KR20030068910A - Granular Zeolite. - Google Patents

Granular Zeolite. Download PDF

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Publication number
KR20030068910A
KR20030068910A KR1020020008610A KR20020008610A KR20030068910A KR 20030068910 A KR20030068910 A KR 20030068910A KR 1020020008610 A KR1020020008610 A KR 1020020008610A KR 20020008610 A KR20020008610 A KR 20020008610A KR 20030068910 A KR20030068910 A KR 20030068910A
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KR
South Korea
Prior art keywords
solution
elvan
zeolite
germanium
water
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KR1020020008610A
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Korean (ko)
Inventor
장길석
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장길석
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Priority to KR1020020008610A priority Critical patent/KR20030068910A/en
Publication of KR20030068910A publication Critical patent/KR20030068910A/en

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

PURPOSE: A method for preparing a fertilizer using water-soluble silicic acid and granulate zeolite is provided, to allow the germanium and elvan having the useful functionality to be coated to the granulate zeolite by a simple method. CONSTITUTION: The method comprises the steps of mixing water-soluble silicic acid, germanium and elvan in a suitable ratio; adding granulate zeolite to the mixture to allow the granulate zeolite to be coated with water-soluble silicic acid, germanium and elvan; drying the coated zeolite; repeating the coating and drying processes for two or three times; and packing the obtained product.

Description

수용성규산과 입상(粒狀)제오라이트를 이용한 비료 제조방법.{Granular Zeolite.}Fertilizer manufacturing method using water-soluble silicic acid and granular zeolite. {Granular Zeolite.}

본 발명은 수용성규산과 입상(粒狀)제오라이트를 이용한 비료 제조방법에 관한 것으로서, 좀 더 상세하게는 농토 등에 살포하면 농작물의 수확에 큰 효과가 있는 입상제오라이트에 수용성규상용액과 게르마늄용액과 맥반석용액를 코팅하여 비료를 완성한 것이다.The present invention relates to a fertilizer manufacturing method using a water-soluble silicic acid and granular zeolite, and more particularly, water-soluble silica solution, germanium solution and ganban stone in granular zeolite having a great effect on the harvest of crops when sprayed on farmland or the like. The solution is coated to complete the fertilizer.

제오라이트(zeolite)란 장석(feldsper)류 광물일종으로 나노(10)크기의 세공이 무수히 존재하며, 그 세공속에는 보통 물분자들이 가득 채우고 있다가 일정한 열이 가해지면 내포된 물분자가 증발하여 수증기를 발산한다, 이러한 사실에 기인하여 끓는(zeo)돌이라고 명명되기도 한다.Zeolite is a kind of feldsper mineral that contains nano (10) -sized pores, and the pores are usually filled with water molecules, and when a certain heat is applied, the contained water molecules evaporate and vaporize. Radiates, due to this fact it is sometimes called a boo stone.

따라서 물적 흡착력과 화학적 양이온 치환작용이 뛰어나 수분 외 다른 ,GAS 등을 20배까지 흡수, 흡착하여 보관하고 있다가 서서히 배출하는 특이한 능력이 있어 이러한 특징적인 특성을 이용하여 지금까지 다양한 용도로 개발 사용되고 있는것인 즉, 농업용으로 토양개량제 비료혼합제, 상토혼합제 등에 널리 이용되고 있다.Therefore, it has excellent physical adsorption power and chemical cation substitution effect, so it has a unique ability to absorb, adsorb and store up to 20 times of GAS etc. in addition to moisture, and has been developed and used for various purposes until now by using these characteristic characteristics. That is, it is widely used for phosphorus fertilizer admixture, top soil admixture and the like for agriculture.

맥반석 및 수용성규산 또는 게르마늄의 분말을 농토에 살포하면 식물성장 촉진 효과 및 토양개량 효과가 우수함은 밝혀져 있다.It has been found that spraying powder of elvan and water-soluble silicic acid or germanium on farmland has excellent plant growth promoting effect and soil improvement effect.

그러나 광석 분말을 미세하게 분쇄하거나 물에 희석시킨 용액을 다량 살포할 경우 토양 개량의 효과는 뛰어나지만 이 광석 물질이 토양에 통풍성을 충분히 부여하기 어렵다는 사실을 밝혀내고 통기성 문제를 해소하기 위한 연구를 한 결과 일정기간 흡수하였다가 서서히 발산한 제오라이트에 상기 맥반석 및 수용성규산 또는 게르마늄용액을 흡수(코팅)시킨 후 건조과정을 걸쳐 농토에 살포할 수 있는 비료를 완성한 것이다.However, when finely pulverized ore powder or spraying a large amount of diluted solution with water is effective in improving soil, it has been studied to solve the problem of air permeability by finding out that the ore material is not sufficiently ventilated to the soil. Results After absorbing (coating) the elvan and the water-soluble silicic acid or germanium solution in zeolite which was absorbed for a certain period of time, the fertilizer can be sprayed onto the soil through a drying process.

본 발명은 농토에 살포하면 식물 성장 촉진 효과 및 토양개량 효과가 우수하다는 수용성규산용액, 게르마늄용액, 맥반석용액이 정당비율로 혼합된 이 용액을 입상제오라이트에 코팅(교반기를 이용하여 교반작업으로)하는 것을 특징으로 한다The present invention is coated with a granular zeolite (by stirring using a stirrer) of this solution mixed with a water-soluble silicic acid solution, germanium solution, elvan rock solution which is excellent in plant growth promoting effect and soil improvement effect when sprayed on farmland. Characterized in

먼저, 수용성규산, 게르마늄, 맥반석 등은 농가에서 편리하게 사용할 수 있도록 용액으로 유통하고 있다.First, water-soluble silicic acid, germanium, ganban stone and the like are distributed in a solution for convenient use in farms.

그 들 용액은 물에 분말(맥반석 등)을 희석시켜 용액화 한 것이다.These solutions are solutions made by diluting powders (such as elvan) with water.

본 발명의 제조공정을 살펴보기로 한다.The manufacturing process of the present invention will be described.

1공정 수용성규산, 게르마늄, 맥반석을 정당비율로 혼합물과 함께 교반기에 용해 한 후 입상제오라이트를 침적하여 코팅되도록 교반기를 작동시킨다.Step 1 Dissolve the water-soluble silicic acid, germanium, and elvan in a ratio with the mixture in the stirrer and operate the stirrer to deposit and coat the granular zeolite.

2공정 상기 교반기의 작동으로 입상제오라이트에 수용성규산용액, 게르마늄용액, 맥반석용액이 1차 코팅된 입상제오라이트는 이송콘베어밸트에 이송하여 건조라인을 통과하여 건조한다.Step 2 The granular zeolite coated with the granular zeolite, the aqueous silicate solution, the germanium solution, and the elvan rock solution, is transferred to a conveyer belt and dried by passing through a drying line.

3공정, 제 2공정에서 입상제오라이에 수용성규상용액, 게르마늄용액, 맥반석용액이 1차 코팅되어 건조된 입상제오라이트를 상기 1. 2공정과 같은 방법으로 2-3회 반복 코팅한 건조단계 후 포대에 포장하여 본 발명의 비료를 완성한다.After the drying step of repeating the coating of granular zeolite 2-3 times in the same manner as in Step 1. Packaged in sacks to complete the fertilizer of the invention.

본 발명의 상기한 바와 같이 맥반석등 및 게르마늄이 지니고 있는 음이온 산소가 생체 성장에 유해한 불순물로 산성화를 제거하는 강력한 탈 수소 능력을 발휘함으로서 작물에 뿌리에 산소 공급과 함께 토양을 알칼리성화로 환원시키는 역할을 하는 용액을 입상제오라이트에 간단한 방법으로 1-3회 코팅함으로서 제조공정이 간단하여 원가를 대폭 낮추어 농가에 보급함으로서 농가의 경제적으로 부담을 줄이는 효과가 있는 아주 유익한 발명이라 할 수 있다.As described above of the present invention, the anion oxygen of elvan and germanium exerts a powerful dehydrogenation ability to remove acidification as an impurity harmful to biological growth, thereby reducing the soil to alkaline with supplying oxygen to the roots. By coating the solution to the granular zeolite 1-3 times by a simple method, the manufacturing process is simple, and the cost is greatly reduced, and it is a very advantageous invention that has the effect of reducing the economic burden on the farmhouse.

Claims (2)

입상제오라이트를 수용성규산용액, 게르마늄용액, 맥반석용액에 침적시켜 코팅되도록 하는 단계와 상기 수용성규산용액, 게르마늄용액, 맥반석용액이 코팅된 입상제오라이트를 건조한 단계에 이어 제품포장 단계로 이루어진 수용성규산과 입상제오라이트를 이용한 비료 제조방법.Soluble silicate and granular zeolite consisting of granular zeolite coated with water-soluble silicate solution, germanium solution, and elvan solution, followed by drying the granular zeolite coated with the water-soluble silicate solution, germanium solution, and elvan solution Fertilizer manufacturing method using. 제 1항에 있어서The method of claim 1 입상제오라이트를 수용성규산용액, 게르마늄용액, 맥반석용액에 침적시켜 1차 코팅 단계이후 건조단계를 지난 상기 1차 코팅된 입상제오라이트를 상기 수용성규산용액, 게르마늄용액, 맥반석용액에 침적시켜 반복코팅 후 건조단계에 이어 제품포장 단계로 이루어진 수용성규산과 입상제오라이트를 이용한 비료 제조방법.Granular zeolite was immersed in an aqueous silicate solution, germanium solution, and elvan solution, and the first coated granular zeolite, which had been dried after the first coating step, was deposited in the aqueous silicate solution, germanium solution, and elvan solution. Subsequently, a fertilizer manufacturing method using water-soluble silicic acid and granular zeolite consisting of product packaging steps.
KR1020020008610A 2002-02-19 2002-02-19 Granular Zeolite. KR20030068910A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101656053B1 (en) 2016-06-28 2016-09-08 김세호 Digital Door Lock
KR20220109962A (en) * 2021-01-29 2022-08-05 주식회사 제이앤티 Manaufacturing method for zeolite for potassium fertilizer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101656053B1 (en) 2016-06-28 2016-09-08 김세호 Digital Door Lock
KR20220109962A (en) * 2021-01-29 2022-08-05 주식회사 제이앤티 Manaufacturing method for zeolite for potassium fertilizer

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