KR20060115785A - A composition for a tire protection and a method of thereof - Google Patents

A composition for a tire protection and a method of thereof Download PDF

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Publication number
KR20060115785A
KR20060115785A KR1020050038076A KR20050038076A KR20060115785A KR 20060115785 A KR20060115785 A KR 20060115785A KR 1020050038076 A KR1020050038076 A KR 1020050038076A KR 20050038076 A KR20050038076 A KR 20050038076A KR 20060115785 A KR20060115785 A KR 20060115785A
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South Korea
Prior art keywords
tire
composition
solvent
protective film
thinner
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KR1020050038076A
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Korean (ko)
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이만수
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이만수
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Priority to KR1020050038076A priority Critical patent/KR20060115785A/en
Publication of KR20060115785A publication Critical patent/KR20060115785A/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
    • B60C13/002—Protection against exterior elements
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

Provided is a composition for a tire protective film, which imparts excellent gloss and appearance to a tire surface, and protects the lateral surface of a tire from severe conditions to improve the wear resistance of the tire. The composition for a tire protective film comprises a resin material, a thinner and a solvent in a ratio of 0.5-2:4-6:2-4. The resin material includes an urethane resin and the solvent includes at least one selected from anone, toluene and xylene. The composition is obtained by the method comprising the steps of: mixing the resin material with thinner, introducing the mixture into a container, and heating the container in a water bath at 100 deg.C or higher; and further mixing the mixture with the solvent.

Description

타이어 보호막용 조성물 및 이의 제조방법{A composition for a tire protection and a method of thereof}A composition for a tire protection and a method of manufacturing the same

본 발명은 타이어 보호막용 조성물과 그 제조방법에 관한 것으로써, 보다 상세하게는 수지원료와 침투성물질 및 용제로 이루어지는 타이어 보호막용 조성물과 이의 제조방법에 관한 것이다.The present invention relates to a composition for a tire protective film and a manufacturing method thereof, and more particularly, to a composition for a tire protective film comprising a water support material, a permeable substance and a solvent, and a method for producing the same.

일반적으로 타이어 등의 재질로 사용되는 고무의 표면은 산화열화, 자외선 열화 등의 열화를 받기 쉽고, 이로인한 크랙 등의 발생에 의해 표면 마모 등이 일어나기 쉬운 상태이다. 특히 외관이 고무재로 형성되는 타이어 등에 있어서는 옥외 사정 특히 폭설이나 폭이 좁은 도로에서의 측벽과의 마찰 주행시의 발열이나 응력 왜곡의 영향으로 인해 타이어 표면은 열화를 받기 쉽다. 이러한 것을 방지하기 위해 시판중인 타이어에서는 사전에 고무재 자체에 고무용 노화 방지제를 배합함으로써 타이어 표면의 열화를 방지하고 있다.In general, the surface of the rubber used as a material such as a tire is susceptible to deterioration such as oxidation deterioration, ultraviolet ray deterioration, and the like, and surface wear is likely to occur due to the occurrence of cracks and the like. Particularly, in tires and the like whose outer appearance is made of rubber material, the tire surface is susceptible to deterioration due to the effects of heat generation or stress distortion during frictional running with side walls in heavy snow or narrow roads. In order to prevent this, commercially available tires are prevented from deterioration of the tire surface by incorporating an anti-aging agent for rubber in the rubber material in advance.

그러나 상기와 같이 타이어에 사용되는 노화 방지제는 갈색 등으로 변색되는 것이 많고 따라서 타이어 미관의 손상을 방지할 수 없어서 타이어에 폴리싱제를 도포하여 타이어 표면에 광택까지 부여하는 것이 실행되고 있다.However, as described above, the anti-aging agent used for tires is often discolored to brown, and thus, it is not possible to prevent damage to the appearance of the tires, so that a polishing agent is applied to the tires to give gloss to the tire surface.

상기와 같은 타이어용 폴리싱제로는 폴리싱성분에 실리콘오일을 배합한 것을 사용하고 있는데, 이들은 브레이크 패드나 타이어의 접지면에 폴리싱제가 부착되는 경우에는 슬립의 원인이 될 뿐만 아니라 실리콘오일에 먼지 등 오염물질이 부착되기 쉬우며, 실리콘오일이 물에 의해 흘러내리기 쉽다는 단점이 있다.As the polishing agent for tires described above, silicone oil is blended with a polishing component, and when the polishing agent is attached to the brake pad or the ground of the tire, it causes slippage and contaminants such as dust on the silicone oil. This is easy to attach and has the disadvantage that silicone oil is easy to flow down by water.

또한 실리콘을 사용하지 않고 왁스, 수지 및 카본블랙을 물에 분산시킨 것도 있으나 이들은 도포의 연속성을 충분히 얻기 어렵기 때문에 타이어 표면의 열화를 충분히 억제할 수가 없다.In addition, waxes, resins, and carbon blacks are dispersed in water without using silicon, but they cannot be sufficiently suppressed from deterioration of the tire surface due to difficulty in obtaining sufficient continuity of coating.

상기한 바와 같은 종래기술의 문제점을 해결하고자 대한민국 공개 특허 공보 2000-34794 호에서는 아크릴산 에테르 중합체 및 또는 메타크릴산에스텔 중합체와 가스제로 이루어지는 타이어용 폴리싱 도료 조성물을 공개하고 있으나 그 조성비가 불명확 하는 등 그 실시에 있어서 의문점이 있어왔다.In order to solve the problems of the prior art as described above, Korean Unexamined Patent Publication No. 2000-34794 discloses a polishing coating composition for a tire consisting of an acrylic acid ether polymer and / or an ester of methacrylic acid polymer and a gas, but its composition ratio is unclear. There have been questions in practice.

본 발명은 상기한 바와 같은 종래기술의 문제점을 해결하기 위한 것으로서 본 발명의 목적은 타이어 표면 특히, 타이어 측면에 도포함으로써 양호한 광택이 부여되어 뛰어난 외관을 줄 수 있고 외부 이물질로부터 타이어 측면을 보호할 수 있어서 타이어의 측면 마모성능 등을 향상시킬 수 있는 타이어 보호막용 조성물과 이의 제조방법을 제공함에 있다.The present invention is to solve the problems of the prior art as described above, the object of the present invention is to apply a good gloss by applying to the tire surface, in particular, the tire side can give excellent appearance and protect the tire side from external foreign matters To provide a composition for a tire protective film and a method for manufacturing the same that can improve the side wear performance of the tire.

본 발명자는 타이어의 외관은 고무성분이므로 동종류의 수지원료를 침투성 및 배합성이 강한 신나와 배합하여 용해시킨 다음 타이어 표면의 광택 등을 위한 용제를 혼합시킴으로서 본 발명을 완성하기에 이르렀다.The inventors of the present invention have completed the present invention by mixing and dissolving this kind of water support material with thinner having high permeability and blendability, and then mixing a solvent for gloss on the surface of the tire.

따라서 본 발명은 상기한 바와 같은 본 발명의 목적을 달성하기 위하여;The present invention thus achieves the object of the present invention as described above;

수지원료 1~4kg에 대하여 신나 8~12kg과 용제 4~8kg 즉, 수지원료 : 신나 : 용제가 0.5~2 : 4~6 : 2~4의 비율로 이루어지는 타이어 보호막용 조성물을 제공한다.Provides a composition for the tire protective film consisting of a ratio of 8 to 12kg of thinner and 4 to 8kg of solvent, that is, a thinner: thinner: solvent of 0.5 to 2: 4 to 6: 2 to 4 for 1 to 4 kg of water support fee.

상기에서 수지원료로는 우레탄수지, 바람직하게는 브랜드명 ESTANS탄 5702 우레타수지를 사용함이 좋다, 상기 우레탄수지는 비료처럼 알갱이 형태의 분말이다. 여기서 수지원료가 1kg이하가 되면 너무 묽게 되고 4kg이상이 되면 용해시간이 너무 길게 되어 바람직하지 않다.As the water support material, it is preferable to use a urethane resin, preferably a brand name ESTANS Tan 5702 urethane resin. The urethane resin is a powder in a granular form like a fertilizer. If the water support fee is less than 1kg, it becomes too thin. If it is more than 4kg, the dissolution time is too long.

또한, 상기에서 신나는 브랜드명 MEK를 사용함이 좋고, 여기서 신나의 양이 8kg이하가 되면 수지원료가 완전히 용해되지 않아 나중에 타이어 외관에 본 발명품을 칠할 때 곤란한점이 생기고 12kg 이상이 되면 조성물이 너무 묽게 된다.In addition, it is good to use the exciting brand name MEK in the above, when the amount of thinner is less than 8kg, the support fee is not completely dissolved, so when the coating of the present invention on the appearance of the tire later, the difficulty arises, the composition becomes too thin when more than 12kg .

또한 상기에서 용제는 광택을 내기 위해 사용하는 것으로서 아농, 토루엔, 기시랜 중에서 1종 이상을 선택하여 사용하고 여기서의 용제의 범위는 상기에서의 이유와 같다.In addition, the solvent used in the above to select the one or more selected from among ananone, toluene, gishiran as used to gloss, the range of the solvent here is the same as the above reason.

본 발명은 또한,The present invention also provides

상기한 바와 같은 수지원료와 신나를 혼합한 다음 용기에 넣고 이 용기를 물이 채워진 철제의 또다른 용기에 넣고 100℃이상으로 1.5~3시간 가열시켜 완전히 용해한 후 용제를 상기 비율로 배합하여 완성되는 타이어 보호막용 조성물의 제조방법을 제공한다.Mix the water support material and thinner as described above, put it in a container, put it in another container filled with water, heat it to 100 ° C or higher for 1.5 to 3 hours, completely dissolve it, and then mix the solvent at the above ratio. It provides a method for producing a composition for tire protective film.

상기에 알 수 있듯이 수지 원료와 신나의 혼합물은 직접 불에 닿으면 위험하므로 간접 가열하여 용해시킴이 바람직하다.As can be seen from the above, since the mixture of the resin raw material and the thinner is dangerous when directly exposed to fire, it is preferable to dissolve it by indirect heating.

여기에서의 가열시간은 혼합물이 충분히 용해되는 시간으로서 상기의 범위가 가장 바람직한 것으로 실험되었다.The heating time here was the time when the mixture was sufficiently dissolved, and the above range was tested as the most preferable.

[실시예]EXAMPLE

18ℓ짜리의 1통을 만들기 위해 브랜드명 ESTANS탄 5702 우레탄 수지 2kg에 브랜드명 MEK신나를 10kg을 혼합시킨 다음 이 혼합물을 스테인레스 용기에 담는다. 한편 스테인레스의 또다른 용기에 물을 넣고 이 용기의 물속으로 혼합물이 들어있는 스테인레스 용기를 위치시킨 다음 또다른 용기내의 물을 100℃이상으로 가열시켜 약 2시간 10분 정도 유지시켰다. 이 시간 후 스테인레스 내의 혼합물이 완전히 용해된 것을 확인한 후 냉각시키고 신나의 냄새를 중화시키고 광택용으로 아농을 6kg 배합시킴으로서 본 발명의 타이어 보호막 조성물을 얻었다.To make 1 bottle of 18 liters, 10 kg of MEK Thinner is mixed with 2 kg of brand name ESTANS Tan 5702 urethane resin, and the mixture is placed in a stainless container. Meanwhile, water was placed in another stainless steel container, and a stainless steel container containing the mixture was placed in the water of the stainless steel container, and the water in the other container was heated to 100 ° C. or more and held for about 2 hours and 10 minutes. After this time, after confirming that the mixture in the stainless was completely dissolved, the tire protective film composition of the present invention was obtained by cooling, neutralizing the smell of the thinner, and blending 6 kg of Arnone for polishing.

상기와 같은 본 발명의 타이어 보호막 조성물은 그 자체로 타이어 측면에 칠해 사용하면 타이어 본래의 색상을 광택 있게 보호하면서 외부의 이물질에 의한 손상을 방지할 수 있다.The tire protective film composition of the present invention as described above can be applied to the side surface of the tire as it is to protect the original color of the gloss of the tire while preventing damage caused by foreign matter.

또한 원료 자체가 타이어와 같은 고무성분이므로 혹한기에도 타이어 측면의 크랙을 방지할 수 있는 것이다.In addition, since the raw material itself is a rubber component such as a tire, it is possible to prevent cracks on the side of the tire even in cold weather.

본 발명의 타이어 보호막용 조성물을 색상이 있게 사용하고자 할 경우에는 본 발명의 조성물이 투명한 것이므로 원하는 색상을 첨가하여 사용할 수도 있다. 이 경우에는 용제에 안료를 섞어 사용한다.When the composition for a tire protective film of the present invention is intended to be used in color, the composition of the present invention may be used because it is transparent. In this case, use a mixture of pigments in the solvent.

상기와 같은 본 발명은 타이어의 측면은 물론 가죽이나 또 다른 고무제품의 외부를 보호하기 위해 사용할 수도 있다.The present invention as described above may be used to protect the outside of the tire as well as leather or another rubber product.

상기한 바와 같은 본 발명에 따르면, 타이어의 성분과 같은 고무성분인 수지를 원료로 하여 사용하므로 타이어의 측면은 물론 기타의 고무제품이나 가죽제품의 외면을 미려하게 보호할 수 있고 특히 타이어의 경우 그 측면에 칠하므로서 혹한기나 악조건 하에서 측면이 마모되는 것을 방지함과 동시에 광택을 유지시킬 수 있어서 타이어의 내구성을 오래 유지시킬 수 있을 뿐 아니라 다양한 색상의 안료를 혼합하여 사용할 수도 있어서 소비자의 기대를 충족시킬 수 있게 된다.According to the present invention as described above, since the resin is used as a rubber component such as the tire component as a raw material can be beautifully protected not only the side of the tire but also the outer surface of other rubber or leather products, especially in the case of tires By painting on the side, it prevents the side from being worn under cold or bad conditions and maintains its gloss, which not only keeps tires durable, but also mixes pigments of various colors to meet consumer expectations. It becomes possible.

Claims (5)

타이어 보호막용 조성물로서, 수지원료 : 신나 : 용제가 0.5~2 : 4~6 : 2~4의 비율로 혼합됨을 특징으로 하는 타이어 보호막용 조성물.A composition for a tire protective film, wherein the composition for tire protective film is characterized in that the water support fee: thinner: solvent is mixed at a ratio of 0.5 to 2: 4 to 6: 2 to 4. 제 1 항에 있어서, 상기 수지원료는 우레탄 수지이고 상기 용제는 아농, 토루엔 및 기시랜 중 1종 이상임을 특징으로 하는 타이어 보호막용 조성물.The composition of claim 1, wherein the water support material is a urethane resin and the solvent is at least one of ananone, toluene, and gishiran. 타이어 보호막용 조성물의 제조방법에 있어서, In the method for producing a composition for a tire protective film, 수지원료 : 신나를 0.5~2 : 4~6의 비율로 혼합한 다음 용기에 넣고 물이 채워진 또다른 용기 위치 시켜 100℃ 이상의 끓는 물에 1.5~3시간 가열시킨 후 수지원료 : 신나의 비율 대비 2~4의 비율로 용제를 혼합함을 특징으로 하는 타이어 보호막용 조성물의 제조방법.Subsidiary Fee: Mix the thinner at the ratio of 0.5 ~ 2: 4 ~ 6, put it in the container and place another container filled with water and heat it in boiling water over 100 ℃ for 1.5 ~ 3 hours. A method for producing a composition for a tire protective film, characterized in that the solvent is mixed at a ratio of ˜4. 상기 수지원료는 우레탄이며 상기 용제는 아농, 토루엔 및 기시랜 중 1종 이상임을 특징으로 하는 타이어 보호막용 조성물의 제조방법.The water support fee is urethane and the solvent is a method for producing a composition for a tire protective film, characterized in that at least one of anon, toluene and gishiran. 제 3 항에 있어서 상기 용기는 철제 용기임을 특징으로 하는 타이어 보호막용 조성물의 제조방법.4. The method of claim 3, wherein the container is an iron container.
KR1020050038076A 2005-05-06 2005-05-06 A composition for a tire protection and a method of thereof KR20060115785A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100934567B1 (en) * 2008-03-31 2009-12-30 금호타이어 주식회사 Tire Coating Composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100934567B1 (en) * 2008-03-31 2009-12-30 금호타이어 주식회사 Tire Coating Composition

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