KR20010094777A - A charcoal vessel - Google Patents

A charcoal vessel Download PDF

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Publication number
KR20010094777A
KR20010094777A KR1020000018028A KR20000018028A KR20010094777A KR 20010094777 A KR20010094777 A KR 20010094777A KR 1020000018028 A KR1020000018028 A KR 1020000018028A KR 20000018028 A KR20000018028 A KR 20000018028A KR 20010094777 A KR20010094777 A KR 20010094777A
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South Korea
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charcoal
container
weight
parts
powder
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KR1020000018028A
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Korean (ko)
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정몽선
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정몽선
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

Abstract

PURPOSE: A charcoal container is provided to prevent reduction of the natural characteristics of charcoal such as deodorization, adsorption, and far-infrared ray emission while preventing the sticking of the charcoal powder by adding reinforcing resin to fine coal power of black oaks, thereby maintaining plants or food fresh for a long time and promoting the growing of plants. CONSTITUTION: A charcoal container is manufacturing by adding 20-50wt% of unsaturated polyester resin to 100wt% of fine charcoal, mixing the unsaturated polyester resin with the fine charcoal, and casting the mixture to mold as a desired shape, wherein an inorganic filler is added by less than 15wt% with respect to 100wt% of the fine charcoal powder of black oaks.

Description

숯용기{A charcoal vessel}Charcoal vessel

본 발명은 숯 분말에 강화수지를 첨가하여 제조한 숯용기에 관한 것으로서, 좀더 자세히는 백탄분말 100중량부에 폴리에스테르 30중량부, 탈크 10중량부를 첨가하여 주조성형한 백탄용기에 관한 것이다.The present invention relates to a charcoal container prepared by adding a reinforced resin to the charcoal powder, and more specifically, to a charcoal container cast by adding 30 parts by weight of polyester and 10 parts by weight of talc to 100 parts by weight of the charcoal powder.

참나무숯은 그 성질에 따라서 백탄과 검탄으로 나뉜다. 백탄과 검탄은 탄소, 산소, 수소, 회분 등의 성분이나 딱딱함, 발열량, 화력의 지속성, 화력 등에서 차이가 난다. 검탄은 400~700℃에서 생성되며, 백탄은 100℃ 이상의 고온에서 생성된다.Oak charcoal is divided into white charcoal and gum charcoal according to its properties. White charcoal and gum charcoal differ in terms of carbon, oxygen, hydrogen, ash, and other components, such as hardness, calorific value, heat sustainability, and thermal power. Gum coal is produced at 400-700 ° C, and white coal is produced at high temperatures of 100 ° C or higher.

백탄의 성질은 화력이 세고, 오래 지속되며, 미세한 기공이 많아 흡착력이 강한 것이 특징이다. 우리나라의 참숯 백탄은 특히 우수하여 숯불구이용, 연료 등으로 오랫동안 사용되어 왔다. 백탄의 물성은 단단하고 두드리면 금속성 소리가 난다. 검탄은 백탄에 비해 탄질이 부드럽고 불이 잘 붙으며 타다 꺼지는 일이 적어 요리보다 제련이나 대장간 등의 철가공에 많이 이용된다.White charcoal is characterized by its high thermal power, long lasting, and fine pores, which have strong adsorptive power. Charcoal white charcoal in Korea is particularly excellent and has been used for a long time as a charcoal roast and fuel. The properties of the sand are hard and give a metallic sound when beaten. Compared to white coal, gum is softer and softer to ignite, and it is less burned and burned, so it is used more for smelting and forging than for cooking.

숯의 원료인 목재는 떡갈나무, 졸참나무, 상수리나무, 밤나무, 낙엽송, 소나무, 삼나무, 노송나무 외 대나무, 왕겨, 야자껍질, 매실, 잣, 뽕나무 등이고 숯의 용도별 분류로는 요리용, 농업용, 공업용, 환경개선용, 건강생활용, 공예, 예술용이 있고 숯의 탄화진행도에 따라 저온 탄화숯은 400~500℃에서 탄화된 건류탄, 평로탄, 중온탄화숯은 600~700℃에서 탄화된 검탄(흑탄), 고온탄화숯은 1000℃ 전후에서 탄화되는 백탄이다.Wood materials of charcoal are oak, prunus oak, oak, chestnut, larch, pine, cedar, cypress, bamboo, chaff, palm bark, plum, pine, mulberry, etc. There are industrial, environmental improvement, health life, crafts and arts. Depending on the progress of carbonization of charcoal, low-temperature charcoal is carbonized charcoal at 400-500 ℃, charcoal, flat coal and mesophilic charcoal at 600-700 ℃. (Black charcoal) and high temperature charcoal are white charcoal carbonized at around 1000 degreeC.

원목의 목질은 셀룰로즈, 헤미셀룰로즈, 리그닌이라는 성분을 가지며, 탄소, 수소 등의 원소로 구성되어 있는데 이것을 산소가 없거나 산소가 적은 환경에서 가열하면 280℃ 전후에서 급격히 분해되기 시작하여 탄산가스, 일산화탄소, 수소, 탄화수소 등 가스를 발생시키고 나무는 점점 탄소성분이 많아지고 결정이 불규칙적인 무정형 탄소로 변한다.Solid wood has cellulose, hemicellulose, and lignin, and is composed of elements such as carbon and hydrogen. When heated in an oxygen-free or low-oxygen environment, the wood is decomposed rapidly at around 280 ° C. Gases such as hydrogen and hydrocarbons are generated, and the wood gradually turns into amorphous carbon, which is rich in carbon and irregular in crystals.

그것을 더욱 가열하여 650~700℃가 되면 산소나 수소가 점점 감소하고 표면 성질이 크게 변하기 시작한다. 원목상태에서는 탄소함유량이 50이지만 탄화온도 400℃가 되면 72, 600℃에서는 89, 1000℃ 이상에서는 95를 넘는다.When it is heated further to 650 ~ 700 ℃, oxygen or hydrogen decreases gradually and surface properties start to change significantly. In the solid state, the carbon content is 50, but when the carbonization temperature reaches 400 ° C, the carbon content is over 89 at 72 and 600 ° C and over 95 at 1000 ° C.

숯의 단면을 현미경으로 확대해 보면 미크론 단위의 미세구멍이 숯 내부에 형성되어 있다. 1g의 숯을 표면적으로 환산하면 약 300㎡이나 된다.When the cross section of the char is magnified under a microscope, microns of micropores are formed inside the char. The surface area of 1 g of charcoal is about 300 m 2.

또한, 숯은 연마성, 흡착성, 전자파 차단 등 인체에 유익한 특성을 많이 가지고 있다.In addition, charcoal has many beneficial properties to the human body, such as abrasive, adsorptive, electromagnetic wave blocking.

최근에는 상기 숯의 물성을 이용하여 환경보존, 농림수산업, 갱활개선, 식품가공 등에 숯을 활용하는 다양한 방법들이 개발되고 있다. 이들 중 몇가지만 살펴 보면Recently, various methods of utilizing charcoal for environmental preservation, agriculture, forestry and fisheries, rehabilitation, and food processing have been developed using the properties of the charcoal. If you look at some of these,

1) 정화작용1) Purification

생활용수나 하천, 호수 등의 수질정화에 숯의 흡착능을 이용하고 있다.The adsorption capacity of charcoal is used to purify water for living water, rivers and lakes.

2) 농림수산업에 이용2) Use for agriculture, forestry and fisheries

현재 숯과 목초액은 시설원예나 논, 밭에 이용되며 야채, 과수, 차 등의 재배에 있어서 토질개량, 퇴비제조 등에 이용된다.Currently, charcoal and wood vinegar are used for horticulture, rice fields and fields, and for soil improvement and compost production in the cultivation of vegetables, fruit trees and tea.

3) 주택자재로의 응용3) Application to housing materials

숯의 탁월한 조습작용을 이용하여 주거환경조습제, 벽지, 장판 등의 제품이 만들어지며, 이때는 숯의 부산물이 많이 활용된다.By using the excellent moisturizing effect of charcoal, products such as residential environment moisturizer, wallpaper, floorboard, etc. are produced, and by-products of charcoal are utilized a lot.

4) 생활용품에 이용4) Use for household goods

정수기, 냉장고, 신발장의 탈취제 및 실내정화용 등으로 많이 이용되고 있으며, 침대패드, 배게, 방석 등 건강제품으로 판매되고 있다.It is widely used as a deodorant for purifiers, refrigerators and shoeboxes, and for indoor cleansing. It is also sold as health products such as bed pads, pillows, and cushions.

한편, 원적외선이란 18세기 독일의 과학자 허셀에 의해 발견되어 1876년부터 의학계에서 질병치료에 이용되기 시작하여 국내에서도 온열 암치료기기 등이 개발되어 임상에 사용되고 있다. 원적외선은 생명생육광선이라 불리며 3.6~16미크론의 긴 파장의 열에너지를 발산한다. 이 열에너지는 피부속 40㎜까지 침투하여 몸의 온영작용을 통해 인체의 모세혈관을 확장시켜 혈액순환을 원활히 하고 인체의 물질들을 순환시키는 유익한 광선이다. 이 광선은 지구상의 모든 물질에서 방사되나 특히 숯, 황토, 돌, 세라믹 등이 방사율이 높다. 원적외선은 물의 분자구조를 바꾸어주는 생명의 에너지로 숯을 물에 넣으면 산소량이 높아져 좀처럼 물이 변질되지 않는다.On the other hand, far infrared rays were discovered by the German scientist Hussel in the 18th century and started to be used in the medical treatment of diseases from 1876, and thermal cancer treatment devices have been developed and used in the clinic in Korea. Far infrared rays are called life-growing rays and emit 3.6 to 16 microns of long-wave heat energy. This heat energy penetrates up to 40mm in the skin and expands the capillaries of the human body through the warming of the body, which facilitates blood circulation and circulates the substances of the human body. These rays are emitted from all matter on Earth, but charcoal, loess, stones and ceramics have high emissivity. Far infrared rays are the energy of life that changes the molecular structure of water. When char is put into water, the amount of oxygen increases and water rarely deteriorates.

또한, 숯에는 냄새를 제거하는 효과도 있다. 방부작용과 부패균의 발생을 억제하여 냄새의 근원을 없애고 악취를 흡착한다.The charcoal also has the effect of removing odors. It suppresses the occurrence of antiseptic and decaying bacteria, eliminating the source of odor and adsorbing odor.

이와 같이 원적외선 방출 등 인체에 유익한 여러 가지 효과를 나타냄에도 불구하고 종래의 숯함유제품들, 예컨대 숯을 포함하는 장판, 벽지 등은 숯 함량이 매우 낮아 실제로 숯의 유익한 효과를 발휘하기가 어려웠다.Despite such various effects beneficial to the human body, such as far-infrared emission, conventional charcoal-containing products, such as jangpan, wallpaper, including charcoal, have a very low charcoal content, and thus it is difficult to achieve the beneficial effect of charcoal.

공개특허공보 특2000-0012409호는 플라스틱 원료 100중량부에 대나무숯 분말 0.5~1.5중량부, 산화티타늄 0.3~0.8중량부를 첨가하여 사출성형한 대나무숯을 넣은 플라스틱 용기에 대하여 개시하고 있다.Korean Patent Laid-Open No. 2000-0012409 discloses a plastic container containing bamboo charcoal injection molded by adding 0.5 to 1.5 parts by weight of bamboo charcoal powder and 0.3 to 0.8 parts by weight of titanium oxide to 100 parts by weight of a plastic raw material.

그러나, 위 대나무숯을 넣은 플라스틱 용기는 대나무숯 분말의 함량이 0.5~1.5중량부에 불과하여 숯의 유익한 효과를 크게 기대하기는 어렵다. 즉, 도 4에 개시된 탈취시험에서는 상기 대나무숯을 넣은 플라스틱 용기의 탈취율이 30~35정도로서 실제로 숯 자체의 탈취능보다는 훨씬 저감된 효과만을 나타낸다. 뿐만 아니라, 소량의 숯분말을 함유하고 있기 때문에 방사되는 원적외선의 양도 미약하다.However, the plastic container containing the bamboo charcoal is hard to expect the beneficial effect of the charcoal because the content of bamboo charcoal powder is only 0.5 to 1.5 parts by weight. In other words, in the deodorization test disclosed in FIG. 4, the deodorization rate of the plastic container containing the bamboo charcoal is about 30 to 35, which shows only a much reduced effect than the deodorizing ability of the charcoal itself. In addition, because it contains a small amount of charcoal powder, the amount of far-infrared rays emitted is also weak.

따라서, 본 발명의 목적은 상기와 같은 문제점을 해결하고 숯함량을 높여 숯을 주원료로 하며 식물 또는 음식물의 장기적인 보존관리가 가능한 용기를 제공하려는 것이다.Accordingly, it is an object of the present invention to solve the above problems and to increase the content of charcoal as a main raw material and to provide a container capable of long-term preservation management of plants or food.

상기 목적을 달성하기 위하여 본 발명은 백탄분말 100중량부에 불포화 폴리에스테르 수지 20~50중량부를 첨가, 혼합하여 주조, 성형된 숯용기를 제공한다.In order to achieve the above object, the present invention provides a charcoal container cast and molded by adding and mixing 20 to 50 parts by weight of an unsaturated polyester resin to 100 parts by weight of white charcoal powder.

또한, 본 발명은 백탄분말 100중량부에 불포화 폴리에스테르 수지 20~50중량부 및 무기충진제 5~10중량부를 첨가, 혼합하여 주조, 성형된 숯용기를 제공한다.In addition, the present invention adds and mixes 20 to 50 parts by weight of unsaturated polyester resin and 5 to 10 parts by weight of inorganic filler to 100 parts by weight of white charcoal powder to provide a cast and molded charcoal container.

본 발명에서 사용하는 백탄분말은 입자크기가 200~300메쉬인 것이 좋고, 백탄분말은 참나무숯으로 제조된 것이 더욱 바람직하다. 백탄분말 100중량부에 대하여 불포화 폴리에스테르 강화수지원료가 20~50중량부인 것이 바람직하다. 불포화 폴리에스테르 강화수지원료가 20중량부 미만인 경우에는 성형이 잘 되지 않는 단점이 있으며, 50중량부를 초과하는 경우에는 탈취효능 등이 저하되는 문제가 있다.The charcoal powder used in the present invention preferably has a particle size of 200 to 300 mesh, and the charcoal powder is more preferably made of oak charcoal. It is preferable that unsaturated polyester reinforcement water support charge is 20-50 weight part with respect to 100 weight part of white coal powder. When the unsaturated polyester reinforced water support material is less than 20 parts by weight, there is a disadvantage in that the molding is not good, and when it exceeds 50 parts by weight, there is a problem in that the deodorizing effect is lowered.

또한, 본 발명의 구성에는 탈크 등의 무기충진제를 백탄분말 중량대비 15중량부 이하 부가하면 숯용기의 강도를 더욱 높일 수 있다. 부가되는 무기충진제가 15중량부를 초과하는 경우에는 성형시 표면이 매끄럽게 성형되지 아니할 뿐만 아니라 생산단가가 높아지는 문제점이 있다.In addition, in the configuration of the present invention, by adding an inorganic filler such as talc to 15 parts by weight or less relative to the weight of the charcoal powder, the strength of the charcoal container can be further increased. When the added inorganic filler exceeds 15 parts by weight, not only the surface is not molded smoothly during molding but also there is a problem in that the production cost increases.

본 발명에서는 백탄이 가지고 있는 고경질, 고강도 특성을 그대로 살리는 용기를 제조하는 것이 특징인데, 백탄, 특히 참나무숯 백탄을 분말화하여 이를 주원료로 하여 숯용기를 제조하되, 사출성형이 아니라 주조성형함으로써 원래의 물성을 발현할 수 있도록 하였다.The present invention is characterized by manufacturing a container utilizing the high hard and high strength properties of the charcoal as it is, the charcoal container is manufactured by powdering the charcoal, in particular oak charcoal charcoal as a main raw material, but by injection molding rather than injection molding The original physical properties can be expressed.

본 발명의 숯용기는 화분, 꽃병, 수반, 음식 담는 그릇용 등으로 제조할 수 있다.Charcoal container of the present invention can be produced in a pot, vase, accompaniment, food container.

이하 본 발명의 구성을 실시예를 통하여 좀더 상세히 설명한다. 그러나, 본발명의 범위가 아래의 실시예 범위에 제한되는 것은 아니다.Hereinafter, the configuration of the present invention will be described in more detail with reference to the following examples. However, the scope of the present invention is not limited to the scope of the following examples.

제조예Production Example

참나무숯 백탄분말 100kg에 폴리에스테르 30kg, 탈크 10kg을 혼합하여 2일동안 숙성시켰다. 숙성시킨 후 전체 혼합물 중량의 1/100가량 되는 주조성형에 일반적으로 사용되는 경화제를 가하여 잘 혼합한 후 주조틀에 혼합한 재료를 부어 화분 및 수반을 주조성형하였다. 상기 경화제를 가한 후 혼합된 주조재료에서 열이 발생한다. 이때, 주조시 주조틀에 일정 정도의 약한 진동을 주어 혼합한 주조재료가 주조틀 안에서 골고루 분산되고 표면이 매끄럽게 성형되도록 하였다.100 kg of oak charcoal charcoal powder was mixed with 30 kg of polyester and 10 kg of talc and aged for 2 days. After aging, the curing agent generally used in casting molding having about 1/100 of the total weight of the mixture was added and mixed well. Then, the mixed material was poured into the casting mold and cast molding was carried out. After adding the curing agent, heat is generated in the mixed casting material. At this time, the casting mold was given a slight vibration to the casting mold so that the mixed casting material was evenly dispersed in the casting mold and the surface was formed smoothly.

이와 같이 성형된 본 발명의 숯용기는 주원료가 참나무숯 백탄으로서 탈취, 항균, 수질 등의 정화, 원적외선 방사, 음이온 방출 효과를 나타내었다.The charcoal container of the present invention thus formed showed deodorizing, antibacterial, water quality purification, far infrared radiation, anion release effect as oak charcoal white charcoal.

물성측정시험Physical property test

참나무숯 백탄 및 본 발명의 숯용기에 대하여 40℃에서 FT-IR Spectrometer를 이용하여 흑체(black body) 대비 방사율과 방사에너지를 측정하였다. 결과는 표 1에 나타내었다.The oak charcoal charcoal and the charcoal container of the present invention were measured for emissivity and radiation energy relative to black body using a FT-IR Spectrometer at 40 ℃. The results are shown in Table 1.

또한, 본 발명의 숯용기가 있는 상태와 없는 상태에서 각각 암모니아 가스 탈취효과가 어느 정도인지 KICM-FIR-1004 방법에 의하여 측정하였다. 결과는 표 2에 제시되었다.In addition, it was measured by the KICM-FIR-1004 method to determine the degree of ammonia gas deodorizing effect in the state with and without the charcoal container of the present invention, respectively. The results are shown in Table 2.

시험결과, 본 발명의 숯용기는 가공하지 않은 숯과 거의 동일한 정도의 원적외선 방사율 및 방사에너지 값을 나타내었다.As a result of the test, the charcoal container of the present invention showed far-infrared emissivity and radiant energy value about the same as the raw charcoal.

또한, 본 발명의 숯용기는 대나무숯을 약1중량부 함유하는 종래기술에 의한플라스틱 용기에 비하여 그 탈취능이 월등히 향상되었다.In addition, the charcoal container of the present invention is significantly improved deodorizing ability compared to the plastic container according to the prior art containing about 1 part by weight of bamboo charcoal.

나아가, 본 발명의 숯용기는 주조성형방법에 의하여 제조되어 숯을 다량 함유하고 있음에도 불구하고 용기의 표면에 숯가루가 묻어나지 않는다.Furthermore, the charcoal container of the present invention is manufactured by a casting molding method, and although the charcoal contains a large amount of charcoal, charcoal powder is not buried on the surface of the container.

시험대상Test subject 방사율(5~20㎛)Emissivity (5 ~ 20㎛) 방사에너지(W/㎡)Radiation energy (W / ㎡) charcoal 0.9250.925 3.73 X 102 3.73 X 10 2 본 발명 숯용기The present charcoal container 0.9090.909 3.67 X 102 3.67 X 10 2

시험항목Test Items 경과시간(분)Elapsed time (minutes) 블랭크 농도(ppm)Blank Concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율()Deodorization rate () 탈취시험Deodorization test 0분(초기)0 minutes (initial) 500500 500500 -- 30분30 minutes 480480 120120 6565 60분60 minutes 470470 9090 7373 90분90 minutes 450450 7070 7777 120분120 minutes 440440 6060 7979

(주) 1) 블랭크(blank): 시료를 넣지 않은 상태에서 측정한 것임. 즉, 본 발명의 숯용기 없이 탈취시험을 수행한 것으로서 대조군임.(Note) 1) Blank: Measured in a state without a sample. That is, as a control deodorization test was performed without the charcoal container of the present invention.

1) 시험방법: KICM-FIR-10041) Test Method: KICM-FIR-1004

2) 시험가스명: 암모니아2) Test gas name: Ammonia

3) 가스농도측정: 가스검지관3) Gas concentration measurement: gas detector tube

상기와 같이, 본 발명의 숯용기는 참나무숯 백탄분말을 주원료로 하고 강화수지를 부가하여 주조성형함으로써 숯 고유의 탈취, 흡착특성, 원적외선 방사특성 등을 저감시키지 않고 숯가루가 묻어나지 않는다.As described above, the charcoal container of the present invention is made of oak charcoal charcoal powder as a main raw material and added by reinforcing resin so that the charcoal is not buried without reducing the deodorization, adsorption characteristics, far-infrared radiation characteristics of charcoal.

또한, 본 발명의 숯용기는 숯가루를 주원료로 하여 제조되었으므로 식물이나 음식물을 오랜 기간동안 신선하게 유지시킬 수 있으며, 식물 생장을 촉진시키는 효과가 현저하다.In addition, since the charcoal container of the present invention was manufactured using charcoal powder as a main raw material, the charcoal container can be kept fresh for a long time, and the effect of promoting plant growth is remarkable.

Claims (3)

백탄분말 100중량부에 불포화 폴리에스테르 수지 20~50중량부를 첨가, 혼합하여 주조, 성형되는 숯용기.Charcoal container which is cast and molded by adding 20-50 parts by weight of unsaturated polyester resin to 100 parts by weight of charcoal powder. 제1항에 있어서,The method of claim 1, 무기충진제를 참나무숯 백탄분말 100중량부 대비 15중량부 이하 부가하는 것을 특징으로 하는 숯용기.Charcoal container, characterized in that the inorganic filler is added 15 parts by weight or less compared to 100 parts by weight of oak charcoal charcoal powder. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2, 상기 백탄분말은 참나무로부터 제조되는 것을 특징으로 하는 숯용기.The charcoal container is characterized in that the charcoal powder is made from oak.
KR1020000018028A 2000-04-06 2000-04-06 A charcoal vessel KR20010094777A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010082459A (en) * 2001-07-21 2001-08-30 배수열 How to infiltrate rosin on charcoal to prevent charcoal black
KR100552403B1 (en) * 2002-04-16 2006-02-20 (주)아이에스디지털 Carbon roasted plate manufacturing mathod using charcoal

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08134361A (en) * 1994-09-13 1996-05-28 Tokuyama Corp Composite resin composition
KR19990046800A (en) * 1999-04-28 1999-07-05 염종무 Plastic vessel containing charcoal powder
KR200170450Y1 (en) * 1999-09-14 2000-02-15 주식회사엔.비.엠 A charcoal-port
KR20000012409A (en) * 1999-12-03 2000-03-06 이지홍 Plastic vessle with bamboo charcoal powder therein
JP2000086775A (en) * 1998-07-15 2000-03-28 Yutaka Imaizumi Molded product having antimicrobial activity

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08134361A (en) * 1994-09-13 1996-05-28 Tokuyama Corp Composite resin composition
JP2000086775A (en) * 1998-07-15 2000-03-28 Yutaka Imaizumi Molded product having antimicrobial activity
KR19990046800A (en) * 1999-04-28 1999-07-05 염종무 Plastic vessel containing charcoal powder
KR200170450Y1 (en) * 1999-09-14 2000-02-15 주식회사엔.비.엠 A charcoal-port
KR20000012409A (en) * 1999-12-03 2000-03-06 이지홍 Plastic vessle with bamboo charcoal powder therein

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010082459A (en) * 2001-07-21 2001-08-30 배수열 How to infiltrate rosin on charcoal to prevent charcoal black
KR100552403B1 (en) * 2002-04-16 2006-02-20 (주)아이에스디지털 Carbon roasted plate manufacturing mathod using charcoal

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