KR20050017511A - Soap composition and preparing method using the same - Google Patents

Abstract

PURPOSE: Provided is soap composition comprising plutonic granite with optimum particle distribution as main component to greatly increase surface of the granite contacting skin and efficiently transfer heat to the skin and render smooth material exchanger between cells, thereby resulting in excellent skin cosmetic and protection effects. CONSTITUTION: The soap composition comprises 92-99 wt.% of soap base and 1-8 wt.% of plutonic granite powder having 0.3-2.0 micrometers of particle size range, 0.5-1.5 micrometers of average particle size and D(V)50 (50% of particle volume distribution) = 0.8-1.2 micrometers. The plutonic granite powders 70-80 wt.% SIO2, 8-16 wt.% AL2O3, 0.1-5 wt.% FE2O3, 3.5-4.5 wt.% K2O, 2-3 wt.% NA2O, 1.5-2.5 wt.% CAO, 0.5-1.0 wt.% MGO and the balance of trace components including germanium. The soap composition is prepared by mixing soap base : plutonic granite powders : water = 5-7 : 1 : 5-7; heating the mixture at 110-130 deg.C for 10 minutes to 1 hour then gradually cooling to obtain solid material; breaking the material into chips; extruding the chips through extruder at 92-98 deg.C then forming into soap product.

Description

Soap composition and manufacturing method of soap using the same {SOAP COMPOSITION AND PREPARING METHOD USING THE SAME}

      The present invention provides a soap composition and a soap using the same that the skin efficiently absorbs the heat source of the air and affects the molecular density of moisture in the skin, thereby facilitating the exchange of substances between cells and providing excellent skin beauty and skin protection effects. It relates to a method for the preparation of, and more specifically, to the normal soap base to add a thick granulated granite powder having an average particle diameter of 0.5 ~ 1.5㎛, so that the weight ratio of the normal soap material: the thick granite powder is 92 ~ 99: 1-8. It relates to a soap composition characterized in that the configuration and a method for producing a soap using the same.

       In general, soaps can be roughly classified into cosmetic soaps for removing dead cell layers, dead skin layers, and external contaminants, and laundry soaps for removing stains on clothes. Usually, soaps are mainly composed of alkali metal salts of higher fatty acids. It is broadly understood to include all metal salts of higher fatty acids, and are classified into cosmetic soaps, laundry soaps, powder soaps, medicinal soaps, water soaps, cream soaps, paper soaps, bath soaps, beauty soaps, and the like according to their use and form.

       Recently, various types of cosmetic soap have been proposed according to its beauty function and shape, but most of them are focused on the inherent cleaning effect and beauty function of soap, and their biological activity or physiology by various actions on the skin. Very few soaps expressing an active effect have been proposed. In addition, most conventional soaps have a high possibility of causing environmental pollution such as water pollution since alkali metal salts and surfactants of higher fatty acids are used as the main ingredients, and in addition to cleaning functions, cosmetic functions such as skin moisturizing and skin protection are reinforced. Due to the large amount of various additives to be used, there is a concern that the cleaning effect may be lowered, as well as the risk of intensifying water pollution increases.

      As a conventional method for solving such a problem, the patent registration No. 10-0249928 (filed date: Dec. 22, 1997) by the present inventor is a soap material: granular granite with a particle size of 325 mesh (ie, particle size of 8 ~ 10㎛) Although a soap composition and a method of preparing the same have been proposed in which the weight ratio of the powder is 20 to 90:10 to 80, in order to obtain sufficient far-infrared radiation effect and ultraviolet ray blocking effect, the content of mental granite is inevitably increased. Due to the large particle size of granite, there is a serious problem that the feeling of inferior use and difficulty in manufacturing are caused, and there is a serious problem that clogging the sweat glands of the skin and causing skin trouble. It is necessary to use, and since the granite granules used are relatively large in particle size, their relative weight is also large, There were serious problems with the quality of that increasingly ubiquitous downward.

Therefore, the present inventors have made various and extensive research efforts to solve the above-mentioned problems. As a result, the granular granite powder has a particle diameter of 0.3-2.0 μm, an average particle diameter of 0.5-1.5 μm, and d ( v) ₅₀ (50% of the particle volume distribution) = 0.8 ~ 1.2㎛ can greatly reduce the amount of plutonite granite powder, but the far-infrared radiation effect is not only superior but also the usability is greatly improved and skin trouble As a result of discovering that the cause of concern can be avoided and based on this, the present invention has been completed.

      Therefore, the first object of the present invention is to allow the skin to efficiently absorb the heat source of the air, and to affect the molecular density of moisture in the skin, thereby facilitating the exchange of intercellular substances, thereby providing excellent skin beauty and skin protection effect and The present invention is to provide a soap composition having a function of activating free active energy and alleviating a concern about environmental pollution, but having a good feeling without deterioration of cleaning power and having no concern for skin troubles.

      A second object of the present invention is to provide a method for producing a soap using the soap composition according to the first object described above.

According to one preferred aspect of the present invention for smoothly achieving the first object according to the present invention, it is in the range of 92 to 99% by weight of a normal soap base and 0.3 to 2.0 µm in particle size, with an average particle diameter of 0.5 A soap composition is provided, characterized in that it is composed of 1 to 10% by weight of deep granulated granite powder having a ˜1.5 μm, and d (v) ₅₀ (50% of the particle volume distribution) = 0.8 to 1.2 μm.

      According to a preferred aspect of the present invention for smoothly achieving the second object according to the present invention, a conventional soap base: a thick granite powder having the above-described particle distribution: water = 5-7: 1: 5-7 Into the reactor under normal pressure by weight ratio, heated at a temperature of 110 ~ 130 ℃ for 10 minutes ~ 1 hour and then cooled slowly to obtain a solid, pulverized and prepared into a soap chip (chip), and then put into an extruder 92 ~ 98 After extruding at a temperature of ℃, it is put into a conventional soap manufacturing apparatus and molded, or the ordinary granulated granite powder having a conventional soap material base chip and the above-described particle size distribution in a vacuum extruder and extruded at 92 ~ 98 ℃, There is provided a method for producing soap, characterized in that by cutting a new chip, putting it in a conventional soap manufacturing apparatus and injection molding.

      Hereinafter, the present invention will be described in more detail.

The soap composition of the present invention is in the range of 92 to 99% by weight of a conventional soap base (which may include other functional components or perfume components) and 0.3 to 2.0 µm in particle size, and 0.5 to 1.5 µm in average particle size, d (v ) ₅₀ (50% of the particle volume distribution) = 0.8 ~ 1.2㎛ agglomerated granite powder 1 ~ 10% by weight.

The deep granite used in the present invention is SiO ₂ 70 ~ 80wt%, Al ₂ O ₃ 8 ~ 16wt%, Fe ₂ O ₃ 0.1 ~ 5wt%, K ₂ O 3.5 ~ 4.5wt%, Na ₂ O 2 ~ 3wt%, CaO 1.5 ~ 2.5wt%, MgO 0.5 ~ 1.0wt% and the balance is composed of trace components containing germanium.

Specifically, SiO ₂ 79.76wt%, Al ₂ O ₃ 9.87wt%, Fe ₂ O ₃ 0.21wt%, K ₂ O 3.79wt%, Na ₂ O 2.81wt%, CaO 1.59wt%, MgO 0.86wt% and Germanium It is a deep granite composed of a trace component 1.11wt% containing SiO ₂ 73.41wt%, Al ₂ O ₃ 14.56wt%, Fe ₂ O ₃ 1.13wt%, K ₂ O 4.13wt%, Na ₂ O 2.48wt% , A deep granite composed of 2.28 wt% CaO, 0.72 wt% MgO and 1.29 wt% of minor components including germanium, or 73.53 wt% SiO _2, 12.52 wt% Al ₂ O _3, 4.76 wt% Fe ₂ O ₃ , K ₂ O 3.78wt%, Na ₂ O 2.07wt%, CaO 1.56wt%, MgO 0.51wt% and a granite granite consisting of a trace component 1.27wt% containing germanium can be preferably used, and the intended and intended It may be desirable to select and use at least one or more of these three types of astral granulation.

      In the deep granite, the germanium content is in the range of 0.5 to 2 ppm.

      The deep granite which can be preferably used in the present invention is that the pure magma in the crust is cooled in the reduced state, each having a unique color, and the color is a unique color formed by cooling the high temperature magma of 4000 ° C. or higher, and the far-infrared emissivity is It is more than 0.90.

The deep granite used in the present invention has a particle diameter in the range of 0.3 to 2.0 µm, an average particle diameter of 0.5 to 1.5 µm, d (v) ₅₀ (50% of the particle volume distribution) = 0.8 to 1.2 µm, and a particle diameter of less than 0.3 µm. It is not preferable to use it because it is not economical and if the particle diameter exceeds 2.0 mu m, the feeling of use becomes inferior.

      In the present invention, the amount of the conventional granite powder having the above-described particle size distribution for the normal soap base is added in a weight ratio of soap base: mental granite powder = 92 to 99: 1 to 8, and the addition rate of the granite granite powder is If it is less than 1% by weight, there is a fear that the desired far-infrared radiation effect is insufficient in the present invention, and if it exceeds 8% by weight, it is difficult to expect a cumulative synergistic effect. This is also undesirable because it may be somewhat inferior.

      Far-infrared emissivity may change somewhat depending on the type of deep granite used, the mixing method, and the mixing ratio. As a typical example, the three types of representative granite rocks mentioned above may be used alone, or any mixture thereof may be used, and the relative addition ratio may also be arbitrary.

      Next, the method for producing a soap according to the present invention will be described.

      A thick granite having a particle size distribution as described above is added, but a normal soap material base: A thick granite powder is added so that the weight percent ratio is 92 to 99: 1 to 8, and the soap manufacturing method according to the present invention is conventional. Soap material base, deep granite powder, and water were added to an atmospheric pressure reactor at a ratio of 5 to 7: 1: 5 to 7, heated at 110 to 130 ° C. for 10 minutes to 1 hour, and then cooled slowly to obtain a solid and pulverized. After making soap chips, it is put into a vacuum extruder and extruded at a temperature of 92-98 ° C., and then it is put into a conventional soap manufacturing apparatus and molded, or a conventional soap material base chip and the particle size distribution described above. The granulated granite powder having a granular powder is put into a vacuum extruder and extruded at 92-98 ° C., and then cut to prepare a new chip, which is injected into a conventional soap manufacturing apparatus and injection molded into 100 g units. Is done.

      As the soap material base, any soap material base of various forms commonly used in the art to which the present invention pertains may be used, and well known additives may be added to improve the use and product properties.

      As an example of the present invention, a palm oil-based soap material, more specifically palm oil 81.45%, glycerin 1.2%, squalene 0.5%, tocopherol 0.5%, fragrance 1.2%, glycerol 1.0%, moisture 13.5%, calcium chloride Soap material base consisting of 0.6% and 0.05% of the free alkali component may be mentioned, but the present invention is not limited thereto.

Specifically, normal granular base rock with normal soap base and particle size in the range of 0.3 to 2.0 µm, average particle diameter of 0.5 to 1.5 µm, and d (v) ₅₀ (50% of the particle volume distribution) = 0.8 to 1.2 µm. Powder and water were added at a weight ratio of 5 to 7: 1: 5 to 7, respectively, and heated at a temperature of 110 to 130 ° C. for 10 minutes to 1 hour, followed by slow cooling with gentle conditions and agitation when they started to solidify to some extent. By stopping the solution, a crude soap having a specific gravity in the range of 0.95 to 0.97 and a far-infrared emissivity in the range of 0.92 to 0.95 is obtained.

      After grinding the crude soap into chips, it is put in a vacuum extruder and extruded at 92-98 ° C., and the extruded chips are put into a conventional soap manufacturing apparatus, cut into 100g units, and then injection-molded. To prepare a soap according to the invention.

      In addition, a conventional soap material base chip and deep granite powder having the above-mentioned particle size distribution were put in a vacuum extruder and extruded at 92-98 ° C., and then cut to prepare a new chip, which was put into a conventional soap manufacturing apparatus and put into 100 g units. Soap may also be produced by injection molding the cut into pieces.

      When the amount of soap material is relatively high during extrusion, it is preferable to use a low temperature range in the above temperature range, and when the amount of deep granite powder is relatively high, it is preferable to use a high temperature range in the above temperature range.

      On the other hand, the fine powder into the deep granite powder having the particle size distribution is pulverized for about 30 minutes to 2 hours using a ball mill, a crusher, etc., which is a normal ceramic material grinding means, and then again by using an impact grinder. It can be obtained by pulverizing for about 2 hours. Investigation and confirmation of the particle size distribution of the unpulverized pterygium granule powders showed that the volume distribution for the particles was determined by laser light scattering devices such as Cis-1 (Gallia), Helos (Sympatek) and Mastersizer X (Malbourne). 1) and the like.

      The deep granulated granite powder having the above-mentioned particle size distribution contained in the soap according to the present invention effectively peels off the dead cell layer of the epidermis and the cured stratum corneum by friction while washing the face, and is adsorbed and coated on the epidermis to reflect the ultraviolet rays, The radiant energy absorbs almost without reflecting. In other words, the radiant energy of the atmosphere, the deep granite powder adsorbed and coated on the epidermal layer, and the water molecular structure present in the human body have mutual resonance effect, effectively absorbing the heat source of the atmosphere, and the energy absorption is maximized in the wavelength range of 7 ~ 14nm band. To this. And since psoriatic granite powder has a molecular density of 10 to 15 molecules in one cluster, water molecule population tends to be smaller and free to enter the cell membrane, thereby facilitating material exchange between cells. When washing with water after using soap for skin cleaning, the penetrated palliative granite powder removes sebum in the sweat glands and narrows the pores to increase skin astringent, so that the skin is softened. By radiating the peripheral blood vessels to facilitate the blood circulation to help the health of the skin and the color will be good.

      Hereinafter, the present invention will be described in more detail with reference to Examples, Comparative Examples and Test Examples.

Example 1

Soap base consisting of 81.45% of palm oil, 1.2% of glycerin, 0.5% of squalene, 0.5% of tocopherol, 1.2% of fragrance, 1.0% of glycerol, 13.5% of moisture, 0.6% of calcium chloride and 0.05% of free alkali, SiO ₂ 79.76wt%, Al ₂ O ₃ 9.87wt%, Fe ₂ O ₃ 0.21wt%, K ₂ O 3.79wt%, Na ₂ O 2.81wt%, CaO 1.59wt%, MgO 0.86wt% and trace components 1.11wt% (Germanium content 0.5 ~ 2ppm ), Consisting of deep granite, SiO ₂ 73.41 wt%, Al ₂ O ₃ 14.56 wt%, Fe ₂ O ₃ 1.13 wt%, K ₂ O 4.13 wt%, Na ₂ O 2.48 wt%, CaO 2.28 wt%, MgO 0.72 Deep granite composed of wt% and trace components 1.29wt% (Germanium content 0.5 ~ 2ppm), 73.53wt% SiO _2, 12.52wt% Al ₂ O _3, 4.76wt% Fe ₂ O _3, 3.78wt% K ₂ O Deep granite, consisting of Na ₂ O 2.07wt%, CaO 1.56wt%, MgO 0.51wt% and trace component 1.27wt% (Germanium content 0.5 ~ 2ppm), is mixed in the same amount and the particle size ranges from 0.3 ~ 2.0㎛ The granulated granite powder having a particle diameter of 0.5 to 1.5 µm and d (v) ₅₀ (50% of the particle volume distribution) = 0.8 to 1.2 µm was 94: 6 by weight. The mixture was put in an extruder, extruded at 96 ° C., cut into chips to make chips, and then injected into a conventional soap manufacturing apparatus, followed by injection molding in 100 g units to prepare a solid soap.

Example 2

      Soap base, deep granite powder and water in Example 1 were added to the atmospheric reactor at a weight ratio of 5 to 7: 1: 5 to 7, respectively, heated at 120 ° C. for 40 minutes, and then slowly cooled and solidified while stirring slowly. When starting, stop stirring and allow to cool again to obtain a solid, which is pulverized into chips, which are then fed into an extruder and extruded at a temperature of 96 ° C., which is then poured into a conventional soap manufacturing apparatus and molded into solid soap. Was prepared.

Examples 3 and 4

      According to the composition and composition ratio as shown in Table 1 to add the water phase component to purified water to dissolve it by heating to 70 ~ 75 ℃ to form an aqueous phase, the oil phase component is heated to melt to 65 ~ 70 ℃ to make an oil phase, oil phase and deep granite The powder was slowly added to an aqueous phase, emulsified at 3500 rpm at 65 to 70 ° C. for 3 minutes, an additive was added at 50 ° C. while cooling, stirred and mixed for 5 minutes, and cooled to room temperature to prepare a liquid soap.

division Raw material name Example 3 Example 4 Awards Alkyl acrylate methacrylate copolymer 15.0 15.0 Carboxy vinyl polymer (2 wt% aqueous solution) 15.0 15.0 glycerin 3.0 3.0 1,3-butylene glycol 3.0 3.0 Methylgluses 20 3.0 3.0 Sorbitol 3.0 3.0 lecithin 1.0 1.0 Purified water To 100 To 100 Paid Volatile Siloxane 10.0 --- Nonvolatile siloxane --- 10.0 Silicone ether copolymer 1.0 1.0 C _10-16 higher alcohol 1.0 1.0 ceramic Amoretic granite powder ^* 4.0 6.0 additive ethanol 5.0 5.0 antiseptic q.s. q.s. incense q.s. q.s. Pigment q.s. q.s.

SiO ₂ 73.41wt%, Al ₂ O ₃ 14.56wt%, Fe ₂ O ₃ 1.13wt%, K ₂ O 4.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and trace components 1.29wt Deep granite, consisting of% (Germanium content 0.5-2 ppm), particle size ranging from 0.3-2.0 μm, average particle diameter 0.5-1.5 μm, d (v) ₅₀ (50% of particle volume distribution) = 0.8-1.2 μm Powder.

Comparative Example 1

Soap base in Example 1 and chemical granules of the same chemical composition as in Example 1 but having a particle diameter of 8 to 10 µm (about 325 mesh) and water were poured into a vacuum reactor at a weight ratio of 3: 1: 3, respectively. After heating for 2 hours at a temperature of 130 ℃ and slowly cooled to separate the three layers are separated into chips, and then put into an extruder and extruded at a temperature of 98 ℃, it is put into a conventional soap manufacturing apparatus and molded To prepare a solid soap.

(Test example)

In order to evaluate the products prepared according to the composition as described in Examples 1 to 4 and Comparative Example 1, the quality evaluation comparing skin safety test results, ease of use and feeling test results was performed.

Test Example 1: Skin Safety Test

Thirty healthy men and women were buried under a patch test hazel chamber with 2.0 g of each soap sample inside a forearm for 48 hours, and after removing the hazel chamber for 1 hour, the skin condition was visually read and changed. The secondary judgment was performed to remove the difference, read it again after 48 hours, and the results are shown in Table 2. Judgment was made based on the following determination table of the value calculated | required by the following magnetic pole intensity calculation formula 1.

* Judgment table

      －: No reaction (Irritation degree: 0)

      ±: suspected positive reaction. Slight erythema reaction (irritation degree: 0.5)

      +: Slight positive reaction; Erythema, papules, positive pullback reactions (irritation degree: 1.0)

      ++: Severe positive reaction. Erythema, papules, infiltrating lesions, vesicles (irritation degree: 2.0)

      +++: Severe positive reaction (Irritation degree: 3.0)

(Equation 1)

division  1st judgment 2nd judgment score - ± + ++ - ± + ++ Example 1 30 0 0 0 30 0 0 0 0.00 Example 2 30 0 0 0 30 0 0 0 0.00 Example 3 30 0 0 0 30 0 0 0 0.00 Example 4 30 0 0 0 30 0 0 0 0.00 Comparative Example 1 24 5 One 0 22 6 2 0 0.66

As can be clearly seen from Table 2, the skin irritation test results show that the granular granulite powder has a significant effect on the skin irritation. It turned out to be absent at all. It is believed that this is due to the fact that the skin does not feel any foreign body when the diameter of the deep granite powder is micronized above a certain limit.

Test Example 2 Usability Evaluation

Twenty females between 25 and 30 years old, when using the cosmetic products of Examples 1,2 and Comparative Example 1 according to the general usage, refreshed after washing, 30 minutes in an indoor environment of 18 ° C after washing and 50% relative humidity. Satisfaction with facial texture at the time of progress was evaluated. The evaluation score is very satisfactory: 2 points, satisfaction: 1 point, normal: 0 points, bad:-1 point, very bad:-2 points The total score is calculated according to the following formula 2 and the result is shown in the following table. 3 is shown.

(Equation 2)

division Freshness  score Surface texture  score 2 One 0 -One -2 2 One 0 -One -2 Example 1 9 11 0 0 0 1.45 8 10 2 0 0 1.30 Example 2 0 9 8 3 0 0.30 5 12 3 0 0 1.10 Comparative Example 1 0 0 6 6 8 －1.10 0 3 10 7 0 -0.20

As can be seen from Table 3 above, when comparing the case of the deep granite powder having a particle size distribution according to the present invention and the case of the conventional deep granite powder having a large particle size distribution, the particle size of the added deep granite The facial texture to be detected later has a significant effect, and in the case of the deep granite powder having a particle size distribution according to the present invention, the facial texture after washing was evaluated to be quite good.

As described above, the soap composition according to the present invention has an effect of significantly increasing the surface area even with a small amount by optimizing the particle size distribution of the main granular granite, so that the skin absorbs the heat source efficiently. In addition, it affects the molecular density of moisture in the skin, thereby facilitating the exchange of substances between cells, thereby providing excellent skin beauty and skin protection effects, activating free energy in the body, and relieving environmental pollution while maintaining good cleaning power. In addition to the reinforcement and improvement of various properties such as, there is an advantage that the use is excellent and there is little concern of skin trouble,

Since the manufacturing method according to the present invention does not require the use of a vacuum reactor in the manufacture of soap, it is possible to avoid the complexity and cost of the equipment, and at the same time, it is possible to significantly reduce the amount of core granite powder used as the main component.

Claims (4)

Soap based 92 ~ 99% by weight, particle size 0.3 ~ 2.0㎛, mean particle size 0.5 ~ 1.5㎛, d (v) ₅₀ (50% of particle volume distribution) = 0.8 ~ 1.2㎛ The deep granite is composed of SiO ₂ 70 ~ 80wt%, Al ₂ O ₃ 8 ~ 16wt%, Fe ₂ O ₃ 0.1 ~ 5wt%, K ₂ O 3.5 ~ 4.5wt%, Na ₂ O 2 ~ 3wt% , CaO 1.5 ~ 2.5wt%, MgO 0.5 ~ 1.0wt% and the soap composition composed of a trace component containing germanium. The method of claim 1, wherein the deep granite is SiO ₂ 79.76wt%, Al ₂ O ₃ 9.87wt%, Fe ₂ O ₃ 0.21wt%, K ₂ O 3.79wt%, Na ₂ O 2.81wt%, CaO 1.59wt Deep granite, consisting of%, 0.86 wt% of MgO and 1.11 wt% of minor components including germanium; SiO ₂ 73.41wt%, Al ₂ O ₃ 14.56wt%, Fe ₂ O ₃ 1.13wt%, K ₂ O 4.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and germanium Deep granite, consisting of a minor component of 1.29 wt%; And SiO ₂ 73.53 wt%, Al ₂ O ₃ 12.52 wt%, Fe ₂ O ₃ 4.76 wt%, K ₂ O 3.78 wt%, Na ₂ O 2.07 wt%, CaO 1.56 wt%, MgO 0.51 wt% and germanium A soap composition, wherein the soap composition is at least one type of deep granite selected from the group consisting of deep granite composed of a minor component of 1.27 wt%.       Soap base: Pulverized granite powder with particle size distribution according to claim 1: Water = 5 ~ 7: 1: 1 to 5 ~ 7% by weight in a reactor under normal pressure and a temperature of 110 ~ 130 ℃ 10 minutes ~ 1 hour After heating for a slow cooling (徐 冷) to obtain a solid, pulverized and formulated into a soap chip (chip), and then put it in an extruder, extruded to a temperature of 92 ~ 98 ℃ and put it in a conventional soap manufacturing apparatus and molding Method for producing a soap having a composition ratio according to claim 1 characterized in that.       The granulated granite powder having the soap base chip and the particle size distribution according to claim 1 is put in a vacuum extruder and extruded at 92-98 ° C., and then cut to prepare chips, which are put into a conventional soap manufacturing apparatus and injection molded. Method for producing a soap having a composition ratio according to claim 1.