1.20 4 Ethanol (95%) 10.00 5 glycerin 8.00 6 Dipropylene glycol 5.00 7 Fiji-12 Dimethicone 0.30 8 Tetrasodium IDT 0.10 9 Methylchloroisothiazolinone / methylisothiazolinone 0.05 10 Vinylpyrrolidone / Vinyl Acetate Copolymer 2.00

Manufacturing method

1) Add the raw materials 2 and 3 to a certain amount of purified water at room temperature, and dissolve and increase it.

2) The raw material 4 was added thereto, the raw materials 5 to 10 were completely dissolved, and then charged and stirred to prepare a final gel type wax composition.

Manufacturing example  2 Preparation of cream wax of emulsified type

To the hair wax composition of the emulsion type having the components and contents as shown in Table 2 was prepared by the following method.

Raw ingredient Production Example 1 One Purified water To 100 2 glycerin 5.0 3 Vinylpyrrolidone / Vinyl Acetate Copolymer 2.0 4 Cetearyl Alcohol / Detyl Phosphate / Cetece-10 Phosphate 3.0 5 Isopropyl myristate 6.0 6 Cyclopentasiloxane 4.0 7 Beads wax 0.5 8 Acrylate / C10-30 alkyl acrylate crosspolymer 1.0 9 Triethanolamine 1.2 10 Methylchloroisothiazolinone / methylisothiazolinone 0.03 11 Spices Suitable amount

Manufacturing method

1) The raw materials 2 and 3 were added to the purified water, dissolved to form an aqueous phase, and heated to 85 ° C., and then emulsified by adding an oil phase (raw materials 4 to 7) heated to 85 ° C. to an aqueous phase, and then cooled to 55 ° C. Raw materials 8-11 were added sequentially, and evenly mixed and cooled, and the composition was obtained.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

(Comparative Example 1)

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

(Comparative Example 2)

A powder type hair composition was prepared with the composition shown in Table 3 by a mixing method using a Henschel mixer.

Formulation is achieved by injecting silica silicate, creating a flow with a Henschel mixer, and spraying moisturizing ingredients and moisture with Top Spray.

Manufacture of powder type wax Raw material composition
Example Comparative Example One 2 3 4 5 6 One 2 Silica silicate 3.0 7.0 10.0 7.0 10.0 7.0 3.0 7.0 glycerin 8.0 8.0 8.0 8.0 8.0 8.0 8.0 8.0 Butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Vinylpyrrolidone / Vinyl Acetate Copolymer 2.0 2.0 2.0 2.0 2.0 5.0 26.0 30.0 Citric acid Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Sodium benzoate Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100

Example 1-3 and Comparative Examples 1 and 2
1) Inject silica silicate into Henschel mixer, mixing speed 800rpm, 5 minutes

2) Dissolve up to 2 ~ 7 in the water phase, mix, spray spray with binder, mix speed 1000rpm

Example 4-6 Manufacturing Method

1) Inject silica silicate into Henschel mixer, mixing speed 800rpm, 5 minutes

2) Dissolve 2,3, 5 ~ 7 in the water phase, mix, spray spray with binder, and mix speed 1000rpm

3) 4 is added to the Henschel mixer, mixing speed 800rpm, 3 minutes

Experimental Example 1 Sensory Evaluation of Stickiness

The evaluators recorded 3 g of hair wax on the hand and applied the hair to the sticky strength on the hand on a five-point scale. Each evaluator's score was added and then divided by the number of evaluators (n = 100) to obtain an average value. The test was conducted in a constant temperature and humidity room (25 degreeC, 40% RH). Evaluation criteria are as follows, and the results are shown in Table 4.

Production Example 1 Production Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 2 Stickiness 3 3 4 4 4 5 4 3 2

(Evaluation standard)

1 point | piece: Stickiness is very high. 2 points | pieces: High stickiness. 3 points | pieces: Stickiness is normal. 4 points | pieces: Low stickiness. 5 points | pieces: The stickiness is very low.

Referring to Table 4, in the case of powder type waxes (Examples 1 to 6) in comparison with general gel type (preparation example 1) and emulsion type cream wax (preparation example 2), stickiness is very high when used. It can be seen that less. In Comparative Example 1, the formulation was not made as the setting agent content was increased, and in Comparative Example 2, the stickiness became severe.

Experimental Example 2 Mechanical Evaluation of Setting Force

The hair with the hair wax contents evenly coated was dried on the spiral. The curled hair was placed in a thermo-hygrostat (25 ° C, 60% RH) and the setting effect was measured using the Curl Retention (%) equation over time, and the results are shown in Table 5.

L ₀ = Hair Tress Length

L _t = Length of hair Tress after t hours

L _s = Length of first curled hair tress (t = 0)

(See Albert L. Micchelli, B.A., and F. Theodore Koehler, B.S. "Polymer Properties Influencing Curl Retention at High Humidity" J. Soc. Cosmetic Chemists. 19, 863-880 (Dec 9,1968).)

Production Example 1 Production Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 2 Setting power 75 81 82 83 85 83 85 91 84

Referring to Table 5, compared to the general gel type (Preparation Example 1) and the emulsion type cream wax (Preparation Example 2), powder type wax in Example 1 to Example 6, when used, the setting force is very excellent Able to know. In the case of Comparative Example 2, the setting force is relatively good, but there is a disadvantage in that the usability is inferior due to a lot of flaking.

Experimental Example 3 Evaluation of Stability of Formulations

Constant temperature of 4 ° C., 40 ° C., 45 ° C. as a powdered state immediately after preparation and one month after using the manufacturing method of Examples 1 to 3 and the manufacturing methods of Examples 4 to 6 prepared according to the composition of Table 3 above. The state and the stability of the formulation after storage in cycling conditions changing the temperature twice a day to -4 ℃ ~ 40 ℃ is observed in Table 6 shown. In addition, the stability to the external impact of each content was measured. As a measuring method, 5 g of each content was placed in a plastic container, and when dropped five times at a height of 70 cm, the contents were broken or agglomerated by the external impact and measured in the table.

Condition Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 1 Comparative Example 2 Room temperature Immediately after manufacture △ ○ ○ ○ ○ ○ × △ 1 month △ ○ ○ ○ ○ ○ × × 4 ℃ Immediately after manufacture △ ○ ○ ○ ○ ○ × △ 1 month △ ○ ○ ○ ○ ○ × × 40 ℃ Immediately after manufacture △ ○ ○ ○ ○ ○ × △ 1 month △ ○ ○ ○ ○ ○ × × 45 ° C Immediately after manufacture △ ○ ○ ○ ○ ○ × △ 1 month △ ○ ○ ○ ○ ○ × × Cycling (-4 ℃ ~ 40 ℃; twice / day) Immediately after manufacture △ ○ ○ ○ ○ ○ × △ 1 month △ ○ ○ ○ ○ ○ × ×  ○: good, △: normal, ×: agglomeration, separation

Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 2 Rating △ ◎ ◎ ◎ ◎ ◎ X

 <Criteria>

 ◎: 5 times stable

 ○: 4 times stable

 △: 3 times stable

 ◇: 2 times stable

Ｘ: 1 bunch

Referring to Tables 6 and 7, the content of silica silicate is low (Example 1), the formulation stability and impact stability tends to be lowered, and the powdery preparations made by the production methods of Examples 1 to 3 and Comparative Example 2 It can be seen that the formulation stability drops as the silver setting agent content increases. On the other hand, when prepared in Examples 4 to 6, even if the amount of the setting agent increases, it can be confirmed that the formulation stability and impact stability are not significantly affected.

Experimental Example 4 Evaluation of Usability of the Formulation

The evaluator allowed the applicator to apply 3 g of the wax composition of the powdery form prepared in the gel type wax preparation example 1, the emulsion type wax preparation example 2 and the examples 1 to 6 to the hair and apply them to the hair. Was evaluated on a five-point scale according to the following evaluation criteria. After adding each evaluator score, the average value is divided by the number of evaluators (n = 100) and is shown in Table 8 below.

Production Example 1 Production Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Rating 3 3 3 5 4 5 4 4

Looking at Table 8, the wax in the form of powder showed a higher satisfaction in terms of ease of use compared to the gel-type or emulsion-type hair styling cream wax that is conventionally sold in the market.

As described above in detail a specific part of the present invention, it is apparent to those skilled in the art that the specific technology is only a preferred embodiment, and the scope of the present invention is not limited thereto. Therefore, the substantial scope of the present invention will be defined by the appended claims and equivalents thereof.

Claims (6)

A hair cosmetic composition in powder form, containing 0.1 to 30.0% by weight of silica sillate, 0.1 to 20.0% by weight of setting agent, and 0.1 to 30.0% by weight of polyol, based on 100.0% by weight of the total composition including purified water;
The setting agent is polyvinylpyrrolidone, vinylpyrrolidone / vinylacetate copolymer, polyvinylpyrrolidone / vinylacetate copolymer, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer, polyvinyl alcohol , Polyethylene glycol, methacryloylethylbetaine / acrylate copolymer, acrylate / octylacrylamide copolymer, acrylate / t-butylacrylamide copolymer, octylacrylamide / acrylate / butylaminoethyl methacrylate At least one selected from the group consisting of beeswax emulsion, and carnauba wax emulsion;
The polyols are derived from ethylene glycol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerin, diglycerin, triglycerine, tetraglycerine, glucose, maltose, maltitol, sucrose, fructose, sorbitol, starch degradate A powder cosmetic hair cosmetic composition, characterized in that one or two or more selected from the group consisting of sugars.
The hair cosmetic composition according to claim 1, wherein the hair cosmetic composition of the powder property becomes liquid when rubbed by hand to make a hairstyle from the hair.
delete delete The manufacturing method for making the hair cosmetic composition of the powder property according to claim 1, wherein the setting agent is dissolved in an aqueous phase so that silica silylate is sprayed in the form of a binder in a fluidized state in a fluidized state in a top-spray manner.
In the method for preparing a powder cosmetic composition according to claim 5, when the setting agent is in powder form, the moisturizing component and purified water are sprayed in a top-spray method to obtain a product, and then the setting agent is mixed in a post-injection form. The manufacturing method to make.