KR200399152Y1 - Socks that antibiotics and deodorizer composite are spread - Google Patents

Abstract

The present invention relates to antibacterial and deodorant socks coated with an antibacterial and deodorant composition,

It consists of a safe and effective amount of an aliphatic amino acid, a composite metal salt comprising Ag metal, an amphoteric surfactant as an optional component, an imidazole-silane reaction product having a metal trapping functional group as a binder, and a water or water miscible solvent. Manufacturing antibacterial and deodorant composition,

After immersing the antibacterial and deodorant composition in the socks to be sufficiently absorbed, the socks are removed by using a high speed dehydrator and the coated object is subjected to a crosslinking reaction and an immobilization reaction in a hot air dryer, and then uniform and solid antibacterial and deodorizing coating film. By completing the antibacterial, deodorizing socks made by forming a,

Immediate and sustained antibacterial, deodorant and antiperspirant effects during use result in improved pathogen reduction and deodorant effect upon use, as well as matrix-metalloprotease, which is particularly useful for promoting healthy skin and treating wounds Inhibitors of matrix-metalloproteinases are provided, and the amino acid combinations provide an improved healing effect on scars and skin damage so that the condition of the foot is always kept clean, clean and healthy.

Description

Antibacterial and deodorant socks coated with antibacterial and deodorant compositions {Socks that antibiotics and deodorizer composite are spread}

The present invention relates to antimicrobial and deodorant socks coated with an antibacterial and deodorant composition, and more particularly, to a safe and effective amount of an aliphatic amino acid, a composite metal salt containing Ag metal, an amphoteric surfactant as an optional component, and a binder. As an antimicrobial and deodorant composition coated with an imidazole-silane reaction product having a metal trapping functional group and an antimicrobial and deodorant composition consisting of water or a water miscible solvent, the antibacterial, deodorizing function, and antiperspirant that are used immediately and for a long time are used. It was to work.

The causes of odors occurring in human parts, especially the feet, vary somewhat from person to person, but in particular in wet, warm feet are caused during the bacterial breakdown of sweat, which is itself odorless, or by similar conditions that make microbial life better.

In other words, it can cause foot odor from long-ventilated shoe structure and socks, and if severe, can cause skin disease called Trichophyton mentagrophytes, that is, athlete's foot.

In addition, glyceride (glyceride), which is a sweat component generated in the foot, is decomposed into fatty acids and glycerin by bacteria, and a bad smell occurs in the foot.

These foot odors can also be suppressed by the use of agents that inhibit sweat release by themselves or inhibit the degradation of sweat (so-called antiperspirants, antiperspirants), and representative examples of such substances include aluminum sulfate or aluminum hydrochloride. The same aluminum compound, zinc salt, a citric acid compound, etc. are mentioned.

However, it can be seen that the use of such antiperspirant does not completely solve the problem of foot odor suppression in daily life.

In addition, there are antimicrobial socks using conventional organic antimicrobials or natural antimicrobials extracted from plants, but organic antimicrobials or natural antimicrobials are diluted with a resin binder and coated with an antimicrobial agent on the socks. When repeated washing after washing there was a problem that the coating solution is dropped and the antibacterial function is sharply dropped.

The present invention is to solve the above problems, imidazole having a safe and effective amount of an aliphatic amino acid, a complex metal salt containing Ag metal, an amphoteric surfactant as an optional component, and a metal trapping functional group as a binder- Preparing an antimicrobial and deodorant composition consisting of a silane reaction product and a water or water miscible solvent,

After the antibacterial and deodorant composition is immersed in the socks to be sufficiently absorbed, the socks are removed by using a high speed dehydrator and the coated object is subjected to a crosslinking reaction and an immobilization reaction in a hot air dryer, and then uniform and solid antibacterial and deodorizing coating film. By completing the antibacterial, deodorizing socks made by forming a,

Immediate and sustained antibacterial, deodorant, and antiperspirant effects during use result in improved pathogen reduction and deodorant effect immediately after use, as well as matrix-metalloprotease, particularly useful for promoting healthy skin and treating wounds Inhibitors of matrix-metalloproteinases are provided, and the amino acid combinations have improved healing effects on scars and skin damages, so that the condition of the feet is always kept clean, clean and healthy.

The present invention for achieving the above object is a safe and effective amount of an aliphatic amino acid, a composite metal salt comprising Ag metal, an amphoteric surfactant as an optional component, and a metal as a binder, as shown in Figure 1 Preparing an antibacterial and deodorant composition comprising an imidazole-silane reaction product having a trapping functional group and a water or water miscible solvent,

Socks in which the fibrous structure of this antimicrobial and deodorant composition is made of a blend of cotton, rayon, acetate, polyamide, or polyester / wool, polyester / cotton, polyester / rayon blends and blends, etc. (10) After soaking for 1 to 5 minutes, dehydrated in a high speed dehydrator at an appropriate wet pick-up of 20 to 50wt% to remove excess solution, and then crosslinking the workpiece to a hot air dryer at 60 to 120 ° C for 1 to 15 minutes. The antimicrobial and deodorant composition 110 is firmly fixed to the fibrous structure (socks) through the reaction and the immobilization reaction to prepare the antimicrobial and deodorant socks 100.

On the other hand, the antibacterial, deodorant composition treatment of the present invention can be treated in a variety of ways, such as processed in a refined fabric state or processed after dyeing, there is no significant difference in its functionality.

Hereinafter, a safe and effective amount of an aliphatic amino acid, a safe and effective amount of a peptide inhibitor used in the preparation of the antimicrobial and deodorant composition, in order to achieve the above object before explaining the method for preparing the antimicrobial and deodorant composition applied to socks. Complex metal salts and an imidazole-silane reaction product having a metal trapping functional group as a binder for attachment to an amphoteric surfactant and a fibrous structure (sock) in a safe and effective amount as an optional component and a water or water miscible solvent. The antimicrobial and deodorant composition will be described.

First, when describing the aliphatic amino acid, the antibacterial and deodorant composition of the present invention contains the aliphatic amino acid as a matrix-metalloproteinase inhibitor which is useful for promoting the development of healthy skin and treating wounds.

These aliphatic amino acid inhibitors are reported to play a role in inhibiting the matrix-metalloproteinases as well as promoting healing and healthy skin development in various cell types including fibroblasts, endothelial cells and keratinocytes.

The present invention provides a peptide containing composition that is also useful as a wound healing agent.

Examples of such peptide inhibitors include non-polar amino acids, cystean-like amino acids, aliphatic amino acids, acidic amino acids, aromatic amino acids, and the like. It is used in norleucine, N-methylvaline, cyclohexylalanine, β-alanine, N-methylglycine or α-aminoisobutyric acid.

The composition of the present invention preferably contains aliphatic amino acids from 0.01 wt% to about 5 wt% with respect to the weight of the composition.

This time, metal salts are explained.

Antibacterial and deodorant composition of the present invention is composed of a safe and effective amount of metal salts.

Metal salts include metal salts selected from the group consisting of Mn, Ag, Zn, Fe, Ca, Ce, Al, Ni, Ti, Zr and combinations thereof.

More specific metal salts include metal chelates and salts that do not cause abnormalities in the skin, such as bicistine complexes, bromides, chondroitin sulfates, chromides, glycerol complexes, pyrithione fluorides, and laurates. , Palmitate, oleate, iodine, nicotinate, nitrate, phosphate, sulfide, nicotinamide, acetate, arcorbate, chloride, benzoate, citrate, fumarate, gluconate, lactate, malate and these Combinations include, but are not limited to.

More preferred metal complexes with ascorbates, chlorides, Nates, gluconates, acetates, lactates, sulfates, salicylates and combinations thereof.

Without being bound by theory, it is believed that synergistic antiviral and antibacterial effects appear immediately and continuously when amino acid and metal salts form metal-acid complexes in the composition of the present invention.

In the antimicrobial and deodorant composition of the present invention, the metal salt contains the last metal ion in an amount of 0.001 wt% to 2 wt% by weight of the composition.

Next, safe and effective amounts of amphoteric surfactants are described as optional ingredients.

The antimicrobial and deodorant composition of the present invention preferably contains an ampholytic surfactant in addition to amino acids and complex metal salts.

Amphoteric surfactants useful in the antimicrobial and deodorant compositions of the present invention contain organic amino groups and one or more -COOH- or -SO ₃ H groups in addition to C ₈ N ₈ alkyl or acyl groups in the molecule to form inert salts. It is a surface active compound which can be.

Examples of suitable amphoteric surfactants include N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyl acid, N-alkylaminopropionic acid, N-hydroxyethyl-N-alkylamino having 8 to 18 carbon atoms in the alkyl group Propylglycine, N-alkyltaurine, N-alkylsacosine, 2-alkylaminopropionic acid and alkylaminoacetic acid, with particularly preferred amphoteric surfactants being -N-cocoalkylaminopropionate, cocoacylaminoethyl, aminopropionate And C _{12/18 acylsacosine} .

The amount of amphoteric surfactant used in the antimicrobial and deodorant composition of the present invention is about 0.01 wt% to 0.2 wt% by weight of the composition.

This time the imidazole-silane coupling agent binder is demonstrated.

The antimicrobial and deodorant composition of the present invention includes an imidazole-silane compound binder which can improve the adhesion of the organic-inorganic hybrid antimicrobial and deodorant material to the fiber structure, that is, the socks.

The said imidazole-silane compound is obtained by making an imidazole compound and the silane compound which has glycidoxy group react at 80-100 degreeC, and then reacting with an organic monocarboxylic acid at 50-80 degreeC.

That is, by adhering a metal salt to the silane-coupling agent which has a metal trapping functional group in a molecule | numerator, it improves the adhesive strength with a fiber structure.

As said imidazole compound, it is a nitrogen-containing heterocyclic azole compound, and an imidazole, 2-methylimidazole, 2-ethylimidazole, 2-undecyl imidazole, 2-ethyl-4-methylimidazole, etc. Can be mentioned.

Silane compounds having a glycidoxy group include 3-glycidoxypropyltriethoxysilane, 3-glycidoxypropyldimethoxymethylsilane, and 3-glycidoxypropylethoxydimethylsilane.

Examples of the organic monocarboxylic acid are acrylic acid, methacrylic acid, isobutyric acid, octylic acid, formic acid, glycic acid, acetic acid, propionic acid, benzoic acid, salicylic acid, cyclohexanecarboxylic acid, toluic acid, phenylacetic acid, methanesulfonic acid, toluenesulfonic acid Can be mentioned.

As the solvent, water and water miscible solvents, for example, methanol, ethanol, propanol, isopropanol, alcohols such as glycols, ketones such as acetone and methyl ethyl ketone, N, N-dimethylformamide, N, N-dimethyl Amides such as acetamide, N-methylpyrrolidone can be used as a solvent in the solution according to the present invention.

The content of the imidazole-silane reaction product has a composition of 0.01 wt% to 4 wt% based on the total coating solution.

Hereinafter will be described in more detail based on the embodiment of the antimicrobial, deodorant socks excellent washing fastness using the antibacterial, deodorant composition as described above.

(Example)

Aliphatic amino acid alanine (L-Alanine, C ₃ H ₇ NO ₂ ) 0.1wt%, complex metal salt 0.5wt%, amphoteric surfactant N-alkylpropionic acid 0.05wt%, imidazole-silane compound 1.2wt%, miscibility After reacting 2wt% solvent and 91.5∼92wt% of distilled water to prepare an antibacterial and deodorant composition,

After immersing cotton socks for 5 minutes in the antimicrobial and deodorant composition prepared in this way, dewatering with a high speed dehydrator for 1 minute to remove the excess solution, and then drying the coated object at 100 ° C. for 5 minutes with hot air drying, and having excellent washing fastness. The antimicrobial and deodorant socks coated with the composition were obtained.

Antibacterial, deodorant socks of the present invention obtained by one embodiment as described above,

Aliphatic amino acids, which are matrix-metalloproteinase inhibitors that promote the development of healthy skin and treat wounds, not only inhibit matrix-metalloproteinases but also fibroblasts, endothelial cells, and keratinocytes. It promotes healing and healthy skin development in many cell types, including cells.

In addition, amino acids and metal salts form metal-acid complexes, resulting in synergistic antiviral and antibacterial effects that are immediate and persistent.

On the other hand, by attaching a metal salt to the silane-coupling agent having a metal-encapsulating functional group in the molecule, the adhesion strength with the fiber structure is greatly improved and the washing fastness is excellent. Because of its action, it has improved pathogen reduction and deodorizing effect immediately after use, and especially promotes the development of healthy skin and heals wounds.

The antimicrobial and deodorant composition treatment of the present invention can be treated in various ways, such as treatment in a refined fabric state or in a dyeing process and there is no significant difference in its functionality.

For reference, the antibacterial activity and deodorization rate (deodorization rate) of the sock coated with the antimicrobial and deodorant composition of the present invention are described.

(2) Pictures of antimicrobial activity test results of control specimens and test specimens for test bacteria 1 (test bacteria 1)

(3) Pictures of antimicrobial activity test results of control and test pieces against test bacteria 2 (test bacteria 2)

(4) Ammonia deodorization rate (deodorization rate) test result table

(5) Ammonia deodorization rate increase and decrease graph

As described above, the socks treated by the antibacterial and deodorant composition according to the present invention used representative Gram-positive bacteria, Staphylococcus aureus and Gram-negative bacteria, pneumococcal bacteria, and the gas test was conducted with ammonia gas.

Both the staphylococcus aureus and pneumococcal bacterium showed antimicrobial activity of 99.9% even after 30 washes, and the deodorization rate of ammonia gas was 98% with time.

Therefore, the sock coated with the antibacterial and deodorant composition of the present invention performs an immediate and continuous antibacterial, antiviral, and deodorizing function to show an improved pathogen reduction and deodorizing effect, and in particular, promotes the development of healthy skin and treats wounds by athlete's foot. You can see the zoom.

The present invention is an antibacterial and deodorizing sock coated with an antibacterial and deodorant composition, which is not only immediate but also has a long-term washing effect and has a continuous antibacterial and high deodorizing function.

That is, the antimicrobial and deodorant socks coated with the antimicrobial and deodorant composition of the present invention exhibit a continuous effect not previously seen against Gram-negative bacteria, Gram-positive bacteria, and virus bacteria, and immediately reduce the use of detoxification and deodorizing effects. Indicates.

In addition, matrix-metalloproteinase inhibitors are provided which are particularly useful for promoting the development of healthy skin and for treating wounds, and have an improved healing effect on scars and skin damage by amino acid combinations .

Therefore, the present invention is a very innovative design that can always keep the state of the foot clean, clean and healthy.

Figure 1 is an exemplary state of the present invention antibacterial, deodorant socks.

♣ Explanation of symbols for the main parts of the drawing

10: Socks 100: Antibacterial, deodorant socks

110: antibacterial, deodorant composition

Claims (5)

Aliphatic amino acid 0.01wt% ~ 5wt%, single or complex metal salt 0.001wt% ~ 2wt%, amphoteric surfactant 0.01wt% ~ 0.2wt%, imidazole-silane compound 0.01wt% ~ 4wt%, miscible solvent 2wt%, After dipping the antibacterial and deodorant composition manufactured by reacting distilled water (the rest wt%), the socks made of fiber material were immersed and dehydrated with a high speed dehydrator to remove the excess solution. Antibacterial and deodorant socks coated with an antibacterial and deodorant composition characterized by forming a coating layer of antibacterial and deodorant composition having a continuous antibacterial and a high deodorizing function on the fiber surface of the socks by drying with hot air for a minute. delete. delete. delete. delete.