KR200282026Y1 - Inorganic Insulation And Inorganic Foam Material Including Thereof - Google Patents

Abstract

Inorganic thermal insulation including inorganic foams is described. The inorganic foam is a foam mixture of 70 to 90% by weight of water glass (Na ₂ O.nSiO ₂ [n = 2 to 4]), 0.5 to 2.5% by weight of boric acid, 0.7 to 3.0% by weight of blowing agent and 4.5 to 28.8% by weight of water. It is prepared by foaming. The inorganic insulation is prepared by solidifying 11 to 17 wt% of the inorganic foam, 7 to 45 wt% of the Portland cement, 3.5 wt% of the filler, and 34.5 to 82 wt% of the binder solution. The inorganic heat insulating material manufactured using such an inorganic foam can be widely used in industry because of its low thermal conductivity, excellent mechanical strength, and no emission of harmful substances to the human body.

Description

Inorganic Insulation And Inorganic Foam Material Including Thereof}

The present invention relates to an inorganic foam and an inorganic insulating material, and more particularly, to an inorganic insulating material that can be used alternatively for thermal mortar, gypsum board, sandwich panel, styrofoam, using pure inorganic foam as a main component. .

Insulation is a structure that prevents the flow of heat from high place to low place. It effectively blocks heat loss and heat gain, saves energy, and prevents surface condensation caused by surface temperature drop. . In addition, by reducing the temperature change in the space it is possible to further improve the comfort, and to reduce the transmission of noise or vibration, and can additionally obtain the effects of sound absorption and sound insulation.

Generally, the type of insulation used can be largely classified according to the physical structure and the type of material. First, if the type of insulation is classified according to the physical structure, it can be divided into cell type and reflective insulation.

U.S. Pat.Nos. 5,173,517 (huroishi et, al), 5,093,384 (hayashi. Et, al) and 5,693,685 (kishimotor, et, al) have a small space or a hollow space when a part of a solid material is bonded or melted. Describes a cell type (bubble type) insulating material having a uniform shape by producing a sealed type. The cellular insulation may be divided into fine, granular, fibrous.

U.S. Patent No. 4,865,106 (wichelman. Et, al) consists of a multi-layered equilibrium lamina or a plurality of very thin metal plates with high reflectivity, which are spaced apart to reflect radiant heat to impede the flow of air. It describes a reflective insulation that has been designed or has a structure in which insulation has been inserted.

In addition, if the insulating material is classified according to the type of material, it may be classified into an inorganic or organic insulating material. U.S. Pat.Nos. 5,296,260 (sawada. Et, al) and 5,869,407 (rusek.jr, et, al) use inorganic materials such as rock wool, fiberglass, asbestos powder, perlite, diatomaceous earth, and foamed glass as main materials. Insulation is described. And U.S. Pat. Nos. 5,008,297 (maruyama. Et, al), 4,882,363 (conkey. Et, al) and 4,743,628 (neuhaus. Et, al) disclose corky polymers, polystyrene, polyethylene, isopides, urethanes, It describes organic insulating materials which are formed into foamed resin products using organic polymer materials such as urea and urea.

However, the inorganic heat insulating material formed using the asbestos powder, glass fiber and dark lead as the main material is a non-flammable material, and the heat insulating property is also excellent, but when inhaled in contact with the human body, it is gradually being prohibited from being used because it is a harmful substance causing cancer. . In addition, the inorganic heat insulating material formed using the foam glass as a subject is excellent in heat insulation, but its use is extremely limited due to its weak strength and easy breakage. In addition, organic foamed resin insulation formed by using main materials such as corkyl polymer, polystyrene, polyethylene, isopide, urethane, urea and urea is excellent in thermal insulation performance and moisture, but is very susceptible to heat in a fire, so it is easily burned and harmful. Generate gas. For this reason, organic heat insulating material that emits harmful gases in a fire is a trend to prohibit use because it causes a loss of life.

As a result, inorganic insulating materials are produced using inorganic raw materials, which are safe for fire, heat insulating, and harmless to human body. However, the inorganic heat insulating material is heavier than the conventional organic heat insulating material, and because of the high manufacturing cost is not widely used in a wide range of industries.

The first object of the present invention is to provide an inorganic foam having excellent heat insulation, light weight and fire resistance.

A second object of the present invention is to provide an inorganic heat insulating material including an inorganic foam having excellent heat insulating and lightweight and fire resistance.

1 is a schematic view showing an inorganic foam of the present invention.

2 is a schematic view showing an inorganic heat insulating material of the present invention.

3 is a process chart showing a first embodiment of the present invention.

4 is a process chart showing a second embodiment of the present invention.

Figure 5 is a block diagram showing a gypsum board comprising an inorganic insulating material prepared by the method of Examples 3, 4 and 5 of the present invention.

Figure 6 is a block diagram showing a sandwich panel including an inorganic insulating material prepared by the method of Examples 3, 4 and 5 of the present invention.

* Explanation of symbols for the main parts of the drawings *

10 inorganic foam 20 inorganic insulating material

30: plasterboard 40: panel

50: gypsum board 60: sandwich panel

The inorganic foam for achieving the first object of the present invention is water glass (Na ₂ O · nSiO ₂ [n = 2 ~ 4]) 70 to 90% by weight, boric acid 0.5 to 2.5% by weight, blowing agent 0.7 to 3.0% by weight And 4.5-28.8% by weight of the foam mixture can be obtained by foaming.

The inorganic insulating material for achieving the second object of the present invention is obtained by using an insulating mixture of 11 to 17% by weight of inorganic foam, 7 to 45% by weight of cement, 3.5% by weight of filler and 34.5 to 82% by weight of binder solution. Can be.

The inorganic heat insulating material formed using the inorganic foam can be widely commercialized because it has low thermal conductivity, excellent mechanical strength, and does not emit harmful substances to the human body.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

The inorganic heat insulating material using the inorganic material of the present invention is manufactured by using the inorganic foam, portland cement, filler and binder solution.

1 is a schematic view showing an inorganic foam of the present invention.

According to Figure 1, the inorganic foam 10 is 70 to 90% by weight of water glass (Na ₂ O · nSiO ₂ [n = 2 ~ 4]), 0.5 to 2.5% by weight boric acid, 0.7 to 3.0% by weight blowing agent and 4.5 water To 28.8% by weight of the foam mixture. The inorganic foam 10 has a specific gravity of 0.08 (g / cm ₃ ), the round shape of the foam is 0.1mm to 4mm, and has a hydrophobic and white characteristics.

It is preferable that the water glass (Na ₂ O.nSiO ₂ [n = 2 to 4]) has 70 to 90% by weight. If it is less than 70% by weight, the drying time may be increased, resulting in a decrease in productivity. If it is more than 90% by weight, it is difficult to form an excellent inorganic foam because it is not easily mixed with other mixtures.

The boric acid (Boric acid) is vitrified at a relatively low temperature (184 ℃) serves to provide the effect of lowering the hydrophobic characteristics and foaming temperature to the foam. The boric acid preferably has a range of 0.5 to 2.5% by weight. If it is less than 0.5% by weight, it is difficult to expect the effect of the excellent inorganic foam, and if it exceeds 2.5% by weight, the inorganic foam formation cost increases and productivity is lowered.

The blowing agent preferably has a range of 0.7 to 3% by weight. If it is less than 0.7 wt%, it is difficult to expect the effect of excellent foaming, and if it is 3 wt% or more, only a cost increase is obtained without improving the foaming function. And the blowing agent may use any one selected from sodium bicarbonate, ammonium carbonate, ammonium bicarbonate and sodium borohydride.

The foaming temperature of the mixture is preferably foamed at a temperature in the range of 400 to 700 ℃. This is because the vitrification of the water glass is made at 600 to 1000 ° C., so that foaming at the low point of the vitrification temperature can prevent stabilization of the foam and deformation by moisture.

2 is a schematic view showing an inorganic heat insulating material of the present invention.

2, the inorganic heat insulating material 20 is formed by mixing the inorganic foam 10, cement, filler and binder solution to solidify on a mold of a desired shape.

It is preferable that the inorganic foam having a specific gravity of 0.08 (g / cm ₃ ), the particle size of 0.1 mm to 4 mm, and having hydrophobic and white characteristics have a range of 11 to 17 wt%. If the inorganic foam is less than 11% by weight, it can not function as a heat insulating material due to the increase in thermal conductivity, and when it exceeds 17% by weight, the performance of the heat insulating material is increased due to the decrease in thermal conductivity, but widely used industrially due to the decrease in strength. It is not possible.

The cement preferably has a range of 7 to 45% by weight as portland cement. If the Portland cement is less than 7% by weight, the binding force of the inorganic foam is lowered, if the Portland cement exceeds 45% by weight, the binding force to the inorganic foam is increased but the performance of the heat insulating material is lost due to the increase in thermal conductivity.

The filler may be at least one selected from the group consisting of perlite powder, zeolite powder, magnesia, alumina and zinc oxide, and preferably less than 3.5% by weight. This is because the filler may play an important role in increasing the bonding strength of the binder and increasing the fire resistance of the molded insulation by filling a gap between the inorganic foams.

It is preferable that the binder solution for increasing the bonding force between the inorganic foam and the components has a range of 34.5 to 82% by weight.

The binder solution is composed of 3.3 to 15% by weight of water glass, 0.1 to 0.5% by weight of antioxidant and 84.5 to 96.4% by weight of water. The water glass preferably has a range of 3.3 to 15% by weight of the binder solution. If it is less than 3.3% by weight, the ability to maintain the high density of each of the components is reduced, if it exceeds 15% by weight results in an increase in the production cost.

The antioxidant may be one selected from ethylamine, methylamine and hydroquinone, preferably has a range of 0.1 to 0.5% by weight. This is because if it is less than 0.1% by weight, it is difficult to expect a role as an antioxidant, and if it exceeds 0.5% by weight, the production cost is increased without improving the performance of the antioxidant.

The lightweight fireproof foam insulation material manufacturing method according to the present invention first forms an inorganic foam. Subsequently, the inorganic foam, cement, filler and binder solution are mixed to form a heat insulating mixture. Thereafter, the thermally insulative mixture is injected onto a mold to solidify.

The inorganic foam is formed of 70 to 90% by weight of water glass (Na ₂ O.nSiO ₂ [n = 2 to 4]), 0.5 to 2.5% by weight of boric acid, 0.7 to 3.0% by weight of blowing agent, and 4.5 to 28.8% by weight of water. The foam mixture is formed by sufficiently stirring and thermally foaming at a temperature of 400 to 700 ° C.

The foaming temperature of the foam mixture is preferably foamed at a temperature in the range of 400 to 700 ℃. This is because since the water glass is vitrified at 500 to 1000 ° C., foaming at a lower point than the vitrification temperature can prevent stabilization of the inorganic foam and deformation by moisture.

Foaming of the foam mixture may be a method of drying the foam mixture to form fine particles and then foaming, and a method of spraying the foam mixture into a spray device to foam.

Forming and foaming the fine particles may form a size of the inorganic foam according to the size of the fine particles. This is because the size of the inorganic foam is reduced when the size of the fine particles is reduced, and the size of the inorganic foam is increased when the size of the fine particles is increased.

In addition, the method of spraying the foam mixture into the spray apparatus can adjust the size of the inorganic foam by adjusting the concentration of the foam mixture and the nozzle size of the spray apparatus. This is because the size of the inorganic foam is small when the concentration of the foam mixture and the size of the nozzle are reduced, and the size of the inorganic foam is increased when the concentration of the foam mixture and the size of the nozzle are increased.

The specific gravity of the inorganic foam formed in this way is 0.08 (g / cm ₃ ), the size of the foam particles is 0.1mm to 4mm, and has hydrophobic and white characteristics.

Subsequently, 11 to 17 wt% of the inorganic foam, 7 to 45 wt% of cement, 3.5 wt% of filler, and 34.5 to 75 wt% of binder solution are sufficiently mixed to form a heat insulating mixture.

And, in the manufacture of the inorganic heat insulating material, in order to increase the fire resistance of the inorganic foam may be further used at least one selected from the group consisting of magnesium oxide, aluminum oxide, zinc oxide and metal oxide.

In addition, methylcellulose, ethyl cellulose, casein, gelatin, polyvinyl alcohol and polyvinylacetate having 0.2 to 1% by weight of the inorganic foam by weight to increase the adhesion to the wall or slab, etc. when manufacturing the inorganic insulation At least one selected from the group consisting of these may be further added and used.

Thereafter, the insulating mixture may be injected onto the mold and solidified at a temperature of 80 to 300 ° C. for 30 minutes to 1 hour to prepare an inorganic insulating material. After the step of solidifying the heat insulating mixture, it may further comprise the step of surface treatment using a water repellent to prevent moisture absorption of the prepared inorganic heat insulating material.

Hereinafter, a light weight inorganic foam, a refractory foam insulation, and a method for manufacturing the same according to the present invention will be described in detail.

Example 1

1.3 wt% boric acid, 1.7 wt% sodium hydrocarbon used as blowing agent and 17 wt% water were mixed. Subsequently, 80% by weight of water glass (Na ₂ O. nSiO ₂ [n = 2-4]) was placed in a stirrer and stirred until the mixture was thoroughly mixed while slowly entering the mixture to form a foam mixture. The foam mixture was then dried to form fine particles using a grinder. Thereafter, the fine particles were instantaneously foamed at a temperature of 600 ° C. to form an inorganic foam. The inorganic foam obtained by the above method has a specific gravity of 0.08 (g / cm ₃ ), a round shape of foam particles of 0.1 mm to 4 mm, and has hydrophobic and white characteristics. At this time, the size of the inorganic foam can be adjusted according to the size of the fine particles.

Example 2

1.3 wt% boric acid, 1.7 wt% sodium hydrocarbon used as blowing agent and 17 wt% water were mixed. Subsequently, 80% by weight of water glass (Na ₂ O.nSiO ₂ [n = 2-4]) was placed in a stirrer and stirred until the mixture was thoroughly mixed while slowly entering the mixture to form a foam mixture. The foam mixture was then sprayed using a spray apparatus. The sprayed foam mixture was instantaneously foamed at a temperature of 600 ° C. to form inorganic foams. The inorganic foam obtained by the above method has a specific gravity of 0.08 (g / cm ₃ ), a round shape of foam particles of 0.1 mm to 4 mm, and has hydrophobic and white characteristics. At this time, the size of the inorganic foam can be adjusted by adjusting the nozzle size of the spray apparatus and the concentration of the foam mixture.

3 is a process chart showing Example 1 of the present invention.

According to Figure 3, the characteristic of the process chart of Example 1 is to crush the foam mixture into fine particles after drying, and to form the inorganic foam by foaming the fine particles at a high temperature. The inorganic foam size can be adjusted to the size of the dried foam mixture particles.

4 is a process chart showing Example 2 of the present invention.

According to FIG. 4, the characteristic of the second embodiment is to spray the foam mixture with a spray and to foam the sprayed foam mixture at a high temperature to form an inorganic foam. The size of the inorganic foam can be adjusted by the nozzle size of the spray device and the concentration of the foam mixture.

The inorganic foam may be mixed with a back cement or a portland cement, in some cases, to prepare a mortar, and the mortar may be sprayed or plastered at a place where insulation is required to obtain insulation and sound insulation. In addition, the use of the mortar can be insulated even where it was difficult to insulate normally, and can be effectively insulated on the rooftop, the inner wall of the building and the weak part of the existing heat treatment. In addition, the products being produced and sold by three other companies, such as Yongjin Development, are made of ferrite, vermiculite, synthetic resin foam particles, etc., and cement is mixed therein, which has a low thermal insulation effect when compared with the product of the present invention. In addition, the production cost is 1.5 to 2.5 times higher.

Example 3

A binder solution was formed by mixing 6.7% by weight of water glass (Na ₂ O · nSiO ₂ [n = 2 ~ 4]), 0.3% of ethylamine used as an antioxidant, and 93% by weight of water. Subsequently, 13.8 wt% of the inorganic foam 10 of Preparation Example 1 and Preparation Example 2, 15 wt% of Portland Cement, 1.7 wt% of Filler, and 69.2 wt% of Binder Solution were sufficiently mixed to form a heat insulating mixture. The thermally insulative mixture was then poured onto the mold and solidified for 30 to 60 minutes at a temperature of 100 ° C. or higher to form the inorganic thermal insulator 20. Physical properties of the inorganic insulating material 20 is specific gravity of 0.375 (g / cm ₃ ), the thermal conductivity is 0.057 (kcal / m.hr. ℃). Subsequently, in order to prevent water absorption, a water repellent (zero-illumination; B, B) was treated on the surface of the inorganic insulating material 20.

And by attaching the manila cardboard, gypsum board 30 or panel 40 on the front, the back of the inorganic insulating material 20 produced in the same way as the fire-resistant gypsum board 50 and sandwich panel 60 It can manufacture.

Example 4

A binder solution was formed by mixing 3.3% by weight of water glass (Na ₂ O · nSiO ₂ [n = 2 ~ 4]), 0.3% of ethylamine used as an antioxidant, and 96.4% by weight of water. Subsequently, 7.4 wt% of the inorganic foam 10 of Preparation Example 1 and Preparation Example 2, 34.7 wt% of the Portland cement, and 57.8 wt% of the binder solution were sufficiently mixed to form a heat insulating mixture. The thermally insulative mixture was then poured onto the mold and solidified for 30 to 60 minutes at a temperature of 100 ° C. or higher to form the inorganic thermal insulator 20. Physical properties of the inorganic insulating material 20 is 0.575 (g / cm ₃ ), the thermal conductivity is 0.063 (kcal / m.hr. ℃). Subsequently, in order to prevent water absorption, a water repellent agent (young ililability; B, B) was treated on the surface of the inorganic insulating material 20.

And by attaching the manila cardboard, gypsum board 30 or panel 40 on the front, the back of the inorganic insulating material 20 produced in the same way as the fire-resistant gypsum board 50 and sandwich panel 60 It can manufacture.

Example 5

5% by weight of magnesium chloride and 95% by weight of water were mixed to form a binder material. Subsequently, 13.6 wt% of the inorganic foams 10, 18 wt% of magnesium oxide, and 68 wt% of the binder material of Preparation Example 1 and Preparation Example 2 were sufficiently mixed to form an insulating mixture. The thermal insulation mixture was then poured onto the mold and solidified at temperatures above 100 ° C. for 30 to 60 minutes to form the inorganic thermal insulation 20. Physical properties of the inorganic insulating material 20 is 0.425 (g / cm ₃ ), the thermal conductivity is 0.063 (kcal / m.hr. ℃). Subsequently, in order to prevent water absorption, a water repellent agent was applied on the surface of the lightweight refractory foam insulation 20.

And, by attaching a manila cardboard, gypsum board 30 or panel 40 on the front and back of the lightweight fire-resistant foam insulation 20 prepared by the above method, gypsum board 50 and sandwich panels excellent in fire resistance (60) can be manufactured.

Figure 5 is a block diagram showing a gypsum board comprising an inorganic insulating material prepared by the method of Examples 3, 4 and 5 of the present invention.

Figure 6 is a block diagram showing a sandwich panel including an inorganic insulating material prepared by the method of Examples 3, 4 and 5 of the present invention.

Experimental Example

The thermal conductivity test results of the inorganic heat insulating material of Table 1 were measured according to the test method and quality standards of the Korea Household Goods Testing Institute (KS L 9106-99) using the inorganic heat insulating material prepared in Examples 3, 4 and 5.

Test Methods Test result Test Items unit Example 3 Example 4 Example 5 Thermal conductivity ㎉ / m.hr. ℃ 0.057 0.063 0.061

Inorganic insulation prepared by the above method is lightweight and excellent in heat insulation can be used as a substitute for gypsum board. Currently, gypsum boards generally used provide functions such as waterproof gypsum board and fireproof gypsum board, but it is difficult to find more functions than plywood substitutes. In addition, heavy weight is a big disadvantage. In general, the bending failure load of gypsum board is very important. The inorganic insulation material of the present invention can adjust the bending failure load according to the amount of cement used. However, when the cement is used too much, the bending fracture load increases greatly but the thermal conductivity increases, so the amount of cement should be appropriately used for the application. In addition, when the manila board, the gypsum board or panel is attached to the front and back, the bending fracture load is greatly increased, so that it can meet various demands of the market.

In addition, the inorganic heat insulating material produced by the above method is lightweight and excellent in heat insulation can be used as a substitute for sandwich panels. Currently, sandwich panels manufactured by each company contain styrofoam or fiberglass. Sandwich panels using styrofoam have excellent thermal insulation, but can be easily exposed to fire and are dangerous. Glass fiber is not an ideal product because it is expensive and harmful to human body.

Therefore, the lightweight inorganic heat insulating material according to the present invention includes an inorganic foam having excellent properties as a main component, so it is hydrophobic and has excellent mechanical strength, and does not generate fire and harmful gases to the human body. In addition, the heat insulating property is superior to the conventional inorganic heat insulating material, and the production cost is low, so that the economic value is high. In addition, due to the above characteristics can reduce environmental pollution, it can prevent human, property loss due to fire.

Although described above with reference to a preferred embodiment of the present invention, those skilled in the art various modifications and changes to the present invention without departing from the spirit and scope of the present invention described in the claims below I can understand that you can.

Claims (6)

Inorganic molded bodies made into a board shape by mixing and solidifying inorganic foams, cement, inorganic fillers and binder solutions; And Lightweight refractory inorganic insulating material comprising a moisture barrier film made by coating a water repellent agent on the surface of the inorganic molded body. 2. The lightweight refractory inorganic material according to claim 1, wherein the inorganic foam is made of water glass (Na2O.nSiO2 [n = 2 to 4]) boric acid and a blowing agent as a main component, and has a spherical shape with a diameter of 1 to 4 mm. insulator. The lightweight refractory inorganic insulating material according to claim 1, wherein the inorganic filler is at least one selected from the group consisting of perlite powder, zeolite powder, magnesia, alumina and zinc oxide. The lightweight refractory inorganic insulator of claim 1, wherein the binder solution comprises 3.3 to 15 wt% of water glass, 0.1 to 0.5 wt% of antioxidant, and 84.5 to 96.4 wt% of water. Inorganic molded bodies made into a board shape by mixing and solidifying inorganic foams, cements, inorganic fillers, and binder solutions; A moisture barrier membrane formed by coating a water repellent on the surface of the inorganic molded body; And Lightweight fire resistant gypsum board, characterized in that it comprises a gypsum board attached on the moisture barrier film. Inorganic molded bodies made into a board shape by mixing and solidifying inorganic foams, cements, inorganic fillers, and binder solutions; A moisture barrier membrane formed by coating a water repellent on the surface of the inorganic molded body; And Lightweight fireproof sandwich panel, characterized in that it comprises a panel attached to the moisture barrier membrane.