KR20020018928A - A purgation methods for the swimming pool water - Google Patents

Abstract

PURPOSE: Provided is a purification method for the swimming pool water, which is characterized in that a bio-reactor installed in a purification system is packed with silicate and soil containing poly-phenolic metabolism materials of microorganisms. CONSTITUTION: Swimming pool water is flowed into the bioreactor. Organics of swimming pool water is removed by coagulation, polymerization, condensation, and polycondensation in the bioreactor. And pathogenic organism and bacilli are sterilized by antibiotic of metabolism materials of the soil. Therefore, usage of coagulants is minimized, and chlorine disinfection is not necessary.

Description

A PURGATION METHODS FOR THE SWIMMING POOL WATER

The present invention relates to a method for purifying pool water, and more particularly, to a culture tank equipped with a reactor soil filled with a calm soil and an active silicate enriched with metabolites of microorganisms having an aromatic polyphenol aromatic nature. Here, the pool water is introduced and stirred, so that the organic matter contained in the pool water is agglomerated, polymerized, condensed, and polycondensed to minimize the use of flocculants (ALUM) and neutralizers (NaOH), and in the microbial metabolite with polyphenol aromatic nature. E. coli, pathogens, etc. are sterilized by various antibiotics, and useful bacteria adapt metabolic functions to calm soil to change metabolites with polyphenol aromatic essences. It relates to a purification method.

In general, swimming pools are bathed by a large number of swimmers, and various organic substances are dissolved in the swimming pool, and various harmful microorganisms are inhabited.

In other words, the conventional method of purifying water in swimming pools is to install sand filters and activated carbon adsorption towers, and to remove various contaminants in the water by administering flocculants in the process of transporting the pool water through pumps. Since the amount of is excessively used, the pH of the pool water is lowered, so it is neutralized by administering NaOH, and sterilization using chlorine disinfectant or ozone sterilization is used to sterilize E. coli, pathogens, etc. in the pool water.

As a result, odor of chemicals or disgusting ozone odors are generated in the swimming pool, and the use of excessive chemicals in particular affects the respiratory and skin of swimmers.

In summary, since the water is purified by passing the pool water through a sand and activated carbon filter to purify the water, a large amount of flocculant having a low pH is used to aggregate and remove various organic substances.

Since the amount of these flocculants is high, the pH is lowered, and a neutralizing agent such as caustic soda is used to neutralize it.

In addition, by using a large amount of chlorine disinfectant to sterilize harmful bacteria, swimmers by chlorine disinfectant can not swim without eyes without swimming glasses, skin damage of swimmers, hair discoloration and chemicals in water It smelled and had an unpleasant disadvantage.

The present invention has been researched and developed in order to effectively solve the disadvantages of the problem in the conventional method for treating pool water,

An object of the present invention is to purify pool water by minimizing the amount of flocculant used by agglomeration, condensation, and condensation of organic matter contained in the pool water by contacting the calm soil enriched with microbial metabolites having aromatic polyphenols with water. In providing.

An object of the present invention is to purify swimming pool water by sterilizing harmful bacteria such as Escherichia coli, pathogens, etc. inhabiting pool water without chlorine disinfection by contacting the calm soil enriched with microbial metabolites having polyphenol aromatic nature with water. In providing.

1 is a treatment flow diagram of the pool water of the present invention,

In general, the degeneration of organic matter in nature is directed in two directions.

That is, metamorphosis in two completely different directions, such as low molecular weight and high molecular weight, is occurring universally. Of the degenerations of these organic materials, which one is more common, it can be said to be the direction of high (macro) molecularization.

Degeneration to low molecular weight can be widely seen in the decay of organic matter in the form of enzymatic degradation, but in quantitative terms it is a very few.

On the other hand, the transformation into high molecular mass is a major transformation circuit occurring in the natural world, for example, soils as polycondensates in which organic and inorganic substances are structurally connected, or polycondensates of coal series such as coal, peat, peat, peat, and swamp. Inna lake's quality and countless.

The high (macro) molecularization of organics in nature is a reaction caused by the physicochemical reaction of organics with metabolites, including compounds with phenols and / or phenol-exposed compounds produced by aerobic bacteria and anaerobic bacteria in common soil bacterial groups. to be.

In addition, when a substance containing a lot of activated silicic acid is administered to the reaction system, a corrosive reaction occurs and macromolecularization and oniization progress.

<Basic Reaction 1>

Organic matters (organic aqueous solutions and water-soluble organic mixtures) are rapidly bonded, granulated, aggregated, condensed, and polymerized by adding microbial metabolites including phenols and / or compounds with phenolic exposure groups to form macromolecules and bulk products. Make up.

<Basic Reaction 2>

When an appropriate amount of a substance containing a lot of activated silicic acid content is added to the reaction, a polycondensation reaction for corrosion occurs.

The above-mentioned compound having a phenolic exposure group refers to a general organic substance having a phenolic exposure group, but an enzyme having a phenolic exposure group is particularly effective.

In addition, a substance containing a lot of activated silicic acid refers to an unstable substance having high activity such as volcanic glass having a composition of andesite and rhyolite.

When the substance containing a lot of activated silicic acid in the reaction system of the basic reaction 1 is embedded or added, or when the raw water contains the same substance, for example, the synthesis of clay minerals in paper wastewater and pig wastewater All reactions in mineral extenders in the feed occur in the state of base reaction 2.

The difference between the basic reaction 1 and the basic reaction 2 is that the silicic acid powder is activated when the purpose of removing the inorganic ionic substance is that the reaction product is more prominent in the material produced in the basic reaction 2. It is beneficial to squeeze a substance containing a large amount into the reaction system. And it does not mean that the keylet structure does not develop in the reaction product of the basic reaction 1, but it is merely that the development of the keylet structure is accompanied by more technical difficulties.

On the other hand, since wastewater treatment plants, waste treatment plants, and swimming pools are artificial environments, there are no silicic acid salts or corrosive substances present in the great outdoors, and even if they are trace amounts, they cannot be soil environments. This can't happen.

However, if we assume that the environment in which the waste water treatment plants, waste treatment plants, corrosive substances or silicates in the pool there exists the organic substances contained in waste water, water is decomposed by microorganisms in the environment in which corrosive substances present in the soil CO ₂ , N ₂ , H ₂ O and the like, and various microbial metabolites, decomposition products of organic matter, chelate products, recombination products, and caking substances produced in the process are aggregated, condensed, agglomerated, polymerized, and polycondensed. As it grows, organic substances contained in wastewater are removed from the liquid phase and at the same time, they are combined in the form of various ionic substances, arrival compounds, internal compounds, and other organic-inorganic compounds contained in the waste water, and are removed from the liquid phase.

Odor molecules that exist in water in an ionic state are chelated products, which trap (+) ions (eg NH4, etc.) of the odor molecules as constituent molecules of the chelate and change them into compounds different from their original properties. In addition, various antibiotics produced during the corrosive process sterilize pathogenic microorganisms, and microbial groups that are not affected by the antibiotics are promoted by biologically active substances.

However, in anthropogenic environments such as wastewater treatment plants, waste treatment plants, and swimming pools where corrosives do not exist, organic substances are enzymatically degraded in the form of enzymatic decomposition.

As mentioned above, such a phenomenon is not a phenomenon commonly occurring in Mother Nature, but is sometimes a local phenomenon such as an early decay of a dead body of an animal, and mainly occurs in an artificial environment. The above reactions do not produce corrosive substances and microbial metabolites (chelate products, growth promoters, antimicrobial substances, etc.) having various aromatic qualities generated during the formation of corrosive substances do not produce odors and pathogenic bacteria. This is to be simmered.

Corrosion reactions of organic substances occurring in the great outdoors are very slow, taking 10 to 20 years in large areas. Even if there are corrosive substances or silicates in the wastewater treatment plant and waste treatment plant, the corrosive reaction is not completed. In order to take a very large area and a lot of time, economic efficiency is low.

To solve this problem, microbial metabolites with excellent activity and polyphenol aromatic qualities are found among the corrosive substances in Mother Nature and processed again to produce strong polycondensation reactions. By repeatedly injecting active silicates, which are more active than they exist, at the point where organic matter is introduced, the corrosion reaction can be promoted more than what is happening in Mother Nature.

In other words, when microorganism metabolites with aromatic polyphenols are concentrated in a high concentration of environmental substances into the 'intestine of pollution', the microbial population that adapts to the 'intestine of pollution' is responsible for metabolic functions. Metabolites, ie compounds with polyphenol aromatic essences, are secreted, and pathogens that do not adapt are killed. On the contrary, if contaminants with high concentrations continue to be injected into the 'cleaner', the microbial population living in the 'cleaner' will adapt to the 'cleaner'.

Therefore, in order to maintain the sewage treatment plant at all times, it is necessary to repeatedly input highly concentrated material of microbial metabolite having poly phenol aromatic nature at the point of sewage input.

When the concentration of the substance having the polyphenol aromatic essence is weak compared to the input organic matter or when the input is stopped, the 'field of purification' is induced to the 'field of pollution'.

That is, when microbial metabolites having an aromatic nature of polyphenols are added to organic substances, they are aggregated and condensed to form macromolecules and agglomerates, where they are added by stirring and corroding rhyolite active silicates such as volcanic glass, which is similar to the average plasticity of surface elements. Reaction (soilation reaction) takes place and polycondensation occurs. (1985.UCHIMIZU)

In addition, in the artificial environment with or without free oxygen, phenolic metabolic function is expressed in soil anaerobic bacteria or bacterial groups composed of soil aerobic bacteria and anaerobic bacteria. Induction culture of microbial metabolic function is only possible in the presence of (metabolites including compounds with phenol or / and phenol exposure groups).

To this end, as mentioned above, a metabolite including the phenol or / and a phenol-exposed compound or a substance containing the metabolite (such as a corrosive) is added, or a phenol-based metabolic function existing in nature This particular bacteriological group, which has been strengthened, and which has an official relationship with the soil-organic anaerobic bacterial group, should be used as a spawn under certain conditions.

That is, if only good spawns are available, it is feasible to induce the metabolism of the soil microbial group in the wastewater by phenol-based culture, but it is difficult to cultivate spawns.

However, as mentioned above, soil bacterial populations inhabiting soil generally express phenolic metabolic functions.

The most widely distributed substance containing phenolic metabolites is the soil itself. Soil is the end product of the reaction (corrosion reaction) caused by the action of phenolic metabolites on organic matter and silicates. The process material of the corrosion reaction is collectively referred to as corrosion precursors, corrosion precursors and mixtures of corrosion. Called corrosive, it is possible to say that good quality soil is the corrosive itself.

However, silicates are generally physicochemically stable substances, and the ratios of phenol-based metabolites, organic substances, and silicates are not overwhelmingly proportional to the progress of the corrosion reaction. As a result, the soil should generally be regarded as a mixture of plants and silicates.

Corrosion precursors are generic terms of process substances in which various organic substances are changed to corrosion by the action of phenolic metabolites and silicates as described above. In other words, corrosion precursors are substances derived from phenolic metabolites and silicates. It will contain.

Therefore, the corrosive precursor, and moreover the corrosive, is said to contain a phenolic metabolite as described herein, but only the corrosive precursor functions as an inducer and culture material for the soil flora.

In the corrosive reaction, silicate is involved, and the average composition of the earth's crust in which the soil flora originated is granite or nitrite silicate, and it is alkalite, which is unstable or activated under surface physicochemical conditions. In the presence of volcanic glass, it is assumed that the high-quality corrosive layer with high content of corrosive precursors is relatively widely distributed in the special terrain of the andesite volcanic zone.

In addition, since the corrosives may be produced by synthesis, it may be more rational to use the corrosives rather than the use of spawn when culturing the metabolic function of the soil bacteria group to the phenolic system.

The present invention implements the method of purifying pool water by applying the theory revealed by the studies of many scholars described above.

Hereinafter, the method of purifying pool water of the present invention will be described in detail.

1 is a process flow diagram of the present invention, in which a part of the water contaminated by a swimmer in a swimming pool is returned to a culture tank by a primary pump (Pump A), so that the calm soil and active silicate filled in a reactor tower of the culture tank are A soiling reaction occurs in contact with the organics contained in the returned water.

As a result, the organic material in the return water becomes a corrosive process material for corrosiveness, and secretes a compound having polyphenol aromatic essences such as the metabolic function inhabiting calm soil in the calm soil. It is excellent in the function of agglomeration and condensation of organic matter, and has antibacterial activity against harmful microorganisms such as E. coli and pathogens in water.

In this process, when microbial metabolism is induced in the culture tank and the cultured water is put back into the swimming pool, a corrosion reaction occurring in the culture tank is caused in the swimming pool, thereby inducing the entire swimming pool into a calm soil environment.

As such, the organic matters in the water in the pool are condensed and condensed by the soiling reaction, so that they are sent to the filter by the secondary pump (Pump B) of the pool to easily remove the organic matter and the water is purified with clean water.

During this process, antibiotics contained in soothing soils and various antibiotics contained in secretions of microorganisms living in soothing soil environments sterilize E. coli and pathogens.

In addition, the chelate compound contained in the calm soil is transported in a state in which various ionic substances contained in the water are collected and removed while passing through the filter.

As a result, even if the water is not sterilized with chlorine, E. coli and pathogens do not exist, and low pH coagulants are not used, or even very small amounts are easily removed from the filter so that the pH of the water is not lowered. You do not need to use.

As described in detail above, the present invention is provided with sterilization of E. coli and pathogens without chlorine disinfection in the pool, minimizing the amount of flocculant used (less than 30% of the previous usage), and does not require the use of caustic soda. In addition, the smell of chemicals in the swimming pool is eliminated, and the chemicals contained in the water in large quantities have the effect of preventing the skin from deteriorating.

Claims (2)

A portion of the contaminated water in the swimming pool is introduced into the culture tank by a primary pump (Pump A), followed by stirring, so that the calm soil and active silica filled in the reactor tower included in the culture tank contain organic substances in the pool water. In contact with soil to induce soil reaction to agglomerate, polymerize, condense and polycondensate organic matter in the water, reduce it back to the pool to induce the corrosion reaction in the pool, and then filter by the secondary pump (Pump B) of the pool. A method for purifying pool water, characterized in that the organic matter is sent to remove the organic matter to minimize the use of flocculant. The method of claim 1, wherein the microbial metabolite having the polyphenol aromatic essence is in contact with the water of the swimming pool so that harmful bacteria such as Escherichia coli, pathogens, etc. in the water are sterilized without chlorine disinfection. Purification method of pool water to be done.