KR20070039146A - Selective insecticides based on haloalkylnicotinic acid derivatives, anthranilic acid derivatives, or phthalic acid derivatives and safeners - Google Patents

Abstract

Compositions contain (A) haloalkyl-nicotinic acid derivative(s) (I), phthalic acid diamide derivative(s) (II) or anthranilamide derivative(s) (III) and (B) safener(s) selected from about 60 specific compounds (e.g. cloquintocet-mexyl, isoxadifen-ethyl, fenclorim or mefenpyr-diethyl) and 4 general classes of azole, quinoline, alkanamide or N-(phenylsulfonyl)-benzamide compounds (IVa)-(IVd). Compositions comprise: (1) at least one haloalkyl-nicotinic acid derivative of formula (I), phthalic acid diamide derivative of formula (II) or anthranilamide derivative of formula (III) (optionally in N-oxide or salt form) as active agent (A); and (2) at least one safener (B) selected from e.g. azole derivatives of formula (IV-a), quinoline derivatives of formula (IV-b), alkanamides of formula R 10d>-CO-NR 11d>R 12d> (IV-c) and N-(phenylsulfonyl)-benzamide compounds of formula (IV-d). A a>C(W a>)-NR 2a>R 3a>, C(W a>)-N=SR 9a>R 10a> or Het; R 1a>haloalkyl; R 2a>, R 3a>e.g. U-cycloalkyl (optionally substituted (os) by R 4a> or Q a>), C(X a>)-Y a>; or CH 2-heterocyclyl (os by R 5a>); or NR 2a>R 3a>e.g. heteroaryl os by R 4a>, U' or Q a>; Q a>hydrazono (os); R 4a>e.g. S(O) n-U'; X a>, W a>O or S; Y a>e.g. R 6a> or NR 7a>R 8a>; R 6a>e.g. -U-cycloalkyl (os); R 7a>e.g. U-cycloalkyl (os); R 8a>e.g. aryl (os by R 5a>); R 9a>, R 10a>e.g. C(X a>)-Y a>; or R 9a>R 10a>heterocycle; Het : e.g. heterocycle os by R 4a>, U' or Q a>; X b>e.g. haloalkoxy; R 1b>-R 3b>e.g. M 1b>-Q b>; or R 1b>+R 2b>e.g. complete ring; M 1b>e.g. os alkylene; Q b>e.g. T b>-R 4b>; T b>e.g. S(O) m or N(R 5b>); R 4b>e.g. T-heteroaryl (os); R 5b>e.g. CO-O-T-Ph (os); k : 1-4; m : 0-2; L 1b>, L 3b>e.g. S(O) m-U; L 2b>e.g. M 2b>-R 6b>; or L 1b>+L 3b>e.g. complete ring; M 2b>e.g. S(O) m; R 6b>e.g. heteroaryl (os); A 1c>, A 2c>e.g. S; X c>e.g. CR 10c>; R 1c>e.g. V (os by R 6c> or R 11c>); R 2c>e.g. H; R 3c>e.g. R 11c> or heteroaryl (os by 1-3 W c> or R 12c>)); or R 2c>+R 3c>complete ring M c>; R 4c>e.g. OT' (os); R 5c>, R 8c>e.g. G c>, J c> or S(O) p-Ph (all os by e.g. V (os by e.g. Ph (os by W or R 12c>))); G c>e.g. carbocycle; J c>e.g. heteroaryl (os); R 6c>e.g. C(E c>)-R 19c>, OP(Q c>)(OR 19c>) 2, SO 2L c>R 18c> or L c>SO 2L c>R 19c>; E 1c>e.g. NR 19c>; R 7c>e.g. SO 2T'; R 9c>e.g. halo; R 10c>e.g. T'; R 11>e.g. phenylsulfenyl (os by W c>, S(O) n(R 16c>) 2 or S(O) nNR 13c>SO 2L c>R 14c>); L c>e.g. NR 18c>; R 12c>e.g. B(OR 17c>) 2; Q c>O or S; R 13c>e.g. V (os); R 14c>e.g. Cyc (os by e.g. R 6>); R 15c>U' (os by e.g. SOT' or Ph (os by 1-3 W c> or R 12c>); R 16c>e.g. haloalkyl; or N(R 15c>) 2 or N(R 16c>) 2M c>; R 17c>e.g. T; R 18c>e.g. U'; or NR 13c>R 18c>M c>; R 19c>e.g. U (os) M c>e.g. ring W c>e.g. T; n : 0 or 1; p : 0-2; A 12>group of formula (a)-(c); r, s : 0-5; A 11d>e.g. N; A 2d>e.g. alkanediyl (os); R 8d>e.g. NT 2; R 9d>e.g. NT 2; R 10d>T (os); R 11d>, R 12d>e.g. V (os); or R 11d>+R 12d>e.g. alkanediyl; R 13d>, R 15d>e.g. halo; R 14d>e.g. U (os); X 1d>e.g. T'; X 2d>, X 3d>e.g. H; Q : N(R 17d>)-COR 18d> or CO-NR 19d>R 20d>; t : 0-5; v : 0-4; R 16d>, R 17d>e.g. T; R 18d>e.g. NT 2 (os); R 19d>e.g. U (os); R 20d>e.g. phenyl (os by e.g.T' or OT'); or R 19d>+R 20d>e.g. 3-6C alkanediyl ( os); X 4d>, X 5d>e.g. T'; T : 1-4C alkyl, U : 1-6C alkyl; T' : T or 1-4C haloalkyl; U' : U or 1-6C haloalkyl; V : 2-6C alkenyl or 2-6C alkynyl; Cyc : 3-6C cycloalkyl; and with provisos. Full Definitions are given in Definitions (Full Definitions) Field. An independent claim is included for controlling insects and/or acarina, involving applying the composition to insects and/or acarina and/or their habitat. [Image] [Image] [Image] [Image] ACTIVITY : Insecticide; acaricide; safener; nematocide. In pre-tests for control of Aphis gosspii aphids on cotton plants, mortality after 2 days was 0% using 120 g/ha N-cyanomethyl-4-trifluoromethyl-nicotinamide (flonicamid) (A'), 0% using 50 g/ha isoxadifen-ethyl (B') and 50% using a combination of 120 g/ha (A') and 50 g/ha (B'). MECHANISM OF ACTION : None given.

Description

Selective insecticides based on haloalkylnicotinic acid derivatives, anthranilic acid derivatives, or phthalic acid derivatives and safeners}

The present invention firstly provides a pesticidal and / or acaricide effective combination comprising a haloalkylnicotinic acid derivative, phthalic acid diamide or anthranilic acid diamide and then at least one crop plant compatibility improving compound, and various useful crops. And to the use of said combination for the selective control of insects and / or leaf mites.

It is known that certain haloalkylnicotinic acid derivatives are pesticidal (EP-A 0 580 374, JP-A 7-010841, JP-A 7-025853, JP-A 10-101648, JP-A 10- 195072, JP-A 11-180957, JP-A 2002-205991, JP-A 2003-113179, JP-A 2004-035439, JP-A 2004-083415, WO 98/57969, WO 99/59993, WO 00 / 35912, WO 00/35913, WO 01/09104, WO 01/14373, WO 01/47918, WO 01/70692, WO 02/12229, WO 03/028458, WO 03/028459, WO 03/043990, WO 03 / 044013, WO 03/097604, WO 03/097605).

It is also known that certain anthranilic acid diamides have pesticidal properties (WO 01/70671, WO 02/094791, WO 03/015519, WO 03/016284, WO 03/015518, WO 03/024222, WO). 03/016282, WO 03/016283, WO 03/062226, WO 03/027099).

Phthalic acid diamides are also known as pesticidal compounds (see EP-AO 919 542, EP-AI 006 107, WO 01/00 575, WO 01/00 599, WO 01/46 124, JP-A 2001). -33 555 9, WO 01/02354, WO 01/21 576, WO 02/08 8074, WO 02/08 8075, WO 02/094765, WO 02/094766, WO 02/062807.

The general formulas and definitions described in these documents and the individual compounds included therein are expressly incorporated herein by reference.

It is also known that mixtures of phthalic acid diamides and further biologically active compounds have pesticidal and / or acaricide actions (WO 02/087 334). However, the activity of these mixtures is not always satisfactory.

Surprisingly, when using certain haloalkylnicotinic acid derivatives, phthalic acid diamides or anthranilic acid amides according to the invention in combination with crop compatibility improving compounds (detoxifiers / detoxifiers) described below, It has been found that it can be particularly advantageously used as a broad formulation for the selective control of insects.

The present invention is a component,

(a) (1) at least one haloalkylnicotinic acid derivative of the general formula (I)

(2) at least one phthalic acid diamide of the general formula (II)

(3) at least one anthranylamide of the following general formula (III), and

(b) 4-dichloroacetyl-1-oxa-4-azaspiro [4.5] -decane (AD-67, MON-4660), 1-dichloroacetylhexahydro-3,3,8a-trimethylpyrrolo [1, 2-a] -pyrimidin-6 (2H) -one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (beta) Noxacor), 1-methylhexyl 5-chloroquinoline-8-oxyacetate (cloquintocet-mexyl-also related to EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366 Compound)), 3- (2-chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumyluron), α- (cyanomethoximino) phenylacetonitrile (siomethynyl) , 2,4-dichlorophenoxy acetic acid (2,4-D), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), 1- (1-methyl-1-phenylethyl)- 3- (4-methylphenyl) urea (dimuron, dimron), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl piperidine-1-thiocarboxylate (Dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenyl) Mino) ethyl) -N- (2-propenyl) acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichloromide), 4,6-dichloro 2-phenylpyrimidine (fenchlorim), ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (penchlorazole- Ethyl, see also related compounds of EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethylthiazole-5-carboxylate (flurazole), 4-chloro-N- (1,3-dioxolan-2-ylmethoxy) -α-trifluoroacetophenone oxime (fluxopenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazoli Dine (furylazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl, also related compounds of WO-A-95 / 07897 1- (ethoxycarbonyl) ethyl-3,6-dichloro-2-methoxybenzoate (lactidichlor), (4-chloro-o-tolyloxy) acetic acid (MCPA), 2- (4 -Chloro-o-tolyl Oxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-di Ethyl, see also related compounds of WO-A-91 / 07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2-propenyl-1-oxa-4-azaspiro [4.5] decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-ylmethoximino) phenylacetonitrile (oxabetrinyl), 2,2-dichloro-N- (1,3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyloxazoli Dean (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148), 4- (4-chloro-o-tolyl) butyric acid, 4- (4-chlorophenoxy) Butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3-carboxylate, ethyl 1- ( 2,4-Diclo Phenyl) -5-methyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-isopropyl-1H-pyrazole-3-carboxylate, ethyl 1- (2, 4-dichlorophenyl) -5- (1,1-dimethylethyl) -1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-phenyl-1H-pyrazole-3- Carboxylate (see also related compounds of EP-A-269806 and EP-A-333131), ethyl 5- (2,4-dichlorobenzyl) -2-isoxazolin-3-carboxylate, ethyl 5-phenyl-2 Isoxazolin-3-carboxylate, ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also related compounds of WO-A-91 / 08202), 1,3-dimethylbut-1-yl 5-chloroquinolin-8-oxyacetate, 4-allyloxybutyl 5-chloroquinolin-8-oxyacetate, 1-allyloxyprop-2-yl 5-chloroquinoline- 8-oxyacetate, methyl 5-chloroquinoxaline-8-oxyacetate, ethyl 5-chloroquinoline-8-oxyacetate, allyl 5-chloroquinoxaline-8-oxy Cetate, 2-oxoprop-1-yl 5-chloroquinoline-8-oxyacetate, diethyl 5-chloroquinolin-8-oxymalonate, diallyl 5- chloroquinoxaline-8-oxymalonate, di Ethyl 5-chloroquinoline-8-oxymalonate (see also related compounds of EP-A-582198), 4-carboxychroman-4-ylacetic acid (see AC-304415, EP-A-613618), 4-chloro Phenoxyacetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl]- 3-methylurea (especially N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) phenyl] -3 , 3-dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) benzenesulfonamide and / or

Selected from the group consisting of one compound of the compounds of formula (IV-a), (IV-b), (IV-c) and / or one compound of the compounds of formula (IV-d), (IV-e) Provided are selective pesticidal and / or acaricide compositions for controlling insects and / or arachnids containing an effective amount of an active combination comprising at least one crop compatibility improving compound:

Where

A ^A represents one of the following groups:

R ^1A represents C ₁ -C ₄ -haloalkyl,

R ^2A and R ^3A independently of one another represent hydrogen or hydroxyl, or

C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C _6- , optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of R ^4A , oximino and hydrazono, respectively Alkynyl, C ₁ -C ₆ -alkoxy, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, wherein the substituents oximino and hydrazono are their The moiety is unsubstituted in each case or is C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C _8- Cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C _1- C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, (C ₁ -C ₈ -alkoxy) carbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl or -CH ₂ -aryl May be substituted by

-C (= X ^A ) -Y ^A , or

Each represent aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , or

R ^2A and R ^3A together with the nitrogen atom to which they are attached, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl, 3- to substituted by the same or different radicals selected from the group consisting of C ₁ -C ₆ -haloalkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, oxo, oximino and hydrazono To form an 8-membered saturated, unsaturated or aromatic heterocyclic ring wherein the substituents oximino and hydrazono are in each case unsubstituted, or C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₈ - cycloalkyl, C ₃ -C ₈ - cycloalkyl, -C ₁ -C ₆ - alkyl, C ₁ -C ₈ - alkoxy -C ₁ - C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxy carbonyl, di - (C ₁ -C ₈ - alkyl) aminocarbonyl, Reel or -CH ₂ - may be substituted by aryl,

R ^4A is halogen, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkoxy, -S (O) _n -C ₁ -C ₆ -alkyl, -S (O) _n -C ₁ -C _6- Haloalkyl, hydroxyl, cyano, carboxyl, azido, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C _1- C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, nitro, di- (C ₁ -C ₆ -alkyl) amino, or C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl and Phenoxy optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of halogen,

R ^5A represents R ^4A , C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl,

X ^A represents oxygen or sulfur,

Y ^A represents R ^6A , OR ^6A , SR ^6A or NR ^7A R ^8A ,

W ^A represents oxygen or sulfur,

R ^6A is each C ₁ -C ₈ -alkyl, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ optionally mono- or polysubstituted by the same or different substituents R ^4A -Alkyl or aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively,

R ^7A represents C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, which represent hydroxyl or are each optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₁ -C ₈ -alkoxy, hydroxyl-C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyloxy, C ₃ -C ₆ -alkynyloxy, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl or -O-CH ₂ -C ₃ -C ₈ -cycloalkyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A Aryl, heterocyclyl, aryloxy, heterocyclyloxy, -CH ₂ -aryl, -O-CH ₂ -aryl, -CH ₂ -heterocyclyl or -O-CH ₂ -heterocyclyl,

R ^8A represents hydrogen or is C ₁ -C ₈ -alkyl, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-, optionally mono- or polysubstituted by the same or different substituents R ^4A , respectively. C ₁ -C ₆ -alkyl, or aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively,

R ^9A and R ^10A are each independently of each other C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, or -C (= X ^A ) -Y ^A , or each the same or different substituents R Aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl optionally substituted by ^5A , or

R ^9A and R ^10A together with the sulfur atom to which they are attached, contain three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, and are unsubstituted, R ^4A , C ₁ -C ₆ -alkyl, C A 3- to 8-membered saturated or unsaturated heterocyclic ring which is mono- or polysubstituted by the same or different radicals selected from the group consisting of _1- C ₆ -haloalkyl, oxo, oximino and hydrazono, wherein Substituents oximino and hydrazono in which these moieties are unsubstituted, C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C _8- Alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl or -CH May be substituted by ₂ -aryl,

Het has 1 or 2 rings and may be fully saturated, partially saturated or fully unsaturated or aromatic and is interrupted by at least one or more identical or different atoms selected from the group consisting of nitrogen, sulfur and oxygen, wherein both oxygen atoms are Should not be directly adjacent and at least one carbon atom is present in the ring and the cyclic radical is unsubstituted or R ^4A , C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, oxo, oximino and hydra Substituted by one or more radicals selected from the group consisting of zono, wherein the substituents oximino and hydrazono are unsubstituted, or C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C _3- C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano -C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ - alkoxycarbonyl, di - (C ₁ -C ₈ - alkyl) aminocarbonyl, aryl or -CH ₂ - represents a heterocyclic radical which may be substituted by aryl,

X ^B represents halogen, cyano, C ₁ -C ₈ -alkyl, C ₁ -C ₈ -haloalkyl, C ₁ -C ₈ -alkoxy or C ₁ -C ₈ -haloalkoxy,

를 나타내며,R ^1B , R ^2B and R ^3B independently of one another represent hydrogen or cyano, optionally halogen-substituted C ₃ -C ₈ -cycloalkyl, or a group

Indicates

M ^1B represents an optionally substituted C ₁ -C ₁₂ -alkylene, C ₃ -C ₁₂ -alkenylene or C ₃ -C ₁₂ -alkynylene,

를 나타내며,Q ^B is hydrogen, halogen, cyano, nitro, C ₁ -C ₈ -haloalkyl, in each case optionally substituted C ₃ -C ₈ -cycloalkyl, C ₁ -C ₈ -alkylcarbonyl or C ₁ -C ₈ -alkoxycarbonyl, in each case optionally substituted phenyl, hetaryl or group

Indicates

T ^B represents oxygen, -S (O) _m or -N (R ^5B )-,

R ^4B is hydrogen, in each case optionally substituted C ₁ -C ₁₂ -alkyl, C ₃ -C ₁₂ -alkenyl, C ₃ -C ₁₂ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₄ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, phenyl , Phenyl-C ₁ -C ₄ -alkyl, phenyl-C ₁ -C ₄ -alkoxy, hetaryl or hetaryl-C ₁ -C ₄ -alkyl,

R ^5B represents hydrogen or in each case optionally substituted C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, phenylcarbonyl or phenyl-C ₁ -C ₆ -alkoxycarbonyl Indicate,

k represents 1, 2, 3 or 4,

m represents 0, 1 or 2,

R ^1B and R ^2B together form an optionally substituted 4- to 7-membered ring which may be optionally interrupted by a heteroatom,

L ^1B and L ^3B are independently of each other hydrogen, halogen, cyano or in each occurrence an optionally substituted C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkoxy, C ₁ -C ₆ -alkyl-S (O) _m- , phenyl, phenoxy or hetaryloxy,

를 나타내며,L ^2B is hydrogen, halogen, cyano, optionally substituted C ₁ -C ₁₂ -alkyl, C ₂ -C ₁₂ -alkenyl, C ₂ -C ₁₂ -alkynyl, C ₁ -C ₁₂ -haloalkyl , C ₃ -C ₈ -cycloalkyl, phenyl, hetaryl or group

Indicates

M ^2B represents oxygen or —S (O) _m −,

R ^6B represents in each occurrence an optionally substituted C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, phenyl or hetaryl ,

L ^1B and L ^3B or L ^1B and L ^2B together in each case form an optionally substituted 5- to 6-membered ring which may be optionally interrupted by a heteroatom,

A ^1C and A ^2C independently represent oxygen or sulfur,

X ^C represents N or CR ^10C ,

R ^1C represents hydrogen or may each be optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C _6- Cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulphi Nyl, C ₁ -C ₄ -alkylsulfonyl, C ₂ -C ₄ -alkoxycarbonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino , (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkylamino and R ^11C , and

R ^2C is hydrogen, C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino, C ₂ -C ₆ -alkoxycarbonyl or C ₂ -C ₆ -alkylcarbonyl,

R ^3C represents hydrogen or R ^11C or is each optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -Cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkyl Thio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C ₃ -C ₆ -trialkyl It may be selected from the group consisting of silyl, R ^11C , phenyl, phenoxy and 5- or 6-membered heteroaromatic rings, wherein each phenyl, phenoxy and 5- or 6-membered heteroaromatic ring is 1 to 3 radicals Optionally substituted by a substituent which may be independently selected from W ^C and one or more radicals R ^12C , or

R ^2C and R ^3C may combine with each other to form a ring M ^C ,

R ^4C is hydrogen, C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₆ -haloalkyl, C ₂ -C ₆ -haloalkenyl, C ₂ -C ₆ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C _1- C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -Haloalkylsulfinyl, C ₁ -C ₄ -haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino or C ₃ -C ₆ -trialkylsilyl or each independently represent C ₁ -C ₄ -alkyl, C ₂ -C ₄ -alkenyl, C ₂ -C ₄ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₄ -haloalkyl, C ₂ -C ₄ -haloalkenyl, C ₂ -C ₄ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, C ₁ -C _4- alkoxy, C ₁ -C ₄ - haloalkoxy, C ₁ -C ₄ - alkylthio, C ₁ -C ₄ - alkyl, Sulfinyl, C ₁ -C ₄ - alkylsulfonyl, C ₁ -C ₄ - alkyl amino furnace, C ₂ -C ₈ - dialkylamino, C ₃ -C ₆ - cycloalkyl, amino, (C ₁ -C ₆ - alkyl )-(C ₃ -C ₆ -cycloalkyl) amino, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylaminocarbonyl, C ₃ -C ₈ Phenyl, benzyl or phenoxy which may be optionally mono- or polysubstituted by a substituent which may be selected from the group consisting of -dialkylaminocarbonyl and C ₃ -C ₆ -trialkylsilyl,

R ^5C and R ^8C in each case independently represent hydrogen or halogen, or in each case optionally substituted C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, R ^12C , G ^C , J ^C , -OJ ^C , -OG ^C , -S (O) _p -J ^C , -S (O) _p -G ^C or -S (O) _p -phenyl, wherein the substituents are independently of each other 1 to 3 Radicals W or R ^12C , C ₁ -C ₁₀ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₁ -C ₄ -alkoxy and C ₁ -C _4- It may be selected from the group consisting of alkylthio, wherein each substituent is independently of each other G ^C , J ^C , R ^6C , halogen, cyano, nitro, amino, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C _4-haloalkyl sulfinyl, C ₁ -C ₄ -haloalkyl-sulfonyl, C ₁ -C ₄ - alkylamino, C ₂ -C ₈ - dialkylamino, C ₃ -C ₆ - trialkylsilyl, Fe And may be optionally substituted by one or more substituents selected from the group consisting of phenoxy, by each page carbonyl or phenoxy ring with one to three radicals of W and the substituents that may be independently selected from each other from one or more radicals R ^12C where Optionally substituted,

G ^C may optionally include one or two ring members selected from the group consisting of C (═O), SO and S (═O) ₂ , independently of each other, and independently of _one another C ₁ -C _2- 5- or 6-membered non-aromatic carbocyclic or heterocyclic rings which may be optionally substituted by 1 to 4 substituents selected from the group consisting of alkyl, halogen, cyano, nitro and C ₁ -C ₂ -alkoxy Or independently of one another, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₇ -cycloalkyl, (cyano) -C ₃ -C ₇ -cycloalkyl, (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkyl or (C ₃ -C ₆ -cycloalkyl) -C ₁ -C ₄ -alkyl, wherein each cycloalkyl, (alkyl) cycloalkyl and ( Cycloalkyl) alkyl may be optionally substituted by one or more halogen atoms,

J ^C represents a 5- or 6-membered heteroaromatic ring optionally substituted at each occurrence independently of one another, wherein the substituents may be independently selected from one to three radicals W ^C and one or more radicals R ^12C ,

R ^6C are independently of each other -C (= E ^1C ) R ^19C , -L ^C C (= E ^1C ) R ^19C , -C (= E ^1C ) L ^C R ^19C , -L ^C C (= E ^1C ) L ^C R ^19C , -OP (= Q ^C ) (OR ^19C ) ₂ , -SO ₂ L ^C R ^18C or -L ^C SO ₂ L ^C R ^19C , wherein each E ^1C is independently of each other O, S, NR ^15C , N-OR ^15C , NN (R ^15C ) ₂ , NS = O, N-CN or N-NO ₂ ;

R ^7C is hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, halogen, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl or C ₁ -C ₄ -haloalkylsul Phonyl;

R ^9C represents C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -haloalkylsulfinyl or halogen,

R ^10C represents hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, halogen, cyano or C ₁ -C ₄ -haloalkoxy,

R ^11C in each occurrence independently of one another is in each case optionally substituted with _one to trisubstituted C ₁ -C ₆ -alkylthio, C ₁ -C ₆ -alkylsulphenyl, C ₁ -C ₆ -haloalkylthio, C ₁ -C ₆ -haloalkylsulphenyl, phenylthio or phenylsulphenyl, wherein the substituents are independently of each other W ^C , -S (O) _n N (R ^16C ) ₂ , -C (= O) R ^13C , -L ^C (C = O) R ^14C , -S (C = O) L ^C R ^14C , -C (= O) L ^C R ^13C , -S (O) _n NR ^13C C (= O) R ^13C , May be selected from the group consisting of -S (O) _n NR ^13C C (= 0) L ^C R ^14C and -S (O) _n NR ^13C S (O) ₂ L ^C R ^14C ,

L ^C represents a O, NR ^18C or S independently from each other in each case,

R ^12C in each occurrence independently of one another is —B (OR ^17C ) ₂ , amino, SH, thiocyanato, C ₃ -C ₈ -trialkylsilyloxy, C ₁ -C ₄ -alkyl disulfide, -SF ₅ , -C (= E ^1C ) R ^19C , -L ^C C (= E ^1C ) R ^19C , -C (= E ^1C ) L ^C R ^19C , -L ^C C (= E ^1C ) L ^C R ^19C , -OP (= Q ^C ) (OR ^{19 C} ) ₂ , -SO ₂ L ^C R ^{19 C,} or -L ^C SO ₂ L ^C R ^{19 C} ;

Q ^C represents O or S,

R ^13C in each occurrence independently represents hydrogen, or in each case is optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino and (C ₁ -C ₄ -alkyl) -C It may be selected from the group consisting of ₃ -C ₆ -cycloalkylamino,

R ^14C is independently of each other at each occurrence at each occurrence R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkyl Sulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino and (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkyl C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₂ -C ₂₀ -alkynyl or C ₃ optionally mono- or polysubstituted by a substituent which may be independently selected from the group consisting of amino -C ₆ -cycloalkyl or independently of one another represent phenyl optionally substituted by substituents which can be selected from 1 to 3 radicals W ^C and one or more radicals R ^12C ,

R ^15C in each case independently represents hydrogen, or in each case independently cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -Alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl, C ₁ -C ₄ -Haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C ₃ -C ₆ Optionally mono- or by a substituent which may be selected from the group consisting of trialkylsilyl and optionally substituted phenyl, wherein the substituents may be independently selected from one to three radicals W and one or more radicals R ^12C Polysubstituted C ₁ -C ₆ -haloalkyl or C ₁ -C ₆ -alkyl, or N (R ^15C ) ₂ represents a cycle forming the ring M ^C ,

R ^16C represents C ₁ -C ₁₂ -alkyl or C ₁ -C ₁₂ -haloalkyl, or N (R ^16C ) ₂ represents a cycle forming the ring M ^C ,

R ^17C in each occurrence independently represents hydrogen or C ₁ -C ₄ -alkyl, or B (OR ^17C ) ₂ represents a ring, wherein the two oxygen atoms are independently of one another in the chain via methyl and C _2- Is bonded to 2 to 3 carbon atoms optionally substituted by one or two substituents selected from the group consisting of C ₆ -alkoxycarbonyl,

R ^18C in each occurrence independently represents hydrogen, C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, or N (R ^13C ) (R ^18C ) represents a cycle forming the ring M ^C ,

R ^19C in each case independently represents hydrogen, or in each case independently cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -Alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl, C ₁ -C ₄ -Haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, CO ₂ H, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C Optionally mono- or multi-substituted by a substituent which may be selected from the group consisting of ₃ -C ₆ -trialkylsilyl and optionally substituted phenyl, wherein the substituents are independently of each other selected from 1 to 3 radicals W ^C Substituted C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, C ₃ -C ₆ -cycloalkyl, or phenyl or pyridyl, optionally mono- to trisubstituted by W ^C , respectively,

M ^C is in each case in addition to the nitrogen atoms bonded to the substituent pairs R ^13C and R ^18C , (R ^15C ) ₂ or (R ^16C ) ₂ is 2 to 6 carbon atoms and optionally further nitrogen, sulfur or oxygen atoms And optionally mono- to tetrasubstituted rings, wherein the substituents can be independently selected from the group consisting of C ₁ -C ₂ -alkyl, halogen, cyano, nitro and C ₁ -C ₂ -alkoxy ,

W ^C is independently of each other at each occurrence C ₁ -C ₄ -alkyl, C ₂ -C ₄ -alkenyl, C ₂ -C ₄ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C _4- Haloalkyl, C ₂ -C ₄ -haloalkenyl, C ₂ -C ₄ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -Dialkylamino, C ₃ -C ₆ -cycloalkylamino, (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkylamino, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C ₆ -Alkoxycarbonyl, CO ₂ H, C ₂ -C ₆ -alkylaminocarbonyl, C ₃ -C ₈ -dialkylaminocarbonyl or C ₃ -C ₆ -trialkylsilyl,

n represents 0 or 1,

p represents 0, 1 or 2,

(a) R ^5C is hydrogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₂ -C ₆ -haloalkenyl, C ₂ -C ₆ -haloalkynyl, C ₁ -C ₄ -Haloalkoxy, C ₁ -C ₄ -haloalkylthio or halogen, (b) R ^8C is hydrogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₂ -C ₆ -halo Alkenyl, C ₂ -C ₆ -haloalkynyl, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -haloalkylthio, halogen, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C _6- When representing alkoxycarbonyl, C ₂ -C ₆ -alkylaminocarbonyl or C ₃ -C ₈ ^{-dialkylaminocarbonyl} , (c) at least one substituent selected from the group consisting of R ^6C , R ^11C and R ^12C Is present and (d) R ^12C is absent, at least one of radicals R ^6C and R ^11C is C ₂ -C ₆ -alkylcarbonyl, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ Is not -alkylaminocarbonyl and C ₃ -C ₈ -dialkylaminocarbonyl,

Compounds of formula (III) also include N-oxides and salts,

r represents 0, 1, 2, 3, 4 or 5,

A ^1D represents one of the following divalent heterocyclic groups:

s is 0, 1, 2, 3, 4, or 5141

Indicates,

A ^2D optionally represents C ₁ -C ₄ -alkyl-, C ₁ -C ₄ -alkoxycarbonyl- and / or C ₁ -C ₄ -alkenyloxycarbonyl-substituted C ₁ -C ₂ -alkanediyl Indicates,

R ^8D represents hydroxyl, mercapto, amino, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -alkylthio, C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino Indicate,

R ^9D is hydroxyl, mercapto, amino, C ₁ -C ₇ -alkoxy, C ₁ -C ₆ -alkenyloxy, C ₁ -C ₆ -alkenyloxy-C ₁ -C ₆ -alkoxy, C _1- C ₆ -alkylthio, C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino,

R ^10D in each case optionally represents fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl,

R ^11D is hydrogen, in each case fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl, C _1- C ₄ -alkoxy-C ₁ -C ₄ -alkyl, dioxolanyl-C ₁ -C ₄ -alkyl, furyl, furyl-C ₁ -C ₄ -alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine -Chlorine- and / or bromine- or C ₁ -C ₄ -alkyl-substituted phenyl,

R ^12D is hydrogen, in each case fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl, C _1- C ₄ -alkoxy-C ₁ -C ₄ -alkyl, dioxolanyl-C ₁ -C ₄ -alkyl, furyl, furyl-C ₁ -C ₄ -alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine -Represent chlorine- and / or bromine- or C ₁ -C ₄ -alkyl-substituted phenyl,

R ^11D and R ^12D together form two 5- or 6-membered carbocycles, together with C ₁ -C ₄ -alkyl, phenyl, furyl, fused benzene ring, or together with the carbon atoms bonded, respectively; C ₃ -C ₆ -alkanediyl or C ₂ -C ₅ -oxalkanediyl optionally substituted by substituents,

R ^13D represents hydrogen, cyano or halogen, or in each case optionally represents fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl, C ₃ -C ₆ -cycloalkyl or phenyl,

R ^14D is hydrogen, optionally hydroxyl-, cyano-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or tri- (C _1- C ₄ -alkyl) silyl,

R ^15D represents hydrogen, cyano or halogen, or in each case optionally represents fluorine, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl, C ₃ -C ₆ -cycloalkyl or phenyl,

X ^1D represents nitro, cyano, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy,

X ^2D represents hydrogen, cyano, nitro, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy,

X ^3D represents hydrogen, cyano, nitro, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy,

t represents 0, 1, 2, 3, 4 or 5,

v represents 0, 1, 2,3 or 4,

R ^16D represents hydrogen or C ₁ -C ₄ -alkyl,

R ^17D represents hydrogen or C ₁ -C ₄ -alkyl,

R ^18D is hydrogen, in each case optionally cyano-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -alkylthio , C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino, or in each case optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -Cycloalkyl, C ₃ -C ₆ -cycloalkyloxy, C ₃ -C ₆ -cycloalkylthio or C ₃ -C ₆ -cycloalkylamino,

R ^19D is hydrogen, optionally cyano-, hydroxyl-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, in each case optionally cyano- or halogen-substituted C _3- C ₆ -alkenyl or C ₃ -C ₆ -alkynyl, or optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -cycloalkyl,

R ^20D is hydrogen, optionally cyano-, hydroxyl-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, in each case optionally cyano- or halogen-substituted C _3- C ₆ -alkenyl or C ₃ -C ₆ -alkynyl, optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -cycloalkyl, or optionally nitro-, cyano- , halogen, C ₁ -C ₄ - alkyl -, C ₁ -C ₄ - haloalkyl -, C ₁ -C ₄ - alkoxy - or C ₁ -C ₄ - haloalkoxy, - or represents a substituted phenyl, and R ^19D Together, in each case optionally represents C ₁ -C ₄ -alkyl-substituted C ₂ -C ₆ -alkanediyl or C ₂ -C ₅ -oxaalkanediyl,

X ^4D is nitro, cyano, carboxy, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy Or C ₁ -C ₄ -haloalkoxy,

X ^5D is nitro, cyano, carboxy, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy Or C ₁ -C ₄ -haloalkoxy.

In the above and later definitions, hydrocarbon chains such as alkyl, alkenyl or alkanediyl, in combination with heteroatoms such as in alkoxy, are in each case straight or branched chain.

Unless stated otherwise, optionally substituted radicals may be mono- or polysubstituted, and in the case of polysubstitution the substituents may be the same or different.

Definitions C ₁ -C ₂₀ -alkyl includes the broadest scope defined herein for alkyl radicals. Specifically, this definition is methyl, ethyl, n-, isopropyl, n-, iso-, sec-, t-butyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1- Ethylpropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and in each case all hexyl isomers (eg n-hexyl, 1-methylpentyl, 2-methylpentyl, 3- Methylpentyl, 4-methylpentyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,3-dimethylbutyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-dimethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethylbutyl, 2-ethylbutyl, 1-ethyl-2-methylpropyl), heptyl isomer (e.g. n-heptyl, 1-methyl Hexyl, 1-ethylpentyl, 2-ethylpentyl, 1-propylbutyl), octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl And the meaning of all isomers of eicosyl.

These definitions may also apply to alkyl radicals in the combined sense, for example as in alkoxy, alkylamine, haloalkyl or cycloalkylalkyl. The scope of the definition depends on the range of carbon atoms given.

Definitions C ₂ -C ₂₀ -alkenyl encompasses the widest range defined herein for alkenyl radicals. Specifically, this definition includes vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl , 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2- Methyl-1-butenyl, 3-methyl-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-part Tenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2- Propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 2-ethyl-2-propenyl, 1-propylvinyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl, 4-methyl-1-pentenyl, 1-methyl- 2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-meth Methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,2-dimethyl-1-butenyl, 1,3-dimethyl-1-butenyl, 1,2 -Dimethyl-1-butenyl, 2,3-dimethyl-1-butenyl, 3,3-dimethyl-1-butenyl, 1-ethyl-1-butenyl, 2-ethyl-1-butenyl, 1, 1-dimethyl-2-butenyl, 1,2-dimethyl-2-butenyl, 1,3-dimethyl-2-butenyl, 2,3-dimethyl-2-butenyl, 1-ethyl-2-butenyl , 2-ethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3 -Butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-3-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl- 1-methyl-2-propenyl, 1-ethyl-2-methyl-2-propenyl, and in each case heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetra Desenyl, pentadecenyl, hexadecenyl, heptadesenyl, octadecenyl, nonadecenyl and eicosenyl.

These definitions may also apply to alkenyl radicals in the combined sense, for example as in alkenyloxy or haloalkenyl. The scope of the definition is each determined by the given range of carbon atoms.

Definitions C ₂ -C ₂₀ -alkynyl includes the broadest range defined herein for alkynyl radicals. Specifically, this definition specifically refers to ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2 -Pentynyl, 3-pentynyl, 4-pentynyl, 3-methyl-1-butynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 3-methyl-1 -Pentynyl, 4-methyl-1-pentynyl, 1-methyl-2-pentynyl, 4-methyl-2-pentynyl, 1-methyl-3-pentynyl, 2-methyl-3-pentynyl, 1 -Methyl-4-pentynyl, 2-methyl-4-pentynyl, 3-methyl-4-pentynyl, 3,3-dimethyl-1-butynyl, 1,1-dimethyl-2-butynyl, 1- Ethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-3-butynyl, 2 -Ethyl-3-butynyl, and in each case heptynyl, octynyl, noninyl, decinyl, undecynyl, dodecynyl, tridecynyl, tetradecynyl, pentadecynyl, hexadecynyl, heptadecyl Neal, Octadesinyl, Comprises or decynyl and Eiko means when all of the isomers of the carbonyl.

These definitions may also apply to alkynyl radicals in the combined sense, for example as in alkynyloxy or haloalkynyl. The scope of the definition is each determined by the given range of carbon atoms.

Definitions C ₃ -C ₈ -cycloalkyl includes the broadest scope defined herein for cycloalkyl radicals. Specifically, this definition includes the meanings of cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl.

These definitions can also apply to cycloalkyl radicals in the combined sense, for example as in halocycloalkyl, cycloalkylamino or cycloalkylalkyl. The scope of the definition is each determined by the given range of carbon atoms.

Oximino (hydroxyimino) represents a substituent = N-OH, where a hydrogen atom can be replaced with a substituent given in each case.

Hydrazono represents a substituent = N-NH ₂ , where two hydrogen atoms can be substituted in each case with a given substituent.

Aryl is mono- or polycyclic aromatic hydrocarbon radicals, preferably mono- to tricyclic radicals having 6 to 14 carbon atoms, particularly preferably phenyl, naphthyl, anthracenyl or phenanthrenyl, very particularly preferably Phenyl.

Heterocyclyl may be fully saturated, partially saturated or fully unsaturated or aromatic and is interrupted by at least one or more identical or different atoms selected from the group consisting of nitrogen, sulfur and oxygen, wherein the two oxygen atoms should not be directly adjacent At least one carbon atom represents mono- or bicyclic 3- to 10-membered radicals which must be present in the ring. Heterocycles in particular thiophene, furan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole, 1,3,4-triazole, 1,2,4-oxadiazole, 1,2,4-thiadiazole, 1,2,4-triazole, 1,2,3-triazole, 1,2 , 3,4-tetrazole, benzo [b] thiophene, benzo [b] furan, indole, benzo [c] thiophene, benzo [c] furan, isoindole, benzoxazole, benzothiazole, benzimidazole, Benzisoxazole, benzisothiazole, benzopyrazole, benzothiadiazole, benzotriazole, dibenzofuran, dibenzothiophene, carbazole, pyridine, pyrazine, pyrimidine, pyridazine, 1,3,5- Triazine, 1,2,4-triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, cynoline, 1,8-naphthyridine, 1,5-naphthyridine , 1,6-naphthyridine, 1,7-naphthyridine, phthalazine, pyridopyrimidine, purine, putridine, 4H-quinolizine, piperidine, pyrrolidine, oxazoline, tetra Jethro furan, a tetrahydropyranyl, tetrahydro-thiopyran, tetrahydro-thiophene, isoxazolyl Jolly Dean or thiazolidine and the like can be mentioned.

Hetaryl or heteroaryl represents a substitution-group of the definition selected from heterocyclyls defined by heteroaromatic ring systems.

Depending on the nature of the substituents, in particular, the compounds of the general formula (I) may exist in geometric and / or optical isomers or mixtures of isomers of various compositions which can be separated by conventional methods as required. Both pure isomers and isomer mixtures are suitable for use in the compositions according to the invention and for use according to the invention. However, for the sake of convenience, only the compounds of the general formula (I) will be referred to hereinafter, even when referring to both pure compounds and optionally mixtures of isomer compounds in different proportions.

Including the individual meanings of A ^A , the following main structures (Ia), (Ib) and (Ic) are formed:

Formula (I) provides a general definition of haloalkylnicotinic acid derivatives of acaricide and / or pesticidal compositions. Hereinafter, the range of preferred substituents or radicals set forth in the formulas mentioned above and hereinafter will be described:

R ^1A is C ₁ -C ₄ -alkyl, particularly preferably CF ₃ , CHF ₂ or CF ₂ Cl, very particularly mono- or polysubstituted by the same or different substituents selected from the group consisting of fluorine and chlorine Preferably CF ₃ ,

R ^2A and R ^3A independently of one another preferably represent hydrogen or hydroxyl, or

C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of R ^4A and oximino, respectively , C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl, wherein the substituent oximino is unsubstituted a portion thereof, C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ - cycloalkyl, -C ₁ -C ₆ - Alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ -alkyl) aminocarbonyl, aryl (especially phenyl) or -CH ₂ -aryl (especially benzyl) Can be, or

-C (= X ^A ) -Y ^A , or

Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, pyrimidinyl, pyridazinyl, pyrazinyl, thiazolyl, isothiazolyl, oxazolyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A ) Isoxazolyl, furyl, thienyl, pyrrolyl, pyrazolyl, thiadiazolyl, tetrahydropyranyl, tetrahydrothiopyranyl, tetrahydrofuryl, tetrahydrothienyl), -CH ₂ -aryl (especially benzyl) Or -CH ₂ -heterocyclyl (particularly -CH ₂ -pyridinyl, -CH ₂ -pyrimidinyl, -CH ₂ -pyridazinyl, -CH ₂ -pyrazinyl, -CH ₂ -thiazolyl, -CH ₂ -Isothiazolyl, -CH ₂ -oxazolyl, -CH ₂ -isoxazolyl, furfuryl, tenyl, -CH ₂ -pyrrolyl, -CH ₂ -pyrazolyl, -CH ₂ -thiadiazolyl, -CH ₂ -tetrahydropyranyl, -CH _2-tetrahydro pyranyl alkylthio, -CH _{2-tetrahydro-furyl,} -CH ₂ - naegeona that the tetrahydro-thienyl),

R ^2A and R ^3A together with the nitrogen atom to which they are attached are preferably unsubstituted, containing up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or R ^4A , C ₁ -C ₆ To form a 3- to 8-membered saturated, unsaturated or aromatic heterocyclic ring substituted by one or more radicals selected from the group consisting of -alkyl, C ₁ -C ₆ -haloalkyl and oximino, wherein the substituent is his portion already played or unsubstituted, C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ - Cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C _1- C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ -alkyl) aminocarbonyl, aryl (especially phenyl) or -CH _2- Substituted by aryl (especially benzyl),

R ^4A is preferably halogen (especially fluorine, chlorine), C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkoxy, -S (O) _n -C ₁ -C ₆ -alkyl, cya Furnace, carboxyl, azido, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, nitro or di- (C ₁ -C ₆ -alkyl) amino,

R ^5A preferably represents R ^4A , C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl,

X ^A preferably represents oxygen, or

X ^A also preferably represents sulfur,

Y ^A preferably represents R ^6A , OR ^6A , SR ^6A or NR ^7A R ^8A ,

W ^A preferably represents oxygen, or

W ^A also preferably represents sulfur,

R ^6A is preferably optionally substituted by one, identical or different substituents R ^4A, respectively, or the substituted C ₁ -C ₆ - alkyl, C ₃ -C ₆ - cycloalkyl or C ₃ -C ₆ - cycloalkyl, -C ₁ Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl, which represents -C ₄ -alkyl or is optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively (Especially benzyl) or -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl),

R ^7A preferably denotes C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ which represent hydroxyl or are each optionally mono- or polysubstituted by the same or different substituents R ^4A -Alkynyl, C ₁ -C ₆ -alkoxy, hydroxyl-C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyloxy, C ₃ -C ₆ -alkynyloxy, C ₃ -C ₆ -cyclo Alkyl, C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl or -O-CH ₂ -C ₃ -C ₆ -cycloalkyl, each optionally substituted by the same or different substituents R ^5A Polysubstituted aryl (especially phenyl), heterocyclyl (especially pyridinyl, thienyl, furyl), aryloxy (especially phenoxy), heterocyclyloxy (especially pyridinyloxy, thienyloxy, furyloxy),- CH ₂ -aryl (particularly benzyl), -O-CH ₂ -aryl (particularly benzyloxy), -CH ₂ -heterocyclyl (particularly pyridinylmethyl, tenyl, furfuryl) or -O-CH ₂ -heterocyclyl (Especially pyridinylmethoxy, tenyloxy, fu It represents a furyl oxy),

R ^8A preferably represents C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl, or C ₃ -C _6- , which represent hydrogen or are each optionally mono- or polysubstituted by the same or different substituents R ^4A Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), which represents cycloalkyl-C ₁ -C ₄ -alkyl or is optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively, -CH ₂ -aryl (especially benzyl) or -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl),

R ^9A and R ^10A are each independently of each other preferably C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ optionally mono- or polysubstituted by the same or different substituents R ^4A -Alkynyl, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, or represent -C (= X ^A ) -Y ^A , or each the same Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl (particularly benzyl) or -CH ₂ -heterocycle optionally or mono- or polysubstituted by different substituents R ^5A Reel (especially pyridinylmethyl, tenyl, furfuryl),

R ^9A and R ^10A together with the sulfur atom to which they are attached, are preferably unsubstituted or contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or R ^4A , C ₁ -C _6- To form a 3- to 8-membered saturated or unsaturated heterocyclic ring substituted by one or more radicals selected from the group consisting of alkyl, C ₁ -C ₆ -haloalkyl, oxo, oximino and hydrazono, wherein Substituents oximino and hydrazono are in each case unsubstituted, or C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C _8- Cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C _1- C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl (Especially phenyl) or -CH ₂ -aryl (specific Hybenzyl)

Het is thiophene, furan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole, 1, 3,4-triazole, 1,2,4-oxadiazole, 1,2,4-thiadiazole, 1,2,4-triazole, 1,2,3-triazole, 1,2,3 , 4-tetrazole, benzo [b] thiophene, benzo [b] furan, indole, benzo [c] thiophene, benzo [c] furan, isoindole, benzoxazole, benzothiazole, benzimidazole, benzi Soxazole, benzisothiazole, benzopyrazole, benzothiadiazole, benzotriazole, dibenzofuran, dibenzothiophene, carbazole, pyridine, pyrazine, pyrimidine, pyridazine, 1,3,5-tri Azine, 1,2,4-triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, cynoline, 1,8-naphthyridine, 1,5-naphthyridine, 1,6-naphthyridine, 1,7-naphthyridine, phthalazine, pyridopyrimidine, purine, putridine, 4H-quinolizine, piperidine, pyrrolidine, oxazoline, tetrahydrofuran, rim La dihydro-pyran, isoxazolyl Jolly Dean and represents the thiazolidine-heterocyclic radical selected from the group consisting of a cyclic radical here is ^{_{unsubstituted, R 4A, C 1 -C 6}} - alkyl, C ₁ -C ₆ -Substituted by one or more radicals selected from the group consisting of haloalkyl, oxo, oximino and hydrazono, and the substituents oximino and hydrazono are unsubstituted parts of these or C ₁ -C ₈ -alkyl, C _3- C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₈ - cycloalkyl, C ₃ -C ₈ - cycloalkyl, -C ₁ -C ₆ - alkyl, C ₁ -C ₈ - alkoxy -C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ - alkoxycarbonyl, di-, can be substituted by aryl (especially benzyl) - (C ₁ -C ₈ - alkyl) aminocarbonyl, aryl (especially phenyl), or -CH _2.

The definitions or explanations of the above mentioned general or preferred radicals may be combined with one another as necessary, ie, between the respective ranges and the preferred ranges.

According to the invention, the pesticidal and / or acaricide composition preferably comprises a compound of formula (I) comprising a combination of the meanings mentioned above as preferred (preferred).

According to the invention, the pesticidal and / or acaricide composition particularly preferably comprises a compound of formula (I) which comprises a combination of the meanings mentioned as particularly preferred above.

According to the invention, the pesticidal and / or acaricide composition comprises very particularly preferably a compound of formula (I) which comprises a combination of the meanings mentioned above as very particularly preferred.

In particular, compounds of the general formula (I-a) may be specifically mentioned:

Table 1 :

In particular, compounds of the general formula (I-b) may be specifically mentioned:

Table 2 :

In particular, compounds of the general formula (I-c) may be mentioned specifically:

Table 3 :

Depending on the nature of the substituents, in particular, the compounds of the general formula (II) may exist in geometric and / or optical isomers or mixtures of isomers of various compositions which can be separated by conventional methods as necessary. Both pure isomers and isomer mixtures are suitable for use in the compositions according to the invention and for use according to the invention. However, for convenience, hereinafter only reference is made to compounds of general formula (II), even when both pure compounds and optionally mixtures of isomer compounds in different proportions.

Formula (II) provides a general definition of phthalic acid diamide of acaricide and / or pesticidal compositions. Hereinafter, the range of preferred substituents or radicals set forth in the formulas mentioned above and hereinafter will be described:

X ^B is preferably fluorine, chlorine, bromine, iodine, cyano, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₁ -C ₆ -alkoxy or C ₁ -C ₆ -haloalkoxy Indicates,

를 나타내며,R ^1B , R ^2B and R ^3B independently of one another preferably represent hydrogen or cyano, or optionally halogen-substituted C ₃ -C ₆ -cycloalkyl or a group

Indicates

M ^1B preferably represents C ₁ -C ₈ -alkylene, C ₃ -C ₆ -alkenylene or C ₃ -C ₆ -alkynylene,

를 나타내며,Q ^B preferably represents hydrogen, halogen, cyano, nitro or C ₁ -C ₆ -haloalkyl, or optionally fluorine-, chlorine-, C ₁ -C ₆ -alkyl- or C ₁ -C ₆ -ylcock when - is optionally substituted with one or two of the ring members are not directly adjacent replaced by oxygen and / or sulfur, C ₃ -C ₈ - cycloalkyl, or represent, in each case optionally halogen-substituted C ₁ -C ₆ -Alkylcarbonyl or C ₁ -C ₆ -alkoxycarbonyl, or in each case optionally halogen-, C ₁ -C ₆ -alkyl-, C ₁ -C ₆ -haloalkyl-, C ₁ -C _6- Alkoxy-, C ₁ -C ₆ -haloalkoxy-, cyano- or nitro-substituted phenyl or hetaryl of 5 to 6 ring atoms (e.g. furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, Pyrimidyl, thiazolyl or thienyl) or a group

Indicates

T ^B preferably represents oxygen, -S (O) _m -or -N (R ^5B )-,

R ^4B preferably represents hydrogen or in each case is optionally fluorine- and / or chlorine-substituted C ₁ -C ₈ -alkyl, C ₃ -C ₈ -alkenyl, C ₃ -C ₈ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₂ -alkyl, C ₁ -C ₆ -alkylcarbonyl or C ₁ -C ₆ -alkoxycarbonyl, or Phenyl mono- to tetrasubstituted by halogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, nitro or cyano, Phenyl-C ₁ -C ₄ -alkyl, phenyl-C ₁ -C ₄ -alkoxy, hetaryl or hetaryl-C ₁ -C ₄ -alkyl, where hetaryl has 5 to 6 ring atoms ( Eg furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl),

R ^5B preferably represents hydrogen or in each case optionally represents fluorine- and / or chlorine-substituted C ₁ -C ₆ -alkylcarbonyl or C ₁ -C ₆ -alkoxycarbonyl, or each halogen, Phenylcarbonyl optionally mono- to tetrasubstituted by C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, nitro or cyano Or phenyl-C ₁ -C ₄ -alkyloxycarbonyl,

k preferably represents 1, 2 or 3,

m preferably represents 0, 1 or 2,

R ^1B and R ^2B together form a 5- to 6-membered ring which may be optionally interrupted by oxygen or sulfur atoms,

L ^1B and L ^3B are independently of each other preferably hydrogen, cyano, fluorine, chlorine, bromine, iodine, C ₁ -C ₆ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkyl-S (O) _m -or C ₁ -C ₄ -haloalkyl-S (O) _m -or each represent fluorine, chlorine, bromine, Phenyl, phenoxy, mono- to trisubstituted by C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, cyano or nitro , Pyridinyloxy, thiazolyloxy or pyrimidinyloxy,

를 나타내며,L ^2B preferably represents hydrogen, fluorine, chlorine, bromine, iodine or cyano, or in each case optionally fluorine- and / or chlorine-substituted C ₁ -C ₁₀ -alkyl, C ₂ -C ₁₀ -al alkenyl or C ₂ -C ₆ - alkynyl represents a carbonyl, or optionally fluorine in each case chlorine-substituted C ₃ -C ₆ - cycloalkyl, or represent an alkyl, respectively as fluorine, chlorine, bromine, C ₁ -C ₆ - alkyl, C ₁ -C ₆ - alkoxy, C ₁ -C ₄ - haloalkyl, C ₁ -C ₄ - haloalkoxy, cyano or by nitro, optionally one-to tri-substituted phenyl, pyridinyl, thienyl, pyridinyl Represent midyl or thiazolyl, or group

Indicates

M ^2B preferably represents oxygen or —S (O) _m −,

R ^6B is preferably in each case optionally fluorine- and / or chlorine-substituted C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl or C ₃ -C ₆ -Cycloalkyl or fluorine, chlorine, bromine, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, cyano Or phenyl, pyridyl, pyrimidinyl or thiazolyl optionally mono- to trisubstituted by nitro,

L ^1B and L ^3B or L ^1B and L ^2B together may each be preferably optionally interrupted by one or two oxygen atoms and are optionally fluorine- and / or C ₁ -C ₂ -alkyl-substituted 5- to Forms a six-membered ring.

X ^B particularly preferably represents chlorine, bromine or iodine,

를 나타내며,R ^1B , R ^2B and R ^3B independently of one another particularly preferably represent hydrogen, or

Indicates

M ^1B particularly preferably represents C ₁ -C ₈ -alkylene, C ₃ -C ₆ -alkenylene or C ₃ -C ₆ -alkynylene,

를 나타내며,Q ^B particularly preferably represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl or C ₃ -C ₆ -cycloalkyl, or

Indicates

T ^B particularly preferably represents oxygen or -S (O) _m- ,

R ^4B particularly preferably represents hydrogen or is C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C _6- , optionally mono- to trisubstituted by fluorine and / or chlorine, respectively Alkynyl or C ₃ -C ₆ -cycloalkyl,

k particularly preferably represents 1, 2 or 3,

m particularly preferably represents 0, 1 or 2,

L ^1B and L ^3B are independently of each other particularly preferably hydrogen, fluorine, chlorine, bromine, iodine, cyano, C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₄ -alkoxy Or C ₁ -C ₂ -haloalkoxy, or fluorine, chlorine, bromine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ Phenyl or phenoxy mono- to di-substituted by haloalkoxy, cyano or nitro,

를 나타내며,L ^2B particularly preferably represents C ₁ -C ₆ -alkyl, C ₂ -C which represent hydrogen, fluorine, chlorine, bromine, iodine or cyano, or optionally mono- to thirteen-substituted by fluorine and / or chlorine, respectively ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl, or

Indicates

M ^2B particularly preferably represents oxygen or —S (O) _m —,

R ^6B is particularly preferably C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ , optionally mono- to thirteen substituted by fluorine and / or chlorine, respectively -C ₆ -cycloalkyl or fluorine, chlorine, bromine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano Or phenyl or pyridyl, optionally mono- to di-substituted by nitro.

X ^B very particularly preferably represents iodine,

R ^1B and R ^2B very particularly preferably represent hydrogen,

를 나타내고,R ^3B is very particularly preferably a group

Indicates,

M ^1B is very particularly preferably -CH (CH ₃ ) CH _2- , -C (CH ₃ ) ₂ CH _2- , -CH (C ₂ H ₅ ) CH _2- , -C (CH ₃ ) (C ₂ H ₅ ) CH ₂ -or -C (C ₂ H ₅ ) ₂ CH _2- ,

를 나타내고,Q ^B very particularly preferably represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl or C ₃ -C ₆ -cycloalkyl, or

Indicates,

T ^B very particularly preferably represents -S-, -SO- or -SO _2- ,

R ^4B is very particularly preferably methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl or t-butyl, allyl, optionally mono- to trisubstituted by fluorine and / or chlorine, respectively , Butenyl or isoprenyl,

L ^1B and L ^3B are independently of one another very particularly preferably hydrogen, fluorine, chlorine, bromine, iodine, cyano, methyl, ethyl, n-propyl, isopropyl, t-butyl, methoxy, ethoxy, trifluor Chloromethyl, difluoromethoxy or trifluoromethoxy,

를 나타내고,L ^2B very particularly preferably represents methyl, ethyl, n-propyl, isopropyl, hydrogen, fluorine, chlorine, bromine, iodine or cyano, or optionally mono- to substituted by fluorine and / or chlorine, respectively; n-butyl, isobutyl, sec-butyl, t-butyl, allyl, butenyl or isoprenyl

Indicates,

M ^2B very particularly preferably represents oxygen or sulfur,

R ^6B is very particularly preferably methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, t-butyl, allyl, optionally mono- to substituted by fluorine and / or chlorine, respectively , Butenyl or isoprenyl, optionally mono- to di-substituted by fluorine, chlorine, bromine, methyl, ethyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro Phenyl is represented.

In particular, the compounds of the following general formula (II) may be specifically mentioned:

Table 4 :

Depending on the nature of the substituents in particular, the compounds of the general formula (III) may exist in geometric and / or optical isomers or in mixtures of isomers of various compositions which can be separated by conventional methods as required. Both pure isomers and isomer mixtures are suitable for use in the compositions according to the invention and for use according to the invention. However, for convenience, hereinafter only reference is made to compounds of general formula (III), even when both pure compounds and optionally mixtures of isomer compounds in different proportions are meant.

Formula (III) provides a general definition of anthranilamide in acaricide and / or pesticidal compositions. Hereinafter, the range of preferred substituents or radicals set forth in the formulas mentioned above and hereinafter will be described:

Preference is given to active combinations comprising the compounds of the general formula (III-a):

Where

R ^2C represents hydrogen or C ₁ -C ₆ -alkyl,

R ^3C represents C ₁ -C ₆ -alkyl optionally substituted by substituent R ^6C ,

R ^4C represents C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy or halogen,

R ^5C represents hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy or halogen,

R ^6C is -C (= E ^2C ) R ^19C , -L ^C C (= E ^2C ) R ^19C , -C (= E ^2C ) L ^C R ^19C or -L ^C C (= E ^2C ) L ^C R ^{19C Wherein} each E ^2C independently of one another represents O, S, NR ¹⁵ , N-OR ¹⁵ or NN (R ¹⁵ ) ₂ , wherein each L ^C independently of one another represents O or NR ^18C ,

R ^7C represents C ₁ -C ₄ -haloalkyl or halogen,

R ^8C represents hydrogen,

R ^9C represents C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy, S (O) _p -C ₁ -C ₂ -haloalkyl or halogen,

R ^15C in each case independently represents hydrogen, or in each case optionally represents C ₁ -C ₆ -haloalkyl or C ₁ -C ₆ -alkyl, wherein the substituents are independently of each other cyano, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ May be selected from the group consisting of -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl and C ₁ -C ₄ -haloalkylsulfonyl,

R ^18C each represents hydrogen or C ₁ -C ₄ -alkyl,

R ^19C in each occurrence independently represents hydrogen or C ₁ -C ₆ -alkyl,

p represents 0, 1 or 2 independently of each other.

Halogen in the radical definitions mentioned as preferred denotes fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine.

R ^2C represents hydrogen or methyl,

R ^3C represents C ₁ -C ₄ -alkyl,

R ^4C represents methyl, trifluoromethyl, trifluoromethoxy, fluorine, chlorine, bromine or iodine,

R ^5C represents hydrogen, fluorine, chlorine, bromine, iodine, trifluoromethyl or trifluoromethoxy,

R ^7C represents chlorine or bromine,

R ^8C represents hydrogen,

R ^9C is particularly preferably an active combination comprising a compound of formula (III-a) which represents trifluoromethyl, chlorine, bromine, difluoromethoxy or trifluoroethoxy.

Very particular preference is given to active combinations comprising the compounds of the general formula (III-a):

Table 5 :

In particular depending on the nature of the substituents, the compounds of the general formulas (IV-a), (IV-b), (IV-c), (IV-d) and (IV-e) may be geometric and / or optical isomers or And isomeric mixtures of various compositions that can be separated by conventional methods. Both pure isomers and isomer mixtures are suitable for use in the compositions according to the invention and for use according to the invention. However, for the sake of convenience, the following formulas (IV-a), (IV-b), (IV-c), (IV-d), even if both mean pure compounds and optionally mixtures of isomer compounds in different proportions And only compounds of (IV-e).

Hereinafter, compounds related to improving crop compatibility of general formulas (IV-a), (IV-b), (IV-c), (IV-d) and (IV-e) ("herbicide weakeners") The preferred meaning of the groups listed above is thus defined.

r preferably represents 0, 1, 2, 3 or 4,

A ^1D preferably represents one of the following divalent heterocyclic groups:

s preferably represents 0, 1, 2, 3 or 4,

A ^2D preferably represents in each case optionally methyl-, ethyl-, methoxycarbonyl-, ethoxycarbonyl- or allyloxycarbonyl-substituted methylene or ethylene,

R ^8D is preferably hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, 1-methylhexyloxy, allyl Oxy, 1-allyloxymethylethoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propyl Amino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino,

R ^9D is preferably hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- Or i-propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino Or diethylamino,

R ^10D preferably in each case optionally represents fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl,

R ^11D is preferably hydrogen, in each case optionally fluorine- and / or chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl , Propynyl or butynyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine, chlorine- , Methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl,

R ^12D is preferably hydrogen, in each case optionally fluorine- and / or chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl , Propynyl or butynyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine, chlorine- , Methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl, or with R ^11D , methyl, ethyl, furyl, phenyl, fused Radicals —CH ₂ —O—CH ₂ —CH ₂ — and —CH ₂ —CH, optionally substituted by a benzene ring or with two substituents forming a 5- or 6-membered carbocycle, together with a bonded carbon atom _{One of 2} -O-CH ₂ -CH _2- ;

R ^13D preferably represents hydrogen, cyano, fluorine, chlorine or bromine or in each case optionally fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl, cyclopropyl, Cyclobutyl, cyclopentyl, cyclohexyl or phenyl,

R ^14D is preferably hydrogen, optionally hydroxyl-, cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i- Propyl, n-, i-, s- or t-butyl,

R ^15D preferably represents hydrogen, cyano, fluorine, chlorine or bromine, or in each case optionally fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl,

X ^1D is preferably nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, Trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy,

X ^2D is preferably hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl Trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, and

X ^3D is preferably hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl Trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy,

t preferably represents a number of 0, 1, 2, 3 or 4,

v preferably represents a number of 0, 1, 2 or 3,

R ^16D preferably represents hydrogen, methyl, ethyl, n- or i-propyl,

R ^17D preferably represents hydrogen, methyl, ethyl, n- or i-propyl,

R ^18D is preferably hydrogen, in each case optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl , n-, i-, s- or t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- Or i-propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino Or diethylamino, or in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclo Hexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, Dichlorobutylamino, cyclopentylamino or cyclohexylamino, and

R ^19D is preferably hydrogen, in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- Or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine, chlorine- or bromine-substituted propenyl, butenyl, propynyl or butynyl, or optionally in each case Cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl,

R ^20D preferably represents hydrogen or in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl , n- or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propynyl or butynyl, in each case Optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, or optionally nitro-, cyano- , Fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy -, n- or i-propoxy-, difluoromethoxy or trifluoromethoxy-substituted phenyl, or together with R ¹⁹ , in each case optionally methyl- or ethyl-substituted butane-1,4- Dile (Trime Alkylene), pentane-1,5-diyl, 1-oxa-butane-1,4-diyl or 3-oxa-pentane-1,5-diyl represents,

X ^4D is preferably nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy,

X ^5D is preferably nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy.

Examples of compounds of the general formula (IV-a) which are very particularly preferred as herbicide safeners according to the invention are listed in the table below.

In particular, compounds of the general formula (IV-a) may be specifically mentioned:

Table 6 :

In particular, compounds of the general formula (IV-b) may be specifically mentioned:

Table 7 :

In particular, compounds of the general formula (IV-c) may be specifically mentioned:

Table 8 :

In particular, the compounds of the following general formula (IV-d) may be specifically mentioned:

Table 9 :

In particular, compounds of the general formula (IV-e) may be specifically mentioned:

Table 10 :

Crop compatibility-compound improving compounds [component (b)] are cloquintocet-mexyl, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, furylazole, fenchlorim, cumyluron, dimlon, Most preferred are dimepiperate, compounds IV-e-5 and IV-e-11, and cloquintocet-mexyl and mefenpyr-diethyl are particularly preferred. Particular preference is given to isoxadifen-ethyl and IV-e-5.

In each case an example of a selective pesticidal and / or acaricide combination according to the invention consisting of one active compound of general formula (I) and in each case one of the safeners defined above is shown in the following table.

Table 11 : Examples of Formulations According to the Invention

Active compound of formula (I), (II) or (III) Softener (I-a-1) Cloquintocet-Mexyl (I-a-1) Phenchlorazole-ethyl (I-a-1) Isoxadifen-ethyl (I-a-1) Mefenpyr-diethyl (I-a-1) Furilazol (I-a-1) Penchlorim (I-a-1) Cumiluron (I-a-1) Daimuron / Dimron (I-a-1) Dimepiperate (I-a-1) IV-e-11 (I-a-1) IV-e-5 (I-a-2) Cloquintocet-Mexyl (I-a-2) Phenchlorazole-ethyl (I-a-2) Isoxadifen-ethyl (I-a-2) Mefenpyr-diethyl (I-a-2) Furilazol (I-a-2) Penchlorim (I-a-2) Cumiluron (I-a-2) Daimuron / Dimron (I-a-2) Dimepiperate (I-a-2) IV-e-11 (I-a-2) IV-e-5 (I-a-45) Cloquintocet-Mexyl (I-a-45) Phenchlorazole-ethyl (I-a-45) Isoxadifen-ethyl (I-a-45) Mefenpyr-diethyl (I-a-45) Furilazol (I-a-45) Penchlorim (I-a-45) Cumiluron (I-a-45) Daimuron / Dimron (I-a-45) Dimepiperate (I-a-45) IV-e-11 (I-a-45) IV-e-5 (I-a-55) Cloquintocet-Mexyl (I-a-55) Phenchlorazole-ethyl (I-a-55) Isoxadifen-ethyl (I-a-55) Mefenpyr-diethyl (I-a-55) Furilazol (I-a-55) Penchlorim (I-a-55) Cumiluron (I-a-55) Daimuron / Dimron (I-a-55) Dimepiperate (I-a-55) IV-e-11 (I-a-55) IV-e-5

Active compound of formula (I), (II) or (III) Softener (I-b-2) Cloquintocet-Mexyl (I-b-2) Phenchlorazole-ethyl (I-b-2) Isoxadifen-ethyl (I-b-2) Mefenpyr-diethyl (I-b-2) Furilazol (I-b-2) Penchlorim (I-b-2) Cumiluron (I-b-2) Daimuron / Dimron (I-b-2) Dimepiperate (I-b-2) IV-e-11 (I-b-2) IV-e-5 (II-3) Cloquintocet-Mexyl (II-3) Phenchlorazole-ethyl (II-3) Isoxadifen-ethyl (II-3) Mefenpyr-diethyl (II-3) Furilazol (II-3) Penchlorim (II-3) Cumiluron (II-3) Daimuron / Dimron (II-3) Dimepiperate (II-3) IV-e-11 (II-3) IV-e-5 (II-6) Cloquintocet-Mexyl (II-6) Phenchlorazole-ethyl (II-6) Isoxadifen-ethyl (II-6) Mefenpyr-diethyl (II-6) Furilazol (II-6) Penchlorim (II-6) Cumiluron (II-6) Daimuron / Dimron (II-6) Dimepiperate (II-6) IV-e-11 (II-6) IV-e-5 (III-a-4) Cloquintocet-Mexyl (III-a-4) Phenchlorazole-ethyl (III-a-4) Isoxadifen-ethyl (III-a-4) Mefenpyr-diethyl (III-a-4) Furilazol (III-a-4) Penchlorim (III-a-4) Cumiluron (III-a-4) Daimuron / Dimron (III-a-4) Dimepiperate (III-a-4) IV-e-11 (III-a-4) IV-e-5

Active compound of formula (I), (II) or (III) Softener (III-a-9) Cloquintocet-Mexyl (III-a-9) Phenchlorazole-ethyl (III-a-9) Isoxadifen-ethyl (III-a-9) Mefenpyr-diethyl (III-a-9) Furilazol (III-a-9) Penchlorim (III-a-9) Cumiluron (III-a-9) Daimuron / Dimron (III-a-9) Dimepiperate (III-a-9) IV-e-11 (III-a-9) IV-e-5

Compounds of formula (IV-a) which are used as safeners are known and / or may be prepared by known methods per se (see WO-A-91 / 07874, WO-A-95 / 07897).

Compounds of general formula (IV-b) which are used as safeners are known and / or can be prepared by known methods per se (EP-A-191736).

Compounds of formula (IV-c) which are used as safeners are known and / or can be prepared by known methods per se (DE-A-2218097, DE-A-2350547).

Compounds of formula (IV-d) which are used as safeners are known and / or can be prepared by known methods per se (DE-A-19621522 / US-A-6235680).

Compounds of the general formula (IV-e) used as weakening agents are known and / or can be prepared by known methods per se (see WO-A-99 / 66795 / US-A-6251827).

Surprisingly, according to the invention, haloalkylnicotinic acid derivatives of the general formula (I), phthalic acid diamides of the general formula (II) or anthraninilamides of the general formula (III) and the weakening agents (detoxification agents) of the group (b) listed above It has been found that the above defined active combinations show very good pesticidal and / or acaricide activity and can be used to selectively control insects in various crops while having very good compatibility with useful plants.

Wherein, in some cases, the compounds of group (b) mentioned above are pesticides of haloalkylnicotinic acid derivatives of general formula (I), phthalic acid diamides of general formula (II) or anthranylamides of general formula (III), and / Or it should be considered surprising that the acaricide activity can be increased to have a synergistic effect.

The active combinations according to the invention can be used, for example, in connection with the following plants:

To the genus dicotyledonous crops: Notice europium (Gossypium), Glycine (Glycine), Beta (Beta), Dow kusu (Daucus), Pace come loose (Phaseolus), pisum (Pisum), Solar num (Solanum), rinum (Linum), Ipomoea , Vicia , Nicotiana , Lycopersicon , Arachis , Brassica , Lactuca , Cucumis , Cucurbita , Helianthus .

To the genus monocotyledonous crops: Duck Party (Oryza), ZE (Zea), tree tikum (Triticum), Johor deum (Hordeum), ABE or (Avena), three-Calais (Secale), sorbitol gum (Sorghum), Trapani Qom (Panicum ), Saccharomyces Room (Saccharum), Ananas (Ananas), aspartate Goose (asparagus), allium (allium).

However, the use of the active combinations according to the invention is not limited at all in the above, but also extends to other plants in the same way.

The beneficial effect of crop compatibility of the active combinations according to the invention is particularly high at certain concentration ratios. However, the weight ratio of active compound in the active combination can vary within a relatively wide range. In general, one of the compounds which improve the crop compatibility mentioned in (b) (detoxification agent / mitigator) per weight part of active compound of formula (I), (II) or (III) or salt thereof is 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight, particularly preferably 0.05 to 10 parts by weight, most preferably 0.07 to 1.5 parts by weight.

The active compounds or active combinations are conventional formulations, for example solutions, emulsions, hydrating powders, suspensions, powders, powders, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with the active compounds. And microcapsules in the polymeric material.

These formulations are known methods, for example by using surfactants, ie emulsifiers and / or dispersants and / or foam formers, to mix the active compounds according to the invention with extenders, ie liquid solvents and / or solid carriers. Manufacture.

If the extender used is water, it is also possible to use, for example, organic solvents as auxiliary solvents. Primarily, suitable liquid solvents include aromatic compounds such as xylene, toluene or alkylnaphthalene; Chlorinated aromatic and chlorinated aliphatic hydrocarbons such as chlorobenzene, chloroethylene or methylene chloride; Aliphatic hydrocarbons such as cyclohexane or paraffins such as petroleum fractions, mineral oils and vegetable oils; Alcohols such as butanol or glycols and their ethers and esters; Ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone; Strong polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

Suitable solid carriers are, for example, ammonium salts and ground natural minerals such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetics such as finely divided silica, alumina and silicates. Mineral; Suitable granular carriers for granules are, for example, pulverized and classified natural rocks such as calcite, marble, pumice, calcite and dolomite, or synthetic granules of inorganic and organic powders, and organic such as sawdust, coconut husks, corn cobs and tobacco stems. Granules of material; Suitable emulsifiers and / or foam formers are for example nonionic and anionic emulsifiers, for example polyoxyethylene fatty alcohol ethers such as polyoxyethylene fatty acid esters, alkylaryl polyglycol ethers, alkylsulfonates, alkylsulphates, aryls Sulfonates and protein hydrolysates; Suitable dispersants are for example lignosulphite waste liquors and methylcellulose.

Adhesives such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latex, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or natural and synthetic phospholipids such as cephalin and lecithin, may be used in the formulation. Can be. Other possible additives are mineral and vegetable oils.

Inorganic pigments such as iron oxide, titanium oxide and prussian blue, and colorants such as alizarin dyes, azo dyes and organic dyes such as metal phthalocyanine dyes and micronutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc It is possible to use

The formulations generally contain the active compound in an amount of 0.1 to 95% by weight, preferably 0.5 to 90% by weight.

The active combinations according to the invention can generally be used in the form of ready-to-use preparations. However, the active compounds contained in the active combinations can also be applied as individual preparations to be mixed in use, ie in the form of tank mixes.

The active combination can be used on its own or as a mixture with other herbicides also known in the formulation, and ready-to-use formulations or tank mixes are possible. Mixtures with other known active compounds such as fungicides, insecticides, acaricides, nematicides, attractants, sterilizers, fungicides, algal repellents, growth substances, plant nutrients and soil improvers are also possible. For specific purposes, especially in post-germination methods, plant compatible mineral oils or vegetable oils (eg commercially available formulations "Rako Binol"), or ammonium salts such as ammonium sulfate or ammonium thiocyanate may be added in the formulation. Including as an additive may also be advantageous.

The active combinations can be used on their own, in the form of their preparations or in the form of further dilution thereof, eg in ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in conventional manner, for example by spraying, spraying, misting, spraying or spreading.

The amount of active combination according to the invention may vary within certain ranges. This depends in particular on climate and soil factors. Generally the application rate is from 0.005 to 5 kg per hectare, preferably from 0.01 to 2 kg per hectare, particularly preferably from 0.05 to 1.0 kg per hectare.

The active combinations according to the invention can be applied before and after the emergence of plants, ie by pre-germination and post-germination methods.

The anti-mitigatory agents used according to the invention can be used for pretreatment (seed dressing) of crop seeds, depending on their properties, can be introduced into seed furrows before sowing, or herbicides after plant germination. Can be applied together.

The active formulations are suitable for controlling animal pests, preferably arthropods and nematodes, especially insects and arachnids, which are encountered in the field of protection and hygiene in agriculture, forestry, storage products and materials. These can preferably be used for protecting plants. They are active for normal or sensitive species and for all or some stages of development. The pests mentioned above include:

The order of Isopoda , for example Oniscus asellus , Armadillidium vulgare and Porcellio scaber .

Millipedes (Diplopoda) tree, for example Blast niul loose obtain Tula tooth (Blaniulus guttulatus).

From the genus Chilopoda , for example Geophilus carpophagus and Scutigera spec .

From the order of Symphyla , for example Scutigerella immaculata .

Thysanura , for example Lepisma saccharina .

From the order of Collembola , for example Onychiurus armatus .

Orthoptera , for example, Acheta domesticus , Gryllotalpa spp. , Locusta migratoria migratorioides , Melanofluus species ( Melanoplus spp.) And Schistocerca gregaria .

From the tree of Blattaria , for example Blatta orientalis , Periplaneta americana , Leucophaea maderae , Blattella germanica .

Dermaptera , for example Forficula auricularia .

Termite Isoptera , for example Reticulitermes spp .

Phthiraptera , for example Pediculus humanus corporis , Haematopinus spp ., Linognathus spp ., Trichodectes spp. .) And damalinia spp .

From the order of the Thysanoptera , for example Hercinothrips femoralis , Thrips tabaci , Thrips palmi and Frankliniella occidentalis ).

From the order of Heteroptera , for example Eurygaster spp ., Dysdercus intermedius , Piesma quadrata , Cimex lectularius , Rodney Rhodnius prolixus and Triatoma spp .

Cicadas (Homoptera) tree, for example, waters right Death in Brassica (Aleurodes brassicae), bemi cyano other dedicate (Bemisia tabaci), the tree Valley right des bar Fora Rio room (Trialeurodes vaporariorum), Apis notice blood (Aphis gossypii), the breather Vico Rhine Brassica (Brevicoryne brassicae), the creep Tommy juice Leavis (Cryptomyzus ribis), Apis wave bar (Aphis fabae), Apis breech (Aphis pomi), Erie O Soma Raney gerum (Eriosoma lanigerum), hyaluronic rope Teruel's Arun Dinis ( Hyalopterus arundinis ), Phylloxera vastatrix , Pemphigus spp. , Macrosiphum avenae , Myzus spp ., Phorodon humulley humuli , Rhopalosiphum padi , Empoasca spp ., Euscelis bilobatus , Nephotettix cincticeps , Lecanium corni co rni), the poinsettia Ole Ah between (Saissetia oleae), Lao del Parks Austria Tel Ruth (Laodelphax striatellus), Neela Parque Bata Lou Regensburg (Nilaparvata lugens), Oh sludge de Ella Augusta is T (Aonidiella aurantii), Oh Speedy Aspidiotus hederae , Pseudococcus spp . And Psylla spp .

Lepidoptera , for example Pectinophora gossypiella , Bupalus piniarius , Cheimatobia brumata , Lithocolletis blancardella , Hyponomeuta padella , Plutella x ylostella , Malacosoma neustria , Euproctis chrysorrhoea , Lymantria spp. ), part Kula matrix Tour Barry Ella (Bucculatrix thurberiella), Philo greatest seutiseu sheet mozzarella (Phyllocnistis citrella), Agrobacterium-Tees species (Agrotis spp.), six pediatric species (Euxoa spp.), Pell Tia species (Feltia spp.), Earias insulana , Heliothis spp ., Mamestra brassicae , Panolis flammea , Spodoptera s pp .), Trichoplusia ni , Carpocapsa pomonella , Pieris spp. , Chilo spp ., Pyrausta nubilalis , Ephestia kuehniella , Galleria mellonella , Tineola bisselliella , Tinea pellionella , Hofmannophila Pseudospretella , Cacoecia podana , Capua reticulana , Choristoneura fumiferana , Clysia ambiguella , Homona magnanima ), Tortrix viridana , Cnaphalocerus spp . And Oulema oryzae .

Coleoptera , for example, Anobium punctatum , Rhizopertha dominica , Bruchidius obtectus , Acanthoscelides obtectus , Hylotrupes bajulus , Agelastica alni , Leptinotarsa decemlineata , Phaedon cochleariae , Diabrotica spp ), peusil Rio des Creative sose Palacio (Psylliodes chrysocephala), epilra keuna Bari Betsy's (Epilachna varivestis), Ato Maria kinds (Atomaria spp.), duck chair Phil Ruth repairs namen system (Oryzaephilus surinamensis), St labor's servants (Anthonomus spp.), Citrus peel loose species (Sitophilus spp.), cut out ot kusu sulka tooth (Otiorrhynchus sulcatus), poly Cosmo test sorbitan di Douce (Cosmopolites sordidus), establish Torin Scotland know Millie's (Ceuthorrhynchus assimilis), Hebrews Blow Force Galactica (Hypera postica), no scalpel test species (Dermestes spp.), Tree logo Dumaguete species (Trogoderma spp.), No trail pandanus species (Anthrenus spp.), Oh ride Attagenus spp ., Lyctus spp ., Meligethes aeneus , Ptinus spp ., Niptus hololeucus , Gibiumuf Gibbium psylloides , Tribolium spp ., Tenebrio molitor , Agriotes spp ., Conoderus spp ., Melonta Melonta ( Melolontha melolontha ), Amphimallon solstitialis , Costelytra zealandica and Lissorhoptus oryzophilus .

Hymenopera species, for example Diprion spp ., Hoplocampa spp ., Lasius spp ., Monomorium pharaonis and Vespa species Vespa spp .

Diptera , for example Aedes spp ., Anopheles spp ., Culex spp ., Drosophila melanogaster , Musca species. Musca spp .), Fannia spp ., Calliphora erythrocephala , Lucilia spp ., Chrysomyia spp ., Cuterebra spp . ), Gastrophilus spp ., Hyppobosca spp ., Stomoxys spp ., Oestrus spp ., Hypoderma spp . , Tabanus spp. , Tannia spp ., Bibio hortulanus , Oscinella frit , Phorbia spp ., Pegomia hyosquiami ( Pegomyia hyoscyami ), Ceratitis capitata , Dacus oleae , Tifula paludosa ( Tipula paludosa ), Hylemyia spp . And Liriomyza spp .

From the order of Siphonaptera , for example Xenopsylla cheopis and Ceratophyllus spp .

Arachnida , for example, Scorpio maurus , Latrodectus mactans , Acarus siro , Argas spp ., Ornitodoros species (Ornithodoros spp.), der Mani in Sousse Galina (Dermanyssus gallinae), Erie ohpieseu Leavis (Eriophyes ribis), Philo Coptic doubles Olay Bora (Phyllocoptruta oleivora), bupil Ruth species (Boophilus spp.), Lippi three Palouse species (Rhipicephalus spp ., Amblyomma spp. , Hyalomma spp ., Ixodes spp ., Psoroptes spp ., Coriooptes spp . Chorioptes spp. ), Sarcoptes spp ., Tarsonemus spp ., Bryobia praetiosa , Panonychus spp ., Tetranicus spp . ( Tetranychus spp. ), Hemitarsonemus spp . And Brevipalpus species ( Br evipalpus spp .).

Plant parasitic nematodes include, for example, Pratylenchus spp ., Radopholus similis , Ditylenchus dipsaci , Tylenchulus semipenetrans . , Heterodera spp ., Globodera spp ., Meloidogyne spp ., Apelenchoides spp ., Longidorus spp . , Xiphinema spp. , Trichodorus spp . And Bursaphelenchus spp .

When used as insecticides, the active compounds according to the invention may also be present in their commercially available formulations and in the use forms prepared from these formulations as a mixture with synergists. Synergists are compounds that increase the activity of the active compound without the need for the synergist added itself to be activated.

The concentration of the active compound of the use form prepared from a commercially available formulation can vary widely. The active compound concentration of the use forms is 0.0000001 to 95% by weight, preferably 0.001 to 1% by weight.

This applies in a conventional manner suitable for the use form.

According to the invention, all plants and parts of plants can be treated. A plant is to be understood herein as meaning all plants and plant populations, such as desired or unwanted wild plants or crops (including naturally occurring crops). Crops include plant varieties and transgenic plants that may or may not be protected by plant breeder authority, by conventional plant breeding and optimization methods, by biotechnology and genetic engineering, or by these methods. It may be a plant obtainable in combination. Parts of the plant are to be understood as meaning all parts and organs of the plant that exist above and below the ground, such as young shoots, leaves, flowers and roots, and examples of which may be mentioned are leaves, leaves and stems. ), Trunks, flowers, fruits, fruits, seeds, roots, tubers and rhizomes may be mentioned. Some of the plants also include harvesting materials, and nutritional and reproductive materials such as seedlings, tubers, rhizomes, cuttings and seeds.

Treatment of plants and parts of plants with the active compounds according to the invention is also one in accordance with conventional processing methods, for example by dipping, spraying, evaporating, misting, spraying, applying, in the case of propagation materials, in particular seed. By the above coating, or by acting the compound on its environment, habitat or storage area.

As mentioned above, it is possible to treat all plants and their parts according to the invention. In a preferred embodiment, wild plant species and plant varieties or those obtained by conventional biological breeding methods such as hybrid breeding or protoplast fusion are treated as well as some of them. In another preferred embodiment, transgenic plants and plant varieties (genetically modified organisms) and parts thereof obtained by recombinant methods are treated, if appropriate, in combination with conventional methods. The terms "part", "part of the plant" or "plant part" have been described above.

Plants which are particularly preferably treated according to the invention are those of the plant variety which are in each case commercially available or in use.

Depending on the plant species or plant variety, their location and growing conditions (soil, climate, growing season, nutrients), an additive ("raising") effect may also be produced by treatment according to the invention. Thus, for example, reduction in the application rate of the materials and compositions used according to the invention and / or broadening the activity spectrum and / or increasing activity, improving plant growth, increasing hot or cold resistance, drought, or water or soil salinity Actually expected effects such as increased resistance to plants, increased blooms, easier harvesting, increased maturity, increased crop yields, improved quality and / or nutritional value of harvested products, and improved storage stability and / or processability of harvested products. It may appear abnormal.

Preferred transgenic plants or plant varieties (ie, genetically engineered) to be treated according to the invention include all plants which accept genetic material which confers useful properties which are particularly advantageous for these plants in genetic modification. Examples of such properties include improved plant growth, increased high or low temperature resistance, drought, or increased resistance to water or soil salts, increased flowering, ease of harvest, increased maturity, increased crop yields, improved quality of harvested products, and / or Increased nutritional value, and increased storage stability and / or processability of the harvested product. Further particularly notable examples of such properties include increased plant defense against animal and microbial pests such as insects, mites, phytopathogenic fungi, bacteria and / or viruses, and also increased plant resistance to certain herbicidally active compounds. Examples of transgenic plants may include important crops such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, oilseed rape, and also fruit trees (opening apples, pears, citrus fruits and grape fruits), Of particular interest are corn, soybeans, potatoes, cotton and oilseed rape. Highlighted properties are in particular genetic material derived from toxins formed in plants, in particular Bacillus thuringiensis (eg genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c) , Cry2Ab, Cry3Bb and CryIF and combinations thereof) is an increase in the plant's defense against insects due to toxins formed in plants (hereinafter referred to as "Bt plants"). Also of particular emphasis is the increased defense of plants against fungi, bacteria and viruses due to systemically acquired resistance (SAR), cystemine, phytoalexin, eliminator and resistance genes and correspondingly expressed proteins and toxins. . Particularly emphasized properties are also the increased tolerance of plants to certain herbicidally active compounds such as imidazolinone, sulfonylurea, glyphosate or phosphinothricin (eg the "PAT" gene). Genes that confer the desired properties of interest can also be present in a combination in a transgenic plant. Examples of "Bt plants" include YIELD GARD ^® (e.g. corn, cotton, soybean), KnockOut ^® (e.g. corn), StarLink ^® (e.g. corn), Bollgard ^® (e.g. cotton), Nucotn ^® (e.g. cotton) And corn varieties, cotton varieties, soybean varieties and potato varieties which are commercially available under the NewLeaf ^® (eg potato) brand name. Examples of herbicide-tolerant plants include Roundup Ready ^® (glyphosate tolerant, eg corn, cotton, soybean), Liberty Link ^® (phosphinothricin tolerant, e.g. oilseed rape), IMI ^® (imidazolinone tolerant) And corn varieties, cotton varieties and soybean varieties available under the trade name STS ^® (sulfonylurea tolerant such as corn). Examples of herbicide-tolerant plants (plants bred by conventional methods for herbicide tolerability) may also be mentioned varieties sold under the name Clearfield ^® (eg corn). Of course, the above description also applies to plant varieties which are to be developed and / or marketed in the future, having the above-mentioned characteristics or where the genetic characteristics are still left to be developed.

The above-mentioned plants can be treated in a particularly advantageous manner according to the invention using mixtures of the active compounds. The abovementioned preferred ranges for these mixtures also apply to the treatment of these plants. Particular emphasis is given to the treatment of plants with mixtures specifically mentioned in the present text.

Equation for calculating the rescue rate for a combination of two active compounds

The expected activity for a given combination of two active compounds can be calculated using Colby's equation as follows: Colby, SR; "Calculating Synergistic and antagonistic Responses of Herbicide Combinations", Weeds 15, pages 20- 22, 1967):

Where

X is% rescue relative to untreated control when active compound A is used at a concentration of m ppm,

Y is% rescue relative to untreated control when active compound B is used at a concentration of n ppm,

E is the percent rescue relative to untreated control when active compounds A and B are used at concentrations of m and n ppm.

If the actual pesticide control rate exceeds the calculated value, the activity of the combination is superadditive, ie there is a synergistic effect. In this case, the actual observed rescue rate should be greater than the value of the expected rescue rate (E) calculated using the above formula.

Drenched sprayed embodiment

Solvent: Water

Supplements: Rapeseed oil methyl ester

One part by weight of the formulation is mixed with the mentioned amounts of water and auxiliary and the concentrate is diluted with water to the desired concentration to prepare a suitable solution.

Heliotis Armigera Heliothis armigera ) exam

Cotton plants ( Gossypium hirsutum ) were sprayed with the active compound formulation at a predetermined use concentration until flowing down, and infected with cottonseed worms (Heliotis armigera) while the leaves were moist.

Spodoptera prugiferda Spodoptera frugiperda ) exam

Corn plants ( Zea mays ) were sprayed with the active compound formulation at a predetermined use concentration until running down, and infected with giant caterpillar (Spodoptera prugiferda) caterpillars while the leaves were moist.

Flutella xyllstella Plutella x ylostella ) exam

Cabbage plants ( Brassica pekinensis ) were sprayed with the active compound formulation at the desired concentration until flowing down, and infected with cabbage moth (flutella xyclestella) larva while the leaves were damp.

After a certain period of time, the relief rate was determined in%. 100% means that all larvae have been killed; 0% means that none of the larvae have been killed. The determined rescue rate was substituted into Colby's formula (see above).

In this test, for example, the following active combinations according to the invention showed a synergistically improved activity compared to the individually applied active compounds:

Table A1

Insects that damage plants

Heliotis Armigera Test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  II-6 0.032 50  Isoxadifen-ethyl WG50 25 0  II-6 + isoxadifen-ethyl (1: 781.25), the present invention 0.032 + 25 Found * 100 Theory ** 50  IV-e-5 active ingredient 100 0  II-6 + IV-e-5 (1: 3125), the present invention 0.032 + 100 Found * 100 Theory ** 50  Dichloramide Active Ingredient 100 0  II-6 + Dichloromide (1: 3125), the present invention 0.032 + 100 Found * 100 Theory ** 50  Furylazole active ingredient 25 0  II-6 + furylazole (1: 781.25), the present invention 0.032 + 25 Found * 100 Theory ** 50

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table A2

Insects that damage plants

Heliotis Armigera Test

 Formulation Concentration (ppm) Relief rate after 3 days (%)  II-3 0.16 60  Isoxadifen-ethyl WG50 100 0  II-3 + isoxadifen-ethyl (1: 625), the present invention 0.16 + 100 Found * 83 Theoretical ** 60  Mefenfir WG15 100 0  II-3 + mefenpyr (1: 625), the present invention 0.16 + 100 Found * 100 Theoretical ** 60  IV-e-5 Active Ingredients 50 0  II-3 + IV-e-5 (1: 312.5), the present invention 0.16 + 50 Found * 83 Theoretical ** 60  Cloquintocet-Mexyl WP20 50 0  II-3 + cloquintocet-mexyl (1: 312.5), the present invention 0.16 + 50 Found * 100 Theoretical ** 60

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table A3

Insects that damage plants

Heliotis Armigera Test

 Formulation Concentration (ppm) Relief rate after 3 days (%)  Dichloramide Active Ingredient 100 0  II-3 + dichloramide (1: 625), the present invention 0.16 + 100 Found * 83 Theoretical ** 60  Fenchlorim Active Ingredient 100 0  II-3 + Fenchlorim (1: 625), the present invention 0.16 + 100 Found * 100 Theoretical ** 60  Furylazole active ingredient 50 0  II-3 + furylazole (1: 312.5), the present invention 0.16 + 50 Found * 100 Theoretical ** 60

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table B1

Insects that damage plants

Flutella xyllstella test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  II-6 0.032 33  IV-e-5 active ingredient 100 0  II-6 + IV-e-5 (1: 3125), the present invention 0.032 + 100 Found * 100 Theory ** 33  Fenchlorim Active Ingredient 25 0  II-6 + Fenchlorim (1: 781.25), the present invention 0.032 + 25 Found * 60 Theory ** 33  Furylazole active ingredient 50 0  II-6 + furylazole (1: 1562.5), the present invention 0.032 + 50 Found * 100 Theory ** 33

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table B2

Insects that damage plants

Flutella xyllstella test

 Formulation Concentration (ppm) Relief rate after 3 days (%)  II-3 0.032 30  Isoxadifen-ethyl WG50 100 0  II-3 + isoxadifen-ethyl (1: 3125), the present invention 0.032 + 100 Found * 83 Theory ** 30  Mefenfir WG15 50 0  II-3 + mefenpyr (1: 1562.5), the present invention 0.032 + 50 Found * 60 Theory ** 30  Cloquintocet-Mexyl WP20 50 0  II-3 + cloquintocet-mexyl (1: 1562.5), the present invention 0.032 + 50 Found * 90 Theory ** 30  Dichloramide Active Ingredient 100 0  II-3 + dichloromide (1: 3125), the present invention 0.032 + 100 Found * 50 Theory ** 30

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table C1

Insects that damage plants

Spodoptera prugiferda test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  II-6 0.032 0  Isoxadifen-ethyl WG50 50 0  II-6 + isoxadifen-ethyl (1: 1562.5), the present invention 0.032 + 50 Found * 66 Theory ** 0  Mefenfir WG15 25 0  II-6 + mefenpyr (1: 781.25), the present invention 0.032 + 25 Found * 100 Theory ** 0  IV-e-5 active ingredient 100 0  II-6 + IV-e-5 (1: 3125), the present invention 0.032 + 100 Found * 100 Theory ** 0

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table C2

Insects that damage plants

Spodoptera prugiferda test

 Formulation Concentration (ppm) Relief rate after 3 days (%)  II-3 0.16 60  Isoxadifen-ethyl WG50 100 0  II-3 + isoxadifen-ethyl (1: 625), the present invention 0.16 + 100 Found * 100 Theory ** 50  Mefenfir WG15 100 0  II-3 + mefenpyr (1: 625), the present invention 0.16 + 100 Found * 100 Theory ** 50  IV-e-5 Active Ingredients 100 0  II-3 + IV-e-5 (1: 625), the present invention 0.16 + 100 Found * 100 Theory ** 50  Cloquintocet-Mexyl WP20 50 0  II-3 + cloquintocet-mexyl (1: 312.5), the present invention 0.16 + 50 Found * 83 Theory ** 50

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table C3

Insects that damage plants

Spodoptera prugiferda test

 Formulation Concentration (ppm) Relief rate after 3 days (%)  Dichloramide Active Ingredient 100 0  II-3 + dichloramide (1: 625), the present invention 0.16 + 100 Found * 100 Theory ** 50  Fenchlorim Active Ingredients 100 0  II-3 + Fenchlorim (1: 625), the present invention 0.16 + 100 Found * 83 Theory ** 50  Furilazole Active Ingredient 100 0  II-3 + furylazole (1: 625), the present invention 0.16 + 100 Found * 100 Theory ** 50

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Drenched sprayed embodiment

Solvent: Water

Supplements: Rapeseed oil methyl ester

One part by weight of the formulation is mixed with an appropriate amount of water and adjuvants and the concentrate is diluted with water to the desired concentration to prepare a suitable application solution.

Apis Notice Aphis gossypii ) exam

Cotton plants ( Gossypium herbaceum ) heavily infected with cotton aphids (Apis gopi ) were sprayed with an application solution of the desired concentration.

Metopolomium dirhodium ( Metopolophium dirhodum ) exam

Barley plants ( Hordeum vulgare ) heavily infected with Grain Aphid ( Metopolophium dirhodum ) were sprayed to run the application solution of the desired concentration.

Missoise Persia ( Myzus persicae ) exam

Pepper plants ( Capsicum sativum ) heavily infected with peach aphids ( Myzus persicae ) were sprayed to run the application solution of the desired concentration.

After a certain period of time, the relief rate was determined in%. 100% means that all aphids have been killed; 0% means that none of the aphids have been killed. The determined rescue rate was substituted into Colby's formula (see above).

In this test, for example, the following active combinations according to the invention showed a synergistically improved activity compared to the individually applied active compounds:

Table D1

Insects that damage plants

Apis Examination Exam

 Formulation Concentration (ppm) Relief rate after 7 days (%)  I-a-45 20 60  Dichloramide Active Ingredient 100 0  I-a-45 + dichloromide (1: 5), the present invention 20 + 100 Found * 90 Theoretical ** 60  Fenchlorim Active Ingredient 100 0  I-a-45 + penchlorim (1: 5), the present invention 20 + 100 Found * 95 Theoretical ** 60  Furylazole active ingredient 100 0  I-a-45 + furylazole (1: 5), the present invention 20 + 100 Found * 95 Theoretical ** 60

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table D2

Insects that damage plants

Apis Examination Exam

 Formulation Concentration (ppm) Relief rate after 7 days (%)  I-a-55 20 4 65 15  Mefenfir WG15 100 0  I-a-55 + mefenpyr (1: 5), the present invention 20 + 100 Found * 90 Theory ** 65  IV-e-5 Active Ingredients 100 0  I-a-55 + IV-e-5 (1:25), the present invention 4 + 100 Found * 65 Theory ** 15  Cloquintocet-Mexyl WP20 100 0  I-a-55 + cloquintocet-mexyl (1:25), the present invention 4 + 100 Found * 60 Theory ** 15

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table D3

Insects that damage plants

Apis Examination Exam

 Formulation Concentration (ppm) Relief rate after 7 days (%)  Dichloramide Active Ingredient 50 0  I-a-55 + dichloromide (1: 12.5), the present invention 4 + 50 Found * 65 Theory ** 15  Fenchlorim Active Ingredients 100 0  I-a-55 + penchlorim (1:25), the present invention 4 + 100 Found * 65 Theory ** 15  Furilazole Active Ingredient 100 0  I-a-55 + furylazole (1:25), the present invention 4 + 100 Found * 60 Theory ** 15

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table E1

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  I-a-45 20 20  Dichloramide Active Ingredient 100 0  I-a-45 + dichloromide (1: 5), the present invention 20 + 100 Found * 90 Theory ** 20  Fenchlorim Active Ingredient 100 0  I-a-45 + penchlorim (1: 5), the present invention 20 + 100 Found * 90 Theory ** 20  Furylazole active ingredient 100 0  I-a-45 + furylazole (1: 5), the present invention 20 + 100 Found * 55 Theory ** 20

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table E2

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  I-a-55 20 4 25 0  Isoxadifen-ethyl WG50 25 0  I-a-55 + isoxadifen-ethyl WG50 (1: 6.25), the present invention 4 + 25 Found * 70 Theory ** 0  Mefenfir WG15 100 0  I-a-55 + mefenpyr (1:25), the present invention 4 + 100 Found * 75 Theory ** 0  IV-e-5 Active Ingredients 25 0  I-a-55 + IV-e-5 (1: 1.25), the present invention 20 + 25 Found * 85 Theory ** 25  Cloquintocet-Mexyl WP20 100 0  I-a-55 + cloquintocet-mexyl (1: 5), the present invention 20 + 100 Found * 90 Theory ** 25

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table E3

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  Dichloramide Active Ingredient 100 0  I-a-55 + dichloromide (1: 5), the present invention 20 + 100 Found * 55 Theory ** 25  Fenchlorim Active Ingredients 100 0  I-a-55 + penchlorim (1: 5), the present invention 20 + 100 Found * 75 Theory ** 25  Furilazole Active Ingredient 100 0  I-a-55 + furylazole (1: 1.25), the present invention 20 + 25 Found * 55 Theory ** 25

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

TABLE F1

Insects that damage plants

Exam in misso persia

 Formulation Concentration (ppm) Relief rate after 3 days (%)  I-a-45 20 4 30 5  Dichloramide Active Ingredient 25 0  I-a-45 + dichloramide (1: 6.25), the present invention 4 + 25 Found * 30 Theory ** 5  Fenchlorim Active Ingredient 25 0  I-a-45 + penchlorim (1: 1.25), the present invention 20 + 25 Found * 50 Theory ** 30  Furylazole active ingredient 100 0  I-a-45 + furylazole (1: 5), the present invention 20 + 100 Found * 60 Theory ** 30

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

TABLE F2

Insects that damage plants

Exam in misso persia

 Formulation Concentration (ppm) Relief rate after 7 days (%)  I-a-55 20 0  Mefenfir WG15 100 0  I-a-55 + mefenpyr (1: 5), the present invention 20 + 100 Found * 40 Theory ** 0  IV-e-5 Active Ingredients 100 0  I-a-55 + IV-e-5 (1: 5), the present invention 20 + 100 Found * 40 Theory ** 0  Cloquintocet-Mexyl WP20 50 0  I-a-55 + cloquintocet-mexyl (1: 2.5), the present invention 20 + 50 Found * 40 Theory ** 0

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

TABLE F3

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (ppm) Relief rate after 7 days (%)  Dichloramide Active Ingredient 100 0  I-a-55 + dichloromide (1: 5), the present invention 20 + 100 Found * 25 Theory ** 0  Fenchlorim Active Ingredients 100 0  I-a-55 + penchlorim (1: 5), the present invention 20 + 100 Found * 35 Theory ** 0

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Spray Treatment Examples-Track Sprayers

Solvent: Water

Supplements: Rapeseed oil methyl ester

One part by weight of the formulation is mixed with the mentioned amounts of water and auxiliary and the concentrate is diluted with water to the desired concentration to prepare a suitable solution.

Apis Notice Aphis gossypii ) exam

Cotton plants ( Gossypium herbaceum ) heavily infected with cotton aphid (Apis gopi ) were sprayed with the application solution of the desired concentration.

Heliotis Armigera Heliothis armigera ) exam

Cotton plants ( Gossypium hirsutum ) were sprayed with an active compound formulation at a predetermined use concentration and infected with cotton seed worms (Heliotis armigera) while the leaves were moist.

Metopolomium dirhodium ( Metopolophium dirhodum ) exam

Barley plants ( Hordeum vulgare ) heavily infected with Grain Aphid ( Metopolophium dirhodum ) were sprayed with the application solution of the desired concentration.

Missoise Persia ( Myzus persicae ) exam

Red pepper plants ( Capsicum sativum ) infected with peach aphids ( Myzus persicae ) were sprayed with the application solution of the desired concentration.

Spodoptera prugiferda Spodoptera frugiperda ) exam

Corn plants ( Zea mays ) were sprayed with the active compound formulation at a predetermined use concentration and infected with giant worms (Spodoftera prugiferda) caterpillars while the leaves were moist.

After a certain period of time, the relief rate was determined in%. 100% means that all aphids have been killed; 0% means that none of the aphids have been killed. The determined rescue rate was substituted into Colby's formula (see above).

In this test, for example, the following active combinations according to the invention showed a synergistically improved activity compared to the individually applied active compounds:

Table G1

Insects that damage plants

Apis Examination Exam

 Formulation Concentration (active ingredient g / ha) Relief rate after 3 days (%)  I-a-45 WG50 120 57  Isoxadifen-ethyl 50 0  I-a-45 + isoxadifen-ethyl WG50 (2.4: 1), the present invention 120 + 50 Found * 87 Theory ** 57  Mefenfir WG15 50 0  I-a-45 + mefenpyr (2.4: 1), the present invention 120 + 50 Found * 83 Theory ** 57  Cloquintocet-Mexyl WP20 50 0  I-a-45 + cloquintocet-mexyl (2.4: 1), the present invention 120 + 50 Found * 80 Theory ** 57

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table G2

Insects that damage plants

Apis Examination Exam

 Formulation Concentration (active ingredient g / ha) Relief rate after 2 days (%)  Floricamide (I-a-2) WG50 120 0  Isoxadifen-ethyl WG50 50 0  Floricamid (I-a-2) + isoxadifen-ethyl (2.4: 1), the present invention 120 + 50 Found * 50 Theory ** 0  Mefenfir WG15 50 0  Flonicamid (I-a-2) + mefenpyr (2.4: 1), the present invention 120 + 50 Found * 50 Theory ** 0  IV-e-5 WG50 50 0  Flonicamid (I-a-2) + IV-e-5 (2.4: 1), the present invention 120 + 50 Found * 40 Theory ** 0  Cloquintocet-Mexyl WP20 50 0  Floricamid (I-a-2) + cloquintocet-mexyl (2.4: 1), this invention 120 + 50 Found * 60 Theory ** 0

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table H

Insects that damage plants

Heliotis Armigera Test

 Formulation Concentration (active ingredient g / ha) Relief rate after 3 days (%)  III-a-4 SC 015 0.192 38  Isoxadifen-ethyl WG50 50 0  III-a-4 + isoxadifen-ethyl (1: 260.4), the present invention 0.192 + 50 Found * 88 Theoretical ** 38  Mefenfir WG15 50 0  III-a-4 + mefenpyr (1: 260.4), the present invention 0.192 + 50 Found * 75 Theoretical ** 38  IV-e-5 WG50 50 0  III-a-4 + IV-e-5 (1: 260.4), the present invention 0.192 + 50 Found * 100 Theoretical ** 38  Cloquintocet-Mexyl WP20 50 0  III-a-4 + cloquintocet-mexyl (1: 260.4), the present invention 0.192 + 50 Found * 100 Theoretical ** 38

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table I1

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (active ingredient g / ha) Relief rate after 7 days (%)  I-a-45 WG50 24 53  Isoxadifen-ethyl WG50 50 0  I-a-45 + isoxadifen-ethyl (1: 2.1), the present invention 24 + 50 Found * 80 Theory ** 53  Mefenfir WG15 50 0  I-a-45 + mefenpyr (1: 2.1), the present invention 24 + 50 Found * 86 Theory ** 53  IV-e-5 active ingredient 50 0  I-a-45 + IV-e-5 (1: 2.1), the present invention 24 + 50 Found * 77 Theory ** 53  Cloquintocet-Mexyl WP20 50 5  I-a-45 + cloquintocet-mexyl (1: 2.1), the present invention 24 + 50 Found * 99 Theory ** 53

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table I2

Insects that damage plants

Metopolomium Dirhodium Test

 Formulation Concentration (active ingredient g / ha) Relief rate after 7 days (%)  Floricamide (I-a-2) WG50 4.8 70  Isoxadifen-ethyl WG50 50 0  Floricamide (I-a-2) + isoxadifen-ethyl (1: 10.42), the present invention 4.8 + 50 Found * 99 Theory ** 70  Mefenfir WG15 50 0  Flonicamid (I-a-2) + mefenpyr (2.4: 1), the present invention 4.8 + 50 Found * 88 Theory ** 70  IV-e-5 active ingredient 50 0  Flonicamid (I-a-2) + IV-e-5 (1: 10.42), the present invention 4.8 + 50 Found * 100 Theory ** 70  Cloquintocet-Mexyl WP20 50 0  Floricamid (I-a-2) + cloquintocet-mexyl (1: 10.42), this invention 4.8 + 50 Found * 90 Theory ** 70

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table J

Insects that damage plants

Exam in misso persia

 Formulation Concentration (active ingredient g / ha) Relief rate after 3 days (%)  I-a-45 WG50 120 70  Isoxadifen-ethyl WG50 50 0  I-a-45 + isoxadifen-ethyl (2.4: 1), the present invention 120 + 50 Found * 90 Theory ** 70  Mefenfir WG15 50 0  I-a-45 + mefenpyr (2.4: 1), the present invention 120 + 50 Found * 90 Theory ** 70  IV-e-5 WG50 50 0  I-a-45 + IV-e-5 (2.4: 1), the present invention 120 + 50 Found * 90 Theory ** 70  Cloquintocet-Mexyl WP20 50 0  I-a-45 + cloquintocet-mexyl (2.4: 1), the present invention 120 + 50 Found * 87 Theory ** 70  Floricamide (I-a-2) WG50 4.8 50  Isoxadifen-ethyl WG50 50 0  Flornicamid (I-a-2) + isoxadifen-ethyl (1: 10.42), the present invention 4.8 + 50 Found * 80 Theory ** 50

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Table K

Insects that damage plants

Spodoptera prugiferda test

 Formulation Concentration (active ingredient g / ha) Relief rate after 7 days (%)  III-a-4 SC 015 0.192 60  Isoxadifen-ethyl WG50 50 0  III-a-4 + isoxadifen-ethyl (1: 260.4), the present invention 0.192 + 50 Found * 100 Theoretical ** 60  Mefenfir WG15 50 0  III-a-4 + mefenpyr (1: 260.4), the present invention 0.192 + 50 Found * 100 Theoretical ** 60  IV-e-5 WG50 50 0  III-a-4 + IV-e-5 (1: 260.4), the present invention 0.192 + 50 Found * 100 Theoretical ** 60

* Found = observed activity

** theoretical value = activity calculated using Colby's equation

Claims (8)

(a) (1) at least one haloalkylnicotinic acid derivative of the general formula (I) (2) at least one phthalic acid diamide of the general formula (II) (3) at least one anthranylamide of the following general formula (III), and (b) 4-dichloroacetyl-1-oxa-4-azaspiro [4.5] -decane (AD-67, MON-4660), 1-dichloroacetylhexahydro-3,3,8a-trimethylpyrrolo [1, 2-a] -pyrimidin-6 (2H) -one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (beta) Noxacor), 1-methylhexyl 5-chloroquinoline-8-oxyacetate (cloquintocet-mexyl-also related to EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366 Compound)), 3- (2-chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumyluron), α- (cyanomethoximino) phenylacetonitrile (siomethynyl) , 2,4-dichlorophenoxy acetic acid (2,4-D), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), 1- (1-methyl-1-phenylethyl)- 3- (4-methylphenyl) urea (dimuron, dimron), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl piperidine-1-thiocarboxylate (Dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenyl) Mino) ethyl) -N- (2-propenyl) acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichloromide), 4,6-dichloro 2-phenylpyrimidine (fenchlorim), ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (penchlorazole- Ethyl, see also related compounds of EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethylthiazole-5-carboxylate (flurazole), 4-chloro-N- (1,3-dioxolan-2-ylmethoxy) -α-trifluoroacetophenone oxime (fluxopenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazoli Dine (furylazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl, also related compounds of WO-A-95 / 07897 1- (ethoxycarbonyl) ethyl-3,6-dichloro-2-methoxybenzoate (lactidichlor), (4-chloro-o-tolyloxy) acetic acid (MCPA), 2- (4 -Chloro-o-tolyl Oxy) propionic acid (mecoprop), diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr- Diethyl, see also related compounds of WO-A-91 / 07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2-propenyl-1-oxa-4-aza Spiro [4.5] decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, α- (1,3-dioxolane-2-ylmethoximino) phenylacetonitrile (oxabetrinyl) , 2,2-dichloro-N- (1,3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyloxa Zolidine (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148), 4- (4-chloro-o-tolyl) butyric acid, 4- (4-chlorophenoxy Butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-Diclo Phenyl) -5-methyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-isopropyl-1H-pyrazole-3-carboxylate, ethyl 1- (2, 4-dichlorophenyl) -5- (1,1-dimethylethyl) -1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-phenyl-1H-pyrazole-3- Carboxylate (see also related compounds of EP-A-269806 and EP-A-333131), ethyl 5- (2,4-dichlorobenzyl) -2-isoxazolin-3-carboxylate, ethyl 5-phenyl-2 Isoxazolin-3-carboxylate, ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also related compounds of WO-A-91 / 08202), 1,3-dimethylbut-1-yl 5-chloroquinolin-8-oxyacetate, 4-allyloxybutyl 5-chloroquinolin-8-oxyacetate, 1-allyloxyprop-2-yl 5-chloroquinoline- 8-oxyacetate, methyl 5-chloroquinoline-8-oxyacetate, ethyl 5-chloroquinoline-8-oxyacetate, allyl 5-chloroquinoline-8-oxyacetate , 2-oxoprop-1-yl 5-chloroquinolin-8-oxyacetate, diethyl 5-chloroquinolin-8-oxymalonate, diallyl 5-chloroquinoline-8-oxymalonate, diethyl 5 -Chloroquinoline-8-oxymalonate (see also related compounds of EP-A-582198), 4-carboxychroman-4-ylacetic acid (see AC-304415, EP-A-613618), 4-chlorophenoxy Acetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3- Methylurea (especially N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3 , 3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) phenyl] -3,3 -Dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) benzenesulfonamide and / or Selected from the group consisting of one compound of the compounds of formula (IV-a), (IV-b), (IV-c) and / or one compound of the compounds of formula (IV-d), (IV-e) Compositions containing an effective amount of an active combination comprising, as ingredients, at least one crop compatibility improving compound:

Where A ^A represents one of the following groups:

R ^1A represents C ₁ -C ₄ -haloalkyl, R ^2A and R ^3A independently of one another represent hydrogen or hydroxyl, or C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C _6- , optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of R ^4A , oximino and hydrazono, respectively Alkynyl, C ₁ -C ₆ -alkoxy, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, wherein the substituents oximino and hydrazono are their The moiety is unsubstituted in each case or is C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C _8- Cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C _1- C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, (C ₁ -C ₈ -alkoxy) carbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl or -CH ₂ -aryl May be substituted by -C (= X ^A ) -Y ^A , or Each represents aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , or R ^2A and R ^3A together with the nitrogen atom to which they are attached, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl, 3- to substituted by the same or different radicals selected from the group consisting of C ₁ -C ₆ -haloalkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, oxo, oximino and hydrazono To form an 8-membered saturated, unsaturated or aromatic heterocyclic ring wherein the substituents oximino and hydrazono are in each case unsubstituted, or C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₈ - cycloalkyl, C ₃ -C ₈ - cycloalkyl, -C ₁ -C ₆ - alkyl, C ₁ -C ₈ - alkoxy -C ₁ - C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxy carbonyl, di - (C ₁ -C ₈ - alkyl) aminocarbonyl, Reel or -CH ₂ - may be substituted by aryl, R ^4A is halogen, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkoxy, -S (O) _n -C ₁ -C ₆ -alkyl, -S (O) _n -C ₁ -C _6- Haloalkyl, hydroxyl, cyano, carboxyl, azido, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C _1- C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, nitro, di- (C ₁ -C ₆ -alkyl) amino, or C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl and Phenoxy optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of halogen, R ^5A represents R ^4A , C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, X ^A represents oxygen or sulfur, Y ^A represents R ^6A , OR ^6A , SR ^6A or NR ^7A R ^8A , W ^A represents oxygen or sulfur, R ^6A is each C ₁ -C ₈ -alkyl, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ optionally mono- or polysubstituted by the same or different substituents R ^4A -Alkyl or aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively, R ^7A represents C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, which represent hydroxyl or are each optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₁ -C ₈ -alkoxy, hydroxyl-C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyloxy, C ₃ -C ₆ -alkynyloxy, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl or -O-CH ₂ -C ₃ -C ₈ -cycloalkyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A Aryl, heterocyclyl, aryloxy, heterocyclyloxy, -CH ₂ -aryl, -O-CH ₂ -aryl, -CH ₂ -heterocyclyl or -O-CH ₂ -heterocyclyl, R ^8A represents hydrogen or is C ₁ -C ₈ -alkyl, C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-, optionally mono- or polysubstituted by the same or different substituents R ^4A , respectively. C ₁ -C ₆ -alkyl, or aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl, optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively, R ^9A and R ^10A are each independently of each other C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, or -C (= X ^A ) -Y ^A , or each the same or different substituents R Aryl, heterocyclyl, -CH ₂ -aryl or -CH ₂ -heterocyclyl optionally mono- or polysubstituted by ^5A , or R ^9A and R ^10A together with the sulfur atom to which they are attached, contain three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, and are unsubstituted, R ^4A , C ₁ -C ₆ -alkyl, C A 3- to 8-membered saturated or unsaturated heterocyclic ring which is mono- or polysubstituted by the same or different radicals selected from the group consisting of _1- C ₆ -haloalkyl, oxo, oximino and hydrazono, wherein Substituents oximino and hydrazono in which these moieties are unsubstituted, C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C _8- Alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl or -CH May be substituted by ₂ -aryl, Het has 1 or 2 rings and may be fully saturated, partially saturated or fully unsaturated or aromatic and is interrupted by at least one or more identical or different atoms selected from the group consisting of nitrogen, sulfur and oxygen, wherein both oxygen atoms are Should not be directly adjacent and at least one carbon atom is present in the ring and the cyclic radical is unsubstituted or R ^4A , C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, oxo, oximino and hydra Substituted by one or more radicals selected from the group consisting of zono, wherein the substituents oximino and hydrazono are unsubstituted or partially substituted with C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cya No-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl , C ₁ -C ₈ - alkoxycarbonyl, di - (C ₁ -C ₈ - alkyl) aminocarbonyl, aryl or -CH ₂ - represents a heterocyclic radical which may be substituted by aryl, X ^B represents halogen, cyano, C ₁ -C ₈ -alkyl, C ₁ -C ₈ -haloalkyl, C ₁ -C ₈ -alkoxy or C ₁ -C ₈ -haloalkoxy, R ^1B , R ^2B and R ^3B independently of one another represent hydrogen or cyano, optionally halogen-substituted C ₃ -C ₈ -cycloalkyl, or a group

Indicates M ^1B represents an optionally substituted C ₁ -C ₁₂ -alkylene, C ₃ -C ₁₂ -alkenylene or C ₃ -C ₁₂ -alkynylene, Q ^B is hydrogen, halogen, cyano, nitro, C ₁ -C ₈ -haloalkyl, in each case optionally substituted C ₃ -C ₈ -cycloalkyl, C ₁ -C ₈ -alkylcarbonyl or C ₁ -C ₈ -alkoxycarbonyl, in each case optionally substituted phenyl, hetaryl or group

Indicates T ^B represents oxygen, -S (O) _m or -N (R ^5B )-, R ^4B is hydrogen, in each case optionally substituted C ₁ -C ₁₂ -alkyl, C ₃ -C ₁₂ -alkenyl, C ₃ -C ₁₂ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₄ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, phenyl , Phenyl-C ₁ -C ₄ -alkyl, phenyl-C ₁ -C ₄ -alkoxy, hetaryl or hetaryl-C ₁ -C ₄ -alkyl, R ^5B represents hydrogen or in each case optionally substituted C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, phenylcarbonyl or phenyl-C ₁ -C ₆ -alkoxycarbonyl Indicate, k represents 1, 2, 3 or 4, m represents 0, 1 or 2, R ^1B and R ^2B may be optionally interrupted by heteroatoms and form an optionally substituted 4- to 7-membered ring, L ^1B and L ^3B are taken together independently of one another hydrogen, halogen, cyano or in each occurrence an optionally substituted C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkoxy, C ₁ -C ₆ -alkyl-S ( O) _m- , phenyl, phenoxy or hetaryloxy, L ^2B is hydrogen, halogen, cyano, optionally substituted C ₁ -C ₁₂ -alkyl, C ₂ -C ₁₂ -alkenyl, C ₂ -C ₁₂ -alkynyl, C ₁ -C ₁₂ -haloalkyl , C ₃ -C ₈ -cycloalkyl, phenyl, hetaryl or group

Indicates M ^2B represents oxygen or —S (O) _m −, R ^6B represents in each occurrence an optionally substituted C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl, phenyl or hetaryl , L ^1B and L ^3B or L ^1B and L ^2B together in each case form an optionally substituted 5- to 6-membered ring which may be optionally interrupted by a heteroatom, A ^1C and A ^2C independently represent oxygen or sulfur, X ^C represents N or CR ^10C , R ^1C represents hydrogen or may each be optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C _6- Cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulphi Nyl, C ₁ -C ₄ -alkylsulfonyl, C ₂ -C ₄ -alkoxycarbonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino , (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkylamino and R ^11C , and R ^2C is hydrogen, C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino, C ₂ -C ₆ -alkoxycarbonyl or C ₂ -C ₆ -alkylcarbonyl, R ^3C represents hydrogen or R ^11C or is each optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -Cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkyl Thio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C ₃ -C ₆ -trialkyl It may be selected from the group consisting of silyl, R ^11C , phenyl, phenoxy and 5- or 6-membered heteroaromatic rings, wherein each phenyl, phenoxy and 5- or 6-membered heteroaromatic ring is 1 to 3 radicals Optionally substituted by a substituent which may be independently selected from W ^C and one or more radicals R ^12C , or R ^2C and R ^3C may combine with each other to form a ring M ^C , R ^4C is hydrogen, C ₁ -C ₆ - alkyl, C ₂ -C ₆ - alkenyl, C ₂ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₁ - C ₆ - haloalkyl, C ₂ -C ₆ -haloalkenyl, C ₂ -C ₆ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C _1- C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -Haloalkylsulfinyl, C ₁ -C ₄ -haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino or C ₃ -C ₆ -trialkylsilyl or each independently represent C ₁ -C ₄ -alkyl, C ₂ -C ₄ -alkenyl, C ₂ -C ₄ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₄ -haloalkyl, C ₂ -C ₄ -haloalkenyl, C ₂ -C ₄ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, C ₁ -C _4- Alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkyl Sulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino, (C ₁ -C ₆ -alkyl )-(C ₃ -C ₆ -cycloalkyl) amino, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylaminocarbonyl, C ₃ -C ₈ Phenyl, benzyl or phenoxy which may be optionally mono- or polysubstituted by a substituent which may be selected from the group consisting of -dialkylaminocarbonyl and C ₃ -C ₆ -trialkylsilyl, R ^5C and R ^8C in each case independently represent hydrogen or halogen, or in each case optionally substituted C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, R ^12C , G ^C , J ^C , -OJ ^C , -OG ^C , -S (O) _p -J ^C , -S (O) _p -G ^C or -S (O) _p -phenyl, wherein the substituents are independently of each other 1 to 3 Radicals W or R ^12C , C ₁ -C ₁₀ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₁ -C ₄ -alkoxy and C ₁ -C _4- It may be selected from the group consisting of alkylthio, wherein each substituent is independently of each other G ^C , J ^C , R ^6C , halogen, cyano, nitro, amino, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C _4-haloalkyl sulfinyl, C ₁ -C ₄ -haloalkyl-sulfonyl, C ₁ -C ₄ - alkylamino, C ₂ -C ₈ - dialkylamino, C ₃ -C ₆ - trialkylsilyl, Fe And it may be optionally substituted by one or more substituents selected from the group consisting of phenoxy, where the optionally each phenyl or phenoxy ring with one to three radicals W, and the substituent in one or more radicals R ^12C may be selected from, independently of each other Can be substituted, G ^C may optionally include one or two ring members selected from the group consisting of C (═O), SO and S (═O) ₂ , independently of each other, and independently of _one another C ₁ -C _2- 5- or 6-membered non-aromatic carbocyclic or heterocyclic rings which may be optionally substituted by 1 to 4 substituents selected from the group consisting of alkyl, halogen, cyano, nitro and C ₁ -C ₂ -alkoxy Or independently from each other C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₇ -cycloalkyl, (cyano) -C ₃ -C ₇ -cycloalkyl, (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkyl or (C ₃ -C ₆ -cycloalkyl) -C ₁ -C ₄ -alkyl, wherein each cycloalkyl, (alkyl) cycloalkyl and ( Cycloalkyl) alkyl may be optionally substituted by one or more halogen atoms, J ^C represents a 5- or 6-membered heteroaromatic ring optionally substituted at each occurrence independently of one another, wherein the substituents may be independently selected from one to three radicals W ^C and one or more radicals R ^12C , R ^6C are independently of each other -C (= E ^1C ) R ^19C , -L ^C C (= E ^1C ) R ^19C , -C (= E ^1C ) L ^C R ^19C , -L ^C C (= E ^1C ) L ^C R ^19C , -OP (= Q ^C ) (OR ^19C ) ₂ , -SO ₂ L ^C R ^18C or -L ^C SO ₂ L ^C R ^19C , wherein each E ^1C is independently of each other O, S, NR ^15C , N-OR ^15C , NN (R ^15C ) ₂ , NS = O, N-CN or N-NO ₂ ; R ^7C is hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, halogen, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl or C ₁ -C ₄ -haloalkylsul Phonyl; R ^9C represents C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -haloalkylsulfinyl or halogen, R ^10C represents hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, halogen, cyano or C ₁ -C ₄ -haloalkoxy, R ^11C in each occurrence independently of one another is in each case optionally substituted with _one to trisubstituted C ₁ -C ₆ -alkylthio, C ₁ -C ₆ -alkylsulphenyl, C ₁ -C ₆ -haloalkylthio, C ₁ -C ₆ -haloalkylsulphenyl, phenylthio or phenylsulphenyl, wherein the substituents are independently of each other W ^C , -S (O) _n N (R ^16C ) ₂ , -C (= O) R ^13C , -L ^C (C = O) R ^14C , -S (C = O) L ^C R ^14C , -C (= O) L ^C R ^13C , -S (O) _n NR ^13C C (= O) R ^13C , May be selected from the group consisting of -S (O) _n NR ^13C C (= 0) L ^C R ^14C and -S (O) _n NR ^13C S (O) ₂ L ^C R ^14C , L ^C represents a O, NR ^18C or S independently from each other in each case, R ^12C in each occurrence independently of one another is —B (OR ^17C ) ₂ , amino, SH, thiocyanato, C ₃ -C ₈ -trialkylsilyloxy, C ₁ -C ₄ -alkyl disulfide, -SF ₅ , -C (= E ^1C ) R ^19C , -L ^C C (= E ^1C ) R ^19C , -C (= E ^1C ) L ^C R ^19C , -L ^C C (= E ^1C ) L ^C R ^19C , -OP (= Q ^C ) (OR ^{19 C} ) ₂ , -SO ₂ L ^C R ^{19 C,} or -L ^C SO ₂ L ^C R ^{19 C} ; Q ^C represents O or S, R ^13C in each occurrence independently represents hydrogen, or in each case is optionally mono- or polysubstituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl, wherein the substituents are independently of each other R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino and (C ₁ -C ₄ -alkyl) -C It may be selected from the group consisting of ₃ -C ₆ -cycloalkylamino, R ^14C is independently of each other at each occurrence at each occurrence R ^6C , halogen, cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkyl Sulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₃ -C ₆ -cycloalkylamino and (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkyl C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₂ -C ₂₀ -alkynyl or C ₃ optionally mono- or polysubstituted by a substituent which may be independently selected from the group consisting of amino -C ₆ -cycloalkyl or independently of one another represent phenyl optionally substituted by substituents which can be selected from 1 to 3 radicals W ^C and one or more radicals R ^12C , R ^15C in each case independently represents hydrogen, or in each case independently of cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl, C ₁ -C ₄ -haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C ₃ -C Optionally mono- by a substituent which may be selected from the group consisting of ₆ -trialkylsilyl and optionally substituted phenyl, wherein the substituents may be independently selected from 1 to 3 radicals W and one or more radicals R ^12C . Or polysubstituted C ₁ -C ₆ -haloalkyl or C ₁ -C ₆ -alkyl, or N (R ^15C ) ₂ represents a cycle forming a ring M ^C , R ^16C represents C ₁ -C ₁₂ -alkyl or C ₁ -C ₁₂ -haloalkyl, or N (R ^16C ) ₂ represents a cycle forming the ring M ^C , R ^17C in each occurrence independently represents hydrogen or C ₁ -C ₄ -alkyl, or B (OR ^17C ) ₂ represents a ring, wherein the two oxygen atoms are independently of one another in the chain via methyl and C _2- Is bonded to 2 to 3 carbon atoms optionally substituted by one or two substituents selected from the group consisting of C ₆ -alkoxycarbonyl, R ^18C in each occurrence independently represents hydrogen, C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, or N (R ^13C ) (R ^18C ) represents a cycle forming the ring M ^C , R ^19C in each case independently represents hydrogen, or in each case independently cyano, nitro, hydroxyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -Alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl, C ₁ -C ₄ -Haloalkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -dialkylamino, CO ₂ H, C ₂ -C ₆ -alkoxycarbonyl, C ₂ -C ₆ -alkylcarbonyl, C Optionally mono- or multi-substituted by a substituent which may be selected from the group consisting of ₃ -C ₆ -trialkylsilyl and optionally substituted phenyl, wherein the substituents are independently of each other selected from 1 to 3 radicals W ^C Substituted C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, C ₃ -C ₆ -cycloalkyl, or phenyl or pyridyl, optionally mono- to trisubstituted by W ^C , respectively, M ^C is in each case in addition to the nitrogen atoms bonded to the substituent pairs R ^13C and R ^18C , (R ^15C ) ₂ or (R ^16C ) ₂ is 2 to 6 carbon atoms and optionally further nitrogen, sulfur or oxygen atoms And optionally mono- to tetrasubstituted rings, wherein the substituents can be independently selected from the group consisting of C ₁ -C ₂ -alkyl, halogen, cyano, nitro and C ₁ -C ₂ -alkoxy , W ^C is independently of each other at each occurrence C ₁ -C ₄ -alkyl, C ₂ -C ₄ -alkenyl, C ₂ -C ₄ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C _4- Haloalkyl, C ₂ -C ₄ -haloalkenyl, C ₂ -C ₄ -haloalkynyl, C ₃ -C ₆ -halocycloalkyl, halogen, cyano, nitro, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ -alkylamino, C ₂ -C ₈ -Dialkylamino, C ₃ -C ₆ -cycloalkylamino, (C ₁ -C ₄ -alkyl) -C ₃ -C ₆ -cycloalkylamino, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C ₆ -Alkoxycarbonyl, CO ₂ H, C ₂ -C ₆ -alkylaminocarbonyl, C ₃ -C ₈ -dialkylaminocarbonyl or C ₃ -C ₆ -trialkylsilyl, n represents 0 or 1, p represents 0, 1 or 2, (a) R ^5C is hydrogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₂ -C ₆ -haloalkenyl, C ₂ -C ₆ -haloalkynyl, C ₁ -C ₄ -Haloalkoxy, C ₁ -C ₄ -haloalkylthio or halogen, (b) R ^8C is hydrogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₂ -C ₆ -halo Alkenyl, C ₂ -C ₆ -haloalkynyl, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -haloalkylthio, halogen, C ₂ -C ₄ -alkylcarbonyl, C ₂ -C _6- When representing alkoxycarbonyl, C ₂ -C ₆ -alkylaminocarbonyl or C ₃ -C ₈ ^{-dialkylaminocarbonyl} , (c) at least one substituent selected from the group consisting of R ^6C , R ^11C and R ^12C is present and, (d) when R ^12C is not present, at least one radical R ^6C and R ^11C is C ₂ -C ₆ - alkylcarbonyl, C ₂ -C ₆ - alkoxycarbonyl, C ₂ -C ₆ Is not -alkylaminocarbonyl and C ₃ -C ₈ -dialkylaminocarbonyl, Compounds of formula (III) also include N-oxides and salts, r represents 0, 1, 2, 3, 4 or 5, A ^1D represents one of the following divalent heterocyclic groups:

s represents a number of 0, 1, 2, 3, 4 or 5, A ^2D optionally represents C ₁ -C ₄ -alkyl-, C ₁ -C ₄ -alkoxycarbonyl- and / or C ₁ -C ₄ -alkenyloxycarbonyl-substituted C ₁ -C ₂ -alkanediyl Indicates, R ^8D represents hydroxyl, mercapto, amino, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -alkylthio, C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino Indicate, R ^9D is hydroxyl, mercapto, amino, C ₁ -C ₇ -alkoxy, C ₁ -C ₆ -alkenyloxy, C ₁ -C ₆ -alkenyloxy-C ₁ -C ₆ -alkoxy, C _1- C ₆ -alkylthio, C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino, R ^10D in each case optionally represents fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl, R ^11D is hydrogen, in each case fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl, C _1- C ₄ -alkoxy-C ₁ -C ₄ -alkyl, dioxolanyl-C ₁ -C ₄ -alkyl, furyl, furyl-C ₁ -C ₄ -alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine -Chlorine- and / or bromine- or C ₁ -C ₄ -alkyl-substituted phenyl, R ^12D is hydrogen, in each case fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl or C ₂ -C ₆ -alkynyl, C _1- C ₄ -alkoxy-C ₁ -C ₄ -alkyl, dioxolanyl-C ₁ -C ₄ -alkyl, furyl, furyl-C ₁ -C ₄ -alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine -Chlorine- and / or bromine- or C ₁ -C ₄ -alkyl-substituted phenyl, or R ^11D and R ^12D together are also C ₁ -C ₄ -alkyl, phenyl, furyl, fused benzene, respectively C ₃ -C ₆ -alkanediyl or C ₂ -C ₅ -oxalkandi, optionally substituted by rings or with two carbon atoms to form a 5- or 6-membered carbocycle Indicates work, R ^13D represents hydrogen, cyano or halogen, or in each case optionally represents fluorine-, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl, C ₃ -C ₆ -cycloalkyl or phenyl, R ^14D is hydrogen, optionally hydroxyl-, cyano-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or tri- (C _1- C ₄ -alkyl) silyl, R ^15D represents hydrogen, cyano or halogen, or in each case optionally represents fluorine, chlorine- and / or bromine-substituted C ₁ -C ₄ -alkyl, C ₃ -C ₆ -cycloalkyl or phenyl, X ^1D represents nitro, cyano, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy, X ^2D represents hydrogen, cyano, nitro, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy, X ^3D represents hydrogen, cyano, nitro, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkoxy, t represents 0, 1, 2, 3, 4 or 5, v represents 0, 1, 2,3 or 4, R ^16D represents hydrogen or C ₁ -C ₄ -alkyl, R ^17D represents hydrogen or C ₁ -C ₄ -alkyl, R ^18D is hydrogen, in each case optionally cyano-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -alkylthio , C ₁ -C ₆ -alkylamino or di- (C ₁ -C ₄ -alkyl) amino, or in each case optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -Cycloalkyl, C ₃ -C ₆ -cycloalkyloxy, C ₃ -C ₆ -cycloalkylthio or C ₃ -C ₆ -cycloalkylamino, R ^19D is hydrogen, optionally cyano-, hydroxyl-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, in each case optionally cyano- or halogen-substituted C _3- C ₆ -alkenyl or C ₃ -C ₆ -alkynyl, or optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -cycloalkyl, R ^20D is hydrogen, optionally cyano-, hydroxyl-, halogen- or C ₁ -C ₄ -alkoxy-substituted C ₁ -C ₆ -alkyl, in each case optionally cyano- or halogen-substituted C _3- C ₆ -alkenyl or C ₃ -C ₆ -alkynyl, optionally cyano-, halogen- or C ₁ -C ₄ -alkyl-substituted C ₃ -C ₆ -cycloalkyl, or optionally nitro-, cyano- , halogen, C ₁ -C ₄ - alkyl -, C ₁ -C ₄ - haloalkyl -, C ₁ -C ₄ - alkoxy - or C ₁ -C ₄ - haloalkoxy, - or represents a substituted phenyl, and R ^19D Together, in each case optionally represents C ₁ -C ₄ -alkyl-substituted C ₂ -C ₆ -alkanediyl or C ₂ -C ₅ -oxaalkanediyl, X ^4D is nitro, cyano, carboxy, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy Or C ₁ -C ₄ -haloalkoxy, X ^5D is nitro, cyano, carboxy, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, halogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy Or C ₁ -C ₄ -haloalkoxy. (a) (1) at least one haloalkylnicotinic acid derivative of the general formula (I-a), (I-b) or (I-c) (2) at least one phthalic acid diamide of the general formula (II) (3) at least one anthranylamide of the following general formula (III-a), and (b) 4-dichloroacetyl-1-oxa-4-azaspiro [4.5] -decane (AD-67, MON-4660), 1-dichloroacetylhexahydro-3,3,8a-trimethylpyrrolo [1, 2-a] -pyrimidin-6 (2H) -one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (beta) Noxacor), 1-methylhexyl 5-chloroquinoline-8-oxyacetate (cloquintocet-mexyl-also related to EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366 Compound)), 3- (2-chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumyluron), α- (cyanomethoximino) phenylacetonitrile (siomethynyl) , 2,4-dichlorophenoxyacetic acid (2,4-D), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), 1- (1-methyl-1-phenylethyl)- 3- (4-methylphenyl) urea (dimuron, dimron), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl piperidine-1-thiocarboxylate (Dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenyl) Mino) ethyl) -N- (2-propenyl) acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichloromide), 4,6-dichloro 2-phenylpyrimidine (fenchlorim), ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (penchlorazole- Ethyl, see also related compounds of EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethylthiazole-5-carboxylate (flurazole), 4-chloro-N- (1,3-dioxolan-2-ylmethoxy) -α-trifluoroacetophenone oxime (fluxopenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazoli Dine (furylazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl, also related compounds of WO-A-95 / 07897 1- (ethoxycarbonyl) ethyl-3,6-dichloro-2-methoxybenzoate (lactidichlor), (4-chloro-o-tolyloxy) acetic acid (MCPA), 2- (4 -Chloro-o-tolyl Oxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-di Ethyl, see also related compounds of WO-A-91 / 07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2-propenyl-1-oxa-4-azaspiro [4.5] decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-ylmethoximino) phenylacetonitrile (oxabetrinyl), 2,2-dichloro-N- (1,3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyloxazoli Dean (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148), 4- (4-chloro-o-tolyl) butyric acid, 4- (4-chlorophenoxy) Butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3-carboxylate, ethyl 1- ( 2,4-Diclo Phenyl) -5-methyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-isopropyl-1H-pyrazole-3-carboxylate, ethyl 1- (2, 4-dichlorophenyl) -5- (1,1-dimethylethyl) -1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-phenyl-1H-pyrazole-3- Carboxylate (see also related compounds of EP-A-269806 and EP-A-333131), ethyl 5- (2,4-dichlorobenzyl) -2-isoxazolin-3-carboxylate, ethyl 5-phenyl-2 Isoxazolin-3-carboxylate, ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also related compounds of WO-A-91 / 08202), 1,3-dimethylbut-1-yl 5-chloroquinolin-8-oxyacetate, 4-allyloxybutyl 5-chloroquinolin-8-oxyacetate, 1-allyloxyprop-2-yl 5-chloroquinoline- 8-oxyacetate, methyl 5-chloroquinoxaline-8-oxyacetate, ethyl 5-chloroquinoline-8-oxyacetate, allyl 5-chloroquinoxaline-8-oxy Cetate, 2-oxoprop-1-yl 5-chloroquinoline-8-oxyacetate, diethyl 5-chloroquinolin-8-oxymalonate, diallyl 5-chloroquinoxaline-8-oxymalonate, di Ethyl 5-chloroquinoline-8-oxymalonate (see also related compounds of EP-A-582198), 4-carboxychroman-4-ylacetic acid (see AC-304415, EP-A-613618), 4-chloro Phenoxyacetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl]- 3-methylurea (especially N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) phenyl]- 3,3-dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) benzenesulfonamide and / or At least one crop compatibility improving compound selected from the group consisting of one of the compounds of formulas (IV-a), (IV-b), (IV-c), (IV-d) and (IV-e) Compositions containing an effective amount of an active combination comprising the ingredients:

Where R ^1A represents C ₁ -C ₄ -alkyl mono- or polysubstituted by the same or different substituents selected from the group consisting of fluorine and chlorine, R ^2A and R ^3A independently of one another represent hydrogen or hydroxyl, or C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents selected from the group consisting of R ^4A and oximino, respectively , C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl, wherein the substituent oximino is unsubstituted a portion thereof, C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₆ -cycloalkyl, C ₃ -C ₆ -cycloalkyl-C ₁ -C _6- Alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ -alkyl) aminocarbonyl, aryl (especially phenyl) or -CH ₂ -aryl (especially benzyl) Can be, or -C (= X ^A ) -Y ^A , or Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, pyrimidinyl, pyridazinyl, pyrazinyl, thiazolyl, isothiazolyl, oxazolyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A ) Isoxazolyl, furyl, thienyl, pyrrolyl, pyrazolyl, thiadiazolyl, tetrahydropyranyl, tetrahydrothiopyranyl, tetrahydrofuryl, tetrahydrothienyl), -CH ₂ -aryl (especially benzyl) Or -CH ₂ -heterocyclyl (particularly -CH ₂ -pyridinyl, -CH ₂ -pyrimidinyl, -CH ₂ -pyridazinyl, -CH ₂ -pyrazinyl, -CH ₂ -thiazolyl, -CH ₂ -Isothiazolyl, -CH ₂ -oxazolyl, -CH ₂ -isoxazolyl, furfuryl, tenyl, -CH ₂ -pyrrolyl, -CH ₂ -pyrazolyl, -CH ₂ -thiadiazolyl, -CH ₂ -tetrahydropyranyl, -CH _2-tetrahydro pyranyl alkylthio, -CH _{2-tetrahydro-furyl,} -CH ₂ -, or represents a tetrahydro-thienyl), R ^2A and R ^3A together with the nitrogen atom to which they are attached, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl , To form a 3- to 8-membered saturated, unsaturated or aromatic heterocyclic ring substituted by one or more radicals selected from the group consisting of C ₁ -C ₆ -haloalkyl and oximino, wherein the substituent oximino a portion thereof or unsubstituted, C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ - cycloalkyl, -C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -Alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ -alkyl) aminocarbonyl, aryl (especially phenyl) or -CH ₂ -aryl ( In particular benzyl), R ^4A is halogen, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkoxy, -S (O) _n -C ₁ -C ₆ -alkyl, cyano, carboxyl, azido, C ₁ -C ₆ -Alkoxy-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, nitro or di - (C ₁ -C ₆ - alkyl) amino, R ^5A represents R ^4A , C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, X ^A represents oxygen, or X ^A also represents sulfur, Y ^A represents R ^6A , OR ^6A , SR ^6A or NR ^7A R ^8A , W ^A represents oxygen, or W ^A also represents sulfur, R ^6A is each C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-C ₁ -C ₄ , optionally mono- or polysubstituted by the same or different substituents R ^4A Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl (particularly benzyl) which represents alkyl or is optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively ) Or -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl), R ^7A represents C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, which represent hydroxyl or are each optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₁ -C ₆ - alkoxy, hydroxyl -C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyloxy, C ₃ -C ₆ - alkynyloxy, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl or -O-CH ₂ -C ₃ -C ₆ -cycloalkyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A Aryl (especially phenyl), heterocyclyl (especially pyridinyl, thienyl, furyl), aryloxy (especially phenoxy), heterocyclyloxy (especially pyridinyloxy, thienyloxy, furyloxy), -CH _2- Aryl (especially benzyl), -O-CH ₂ -aryl (especially benzyloxy), -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl) or -O-CH ₂ -heterocyclyl (especially Pyridinylmethoxy, tenyloxy, furfuryloxy) Indicate, R ^8A represents hydrogen, or C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-, optionally mono- or polysubstituted by the same or different substituents R ^4A , respectively. Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), —CH ₂ , representing C ₁ -C ₄ -alkyl or optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively -Aryl (particularly benzyl) or -CH ₂ -heterocyclyl (particularly pyridinylmethyl, tenyl, furfuryl), R ^9A and R ^10A are each independently of each other C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, or -C (= X ^A ) -Y ^A , or each the same or different substituents R Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl (particularly benzyl) or -CH ₂ -heterocyclyl (particularly pyri) optionally substituted by ^5A Diylmethyl, tenyl, furfuryl), or R ^9A and R ^10A together with the sulfur atom to which they are attached, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl, Form a 3- to 8-membered saturated or unsaturated heterocyclic ring substituted by one or more radicals selected from the group consisting of C ₁ -C ₆ -haloalkyl, oxo, oximino and hydrazono, wherein the substituent ox is Minnows and hydrazonos are unsubstituted or substituted in each case with C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl , C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -Alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl (especially Phenyl) or -CH ₂ -aryl (especially benzyl) Displaced by Het is thiophene, furan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole, 1, 3,4-triazole, 1,2,4-oxadiazole, 1,2,4-thiadiazole, 1,2,4-triazole, 1,2,3-triazole, 1,2,3 , 4-tetrazole, benzo [b] thiophene, benzo [b] furan, indole, benzo [c] thiophene, benzo [c] furan, isoindole, benzoxazole, benzothiazole, benzimidazole, benzisox Solazole, benzisothiazole, benzopyrazole, benzothiadiazole, benzotriazole, dibenzofuran, dibenzothiophene, carbazole, pyridine, pyrazine, pyrimidine, pyridazine, 1,3,5-triazine , 1,2,4-triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, cynoline, 1,8-naphthyridine, 1,5-naphthyridine, 1 , 6-naphthyridine, 1,7-naphthyridine, phthalazine, pyridopyrimidine, purine, putridine, 4H-quinolizine, piperidine, pyrrolidine, oxazoline, tetrahydrofuran, te La dihydro-pyran, isoxazolyl Jolly Dean and represents the thiazolidine-heterocyclic radical selected from the group consisting of cyclic herein radical is _{^{unsubstituted, R 4A, C 1 -C 6}} - alkyl, C ₁ -C ₆ -Substituted by one or more radicals selected from the group consisting of haloalkyl, oxo, oximino and hydrazono, and the substituents oximino and hydrazono are unsubstituted parts of these or C ₁ -C ₈ -alkyl, C _3- C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₈ - cycloalkyl, C ₃ -C ₈ - cycloalkyl, -C ₁ -C ₆ - alkyl, C ₁ -C ₈ - alkoxy -C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ - alkoxycarbonyl, di-, and may be substituted by aryl (especially _{benzyl), - (C 1 -C 8} - alkyl) aminocarbonyl, aryl (especially phenyl), or -CH ₂ X ^B represents fluorine, chlorine, bromine, iodine, cyano, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₁ -C ₆ -alkoxy or C ₁ -C ₆ -haloalkoxy, R ^1B , R ^2B and R ^3B independently of one another represent hydrogen or cyano, or optionally halogen-substituted C ₃ -C ₆ -cycloalkyl or group

Indicates M ^1B represents C ₁ -C ₈ -alkylene, C ₃ -C ₆ -alkenylene or C ₃ -C ₆ -alkynylene, Q ^B represents hydrogen, halogen, cyano, nitro or C ₁ -C ₆ -haloalkyl, or optionally fluorine-, chlorine-, C ₁ -C ₆ -alkyl- or C ₁ -C ₆ -yloxy- Substituted or optionally one or two directly non-contiguous ring members represent C ₃ -C ₈ -cycloalkyl substituted by oxygen and / or sulfur, or in each case optionally halogen-substituted C ₁ -C ₆ -alkyl Carbonyl or C ₁ -C ₆ -alkoxycarbonyl, or in each case optionally halogen-, C ₁ -C ₆ -alkyl-, C ₁ -C ₆ -haloalkyl-, C ₁ -C ₆ -alkoxy- , C ₁ -C ₆ -haloalkoxy-, cyano- or nitro-substituted phenyl or hetaryl of 5 to 6 ring atoms (e.g. furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl , Thiazolyl or thienyl), or

Indicates T ^B represents oxygen, -S (O) _m -or -N (R ^5B )-, R ^4B represents a hydrogen, or fluorine, optionally in each case - and / or chlorine-substituted C ₁ -C ₈ - alkyl, C ₃ -C ₈ - alkenyl, C ₃ -C ₈ - alkynyl, C ₃ - C ₈ -cycloalkyl, C ₃ -C ₈ -cycloalkyl-C ₁ -C ₂ -alkyl, C ₁ -C ₆ -alkylcarbonyl or C ₁ -C ₆ -alkoxycarbonyl, or respectively halogen, C Phenyl, phenyl-C, mono- to tetrasubstituted by _1- C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, nitro or cyano _1- C ₄ -alkyl, phenyl-C ₁ -C ₄ -alkoxy, hetaryl or hetaryl-C ₁ -C ₄ -alkyl, wherein hetaryl has 5 to 6 ring atoms (e.g. fura Nil, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl), R ^5B represents hydrogen or, in each case, optionally represents fluorine- and / or chlorine-substituted C ₁ -C ₆ -alkylcarbonyl or C ₁ -C ₆ -alkoxycarbonyl, or each of halogen, C _1- Phenylcarbonyl or phenyl- optionally mono- to substituted by C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, nitro or cyano C ₁ -C ₄ -alkyloxycarbonyl; k represents 1, 2 or 3, m represents 0, 1 or 2, R ^1B and R ^2B together form a 5- to 6-membered ring which may be optionally interrupted by oxygen or sulfur atoms, L ^1B and L ^3B are independently of each other hydrogen, cyano, fluorine, chlorine, bromine, iodine, C ₁ -C ₆ -alkyl, C ₁ -C ₄ -haloalkyl, C ₁ -C ₆ -alkoxy, C _1- C ₄ -haloalkoxy, C ₁ -C ₄ -alkyl-S (O) _m -or C ₁ -C ₄ -haloalkyl-S (O) _m -or each represent fluorine, chlorine, bromine, C _1- Phenyl, phenoxy, pyridinyl, mono- to trisubstituted by C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, cyano or nitro Oxy, thiazolyloxy or pyrimidinyloxy; L ^2B represents hydrogen, fluorine, chlorine, bromine, iodine or cyano, or in each case optionally fluorine- and / or chlorine-substituted C ₁ -C ₁₀ -alkyl, C ₂ -C ₁₀ -alkenyl or C ₂ -C ₆ -alkynyl, or in each case optionally fluorine-, chlorine-substituted C ₃ -C ₆ -cycloalkyl, or fluorine, chlorine, bromine, C ₁ -C ₆ -alkyl, C, respectively Phenyl, pyridinyl, thienyl, pyrimidyl or thia optionally mono- to trisubstituted by _1- C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, cyano or nitro Represent sleepy, or group

Indicates M ^2B represents oxygen or —S (O) _m −, R ^6B is in each case optionally fluorine- and / or chlorine-substituted C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl Or fluorine, chlorine, bromine, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy, cyano or nitro, respectively Phenyl, pyridyl, pyrimidinyl or thiazolyl optionally substituted by one to trisubstituted, L ^1B and L ^3B or L ^1B and L ^2B together may be optionally interrupted by one or two oxygen atoms respectively and are optionally fluorine- and / or C ₁ -C ₂ -alkyl-substituted 5- to 6-membered Forming a ring, R ^2C represents hydrogen or C ₁ -C ₆ -alkyl, R ^3C represents C ₁ -C ₆ -alkyl optionally substituted by substituent R ^6C , R ^4C represents C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy or halogen, R ^5C represents hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy or halogen, R ^6C is -C (= E ^2C ) R ^19C , -L ^C C (= E ^2C ) R ^19C , -C (= E ^2C ) L ^C R ^19C or -L ^C C (= E ^2C ) L ^C R ^{19C Wherein} each E ^2C independently of one another represents O, S, NR ¹⁵ , N-OR ¹⁵ or NN (R ¹⁵ ) ₂ , wherein each L ^C independently of one another represents O or NR ^18C , R ^7C represents C ₁ -C ₄ -haloalkyl or halogen, R ^8C represents hydrogen, R ^9C represents C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy, S (O) _p -C ₁ -C ₂ -haloalkyl or halogen, R ^15C in each case independently represents hydrogen, or in each case optionally represents C ₁ -C ₆ -haloalkyl or C ₁ -C ₆ -alkyl, wherein the substituents are independently of each other cyano, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -alkylsulfinyl, C ₁ -C ₄ -alkylsulfonyl, C ₁ -C ₄ Can be selected from the group consisting of -haloalkylthio, C ₁ -C ₄ -haloalkylsulfinyl and C ₁ -C ₄ -haloalkylsulfonyl, R ^18C each represents hydrogen or C ₁ -C ₄ -alkyl, R ^19C in each occurrence independently represents hydrogen or C ₁ -C ₆ -alkyl, p represents 0, 1 or 2 independently of each other, r represents 0, 1, 2, 3 or 4, A ^1D represents one of the following divalent heterocyclic groups:

s represents 0, 1, 2, 3 or 4, A ^2D in each case optionally represents methyl-, ethyl-, methoxycarbonyl-, ethoxycarbonyl- or allyloxycarbonyl-substituted methylene or ethylene, R ^8D is hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i- Propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethyl Amino, R ^9D is hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, 1-methylhexyloxy, allyloxy, 1 Allyloxymethylethoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n -, i-, s- or t-butylamino, dimethylamino or diethylamino, R ^10D in each case optionally represents fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl, R ^11D is hydrogen, in each case optionally fluorine- and / or chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propynyl Or butynyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine-, methyl- , Ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl, R ^12D is hydrogen, in each case optionally fluorine- and / or chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propynyl Or butynyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine-, methyl- , Ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl, or together with R ^11D to a methyl, ethyl, furyl, phenyl, fused benzene ring Radicals —CH ₂ —O—CH ₂ —CH ₂ — and —CH ₂ —CH ₂ —, optionally substituted by two substituents to form a 5- or 6-membered carbocycle, or together with the carbon atom bonded thereto; One of O-CH ₂ -CH _2- ; R ^13D represents hydrogen, cyano, fluorine, chlorine or bromine, in each case optionally fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl, cyclopropyl, cyclobutyl, Cyclopentyl, cyclohexyl or phenyl, R ^14D is hydrogen, optionally hydroxyl-, cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n -, i-, s- or t-butyl, R ^15D represents hydrogen, cyano, fluorine, chlorine or bromine, in each case optionally fluorine-, chlorine- and / or bromine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl, X ^1D is nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluoromethyl , Trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, X ^2D is hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluor Chloromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, X ^3D is hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluor Chloromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, t represents a number of 0, 1, 2, 3 or 4, v represents a number of 0, 1, 2 or 3, R ^16D represents hydrogen, methyl, ethyl, n- or i-propyl, R ^17D represents hydrogen, methyl, ethyl, n- or i-propyl, R ^18D is hydrogen, in each case optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n- , i-, s- or t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i- Propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethyl Amino, or in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclo Propyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutyla Mino, cyclopentylamino or cyclohexylamino, and R ^19D is hydrogen, in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i- Propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propynyl or butynyl, or in each case optionally cyano- , Fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, R ^20D represents hydrogen or in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- Or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propynyl or butynyl, in each case optionally cyan No-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, or optionally nitro-, cyano-, fluorine- , Chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n Or i-propoxy-, difluoromethoxy or trifluoromethoxy-substituted phenyl, or together with R ¹⁹ , in each case optionally methyl- or ethyl-substituted butane-1,4-diyl (tri Methylene), pentane-1,5- Diyl, 1-oxa-butane-1,4-diyl or 3-oxa-pentane-1,5-diyl, X ^4D is nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, X ^5D is nitro, cyano, carboxyl, carbamoyl, formyl, sulfamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy. (a) (1) at least one haloalkylnicotinic acid derivative of the general formula (I-a), (I-b) or (I-c) (2) at least one phthalic acid diamide of the general formula (II) (3) at least one anthranylamide of the following general formula (III-a), and (b) 4-dichloroacetyl-1-oxa-4-azaspiro [4.5] -decane (AD-67, MON-4660), 1-dichloroacetylhexahydro-3,3,8a-trimethylpyrrolo [1, 2-a] -pyrimidin-6 (2H) -one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (beta) Noxacor), 1-methylhexyl 5-chloroquinoline-8-oxyacetate (cloquintocet-mexyl-also related to EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366 Compound)), 3- (2-chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumyluron), α- (cyanomethoximino) phenylacetonitrile (siomethynyl) ), 2,4-dichlorophenoxyacetic acid (2,4-D), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), 1- (1-methyl-1-phenylethyl) -3- (4-methylphenyl) urea (dimuron, dimron), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl piperidine-1-thiocarboxyl Rate (dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenyl) Mino) ethyl) -N- (2-propenyl) acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichloromide), 4,6-dichloro 2-phenylpyrimidine (fenchlorim), ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (penchlorazole- Ethyl, see also related compounds of EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethylthiazole-5-carboxylate (flurazole), 4-chloro-N- (1,3-dioxolan-2-ylmethoxy) -α-trifluoroacetophenone oxime (fluxopenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazoli Dine (furylazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl, also related compounds of WO-A-95 / 07897 1- (ethoxycarbonyl) ethyl-3,6-dichloro-2-methoxybenzoate (lactidichlor), (4-chloro-o-tolyloxy) acetic acid (MCPA), 2- (4 -Chloro-o-tolyl Oxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-di Ethyl, see also related compounds of WO-A-91 / 07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2-propenyl-1-oxa-4-azaspiro [4.5] decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-ylmethoximino) phenylacetonitrile (oxabetrinyl), 2,2-dichloro-N- (1,3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyl oxazoli Dean (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148), 4- (4-chloro-o-tolyl) butyric acid, 4- (4-chlorophenoxy) Butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3-carboxylate, ethyl 1- ( 2,4-Diclo Phenyl) -5-methyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-isopropyl-1H-pyrazole-3-carboxylate, ethyl 1- (2, 4-dichlorophenyl) -5- (1,1-dimethylethyl) -1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-phenyl-1H-pyrazole-3- Carboxylate (see also related compounds of EP-A-269806 and EP-A-333131), ethyl 5- (2,4-dichlorobenzyl) -2-isoxazolin-3-carboxylate, ethyl 5-phenyl-2 Isoxazolin-3-carboxylate, ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also related compounds of WO-A-91 / 08202), 1,3-dimethylbut-1-yl 5-chloroquinolin-8-oxyacetate, 4-allyloxybutyl 5-chloroquinolin-8-oxyacetate, 1-allyloxyprop-2-yl 5-chloroquinoline- 8-oxyacetate, methyl 5-chloroquinoxaline-8-oxyacetate, ethyl 5-chloroquinoline-8-oxyacetate, allyl 5-chloroquinoxaline-8-oxy Cetate, 2-oxoprop-1-yl 5-chloroquinoline-8-oxyacetate, diethyl 5-chloroquinolin-8-oxymalonate, diallyl 5-chloroquinoxaline-8-oxymalonate, di Ethyl 5-chloroquinoline-8-oxymalonate (see also related compounds of EP-A-582198), 4-carboxychroman-4-ylacetic acid (see AC-304415, EP-A-613618), 4-chloro Phenoxyacetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl]- 3-methylurea (especially N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) phenyl] -3 , 3-dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) benzenesulfonamide and / or One of the compounds of the general formula (IV-a) according to the following table, one of the compounds of the general formula (IV-b) according to the following table, one of the compounds of the general formula (IV-c) according to the following table, the following table An effective amount of an active combination comprising as an ingredient at least one crop compatibility improving compound selected from the group consisting of one of the compounds of the formula (IV-d) according to Compositions Containing:

Where R ^1A represents CF ₃ , CHF ₂ or CF ₂ Cl, R ^2A and R ^3A independently of one another represent hydrogen or hydroxyl, or C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, mono- or polysubstituted by the same or different substituents each selected from the group consisting of R ^4A and oximino, C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl, wherein the substituent oximino is unsubstituted a portion thereof or C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ - cycloalkyl, -C ₁ -C ₆ - alkyl , C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -Alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ -alkyl) aminocarbonyl, aryl (especially phenyl) or -CH ₂ -aryl (especially benzyl) Or -C (= X ^A ) -Y ^A , or Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, pyrimidinyl, pyridazinyl, pyrazinyl, thiazolyl, isothiazolyl, oxazolyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A ) Isoxazolyl, furyl, thienyl, pyrrolyl, pyrazolyl, thiadiazolyl, tetrahydropyranyl, tetrahydrothiopyranyl, tetrahydrofuryl, tetrahydrothienyl), -CH ₂ -aryl (especially benzyl) Or -CH ₂ -heterocyclyl (particularly -CH ₂ -pyridinyl, -CH ₂ -pyrimidinyl, -CH ₂ -pyridazinyl, -CH ₂ -pyrazinyl, -CH ₂ -thiazolyl, -CH ₂ -Isothiazolyl, -CH ₂ -oxazolyl, -CH ₂ -isoxazolyl, furfuryl, tenyl, -CH ₂ -pyrrolyl, -CH ₂ -pyrazolyl, -CH ₂ -thiadiazolyl, -CH ₂ -tetrahydropyranyl, -CH _2-tetrahydro pyranyl alkylthio, -CH _{2-tetrahydro-furyl,} -CH ₂ -, or represents a tetrahydro-thienyl), R ^2A and R ^3A together with the nitrogen atom to which they are attached, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl, To form a 3- to 8-membered saturated, unsaturated or aromatic heterocyclic ring substituted by one or more radicals selected from the group consisting of C ₁ -C ₆ -haloalkyl and oximino, wherein the substituent oximino his part is unsubstituted or in each case, C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ -Cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy-C ₁ -C ₆ -alkyl, cyano-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, di- (C ₁ -C ₆ ) aminocarbonyl, aryl (especially phenyl) or -CH ₂ -aryl (Especially benzyl), R ^4A is fluorine, chlorine, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkoxy, -S (O) _n -C ₁ -C ₆ -alkyl, cyano, carboxy, azido, C _1- C ₆ -alkoxy-C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylthio-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, nitro or di - (C ₁ -C ₆ - alkyl) amino, R ^5A represents R ^4A , C ₁ -C ₆ -alkyl or C ₁ -C ₆ -haloalkyl, X ^A represents oxygen, or X ^A also represents sulfur, Y ^A represents R ^6A , OR ^6A , SR ^6A or NR ^7A R ^8A , W ^A represents oxygen, or W ^A also represents sulfur, R ^6A is each C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-C ₁ -C ₄ , optionally mono- or polysubstituted by the same or different substituents R ^4A Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl (particularly benzyl) which represents alkyl or is optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively ) Or -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl), R ^7A represents C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, which represent hydroxyl or are each optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₁ -C ₆ - alkoxy, hydroxyl -C ₁ -C ₆ - alkyl, C ₃ -C ₆ - alkenyloxy, C ₃ -C ₆ - alkynyloxy, C ₃ -C ₆ - cycloalkyl, C ₃ -C ₆ -cycloalkyl-C ₁ -C ₆ -alkyl or -O-CH ₂ -C ₃ -C ₆ -cycloalkyl, each optionally mono- or polysubstituted by the same or different substituents R ^5A Aryl (especially phenyl), heterocyclyl (especially pyridinyl, thienyl, furyl), aryloxy (especially phenoxy), heterocyclyloxy (especially pyridinyloxy, thienyloxy, furyloxy), -CH _2- Aryl (especially benzyl), -O-CH ₂ -aryl (especially benzyloxy), -CH ₂ -heterocyclyl (especially pyridinylmethyl, tenyl, furfuryl) or -OCH ₂ -heterocyclyl (especially pyridinylme Methoxy, tenyloxy, furfuryloxy) Get out, R ^8A represents hydrogen, or C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl or C ₃ -C ₆ -cycloalkyl-, optionally mono- or polysubstituted by the same or different substituents R ^4A , respectively. Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), —CH ₂ , representing C ₁ -C ₄ -alkyl or optionally mono- or polysubstituted by the same or different substituents R ^5A , respectively -Aryl (particularly benzyl) or -CH ₂ -heterocyclyl (particularly pyridinylmethyl, tenyl, furfuryl), R ^9A and R ^10A are each independently of each other C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, optionally mono- or polysubstituted by the same or different substituents R ^4A , C ₃ -C ₈ -cycloalkyl or C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, or -C (= X ^A ) -Y ^A , or each the same or different substituents R Aryl (particularly phenyl), heterocyclyl (particularly pyridinyl, thienyl, furyl), -CH ₂ -aryl (particularly benzyl) or -CH ₂ -heterocyclyl (particularly pyri) optionally substituted by ^5A Diylmethyl, tenyl, furfuryl), or R ^9A and R ^10A together with the sulfur atom to which they are bonded, contain up to three additional heteroatoms, optionally selected from the group consisting of nitrogen, sulfur and oxygen, or are unsubstituted, or R ^4A , C ₁ -C ₆ -alkyl, C To form a 3- to 8-membered saturated or unsaturated heterocyclic ring substituted by one or more radicals selected from the group consisting of _1- C ₆ -haloalkyl, oxo, oximino and hydrazono, wherein the substituent ox is Minnows and hydrazonos are unsubstituted or substituted in each case with C ₁ -C ₈ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl, C ₃ -C ₈ -cycloalkyl , C ₃ -C ₈ -cycloalkyl-C ₁ -C ₆ -alkyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -Alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ -alkoxycarbonyl, di- (C ₁ -C ₈ -alkyl) aminocarbonyl, aryl (especially Phenyl) or -CH ₂ -aryl (especially benzyl) Can be substituted, Het is thiophene, furan, pyrrole, thiazole, oxazole, imidazole, isothiazole, isoxazole, pyrazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole, 1, 3,4-triazole, 1,2,4-oxadiazole, 1,2,4-thiadiazole, 1,2,4-triazole, 1,2,3-triazole, 1,2,3 , 4-tetrazole, benzo [b] thiophene, benzo [b] furan, indole, benzo [c] thiophene, benzo [c] furan, isoindole, benzoxazole, benzothiazole, benzimidazole, benzisox Solazole, benzisothiazole, benzopyrazole, benzothiadiazole, benzotriazole, dibenzofuran, dibenzothiophene, carbazole, pyridine, pyrazine, pyrimidine, pyridazine, 1,3,5-triazine , 1,2,4-triazine, 1,2,4,5-tetrazine, quinoline, isoquinoline, quinoxaline, quinazoline, cynoline, 1,8-naphthyridine, 1,5-naphthyridine, 1 , 6-naphthyridine, 1,7-naphthyridine, phthalazine, pyridopyrimidine, purine, putridine, 4H-quinolizine, piperidine, pyrrolidine, oxazoline, tetrahydrofuran, te Lahydropyy represents a heterocyclic radical selected from the group consisting of isoxazolidine and thiazolidine, wherein the cyclic radical is unsubstituted or R ^4A , C ₁ -C ₆ -alkyl, C ₁ -C ₆ -Substituted by one or more radicals selected from the group consisting of haloalkyl, oxo, oximino and hydrazono, and the substituents oximino and hydrazono are unsubstituted parts of these or C ₁ -C ₈ -alkyl, C _3- C ₆ - alkenyl, C ₃ -C ₆ - alkynyl, C ₃ -C ₈ - cycloalkyl, C ₃ -C ₈ - cycloalkyl, -C ₁ -C ₆ - alkyl, C ₁ -C ₈ - alkoxy -C ₁ -C ₈ -alkyl, cyano-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylcarbonyl, C ₁ -C ₈ - alkoxycarbonyl, di-it can be optionally substituted with aryl (especially _{benzyl), - (C 1 -C 8} - alkyl) aminocarbonyl, aryl (especially phenyl), or -CH ₂ X ^B represents chlorine, bromine or iodine, R ^1B , R ^2B and R ^3B independently represent hydrogen or are a group

Indicates, M ^1B represents C ₁ -C ₈ -alkylene, C ₃ -C ₆ -alkenylene or C ₃ -C ₆ -alkynylene, Q ^B represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl or C ₃ -C ₆ -cycloalkyl, or a group

Indicates, T ^B represents small or -S (O) _m- , R ^4B represents hydrogen or C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl, C ₃ -C ₆ -alkynyl or C, optionally mono- to trisubstituted by fluorine and / or chlorine, respectively ₃ -C ₆ -cycloalkyl, k represents 1, 2 or 3, m represents 0, 1 or 2, L ^1B and L ^3B are independently of each other hydrogen, fluorine, chlorine, bromine, iodine, cyano, C ₁ -C ₄ -alkyl, C ₁ -C ₂ -haloalkyl, C ₁ -C ₄ -alkoxy or C _1- C ₂ -haloalkoxy, or fluorine, chlorine, bromine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy, Phenyl or phenoxy optionally mono-disubstituted by cyano or nitro, L ^2B represents C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, which represents hydrogen, fluorine, chlorine, bromine, iodine or cyano or is optionally mono- to thirteen substituted by fluorine and / or chlorine, respectively , C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl, or

Indicates, M ^2B represents oxygen or -S (O) _m- , R ^6B is each C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl or C ₃ -C ₆ -optionally substituted with fluorine and / or chlorine, respectively. Cycloalkyl or by fluorine, chlorine, bromine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro, respectively Optionally mono- to di-substituted phenyl or pyridyl, R ^2C represents hydrogen or methyl, R ^3C represents C ₁ -C ₄ -alkyl, R ^4C represents methyl, trifluoromethyl, trifluoromethoxy, fluorine, chlorine, bromine or iodine, R ^5C represents hydrogen, fluorine, chlorine, bromine, iodine, trifluoromethyl or trifluoromethoxy, R ^7C represents chlorine or bromine, R ^8C represents hydrogen, R ^9C represents trifluoromethyl, chlorine, bromine, difluoromethoxy or trifluoroethoxy, Compounds of formula (III-a) also include N-oxides and salts. (a) (1) at least one haloalkylnicotinic acid derivative of formula (Ia), (Ib) or (Ic) according to claim ₃ , wherein R ^1A represents a CF ₃ rule; or (2) at least one phthalic acid diamide of the general formula (II) (3) at least one anthranylamide of formula (III-a) according to the table below, and (b) 4-dichloroacetyl-1-oxa-4-azaspiro [4.5] -decane (AD-67, MON-4660), 1-dichloroacetylhexahydro-3,3,8a-trimethylpyrrolo [1, 2-a] -pyrimidin-6 (2H) -one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (beta) Noxacor), 1-methylhexyl 5-chloroquinoline-8-oxyacetate (cloquintocet-mexyl-also related to EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366 Compound)), 3- (2-chlorobenzyl) -1- (1-methyl-1-phenylethyl) -urea (cumyluron), α- (cyanomethoximino) phenylacetonitrile (siomethynyl) , 2,4-dichlorophenoxy acetic acid (2,4-D), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), 1- (1-methyl-1-phenylethyl)- 3- (4-methylphenyl) urea (dimuron, dimron), 3,6-dichloro-2-methoxybenzoic acid (dicamba), S-1-methyl-1-phenylethyl piperidine-1-thiocarboxylate (Dimepiperate), 2,2-dichloro-N- (2-oxo-2- (2-propenyl) Mino) ethyl) -N- (2-propenyl) acetamide (DKA-24), 2,2-dichloro-N, N-di-2-propenylacetamide (dichloromide), 4,6-dichloro 2-phenylpyrimidine (fenchlorim), ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (penchlorazole- Ethyl, see also related compounds of EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethylthiazole-5-carboxylate (flurazole), 4-chloro-N- (1,3-dioxolan-2-ylmethoxy) -α-trifluoroacetophenone oxime (fluxopenim), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazoli Dine (furylazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl, also related compounds of WO-A-95 / 07897 1- (ethoxycarbonyl) ethyl-3,6-dichloro-2-methoxybenzoate (lactidichlor), (4-chloro-o-tolyloxy) acetic acid (MCPA), 2- (4 -Chloro-o-tolyl Oxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-di Ethyl, see also related compounds of WO-A-91 / 07874), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2-propenyl-1-oxa-4-azaspiro [4.5] decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, α- (1,3-dioxolan-2-ylmethoximino) phenylacetonitrile (oxabetrinyl), 2,2-dichloro-N- (1,3-dioxolan-2-ylmethyl) -N- (2-propenyl) acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyloxazoli Dean (R-28725), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148), 4- (4-chloro-o-tolyl) butyric acid, 4- (4-chlorophenoxy) Butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl 1- (2-chlorophenyl) -5-phenyl-1H-pyrazole-3-carboxylate, ethyl 1- ( 2,4-Diclo Phenyl) -5-methyl-1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-isopropyl-1H-pyrazole-3-carboxylate, ethyl 1- (2, 4-dichlorophenyl) -5- (1,1-dimethylethyl) -1H-pyrazole-3-carboxylate, ethyl 1- (2,4-dichlorophenyl) -5-phenyl-1H-pyrazole-3- Carboxylate (see also related compounds of EP-A-269806 and EP-A-333131), ethyl 5- (2,4-dichlorobenzyl) -2-isoxazolin-3-carboxylate, ethyl 5-phenyl-2 Isoxazolin-3-carboxylate, ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazolin-3-carboxylate (see also related compounds of WO-A-91 / 08202), 1,3-dimethylbut-1-yl 5-chloroquinolin-8-oxyacetate, 4-allyloxybutyl 5-chloroquinolin-8-oxyacetate, 1-allyloxyprop-2-yl 5-chloroquinoline- 8-oxyacetate, methyl 5-chloroquinoxaline-8-oxyacetate, ethyl 5-chloroquinoline-8-oxyacetate, allyl 5-chloroquinoxaline-8-oxy Cetate, 2-oxoprop-1-yl 5-chloroquinoline-8-oxyacetate, diethyl 5-chloroquinolin-8-oxymalonate, diallyl 5-chloroquinoxaline-8-oxymalonate, di Ethyl 5-chloroquinoline-8-oxymalonate (see also related compounds of EP-A-582198), 4-carboxychroman-4-ylacetic acid (see AC-304415, EP-A-613618), 4-chloro Phenoxyacetic acid, 3,3'-dimethyl-4-methoxybenzophenone, 1-bromo-4-chloromethylsulfonylbenzene, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl]- 3-methylurea (especially N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-naphthylsulfamoyl) phenyl] -3 , 3-dimethylurea, N- (2-methoxy-5-methylbenzoyl) -4- (cyclopropylaminocarbonyl) benzenesulfonamide and / or A composition containing an effective amount of an active combination comprising as an ingredient at least one crop compatibility enhancing compound selected from the group consisting of one of the compounds of formula (IV-e) according to the table below:

Where X ^B represents iodine, R ^1B and R ^2B represent hydrogen, R ^3B is a group

Indicates, M ^1B is -CH (CH ₃ ) CH _2- , -C (CH ₃ ) ₂ CH _2- , -CH (C ₂ H ₅ ) CH _2- , -C (CH ₃ ) (C ₂ H ₅ ) CH ₂ -Or -C (C ₂ H ₅ ) ₂ CH _2- , Q ^B represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl or C ₃ -C ₆ -cycloalkyl, or a group

Indicates, T ^B represents -S-, -SO- or -SO _2- , R ^4B is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl or t-butyl, allyl, butenyl or iso, optionally mono- to trisubstituted by fluorine and / or chlorine, respectively Represent prenyl, L ^1B and L ^3B are independently of each other hydrogen, fluorine, chlorine, bromine, iodine, cyano, methyl, ethyl, n-propyl, isopropyl, t-butyl, methoxy, ethoxy, trifluoromethyl, difluoro Methoxy or trifluoromethoxy, L ^2B represents methyl, ethyl, n-propyl, isopropyl, n-butyl, iso, which represents hydrogen, fluorine, chlorine, bromine, iodine or cyano, or optionally mono- to substituted by fluorine and / or chlorine, respectively Butyl, sec-butyl, t-butyl, allyl, butenyl or isoprenyl, or a group

Indicates, M ^2B represents oxygen or sulfur, R ^6B is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, t-butyl, allyl, butenyl or iso, optionally mono- to substituted by fluorine and / or chlorine, respectively Prenyl or phenyl optionally mono-disubstituted by fluorine, chlorine, bromine, methyl, ethyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro. (a) (1) at least one haloalkylnicotinic acid derivative of formula (I-a), (I-b) or (I-c) according to the table below or (2) at least one phthalic acid diamide of formula (II) according to the table below or (3) at least one anthranylamide of formula (III-a) according to item 4, and (b) cloquintocet-mexyl, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, furylazole, fenchlorim, cumyluron, dimrone, dimepiperate and / or A composition containing an effective amount of an active combination comprising as an ingredient at least one crop compatibility enhancing compound selected from the group consisting of one of the compounds of formula (IV-e) according to the table below:

(a) (1) at least one haloalkylnicotinic acid derivative of formula (I-a), (I-b) or (I-c) according to claim 5 or (2) at least one phthalic acid diamide of formula (II) according to claim 5 or (3) at least one anthranylamide of formula (III) according to claim 4, and (b) cloquintocet-mexyl, isoxadifen-ethyl, mefenpyr-diethyl and / or A composition containing an effective amount of an active combination comprising as an ingredient at least one crop compatibility enhancing compound selected from the group consisting of compounds of the general formula (IV-e) according to the table below:

Use of a composition according to any one of claims 1 to 6 for controlling insects and / or arachnids. A method for controlling insects and / or arachnids, characterized in that the composition according to any one of claims 1 to 6 acts on insects and / or arachnids and / or their habitats.