KR20040038609A - Red tide removal materials and its manufacturing method - Google Patents

Red tide removal materials and its manufacturing method Download PDF

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KR20040038609A
KR20040038609A KR1020030055463A KR20030055463A KR20040038609A KR 20040038609 A KR20040038609 A KR 20040038609A KR 1020030055463 A KR1020030055463 A KR 1020030055463A KR 20030055463 A KR20030055463 A KR 20030055463A KR 20040038609 A KR20040038609 A KR 20040038609A
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powder
red tide
weight
strong
tuff
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정흥제
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정흥제
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3021—Milling, crushing or grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

PURPOSE: Provided is a red tide removal material, which eliminates red tide by settling essential nutrients of various algae, and a method for preparing the red tide removal material is provided. CONSTITUTION: The red tide removal material contains 17-22 wt.% of sedimentary rock powder, 18-21 wt.% of shale powder, 33-36 wt.% of plutonic rock powder and 23-26 wt.% of strong tuff powder. The method comprises steps of (a) pulverizing sedimentary rock, shale, plutonic rock and strong tuff; (b) uniformly stirring 17-22 wt.% of sedimentary rock powder, 18-21 wt.% of shale powder, 33-36 wt.% of plutonic rock powder and 23-26 wt.% of strong tuff powder in a stirrer; (c) producing zeolite by putting an alkaline aqueous solution in the stirrer and heating while stirring the sedimentary rock powder, shale powder, plutonic rock powder and strong tuff powder; and (d) converting the zeolite into imogolite by putting an acid aqueous solution in the stirrer and heating.

Description

적조 제거제 및 그 제조방법{Red tide removal materials and its manufacturing method}Red tide removal materials and its manufacturing method

본 발명은 강이나 바다에서 부유성 조류들이 대량 증식하여 발생되는 적조를 제거하기 위한 적조 제거제에 관한 것으로, 특히 적조의 원인이 되는 각종 조류의 필수 영양분을 침전시켜 효과적으로 적조를 제거할 뿐만 아니라 오염수역에 부유하는 각종 부유물질을 침강시켜 오염수역을 정화하는 적조 제거제 및 그 제조방법에 관한 것이다.The present invention relates to a red tide remover for removing red tide that is generated by the proliferation of floating algae in rivers or the sea, and particularly, effectively removes red tide by precipitating essential nutrients of various algae that cause red tide. The present invention relates to a red tide remover for purifying polluted water by sedimenting various suspended solids suspended in the water and a method of manufacturing the same.

일반적으로 적조(赤潮, red tide)란 조류의 이상 증식으로 바닷물이 붉게 보이는 현상을 말한다. 이러한 적조의 주된 원인으로는 강력한 일사(日射)로 표층수의 수온이 급상승하는 경우, 폭우로 인해 대량 유입된 담수에 의해 영양염류가 크게 증가하는 경우, 무풍상태가 계속되어 해수의 혼합이 저하되는 경우 등이 있다. 이와 같은 원인들로 인해 이상 증식하게 되는 조류로는 편모조류·규조류·야광충 등이 있으며, 적조로 인한 바닷물의 색은 보통 붉은색이지만 조류의 종류에 따라서 황갈색·황록색·암자색을 띠는 경우도 있다.Generally, red tide refers to a phenomenon in which the seawater becomes red due to abnormal growth of algae. The main cause of such red tide is the strong solar radiation, when the surface water temperature rises sharply, when the nutrients are greatly increased by fresh water introduced due to heavy rains, and when there is no wind condition, and the mixing of seawater decreases. Etc. Algae that multiply abnormally due to these causes include flagella algae, diatoms, and nocturnal nematodes, and the color of seawater due to red tide is usually red, but may be yellowish brown, yellowish green, or dark purple depending on the type of algae. .

적조가 진행되는 동안 적조지역의 물은 점성도(粘性度)가 강해지고 악취를 풍기게 되며, 조류의 시체가 한꺼번에 분해되어 수중의 용존산소를 대량으로 소모하기 때문에 어패류는 아가미가 막히거나 호흡곤란에 빠져 폐사하게 될 뿐만 아니라 폐사된 어패류로 인해 심각한 수질오염이 야기된다.During the course of red tide, the water in the red tide area becomes more viscous and odorous, and the fish and shellfish are clogged with gills or have difficulty breathing because the body of the algae decomposes at once and consumes a large amount of dissolved oxygen in the water. Not only will they fall out and die, but they will also cause serious water pollution.

전술한 바와 같이 적조는 강이나 바닥에 서식하는 어패류 뿐만 아니라 수질오염의 주된 원인으로 작용하기 때문에, 적조로 인해 발생되는 각종 폐해를 예방하고자 예전부터 적조의 제거를 위한 다양한 방법들이 개발되어 시행되고 있다.As described above, since red tide acts as a major cause of water pollution as well as fish and shellfish inhabiting rivers or bottoms, various methods for removing red tide have been developed and implemented to prevent various damages caused by red tide. .

첫 째, 화학적인 방법은 고분자 응집제나 황산알루미늄 등의 화학약품을 투입하여 담수를 정화하는 방법이다. 하지만 화학약품을 사용하여 담수를 정화하는 방법은 환경적인 많은 문제점을 내포하고 있으며, 지속적으로 투입하게 되면 자연생태계가 파괴될 위험이 있다.First, the chemical method is a method of purifying fresh water by adding a chemical flocculant or chemicals such as aluminum sulfate. However, the use of chemicals to purify fresh water has many environmental problems, and there is a risk of destroying the natural ecosystem if continuously added.

또한, 화학적인 방법으로 적조발생지역의 물(H2O)과 염화나트륨(NaCl)이 동시에 전기분해될 때 발생되는 음이온이 적조를 제거하게 되는 원리를 이용한 전기분해법이 있으나, 이 전기분해법에 의해 해수를 직접 전기분해하게 되면 전기분해에 소요되는 전력소모가 상당하고 전극의 성능이 단시간에 저화되므로 실용적인 연속조업이 어려울 뿐만 아니라 전력을 공급하고 전극을 교체하는데 많은 비용이 소모되며, 조제된 전해수를 살포하는 경우에는 저장 및 운송의 문제가 발생되므로 경제적인 측면에서 실효성을 거두지 못하고 있다.In addition, there is an electrolysis method using the principle that the anion generated when the water (H 2 O) and sodium chloride (NaCl) in the red tide generating area are electrolyzed by the chemical method removes the red tide. Direct electrolysis of electricity consumes considerable amount of power for electrolysis, and the performance of electrode is reduced in a short time, making practical continuous operation difficult and costly to supply power and replace electrode, and spray prepared electrolyte In this case, there is a problem of storage and transportation, so it is not economically effective.

둘 째, 생물학적인 방법으로 조류의 천적을 살포하여 조류을 제거하는 방법이 있으나, 현재까지 조류의 천적이 될만한 생물이나 미생물을 찾지 못하고 있는 실정이고 연구중인 생물이나 미생물의 경우에도 그 효과가 입증되지 않고 있기 때문에 이 방법은 아직까지 시행되고 있지 않은 실정이다.Second, there is a method to remove algae by spraying algae's natural enemy by biological method, but until now, the organism or microorganism under investigation has not been found and its effect has not been proved This method has not been implemented yet.

또한, 생물학적인 방법으로 적조발생 지역에 황토를 살포하는 황토살포법이 있으나, 이 황토 살포법은 황토 자체의 흡착기능과 구성성분인 알루미늄 등이 적조생물을 제거하는 기능을 갖고 있으나, 적조 제거효율이 낮을 뿐만 아니라 과다 살포된 황토가 해저에 침강하여 조개나 전복 등과 같은 어패류를 폐사시키는등 제2의 환경오염을 야기시키는 원인이 되고 있다.In addition, there is a loess spray method that sprays loess to red tide occurrence area as a biological method. However, the loess spread method has the function of adsorption function of the loess itself and aluminum as a component to remove red tide organisms. Not only is this low, the over-spread loess settles on the sea floor and causes second environmental pollution, such as shellfish and abalone, causing death.

본 발명은 전술한 바와 같은 종래의 문제점을 해소하기 위하여 안출된 것으로, 적조를 발생시키는 각종 조류들의 필수 영양분인 질소, 인과 조류 자체를 응집하여 침전시킴으로써 조류들의 증식을 효과적으로 억제하고 제거할 수 있는 적조제거제 및 그 제조방법을 제공하는데 그 목적이 있다.The present invention has been made to solve the conventional problems as described above, red tide that can effectively suppress and eliminate the growth of algae by agglomeration and precipitation of nitrogen, phosphorus and algae itself as essential nutrients of various algae generating red tide It is an object of the present invention to provide a removing agent and a method of manufacturing the same.

또한, 본 발명은 조류들의 필수 영양분외에도 오염 수역에 부유하는 각종 부유물질을 응집하여 침전시킴으로써 오염수역을 정화할 수 있는 적조 제거제 및 그 제조방법을 제공하는 목적도 있다.In addition, an object of the present invention is to provide a red tide remover capable of purifying the contaminated water by agglomeration and precipitation of various suspended substances suspended in contaminated water in addition to the essential nutrients of algae, and a method of manufacturing the same.

아울러, 본 발명은 원적외선을 방사함으로써 적조발생 수역이나 오염 수역에 서식하고 있는 각종 세균이나 해충들을 박멸하고 수생생물의 성장을 촉진시킬 수 있는 적조 제거제 및 그 제조방법을 제공하는 목적도 있다.In addition, an object of the present invention is to provide a red tide remover capable of eradicating various bacteria and pests inhabiting red tide generating or contaminated water by radiating far infrared rays and promoting the growth of aquatic organisms, and a method of manufacturing the same.

도 1은 본 발명에 따른 적조 제거제의 제조과정을 나타낸 흐름도.1 is a flow chart showing the manufacturing process of the red tide remover according to the present invention.

<도면의 주요부호에 대한 설명><Description of Major Symbols in Drawing>

10 : 분쇄단계 20 : 교반단계10: grinding step 20: stirring step

30 : 제올라이트 생성단계 40 : 이모고라이트 생성단계30: zeolite generation step 40: imogolite generation step

전술한 바와 같은 목적을 달성하기 위해 본 발명에 따른 적조 제거제는, 퇴적암 분말 17~22 중량%, 혈암 분말 18~21 중량%, 심성암 분말 33~36 중량%, 강력응회암 분말 23~26 중량%를 포함하여 이루어진다.In order to achieve the object as described above, the red tide remover according to the present invention, sedimentary rock powder 17-22% by weight, shale powder 18-21% by weight, heart rock powder 33-36% by weight, strong tuff powder 23-26% by weight It is made to include.

이와 같은 구성에 있어서, 퇴적암 분말, 혈암 분말, 심성암 분말, 강력응회암 분말은 325~1000mesh로 분말화되는 것이 바람직하다.In such a configuration, the sedimentary rock powder, shale powder, plutonic rock powder, and strong tuff powder are preferably powdered to 325 to 1000 mesh.

한편, 본 발명에 따른 적조 제거제의 제조방법은, 퇴적암, 혈암, 심성암, 강력응회암을 분쇄기에 투입하여 분말화하는 단계; 퇴적암 분말 17~22 중량%, 혈암 분말 18~21 중량%, 심성암 분말 33~36 중량%, 강력응회암 분말 23~26 중량%를 교반기로 투입하여 균일하게 교반하는 단계; 퇴적암 분말, 혈암 분말, 심성암 분말, 강력응회암 분말을 교반하는 과정에서 알칼리 수용액을 교반기로 투입하고 가열하여 제올라이트를 생성하는 단계; 및 산성 수용액을 교반기로 투입하고 가열하여 제올라이트를 이모고라이트로 전환하는 단계를 포함하여 이루어진 것을 특징으로 한다.On the other hand, the manufacturing method of the red tide remover according to the present invention, the step of powdering the sedimentary rock, shale, heart rock, strong tuff to the grinder; 17-22% by weight of sedimentary rock powder, 18-21% by weight shale powder, 33-36% by weight of plutonic rock powder, 23-26% by weight of strong tuff powder, and stirring it uniformly; In the process of stirring the sedimentary rock powder, shale powder, plutonic rock powder, strong tuff powder, adding an aqueous alkali solution to the stirrer and heating to generate a zeolite; And adding an acidic aqueous solution to a stirrer and heating to convert the zeolite to imogolite.

이하, 본 발명에 따른 적조 제거제 및 그 제조방법을 보다 구체적으로 살펴보기로 한다.Hereinafter, the red tide remover according to the present invention and a manufacturing method thereof will be described in more detail.

첨부된 도면의 도 1은 본 발명에 따른 적조 제거제의 제조과정을 나타낸 흐름도이다.1 of the accompanying drawings is a flow chart showing the manufacturing process of the red tide remover according to the present invention.

본 발명에 따른 적조 제거제는, 천연무기질 재료 즉, 퇴적암, 혈암, 심성암, 강력응회암이 각각 17~22 중량%, 18~21 중량%, 33~36 중량%, 23~26 중량%의 비율로 혼합조성되어 이루어진다.Red tide remover according to the present invention, natural inorganic materials, that is, sedimentary rock, shale, heart rock, strong tuff is mixed 17 to 22% by weight, 18 to 21% by weight, 33 to 36% by weight, 23 to 26% by weight, respectively It is made up.

이와 같은 천연무기질 재료는 그 성분이 규산(SiO2), 알루미나(Al2O3), 산화제이철(Fe2O3), 산화칼슘(CaO), 산화마그네슘(MgO), 산화나트륨(Na2O), 산화칼륨(K2O), 이글로스(Igloss) 등으로 이루어져, 인체에 유익한 원적외선이 다량 방사될 뿐만 아니라 통기성, 응집력, 점착력 등으로 인해 탈취효과 및 정화효과가 우수하며, 어패류에도 매우 유익하여 어패류의 성장을 촉진시키는 효과도 발휘하게 된다.Natural inorganic materials such as silicate (SiO 2 ), alumina (Al 2 O 3 ), ferric oxide (Fe 2 O 3 ), calcium oxide (CaO), magnesium oxide (MgO), sodium oxide (Na 2 O ), Potassium oxide (K 2 O), igloss (Igloss), not only emits a large amount of far-infrared rays, which are beneficial to the human body, but also has excellent deodorizing and purifying effects due to breathability, cohesion, and adhesiveness, and is also very beneficial for fish and shellfish. Therefore, the effect of promoting the growth of fish and shellfish is also exerted.

전술한 각 천연무기질 재료들은 도 1에 도시된 바와 같이 혼합하기 전에 미리 미립자 형태로 분쇄되는 분쇄단계(10)를 거치게 된다. 이 분쇄단계(10)는 천연무기질 재료인 퇴적암, 혈암, 심성암, 강력응회암을 각각 분쇄기에 넣고 3회 정도의 분쇄를 거쳐 325~1000mesh 정도의 크기를 갖는 미세한 입자로 만드는 과정이다.Each of the above-mentioned natural inorganic materials is subjected to a grinding step 10 which is pulverized into fine particles before mixing as shown in FIG. 1. The crushing step 10 is a process of making sedimentary rock, shale, plutonic rock, and strong tuff, which are natural inorganic materials, into granulators and grinding them three times to make fine particles having a size of about 325 to 1000 mesh.

전술한 분쇄단계(10)를 통해 각 천연무기질 재료가 분쇄되어 미립자 형태로 만들어지면, 퇴적암 분말, 혈암 분말, 심성암 분말, 강력응회암 분말을 각각 17~22 중량%, 18~21 중량%, 33~36 중량%, 23~26 중량%의 비율로 무중력 믹서기에 투입하여 균일하게 혼합하는 교반단계(20)를 거치게 된다. 이 때, 바람직한 천연무기질 재료의 투입비율은 아래의 표-1에서 보는 바와 같이 퇴적암 분말 20 중량%, 혈암분말 20 중량%, 심성암 분말 35 중량%, 강력응회암 분말 25 중량%이다.When the natural inorganic material is pulverized through the above-mentioned crushing step (10) to form fine particles, sedimentary rock powder, shale powder, plutonic rock powder, and strong tuff powder are respectively 17-22 wt%, 18-21 wt%, 33- 36% by weight, 23 ~ 26% by weight of the mixture is put into the gravity-free mixer is subjected to the stirring step 20 to uniformly mix. At this time, the input ratio of the preferred natural inorganic material is 20% by weight sedimentary rock powder, 20% by weight shale powder, 35% by weight pumice rock powder, 25% by weight strong tuff powder as shown in Table-1 below.

조 성 물Composition water 투입량(중량비)Input amount (weight ratio) 퇴적암 분말Sedimentary rock powder 20%20% 혈암 분말Shale powder 20%20% 심성암 분말Plutonic rock powder 35%35% 강력응회암 분말Strong Tuff Powder 25%25%

표-1TABLE-1

전술한 교반단계(20) 중에 교반기 내로 가성소다(NaOH), 탄산소다(Na2CO3), 소석회(Ca(OH)2) 등과 같은 알칼리성 물질이 용해된 알칼리 수용액을 투입한 후 90~180℃로 가열하면서 8~24시간 정도 교반하면, 교반기 내의 조성물은 반응 ①에서와 같이 제올라이트로 전환된다.In the aforementioned stirring step 20, an aqueous alkali solution in which alkaline substances such as caustic soda (NaOH), sodium carbonate (Na 2 CO 3 ), slaked lime (Ca (OH) 2 ) and the like are dissolved is added, and then 90 to 180 ° C. When the mixture is stirred for about 8 to 24 hours while heating, the composition in the stirrer is converted to zeolite as in the reaction ①.

이와 같이 제올라이트 생성단계(30)가 완료된 후 연속해서 교반기내로 황산(H2SO4)이나 염산(HCl)과 같은 산 수용액(40)을 투입한 후 90~100℃로 가열하면서 4시간 이상 교반하면, 반응 ②에서와 같이 제올라이트가 이모고라이트로 전환된다.After the zeolite production step 30 is completed, an acid aqueous solution 40 such as sulfuric acid (H 2 SO 4 ) or hydrochloric acid (HCl) is continuously added into the stirrer, and the mixture is stirred at a temperature of 90 to 100 ° C. for at least 4 hours. , As in reaction ②, zeolite is converted to imogolite.

이와 같이 이모로라이트 생성단계(40)에 의해 생성된 이모고라이트는 암모늄이온(NH4 +), 중금속이온과 같은 양이온의 치환능력과 유기산, 인산과 같은 음이온의 치환능력을 동시에 가지고 있기 때문에, 이모고라이트를 적조발생 수역에 살포하면 이모고라이트가 적조의 원인이 되는 조류의 필수 영양성분인 질소와 인, 그리고 조류 자체를 응집하여 침전시키므로 조류의 번식이 억제되어 결국에는 적조가 모두 없어지게 되며, 이모고라이트를 오염 수역에 살포하면 이모고라이트가 오염 수역에 부유하는 각종 중금속 등과 같은 부유물질들을 응집하여 침전시키므로 오염 수역이 정화된다.Since the imogolite produced by the imororite generation step 40 has the substitution ability of cations such as ammonium ion (NH 4 + ) and heavy metal ions and anion such as organic acid and phosphoric acid, When imogolite is sprayed on the water where red tide occurs, imogolite aggregates and precipitates nitrogen, phosphorus, and algae, which are essential nutrients of algae that cause red tide, thus suppressing the reproduction of algae and eventually eliminating all of the red tide. When the imogolite is sprayed into the polluted water, the polluted water is purified because the imogolite aggregates and precipitates suspended solids such as various heavy metals suspended in the polluted water.

그리고, 이모고라이트로 전환된 조성물은 분말 상태가 아닌 액체 상태로 살포되어 살포시 가라앉지 않고 물에 녹아 반응을 하기 때문에, 종래에 황토살포법에서와 같이 바닥에 침강하여 어패류를 폐사시킬 염려가 없다.In addition, since the composition converted to imogolite is sprayed in a liquid state rather than in a powder state, it reacts by dissolving in water instead of sinking during spraying, so that there is no fear of settling to the bottom and killing fish and shellfish as in the conventional ocher spraying method. .

또한, 본 발명 적조 제거제에 의해 응집된 물체는 바닥에 가라앉아 뻘형태가 되며, 뻘속에는 계속해서 천연무기질 성분이 섞여 있으므로 뻘의 부식을 막아줄 뿐만 아니라 응집된 물체가 미생물의 배양원이 되어 제2의 오염발생을 막아준다.In addition, the object aggregated by the red tide remover of the present invention sinks to the bottom to form a 뻘 form, and because the natural inorganic components are continuously mixed in the 줄 not only prevents erosion of the 아니라, but also the aggregated object becomes a culture source of microorganisms Prevents contamination of 2.

아울러, 전술한 바와 같이 각 천연무기질 재료는 원적외선을 방사하는 성분들로 이루어지므로, 본 발명에 따른 적조 제거제를 적조발생 수역에 살포하면 다량의 원적외선이 방사되어 수중에 서식하는 각종 세균이나 해충이 박멸될 뿐만 아니라 수중에 서식하는 각종 생물들의 성장이 촉진된다.In addition, as described above, since each natural inorganic material is composed of components that emit far infrared rays, when the red tide remover according to the present invention is sprayed into a red tide occurrence zone, a large amount of far infrared rays are radiated to eliminate various bacteria and pests inhabiting the water. In addition, the growth of various inhabitants is promoted.

이하, 본 발명의 구체적인 실시예를 살펴보기로 한다. 다음의 실시예는 본 발명을 좀 더 상세히 설명하는 것이지만, 본 발명의 범주를 한정하는 것은 아니다.Hereinafter, a specific embodiment of the present invention will be described. The following examples illustrate the invention in more detail, but do not limit the scope of the invention.

(실시예)(Example)

500mesh로 분말화된 퇴적암 분말 20 중량%, 혈암 분말 20 중량%, 심성암 분말 35 중량%, 강력응회암 분말 25 중량%를 교반기에 투입하고 균일하게 혼합하는 과정에서 교반기 내로 알칼리 수용액을 투입하여 20시간동안 150℃로 가열하고 연속해서 산 수용액을 투입하여 8시간 동안 80℃로 가열함으로써, 본 발명에 따른 적조 제거제를 제조하였다.20% by weight of sedimentary rock powder powdered into 500mesh, 20% by weight shale powder, 35% by weight pumice rock powder, and 25% by weight hard tuff powder were added to the stirrer and an aqueous alkali solution was added to the stirrer for 20 hours. The red tide remover according to the present invention was prepared by heating to 150 ° C. and continuously adding an aqueous acid solution to 80 ° C. for 8 hours.

이와 같이 제조된 본 발명 적조 제거제를 적조 발생지역에 살포한 결과, 육안으로도 적조가 97% 이상 제거됨을 확인할 수 있었으며, 또 30~40분 후에는 적조를 전혀 발견할 수 없었다. 또한, 적조를 제거한 후 당해 수역의 물을 채취하여 성분을 정밀 분석할 결과, 적조가 발생되지 않은 지역의 수질과 동일한 수질인 것으로 판명되었을 뿐만 아니라 적조 외에 당해 수역에 함유되어 있는 중금속 등과 같은 각종 부유물도 상당량 제거되었음을 확인할 수 있었다As a result of spraying the red tide remover of the present invention prepared in the red tide generation region, it was confirmed that the red tide is removed more than 97% even with the naked eye, and after 30 to 40 minutes it was not found at all. In addition, after the red tide was removed, the water in the water was collected and the components were analyzed. As a result, it was found that the water had the same water quality as that of the area where the red tide was not generated, and various suspended solids such as heavy metals contained in the water in addition to the red tide. Could be confirmed that a significant amount of

전술한 바와 같이 구성된 본 발명 적조 제거제에 따르면, 적조를 발생시키는 각종 조류의 필수 영양분인 질소, 인과 조류 자체를 응집하여 침전시킴으로써 조류의 증식을 효과적으로 억제시키고 결과적으로는 적조를 없앨 수 있는 효과를 가진다.According to the red tide remover of the present invention configured as described above, by agglomeration and precipitation of nitrogen, phosphorus and algae itself, which is an essential nutrient of various algae which cause red tide, has the effect of effectively suppressing algal growth and consequently eliminating red tide. .

또한, 본 발명은 조류의 필수 영양분외에도 오염 수역에 부유하는 각종 부유물질을 응집하여 침전시킴으로써 오염 수역을 정화할 수 있는 효과도 가진다.In addition, the present invention also has the effect of purifying the contaminated water by agglomeration and precipitation of various suspended substances suspended in the contaminated water in addition to the essential nutrients of algae.

아울러, 본 발명은 자체에 함유된 미네랄 성분으로 인해 원적외선을 방사함으로써 적조발생수역이나 오염수역에 서식하고 있는 각종 세균이나 해충들을 박멸하고 수생생물의 성장을 촉진시키게 된다.In addition, the present invention by extinguishing far-infrared rays due to the mineral component contained in the present invention to eradicate various bacteria and pests inhabiting red tide generating water or contaminated water and to promote the growth of aquatic organisms.

Claims (3)

퇴적암 분말 17~22 중량%, 혈암 분말 18~21 중량%, 심성암 분말 33~36 중량%, 강력응회암 분말 23~26 중량%를 포함하여 이루어진 것을 특징으로 하는 적조 제거제.Red tide remover comprising 17 to 22% by weight of sedimentary rock powder, 18 to 21% by weight shale powder, 33 to 36% by weight of plutonic rock powder, and 23 to 26% by weight strong tuff powder. 제 1 항에 있어서,The method of claim 1, 상기 퇴적암 분말, 혈암 분말, 심성암 분말, 강력응회암 분말은 325~1000mesh로 분말화된 것을 특징으로 하는 적조 제거제.Red sediment remover, characterized in that the sedimentary rock powder, shale powder, heart rock powder, strong tuff powder is powdered to 325 ~ 1000mesh. 퇴적암, 혈암, 심성암, 강력응회암을 분쇄기에 투입하여 분말화하는 단계;Depositing sedimentary rocks, shales, plutonic rocks, and strong tuffs in a grinder to powder them; 퇴적암 분말 17~22 중량%, 혈암 분말 18~21 중량%, 심성암 분말 33~36 중량%, 강력응회암 분말 23~26 중량%를 교반기로 투입하여 균일하게 교반하는 단계;17-22% by weight of sedimentary rock powder, 18-21% by weight shale powder, 33-36% by weight of plutonic rock powder, 23-26% by weight of strong tuff powder, and stirring it uniformly; 상기 퇴적암 분말, 혈암 분말, 심성암 분말, 강력응회암 분말을 교반하는 과정에서 알칼리 수용액을 교반기로 투입하고 가열하여 제올라이트를 생성하는 단계; 및Adding an aqueous alkali solution to a stirrer and heating the sedimentary rock powder, shale powder, heart rock powder, and strong tuff powder to generate zeolite; And 산성 수용액을 교반기로 투입하고 가열하여 상기 제올라이트를 이모고라이트로 전환하는 단계를 포함하여 이루어진 것을 특징으로 하는 적조 제거제의 제조방법.Injecting an acidic aqueous solution with a stirrer and heating to produce a red tide remover comprising the step of converting the zeolite to imogolite.
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