KR20030027147A - Liquid Stickiness Composition and Writting Set Using The Same - Google Patents

Abstract

PURPOSE: An adhesive liquid composition and a writing instruments set using the composition are provided, to reduce the drying time and to enable the shape and image written or drawn by using the writing instruments set to be maintained when it is separated from the background surface after drying and to be adhered to the surface such as glass. CONSTITUTION: The adhesive liquid composition comprises 10-90 wt% of at least one cohesive resin selected from the group consisting of poly(vinyl alcohol), vinyl acetate, an acrylate copolymer, an acryl resin and a ketone resin; 10-90 wt% of at least one solvent selected from the group consisting of water, an alcohol of a low molecular weight and a glycol; 0.5-10 wt% of a butylcarbitol (diethylene glycol monobutyl ether) plasticizer; and optionally 20 wt% or less of a glitter comprising pearl or metal powder or piece. The writing instruments set comprises an applying instrument(10) (for adhesion) containing the adhesive liquid composition(30); and a writing instrument(20) containing an ink composition(40).

Description

Liquid Stickiness Composition and Writting Set Using The Same

The present invention relates to an adhesive liquid composition and a writing set using the same. More specifically, the drawing and writing surface can be formed in a predetermined shape on a non-absorbent base surface. It is possible to separate from the printing surface while attaching to an adhesive surface such as glass, and the adhesive liquid composition comprising an applicator for forming a writing surface and a writing instrument containing ink capable of writing on the writing surface and a writing set using the same. It is about.

Generally, in order to obtain an effect such as stained glass, an adhesive liquid composition called glass decor is provided so that a character or a picture can be drawn on a base surface of a plate or a film made of a non-absorbent material such as glass, plastic, or metal.

The conventional adhesive liquid composition consists of adhesive resin, a solvent, and a plasticizer, and adds a coloring agent, preservative, wetting agent, surfactant, etc. as needed.

Since the conventional adhesive liquid composition has a long drying time, it is left to dry for a long time (approximately 5 hours or more) after application to the base surface, and the drying is completed, and it can be separated from the base surface and attached to the required attachment surface.

Therefore, the conventional adhesive liquid composition has to wait 5 hours or more (approximately 0.5 mm thick) after application to the barntang, so in the case of children in a hurry to touch the hand drawn before drying the shape is broken Frequently throws or contaminates hands or clothes.

In addition, the conventional adhesive liquid composition is once applied to the base surface in a desired shape and dried to form a specific shape, and then simply peeled off and attached to the attachment surface, and is not used for other purposes.

An object of the present invention is to solve the above problems and to broaden the field of use, and it is possible to draw a picture or a character in a desired shape on a base surface, to shorten the drying time, and to form a smooth surface (writing surface). After the drying, it is to provide a tacky liquid composition that can be freely attached to and detached from the attachment surface by separating from the base surface while maintaining the drawn shape.

Another object of the present invention is to form a writing surface to be attached and detached to the attachment surface with an applicator containing the adhesive liquid composition and to write predetermined characters and drawings with the writing instrument containing a writing ink composition on the writing surface It is to provide a writing set using the adhesive liquid composition made.

Still another object of the present invention is to form a writing surface that can be attached and detached on the attachment surface with an applicator containing an adhesive liquid composition, and the writing instrument containing an ink composition capable of writing and erasing on the writing surface. It is to provide a writing set using the adhesive liquid composition made to be able to write and erase as necessary.

1 is a cross-sectional view schematically showing an embodiment of a writing set using the adhesive liquid composition according to the present invention.

Figure 2 is a cross-sectional view schematically showing another embodiment of a writing set using the adhesive liquid composition according to the present invention.

3 is a perspective view showing a state of drawing on the base surface by using the applicator according to the present invention.

4 is a perspective view showing a state of writing on a writing surface using the writing instrument according to the present invention.

Adhesive liquid composition proposed by the present invention is about 10 to 90% by weight of the adhesive resin formed by selecting one or more from polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, ketone resin, water, lower alcohol, glycols And about 10% to 90% by weight of a solvent formed by selecting one or more from the back, and about 0.5% to 10% by weight of a plasticizer made of butylcarbitol.

It is preferable to contain an adhesive resin and a solvent in the range of about 30 to 70 weight%, respectively, and it is preferable to contain a plasticizer in the range of about 2 to 7 weight% above.

If the adhesive resin is contained in less than 10% by weight, the film-forming ability is insufficient, and when contained in more than 90% by weight, the viscosity is too high to use.

Content of the said solvent becomes inversely proportional to content of said adhesive resin.

In addition, if the above-mentioned plasticizer is contained in less than 0.5% by weight, the adhesive resin hardens easily after drying, and thus, it is impossible to repeatedly peel off and attach to the adhered surface. Since it falls, desired adhesive performance cannot be obtained.

Any solvent may be used as long as it is a substance capable of dissolving the above-mentioned viscous resin. Preferably, it is preferable to use a lower alcohol in which alcohol and water are mixed in consideration of a drying speed.

Any of the above plasticizers can be used as long as the substance can soften the above-mentioned adhesive resin.

Although it is also possible to use glycols such as propylene glycol and ethylene glycol as the plasticizer, in this case, the drying time is about 5 hours or more (when the surface is coated with a thickness of about 0.5 mm). late.

However, when butyl carbitol, also called diethylene glycol monobutyl ether, is used as a plasticizer, the drying time is about 2 to 3 hours (approximately 0.5 mm on the surface). ), It was found that the drying rate is fast and the role as a plasticizer is sufficiently maintained through several experiments.

Therefore, the present invention has been exemplified by using butyl carbitol as a plasticizer, and in addition to butyl carbitol, various other materials having a high drying speed and sufficient role as a plasticizer may be used.

And the adhesive liquid composition which this invention suggests can also contain a coloring agent, a preservative, a wetting agent, surfactant, etc. in the range of about 0.01-20 weight%, respectively.

As the colorant, dyes or pigments may be used, and in order to maintain a transparent state after drying, it is preferable to use a dye, and to maintain an opaque state after drying, a pigment is used. desirable.

Moreover, it is also possible to adjust the transparency after drying by mixing suitably the said dye or pigment.

In addition, when the product which does not contain a color is desired, the said coloring agent may be abbreviate | omitted.

In addition, the adhesive liquid composition proposed by the present invention may further include glitter such as pearl, metal powder or flakes in an amount of 20% by weight or less for the sparkling sparkling effect.

In addition, the handwriting set using the adhesive liquid composition proposed by the present invention is approximately 30 to 70% by weight of the adhesive resin formed by selecting one or more from polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, ketone resin, water, An applicator containing an adhesive liquid composition containing approximately 30 to 70 wt% of a solvent selected from one or more lower alcohols and glycols, and about 2 to 7 wt% of a plasticizer made of butylcarbitol; Approximately 20 to 90% by weight of a solvent formed by selecting one or more from water, alcohols, glycols, and the like, and polyvinylpyrrolidone, celluloses, ketone resins, etc., so as to write on a writing surface formed by an applicator. Approximately 2 to 10% by weight of the selected resin and about 0.1 to 10% by weight of a colorant composed of a dye or a pigment Consists of a built-in ink compositions for writing instruments that do not fit preservability.

And the writing set using the adhesive liquid composition proposed by the present invention is about 30 to 70% by weight of the adhesive resin made of at least one selected from polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, ketone resin, water, An applicator containing an adhesive liquid composition containing approximately 30 to 70% by weight of a solvent formed by selecting at least one of lower alcohols and glycols, and approximately 2 to 7% by weight of a plasticizer made of butylcarbitol; Approximately 20 to 90% by weight of a solvent formed by selecting one or more from water, alcohols, glycols, and the like, and polyvinylpyrrolidone, celluloses, ketone resins, etc., so as to write on a writing surface formed by an applicator. Approximately 2 to 10% by weight of the selected resin, approximately 0.1 to 10% by weight of a colorant composed of dyes and pigments, and fat Erased containing scavengers approximately 0.1 to 10% by weight obtained by selection of one or more alcohols or fatty acid esters, etc. It is also possible to made of a writing instrument with a built-erase ink compositions resistance.

It may further contain 20% by weight or less of glitter, such as pearl, metal powder or flakes, for the sparkling effect of the ink composition which is not erased and the erased ink composition which is erased. It is possible.

Next, a preferred embodiment of the adhesive liquid composition and the writing set using the same according to the present invention will be described in detail with reference to the accompanying drawings.

First, an embodiment of the writing set using the adhesive liquid composition according to the present invention, as shown in Figure 1, by drawing an applicator (10) with a built-in adhesive liquid composition 30, and the above-described applicator (10) It consists of a writing instrument 20 incorporating a preservable ink composition 40 that is not erased so that the writing surface 4 can be written.

The applicator 10 and the writing instrument 20 may be formed integrally as shown in FIG. 1, or may be separately formed by separate members.

The applicator 10 includes a body 12 in which the adhesive liquid composition 30 is embedded, a tip member 14 assembled to the body 12 and the adhesive liquid composition 30 flows out, The lid 16 is detachably assembled to the tip member 14 and / or the body 12 to prevent the adhesive liquid composition 30 from drying out or leaking out.

Since the tip member 14 of the applicator 10 can be generally implemented in various structures applied to the applicator used for applying the correction liquid, liquid adhesive, nail polish, etc., detailed description thereof will be omitted.

For example, one end of the tip member 14 is formed to be assembled to the body 12, and the cross-sectional area is gradually reduced toward the opposite side, and the tip member 14 may be implemented as an integral member formed in a thin pipe shape at the end. In addition, it is also possible to manufacture the pipe-shaped portion by a separate pipe member 15 and to assemble it integrally.

The lid 16 is in close contact with the end surface of the tip member 14 in the assembled state for storage, as well as preventing leakage of the tacky liquid composition 30, as well as contact between the air and the tacky liquid composition 30. A seal 17 is installed to prevent damage.

The seal 17 is configured to be in close contact with the end surface of the pipe member 15, and is formed using a rubber or synthetic resin having a predetermined elasticity.

The writing instrument 20 is assembled with the body 12 of the applicator 10, the body 22, the storage ink composition 40 is built-in, the holder 24 is assembled to the body 22 And a pen body 25 which is assembled to the holder 24 and the preservative ink composition 40 flows out, and is detachably assembled to the holder 24 and / or the body 22 to store the ink composition ( 40 is made of a lid 26 to prevent drying or outflow.

In the writing instrument 20, the pen body 25 may be formed of a fiber member or a porous member which discharges ink by capillary action as shown in FIG. 1, and is generally used in ballpoint pens, sign pens, marking pens, and the like. Since it is also possible to form the tip portion (pen body) in various structures, a detailed description thereof will be omitted.

The body 22 may be inserted into the body for storing and storing the ink composition 40, it is also possible to inject the ink composition 40 directly into the body (22).

The lid 26 is the holder described above so that the ink composition 40 remaining in the pen body 25 exposed to the outside of the holder 24 is not dried in contact with external air in an assembled state for storage. 24) and / or the body 22 is preferably configured to be sealed.

It is preferable to form a clip 29 on the lid 16 of the applicator 10 or the lid 26 of the writing instrument 20 so as to be inserted into a collar or a pocket.

In addition, the lid 16 of the applicator 10 and the lid 26 of the writing instrument 20, as shown in Figs. It is preferable to be assembled and stored on the other lid at the time of drawing so that there is no fear of loss and the length as a writing instrument sufficient for writing is secured.

For example, the outer peripheral surface 18 of the end portion 16 of the lid 16 of the applicator 10 and the outer peripheral surface of the body 22 and / or the holder 24 are assembled with the lid 26 of the writing instrument 20. The body 12 and / or tip member 14 formed in the same shape and assembled with the lid 16 of the lid 26 of the writing instrument 20 with the lid 16 of the applicator 10 described above. It is formed in the same shape as the outer circumferential surface of

The adhesive liquid composition 30 embedded in the applicator 10 includes about 30 to 70 wt% of the adhesive resin formed by selecting one or more selected from polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, ketone resin, and the like. And about 30 to 70% by weight of a solvent obtained by selecting one or more from water, lower alcohol, glycols, and the like, and about 2 to 7% by weight of a plasticizer made of butylcarbitol.

It is also possible to contain an adhesive resin and a solvent in the range of about 10 to 90 weight%, respectively.

If the above-mentioned adhesive resin is contained in less than 10% by weight, the film-forming ability is insufficient, and if it contains more than 90% by weight, the viscosity is too high to be difficult to use, so if it is contained in the range of about 10 to 90% by weight The range of 30-70 weight% is the most preferable.

Content of the said solvent becomes inversely proportional to content of said adhesive resin.

Moreover, the said plasticizer can also be contained in about 0.5 to 10 weight% of range.

If the plasticizer is contained in less than 0.5% by weight, the adhesive resin hardens easily after drying, and thus it is difficult to detach and attach repeatedly to the adhesive surface.If the plasticizer is contained in an amount exceeding 10% by weight, the adhesive resin is softened excessively, resulting in adhesive performance. Since it falls, desired adhesive performance cannot be obtained.

Therefore, although the said plasticizer should just be contained in about 0.5 to 10 weight% of a range, the range of 2 to 7 weight% is the most preferable.

Any solvent may be used as long as it is a substance capable of dissolving the above-mentioned viscous resin. Preferably, it is preferable to use a lower alcohol in which alcohol and water are mixed in consideration of a drying speed.

Any of the above plasticizers can be used as long as the substance can soften the above-mentioned adhesive resin.

Although it is also possible to use glycols such as propylene glycol and ethylene glycol as the plasticizer, in this case, the drying time is about 5 hours or more (when the surface is coated with a thickness of about 0.5 mm). late.

However, when butyl carbitol, also called diethylene glycol monobutyl ether, is used as the plasticizer, the drying time is about 2 to 3 hours (approximately 0.5 mm on the surface). In one case, the drying speed is increased.

The adhesive liquid composition 30 may further contain a colorant, a preservative, a humectant, a surfactant, and the like in the range of approximately 0.01 to 20% by weight, respectively.

As the colorant, dyes or pigments may be used, and in order to maintain a transparent state after drying, it is preferable to use a dye, and to maintain an opaque state after drying, a pigment is used. desirable.

Moreover, it is also possible to adjust the transparency after drying by mixing suitably the said dye or pigment.

In addition, when the product which does not contain a color is desired, the said coloring agent may be abbreviate | omitted.

In addition, the adhesive liquid composition 30 may further include a glitter such as pearl, metal powder or flakes in an amount of 20% by weight or less for the sparkling sparkling effect.

The indelible ink composition 40 embedded in the writing instrument 20 includes about 20 to 90% by weight of a solvent selected from one or more selected from water, alcohols, glycols, and the like, polyvinylpyrrolidone, and cellulose. And about 2 to 10% by weight of a resin obtained by selecting one or more from ketone resins, and about 0.1 to 10% by weight of a colorant made of a dye or a pigment.

The ink composition 40 may further include a glitter such as pearl, metal powder or flakes in an amount of 20 wt% or less for the sparkling sparkling effect.

And another embodiment of the writing set using the adhesive liquid composition according to the present invention, as shown in Figure 2, the applicator 10 incorporating the adhesive liquid composition 30 described above, and eraseable ink composition 42 to be erased It consists of a writing instrument 20 built-in.

Since the structure of the applicator 10 and the writing instrument 20 can be implemented in the same configuration as the above-described embodiment, detailed description thereof will be omitted.

The erasable ink composition 42 to be erased is selected from about 20 to 90% by weight of a solvent formed by selecting at least one from water, alcohols, glycols, and the like, and at least one from polyvinylpyrrolidone, celluloses, ketone resins, and the like. About 2 to 10% by weight of the resin, about 0.1 to 10% by weight of a colorant consisting of dyes and pigments, and about 0.1 to 10% by weight of a scavenger comprising at least one selected from fatty alcohols and fatty acid esters, and the like. .

The ink composition 42 may further include a glitter such as pearl, metal powder or flakes in an amount of 20 wt% or less for the sparkling sparkling effect.

In addition, the writing set using the adhesive liquid composition according to the present invention may combine the above-described applicator 10 and writing instrument 20 to provide various colors in one case.

The applicator 10 and the writing instrument 20 made as mentioned above were manufactured as follows, and drawing and writing were performed, and the state was observed.

Example 1

First, 45% by weight of polyvinyl alcohol as an adhesive resin, 51.4% by weight of water as solvent, 3% by weight of butyl carbitol, 0.1% by weight of preservative, and 0.5% by weight of Yellow 10G (manufactured by Uksung Chemical Co., Ltd.) as a colorant The mixture was stirred evenly for 1 hour to obtain a yellow adhesive liquid composition (30).

The yellow adhesive liquid composition 30 obtained as described above was injected into the body 12, and the tip member 14 and the pipe member 15 were assembled to prepare 10 applicators 10.

Example 2

83.9% by weight of ethyl alcohol, 10% by weight of polyvinylpyrrolidone as resin, 4.0% by weight of Red 2RM (manufactured by Uksung Chemical Co., Ltd.), 2.0% by weight of propylene glycol as a plasticizer and 0.1% by weight of preservative It was added and stirred for 1 hour evenly to obtain a red ink composition (40) of the preservation not to be erased.

The red ink composition 40 of the preservation line obtained as described above was injected into the body 22 to assemble the holder 24 and the pen body 25 to prepare 10 writing instruments 20.

Example 3

80.9 wt% ethyl alcohol as solvent, 10 wt% polyvinylpyrrolidone as resin, 4.0 wt% Red 2RM (manufactured by Uksung Chemical Co., Ltd.) as colorant, 5.0 wt% oleyl alcohol as scavenger, 0.1 wt% preservative Into a red ink composition (42) that was removed by stirring for 1 hour and evenly removed.

The eraser red ink composition 42 obtained as described above was injected into the body 22 to assemble the holder 24 and the pen body 25 to prepare 10 writing instruments 20.

Example 4

40% by weight of polyvinyl alcohol as adhesive, 54.4% by weight of water as solvent, 5% by weight of butyl carbitol as plasticizer, 0.1% by weight of preservative, 0.5% by weight of Red 2RM (manufactured by Uksung Chemical Co., Ltd.) as colorant It stirred evenly for 1 hour and obtained the red adhesive liquid composition 30.

The red adhesive liquid composition 30 obtained as described above was injected into the body 12, and the tip member 14 and the pipe member 15 were assembled to prepare 10 applicators 10.

Example 5

83.9% by weight of ethyl alcohol as solvent, 10% by weight of polyvinylpyrrolidone as resin, 4.0% by weight of yellow 10G (manufactured by Uksung Chemical Co., Ltd.), 2.0% by weight of propylene glycol as plasticizer and 0.1% by weight of preservative Then, the mixture was stirred evenly for 1 hour to obtain a yellow ink composition (40) of the preservation.

The yellow ink composition 40 of the storage composition obtained as described above was injected into the body 22 to assemble the holder 24 and the pen body 25 to prepare 10 writing instruments 20.

Example 6

80.9% by weight of ethyl alcohol as solvent, 10% by weight of polyvinylpyrrolidone as resin, 4.0% by weight of yellow 10G (manufactured by Uksung Chemical Co., Ltd.), 5.0% by weight of oleyl alcohol as scavenger, 0.1% by weight of preservative It was added and stirred evenly for 1 hour to obtain a yellow ink composition (42) of scavenging.

The eraser yellow ink composition 42 obtained as described above was injected into the body 22 to assemble the holder 24 and the pen body 25 to prepare 10 writing instruments 20.

Comparative Example 1

45% by weight of polyvinyl alcohol as a tacky resin, 51.4% by weight of water as solvent, 3% by weight of propylene glycol as plasticizer, 0.1% by weight of preservative, 0.5% by weight of yellow 10G (manufactured by Uksung Chemical Co., Ltd.) as a colorant in a stirrer 1 It stirred evenly over time and obtained the yellow adhesive liquid composition 30.

The red adhesive liquid composition 30 obtained as described above was injected into the body 12, and the tip member 14 and the pipe member 15 were assembled to prepare 10 applicators 10.

Comparative Example 2

83.9% by weight of ethyl alcohol, 10% by weight of polyvinylpyrrolidone as resin, 4.0% by weight of Red 2RM (manufactured by Uksung Chemical Co., Ltd.), 2.0% by weight of propylene glycol as a plasticizer and 0.1% by weight of preservative Then, the mixture was stirred evenly for 1 hour to obtain a red ink composition (40) of the preservation.

10 writing instruments 20 were manufactured by assembling the holder 24 and the pen body 25 by injecting the preservative red ink composition 40 obtained as described above into the body 22.

Comparative Example 3

80.9 wt% ethyl alcohol as solvent, 10 wt% polyvinylpyrrolidone as resin, 4.0 wt% Red 2RM (manufactured by Uksung Chemical Co., Ltd.) as colorant, 5.0 wt% oleyl alcohol as scavenger, 0.1 wt% preservative It was added to the mixture and stirred evenly for 1 hour to obtain an erasable red ink composition (42).

The eraser red ink composition 42 obtained as described above was injected into the body 22 to assemble the holder 24 and the pen body 25 to prepare 10 writing instruments 20.

As shown in FIG. 3 on the base surface 2 made of glass plates, respectively, using the applicator 10 of Examples 1 and 4 and Comparative Example 1 described above, the thickness of 5 cm x 5 cm After writing the rectangular writing surface 4, the time to complete drying was measured. The measured drying completion time is shown in Table 1 below.

Whether or not the drying is complete in the above, it is determined that the drying is completed if the pressure-sensitive adhesive liquid composition does not adhere to the hand and lightly deformed does not occur.

division Example 1 Example 4 Comparative Example 1 Ingredient (% by weight) Polyvinyl alcohol 45 40 45 water 51.4 54.4 51.4 Butyl Carbitol 3 5 Propylene glycol 3 antiseptic 0.1 0.1 0.1 Yellow 10G 0.5 0.5 Red 2RM 0.5 Sum 100 100 100 Drying completion time (hour) 1.5 One 2 2 Three 2.5 5 5 3 2 One 3.5 One One 4 2 5 or more 7

As can be seen from Table 1 above, in the case of the tacky liquid compositions of Examples 1 and 4, the drying time is mostly 2 to 3 hours, while in the case of the tacky liquid composition of Comparative Example 1, the drying is completed. Since most of the time is 5 hours or more, the present invention has an effect that the drying time is greatly shortened.

After the drying is completed as described above, the drawn rectangular writing surface 4 is detached from the base surface 2 of the glass plate and attached to the attaching surface 6 made of synthetic resin, as shown in FIG. A predetermined character 8 or a picture (7) is written on the rectangular writing surface 4 drawn by the applicator 10 of Example 1 by the writing instrument 20 of Example 2, Example 3, Comparative Example 2, or Comparative Example 3 ) And write a predetermined letter (8) or a picture (7) on a rectangular writing surface (4) drawn by the applicator (10) of Example 4 with the writing instrument (20) of the above-described embodiments 5 and 6 ).

Then, the transition and fixability of the written predetermined character 8 or the figure 7 to the writing surface 4 are observed, and the erased predetermined character 8 or the figure 7 is erased (not shown). Was eliminated). The observed results are shown in Table 2 below.

In the above, the transferability and fixability to the writing surface 4 may be rubbed with a finger after 5 minutes of writing, and the ink composition may be smeared on the hand and the written characters 8 or 7 may be completely erased. Very bad ", and if the ink composition is smeared on the hand and the letters (8) or picture (7) remain blurry, it is labeled" bad "and the ink composition is not smeared on the hand (8) or If the picture (7) remains in a written state, mark it as "good." If the text (8) or the picture (7) is clear, the border is clearly written, and the handwritten state remains, "good". Mark as.

In the above description, the eraser is rubbed with an eraser after 5 minutes of writing, and when the written character (8) or the figure (7) is completely erased, it is marked as "very good". ) If it is blurry, mark it as "good"; if the letter (8) or picture (7) is conspicuous, mark it as "bad", and the letter (8) or picture (7) is almost If it is not erased, it is written as "very bad".

division Example 2 Example 3 Example 5 Example 6 Comparative Example 2 Comparative Example 3 Ingredient (% by weight) Ethyl alcohol 83.9 80.9 83.9 80.9 Polypyrrolidone 10 10 10 10 10 10 Red 2RM 4.0 4.0 4.0 4.0 Yellow 10G 4.0 4.0 Propylene glycol 2.0 2.0 2.0 Oleyl alcohol 5.0 5.0 5.0 antiseptic 0.1 0.1 0.1 0.1 0.1 0.1 Sum 100 100 100 100 100 100 Metastasis and fixation Very good One One good 8 Nine Nine 8 Three One Bad One One 2 7 Nine Very bad Scavenging Very good One 2 8 good 8 8 6 2 Bad 2 One Three Four Very bad 8 7

As can be seen from Table 2, in Examples 2 and 5, the transferability and fixability are excellent and the erasure property is bad, but in the case of Examples 3 and 6, the transferability and fixability are also excellent and the eraseability is excellent. Do.

On the other hand, in the case of Comparative Example 2, the transferability and fixability are bad while the scavenging ability is moderate.

Therefore, the preservative ink composition and the erasable ink composition according to the present invention can effectively maintain the written state without changing when the writing on the writing surface made by drying the adhesive liquid composition, the erasable ink composition is If necessary, it is also easy to erase using an eraser.

In the above description of the preferred embodiment of the adhesive liquid composition and the writing set using the same according to the present invention, the present invention is not limited to this, and the present invention is not limited to the claims and the detailed description of the invention and various modifications are made within the scope of the accompanying drawings. It is possible to do this and this also belongs to the scope of the present invention.

According to the adhesive liquid composition according to the present invention made as described above, since the drying speed is greatly shortened compared to the conventional adhesive liquid composition in about 2 to 3 hours, it is possible to reduce the boredom to wait until drying.

In addition, according to the writing set using the adhesive liquid composition according to the present invention as described above, the user forms the writing plate in the shape and shape desired by the user using the above-described applicator, and the writing surface of the writing plate is Since it is possible to write notes or reminders with a writing instrument, it is possible to make a special writing board or a memo board as a new use, instead of simply drawing a predetermined pattern using the adhesive liquid composition.

Furthermore, it is possible to attach and detach a memo board made of your own special patterns to home appliances such as a glass of a desk, a car, a refrigerator, etc., and write the necessary contents with a writing instrument incorporating an erasable ink composition on the memo board. It can also be erased, so it can be extended to a wide variety of uses.

For example, it can be used for notifications between family members, guidance while parking a car, marking the destination when a seat is available, and checking important tasks.

Claims (10)

10 to 90% by weight of an adhesive resin formed by selecting at least one of polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin and ketone resin, 10 to 90% by weight of a solvent formed by selecting at least one of water, lower alcohol and glycols, Adhesive liquid composition containing 0.5-10 weight% of plasticizers which consist of butyl carbitol. The adhesive liquid composition according to claim 1, wherein the adhesive resin and the solvent are contained in the range of 30 to 70% by weight, and the plasticizer is contained in the range of 2 to 7% by weight. The adhesive liquid composition according to claim 1, wherein at least one selected from colorants, preservatives, wetting agents, and surfactants is further contained in the range of 0.01 to 20% by weight. The tacky liquid composition according to claim 1, further comprising 20% by weight or less of a sheet material comprising pearl, metal powder or flakes. 30 to 70 wt% of a tacky resin formed by selecting at least one of polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, and ketone resin, and a solvent formed by selecting at least one from water, lower alcohol, and glycols. An applicator incorporating a tacky liquid composition comprising 70% by weight and 2 to 7% by weight of a plasticizer made of butyl carbitol, 20 to 90% by weight of a solvent formed by selecting at least one of water, alcohols, glycols, and at least one of polyvinylpyrrolidone, cellulose, and ketone resin so as to write on the writing surface formed by the above-described applicator. A writing set using an adhesive liquid composition comprising a writing instrument incorporating an ink composition containing 2 to 10% by weight of a resin obtained by selecting a resin and 0.1 to 10% by weight of a colorant consisting of a dye or a pigment. 30 to 70 wt% of a tacky resin formed by selecting at least one of polyvinyl alcohol, vinyl acetate, acrylate copolymer, acrylic resin, and ketone resin, and a solvent formed by selecting at least one from water, lower alcohol, and glycols. An applicator incorporating a tacky liquid composition comprising 70% by weight and 2 to 7% by weight of a plasticizer made of butyl carbitol, 20 to 90% by weight of a solvent formed by selecting at least one of water, alcohols, glycols, and at least one of polyvinylpyrrolidone, cellulose, and ketone resin so as to write on the writing surface formed by the above-described applicator. An ink composition comprising 2 to 10% by weight of a resin obtained by selecting a resin, 0.1 to 10% by weight of a colorant consisting of a dye or a pigment, and 0.1 to 10% by weight of a scavenger formed by selecting at least one of fatty alcohols and fatty acid esters. Handwriting set using a pressure-sensitive adhesive liquid composition consisting of writing instruments. According to claim 5 or 6, wherein the applicator is a body in which the adhesive liquid composition is embedded, A tip member assembled to the body and leaking the adhesive liquid composition; Handwriting set using a tacky liquid composition consisting of a lid detachably assembled to the tip member and the body to prevent the tacky liquid composition from drying out or spilling out when stored. The body of claim 5 or 6, wherein the writing instrument comprises: a body assembled with the body of the applicator and containing an ink composition; A holder assembled to the body, The pen body is assembled to the holder and the ink composition flows out; Handwriting set using a tacky liquid composition consisting of a lid detachably assembled to the holder and the body to prevent the ink composition from drying out or outflowing during storage. 7. The writing set using the tacky liquid composition according to claim 5 or 6, wherein the tacky liquid composition further contains at least one of colorants, preservatives, wetting agents and surfactants in the range of 0.01 to 20% by weight. The writing set using the adhesive liquid composition according to claim 5 or 6, wherein the ink composition further contains 20% by weight or less of a flap material made of pearl, metal powder or flakes.