KR20030096514A - Method for manufacturing functional synthetic resins - Google Patents
Method for manufacturing functional synthetic resins Download PDFInfo
- Publication number
- KR20030096514A KR20030096514A KR1020020033033A KR20020033033A KR20030096514A KR 20030096514 A KR20030096514 A KR 20030096514A KR 1020020033033 A KR1020020033033 A KR 1020020033033A KR 20020033033 A KR20020033033 A KR 20020033033A KR 20030096514 A KR20030096514 A KR 20030096514A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- synthetic resin
- functional
- powder
- mixed
- Prior art date
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 24
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 title abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000003610 charcoal Substances 0.000 claims abstract description 9
- 239000010977 jade Substances 0.000 claims abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 5
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 4
- 239000011707 mineral Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 235000013305 food Nutrition 0.000 abstract description 11
- -1 loess Substances 0.000 abstract description 11
- 229910052900 illite Inorganic materials 0.000 abstract description 6
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 abstract description 6
- 239000013078 crystal Substances 0.000 abstract description 5
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 241000700605 Viruses Species 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 238000004332 deodorization Methods 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000001877 deodorizing effect Effects 0.000 description 4
- 210000005260 human cell Anatomy 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000008204 material by function Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 210000000601 blood cell Anatomy 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002124 endocrine Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000003743 erythrocyte Anatomy 0.000 description 1
- 235000021107 fermented food Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/015—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Abstract
Description
본 발명은 합성수지에 원적외선, 음이온방출물과 항균, 탈취물등을 혼합시켜 기능성을 부여한 수지로 생활용품을 제조 사용함으로서 기능성물질이 가지고 있는 유익한 기능에 의해 유해성병균 및 독성을 제거하여 성인병의 예방과 음식물의 변질을 방지하며 맛을 증진시킬 수 있도록 하는 기능성 합성수지의 제조방법에 관한 것이다.The present invention is to use the production of household goods with a resin that provides functionality by mixing far-infrared rays, anion emission and antibacterial, deodorant in the synthetic resin to remove harmful germs and toxicity by the beneficial function of the functional material to prevent adult diseases and food It relates to a method for producing a functional synthetic resin to prevent the alteration of and improve the taste.
주지하는 바와 같이 가격이 저렴하고 가공성이 양호하여 생활용품 및 포장용과 농업용 등으로 범용되고 있는 열가소성수지 폴리에틸렌(PE), 폴리에틸렌테레프탈레이트(PET), 폴리프로필렌(PP) 등을 이용한 제품들이 많이 이용되고 있으나 이러한 재질로 구성되는 식품용 기구나 용기·포장의 재질의 합성수지제는 내분비계 장애물질을 함유하거나 용출 가능성이 있는 것으로 의심되는 발암 및 환경호로몬물질로 알려지고 있다.As is well known, products using thermoplastic resin polyethylene (PE), polyethylene terephthalate (PET), polypropylene (PP), etc., which are widely used for household goods, packaging, and agriculture because of low price and good processability, are widely used. However, synthetic resins for food utensils, containers, and packaging made of these materials are known to be carcinogenic and environmental hormone substances suspected of containing endocrine barriers or suspected of dissolution.
그러나 PVC는 가격이 저렴하면서도 내약품성, 내후성, 난연성, 전기절연성 등이 우수하기 때문에 필름, 용기, 완구, 가전기구 등 우리 생활에 광범위하게 사용되는 플라스틱 재질로서 매우 많은 양이 일상생활에서 사용되고 있음으로 부득이 연구에 의한 대체물질의 개발 또는 식품위생학적으로 안전하고 환경 친화적인 물질 개발이 요구되고 있는 실정이다.However, PVC is a plastic material that is widely used in our daily lives such as films, containers, toys, appliances, etc., because PVC is low in price and excellent in chemical resistance, weather resistance, flame retardancy, and electrical insulation. Inevitably, there is a need for development of alternative materials or food hygienically safe and environmentally friendly materials.
이와 함께 원적외선, 바이오, 음이온등이 인체에 미치는 영향이 알려지고 특히 스트레스의 해소에 의한 성인병의 예방과 치료에 커다란 효과를 발휘하는 것으로 연구됨에 따라 이를 이용한 생활용품 및 건자재 섬유 등에 널리 이용되고 있다.In addition, the effects of far-infrared, bio, anion, etc. on the human body is known and has been widely used in the prevention and treatment of adult diseases caused by the elimination of stress, and is widely used in household goods and building materials fibers.
즉, 무독성과 높은 원적외선 방사율 및 우수한 탈취 및 항균력이 발휘되는 황토와 맥반석 및 옥과 함께 항균력과 탈취효과가 탁월한 숯이나 최근의 일라이트(illlte)등과 같은 유용성이 알려지는 물질을 이용하여 합성수지와 적정비율로 혼합시켜 공지의 방법으로 성형한 생활용품은 무독성과 원적외선의 방출에 의한 식품의 신선도를 유지하고 또한 항균력으로 식품을 오랜 기간 보존할 수 있는 특성을 발휘하고 있다.That is, synthetic resins and proper ratios are made by using materials known to be useful such as charcoal having excellent antibacterial and deodorizing effects and illite, along with ocher, elvan, and jade, which exhibit non-toxicity and high far-infrared emissivity and excellent deodorization and antibacterial activity. The household goods molded by a known method by mixing with a known method to maintain the freshness of the food by non-toxic and far-infrared emission, and also has the characteristics that can preserve the food for a long time by the antimicrobial power.
이러한 혼합성형품은 황토나 맥반석 및 숯분말을 합성수지에 극히 미미한 량으로 혼합된다.Such a mixed molded product is mixed with a very small amount of ocher or elvan and charcoal powder in a synthetic resin.
즉, 상기 분말이 적정량 이상이 혼합되면 성형성이 극히 불량하여 상품성을 저하시키고 또는 적정량 이하로 혼합될 때에는 소망하는 기능을 얻을 수 없는 문제가 야기되는 것이다.In other words, when the powder is mixed in an appropriate amount or more, the moldability is extremely poor, thereby lowering the commercial property or when the powder is mixed in an appropriate amount or less, a problem in which a desired function cannot be obtained.
이에 따라 많은 선출원 및 특허발명에서 혼합량에 대한 수치를 한정하고 있으나 그 실시예에서 불량률이 많아 부득이 최소량으로 한정하는 상태에 있는 것이다.Accordingly, in many applications and patent inventions, the numerical value for the amount of the mixture is limited, but the embodiment is in a state of inevitably limited to the minimum amount due to the high defect rate.
또한 원적외선 방사 및 항균 탈취의 기능을 갖도록 합성수지에 세라믹분말을 첨가하여 제조한 합성수지 제품은 그 특성을 높이기 위하여 항균성과 탈취 및 원적외선 방사효과나 음이온, 자력등이 발휘되는 다수의 첨가제로 첨가되고 있다.In addition, synthetic resin products prepared by adding ceramic powder to synthetic resins to have functions of far-infrared radiation and antibacterial deodorization are added as a number of additives that exhibit antimicrobial and deodorization and far-infrared radiation effects, anion, and magnetic force.
이와 같이 여러 종류의 첨가제가 함께 혼합됨에 따라 제조의 어려움이 발생되며 특히 혼합성이 매우 나뿐 결과를 초례하게 된다.As the various types of additives are mixed together, manufacturing difficulties are generated, and particularly, the mixing is very good and the results are preceded.
이에 따라 선발명 제10-0321290호에서는 합성 수지에 5∼20wt% 의 황토를 첨가하여 황토가 수지내에서 고르게 분산되어 제품 성형에서 불균형 혼합으로 인한 얼룩이나 뭉침 현상을 방지하도록 하고 성형물에서 원적외선 방사기능과 항균 탈취기능을 갖도록 황토를 효과적으로 분산하도록 하는 제조방법이 개시된바 있다.Accordingly, in the invention No. 10-0321290, 5 to 20 wt% of loess is added to the synthetic resin so that the loess is evenly dispersed in the resin to prevent staining or agglomeration due to unbalanced mixing in the molding of the product, and far-infrared radiation function in the molding. It has been disclosed a manufacturing method to effectively disperse ocher to have an antibacterial and deodorizing function.
이러한 선발명에서 1∼3㎛의 황토 미분말 5∼20wt%과, 커플링제 2∼3wt%, 부틸스테아레이팬 0.5wt%, 합성수지 미분말 10wt%, 나머지는 상기 합성수지와 동일한 칩 상태의 합성수지로 구성되고 또는 합성수지는 열가소성수지인 폴먕에틸렌, 폴먕프로필렌, 및 폴먕에틸렌테레프탈레이팬 중 어느 하나인 것을 특징하고 있다.In this selection, 5 to 20 wt% of fine powder of ocher 1 to 3 μm, 2 to 3 wt% of coupling agent, 0.5 wt% of butyl stearray pan, 10 wt% of fine powder of synthetic resin, and the remainder are made of synthetic resin in the same chip state as the synthetic resin. Or synthetic resin is characterized in that any one of a thermoplastic resin, polyethylene, polypropylene, and polyethylene terephthalate fan.
그리고 특허 공개 제1999-0044822호는 황토 70%, 저밀도폴리에틸렌(L.D.P.E) 10%, 가소제(D.O.P) 5%, 분산제(Se/a) 5%, 흘림제(P-Wax) 10%를 혼합시킨 후 혼합된 황토수지와 또다른 공개특허 2001-01135920호에서는 1~5%의 착색제, 0.1~25%의 수정분말, 1∼10%의 활석분말과, 합성수지를 배합하고, 탈포제를 포함하는 첨가제로 구성되는 수정분말로 이루어지는 합성수지를 제시한 바 있다.Patent Publication No. 1999-0044822 discloses mixing 70% loess, 10% low density polyethylene (LDPE), 5% plasticizer (DOP), 5% dispersant (Se / a), and 10% shedding agent (P-Wax). In the mixed ocher resin and another Patent Publication No. 2001-01135920, 1 to 5% colorant, 0.1 to 25% modified powder, 1 to 10% talc powder, a synthetic resin, and a defoamer comprising an additive A synthetic resin composed of modified powder has been presented.
이러한 발명에서는 다같이 황토, 수정, 맥반석등의 천연광물 분말을 합성수지에 1~20wt% 까지 혼합시킬 수 있도록 함으로 항균력과 탈취 및 원적외선 방사량이 모두가 우수하고, 합성수지와 혼합한 조성물로 성형성이 가능하며 황토 고유의 토기색을 발현시켜 천연 안료에 따른 효과를 얻을 수 있다는 것이며 이와 함께 특허 등록 제109041호에서는 점토광물인 일라이트(illite)분말 약 60%에 점토소결제In this invention, it is possible to mix natural mineral powders such as ocher, quartz, and elvan to 1 ~ 20wt% in synthetic resin, so that both antibacterial activity, deodorization and far infrared radiation are excellent, and moldability is possible by composition mixed with synthetic resin. In addition, it is possible to obtain the effect according to natural pigments by expressing the earthen color inherent in ocher. In addition, in Patent No. 109041, clay sintering agent is contained in about 60% of the clay mineral illite powder.
(벤토나이트 325메쉬 10% 혼합물)약 15%와 탄산소다(Na2CO3) 25%를 혼합하여 소립자로 성형하고 이를 약 950℃로 소결시켜서 과립상으로 제조하는 흡착탈취제를 제시한바 있다.An adsorbent deodorant is prepared by mixing about 15% of a bentonite 325 mesh 10% and 25% of sodium carbonate (Na 2 CO 3) to form small particles and sintering at about 950 ° C. to produce granules.
이러한 선발명에서는 단순히 원적외선이 방사된다는 효과 또는 탈취효과만을 도출하기 위한 것으로 한정되어 지는 것이다.In this selection, only the effect of emitting far infrared rays or deodorizing effect is limited.
본 발명의 상기와 같은 문제점을 해소하기 위하여 안출한 것으로, 특히 합성 수지에 황토와 진흙분말, 일라이트(illite) 또는 수정, 맥반석과 숯등을 혼합하여 이들이 발산하는 원적외선과 함께 탈취기능의 향상으로 수지용기에서 식품의 신선도를 증대하고 오랜 보관이 이루어질 수 있도록 하되, 상기 첨가제의 량을 조정하여 공기의 순환이 이루어지는 효과를 발휘함과 분말과 수지의 혼합성을 증대시켜 고른 분산혼합으로 제품 성형에서의 불균형에 의한 얼룩이나 뭉침 현상을 방지할 수 있는 기능성 수지제의 제조방법을 제공하려는 것이다.In order to solve the above problems of the present invention, in particular, by mixing the ocher and mud powder, illite or crystals, ganban stone and charcoal in a synthetic resin, they are resins by improving the deodorization function with far-infrared rays Increase the freshness of the food in the container and allow long-term storage, but the effect of the circulation of the air by adjusting the amount of the additive and to increase the mixing of the powder and the resin to evenly disperse mixing in product molding It is an object of the present invention to provide a method for producing a functional resin that can prevent uneven staining and agglomeration.
상기 목적을 달성하기 위한 본 발명은 폴리에틸렌(PE)과 폴리프로필렌(PP) 또는 폴리에틸렌테레프탈레이트(PET)와 같은 범용의 열가소성수지를 이용하여 성형성을 높이고 성형으로는 압출과 사출공법에 의한 성형이 이루어지며 기능성 소재와함께 이들의 경화 및 색상을 고려하여 경화제와 함께 안료와 탈색제등을 첨가할 수 있다.The present invention for achieving the above object is to increase the moldability by using a general-purpose thermoplastic resin, such as polyethylene (PE) and polypropylene (PP) or polyethylene terephthalate (PET) and molding by extrusion and injection method In addition to the functional materials, in consideration of their curing and color, it is possible to add pigments and bleaching agents together with the curing agent.
이하 본 발명의 실시예를 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail.
기능성 소재로 황토, 진흙, 일라니트(illite)[KAl4(AlSi7O20)(OH)], 숯, 옥, 수정을 1∼10㎛크기로 분쇄하여 상기 분말중 선택된 미분말 하나 또는 복수의 분말 1∼30wt%과, 커플링제 2∼3wt%, 분산 유연제 용매로 부틸스테아레이트(Butylsterate) 0.5wt%,와 합성수지 분말을 믹서기로 균일하게 혼합하게 된다.1 to 30 wt% of one or a plurality of fine powders selected from the above powders by pulverizing ocher, mud, illite [KAl4 (AlSi7O20) (OH)], charcoal, jade and quartz as functional materials to a size of 1 to 10 μm. And 2 wt% to 3 wt% of the coupling agent, 0.5 wt% of butyl stearate as the dispersing softener solvent, and the synthetic resin powder are uniformly mixed with a mixer.
이때에 경화제와 함께 선택된 안료를 미량 첨가하여 빠른 경화와 색체를 표출시킬 수 있다.In this case, a small amount of the pigment selected together with the curing agent may be added to express the fast curing and the color body.
이러한 혼합소재는 고속회전장치로 혼합하여 균일한 혼합을 이루고 호퍼로 투입시켜 약 170∼200℃의 온도로 압출함과 함께 냉각조에서 냉각시켜 적당크기로 절단하여 기능성수지제를 얻게 되는 것이다.The mixed material is mixed by a high-speed rotating device to achieve a uniform mixing, introduced into a hopper and extruded at a temperature of about 170 ~ 200 ℃ and cooled in a cooling bath to cut to a suitable size to obtain a functional resin.
상기 기능성 소재 황토, 진흙분말은 주지된바와 같이 원적외선의 방출이 많고 또한 탈취효과와 항균력 및 소량의 공기를 투과시키게 됨으로 발효식품의 발효성증대로 장기간의 보관성이 있으며,As the functional material ocher, mud powder is well known as it emits a lot of far-infrared rays and also has a deodorizing effect, antimicrobial power and a small amount of air permeable, so as to increase the fermentability of fermented foods, it has a long-term storage.
일라니트는 인체세포막을 경계로 형성되는 음(-) 양(+)전위가 손상될 때에 즉,음이온이 부족한 경우 세포호흡 작용이 저하되고 영양공급과 피로물질 배출이 원활하지 못해 인체세포는 활성을 잃게 될 때에 음이온을 방출하여 혈액 속의 적혈구에 함유하고 있는 철분에 작용하여 혈구의 활력이 증가되고 순환기능이 강화하는것으로 알려지고 있고,Ilanite is damaged when the negative (+) potential potential formed at the boundary of the human cell membrane, that is, the lack of negative ions, cell respiration is reduced, nutrient supply and fatigue material discharge is not smooth, so human cells are active When it is lost, it releases negative ions and acts on iron contained in red blood cells in the blood to increase the vitality of blood cells and enhance circulation.
숯은 미크론크기의 미세 구멍들이 무수히 천공된 흡착성으로 탈취기능과 화학물질까지 흡착시켜 그 독소를 제거하는 기능 및 옥(玉) 또는 수정은 인체에 극히 필요한 광물, 칼슘, 마그네슘을 함유하고 있으며 옥에서 나오는 기파동과 인체세포의 기파동이 같아 인체 세포에 골고루 침투하여, 동명공진 작용을 함으로써, 조직의 부활, 혈액순환, 혈액의 약 알카리화, 체내의 유해 노폐물배설, 노쇠를 방지하는 등 건강을 유지하는데 획기적인 효과가 있다.Charcoal is a micron-sized micro-pores adsorbed innumerable perforations to deodorize and adsorb chemicals and remove its toxins, and jade or crystal contains minerals, calcium and magnesium which are extremely necessary for the human body. The same wave wave coming out of the body and the same wave of the human cell are equally penetrated into the human cells, and by the same name resonant action, it is possible to rehabilitate tissues, circulate blood, weakly alkaline the blood, excrete harmful wastes in the body, and prevent decay. It has a dramatic effect on maintaining.
이상과 같은 본 발명의 실시예를 상세히 설명하면 다음과 같다.Referring to the embodiment of the present invention as described above in detail as follows.
본 발명의 기능성 소재로 황토, 진흙, 일라니트, 숯, 옥 또는 수정을 선택하여 하나 또는 복수로 1∼10㎛크기로 분쇄한다.As the functional material of the present invention, ocher, mud, elanite, charcoal, jade or crystals are selected and pulverized to 1 to 10 탆 in size.
이때에 상기 소재를 함께 분쇄기로 투입시켜 분쇄하거나 또는 각각을 분쇄후 혼합할 수 있으며 그 크기는 상기한 1∼10㎛크기보다 클 수 있다.At this time, the material may be put together into a grinder, or may be mixed after grinding each other, the size thereof may be larger than the size of 1 ~ 10㎛.
상기 분말중 선택된 미분말 하나 또는 복수의 분말 1∼30wt%과, 커플링제 2∼3wt% 및 분산 유연제 용매로 부틸스테아레이트 0.5wt%,와 합성수지 분말을 믹서기로 균일하게 혼합하되 이때에 미량의 경화제와 함께 상품의 상품성 및 용도, 기능에 의해 요구되는 필요의 선택된 안료를 미량 첨가하여 혼합하게 된다.1-30 wt% of one or a plurality of fine powders selected from the powder, 2-3 wt% of coupling agent and 0.5 wt% of butyl stearate as a dispersing softener solvent, and a synthetic resin powder are uniformly mixed with a blender. Together, a small amount of selected pigments required by the merchandise, use, and function of the product are added and mixed.
이와 같은 혼합 소재는 고속회전장치로 혼합하며 균일 혼합을 이루어 소성물에서의 기포발생방지와 소재가 일측으로 뭉쳐지는 얼룩 또는 색상의 변조되는 것을 방지할 수 있도록 혼합의 균일성을 유지하는 것이 바람직하다.Such a mixed material is preferably mixed by a high-speed rotating device to achieve uniform mixing to maintain uniformity of the mixing to prevent bubbles from occurring in the plastic material and to prevent staining or color modulation of the material. .
상기에서 혼합된 소재는 압출기의 호퍼로 투입시켜 약 170∼200℃의 온도로압출함과 함께 냉각조를 거치면서 냉각되고 그 일단에서 공지의 적당 크기로 절단하여 칩상태의 기능성 수지제를 얻게 되는 것이다.The mixed material is introduced into the hopper of the extruder, extruded at a temperature of about 170 to 200 ° C, cooled through a cooling bath, and cut into a suitable size known at one end to obtain a functional functional resin of chip state. will be.
본 발명은 합성 수지에 황토와 진흙분말, 일라이트 또는 수정, 맥반석과 숯등을 분쇄한 미세분말을 하나 또는 복수와 함께 수지와 혼합하여 이들이 가지는 원적외선과 함께 탈취기능의 향상으로 수지용기에서 식품의 신선도를 증대하고 오랜 보관이 이루어질 수 있도록 하되, 상기 첨가제의 량을 조정하여 공기의 순환이 이루어지는 효과를 발휘하여 의료용 용기, 식품용 용기, 기타 식품등의 포장재로의 활용이 이루어질 수 있는 효과를 발휘하는 유용한 발명이다.The present invention is to mix the fine powder pulverized ocher and mud powder, illite or crystal, ganban stone and charcoal in the resin with one or more resin and mixed with the resin to improve the deodorization function of the far infrared with the freshness of the food in the resin container To increase the long-term storage, but by adjusting the amount of the additive to exert the effect of the circulation of the air to achieve the effect that can be used as a packaging material for medical containers, food containers, and other foods It is a useful invention.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020020033033A KR20030096514A (en) | 2002-06-12 | 2002-06-12 | Method for manufacturing functional synthetic resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020020033033A KR20030096514A (en) | 2002-06-12 | 2002-06-12 | Method for manufacturing functional synthetic resins |
Publications (1)
Publication Number | Publication Date |
---|---|
KR20030096514A true KR20030096514A (en) | 2003-12-31 |
Family
ID=32386896
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020020033033A KR20030096514A (en) | 2002-06-12 | 2002-06-12 | Method for manufacturing functional synthetic resins |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR20030096514A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040033843A (en) * | 2002-10-16 | 2004-04-28 | 김종고 | Synthetic resin containing powdered amethyst for radiating far-infrared and maunfacturing method therefor |
KR20050120212A (en) * | 2004-06-18 | 2005-12-22 | 주식회사 엘지화학 | Yellow earth resin composition emitting far-infrared rays and polymer articles having improved mechanical properties and esthetic surface characteristics manufactured using the same |
KR100712399B1 (en) * | 2007-02-02 | 2007-04-27 | 주식회사 뉴보텍 | Resin composition for being used to manufacture functional resin articles and functional pipe |
KR101394210B1 (en) * | 2012-01-27 | 2014-05-14 | 주식회사 피시스 | Functional synthetic resin composition and functional plastic use those resins |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01242665A (en) * | 1988-03-24 | 1989-09-27 | Kuraray Co Ltd | Antibacterial molding and its production |
KR19990023150A (en) * | 1998-06-09 | 1999-03-25 | 오창엽 | Foaming Method of Synthetic Resin Using Ventnite and Synthetic Resin Foam |
KR20000038362A (en) * | 1998-12-03 | 2000-07-05 | 권영한 | Synthetic resin product composition having antibacterial and antimold action |
KR100321290B1 (en) * | 1999-04-19 | 2002-03-18 | 김준섭 | A synthetic resin composition having yellow soil and method of the same |
KR200302464Y1 (en) * | 2002-06-12 | 2003-01-30 | 주식회사 세경 | The food tool |
-
2002
- 2002-06-12 KR KR1020020033033A patent/KR20030096514A/en not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01242665A (en) * | 1988-03-24 | 1989-09-27 | Kuraray Co Ltd | Antibacterial molding and its production |
KR19990023150A (en) * | 1998-06-09 | 1999-03-25 | 오창엽 | Foaming Method of Synthetic Resin Using Ventnite and Synthetic Resin Foam |
KR20000038362A (en) * | 1998-12-03 | 2000-07-05 | 권영한 | Synthetic resin product composition having antibacterial and antimold action |
KR100321290B1 (en) * | 1999-04-19 | 2002-03-18 | 김준섭 | A synthetic resin composition having yellow soil and method of the same |
KR200302464Y1 (en) * | 2002-06-12 | 2003-01-30 | 주식회사 세경 | The food tool |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040033843A (en) * | 2002-10-16 | 2004-04-28 | 김종고 | Synthetic resin containing powdered amethyst for radiating far-infrared and maunfacturing method therefor |
KR20050120212A (en) * | 2004-06-18 | 2005-12-22 | 주식회사 엘지화학 | Yellow earth resin composition emitting far-infrared rays and polymer articles having improved mechanical properties and esthetic surface characteristics manufactured using the same |
KR100712399B1 (en) * | 2007-02-02 | 2007-04-27 | 주식회사 뉴보텍 | Resin composition for being used to manufacture functional resin articles and functional pipe |
KR101394210B1 (en) * | 2012-01-27 | 2014-05-14 | 주식회사 피시스 | Functional synthetic resin composition and functional plastic use those resins |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101834116B1 (en) | An antimicrobial resin and the manufacturing method thereof | |
CN105566831B (en) | A kind of Water blown antibacterial, ventilating microporous membrane masterbatch, film and preparation method | |
KR101167070B1 (en) | An anti-bacterial chopping board and a preparation thereof | |
CN109485998A (en) | A kind of composite plastic of novel degradable and preparation method thereof | |
KR101766865B1 (en) | Method for a preparation of organic-inorganic complex resin comprising silver nano particles and water pipe using the complex resin | |
CN102125054A (en) | Antibacterial composition, antibacterial product and antibacterial method | |
KR101684444B1 (en) | Sterilization cutting board having a far-infrared-emitting function and method for manufacturing the same | |
KR200302464Y1 (en) | The food tool | |
KR20100023019A (en) | Functional resin compound | |
KR20030096514A (en) | Method for manufacturing functional synthetic resins | |
KR20000038750A (en) | Synthetic resin product containing shellfish shell powder and method for preparing thereof | |
KR101394210B1 (en) | Functional synthetic resin composition and functional plastic use those resins | |
KR101732142B1 (en) | Sterilization cutting board including charcoal and salt, and method for manufacturing the same | |
KR20040102659A (en) | functional elastomer that radiating an anion or a far infrared rays | |
CN105646984A (en) | Antibacterial polyethylene foam and preparation method thereof | |
KR100622563B1 (en) | Plastic composite having complex function and method for preparation thereof | |
KR20030012511A (en) | A method of manufacturing plastic goods including charcoal and goods thereof | |
JP4264163B2 (en) | Inorganic antibacterial / antifungal agent, antibacterial resin composition and antibacterial resin product | |
KR100636825B1 (en) | The biodegradable polymer containing mineral materials | |
KR20010035535A (en) | Manufacturing method of funtional plastics | |
CN102634141B (en) | Flexible and plastic color clay material and manufacturing method thereof | |
CN105968863A (en) | Functional wood flour composite filling material and preparation method thereof | |
KR101093083B1 (en) | Plastic food case containing charcoal made of oak wood | |
KR20070038938A (en) | Anti-microbial yarn, antifungal yarn, anti-microbial(anti-bacterial) perfume yarn, antifungal perfume yarn and their manufacturing method | |
KR20050103866A (en) | Functional board |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E601 | Decision to refuse application |