KR20020074111A - Method for fixing nanometals to nonmetals and nonmetals thereof - Google Patents

Method for fixing nanometals to nonmetals and nonmetals thereof Download PDF

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KR20020074111A
KR20020074111A KR1020020049864A KR20020049864A KR20020074111A KR 20020074111 A KR20020074111 A KR 20020074111A KR 1020020049864 A KR1020020049864 A KR 1020020049864A KR 20020049864 A KR20020049864 A KR 20020049864A KR 20020074111 A KR20020074111 A KR 20020074111A
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nonmetal
fixing
nanometal
particles
metallic
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안정오
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안정오
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0043—Preparation of sols containing elemental metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/18—Processes for applying liquids or other fluent materials performed by dipping

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

PURPOSE: A method for adhering nanometal to nonmetal is provided to utilize metallic characteristics and maximize merits of the nonmetal by adhering nanometal particles to the nonmetal. CONSTITUTION: The method for adhering nanometal to nonmetal comprises the steps of colloidizing the metallic materials by connecting one metallic material to the anode and the other metallic material to the cathode using silver, copper and titanium metallic materials in distilled water or purified water as an equal metallic material so that a DC power source is alternately switched to the metallic materials; and dipping raw materials of fiber, plastics and synthetic resins into the colloidal solution and heating the raw materials to 30 to 70 deg.C using a heater to expand structure thereof so that particles of a colloid solution are penetrated into the raw materials and adhered thereto, wherein 24 to 60 V of the DC power source is supplied, and 10 to 50 ppm of the metallic material solution is produced, the raw materials are prepared by impregnating nylon, acryl, poly fiber, natural fiber, ABS, AS and PS for 3 to 20 minutes and then drying the impregnated materials, and the formed article completed into a product is dipped into the colloidal solution for 3 to 30 minutes and then dried so that the nanometal particles are adhered to the nonmetal.

Description

비금속에 나노금속을 고착시키는 방법 및 그 비금속물{.}Method of fixing nanometals to nonmetals and nonmetals thereof

본 발명은 비금속에 나노금속을 고착시키는 방법에 관한 것으로서, 더욱 상세하게는 비금속에 나노금속입자를 고착하여 금속의 특성을 살리며 비금속의 장점을 극대화시킨 비금속에 나노금속을 고착시키는 방법에 관한 것이다.The present invention relates to a method of fixing nanometals to nonmetals, and more particularly, to a method of fixing nanometals to nonmetals to preserve the properties of metals and maximize the advantages of nonmetals.

종래의 콜라, 사이다 등의 청량음료 용기나, 사과, 배, 토마토 등의 과일쥬스의 용기는 팩 또는 패트병에 담겨 판매되고 있다.Conventional soft drink containers such as cola and cider and fruit juice containers such as apples, pears and tomatoes are sold in packs or plastic bottles.

이러한, 종래 청량음료나 과일쥬스 등의 용기의 내부에 포장필름을 식품용기의 재질과 동일 또는 유사한 싸이클로서 재생이 가능하도록 폴리프로필렌(PP; POLY PROPYLENE)과 폴리에틸렌(HDPE; HIGH DENSITY POLY ETHYLENE)를 공중합하여 이루어진 필름을 사용한 용기를 사용하고 있다.Polypropylene (PP; POLY PROPYLENE) and polyethylene (HDPE; HIGH DENSITY POLY ETHYLENE) are used to regenerate the packaging film as the same or similar to the material of the food container in the interior of a container such as a conventional soft drink or fruit juice. The container using the film formed by copolymerization is used.

본 발명이 속하는 기술사항으로는 각종 프라스틱 수지중 필름용지나 사출성형용으로 사용되는 대표적인 열가소성수지를 공중합체하거나, 서로 물성이 상이한 여러겹의 필름을 융착하는 다층필름의 생산방법이라고도 할 수 있다.The technical matters to which the present invention pertains can be said to be a method of producing a multilayer film in which a representative thermoplastic resin used for film paper or injection molding among various plastic resins is fused or a plurality of films of different physical properties are fused together.

생활이 윤택해지고 생활의 질은 좋아지고 있으나 이에 따라 자연환경은 날로 오염되어 지고 있다.Life is getting better and the quality of life is getting better, but the natural environment is being polluted day by day.

은(銀)은 콜로이드실버로 인체에 무해하고 무중독, 무내성으로 일반약품과는 달리 부작용이 전혀 없으면서 강력한 자연위생, 살균소독 및 여드름, 부스럼, 뾰루지, 습진, 무좀 등의 피부트러블을 개선하여 피부를 보호하고 피부세포를 재생시키는 효과가 있는 것으로 알려져 있다.Silver is a colloidal silver that is harmless to the human body and is nontoxic and non-tolerant, and has no side effects unlike general medicines. It is known to protect skin and regenerate skin cells.

동(銅)의 특성의 살균력이 뛰어난 수질의 개선에 사용되고 있으며 그에 대한 연구가 진행중에 있다.The bactericidal power of copper is used to improve water quality, and research is underway.

따라서, 본 발명은 이러한 종래의 문제점을 감안하여 안출한 것으로Accordingly, the present invention has been made in view of such a conventional problem.

서, 본 발명의 목적은 비금속제에 금속나노 즉 콜로이드 입자를 고착시키는 방법을 제공하는 데 있다.It is an object of the present invention to provide a method for fixing metal nano-colloid particles to non-metals.

본 발명의 다른 목적은 섬유, 프라스틱, 합성수지 등에 나노입자크기의 금속을 침투시켜 잘 떨어지지 않는 비금속에 나노금속입자를 고착시키는 방법을 제공하는 데 있다.Another object of the present invention is to provide a method for fixing nano metal particles to non-metals that are hard to fall by penetrating metals of nano particle size to fibers, plastics, synthetic resins, and the like.

이러한 목적을 달성하기 위한 본 발명의 금속을 전기분해하여 비금속에 고착시키는 방법에 있어서,In the method for fixing the metal of the present invention to a non-metal to achieve this object,

증류수 또는 정제수의 물에 은(銀), 동(銅), 티타늄의 금속재를 동일한 금속재로 사용하여 한쪽 금속재에 (+)극을 연결하고 다른쪽 금속재에 (-)극을 연결하되직류전원을 교번교차시켜 금속재를 콜로이드화시키는 단계와; 상기 콜로이드화시킨 용액에 섬유, 플라스틱, 합성수지의 원료를 침적시키되 원료의 조직이 확장되도록 30~70℃로 가열하도록 히터장치를 구성하여 원료내에 콜로이드용액 입자가 침투되어 고착시키도록 이루어지도록 달성하였다.Connect the positive electrode to one metal material and the negative electrode to the other metal material by using silver, copper, and titanium metals in distilled or purified water as the same metal. Intersecting to colloid the metal material; Dipping the raw material of the fiber, plastic, synthetic resin in the colloidal solution, but the heater device is configured to be heated to 30 ~ 70 ℃ to expand the structure of the raw material to achieve the colloidal solution particles in the raw material to be made to penetrate.

이하, 본 발명 실시예의 비금속에 나노금속을 고착시키는 방법을 첨부도면에 의거하여 상세히 설명한다.Hereinafter, a method of fixing a nanometal to a nonmetal of an embodiment of the present invention will be described in detail with reference to the accompanying drawings.

본 발명의 금속을 전기분해하여 비금속에 고착시키는 방법에 있어서,In the method of electrolytically fixing the metal of the present invention to a nonmetal,

증류수 또는 정제수의 물에 은(銀), 동(銅), 티타늄의 금속재를 동일한 금속재로 사용하여 한쪽 금속재에 (+)극을 연결하고 다른쪽 금속재에 (-)극을 연결하되 직류전원을 교번교차시켜 금속재를 콜로이드화시키는 단계와; 상기 콜로이드화시킨 용액에 섬유, 플라스틱, 합성수지의 원료를 침적시키되 원료의 조직이 확장되도록 30~70℃로 가열하도록 히터장치를 구성하여 원료내에 콜로이드용액 입자가 침투되어 고착시키도록 이루어진 특징이 있다.Connect the positive electrode to one metal material and the negative electrode to the other metal material by using silver, copper, and titanium metals in distilled or purified water as the same metal material. Intersecting to colloid the metal material; The raw material of the fiber, plastic, synthetic resin is deposited on the colloidal solution, but the heater device is configured to be heated to 30 to 70 ° C. so as to expand the structure of the raw material.

상기 금속재 콜로이드화 시키는 단계는 상기 직류전원을 24~60V 로 공급하고, 상기 금속재 용액이 10~50ppm을 생성한다.In the colloidal forming of the metal material, the DC power is supplied at 24 to 60 V, and the metal solution generates 10 to 50 ppm.

상기 전극에 같은 금속봉을 장착하면 그 금속재의 콜로이드 용액이 형성되고, 일측극에는 은봉을 다른 일측극에는 동을 장착함으로서 두 금속의 콜로이드를 생성할 수 있도록 하였다.When the same metal rod was attached to the electrode, a colloidal solution of the metal material was formed, and a silver rod was attached to one electrode and copper was attached to the other electrode to generate colloids of two metals.

본 발명은 섬유에 사용되는 나이롱, 아크릴, 폴리섬유 등은 열을 가하면 다수의 천공구가 확장되어 0.005~0.015㎛의 나노 크기의 금속재 입자가 침투되도록 하였다.In the present invention, when the nylon, acrylic, polyfiber, and the like used in the fiber are heated, a plurality of drilling holes are expanded to infiltrate the nano-sized metal particles having a size of 0.005-0.015 μm.

다음, 상기 직류전원을 24~60V 로 공급하고, 상기 금속재 용액이 10~50ppm을 생성하였다.Next, the DC power was supplied at 24 to 60 V, and the metal solution produced 10 to 50 ppm.

상기 원료는 나이롱, 아크릴, 폴리섬유, 천연섬유, ABS, AS, PS를 3~20분간 함침시킨 후 건조한 특징이 있다.The raw material is characterized by drying after impregnating for 3 to 20 minutes, nylon, acrylic, poly fiber, natural fiber, ABS, AS, PS.

다음에, 상기 콜로이드용액에 제품을 완성한 성형품을 3~30분간 침적시킨 후 건조하여 비금속에 나노금속입자를 고착시켰다.Subsequently, the molded article which completed the product in the colloidal solution was immersed for 3 to 30 minutes and dried to fix the nanometal particles to the nonmetal.

예컨대, 본 발명의 비금속에 나노금속을 고착시키는 방법 및 그 비금속물은 그 형상 및 모양의 변형이 가능하며 특히. 본 발명은 상술한 실시예에 한정되지 아니하며, 청구범위에서 청구한 본 발명의 요지를 벗어남이 없이 본 발명이 속하는 기술분야에 통상의 지식을 가진 자라면 다양한 변형 실시가 가능한 것임은 물론이고, 그와 같은 변경은 본 발명의 청구범위 내에 있게 된다.For example, the method of fixing a nanometal to a nonmetal of the present invention and the nonmetallic material can be modified in shape and shape, in particular. The present invention is not limited to the above-described embodiments, and various modifications can be made by those skilled in the art without departing from the gist of the invention as claimed in the claims. Such changes are intended to fall within the scope of the present invention.

이상 설명한 바와 같이, 본 발명의 비금속에 나노금속을 고착시키는 방법 및 그 비금속물은 살균효과와 유해세균바이러스의 감염으로부터 보호 및 질환치료에 도움을 줄 수 있는 미세은입자를 비금속물에 침투시켜 금속재의 특성을 극대화시킨 뛰어난 효과가 있다.As described above, the method for fixing nanometals to the nonmetals of the present invention and the nonmetallic substances are characterized by infiltration of fine silver particles into the nonmetallic substance which can help to prevent bactericidal effects and protect against infection of harmful bacterial viruses and to treat diseases. Excellent effect that maximizes the characteristics.

Claims (5)

금속을 전기분해하여 비금속에 고착시키는 방법에 있어서,In the method of electrolytically fixing a metal to a nonmetal, 증류수 또는 정제수의 물에 은(銀), 동(銅), 티타늄의 금속재를 동일한 금속재로 사용하여 한쪽 금속재에 (+)극을 연결하고 다른쪽 금속재에 (-)극을 연결하되 직류전원을 교번교차시켜 금속재를 콜로이드화시키는 단계와;Connect the positive electrode to one metal material and the negative electrode to the other metal material by using silver, copper, and titanium metals in distilled or purified water as the same metal material. Intersecting to colloid the metal material; 상기 콜로이드화시킨 용액에 섬유, 플라스틱, 합성수지의 원료를 침적시키되 원료의 조직이 확장되도록 30~70℃로 가열하도록 히터장치를 구성하여 원료내에 콜로이드용액 입자가 침투되어 고착시키도록 이루어진 것을 특징으로 하는 비금속에 나노금속입자를 고착시키는 방법.Dipping the raw material of the fiber, plastic, synthetic resin in the colloidal solution, but the heater device is configured to be heated to 30 ~ 70 ℃ to expand the structure of the raw material, characterized in that the colloidal solution particles in the raw material is made to penetrate and adhere Method of fixing nanometal particles to nonmetals. 제 1항에 있어서, 상기 직류전원을 24~60V 로 공급하고, 상기 금속재 용액이 10~50ppm을 생성한 것을 특징으로 하는 비금속에 나노금속입자를 고착시키는 방법.The method of claim 1, wherein the DC power is supplied at 24 to 60 V, and the metal solution produces 10 to 50 ppm. 제 1항에 있어서, 상기 원료는 나이롱, 아크릴, 폴리섬유, 천연섬유, ABS, AS, PS를 3~20분간 함침시킨 후 건조한 것을 특징으로 하는 비금속에 나노금속입자를 고착시키는 방법.The method of claim 1, wherein the raw material is impregnated with nylon, acrylic, polyfibers, natural fibers, ABS, AS, PS for 3 to 20 minutes, and the method for fixing the nanometal particles to the nonmetal, characterized in that dry. 제 1항에 있어서, 상기 콜로이드용액에 제품을 완성한 성형품을 3~30분간 침적시킨 후 건조한 것을 특징으로 하는 비금속에 나노금속입자를 고착시키는 방법.2. The method of claim 1, wherein the molded article, which is a finished product, is deposited in the colloidal solution for 3 to 30 minutes and then dried. 제 1항 내지 제 4항에 의해 제조된 비금속에 나노입자를 고착시켜 제조된 비금속물.A nonmetallic material prepared by fixing nanoparticles to a nonmetal prepared according to claim 1.
KR1020020049864A 2002-08-22 2002-08-22 Method for fixing nanometals to nonmetals and nonmetals thereof KR20020074111A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050019555A (en) * 2003-08-19 2005-03-03 주식회사 비에스텍 Simultaneous silver colloid creation and silver plating method
KR100801229B1 (en) * 2006-07-25 2008-02-05 박세환 A method for manufacturing antibiotic plastics with improved silver nano-particles deposition
KR20190095655A (en) 2018-02-07 2019-08-16 손자경 Methods of deposition silver nanoparticles having a good antibacterial by using object
KR20190130553A (en) 2019-11-18 2019-11-22 손자경 Silver nanoparticles deposition method having excellent antibacterial activity and objects on which silver nanoparticles are deposited

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KR20000049701A (en) * 2000-04-24 2000-08-05 안정오 Metal Particles Bonded to Plastic Resin
KR200195342Y1 (en) * 2000-02-08 2000-09-01 안정오 Plastic package
KR20010046162A (en) * 1999-11-10 2001-06-05 안정오 Production of metal fiber with gold or silver

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Publication number Priority date Publication date Assignee Title
KR20010046162A (en) * 1999-11-10 2001-06-05 안정오 Production of metal fiber with gold or silver
KR200195342Y1 (en) * 2000-02-08 2000-09-01 안정오 Plastic package
KR20000049701A (en) * 2000-04-24 2000-08-05 안정오 Metal Particles Bonded to Plastic Resin

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050019555A (en) * 2003-08-19 2005-03-03 주식회사 비에스텍 Simultaneous silver colloid creation and silver plating method
KR100801229B1 (en) * 2006-07-25 2008-02-05 박세환 A method for manufacturing antibiotic plastics with improved silver nano-particles deposition
KR20190095655A (en) 2018-02-07 2019-08-16 손자경 Methods of deposition silver nanoparticles having a good antibacterial by using object
KR20190130553A (en) 2019-11-18 2019-11-22 손자경 Silver nanoparticles deposition method having excellent antibacterial activity and objects on which silver nanoparticles are deposited

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