KR20030046052A - Styling sampoo composition - Google Patents

Abstract

PURPOSE: A styling shampoo composition is provided to give improved styling functions, curl retention and arrangement simultaneously with rinsing activity. CONSTITUTION: A styling shampoo composition contains 0.01-20 wt.% of a styling polymer, 0.01-10 wt.% of a chitosan derivative, and 0.01-30 wt.% of an organic silicon resin variant. The styling polymer is one or more elements selected from the group consisting of copolymers of methacryloylethyl betaine/methacrylate, octylacrylamide/acrylates/butylaminoethyl methacrylate, PVP/VA, PVP/dimethylaminoethylmethacrylate, PVM/MA, acrylate methacrylate, VA/crotonates/vinyl neodecanoate, and polyvinylpyrrolidone, ethyl or butyl ester of PVM/MA, polyquaternium-11, and polyquaternium-46. The chitosan derivative is one or more elements selected from the group consisting of polyoxyalkylene chitosan, carboxymethyl chitosan, dihydroxypropyl chitosan, and N-2-hydroxypropylsulfonic acid chitosan.

Description

Styling Shampoo Composition {STYLING SAMPOO COMPOSITION}

The present invention relates to a styling shampoo composition, and more particularly, to a styling shampoo composition having a cleansing function and imparting and improving the styling and trimming function of hair.

Shampoo is a cosmetic product for hair that is used to decontaminate the scalp and hair and to keep the hair clean and beautiful.In addition to cleaning purposes, it is easy to comb, softness, smoothness, gloss, and the friction of the hair surface, antistatic, hair It is used for additional purposes such as protection.

The desire to shape and maintain hair in particular forms continues to grow.

There are two main ways to style and maintain your hair. The first method is a chemical method of changing the binding position of hair, which is generally called 'perm' and is semipermanent. The second method is a temporary change by a physical change and is removed by water or shampoo.

Temporary style changes are generally made by applying a styling product to the hair after using the shampoo. Generally, styling products include gels, mousses, and sprays made from resins or gums.

This styling product has the following disadvantages.

First, after using the shampoo, it is cumbersome to apply a separate styling product. Second, since the styling product is applied by hand, there is a hassle of washing the hands after application. Third, applying styling products tends to make the hair stiff and stiff.

For this reason, US Pat. No. 6,248,317 discloses a method for enhancing the styling effect by simultaneously including a styling polymer and a cationic material, and US Pat. No. 6,248,615 discloses a styling polymer and an organic oil. ) And a method of increasing the styling effect by simultaneously including a styling polymer and solid particles, US Patent No. 5,977,036 A method of increasing the styling effect by simultaneously including a styling polymer and a crystalline hydroxyl-containing stabilizing agent comprising a crystalline hydroxyl group is disclosed. However, the conventional techniques are directed to a method of increasing the styling effect by strengthening hair deposition by using a styling polymer and a certain component together, and there is a problem that the styling effect is insignificant and the hair trimming effect is insufficient.

Therefore, there is a need for further research on ingredients that simultaneously provide cleaning and styling functions, avoid the hassle of washing hands separately, and may not stiffen or stiffen hair.

In order to solve the above problems, the present invention provides a styling shampoo composition that can simultaneously provide a cleaning and style maintenance function, avoid the hassle of washing hands separately, and can not stiff or stiffen the hair. For the purpose of

Another object of the present invention is to provide a styling shampoo composition which can simultaneously provide a cleaning function, a style maintenance function, and a hair trimming function.

In order to achieve the above object, the present invention provides a shampoo composition,

a) styling polymer;

b) chitosan derivatives; And

c) organic silicone resin variant

It provides a styling shampoo composition comprising a.

Hereinafter, the present invention will be described in detail.

The inventors of the present invention have been studying how to impart a styling function to the shampoo. As a result, the shampoo composition contains a styling polymer, a chitosan derivative, and an organic silicone resin variant. On the basis of this, the present invention has been completed.

The present invention relates to a styling shampoo composition comprising a styling polymer having a styling effect, a chitosan derivative for a styling auxiliary effect, and an organic silicone resin variant for plasticizing the polymer to enhance the styling effect.

The styling shampoo composition of the present invention comprises 0.01 to 20% by weight of the styling polymer, 0.01 to 10% by weight of the chitosan derivative, and 0.01 to 30% by weight of the organic silicone resin variant.

The compositions of the present invention can save time by providing styling and styling maintenance functions simultaneously with cleaning, reducing the hassle of having to wash hands separately, and also not stiff or stiff hair.

The styling polymer of a) used in the present invention is included in an amount of 0.01 to 20% by weight, preferably 0.1 to 5% by weight, based on the total weight of the shampoo composition. If the content is less than 0.01% by weight, there is almost no styling effect. If the content is more than 20% by weight, there is a problem in the usability, such as the physical properties of the product, sticking phenomenon during and after use.

Examples of the styling polymer include methacryloylethyl betaine / methacrylate copolymer, octyacrylamide / acrylate / butylaminoethyl methacrylate copolymer, and octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer. Amphoteric styling polymers such as; Nonionic styling polymers such as polyvinylpyrrolidone, PVP / VA copolymer, PVP / dimethylaminoethylmethacrylate copolymer (PVP / dimethylaminoethylmethacrylate copolymer); PVM / MA copolymer (PVM / MA copolymer), ethyl or butyl ester of PVM / MA copolymer, acrylate methacrylate copolymer (acrylate methacrylate) anionic styling polymers such as copolymer) and V / crotonate / vinyl neodecanoate copolymer; And cationic styling polymers such as polyquaternium-11 and polyquaternium-46 may be used alone or in combination.

When a mixture of the cationic polymer and the anionic polymer is used, complexes related to ionicity can be formed depending on the content ratio between the two ionic polymers, the combination ratio with the surfactant, and the like. In this case, an appropriate content ratio should be selected and used. In general, cationic polymers: anionic polymers are preferably mixed in a ratio of 10:90 to 70:30.

The chitosan derivative of b) used in the present invention is represented by the following formula (1).

[Formula 1]

In the formula of Formula 1,

The average molecular weight is 2,000 to 200,000.

Chitosan derivative represented by the formula (1) is included in 0.01 to 10% by weight, preferably 0.1 to 5% by weight based on the total weight of the shampoo composition. If the content is less than 0.01% by weight, there is almost no effect of improving the trimming and style holding power. If the content is more than 10% by weight, the increase of the trimming effect and the effect of increasing the style holding power is insignificant. have.

Chitosan is a natural cationic polymer deacetylated chitin and has been used in the food industry for the precipitation of proteins in plant components. Chitosan binds tightly to the hair's keratin, creates a uniform surface on the hair's cuticle layer, facilitates combing, and hardens the hair's surface to provide setting force. In addition, soft texture and increased gloss can provide both setting and conditioning effects.

Chitosan represented by the formula (1) has a derivative of various forms by the modification of the functional group, typically polyoxyalkylene chitosan (polyoxyalkylene chitosan), carboxymethyl chitosan (carboxymethyl chitosan), dihydroxypropyl chitosan (dihydroxypropyl chitosan) ), Or N-2-hydroxylpropylsulfonic acid chitosan.

As the organic silicone resin variant of c) used in the present invention, it is preferable to use a silicone glycol copolymer (silicone glycol copolymer) collectively referred to as a dimethicone copolymer represented by the following formula (2).

[Formula 2]

In the formula (2),

R is hydrogen or alkyl having 1 to 12 carbons,

x is an integer from 1 to 100,

y is an integer from 1 to 20,

m and n are each an integer of 10-50.

The organic silicone resin variant is included in an amount of 0.01 to 30% by weight, preferably 0.1 to 15% by weight, based on the total weight of the shampoo composition. If the content is less than 0.01% by weight, there is almost no effect of increasing the holding force, and if it exceeds 30% by weight, the effect of increasing the holding force reaches saturation, and the physical properties of the shampoo, such as a viscosity decrease, are lowered.

Commercialized organic silicone resin variants include Q2-5220 (Dwo Corning).

The organic silicone resin variant represented by Formula 1 may be used in products such as hairspray, hair mousse, setting lotion, styling gel, and the like to act as a plasticizer of the styling polymer, thereby increasing holding power.

The present invention provides a styling shampoo composition by using the hair keratin binding force of the chitosan derivative of b) and the retention effect of the styling polymer of the organic silicone resin variant represented by Chemical Formula 1 of c), thereby enhancing the hair surface binding force of the styling polymer. And by increasing the holding power of the bound polymer component, a better styling effect and hair trimming effect can be obtained.

In the present invention, anionic surfactants or nonionic surfactants may be used alone or in combination, and may be included in an amount of 5 to 50% by weight, and preferably 10 to 25% by weight, based on the total weight of the shampoo composition.

The anionic surfactant is represented by the following formula (3), for example, sodium lauryl sulfate, ammonium lauryl sulfate, magnesium lauryl sulfate, lauryl triethanolamine, sodium polyoxyethylene lauryl sulfate, or polyoxyethylene lauryl sulfate And the like can be used. The anionic surfactants serve to clean various wastes in the shampoo composition.

[Formula 3]

In the formula (3),

R is alkyl having 8 to 20 carbon atoms,

M is sodium, potassium, magnesium, triethanolamine, or ammonium ion,

n is an integer of 0-4.

In addition, the nonionic surfactant of c) is represented by the following formula (4), (5) or (6). As the compound represented by Formula 4, lauryldimethylamine oxide or palm oil alkyldimethylamine oxide may be used, and as the compound represented by Formula 5, lauryl acid ethanolamide, palm oil fatty acid diethanolamide, or palm oil fatty acid mono Ethanolamide may be used, and the compound represented by the following Chemical Formula 6 may be polyoxyethylene lauryl ether, or polyoxyethylene nonylphenyl ether.

[Formula 4]

[Formula 5]

[Formula 6]

In the formula 4, 5, or 6,

R ₁ is alkyl having 8 to 20 carbon atoms,

R ₂ or R ₃ each independently represent an alkyl chain having 1 to 3 carbon atoms,

R ₄ CO group is alkoxy having 8 to 20 carbon atoms,

R ₅ is alkyl having 8 to 20 carbons or alkyl phenyl having 8 to 20 carbon atoms,

m is an integer from 3 to 50,

n is an integer of 0 or 1.

In order to impart viscosity increase, auxiliary cleaning, or solubilizing efficacy to the shampoo composition of the present invention, the nonionic surfactants represented by the above formulas (4), (5) or (6) may be used alone or in combination of two or more thereof.

In addition, the shampoo composition of the present invention, in addition to the above components, further known components for use in hair care or body care products, so long as they are physicochemically compatible or do not excessively impair the stability, aesthetics, or function of the product. It may contain.

Non-limiting examples of optional ingredients for use in shampoo compositions include preservatives, thickeners or viscosity modifiers, pH adjusters, flavorings, dyes, conditioning agents and the like, which are commonly used to maintain the basic physical properties and qualities of a cleaning composition.

As the preservative, a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone, methylisothiazolinone (trade name: Kathon CG, manufacturer: Rohm & Haas, USA), etc. may be used, and as the thickener or viscosity modifier, Hydroxypropylmethylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol and the like can be used. In addition, citric acid, sodium hydroxide, triethanolamine, etc. may be used as the pH adjusting agent, and a water-soluble tar pigment may be used as the dye, and polyquaternium-7, polyquaternium-10, polyoxyethylene lanolin, lanolin as a conditioning agent. Alcohols, hydrolyzed proteins, ethylene glycol monostearic acid and the like can be used, in addition to flavoring can be used.

Hereinafter, preferred examples are provided to help understanding of the present invention, but the following examples are merely to illustrate the present invention, and the scope of the present invention is not limited to the following examples.

EXAMPLE

Examples 1 to 3, and Comparative Examples 1 to 3

30% sodium lauryl sulfate, 30% polyoxyethylene lauryl sulfate, and palm oil fatty acid diethanolamide were added at a composition ratio as shown in Table 1, and the mixture was warmed up to 60 ° C., followed by stirring for 30 minutes while maintaining the temperature. . It was stirred and cooled to 45 ° C. and completely dissolved by adding propylene glycol, an anionic styling polymer (PVM / MA copolymer), an organic silicone resin variant (Q2-5220), and hydroxypropyl chitosan. Stir until. A styling shampoo containing anionic styling polymer was prepared by adding a pigment, carton seed, perfume, and citric acid to the mixture and stirring for 30 minutes. The unit is weight percent.

division Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 30% Sodium Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 30% Sodium Polyoxyethylene Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Propylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 PVM / MA Polymer 3.0 3.0 3.0 3.0 3.0 3.0 Organic Silicone Resin Variant (Q2-5220) 0.4 0.6 0.4 - 0.4 - Hydroxypropyl chitosan 0.5 0.5 1.0 - - 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Cartonsea 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 water Up to 100% by weight

Examples 4-6, and Comparative Examples 4-6

Except for using the amphoteric styling polymer methacryloylethyl betaine / methacrylate copolymer (methacryloylethyl betaine / methacrylate copolymer) as the styling polymer in the composition ratio as shown in Table 2 in Example 1 It carried out by the same method as 1. The unit is weight percent.

division Example 4 Example 5 Example 6 Comparative Example 4 Comparative Example 5 Comparative Example 6 30% Sodium Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 30% Sodium Polyoxyethylene Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Propylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 Methacryloylethylbetaine / methacrylate copolymer 3.0 3.0 3.0 3.0 3.0 3.0 Organic Silicone Resin Variant (Q2-5220) 0.4 0.6 0.4 - 0.4 - Hydroxypropyl chitosan 0.5 0.5 1.0 - - 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Cartonsea 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 water Up to 100% by weight

Examples 7-9, and Comparative Examples 7-9

In Example 1 was carried out in the same manner as in Example 1 except for using a PVP / V copolymer (PVP / VA copolymer) as a ionic styling polymer in a composition ratio as shown in Table 3 below. . The unit is weight percent.

division Example 7 Example 8 Example 9 Comparative Example 7 Comparative Example 8 Comparative Example 9 30% Sodium Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 30% Sodium Polyoxyethylene Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Propylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 PVP / VA Copolymer 3.0 3.0 3.0 3.0 3.0 3.0 Organic Silicone Resin Variant (Q2-5220) 0.4 0.6 0.4 - 0.4 - Hydroxypropyl chitosan 0.5 0.5 1.0 - - 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Cartonsea 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 water Up to 100% by weight

Examples 10-12, and Comparative Examples 10-12

In Example 1 was carried out in the same manner as in Example 1 except that polyquaternium-11, which is a cationic styling polymer, was used as the styling polymer at a composition ratio as shown in Table 4 below. The unit is weight percent.

division Example 10 Example 11 Example 12 Comparative Example 10 Comparative Example 11 Comparative Example 12 30% Sodium Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 30% Sodium Polyoxyethylene Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Propylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 Polyquaternium-11 3.0 3.0 3.0 3.0 3.0 3.0 Organic Silicone Resin Variant (Q2-5220) 0.4 0.6 0.4 - 0.4 - Hydroxypropyl chitosan 0.5 0.5 1.0 - - 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Cartonsea 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 water Up to 100% by weight

Examples 13-15, and Comparative Examples 13-15

Except for using the cationic styling polymer polyquaternium-11 and the nonionic styling polymer fibbi / V copolymer as a styling polymer in the composition ratio as shown in Table 5 in Example 1 It was carried out in the same manner as. The unit is weight percent.

division Example 13 Example 14 Example 15 Comparative Example 13 Comparative Example 14 Comparative Example 15 30% Sodium Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 30% Sodium Polyoxyethylene Lauryl Sulfate 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Propylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 Polyquaternium-11 1.5 1.5 1.5 1.5 1.5 1.5 PVP / VA Copolymer 1.5 1.5 1.5 1.5 1.5 1.5 Organic Silicone Resin Variant (Q2-5220) 0.4 0.6 0.4 - 0.4 - Hydroxypropyl chitosan 0.5 0.5 1.0 - - 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 Cartonsea 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 water Up to 100% by weight

The styling holding power, and hair trimming effect of the styling shampoo prepared in Examples 1 to 15 and Comparative Examples 1 to 15 were evaluated in the same manner as in Experimental Examples 1 and 2 below.

Experimental Example 1. Style Holding Force

A hair stalk having a length of 20 cm and a weight of 0.8 g was immersed in a 5% polyoxyethylene lauryl ether solution for 5 minutes, then rinsed for 1 minute in running water, and left for 24 hours at 25 ° C. and a relative humidity of 50%. Then, the hair stalk was immersed for 5 minutes in the 5% solution of the styling shampoo composition prepared in Examples 1 to 15, and Comparative Examples 1 to 15. After rinsing this for 1 minute in running water, it was left for 30 minutes in a thermo-hygrostat (25 ° C, 50 RH%) to remove water. The hair skewed hair was wound in a spiral coil and dried in a thermo-hygrostat (25 ° C., 30 RH%), and the dried hair was carefully separated from the coil. This was put into a thermo-hygrostat (25 ° C., 50 RH%), and the styling retention effect was compared by the curl retention method, which compares the degree of curling over time. Curl-retention (%) was calculated according to Equation 1, and the average result of three repeated measurements is shown in Table 6 below. The larger the value, the better the style retention.

[Equation 1]

In Equation 1, Lo is the length of the hair used for the test, Lt is the length of the tress (t) after t hours, Ls is the initial length of the curl tress formed (t = 0).

division Style retention (curl retention%) division Style retention (curl retention%) Example 1 64 Comparative Example 1 43 Example 2 72 Comparative Example 2 56 Example 3 68 Comparative Example 3 52 Example 4 61 Comparative Example 4 40 Example 5 68 Comparative Example 5 53 Example 6 64 Comparative Example 6 49 Example 7 58 Comparative Example 7 38 Example 8 66 Comparative Example 8 50 Example 9 61 Comparative Example 9 45 Example 10 54 Comparative Example 10 33 Example 11 60 Comparative Example 11 47 Example 12 58 Comparative Example 12 41 Example 13 54 Comparative Example 13 35 Example 14 64 Comparative Example 14 48 Example 15 60 Comparative Example 15 44

Through Table 6, the shampoo composition of Examples 1 to 15 containing the styling polymer alone or in combination and simultaneously comprising a chitosan derivative and an organic silicone resin variant according to the present invention compared to the compositions of Comparative Examples 1 to 15 It was confirmed that the style retention is excellent. In addition, as the content of the organosilicon resin variant or chitosan derivative was increased, the retention of style was also increased, and the style retention of Examples 1 to 3 using the anionic styling polymer as the styling polymer was the best.

Experimental Example 2. Hair Trimming

30 random women were selected as test subjects, and the shampoo compositions of Examples 1 to 3 to which the FMB / A copolymer, which is an anionic styling polymer, exhibited the best styling retention effect in Experimental Example 1 The usual method was 5 people each for 2 weeks. On the second week, hair trimming effect was evaluated in a completely dry state. Evaluation of hair trimming effect is shown in Table 7 by averaging the score after subjects subjectively scored based on the following evaluation criteria.

<Evaluation Criteria>

grade division 5 Very good trimming effect 4 Excellent tidy effect 3 usually 2 Almost no trimming effect One No trimming effect

division Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Trimming effect 3.4 4.0 3.8 1.2 2.8 2.2

Through the above Table 7, the shampoo composition of Examples 1 to 3 containing the styling polymer alone or in combination and simultaneously comprising a chitosan derivative, and an organic silicone resin variant according to the present invention compared to the compositions of Comparative Examples 1 to 3 It was confirmed that the hair trimming effect is excellent.

As described above, the styling shampoo composition of the present invention can save time by providing styling, styling maintenance, and trimming functions simultaneously with washing, reducing the trouble of separately washing hands, and stiff hair. Not only does not harden or hard, compared to the conventional shampoo has the advantage of excellent styling retention and hair trimming effect.

Claims (8)

In the shampoo composition, a) styling polymer; b) chitosan derivatives; And c) organic silicone resin variant Styling shampoo composition comprising a. The method of claim 1, a) 0.01 to 20% by weight styling polymer; b) 0.01 to 10 weight percent of chitosan derivatives; And c) 0.01 to 30% by weight of organic silicone resin variant Styling shampoo composition comprising a. The method of claim 1, The styling polymer of a) is methacryloylethyl betaine / methacrylate copolymer copolymer, polyvinylpyrrolidone, PVP / VAcopolymer, PVP / dimethylaminoethylmethacrylate copolymer, PVM / AMB aerial PVM / MA copolymer, ethyl or butyl ester of PVM / MA copolymer, acrylate methacrylate copolymer, V / CRO Tonicate / vinyl neodecanoate copolymer (VA / crotonates / vinyl neodecanoate copolymer), polyquaternium-11, and polyquaternium-46 Styling shampoo composition selected from the group consisting of. The method of claim 1, The chitosan derivatives of b) include polyoxyalkylene chitosan, carboxymethyl chitosan, dihydroxypropyl chitosan, and N-2-hydroxypropylsulphonic acid chitosan (N-2). -hydroxylpropylsulfonic acid chitosan) styling shampoo composition selected from the group consisting of. The method of claim 1, Styling shampoo composition wherein the organic silicone resin variant of c) is represented by the following formula: [Formula] In the above formula, R is hydrogen or alkyl having 1 to 12 carbons, x is an integer from 1 to 100, y is an integer from 1 to 20, m and n are each an integer of 10-50. The method of claim 1, Styling shampoo composition of the c) the organic silicone resin variant is a silicone glycol copolymer (silicone glycol copolymer). The method of claim 1, Styling shampoo composition further comprises 5 to 50% by weight based on the total weight of the shampoo composition anionic surfactant, nonionic surfactant, or a mixture thereof in the shampoo composition. The method according to claim 1 or 8, A styling shampoo composition further comprising at least one component selected from the group consisting of preservatives, thickeners or viscosity adjusting agents, pH adjusting agents, flavoring agents, dyes, and conditioning agents in the shampoo composition.