KR20020062542A - Making method of maekban hwangto ceramic brick for interior decoration - Google Patents

Making method of maekban hwangto ceramic brick for interior decoration Download PDF

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KR20020062542A
KR20020062542A KR1020010004705A KR20010004705A KR20020062542A KR 20020062542 A KR20020062542 A KR 20020062542A KR 1020010004705 A KR1020010004705 A KR 1020010004705A KR 20010004705 A KR20010004705 A KR 20010004705A KR 20020062542 A KR20020062542 A KR 20020062542A
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bricks
brick
clay
semi
standard
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KR1020010004705A
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Korean (ko)
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김철중
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김철중
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5035Silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00577Coating or impregnation materials applied by spraying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

PURPOSE: Provided is a manufacturing method of interior ceramic bricks by spraying quartz porphyry over formed bricks made of yellow earth, and sintering at a lower temperature than sintering temperature of clay bricks. The resultant porous bricks have the effects of far infrared emission, sterilization and deodorization. CONSTITUTION: The manufacturing method comprises the steps of: mixing more than 60wt.% of yellow earth and less than 40wt.% of fine sand or polishing sand; kneading, forming, and drying; spraying the surface of formed bricks with a slip containing 20wt.% or more of quartz porphyry to be a thickness of 0.5-1mm; and sintering at 700-1000deg.C over 6hrs.

Description

내장용 맥반황토세라믹벽돌의 제조방법{MAKING METHOD OF MAEKBAN HWANGTO CERAMIC BRICK FOR INTERIOR DECORATION}MAKING METHOD OF MAEKBAN HWANGTO CERAMIC BRICK FOR INTERIOR DECORATION

본 발명은 황토와 맥반석을 상호결합시킨 내장용 맥반황토세라믹벽돌제조에 관한 것으로 현재 내장벽돌로 사용되는 시멘트벽돌, 소성하지 않은 황토벽돌 제조에 관하여는 잘 알려져 있으나 황토벽돌에 맥반석이 함유된 슬립을 표면에 도포하여 턴넬소성로에서 약700~1000℃의 온도로 소결하여 제품의 다공성을 촉진시키고 원적외선 방사를 증진케하는 맥반황토세라믹벽돌제조방법은 알려져 있지 않다.The present invention relates to the manufacture of internal clay machwang ocher ceramic bricks interlocking ocher and elvan, but is well known for the manufacture of cement bricks, unfired ocher bricks used as interior bricks, There is no known method for producing machwang clay ceramic brick which is applied to the surface and sintered at the temperature of about 700 ~ 1000 ℃ in the Tunnel firing furnace to promote the porosity of the product and to promote the far infrared radiation.

일반적으로 벽돌제조에 사용되는 황토는 규소(SiO2), 아루미나(Al2O3), 산화철(Fe2O3), 마그네슘(MgO), 칼륨(K2O) 등이 함유되어 있고 원적외선이 방사되되는 물질로 알려져 있으며 인체의 건강과 황토에 관하여는 연구가 진행되고 있는 상황이다. 이러한 황토의 특성을 활용한 나머지 소성하지 않은 황토벽돌이 사용되었으나 강도가 낮고 습기에 약하여 사용자체가 어려울 뿐아니라 사용후 단기간내에 균열이 가는 등 단점이 노출되어 있다.In general, ocher used for brick production contains silicon (SiO 2 ), alumina (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), magnesium (MgO), potassium (K 2 O), and far-infrared rays. It is known as a substance to be released, and research on human health and ocher is being conducted. The unfired ocher bricks are used by utilizing the characteristics of the ocher, but the strength is low and the moisture is weak, so that the user is difficult and the shortcomings are exposed.

본 발명은 황토를 주재료로 하여 그 표면에 맥반석을 스프레이 도포하여 결합시킨 벽돌이므로 황토의 특성과 맥반석의 특성인 규소(SiO2), 아루미나(Al2O3), 산화철(Fe2O3), 마그네슘(MgO), 칼슘(CaO)등의 무기물(미네랄)과의 상호결합으로 원적외선 방사를 증진시키고 특히 소성과정에서는 일반외장점토벽돌과 비교할 때 턴넬소성로에서 약1100~1250℃ 소성온도로 소결시킨데 비하여 본제품은 내장용으로서 약 700~1000℃의 소성온도에서 소결하므로 다공성이 확대유지 되면서 이온교환작용으로 인한 항균, 탈취, 탈습의 효과가 상승하고 실내를 쾌적하게 유지하는 효과도 지니게 되어 종래의 내장용벽돌인 시멘트벽돌, 소성하지않은 황토벽돌과는 전혀 다른 특성과 공정 그리고 소결온도를 지닌 새로운 내장용 맥반황토세라믹벽돌 제조방법이다.In the present invention, the main material of the loess is a brick combined with a spray of banban rock on its surface, so the characteristics of loess and banban are silicon (SiO 2 ), alumina (Al 2 O 3 ), and iron oxide (Fe 2 O 3 ). Far-infrared radiation is enhanced by mutual coupling with minerals (minerals) such as magnesium, magnesium (MgO) and calcium (CaO), and in the firing process, it is sintered at about 1100 ~ 1250 ℃ firing temperature in the Tunnel firing furnace as compared with general external clay bricks. In contrast, this product is for interior use and is sintered at a firing temperature of about 700 ~ 1000 ℃. As the porosity is maintained, the effect of antibacterial, deodorization, and dehumidification due to ion exchange effect increases, and it also has the effect of keeping the room comfortable. It is a new method of manufacturing Machwang clay ceramic brick with different characteristics, process, and sintering temperature than cement brick, which is a brick for interior use.

종래의 내장벽돌은 시멘트벽돌과 소성하지 않은 황토벽돌이 사용되어 왔으나 시멘트벽돌은 원적외선이 방사되지 않은 것으로 되어있고 항균, 탈취, 이온교환작용이 거의 없다. 또 소성하지 않는 황토벽돌은 소성한 황토벽돌에 비하여 강도 및 습기에 약하고 마모성이 높아 내장용으로는 적정하지 못하다.In the conventional built-in bricks, cement bricks and unfired ocher bricks have been used, but cement bricks have no far-infrared radiation, and have little antibacterial, deodorizing, or ion exchange effects. In addition, loess bricks which are not fired are weaker in strength and moisture and have higher abrasion properties than fired ocher bricks and are not suitable for interior use.

이런한 단점을 보완하면서 황토가 주재료인 성형반제품에 미네랄이 풍부한 신비의 맥반석을 20wt%이상 함유된 슬립을 표면에 스프레이 도포처리하여 이를 700~1000℃의 온도에서 소성시키므로 다공성의 유지와 양이온 교환에 의한 항균, 탈취, 탈습작용을 향상시키고 소성하지 않은 황토벽돌보다 견고하며 인체에 유익한 원적외선 방사효과를 높이는 내장용 맥반황토세라믹벽돌을 제조하는 것임.Compensating for these disadvantages, spray-coating the surface containing slips containing more than 20wt% of mineral-rich myelite stones in molded semi-finished products, the main material of ocher, is fired at the temperature of 700 ~ 1000 ℃. To improve the antibacterial, deodorizing, dehumidifying effect by the sintered bricks, and to make a stronger and better far-infrared radiation effect for the human body than the unfired ocher brick.

본 발명에서는 상기의 과제를 해결하기 위하여 황토를 60wt%이상으로 하고 세사 또는 마사토류를 40wt%이하로 하여 서로 혼합한 다음 점토벽돌제조공정에 준한 방법으로 분쇄하여 분말도가 3mm이하로 한다. 분쇄가 된 혼합물은 혼련을 충분히 한 다음 수분함량이 10~20wt%되게 조절하고 토련한후 원하는 규격에 따라 절단하므로서 성형이 완료된다. 성형이 완료된 반제품은 수분을 제거한 후 소성을 하기 위해 대차에 요적하기전의 공정중 맥반석이 20wt% 함유된 슬립을 반제품 표면에 약 0.5~1mm의 두께로 스프레이 도포한다.In the present invention, in order to solve the above problems to make the loess more than 60wt% and fine sand or masatos 40wt% or less and mixed with each other and then pulverized by the method according to the clay brick manufacturing process to make the powder degree 3mm or less. The pulverized mixture is sufficiently kneaded, then adjusted to have a water content of 10-20 wt%, refined, and cut according to a desired specification to complete molding. The finished semifinished product is spray-coated with a thickness of about 0.5 ~ 1mm on the surface of the semifinished product, in which the slip containing 20wt% of elvan is in the process before removing the moisture and before firing to the bogie for firing.

이때 슬립의 접착효과를 높이기 위해 성형반제품 건조전 표면에 요철의 무늬를 각인하거나 철브러쉬등으로 작은 요철을 내거나 표면을 칼날로 깎는 방법으로 표면을 거칠게 해주는 방법이 있다. 슬립이 도포된 반제품은 소성대차에 일반점토벽돌반제품 조적하는 방법대로 조적하여 소성로에서 예열과 본소성 및 냉각과정을 거쳐 소성하는데 본소성대 소성온도 700~1000℃에서 약6시간이상 소성한후면 원하는 제품을 얻을 수 있다.At this time, in order to enhance the adhesive effect of the slip, there is a method of roughening the surface by imprinting the pattern of the irregularities on the surface before forming the molded semi-finished product, by making small irregularities with an iron brush or by cutting the surface with a blade. The semi-finished product coated with slip is fired by preheating, firing and cooling in the firing furnace by bundling general clay brick semi-finished product in firing truck. After firing at the firing temperature of 700 ~ 1000 ℃ for about 6 hours, the desired product Can be obtained.

맥반석이 20wt%이상 함유된 슬립의 제조는 맥반석 20wt%이상의 고상분말과 황토, 장석, 석회석 등 용제를 적의 혼합한 뒤 1톤볼밀에 약 1,200kg투입후 물을 재료 투입량의 약 60wt%를 투입하여 약 24∼30시간 분쇄하여 스프레이 도포에 적당한 점도의 혼수량을 조절한 뒤 사용하면 된다. 스크레이 도포된 슬립은 소성과정에서 소결되어 표면에 고착된다.In the manufacture of slip containing more than 20wt% of elvanite, a solid mixture of more than 20wt% of elvanite and a solvent such as loess, feldspar, and limestone are mixed in an appropriate amount, and then 1,200kg is added to a 1-ton ball mill, and water is added to about 60 wt% It may be used after grinding for about 24 to 30 hours to adjust the amount of coma at a suitable viscosity for spray application. The scraped slip is sintered during the firing process and adheres to the surface.

내장용 맥반황토세라믹벽돌 외형규격은 조적이 용이하게 현재 사용하고 있는점토벽돌규격과 동일하게 제작하여 사용상의 불편이 없게하고 사용용도에 따라 이형으로 제작할 수 있으며 권장 압력강도는 최저 800N/Cm2이상이어야 한다.The interior specification of the Machwang clay ceramic brick is made in the same way as the clay brick standard currently used, so that it can be produced without any inconvenience in using it, and it can be produced as a mold according to the intended use. The recommended pressure strength is at least 800N / Cm 2 Should be

본 내장용 맥반황토세라믹벽돌은 내장재로서 견고하며 인체에 유익한 이온교환작용으로 쾌적한 실내정화작용과 인체에 해로운 항균작용은 물론 냄새, 습기제거를 향상시키고 또 원적외선 방사로 인한 혈액순환과 신진대사를 촉진시키는 기능과 황토소성제품이 지니는 축열성에 의한 온열작용으로 주거용의 주택실내에 시공시 시멘트벽돌이나 소성하지 않는 황토벽돌보다 인체에 유익을 준다.This interior Machran clay ceramic brick is a solid interior material with ion exchange effect that is beneficial to the human body, which improves pleasant indoor purification and harmful antibacterial effect to the human body, improves odor and moisture removal, and promotes blood circulation and metabolism due to far-infrared radiation. It is beneficial to the human body than cement brick or clay brick that does not fire when built in residential house due to the thermal action by the heat storage property of ocher plastic products.

또 본 맥반황토세라믹벽돌은 내장용으로서 누구나 손쉽게 조적이 용이하며 특히 도시속에 위치한 아파트의 내벽, 거실등에 시공시 실내공기를 정화하는 효과를 지니며 기타 사무실, 건강찜질방, 병실의 내벽등 사람이 거처하는 곳마다 사용이 가능하다. 이와같이 맥반황토벽돌이 지니는 특성은 환경친화적, 친인간적 자재로 우수한 물성을 지닌 세라믹내장재로서 널리 사용이 가능하다.In addition, this Machwang yellow ceramic brick is for interior use, so anyone can easily assemble it. Especially, it has the effect of purifying indoor air when constructing the interior wall and living room of apartments located in the city. You can use it wherever you want. As such, the characteristics of Machwang ocher bricks are environmentally friendly and human-friendly materials and can be widely used as ceramic interior materials with excellent physical properties.

Claims (2)

황토 60wt%이상과 세사 또는 마사토류 40wt%이하를 상호혼합한 후 그 혼합물을 일반점토벽돌 제조공정에 준하여 분쇄, 혼련 및 토련을 거쳐 정제한 후 성형반제품상태에서 건조후 맥반석이 20wt%이상 함유된 슬립을 조제하여 반제품표면에 0.5∼1m/m로 스프레이 도포한 다음 소성대차에 조적하여 턴넬소성로에 요입하고 예열을 거쳐 700∼1000℃의 소성대 온도에서 약 6시간이상 본소성을 거친 뒤 냉각하여 얻은 벽돌제품이며 규격이 일반점토벽돌규격과 같은 내장용 맥반황토세라믹벽돌 제조방법임.After mixing more than 60wt% of loess and less than 40wt% of sesa or masatos, the mixture is refined through grinding, kneading and refining according to the general clay brick manufacturing process, and after drying in the form of semi-finished product, it contains more than 20wt% of elvan. Slip is prepared and sprayed on the surface of semi-finished product at 0.5 ~ 1m / m, then it is loaded on baking trolley and injected into the tunnel furnace, and after preheating, it is cooled for about 6 hours at the baking table temperature of 700 ~ 1000 ℃. It is a brick product obtained, and the standard is the manufacturing method for interior porcelain clay clay brick like the standard clay brick standard. 제 1항에 있어서 맥반석이 20wt%이상 함유된 슬립을 스프레이 도포하는 작업순서는 혼합물이 믹서되어 토련기에서 사출되는 과정에서 할 수도 있고 사출과정을 지나 성형하여 건조한 후 소성하기 위하여 소성대차에 요적하기 전 콘베아 작업을 통하여 반제품이 이동되는 과정에서 시행할 수도 있슴.According to claim 1, the work order of spray application of slip containing more than 20wt% of elvan rock may be performed in the process of mixing the mixture and injecting in the refining machine, and is suitable for the firing balance to be molded and dried after the injection process. This may be done during the transfer of semi-finished products throughout the entire conveyor work.
KR1020010004705A 2001-01-22 2001-01-22 Making method of maekban hwangto ceramic brick for interior decoration KR20020062542A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
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KR100769938B1 (en) * 2006-08-18 2007-10-24 주식회사 명신연와 Method for manufacturing clay brick using inorganic white-masato
CN107244939A (en) * 2017-04-20 2017-10-13 林俊生 A kind of porous closure material and preparation method thereof
KR20240006787A (en) * 2022-07-07 2024-01-16 강춘홍 Eco-friendly solidifying agent composition

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100769938B1 (en) * 2006-08-18 2007-10-24 주식회사 명신연와 Method for manufacturing clay brick using inorganic white-masato
CN107244939A (en) * 2017-04-20 2017-10-13 林俊生 A kind of porous closure material and preparation method thereof
KR20240006787A (en) * 2022-07-07 2024-01-16 강춘홍 Eco-friendly solidifying agent composition

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