KR200258845Y1 - Secondary combustion and reaction device of waste treatment device - Google Patents

Secondary combustion and reaction device of waste treatment device Download PDF

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KR200258845Y1
KR200258845Y1 KR2019980027825U KR19980027825U KR200258845Y1 KR 200258845 Y1 KR200258845 Y1 KR 200258845Y1 KR 2019980027825 U KR2019980027825 U KR 2019980027825U KR 19980027825 U KR19980027825 U KR 19980027825U KR 200258845 Y1 KR200258845 Y1 KR 200258845Y1
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gas
inlet
molten salt
naoh
reaction
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KR20000014502U (en
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지규일
박현서
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김징완
삼성중공업 주식회사
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Abstract

개시된 내용은 폐기물처리장치의 용융로를 거친 고농도의 산성가스와,불완전연소가스와, 분진을 함유한 배가스를 하나의 반응로에서 동시에 처리가능하도록 한 2차 연소 및 반응장치에 관한 것이다.The present disclosure relates to a secondary combustion and reaction apparatus which enables simultaneous treatment of a high concentration of acid gas, incomplete combustion gas, and dust containing exhaust gas through a melting furnace of a waste treatment apparatus in one reactor.

상기한 상기 2차연소 및 반응장치(200)는 수산화나트륨 투입구와, 공기주입구와, 냉각수입구 및 냉각수출구가 형성된 NaOH주입부; 상기 NaOH주입부의 투입구를 통해 주입되는 NaOH가 산성가스와 염화반응을 일으키는 반응로를 형성하고, 상기 반응로 내부로 폐기물처리 후의 배가스를 공급하기 위한 가스흡입구를 형성하고, 상기 가스흡입구로부터 공급된 배가스를 연소하는 가스버너를 구비하며, 상기 가스버너에 의해 연소되는 배가스를 완전 연소하기 위해 공기를 주입하는 2차공기 주입구로 형성된 2차연소부; 및 상기 NaOH주입부로 주입된 NaOH가 산성가스와 염화반응을 일으켜 발생된 용융염을 집진하는 용융풀을 형성하고, 상기 용융풀에 집진된 용융염을 배출하기 위한 용융염배출구를 형성하며, 가스배출부로 형성된 용융염 배출부로 달성된다.The secondary combustion and reaction apparatus 200 includes a sodium hydroxide inlet, an NaOH inlet formed with an air inlet, a cooling inlet and a cooling outlet; NaOH injected through the inlet of the NaOH injection unit forms a reaction reactor for causing a chloride reaction with acid gas, and forms a gas inlet for supplying the waste gas after the waste treatment into the reactor, exhaust gas supplied from the gas inlet A secondary burner having a gas burner for burning the gas and formed with a secondary air inlet for injecting air to completely burn the exhaust gas burned by the gas burner; And forming a molten pool for collecting the molten salt generated by NaOH injected into the NaOH injection unit by causing a chloride reaction with an acidic gas, forming a molten salt outlet for discharging the molten salt collected in the molten pool, and discharging the gas. A molten salt discharge portion formed as a negative portion is achieved.

Description

폐기물 처리장치의 2차연소및 반응장치Secondary combustion and reaction device of waste treatment device

본 고안은 폐기물 처리장치의 2차 연소와 동시에 산화가스의 염화반응 및 용융된 염의 배출수단이 구현된 폐기물 처리장치의 2차연소 및 반응장치에 관한 것이다.The present invention relates to a secondary combustion and reaction apparatus of a waste treatment apparatus in which the chlorination reaction of oxidizing gas and the discharge means of molten salt are implemented simultaneously with the secondary combustion of the waste treatment apparatus.

첨부 도면중 도 1a는 종래 폐기물이 용융로를 거친 뒤 2차 연소되는 과정을 나타내는 일예의 계통도이다.Figure 1a of the accompanying drawings is a schematic diagram showing an example of the process of the secondary combustion of the conventional waste after the melting furnace.

이 도면에 따르는 종래 후처리 과정은 용융로(100)를 나온 불완전 연소가스는 2차 연소로(110)에서 완전연소된 뒤 냉각수단(150)을 거쳐 용융비회는 백휠터(120)에서, 산성가스성분은 왯스크러버(130)에서 제거된 뒤 송풍팬(160)을 통하여 스택(170)으로 배출된다.According to the conventional post-treatment process according to this drawing, the incomplete combustion gas exiting the melting furnace 100 is completely burned in the secondary combustion furnace 110 and then the molten fly ash is passed through the cooling means 150 in the back filter 120, the acidic gas. The components are removed from the shock scrubber 130 and discharged to the stack 170 through the blower fan 160.

도 1b는 종래 폐기물이 용융로를 거친 뒤 2차 연소되는 과정을 나타내는 다른 예의 계통도이다.Figure 1b is a schematic diagram of another example showing a process in which the conventional waste secondary combustion after passing through the melting furnace.

이 도면에 따르는 종래 후처리 과정은 용융로(100)를 나온 불완전 연소가스는 2차 연소로(110)에서 완전연소된 뒤 냉각수단(150)을 거쳐 용융비회는 백휠터(120)에서, 산성가스성분은 반건식흡수탑(140)에서 각각 제거된 뒤송풍팬(160)을 통하여 스택(170)으로 배출된다.According to the conventional post-treatment process according to this drawing, the incomplete combustion gas exiting the melting furnace 100 is completely burned in the secondary combustion furnace 110 and then the molten fly ash is passed through the cooling means 150 in the back filter 120, the acidic gas. The components are discharged to the stack 170 through the back blowing fan 160 respectively removed from the semi-dry absorption tower 140.

이와같은 용융로를 거친 불완전연소가스와, 산성가스와, 일부 분진등을 처리하기 위해서는 필수적으로 2차 연소로(110), 반건식 흡수탑(140), 왯스크러버(130),백휠터(120)등의 설비를 갖추어야 하므로 규모가 대형화하는 단점이 있다.In order to process the incomplete combustion gas, acid gas, and some dust through the melting furnace, the secondary combustion furnace 110, semi-dry absorption tower 140, shock scrubber 130, back filter 120, etc. It must be equipped with the disadvantages of large scale.

또한, 산성가스성분은 왯스크러버에서 처리되는 경우 폐수발생의 문제점이 있으며, 반건식 흡수탑으로 실시하는 경우에는 과량의 Lime 사용으로 분진의 발생량이 많아져 용융비회의 처리에 있어 단점이 있다. 특히 발생된 염의 발생설비는 처음부터 설비되어 있지 않아 염의 배출할 수 없는 문제점도 있었다.In addition, the acidic gas component has a problem of generating waste water when treated in a shock scrubber, when the semi-dry absorption tower is used, the amount of dust generated by the use of excess Lime has a disadvantage in the treatment of molten ash. In particular, the generated salt generating equipment is not equipped from the beginning there was a problem that can not discharge salt.

본 고안은 상기와 같은 2차 연소로를 갖는 후처리설비가 갖는 문제점을 감안하여 폐기물 처리시 다량 발생되는 산성가스 및 불완전연소가스를 동시에 하나의 반응로에서 처리가능하게 하며, 2차 연소시의 연소온도를 소정의 고온으로 연소되게 하면서 NaOH용액과 반응하도록 하므로서 재활용 가능한 용융염으로 배출되게 하며, 동시에 이 용융염의 용융과정에서 소정의 분진도 함께 배출되게 하는 폐기물 처리의 용융2차연소및 반응장치를 제공하는 데에 그 목적이 있다.The present invention, in consideration of the problems of the after-treatment facilities having a secondary combustion furnace as described above, it is possible to simultaneously process a large amount of acid gas and incomplete combustion gas generated in the waste treatment in one reactor, Melting secondary combustion and reaction apparatus for waste treatment which allows the combustion temperature to be burned to a predetermined high temperature and reacts with the NaOH solution to be discharged as a recyclable molten salt and at the same time to discharge a predetermined amount of dust during melting of the molten salt. The purpose is to provide.

도 1a는 종래 폐기물이 용융로를 거친 뒤 2차 연소되는 과정을 나타내는 일예의 계통도Figure 1a is an exemplary system diagram showing a process in which the conventional waste secondary combustion after passing through the melting furnace

도 1b는 종래 폐기물이 용융로를 거친 뒤 2차 연소되는 과정을 나타내는 다른 예의 계통도Figure 1b is a schematic diagram of another example showing a process in which the conventional waste secondary combustion after passing through the melting furnace

도 2는 폐기물이 용융로를 거친 뒤 본 고안의 반응로를 거쳐 2차연소되는 과정을 나타내는 계통도2 is a system diagram showing a process in which waste is secondaryly burned through a reactor according to the present invention after passing through a melting furnace.

도 3은 본 고안 2차연소 및 반응장치의 정면 개략도Figure 3 is a front schematic view of the secondary combustion and reactor design

도 4는 본 고안 2차 연소 및 반응장치의 종단면도Figure 4 is a longitudinal cross-sectional view of the subject secondary combustion and reaction apparatus

도 5a는 도 4의 A-A선 단면도이고,도 5b는 도 4의 B-B선 단면도이며, 도 5c는 도 3의 B부분 요부 확대 단면도이다.5A is a cross-sectional view taken along the line A-A of FIG. 4, FIG. 5B is a cross-sectional view taken along the line B-B of FIG. 4, and FIG. 5C is an enlarged cross-sectional view of the main portion B of FIG.

※도면의 주요 부분에 대한 부호의 설명※ Explanation of code for main part of drawing

200:반응장치................................210:NaOH주입장치200: Reactor ...... 210: NaOH injection device

212:주입구..................................214:공기주입구212: Inlet port ............ 214: Air inlet port

216:냉각수입구..............................218:냉각수출구216: Cooling water inlet ........................ 218: Cooling water inlet

220:2차연소부...............................221:투시창220: Second combustion part ............... 221: Perspective window

222:배가스흡입구............................224:버너222: Exhaust gas inlet ......... 224: Burner

226:반응공간................................228:2차공기주입구226: reaction space ... 228: secondary air inlet

230:용융염배출부............................232:용융풀230: molten salt discharge part ............ 232: molten pool

234:용융염배출구............................236:배가스출구234: molten salt outlet ......... 236: exhaust gas outlet

이와같은 본 고안의 2차연소 및 반응장치는 수산화나트륨 투입구와, 공기주입구와, 냉각수입구 및 냉각수출구가 형성된 NaOH주입부; 상기 NaOH주입부의 투입구를 통해 주입되는 NaOH가 산성가스와 염화반응을 일으키는 반응로를 형성하고,상기 반응로 내부로 폐기물처리 후의 배가스를 공급하기 위한 가스흡입구를 형성하고, 상기 가스흡입구로부터 공급된 배가스를 연소하는 가스버너를 구비하며, 상기 가스버너에 의해 연소되는 배가스를 완전 연소하기 위해 공기를 주입하는 2차공기 주입구로 형성된 2차연소부; 및 상기 NaOH주입부로 주입된 NaOH가 산성가스와 염화 반응을 일으켜 발생된 용융염을 집진하는 용융풀을 형성하고, 상기 용융풀에 집진된 용융염을 배출하기 위한 용융염배출구를 형성하며, 가스배출부로 형성된 용융염 배출부로 달성된다.Such secondary combustion and reaction apparatus of the present invention is a sodium hydroxide inlet, NaOH inlet formed with an air inlet, the cooling inlet and the cooling outlet; NaOH injected through the inlet of the NaOH injection unit forms a reaction reactor for causing a chloride reaction with the acidic gas, forming a gas inlet for supplying the waste gas after the waste treatment into the reactor, exhaust gas supplied from the gas inlet A secondary burner having a gas burner for burning the gas and formed with a secondary air inlet for injecting air to completely burn the exhaust gas burned by the gas burner; And forming a molten pool for collecting the molten salt generated by NaOH injected into the NaOH injection unit by causing a chloride reaction with an acidic gas, and forming a molten salt outlet for discharging the molten salt collected in the molten pool and discharging the gas. A molten salt discharge portion formed as a negative portion is achieved.

이하 본 고안의 바람직한 실시예를 첨부 도면에 의거 상세하게 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

첨부 도면중 도 3은 본 고안 후처리반응로의 정면 개략도이며, 도 4는 본 고안 후처리 반응로의 종단면도이고, 도 5a는 도 4의 A-A선 단면도이고,도 5b는 도 4의 B-B선 단면도이며, 도 5c는 도 3의 B부분 요부 확대 단면도이다.3 is a front schematic view of the present invention aftertreatment reactor, FIG. 4 is a longitudinal sectional view of the present invention aftertreatment reactor, FIG. 5A is a cross-sectional view taken along line AA of FIG. 4, and FIG. 5B is a line BB of FIG. 4. It is sectional drawing, and FIG. 5C is an enlarged sectional view of the principal part B of FIG.

상기 도면에 따르는 본 고안 2차연소및 반응장치(200)는 기본적인 내화재의 로벽을 따라 상방으로 부터 NaOH주입장치(210)와, 2차연소부(220)와, 용융염배출장치(230)으로 이루어진다.Secondary combustion and reaction apparatus 200 according to the drawings comprises a NaOH injection device 210, a secondary combustion unit 220, and a molten salt discharge device 230 from above along the furnace wall of the basic refractory material.

상기 NaOH주입장치(210)는 첨부 도면 도 4에서 도시하는 바와같이 NaOH투입구(212)와, 공기주입구(214)와, 냉각수입구(216) 및 냉각수출구(218)로 이루어진다.The NaOH injection device 210 includes a NaOH inlet 212, an air inlet 214, a cooling inlet 216, and a cooling outlet 218, as shown in FIG. 4.

상기 2차연소부(220)는 가스흡입구(222)와, 2차공기주입구(228)와, 반응공간(226)으로 이루어진다.The secondary combustion unit 220 includes a gas inlet 222, a secondary air inlet 228, and a reaction space 226.

용융염배출장치(230)는 용융풀(232)과,용융염출구(234)와,배가스출구(236)로 이루어진다.The molten salt discharge device 230 includes a molten pool 232, a molten salt outlet 234, and an exhaust gas outlet 236.

이와같이 이루어진 본 고안 2차연소 및 반응장치는 폐기물이 용융로를 거친 뒤 본 고안의 반응로를 거쳐 2차연소되는 과정을 나타내는 계통도 (도 2)에서 도시하는 바와같이 용융로(240)에서 폐기물처리후의 배가스가 2차연소및 반응장치(200)의 가스흡입구(222)로 공급된다. 공급된 가스는 2차연소부(220)의 반응공간(226)에서 가스버너(224)를 통하여 약 1300℃이상의 고열상태에서 연소가 이루어짐과 동시에 2차공기주입구(228)을 통하여 공기를 공급받으면서 불완전가스상태로 공급된 가스를 완전연소시킨다.Secondary combustion and reaction apparatus of the present invention made as described above is a waste gas after the waste treatment in the melting furnace 240 as shown in the schematic diagram (Fig. 2) showing the process of the secondary combustion of the waste through the reactor of the present invention after passing through the melting furnace. It is supplied to the gas inlet 222 of the combustion combustion and reactor 200. The supplied gas is burnt in the high temperature state of about 1300 ° C. or more through the gas burner 224 in the reaction space 226 of the secondary combustion unit 220, and at the same time, the air is supplied incompletely through the secondary air inlet 228. The gas supplied in gas state is completely burned.

동시에 상기한 NaOH주입장치(210)의 투입구(212)를 통하여 NaOH가 투입되면서 공기투입구(214)를 통하여 공기가 공급되고, 냉각수입구(216)와 출구(218)을 통하여 냉각된 상태에서 상기한 연소중인 반응공간(226)에서 소정의 염화반응이 이루어진다.At the same time, NaOH is supplied through the inlet 212 of the NaOH injector 210 while air is supplied through the air inlet 214, and the air is cooled through the cooling inlet 216 and the outlet 218. In the combustion reaction space 226, a predetermined chlorination reaction takes place.

즉, 투입된 NaOH는 배가스 중 HCL등의 산성가스와 반응하여 Nacl을 얻어내고, 이 Nacl은 본 고안 2차연소 및 반응장치의 내벽을 타고 용융액적을 형성하면서 용융염 배출장치(230)의 용융풀(232)에서 고이게 된다. 고여진 용융염은 용융염배출구(234)를 통하여 배출된다.That is, the injected NaOH reacts with an acid gas such as HCL in the exhaust gas to obtain Nacl, and the Nacl forms a molten droplet on the inner wall of the secondary combustion and reactor of the present invention while forming molten droplets of the molten salt discharge device 230. Got to). The molten salt collected is discharged through the molten salt discharge port 234.

이때 배출되는 용융염에는 상당량의 분진이 포함되어 분진제거율을 높이게 되고, 용융염 반응후의 배가스는 배가스출구(236)를 통하여 배출된다.At this time, the molten salt discharged includes a considerable amount of dust to increase the dust removal rate, and the exhaust gas after the molten salt reaction is discharged through the exhaust gas outlet 236.

이와같이 본 고안은 폐기물처리시 용융로를 통하여 슬랙로 용융배출되고 난후의 배가스를 정화화하는 과정에서 고농도 산성가스와 불완전연소가스 및 분진함유의 배가스를 하나의 복합처리장치로서 동시에 처리가능하게 하므로서 후처리설비를 간단하게 하였으며, 이와같은 반응장치로서 분진의 배기를 줄이며, 소정의 반응과정을 통하여 용융염을 회수토록 하므로서 융점 강하제로 재활용 가능하게 되었디.As such, the present invention is capable of simultaneously treating high concentration acid gas, incomplete combustion gas, and dust-containing flue gas as one complex treatment device at the same time in the process of purifying the flue gas after being melted and discharged into slack through the melting furnace during waste treatment. The facility was simplified, and it was possible to recycle dust as a melting point lowering agent by reducing dust emissions and recovering molten salt through a predetermined reaction process.

이와같이 종래 용융로를 거친 불완전연소가스와, 산성가스와, 일부 분진등을 처리하기 위해서는 필수적으로 2차 연소로, 반건식 흡수탑, 왯스크러버,백휠터등의 설비를 갖추어야 함에 따른 설비의 대형화를 개선한 효과가 있으며, 산성가스성분을 왯스크러버를 통하여 처리하는 경우 발생되는 폐수발생의 문제점이 개선되며, 반건식 흡수탑으로 실시하는 경우와 같이 분진의 발생량이 많지 않게 되어 집진효율을 높이며, 특히 발생된 염의 발생설비를 새로이 갖추게 되어 염의 배출이 가능하게 된 효과도 있다.Thus, in order to treat incomplete combustion gas, acid gas, and some dust, which have gone through the conventional melting furnace, it is necessary to equip secondary combustion furnace, semi-dry absorption tower, fan scrubber, back filter, etc. It is effective, and the problem of waste water generation when treating acid gas component through wet scrubber is improved, and the amount of dust is not generated much like the case of semi-dry absorption tower. There is also an effect that the new generation facility can be discharged of salt.

Claims (3)

폐기물처리용 2차연소장치에 있어서,In the secondary combustion device for waste treatment, 수산화나트륨 투입구와, 공기주입구와, 냉각수입구 및 냉각수출구가 형성된 NaOH주입부;A NaOH inlet formed with a sodium hydroxide inlet, an air inlet, a cooling inlet and a cooling outlet; 상기 NaOH주입부의 투입구를 통해 주입되는 NaOH가 산성가스와 염화반응을 일으키는 반응로를 형성하고, 상기 반응로 내부로 폐기물처리 후의 배가스를 공급하기 위한 가스흡입구를 형성하고, 상기 가스흡입구로부터 공급된 배가스를 연소하는 가스버너를 구비하며, 상기 가스버너에 의해 연소되는 배가스를 완전 연소하기 위해 공기를 주입하는 2차공기주입구로 형성된 2차연소부; 및NaOH injected through the inlet of the NaOH injection unit forms a reaction reactor for causing a chloride reaction with acid gas, and forms a gas inlet for supplying the waste gas after the waste treatment into the reactor, exhaust gas supplied from the gas inlet A secondary burner having a gas burner for burning the gas and formed with a secondary air inlet for injecting air to completely burn the exhaust gas burned by the gas burner; And 상기 NaOH주입부로 주입된 NaOH가 산성가스와 염화반응을 일으켜 발생된 용융염을 집진하는 용융풀을 형성하고, 상기 용융풀에 집진된 용융염을 배출하기 위한 용융염배출구를 형성하며, 가스배출부로 형성된 용융염배출부를 포함하는 폐기물 처리장치의 2차연소 및 반응장치.The NaOH injected into the NaOH injection unit forms a molten pool for collecting the molten salt generated by causing a chloride reaction with the acidic gas, and forms a molten salt outlet for discharging the molten salt collected in the molten pool, the gas discharge unit Secondary combustion and reaction apparatus of the waste treatment apparatus comprising a molten salt discharge portion formed. 제 1항에 있어서, 상기 용융염을 Nacl인 것을 특징으로 하는 폐기물 처리장치의 2차연소 및 반응장치.The secondary combustion and reaction apparatus of claim 1, wherein the molten salt is Nacl. 제 1항 또는 제2항에 있어서, 상기 용융염배출부의 용융염배출구로부터 배출되는 상기 용융염은 융점강하제로 재사용되는 것을 특징으로 하는 폐기물 처리장치의 2차연소 및 반응장치.The secondary combustion and reaction apparatus of claim 1 or 2, wherein the molten salt discharged from the molten salt discharge port of the molten salt discharge portion is reused as a melting point lowering agent.
KR2019980027825U 1998-12-30 1998-12-30 Secondary combustion and reaction device of waste treatment device KR200258845Y1 (en)

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