KR20010099048A - Bio Ceramic 2 omitted - Google Patents

Bio Ceramic 2 omitted Download PDF

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Publication number
KR20010099048A
KR20010099048A KR1020010049720A KR20010049720A KR20010099048A KR 20010099048 A KR20010099048 A KR 20010099048A KR 1020010049720 A KR1020010049720 A KR 1020010049720A KR 20010049720 A KR20010049720 A KR 20010049720A KR 20010099048 A KR20010099048 A KR 20010099048A
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South Korea
Prior art keywords
water
present
coating
fungi
coating film
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KR1020010049720A
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Korean (ko)
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KR100484565B1 (en
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김정섭
윤정현
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김정섭
오션씨엔씨 주식회사
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 공동주택의 식수저장탱크, 수영장, 상수도관,정수기,냉온수기 등에 있어서의 수질의 보존과 위생안전대책의 일환으로 본 발명품으로 도장 처리함으로서 기대되는 효과 즉 본 고안품의 도막에서 방사되는 원적외선과 인체에 무해한 항균 성분에 의한 수중의 대장균, 포도상구균과 같은 균류의 번식을 억제함과 동시에 살균 능력을 발휘함으로써 국민 위생 안전에 기여함을 특징으로 한다.The present invention has the effect expected by the coating treatment of the present invention as part of the preservation of water quality and sanitary safety measures in drinking water storage tanks, swimming pools, water pipes, water purifiers, cold and hot water heaters of multi-unit houses, namely far-infrared rays emitted from the coating film of the present invention. It is characterized by contributing to national hygiene safety by suppressing propagation of fungi such as Escherichia coli and Staphylococcus aureus by antibacterial ingredients that are harmless to the human body and at the same time exhibiting sterilizing ability.

Description

항균성 Bio Ceramic 을 주성분으로 하는 2액형 무독성, 무용제형 세라믹 방식 코팅{omitted}Two-component non-toxic, solvent-free ceramic coating based on antimicrobial bio ceramics

본 발명의 목적은 기존의 식수 관련 부속물의 일반도장방식처리의 결점을 보완함과 아울러 원적외선 및 항균기능을 부가함으로서 위생 안전성 확보에 그 목적을 둔다.The object of the present invention is to supplement the shortcomings of the conventional coating method of the conventional drinking water-related accessories, and to provide hygiene safety by adding far infrared rays and antibacterial function.

본 발명은 각종 식수 관련 기술 저장 시설의 장기적이고 안정적 사용을 보장하기 위해 제공되는 항균성 Bio Ceramic 방식 코팅제에 관한 것이다.The present invention relates to an antimicrobial Bio Ceramic anticorrosive coating provided to ensure long-term and stable use of various drinking water related technology storage facilities.

특히 본 발명은 1∼2회의 단순한 코팅 공정을 행함으로써 수중의 유해성 균류의 증식억제, 살균작용과 코팅제의 수지성분이 발휘하는 장기간의 보호기능과 아울러 코팅막에서 방사되는 원적외선에 의한 신선도를 유지케하는 무독성 코팅 도막을 형성하는 것이다.In particular, the present invention performs a simple coating process of one or two times to inhibit the growth of harmful fungi in water, sterilization and long-term protection function of the resin component of the coating agent, as well as maintaining the freshness by far-infrared radiation emitted from the coating film. To form a non-toxic coating film.

일반적으로 각종 수 저장 시설은 콘크리트, 철, F.R.P 등을 소재로 하고 그 소재의 방식과 방청의 목적으로 Epoxy수지 관련 도료로 피복하고 있으나 장기간으저수 과정에서 발생되는 염소 등 화학적 부식,수질의 변질, 각종 균류의 증식 등에 따른 위생 안전성이 결여될 뿐 아니라 도막의 내구성의 한계에 따른 빈번한 재도장, 보수 사례가 빈번할 뿐 아니라 일반페인트로 마감할 경우 도장시에 사용되는 유기 희석제(유기용매)의 잔류 또는 대기중에 비산되는 유기용매의 증기로 인한 환경오염의 원인이 되고 있다.Generally, various water storage facilities are made of concrete, iron, FRP, etc., and they are covered with Epoxy resin-related paints for the purpose of rust prevention and corrosion prevention.However, chemical corrosion, deterioration of water quality, Not only lack of hygienic safety due to the growth of various fungi, but also frequent repainting and repairing due to the limitation of durability of coating film, and residue of organic diluent (organic solvent) used for coating when finishing with general paint Or it is a cause of environmental pollution by the vapor of the organic solvent scattering in the atmosphere.

그러므로 본 발명은 유기 희석제를 사용하지 않고 경화된 도막으로 부터 유해물질의 용출이 없을뿐 아니라 원적외선과 항균 성분의 상승 효과에 의한 수중 균류의 증식 억제 및 제거 효과가 탁월한 무용제형 세라믹 향균 방식코팅제이다.Therefore, the present invention is a solvent-free ceramic antimicrobial anticorrosive coating agent that is excellent in inhibiting and removing proliferation of fungi in water by synergistic effects of far infrared rays and antibacterial components, as well as no elution of harmful substances from the coating film cured without using an organic diluent.

기존의 수저장 설비의 도장재인 Epoxy계 Coating제는 개략적으로 다음과 같다Epoxy-based coating agent, which is a coating material of existing water storage facilities, is schematically as follows.

A. 주제의 조성A. Composition of the subject

B. 경화제의 조성B. Composition of Curing Agents

이상과 같은 형태의 도료 조성물은 주제와 경화제를 일정 비율로 혼합하여 도장작업에 맞도록 희석제를 혼합하여 사용한다. 따라서 그 경화가 늦고 단순히 피도장체를 저장된 물로 부터 차단하는 효과 뿐이다. 그러므로 단순 차단 목적의 도막이 아닌 기능성 도막의 개발이 절실히 요구 되고 있다.The coating composition of the form described above is used by mixing the main agent and the curing agent in a predetermined ratio to mix the diluent to suit the painting work. Therefore, the hardening is late and merely the effect of blocking the coating from stored water. Therefore, there is an urgent need for the development of functional coatings, rather than simple barrier coatings.

따라서 본 발명은 코팅제로서의 기능과 성능을 극대화 하기 위하여 내식성, 내구성, 내화학성이 보장된 기능성의 FDA인가 Epoxy수지와 특수 변성 Amine을 주제로 하는 경화제를 이상적 비율로 배합하고 목적하는 기능을 부여하기 위하여 원적외선 방출 기능을 가진 특수 Bio Ceramic Filler와 인체에 무해한 항균성 Ceramic 성분을 혼합함으로써 본 특허의 목적 달성에 이르게 함으로써 그 안전성을 확보 하는데 목적이 있다.Therefore, the present invention is to formulate the ideal combination of the FDA or Epoxy resin and specially modified Amine-based curing agent of the functional and guaranteed corrosion resistance, durability and chemical resistance in order to maximize the function and performance as a coating agent and to give the desired function The purpose of this invention is to secure safety by mixing special Bio Ceramic Filler with far-infrared ray emission function with antibacterial ceramic component that is harmless to human body.

1. 주 제1. Subject

2. 경화제2. Curing agent

[제조 공정][Manufacture process]

위 실시예의 주제 및 경화제를 각각 별도의 용기에 평량하여 60∼80℃로 가열보온되는 분산기에 이송하여 고속 교반하는데 모든 공정에서의 오염을 예방하기 위하여 내시경 Stainless Steel 재질로 하며 일정 시간의 분산 공정이 완료되면 주제와 경화제의 비율을 5:1로 취하여 혼합하여 시험한다.The main body and the hardener of the above embodiment are weighed in a separate container, respectively, and transferred to a disperser heated to 60 to 80 ° C. for high-speed agitation. When complete, the ratio of the subject and the hardener is 5: 1 and tested.

또 본 고안에 사용되는 Bio Ceramics 및 Cerato 향균제는 화학적으로 대단히 안정한 미세입자로서 단순 혼합 분산에 의하 공정으로 본 고안이 제조된다.In addition, the Bio Ceramics and Cerato antimicrobial agents used in the present invention are chemically very stable microparticles, and the present invention is prepared by a simple mixed dispersion process.

[실시 예의 시험 결과][Test Result of Example]

이상의 시험 결과와 첨부의 음용수 기준 용출시험 및 항균 시험을 각각 화학시험연구원에 시험의뢰하여 그 안전성 및 항균성 시험을 완료하였다.The above test results, the attached drinking water standard dissolution test and the antibacterial test were commissioned to the Korea Testing Institute for their safety and antimicrobial test.

본 발명은 일상생활에 소요되는 생활용수 및 음용수의 장기 보존과 수저장 시설의 수명을 연장하고 보다 안전한 생활 용수를 공급할 수 있는 모든 저수 설비, 상수도 배관, 수영장등 물의 오염에 의한 수인성 질병으로 부터 국민 건강을 지키고 시설의 유지, 보수 비용을 절감하는데 기여하고자 한다.The present invention extends the lifespan of daily and drinking water for daily life and extends the life of water storage facilities, and from water-borne diseases caused by water pollution such as all water facilities, water supply pipes, and swimming pools that can supply safer living water. It is intended to contribute to protecting the public health and reducing the cost of maintenance and repair of facilities.

Claims (1)

Bis Penol A및 Bis Penol F형 Epoxy수지의 함량이 30∼50%이고 지방족 Polyamide를 경화제로 하여 완전 무용제형으로 도장하는 2성분계 자연경화 및 가열경화 방식으로 경화되는 Epoxy수지계 피막 조성물로서 토성Ceramic의 함량이 10∼30%, 항균제Cerato의 함량이 1∼3%의 조성으로 이루어진 코팅제Bis Penol A and Bis Penol F-type Epoxy resins contain 30-50% of the contents of the Epoxy resin-based coating composition which is cured by a two-component natural curing and heat curing method using an aliphatic polyamide as a curing agent. 10 to 30% of the antimicrobial Cerato content of 1 to 3%
KR10-2001-0049720A 2001-08-17 2001-08-17 Two-component, non-toxic, solvent-free ceramic anticorrosive coating mainly composed of antimicrobial bio ceramics KR100484565B1 (en)

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KR10-2001-0049720A KR100484565B1 (en) 2001-08-17 2001-08-17 Two-component, non-toxic, solvent-free ceramic anticorrosive coating mainly composed of antimicrobial bio ceramics

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KR10-2001-0049720A KR100484565B1 (en) 2001-08-17 2001-08-17 Two-component, non-toxic, solvent-free ceramic anticorrosive coating mainly composed of antimicrobial bio ceramics

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KR100484565B1 KR100484565B1 (en) 2005-04-20

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KR100841607B1 (en) 2007-04-22 2008-07-04 한토산업 (주) Paint composition for waterproof and anticorrosion of waterworks-metal pipe

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JPH0717763B2 (en) * 1985-02-14 1995-03-01 喜代志 綛谷 Abrasion resistance repair agent
US4889947A (en) * 1988-07-28 1989-12-26 Ici Americas Inc. Ultraviolet radiation absorbing naphthalenylidene compositions
KR20000035046A (en) * 1998-11-11 2000-06-26 토마스 더블유. 버크맨 Weather resistant polymeric coating system
KR100623607B1 (en) * 1999-12-31 2006-09-12 주식회사 케이씨씨 A epoxy flooring coating composition
KR20010000104A (en) * 2000-04-22 2001-01-05 위승용 Coating material for a fabric in humid condition
US6572971B2 (en) * 2001-02-26 2003-06-03 Ashland Chemical Structural modified epoxy adhesive compositions

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