KR200346604Y1 - Spread textile of fire retardant - Google Patents

Spread textile of fire retardant Download PDF

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Publication number
KR200346604Y1
KR200346604Y1 KR20-2004-0000287U KR20040000287U KR200346604Y1 KR 200346604 Y1 KR200346604 Y1 KR 200346604Y1 KR 20040000287 U KR20040000287 U KR 20040000287U KR 200346604 Y1 KR200346604 Y1 KR 200346604Y1
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South Korea
Prior art keywords
fabric
flame retardant
coating
flame
present
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KR20-2004-0000287U
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Korean (ko)
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권의용
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권의용
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Priority to KR20-2004-0000287U priority Critical patent/KR200346604Y1/en
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Publication of KR200346604Y1 publication Critical patent/KR200346604Y1/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)

Abstract

본 고안은 난연성 도포 직물에 관한 것으로서, 보다 상세하게는 난연직물인 폴리에스테르섬유, 폴리올레핀섬유, 폴리아라미드섬유에 탄성중합체 합성물을 코팅하여 난연성이 우수한 난연성 도포 직물을 제조하는 것에 관한 것이다.The present invention relates to a flame retardant coated fabric, and more particularly, to a flame retardant coated fabric having excellent flame retardancy by coating an elastomeric composite on a polyester fiber, a polyolefin fiber, a polyamide fiber, which is a flame retardant fabric.

상기에서 서술한 바와 같이 본 고안은 난연성 도포 직물에 관한 것으로서, 탄성중합체의 합성물이 우수한 망상구조로 형성되어 있어 직물과 코팅시 견고함과 부착성에 탁월한 효과가 있으며, 난연성 도포 직물이 천막, 철도차량, 지하철, 버스, 비행기의 연결 부재 등에 이용되어 화재 발생시 유독가스가 발생되지 않는 효과를 가져온다.As described above, the present invention relates to a flame retardant coated fabric, and has an excellent composite structure of an elastomeric composite having a network structure, and has excellent effects on the strength and adhesion of the fabric and the coating. It is used for connecting members of subways, buses, airplanes, etc., which brings the effect that no toxic gas is generated in case of fire.

Description

난연성 도포 직물{Spread textile of fire retardant}Spread textile of fire retardant

본 고안은 난연성 도포 직물에 관한 것으로서, 보다 상세하게는 난연직물인 폴리에스테르섬유, 폴리올레핀섬유, 폴리아라미드섬유에 탄성중합체 합성물을 코팅하여 난연성이 우수한 난연성 도포 직물을 제조하는 것에 관한 것이다.The present invention relates to a flame retardant coated fabric, and more particularly, to a flame retardant coated fabric having excellent flame retardancy by coating an elastomeric composite on a polyester fiber, a polyolefin fiber, a polyamide fiber, which is a flame retardant fabric.

종래의 난연성 직물은 난연처리된 직물을 사용하거나, 직물의 표면에 난연제를 처리하여 사용하였다.Conventional flame retardant fabrics are used by using a flame-retardant fabric, or by treating the surface of the fabric with a flame retardant.

그러나, 종래의 화학섬유 또는 직물에 난연 처리하기 때문에 화학섬유의 표면이나 직물의 표면에 난연제가 부착되어 있어 사용되는 시간에 따라 난연제의 탈락이 발생하기 쉬우며, 난연제의 탈락에 의해 난연 능력이 저하되는 단점이 있다.However, since a flame retardant is applied to a conventional chemical fiber or fabric, a flame retardant is attached to the surface of the chemical fiber or the fabric, so that the flame retardant may easily fall off depending on the time used, and the flame retardant ability is reduced by the drop of the flame retardant. There is a disadvantage.

이러한 이유로 본 고안은 난연성 도포 직물인 폴리에스테르섬유, 폴리올레핀섬유, 폴리아라미드섬유의 표면에 탄성중합체의 합성물을 코팅하여 합성물이 직물에 견고하게 반응하여 부착성이 우수한 난연성 도포 직물을 얻는데 있다.For this reason, the present invention is to obtain a flame-retardant coating fabric excellent in adhesion by coating the composite of the elastomer on the surface of the polyester fiber, polyolefin fibers, polyaramid fibers, which is a flame-retardant coating fabric.

또한, 우수한 부착력에 의해 난연성 직물의 표면에 코팅물이 탈락되지 않고 시간이 지남에 따라 그 견고함이 우수해지는 것에 있다.In addition, the coating is not dropped on the surface of the flame-retardant fabric by the excellent adhesion, the durability is excellent over time.

상기와 같은 문제점을 해결하기 위해 난연성 도포 직물의 코팅물 부착성 향상과 직물의 난연성이 우수한 기능을 부가한 난연성 도포 직물을 제공하는 데 그 목적이 있다.In order to solve the above problems, an object of the present invention is to provide a flame retardant coated fabric having a function of improving coating adhesion of the flame retardant coated fabric and excellent flame retardancy of the fabric.

도 1은 본 고안의 난연성 도포 직물의 구조도1 is a structural diagram of the flame retardant coating fabric of the present invention

<도면의 주요부분에 대한 부호의 설명><Description of the code | symbol about the principal part of drawing>

난연직물 : 1 탄성중합체 합성물 : 2a, 2bFlame Retardant Fabric: 1 Elastomer Composite: 2a, 2b

상기와 같은 목적을 달성하기 위해 본 고안은 폴리에스테르섬유, 폴리올레핀섬유, 폴리아라미드섬유 중 하나를 선택한 난연직물(1)에 있어서, 상기 난연직물(1)의 양쪽면에 폴리디메틸시록산(PDMS) 10-20중량부, 하이드로겐폴리실록산(Organohydrogenpolysiloxane) 30-40중량부, 실리콘 수지 40-60중량부의 탄성중합체 합성물(2a, 2b)로 코팅하는 것을 구성하는 난연성 도포 직물에 관한 것이다.In order to achieve the above object, the present invention is a flame retardant fabric (1) selected from polyester fibers, polyolefin fibers, polyaramid fibers, polydimethylsiloxane (PDMS) on both sides of the flame retardant fabric (1) A flame retardant coated fabric comprising 10-20 parts by weight, 30-40 parts by weight of an organohydrogenpolysiloxane, and 40-60 parts by weight of an silicone resin (2a, 2b).

본 고안의 바람직한 실시예를 제공하기 위해 첨부한 도면을 참조하여 상세히 설명하면 다음과 같다.When described in detail with reference to the accompanying drawings to provide a preferred embodiment of the present invention.

도 1은 본 고안의 난연성 도포 직물의 구조도이다.1 is a structural diagram of a flame retardant coated fabric of the present invention.

도 1은 본 고안의 난연성 도포 직물의 단면도이며, 난연직물(1)의 양쪽면에 폴리디메틸시록산(PDMS) 10-20중량부, 하이드로겐폴리실록산(Organohydrogenpolysiloxane) 30-40중량부, 실리콘 수지 40-60중량부의 탄성중합체 합성물(2a, 2b)을 코팅하여 난연성 도포 직물이 제조된다.1 is a cross-sectional view of the flame retardant coated fabric of the present invention, 10-20 parts by weight of polydimethylsiloxane (PDMS), 30-40 parts by weight of organohydrogenpolysiloxane, silicone resin 40 on both sides of the flame retardant fabric (1) A flame retardant coated fabric is made by coating -60 parts by weight of elastomeric composite 2a, 2b.

상기 폴리디메틸시록산(PDMS), 하이드로겐폴리실록산(Organohydrogenpolysiloxane), 실리콘 수지의 탄성중합체 합성물(2a, 2b)이 반응하는 반응기를 하기와 같이 반응 구조식을 갖는다.The reactor in which the polydimethylsiloxane (PDMS), hydrogengen polysiloxane (Organohydrogenpolysiloxane), and the elastomeric composites 2a and 2b of the silicone resin are reacted has a reaction formula as follows.

상기의 반응식에 따라 탄성중합체의 합성물(2a, 2b)은 아주 견고한 망상구조를 가지고 있으며, 상기 탄성중합체의 합성물이 난연직물에 코팅되면 그 부착성과견고성이 강력하게 부여되게 된다.According to the above reaction scheme, the composites 2a and 2b of the elastomer have a very solid network structure, and when the composite of the elastomer is coated on the flame retardant fabric, its adhesion and robustness are strongly imparted.

상기 본 고안에 의해 제조된 난연성 도포 직물에 대하여 아래와 같은 시험방법에 의해 난연성 시험을 하였다.The flame retardant test was performed on the flame retardant coated fabric prepared according to the present invention by the following test method.

본 고안의 난연성 시험방법(BS(British Standard) 6853 : 승객수송용 열차의 모양과 구조물에 대한 난연성시험방법)에 의해 얻어진 결과를 하기의 표-1에 나타내었다.The results obtained by the flame retardancy test method (BS (British Standard) 6853: flame retardancy test method for the shape and structure of passenger transport train) of the present invention are shown in Table-1 below.

상기 표-1에서 본 고안의 유독성값의 수치는 0.365로써 난연성 시험방법(BS 6853)의 기준 유독성값을 1.0이하로 규정하고 있다.In Table-1, the toxic value of the present invention is 0.365, and the standard toxic value of the flame retardancy test method (BS 6853) is defined as 1.0 or less.

따라서 본 고안의 유독성값은 약 0.4로서 난연성 시험방법에 의해 그 우수성을 입증하였다.Therefore, the toxicity value of the present invention was about 0.4, which proved its superiority by the flame retardancy test method.

상기와 같은 방법으로 제조된 난연성 도포 직물인 일명 크린탑(Cleantarp)이라 명명하는 본 고안의 난연성 도포 직물은 천막, 철도차량, 지하철, 버스, 비행기의 연결부용 부재 등의 재료로 사용됨으로써 화재시 발생되는 유독가스를 줄이는 역할을 하며, 상기 직물 표면에 코팅된 탄성중합체 합성물의 반응이 직물과 활성화 되어 코팅력이 우수하여 직물과 코팅물과의 박리현상을 없애준다.The flame-retardant coating fabric of the present invention, called the cleantarp, which is a flame-retardant coating fabric manufactured by the above method, is used as a material for tents, railway vehicles, subways, buses, airplanes, etc. It serves to reduce the toxic gas, and the reaction of the elastomeric composite coated on the surface of the fabric is activated with the fabric and excellent coating power to eliminate the peeling phenomenon of the fabric and the coating.

상기에서 서술한 바와 같이 본 고안은 난연성 도포 직물에 관한 것으로서, 탄성중합체의 합성물이 우수한 망상구조로 형성되어 있어 직물과 코팅시 견고함과 부착성에 탁월한 효과가 있으며, 난연성 도포 직물이 천막, 철도차량, 지하철, 버스, 비행기의 연결 부재 등에 이용되어 화재 발생시 유독가스가 발생되지 않는 효과를 가져온다.As described above, the present invention relates to a flame retardant coated fabric, and has an excellent composite structure of an elastomeric composite having a network structure, and has excellent effects on the strength and adhesion of the fabric and the coating. It is used for connecting members of subways, buses, airplanes, etc., which brings the effect that no toxic gas is generated in case of fire.

Claims (1)

폴리에스테르섬유, 폴리올레핀섬유, 폴리아라미드섬유 중 하나를 선택한 난연직물(1)에 있어서,In the flame retardant fabric (1) which selected one of polyester fiber, polyolefin fiber, and poly aramid fiber, 상기 난연직물(1)의 양쪽면에 폴리디메틸시록산(PDMS) 10-20중량부, 하이드로겐폴리실록산(Organohydrogenpolysiloxane) 30-40중량부, 실리콘 수지 40-60중량부의 탄성중합체 합성물(2a, 2b)로 코팅하는 것을 특징으로 하는 난연성 도포 직물10-20 parts by weight of polydimethylsiloxane (PDMS), 30-40 parts by weight of organohydrogenpolysiloxane, and 40-60 parts by weight of silicone resin (2a, 2b) on both sides of the flame retardant fabric (1) Flame retardant coated fabric, characterized in that the coating
KR20-2004-0000287U 2004-01-03 2004-01-03 Spread textile of fire retardant KR200346604Y1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100806164B1 (en) 2006-10-11 2008-02-22 전경섭 Method for manufacturing silicon products
KR101059554B1 (en) 2009-04-23 2011-08-26 지엔씨중공업(주) Manufacturing method of gangway bellows material for vehicles and the material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100806164B1 (en) 2006-10-11 2008-02-22 전경섭 Method for manufacturing silicon products
KR101059554B1 (en) 2009-04-23 2011-08-26 지엔씨중공업(주) Manufacturing method of gangway bellows material for vehicles and the material

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