KR200305722Y1 - Electrolytic bath for producing sterilizing water - Google Patents

Electrolytic bath for producing sterilizing water Download PDF

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Publication number
KR200305722Y1
KR200305722Y1 KR20-2002-0035694U KR20020035694U KR200305722Y1 KR 200305722 Y1 KR200305722 Y1 KR 200305722Y1 KR 20020035694 U KR20020035694 U KR 20020035694U KR 200305722 Y1 KR200305722 Y1 KR 200305722Y1
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South Korea
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water
cathode
electrolytic cell
anode
chamber
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KR20-2002-0035694U
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Korean (ko)
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권순선
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주식회사 동양과학
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Abstract

본 고안은 살균수 생성을 위한 전해 장치에 관한 것으로, 특히 이온수 전해 장치를 이용하여 소독수로 사용될 수 있는 차아염소산(HClO)과 과산화수소(H2O2)를 다량 생성할 수 있는 전해 장치를 개시한다. 본 고안은 약산성으로부터 알칼리성 산도 1 ~ 16 ppm 의 유료 염도 및 낮은 레벨에서 높은 레벨까지의 산화 환원 전위를 갖는 전해수를 생성하는 것이 가능하도록 하며, 특히 다량의 차아염소산과 과산화수소수를 동시에 얻을 수 있도록 하는 장점이 있다.The present invention relates to an electrolytic device for producing sterile water, and more particularly, to an electrolytic device capable of generating a large amount of hypochlorous acid (HClO) and hydrogen peroxide (H 2 O 2 ) that can be used as disinfectant water using an ionized water electrolytic device. . The present invention makes it possible to produce electrolytic water having a toll salinity of 1 to 16 ppm of alkaline acidity and a redox potential from a low level to a high level, and in particular, a large amount of hypochlorous acid and hydrogen peroxide can be obtained simultaneously. There is an advantage.

Description

살균수 생성 전해조{ELECTROLYTIC BATH FOR PRODUCING STERILIZING WATER}ELECTROLYTIC BATH FOR PRODUCING STERILIZING WATER}

본 고안은 살균수 생성을 위한 전해 장치에 관한 것으로, 특히 차아 염소산(HCLO)과 과산화수소(H2O2)를 다량 생성할 수 있는 전해 장치를 제공한다.The present invention relates to an electrolytic device for producing sterilized water, and in particular, to provide an electrolytic device capable of generating a large amount of hypochlorous acid (HCLO) and hydrogen peroxide (H 2 O 2 ).

흔히 시증에서 사용되어지는 이온수 생성기는 수도물 등을 정수기로 정수한 다음, 전기적 성질을 지닌 이온만 통과할 수 있는 격벽(4)에 의해 양극실과 음극실로 구분되어진 전해로에 층만시키고, 여기에 전압을 인가하여 물을 전개 분해시켜 이온수를 생성하고 있다.Ion water generators, which are often used in test systems, purify tap water with water purifiers, and then layer only in an electrolytic furnace divided into an anode chamber and a cathode chamber by partition walls 4 through which only ions having electrical properties can pass. It is applied to develop and decompose water to generate ionized water.

이 때에, 양극실에서는 수산이본이 환원되어 염소, 인, 유황 등의 음이온이 산을 형성하여, 양극실의 물은 산성을 띠게 되고, 음극실에서는 수소 이온이 환원되며 나트륨, 마그네슘 등의 양이온의 수소이온 쌍을 형성하면서 음극실의 용액은 염기성을 띠게 된다.At this time, the oxygen carbonate is reduced in the anode chamber, and anions such as chlorine, phosphorus, and sulfur form an acid, and the water in the cathode chamber becomes acidic, and hydrogen ions are reduced in the cathode chamber, and cations such as sodium and magnesium are reduced. The solution in the cathode chamber becomes basic while forming a pair of hydrogen ions.

그런데, 종래 기술에 따른 이온 수기에서 배출되는 산성수는 산도(pH)가 3.5 내지 4.5 정도이며 산화 환원 전위(ORP ; oxidution reduction potential)이 +600 mV에서 +700 mV 정도이므로, 의료용 소독수로서 사용되기에는 부족함이 있다.However, the acidic water discharged from the ionizer according to the prior art has an acidity (pH) of about 3.5 to 4.5 and an oxidation reduction potential (ORP) of about +600 mV to +700 mV, so that it may be used as medical disinfectant water. There is a shortage.

즉, 미생물의 생존 범위가 ORP의 경우 약 +900 mV에서 -400 mV이고, pH는 3 ~ 10 임을 감안할 때에, pH가 약 2.7 이하이고 ORP가 +1000 mV 이상이 되는 강한 살균력을 지닌 산성수를 생성하는 것이 필요하다.That is, considering that the survival range of the microorganism is about +900 mV to -400 mV for the ORP, and the pH is 3 to 10, the acidic water having strong sterilizing power with the pH of about 2.7 or less and the ORP being +1000 mV or more It is necessary to produce.

따라서, 본 고안의 제1 목적은 농약 대체용으로 또는 병원 의료기구의 소독 등을 포함한 용도로서 강한 살균력을 지닌 산성수를 생성하는 살균수 생성 전해조를 제공하는데 있다.Accordingly, a first object of the present invention is to provide a sterilizing water generating electrolyzer for producing acidic water having strong sterilizing power as a substitute for pesticide or use including disinfection of hospital medical equipment.

본 고안의 제2 목적은 상기 목적에 부가하여, 생성 전해수 내에 염소 이온 농도가 낮으면서도 강한 살균력을 지닌 강 산성수를 생성하는 살균슈 생성 전해조 장치를 제공하는데 있다.A second object of the present invention is to provide a sterilization shoe generating electrolyzer which generates strong acidic water with a strong sterilizing power while having a low concentration of chlorine ions in the generated electrolytic water.

<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>

4 : 격벽4: bulkhead

10b, 11a : 음극10b, 11a: cathode

10a, 11b : 양극10a, 11b: anode

15 : 원수15: enemies

16 : 제1 전해조 양극실 유입공16: inlet hole of the first electrolytic cell anode chamber

17 : 제1 전해조 양극실 출구17: outlet of the first electrolytic cell anode chamber

18 : 제2 전해조 음극실 유입공18: inlet hole of the second electrolytic cell cathode chamber

19 : 제2 전해조 음극실 출구19: outlet of the second electrolytic cell cathode chamber

26 : 제1 전해조 음극실 유입공26: first electrolytic cell cathode chamber inlet hole

27 : 제1 전해조 음극실 출구27: outlet of the first electrolytic cell cathode chamber

28 : 제2 전해조 양극실 유입공28: second electrolytic cell anode chamber inlet hole

29 : 제2 전해조 양극실 출구29: outlet of the second electrolytic cell anode chamber

30, 40 : 음극실30, 40: cathode chamber

20, 50 : 양극실20, 50: anode chamber

70, 80 : 격막70, 80: diaphragm

상기 목적을 달성하기 위하여, 본 고안은 격막을 사이에 두고 양극실과 음극실로 분리 구성되고, 양극실에 양전극과 음극실에 음전극을 설치하여 각각 양극실 유입공과 음극실 유입공을 통해 유입된 원수를 전기분해하여 각각 양극실 출구에서는 산성수를, 음극실 출구에서는 알칼리수를 배출하는 제1 전해조와; 상기 제1 전해조와 동일한 형태의 격막, 양극실, 음극실, 양전극 및 음전극을 구비하되, 양극실 유입공은 상기 제1 전해조의 음극실 출구와 연결되어 알칼리수를 공급받고, 음극실 유입공은 상기 제1 전해조의 양극실 출구와 연결되어 산성수를 공급받아 전기분해를 수행하여, 각각 양극실 출구에서는 차아염소산을, 음극실 출구에서는 과산화수소수를 배출하는 제2 전해조를 케스케이드하여 구성된 살균수 생성 전해 수기를 제공한다.In order to achieve the above object, the present invention is divided into a cathode chamber and a cathode chamber with a diaphragm interposed therebetween, and a cathode electrode is installed in the anode chamber and the cathode chamber in the anode chamber to respectively receive raw water introduced through the anode chamber inlet hole and the cathode chamber inlet hole. A first electrolytic cell that electrolyzes to discharge acidic water at the outlet of the anode chamber and alkaline water at the outlet of the cathode chamber, respectively; A diaphragm, an anode chamber, a cathode chamber, a cathode electrode, and a cathode of the same type as the first electrolytic cell are provided, and the anode chamber inlet is connected to the cathode chamber outlet of the first electrolytic cell to receive alkaline water, and the cathode chamber inlet is It is connected with the outlet of the anode chamber of the first electrolytic cell and is subjected to electrolysis to perform electrolysis, and each of the cathode chambers cascades a second electrolytic cell which discharges hypochlorous acid and at the outlet of the cathode chamber, hydrogen peroxide water. Provide handwriting.

이하에서는 첨부 도면 도1을 참조하여 본 고안의 양호한 실시예를 상세히 설명한다.Hereinafter, with reference to the accompanying drawings Figure 1 will be described in detail a preferred embodiment of the present invention.

도1을 참조하면, 본 고안에 따른 살균수 생성 전해 수기는 양극실(20), 음극실(30) 및 격막(70)으로 구성된 제1 전해조와, 양극실(50), 음극실(40) 및 격막 (80)으로 구성된 제2 전해조를 서로 케스케이드 연결함으로써 구성된다.Referring to FIG. 1, the sterilizing water generating electrolytic water according to the present invention includes a first electrolytic cell including an anode chamber 20, a cathode chamber 30, and a diaphragm 70, an anode chamber 50, and a cathode chamber 40. And the second electrolytic cell composed of the diaphragm 80 cascaded to each other.

즉, 제1 전해조의 양극실 출구(17)는 제2 전해조의 음극실 유입공(18)과 연결되고, 제1 전해조의 음극실 출구(27)는 제2 전해조의 양극실 유입공(28)과 연결된다.That is, the anode chamber outlet 17 of the first electrolytic cell is connected to the cathode chamber inlet hole 18 of the second electrolytic cell, and the cathode chamber outlet 27 of the first electrolytic cell is the anode chamber inlet 28 of the second electrolytic cell. Connected with

다시 도1을 참조하면, 수도물 또는 정류된 물 등과 같은 원수(15)가 제1 전해조의 양극실 유입공(16)과 음극실 유입공(26)으로 유입되면, 양극실(20)과 음극실(30)에서는 전기분해가 수행된다.Referring back to FIG. 1, when raw water 15 such as tap water or rectified water flows into the anode chamber inlet 16 and the cathode chamber inlet 26 of the first electrolytic cell, the anode chamber 20 and the cathode chamber At 30, electrolysis is performed.

따라서, 제1 전해조의 양극실(20)에서는 물로부터 산소와 수소 이온이 생성되고, 염소이온으로부터 염소가 생성된다Therefore, in the anode chamber 20 of the first electrolytic cell, oxygen and hydrogen ions are generated from water and chlorine is generated from chlorine ions.

한편, 제1 전해조의 음극실(30)에서는 수소 이온 H+이 음극(10b)으로부터 전자를 빼앗아 수소 분자(H2)로 되어 공기 중으로 날아가 버리기 때문에 수산 이온 (OH-)이 증가하여 물은 알칼리수가 된다.On the other hand, in the cathode chamber 30 of the first electrolytic cell, since hydrogen ions H + take electrons from the cathode 10b to form hydrogen molecules (H 2 ) and fly off into the air, the hydroxyl ions (OH ) are increased so that the water is alkaline water. Becomes

한편, 제1 전해조의 음극실 출구(27)는 제2 전해조의 양극실 유입공(28)과 연결되어, 제2 전해조의 양극실(50)에서는 수산 이온(OH-)은 양극(11b)에 전자를 빼앗기게 되고, 차아염소산(70)이 다량 발생하여 양극실 출구(29)를 통해 배출된다.On the other hand, the cathode chamber outlet 27 of the first electrolytic cell is connected to the anode chamber inlet 28 of the second electrolytic cell, and in the anode chamber 50 of the second electrolytic cell, hydroxyl ions OH − are supplied to the anode 11b. The electrons are taken away, and a large amount of hypochlorous acid 70 is generated and discharged through the anode chamber outlet 29.

전술한 내용은 후술할 발명의 특허 청구 범위를 보다 잘 이해할 수 있도록 본 발명의 특징과 기술적 장점을 다소 폭넓게 개설하였다. 본 발명의 특허 청구 범위를 구성하는 부가적인 특징과 장점들이 이하에서 상술될 것이다. 개시된 본발명의 개념과 특정 실시예는 본 발명과 유사 목적을 수행하기 위한 다른 구조의 설계나 수정의 기본으로서 즉시 사용될 수 있음이 당해 기술 분야의 숙련된 사람들에 의해 인식되어야 한다.The foregoing has outlined rather broadly the features and technical advantages of the present invention to better understand the claims of the invention which will be described later. Additional features and advantages that make up the claims of the present invention will be described below. It should be appreciated by those skilled in the art that the conception and specific embodiments of the disclosed subject matter can be used immediately as a basis for designing or modifying other structures for carrying out similar purposes to the present invention.

또한, 본 발명에서 개시된 발명 개념과 실시예가 본 발명의 동일 목적을 수행하기 위하여 다른 구조로 수정하거나 설계하기 위한 기초로서 당해 기술 분야의 숙련된 사람들에 의해 사용되어질 수 있을 것이다. 또한, 당해 기술 분야의 숙련된 사람에 의한 그와 같은 수정 또는 변경된 등가 구조는 특허 청구 범위에서 기술한 발명의 사상이나 범위를 벗어나지 않는 한도 내에서 다양한 변화, 치환 및 변경이 가능하다.In addition, the inventive concepts and embodiments disclosed herein may be used by those skilled in the art as a basis for modifying or designing other structures for carrying out the same purposes of the present invention. In addition, such modifications or altered equivalent structures by those skilled in the art may be variously changed, substituted, and changed without departing from the spirit or scope of the invention described in the claims.

이상과 같이, 본 고안은 약산성으로부터 알칼리성 산도 1 ~ 16 ppm 의 유료염도 및 낮은 레벨에서 높은 레벨까지의 산화 환원 전위를 갖는 전해수를 생성하는 것이 가능하며, 차아염소산과 과산화수소수를 동시에 얻을 수 있는 장점이 있다.As described above, the present invention is capable of producing electrolyzed water having a redox potential from a weak acidity to an alkaline acidity of 1 to 16 ppm and a redox potential from a low level to a high level, and can simultaneously obtain hypochlorous acid and hydrogen peroxide water. There is this.

Claims (1)

격막을 사이에 두고 양극실과 음극실로 분리 구성되고, 양극실에 양전극과 음극실에 음전극을 설치하여 각각 양극실 유입공과 음극실 유입공을 통해 유입된 원수를 전기분해하여 각각 양극실 출구에서는 산성수를, 음극실 출구에서는 알칼리수를 배출하는 제1 전해조와;It is composed of the anode and cathode chambers with the diaphragm in between, and the anode and cathode chambers are installed in the anode chamber to electrolyze raw water introduced through the anode and cathode chamber inlets, respectively. A first electrolytic cell for discharging alkaline water at the cathode chamber outlet; 상기 제1 전해조와 동일한 형태의 격막, 양극실, 음극실, 양전극 및 음전극을 구비하되, 양극실 유입공은 상기 제1 전해조의 음극실 출구와 연결되어 알칼리수를 공급받고, 음극실 유입공은 상기 제1 전해조의 양극실 출구와 연결되어 산성수를 공급받아 전기분해를 수행하여, 각각 양극실 출구에서는 차아염소산을, 음극실 출구에서는 과산화수소수를 배출하는 제2 전해조A diaphragm, an anode chamber, a cathode chamber, a cathode electrode, and a cathode of the same type as the first electrolytic cell are provided, and the anode chamber inlet is connected to the cathode chamber outlet of the first electrolytic cell to receive alkaline water, and the cathode chamber inlet is A second electrolytic cell connected to the anode chamber outlet of the first electrolytic cell to receive acidic water for electrolysis, each of which discharges hypochlorous acid at the anode chamber outlet and hydrogen peroxide solution at the cathode chamber outlet; 를 케스케이드하여 구성된 살균수 생성 전해 수기.An electrolytic water generator that produces sterile water composed by cascading.
KR20-2002-0035694U 2002-11-29 2002-11-29 Electrolytic bath for producing sterilizing water KR200305722Y1 (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
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KR100825489B1 (en) 2006-08-25 2008-04-25 박상길 An electrolyzer
KR100954028B1 (en) 2007-09-20 2010-04-20 광주과학기술원 Apparatus for treating wastewater using electrochemical reactor with immobilized peroxidase and method thereof
KR101187433B1 (en) * 2010-08-10 2012-10-02 (주) 테크윈 A production system of a disinfection compound
WO2013058497A1 (en) * 2011-10-21 2013-04-25 Lim Dong Won Three-compartment-cell one-port type electrolysis apparatus
KR101947687B1 (en) * 2017-09-06 2019-02-14 (주) 테크로스 Water treatment device using electrolysis and heterogeneous catalytic oxidation reaction
WO2019050079A1 (en) * 2017-09-06 2019-03-14 (주) 테크로스 Water treatment apparatus for simultaneously generating hydrogen peroxide and hypochlorite ion

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100825489B1 (en) 2006-08-25 2008-04-25 박상길 An electrolyzer
KR100954028B1 (en) 2007-09-20 2010-04-20 광주과학기술원 Apparatus for treating wastewater using electrochemical reactor with immobilized peroxidase and method thereof
KR101187433B1 (en) * 2010-08-10 2012-10-02 (주) 테크윈 A production system of a disinfection compound
WO2013058497A1 (en) * 2011-10-21 2013-04-25 Lim Dong Won Three-compartment-cell one-port type electrolysis apparatus
KR101947687B1 (en) * 2017-09-06 2019-02-14 (주) 테크로스 Water treatment device using electrolysis and heterogeneous catalytic oxidation reaction
WO2019050079A1 (en) * 2017-09-06 2019-03-14 (주) 테크로스 Water treatment apparatus for simultaneously generating hydrogen peroxide and hypochlorite ion
WO2019050078A1 (en) * 2017-09-06 2019-03-14 (주) 테크로스 Water treatment apparatus using electrolysis and heterogeneous catalytic oxidation reaction

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