KR20050095035A - An advanced porous concrete - Google Patents
An advanced porous concrete Download PDFInfo
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- KR20050095035A KR20050095035A KR1020040020045A KR20040020045A KR20050095035A KR 20050095035 A KR20050095035 A KR 20050095035A KR 1020040020045 A KR1020040020045 A KR 1020040020045A KR 20040020045 A KR20040020045 A KR 20040020045A KR 20050095035 A KR20050095035 A KR 20050095035A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/0481—Other specific industrial waste materials not provided for elsewhere in C04B18/00
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/08—Slag cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/08—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4857—Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
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Abstract
본 발명은 고기능성 포러스 콘크리트에 관한 것으로 좀더 상세히는 포러스 콘크리트를 포설하고 그 포설된 콘크리트 표면에 SBR 라텍스 고무, NBR 등의 합성고무 또는 천연고무, SBS 에멀젼을 유화아스팔트에 혼합하여 0.1~10ℓ/㎡의 양으로 산포하여 제조되는 고기능성 포러스 콘크리트에 관한 것이다.The present invention relates to high-functional porous concrete, and more specifically, to install porous concrete and to the surface of the concrete, SBR latex rubber, synthetic rubber such as NBR or natural rubber, and SBS emulsion by mixing 0.1 to 10 l / ㎡ The present invention relates to a highly functional porous concrete produced by scattering in an amount of.
Description
본 발명은 고기능성 포러스 콘크리트에 관한 것으로 좀더 상세히는 포러스 콘크리트를 포설하고 그 포설된 콘크리트 표면에 SBR 라텍스 고무, NBR 등의 합성고무 또는 천연고무, SBS 에멀젼을 유화아스팔트에 혼합하여 0.1~10ℓ/㎡의 양으로 산포하여 제조되는 고기능성 포러스 콘크리트에 관한 것이다.The present invention relates to high-functional porous concrete, and more specifically, to install porous concrete and to the surface of the concrete, SBR latex rubber, synthetic rubber such as NBR or natural rubber, and SBS emulsion by mixing 0.1 to 10 l / ㎡ The present invention relates to a highly functional porous concrete produced by scattering in an amount of.
통상 종래의 도로포장은 불투수성인 아스팔트 또는 콘크리트 포장으로 되어 있다. 그런데, 이러한 불투수성 포장은 강우시 빗물이 도로에 잔류하여 교통에 장애가 되며, 차량 제동시 미끄러지는 문제점이 있어 사고의 위험을 증가시킨다. 또한, 빗물이 지하로 침투되지 못하여 하천을 범람시키는 원인이 되는 등 여러 가지 문제점이 있다.Conventional road pavement is usually an impermeable asphalt or concrete pavement. However, such an impervious pavement has a problem in that rainwater remains on the road during rainfall, which impedes traffic, and there is a problem of slipping when braking the vehicle, thereby increasing the risk of an accident. In addition, there are various problems such as rainwater does not penetrate underground, causing flooding of rivers.
또한, 도시가 증가, 확장되면서 아스팔트, 콘크리트 포장으로 수분이 자연적으로 땅속으로 침투하는 것을 막게 되어 지하수량이 급격히 감소하고 이로 인하여 지반 침하, 수목의 발육 둔화, 생태 변화가 일어난다. 따라서 도로 포장시 우수가 지층으로 침투될 수 있는 시공 방법이 고려되어야 한다. 종래 도시개발 및 조경공사를 함에 있어서 빗물을 지중으로 침투시킬 목적으로 다양한 투수성 포장이 개발되어 왔다.In addition, as the city expands and expands, it prevents water from penetrating into the ground naturally with asphalt and concrete pavements, which causes a rapid decrease in the amount of groundwater, resulting in ground subsidence, slowing the growth of trees, and ecological changes. Therefore, construction methods that can infiltrate rainwater into the strata should be considered. Various permeable pavements have been developed for the purpose of infiltrating rainwater into the ground in urban development and landscaping.
기존의 투수성 콘크리트의 경우에는 투수성 아스팔트와 같이 기후에 따른 변성은 일어나지 않으나 먼지 등의 오염원에 의하여 공극이 쉽게 막히며, 투수성 아스팔트에 비하여 표면 탈리현상이나 소음이 크고 미끄럼 저항이 낮아 제동거리가 길어, 특히 빗길 등에서 사고의 위험이 따르는 문제점이 있고, 강도가 약해 일반 도로에 사용하는 데 한계가 있다.Conventional water-permeable concrete does not occur due to climate change, like water-permeable asphalt, but pores are easily blocked by pollution sources such as dust, and have a higher surface detachment or noise and lower sliding resistance than water-permeable asphalt. There is a problem that the risk of accidents, especially in the rain, such as long, there is a limit to use on a general road due to the weak strength.
상기 문제점을 해결하기 위하여 본 발명은 포러스 콘크리트를 포설하고 그 표면에 천연고무 또는 합성고무 등을 함유하는 유화아스팔트 혼합물을 산포하여 투수성은 유지하면서도 표면탈리현상을 방지하고 소음감소 효과와 미끄럼 저항을 높이는 포러스 콘크리트를 제공하는 것을 목적으로 한다.In order to solve the above problems, the present invention distributes emulsified asphalt mixture containing natural rubber or synthetic rubber on the surface of the porous concrete and prevents surface detachment while maintaining water permeability and improving noise reduction effect and sliding resistance. It is an object to provide porous concrete.
또한, 본 발명의 다른 목적은 포러스 콘크리트의 표면에 산포시 콘크리트 기공의 막힘현상이 없이 공극이 그대로 유지되며, 표면탈리현상이 현저히 저감되고 소음방지효과가 미끄럼저항을 높이는 천연고무 또는 합성고무를 함유한 유화아스팔트 혼합물을 제공하는 것이다. In addition, another object of the present invention is to maintain the voids without clogging of the concrete pores when sprayed on the surface of the porous concrete, the surface desorption phenomenon is significantly reduced and the noise prevention effect contains a natural rubber or synthetic rubber to increase the sliding resistance One emulsified asphalt mixture is provided.
상기 목적을 달성하기 위하여 본 발명자는 기존의 포러스 콘크리트를 포설하고 표면에 천연고무 또는 합성고무 등을 함유한 유화아스팔트 혼합물을 산포하여 포러스 콘크리트의 공극은 그대로 유지되면서 소음과 표면 탈리현상 등을 감소시킨 포러스 콘크리트를 제조하였다. 제조된 포러스 콘크리트는 45kgf/㎠ 이상의 휨강도와 15%이상의 공극율을 나타내었다.In order to achieve the above object, the present inventors laid down existing porous concrete and scattered emulsion asphalt mixture containing natural rubber or synthetic rubber on the surface to reduce noise and surface detachment while maintaining voids of the porous concrete. Porous concrete was prepared. The produced porous concrete showed flexural strength of more than 45kgf / ㎠ and porosity of more than 15%.
본 발명은 유화아스팔트에 양이온화시킨 SBR 라텍스 고무, NBR, 클로로프렌고무, 폴리부타디엔고무, 에틸렌프로필렌고무, 아크릴고무, 이소프렌-이소부틸고무, 천연고무 및 SBS 에멀젼으로 이루어진 그룹 중에서 선택된 1종 이상을 고형분기준 0.1~50중량% 혼합한 유화아스팔트 혼합물에 관한 것이다The present invention is a solid content of at least one selected from the group consisting of SBR latex rubber, NBR, chloroprene rubber, polybutadiene rubber, ethylene propylene rubber, acrylic rubber, isoprene-isobutyl rubber, natural rubber and SBS emulsion cationicly emulsified in the emulsion It is about emulsion emulsion asphalt mixture which mixed standard 0.1-50 weight%
상기 유화아스팔트의 예로는 동남유화의 유화아스팔트 QSC, 인성산업의 RSC-3, RSC-4, QRS-4, CRS-2P 또는 한국석유공업의 RSC-1, RSC-2, RSC-3, RSC-4 또는 QSC 등을 사용하였다.Examples of the above-mentioned emulsified asphalt include Southeast Emulsified Asphalt QSC, Insung Industries 'RSC-3, RSC-4, QRS-4, CRS-2P or Korea Petroleum Industries' RSC-1, RSC-2, RSC-3, RSC- 4 or QSC or the like was used.
또한, 본 발명은 포설 후 양생이 끝난 포러스 콘크리트 표면에 양이온화시킨 SBR 라텍스 고무, NBR, 클로로프렌고무, 폴리부타디엔고무, 에틸렌프로필렌고무, 아크릴고무, 이소프렌-이소부틸고무, 천연고무 및 SBS 에멀젼으로 이루어진 그룹 중에서 선택된 1종 이상을 고형분기준 0.1~50중량%로 유화아스팔트에 혼합한 유화아스팔트 혼합물을 0.1~10ℓ/㎡의 양으로 산포하여 제조하는 고기능성 포러스 콘크리트에 관한 것이다. In addition, the present invention is composed of SBR latex rubber, NBR, chloroprene rubber, polybutadiene rubber, ethylene propylene rubber, acrylic rubber, isoprene-isobutyl rubber, natural rubber and SBS emulsion cationized on the surface of the porous concrete after curing The present invention relates to a highly functional porous concrete produced by dispersing an emulsion asphalt mixture obtained by mixing at least one selected from the group in an amount of 0.1 to 50 wt% based on solid content in an amount of 0.1 to 10 l / m 2.
또한, 본 발명은 상기 포러스 콘크리트가 1㎥당 250∼400kg/㎥ 포오틀랜드 시멘트 또는 조강시멘트, 60∼160kg/㎥ 물, 조골재 1000~1900kg/㎥, 세골재 또는 모래 50~500kg/㎥, AE감수제, 나프탈린계 고성능 감수제, 합성고무 SBR 라텍스, NBR, 아크릴계수지, 에폭시수지 및 섬유질 보강제로 이루어지는 그룹 중에서 선택된 1종 이상인 혼화제 0.1∼60kg/㎥ 및 SiO2, CaO, SO2 또는 실리카 흄 중 1종이상인 바인더 0.1∼60kg/㎥를 투입하여 배합되는 것을 특징으로 한다.In addition, the present invention is the porous concrete 250 ~ 400kg / ㎥ Polandland cement or crude steel cement, 1 ~ 60 ~ 160kg / ㎥ water, crude aggregate 1000 ~ 1900kg / ㎥, fine aggregate or sand 50 ~ 500kg / ㎥, AE water reducing agent per 1㎥ At least one selected from the group consisting of naphthalene-based high performance water sensitizers, synthetic rubber SBR latex, NBR, acrylic resins, epoxy resins and fiber reinforcing agents and at least one of SiO 2 , CaO, SO 2 or silica fume It is characterized in that it is compounded by adding 0.1 to 60kg / ㎥ of merchant binder.
또한, 본 발명은 상기 포오틀랜드 시멘트 또는 조강시멘트 사용중량에 대하여 0~60중량%를 고로슬래그 시멘트로 치환하여 사용하는 것을 특징으로 한다.In addition, the present invention is characterized by using 0 to 60% by weight of blast furnace slag cement with respect to the portland cement or crude cement used weight.
뿐만 아니라, 본 발명은 긴급보수시에는 상기 포오틀랜드시멘트 또는 조강시멘트를 초속경시멘트 또는 초조강시멘트로 치환하여 사용하는 것을 특징으로 한다.In addition, the present invention is characterized in that the portland cement or the crude steel cement to replace the cemented carbide cement or super-tight steel cement for emergency repair.
나아가, 본 발명은 상기 골재가 기존포장의 폐재로부터 얻은 재생골재를 전체사용량의 0~100중량%로 사용하는 것을 특징으로 한다.Furthermore, the present invention is characterized in that the aggregate is used from 0 to 100% by weight of the total aggregate recycled aggregate obtained from the waste of the existing packaging.
본 발명에서 포러스 콘크리트의 포설방법은 공지의 방법으로 시공하는 것으로서 시공장소와 목적에 따라 다양한 방법으로 기층 및 휠터층공사 등을 수행한다.In the present invention, the method of laying the porous concrete is to be constructed by a known method, and the substrate and the filter layer construction are performed in various ways according to the factory and the purpose.
그리고, 사용되는 골재는 19mm체의 통과 중량 백분율이 100%이고 13mm체의 통과 중량 백분율이 90∼100%이며 5mm체의 통과 중량 백분율이 5∼40%의 입도분포를 가지는 골재, 13mm체의 통과 중량 백분율이 100%이고 10mm체의 통과 중량 백분율이 90∼100%이며 5mm체의 통과 중량 백분율이 5∼40%의 입도분포를 가지는 골재 또는 10㎜체의 통과 중량 백분율이 100%이고 8mm체의 통과 중량 백분율이 90∼100%이며 5mm체의 통과 중량 백분율이 5∼40%의 입도분포를 가지는 골재 중 1종 이상을 사용한다.In addition, the aggregate used is the aggregate weight percentage of the 19mm sieve 100%, the passing weight percentage of the 13mm sieve is 90-100%, the passing weight percentage of the 5mm sieve has a particle size distribution of 5-40%, the passage of 13mm sieve The percentage by weight of 100 mm, 10 mm sieve is 90-100%, the weight percentage of 5 mm sieve has a particle size distribution of 5-40%, or the aggregate weight percentage of 10 mm sieve is 100% and 8 mm sieve At least one of the aggregates having a particle size distribution of 5 to 40% by weight percentage of the passage weight of 90 to 100% and 5 mm sieve is used.
이하, 본 발명의 실시예를 통하여 구체적으로 설명한다. 그러나, 본 발명의범위가 실시예에 한정되는 것은 아니다.Hereinafter, the embodiment of the present invention will be described in detail. However, the scope of the present invention is not limited to the examples.
<실시예 1><Example 1>
최대치수 13㎜인 골재 1550kg/㎥, 포오틀랜드 시멘트 340kg/㎥, 물 100kg/㎥ 혼화재 및 바인더 33kg/㎥를 배합한 포러스 콘크리트 포설하고 그 표면에 양이온화시킨 SBR 라텍스 고무, NBR, 클로로프렌고무, 폴리부타디엔고무, 에틸렌프로필렌고무, 아크릴고무, 이소프렌-이소부틸고무, 천연고무 및 SBS 에멀젼으로 이루어진 그룹 중에서 선택된 1종 이상을 고형분기준 0.1~50중량% 유화아스팔트에 혼합한 유화아스팔트 혼합물을 0.1~10ℓ/㎡의 양으로 산포하여 고기능성 포러스 콘크리트를 시공하였다.SBR latex rubber, NBR, chloroprene rubber, which was placed on a surface of porous concrete mixed with 1550kg / ㎥ of aggregates with a maximum dimension of 13mm, 340kg / ㎥ of Portland cement, and 100kg / ㎥ of water admixture and 33kg / ㎥ of binder. 0.1-10 l of an emulsified asphalt mixture, in which at least one selected from the group consisting of polybutadiene rubber, ethylene propylene rubber, acrylic rubber, isoprene-isobutyl rubber, natural rubber and SBS emulsion is mixed in 0.1 to 50% by weight emulsion asphalt based on solid content Scattered in an amount of / ㎡ to construct a high functional porous concrete.
<비교예 1>Comparative Example 1
개질제 조성물 총 중량에 대하여 SBS 60.5중량%, 저온개선제 16.2 중량%, 점착부여제 22.0중량%, 자외선흡수제 0.3중량%, 열노화방지제 1.0중량%를 함유하는 고점도아스팔트 개질재 6㎏과 아스팔트 AP5 44㎏, 13㎜골재 807㎏, 모래 95㎏, 필러 47㎏을 185℃로 가열, 혼합한 포러스 아스팔트를 포설, 시공하였다.6 kg of high-viscosity asphalt modifier containing 60.5 wt% of SBS, 16.2 wt% of low temperature improver, 22.0 wt% of tackifier, 0.3 wt% of UV absorber, 1.0 wt% of heat aging inhibitor and 44 kg of asphalt AP5. , 807 kg of 13 mm aggregate, 95 kg of sand and 47 kg of filler were heated and mixed at 185 ° C. to form asphalt asphalt.
<비교예 2>Comparative Example 2
최대치수 13㎜인 골재 1550kg/㎥, 포오틀랜드 시멘트 340kg/㎥, 물 100kg/㎥ 혼화제 및 바인더 33kg/㎥를 배합한 포러스 콘크리트를 포설, 시공하였다.Porous concrete containing 1550 kg / m3 aggregate with a maximum dimension of 13 mm, 340 kg / m3 of Portland cement, 100 kg / m3 water admixture and 33 kg / m3 of binder was installed and constructed.
<실험예>Experimental Example
동일한 공극률을 가지며 유화아스팔트 혼합물을 산포한 포러스 콘크리트(실시예1), 산포하지 않은 포러스 콘크리트(비교예2)와 포러스 아스팔트(비교예1)에 대하여 동일 조건하에서 최대마모정도, 소음, 마찰계수 및 투수계수 등을 측정하여 하기 표 1에 나타내었다. 측정결과, 마모정도는 비교예 2의 포러스 콘크리트와 유사하며 소음 및 마찰계수는 비교예 1의 포러스 아스팔트와 동일한 것을 확인하였다. 또한, 투수계수가 비교예 1, 2와 유사한 것으로부터 유화아스팔트 혼합물의 산포에 따른 공극막힘 현상이 발생하지 않고 공극이 그대로 유지되는 것을 확인하였다.The maximum wear, noise, coefficient of friction and the same for the porous concrete with the same porosity and the dispersion of emulsion asphalt mixture (Example 1), unspread porous concrete (Comparative Example 2) and porous asphalt (Comparative Example 1) Permeability coefficients are measured and shown in Table 1 below. As a result, the degree of wear was similar to that of the porous concrete of Comparative Example 2, and the noise and friction coefficients were the same as those of the porous asphalt of Comparative Example 1. In addition, the permeability coefficient was similar to that of Comparative Examples 1 and 2, and it was confirmed that the voids were not generated due to the dispersion of the emulsion asphalt mixture, and the voids were maintained as they were.
본 발명에 의해 제조된 포러스 콘크리트는 표면을 합성 고무 또는 천연고무가 함유된 유화아스팔트 혼합물로 코팅하므로 기존의 포러스 콘크리트와 마모율은 유사하나 미끄럼 마찰저항과 소음저감 효과 및 표면탈리 방지효과가 뛰어나 차도용으로 사용가능한 고기능성 포러스 콘크리트로 제공할 수 있다.Since the porous concrete prepared by the present invention is coated with an emulsified asphalt mixture containing synthetic rubber or natural rubber, the wear rate is similar to that of the existing porous concrete, but the sliding friction resistance, noise reduction effect, and surface detachment prevention effect are excellent. It can be provided with high functional porous concrete which can be used as
또한, 본 발명에 의해 제조되는 포러스 콘크리트는 기존의 포러스 아스팔트보다 표면 마모율과 온도나 충격에 의한 변형율이 매우 낮아 포러스 아스팔트의 단점을 극복한 포러스 콘크리트를 제공할 수 있다.In addition, the porous concrete produced according to the present invention can provide a porous concrete that overcomes the disadvantages of the porous asphalt is very low surface wear rate and strain due to temperature or impact than conventional porous asphalt.
또한, 본 발명은 포설된 포러스 콘크리트의 공극막힘 현상이 없이 공극을 그대로 유지하면서 포러스 콘크리트의 기능을 강화하는 유화아스팔트 혼합물을 제공할 수 있다.In addition, the present invention can provide an emulsified asphalt mixture that enhances the function of the porous concrete while maintaining the voids without the pore clogging phenomenon of the installed porous concrete.
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KR100731614B1 (en) * | 2006-11-28 | 2007-06-25 | 주식회사 스페이스 | Waterproof agent and construction method using the agent |
KR100774448B1 (en) * | 2006-06-22 | 2007-11-08 | (주)삼우아이엠씨 | Latex modified concrete composition using high early strength cement |
KR100778528B1 (en) * | 2006-09-29 | 2007-11-29 | 주식회사 유로바이탈스톤 | Method for manufacturing artificial marble |
KR100884355B1 (en) * | 2008-06-10 | 2009-02-17 | 양희용 | Concrete composite contained textile polymer, concrete cross surface pavement using it and repair method of concrete structure |
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CN105907020B (en) * | 2016-04-21 | 2018-10-26 | 天津市公路工程总公司 | Not viscous wheel modified emulsifying asphalt and preparation method thereof |
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KR100774448B1 (en) * | 2006-06-22 | 2007-11-08 | (주)삼우아이엠씨 | Latex modified concrete composition using high early strength cement |
KR100778528B1 (en) * | 2006-09-29 | 2007-11-29 | 주식회사 유로바이탈스톤 | Method for manufacturing artificial marble |
KR100731614B1 (en) * | 2006-11-28 | 2007-06-25 | 주식회사 스페이스 | Waterproof agent and construction method using the agent |
KR100884355B1 (en) * | 2008-06-10 | 2009-02-17 | 양희용 | Concrete composite contained textile polymer, concrete cross surface pavement using it and repair method of concrete structure |
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