KR20040056876A - Method for combustion of gas-solid two phase fuel in a calcination rotary kiln - Google Patents
Method for combustion of gas-solid two phase fuel in a calcination rotary kiln Download PDFInfo
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- KR20040056876A KR20040056876A KR1020020083462A KR20020083462A KR20040056876A KR 20040056876 A KR20040056876 A KR 20040056876A KR 1020020083462 A KR1020020083462 A KR 1020020083462A KR 20020083462 A KR20020083462 A KR 20020083462A KR 20040056876 A KR20040056876 A KR 20040056876A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2/00—Lime, magnesia or dolomite
- C04B2/10—Preheating, burning calcining or cooling
- C04B2/108—Treatment or selection of the fuel therefor
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2/00—Lime, magnesia or dolomite
- C04B2/02—Lime
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
Abstract
Description
본 발명은 석회소성용 로타리킬른(rotary kiln)에서의 기상-고상 혼합연소 방법에 관한 것으로서, 더욱 상세하게는 석회소성용 로타리킬른에서 기상연료인 코크스오븐가스와 고상연료인 분코크스의 혼합연소시 질소산화물(NOx)의 발생과 에너지손실을 최소화할 수 있는 방법에 관한 것이다.The present invention relates to a gas-solid mixed combustion method in a rotary kiln for calcining, and more particularly, to a mixed combustion of coke oven gas and solid fuel in the lime kiln. The present invention relates to a method for minimizing the generation of NOx and energy loss.
종래의 로타리킬른(rotary kiln)에서는 가스 및 액상연료의 단독연소, 액상-고상, 기상-고상, 기상-액상의 혼합연소를 이용하여 열원을 얻었다. 그러나, 발생열을 효과적으로 이용하기보다는 석회석을 소성시키는 충분한 열을 공급하는 것만을 목표로 하여 로내의 균일가열이나 공해물질인 질소산화물(NOx)의 저감에는 효과적이지 못하였다.In the conventional rotary kiln (rotary kiln), the heat source was obtained using a single combustion of the gas and liquid fuel, liquid-solid phase, gas phase-solid phase, gas phase-liquid mixed combustion. However, it was not effective in reducing the uniform heating in the furnace or reducing nitrogen oxides (NOx) in the furnace, aiming only to supply sufficient heat for calcining limestone, rather than using the generated heat effectively.
본 발명은 상기와 같은 제반 문제점을 해결하기 위하여 창안된 것으로서, 열에너지가 과량으로 사용되는 것을 방지함과 동시에 질소산화물의 발생을 최소화할 수 있는 석회소성용 로타리킬른에서의 기상-고상 혼합연소 방법을 제공하는데 그목적이 있다.The present invention was devised to solve the above problems, and a gas-solid mixed combustion method in a rotary kiln for lime firing that can minimize the generation of nitrogen oxides while preventing excessive use of thermal energy. The purpose is to provide.
상기와 같은 목적을 달성하기 위한 본 발명의 석회소성용 로타리킬른에서의 기상-고상 혼합연소 방법은, 버너의 중심부에 고상연료를 일정속도로 공기와 함께 분사하여 주입하고, 주변부위로 기상연료와 연소용공기를 주입하며, 상기 고상연료와 기상연료의 주입량에 따라 상기 연소용공기의 양을 연동하여 조정하되, 상기 고상연료의 유속은 25~50m/s으로 조정하고, 상기 기상연료의 유속은 10~30m/s으로 조정하며, 상기 고상연료의 분사속도를 항상 상기 기상연료의 분사속도보다 크게 하는 것을 특징으로 한다.The gas-solid mixed combustion method in the rotary kiln for lime firing of the present invention for achieving the above object is injected by injecting solid fuel with air at a constant speed in the center of the burner, the gaseous fuel and combustion to the surrounding area Inject the air, and adjust the amount of the combustion air in accordance with the injection amount of the solid fuel and gaseous fuel, the flow rate of the solid fuel is adjusted to 25 ~ 50m / s, the flow rate of the gaseous fuel 10 The injection speed of the solid fuel is always greater than the injection speed of the gas phase fuel.
이하, 본 발명의 석회소성용 로타리킬른(rotary kiln)에서의 기상-고상 혼합연소 방법에 대하여 상세히 설명하기로 한다.Hereinafter, a gas-solid mixed combustion method in a rotary kiln for lime firing of the present invention will be described in detail.
버너의 중심부에는 고상연료를 일정한 속도로 공기와 함께 분사하여 주입하고, 주변부위로는 기상연료와 연소용공기를 주입하며, 고상연료와 기상연료의 주입량에 따라 연소용공기의 양을 자동으로 조정하도록 한다.In the center of the burner, solid fuel is injected and injected with air at a constant speed, gaseous fuel and combustion air are injected into the peripheral portion, and the amount of combustion air is automatically adjusted according to the injection amount of solid fuel and gaseous fuel. do.
중앙운전제어반에서 전체 소요열량 및 고상, 기상연료의 유량을 설정하면, 그에 따른 연소용공기량이 계산되어 설정되고, 처음 운전이 시작되면, 설정값으로 운전되도록 한다. 일단, 운전이 시작되면, 로온이 최대로 되도록 피드백제어를 이용하여 연소용공기량을 조절하고, 로온이 최대로 유지되는 시점에서 석회소성에 적합한 로온이 되도록 연료유량과 연소용공기량이 같은 비율로 변하도록 한다. 여기서, 연료유량은 먼저 설정된 비율이 유지되도록 하고, 연소용공기량은 추가적으로앞에서와 같이 최대 로온이 되도록 반복 조절하여 최적 제어가 이루어지도록 한다.If the total required heat quantity and the flow rate of the solid and gaseous fuel is set in the central operating control panel, the combustion air amount is calculated and set accordingly, and when the first operation is started, the operation is performed at the set value. Once the operation is started, the combustion air volume is adjusted using feedback control to maximize the low temperature, and the fuel flow rate and the air volume for combustion are changed at the same rate so that the low temperature is suitable for calcining at the time when the low temperature is maintained. Do it. In this case, the fuel flow rate is maintained at the first set ratio, and the combustion air amount is additionally repeatedly adjusted so as to be the maximum low temperature as before, so that optimal control is achieved.
석회소성용 로타리킬른에서 고상연료의 유속은 25~50m/s으로 조정하고, 기상연료의 유속은 10~30m/s으로 조정하며, 고상연료의 분사속도는 항상 기상연료의 분사속도보다 크도록 한다. 여기서, 기상연료는 운동량이 적기 때문에 로타리킬른 내부에 분사되자마자 내부의 평균속도인 2~3m/s로 떨어지면서 화염길이가 짧고, 고상연료는 자체 운동량을 어느정도 가지고 있을 뿐 아니라 기상연료의 분사속도보다 항상 크기 때문에 분사속도를 유지하면서 더 멀리까지 분사되어 기상연료인 코크스오븐가스의 화염과 분리가 일어나며, 코크스오븐가스는 연소가 잘 일어나기 때문에 화염을 안정화시키는 역할을 하고, 고상연료인 분코크스는 화염길이를 더 길게 하면서 동시에 복사열을 발생시켜 로내온도를 좀 더 균일하게 유지하는 역할을 하여 열효율을 향상시키게 된다.In the rotary kiln for lime-calcination, the flow rate of solid fuel is adjusted to 25-50m / s, the flow rate of meteorological fuel is adjusted to 10-30m / s, and the injection speed of solid fuel is always greater than that of meteorological fuel. . Here, the meteorological fuel has a small momentum, and as soon as it is injected into the rotary kiln, the flame length is shortened to an average speed of 2 to 3 m / s, and the solid fuel has its own momentum as well as the injection speed of the meteorological fuel. Because it is always larger, it is sprayed farther while maintaining the injection speed, so that it is separated from the flame of the coke oven gas, which is a gaseous fuel, and the coke oven gas plays a role in stabilizing the flame because the combustion occurs well. The flame length is longer and at the same time radiant heat is generated to maintain the furnace temperature more uniformly, thereby improving thermal efficiency.
이때, 기상 단독으로 연소시킬 때보다는 보다 더 저온에서 연소가 일어나게 조정하는 것이 가능하므로 연소시 발생하는 질소산화물(NOx)의 발생을 억제할 수 있게 된다.At this time, it is possible to adjust the combustion to occur at a lower temperature than when burning in the gas phase alone, it is possible to suppress the generation of nitrogen oxide (NOx) generated during combustion.
그리고, 고상연료와 기상연료의 분사비율에 따라 로타리킬른의 내부온도를 조정할 수 있도록 연료량을 동시에 조정하고, 연료소비가 최소화할 수 있는 양으로 조정하는 것이 가능해지기 때문에, 기존의 연소방법에 비하여 연료소비를 줄일 수 있고, 공해물질의 배출을 저감할 수 있게 된다.In addition, the amount of fuel can be adjusted at the same time to adjust the internal temperature of the rotary kiln according to the injection ratio of the solid fuel and the gaseous fuel, and the fuel consumption can be adjusted to the amount that minimizes fuel consumption. Consumption can be reduced and emissions of pollutants can be reduced.
본 발명에 따르면, 소성품 품질을 최상으로 유지할 수 있고, 연료소비량을저감할 수 있으며, 질소산화물의 배출을 최소화하여 환경오염을 방지할 수 있는 효과가 있다.According to the present invention, it is possible to maintain the best quality of the fired product, to reduce fuel consumption, and to minimize the emission of nitrogen oxides, thereby preventing environmental pollution.
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CN112250325A (en) * | 2020-10-29 | 2021-01-22 | 中南大学 | Method for reducing NOx emission peak value in double-chamber lime kiln switching combustion process |
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CN112250325A (en) * | 2020-10-29 | 2021-01-22 | 中南大学 | Method for reducing NOx emission peak value in double-chamber lime kiln switching combustion process |
CN112250325B (en) * | 2020-10-29 | 2021-11-09 | 中南大学 | Method for reducing NOx emission peak value in double-chamber lime kiln switching combustion process |
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