KR20010070816A - Lock of vegetable fiber for purification of the polluted water and waste water - Google Patents

Lock of vegetable fiber for purification of the polluted water and waste water Download PDF

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KR20010070816A
KR20010070816A KR1020010032312A KR20010032312A KR20010070816A KR 20010070816 A KR20010070816 A KR 20010070816A KR 1020010032312 A KR1020010032312 A KR 1020010032312A KR 20010032312 A KR20010032312 A KR 20010032312A KR 20010070816 A KR20010070816 A KR 20010070816A
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weight
coconut shell
activated carbon
mixture
purification
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KR1020010032312A
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KR100403782B1 (en
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송정호
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박승상
신성메디아 주식회사
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/06Aerobic processes using submerged filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • C02F3/106Carbonaceous materials
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • C02F3/107Inorganic materials, e.g. sand, silicates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

PURPOSE: A vegetable fiber material lock for purifying sewage and wastewater is provided, which is suitable for habitation of microorganisms that oxidize, decompose and reduce organic matter by excellent affinity of the natural vegetable fiber for microorganism, does not untie in water, is large in porosity and can be used for an extended time, so that the system can treat sewage and wastewater efficiently. CONSTITUTION: The is made by the following steps: (i) laminate 0.5-2 kg per square meter of coconut shell and compact the laminated shell; (ii) mix an adhesive 40-65wt%, activated carbon 20-45wt% and bioceramic 15-40wt%; (iii) spray the mixture of 40-50 wt.% based on the weight of the coconut shell, on the both sides of the laminated shell; and (iv) dry the material naturally.

Description

오,폐수 정화용 식물성 섬유재 락{Lock of vegetable fiber for purification of the polluted water and waste water}Lock of vegetable fiber for purification of the polluted water and waste water}

본 발명은 오,폐수 정화용 식물성 섬유재 락(lock)에 관한 것으로, 좀 더 구체적으로는 오,폐수처리에 사용되는 미생물이 충분히 증식되도록 하는 단위 부피당 표면적이 타 접촉재 보다 월등히 크고, 공극율이 높으며, 기준의 어떤 여재보다 제거부하가 크고, 큰 공극율을 갖도록 하여 공기, 오,폐수 통과에 대한 저항율이 매우 적고, 미립자나 기체의 충돌 흡착시 작용하는 표면적이 매우 클 뿐만 아니라 특수표면처리에 의해 집전이 용이하고, 미생물 서식을 최적화 할 수 있도록 한 오,폐수 정화용 식물성 섬유재 락 및 이의 제조방법에 관한 것이다.The present invention relates to a plant fiber material lock for sewage and wastewater purification. More specifically, the surface area per unit volume to allow the microorganisms used for sewage and wastewater to fully grow is significantly larger than that of other contact materials, and the porosity is high. In addition, the removal load is greater than that of any standard media, and it has a large porosity, so that the resistance to air, waste, and waste water passage is very low, and the surface area acting upon the collision adsorption of particulates or gases is very large, and the current is collected by special surface treatment. The present invention relates to a plant fiber material rock for filthy and wastewater purification, and to a method for producing the same, which facilitate and optimize microbial habitat.

일반적으로, 락(lock)이란 동식물 섬유 및 합성섬유 등을 스프링 모양으로 컬링(curling) 가공하여 작은 탄성체를 만들고 이를 표면 결합시킨 것으로서, 오,폐수 처리를 위해 유기물의 산화분해 및 환원을 담당하는 미생물이 서식할 수 있도록 하기 위한 것이다.In general, the lock (lock) is a small elastic body made by curling (curling) the flora and fauna fibers and synthetic fibers, etc. in a spring shape and bonded to the surface, microorganisms responsible for oxidative decomposition and reduction of organic matter for the treatment of wastewater This is to allow for formatting.

종래에는 상기와 같은 락으로서 단지 합성섬유 원사를 소정 길이로 절단한후, 이를 용해시키거나 접착제를 정착하여 굳힌 부직포 등을 사용하였다.Conventionally, as a lock as described above, only a synthetic fiber yarn was cut to a predetermined length, and then a nonwoven fabric or the like was used, which was dissolved or fixed by fixing an adhesive.

그러나, 상기와 같은 구성을 지닌 종래의 락은 수중에 장시간 설치하게 되면, 풀림과 처짐이 발생되어 기능이 현저히 저하될 뿐만 아니라 오,폐수를 분해하는 미생물의 서식환경이 열악하여 미생물의 번식이 위축되어 효과적인 오,폐수처리를 기대할 수 없다는 문제점이 있으며, 합성섬유사를 사용하게 되므로 원재료의 구입에 따른 비용이 소요되고, 폐기시에는 매립이나 소각을 하여야 하지만 소각시에는 합성섬유사에서 인체에 유해한 성분들이 배출되고 매립시에는 분해가 거의 이루어지지 않아 환경오염을 유발하는 문제점이 있었다.However, if the conventional lock having the above-described configuration is installed in water for a long time, loosening and sagging occur, not only the function is significantly degraded, but the habitat environment of microorganisms that decompose waste and waste water is poor, and the reproduction of microorganisms is reduced. There is a problem that effective wastewater treatment cannot be expected, and synthetic fiber yarns are used, which requires the cost of purchasing raw materials, and when discarded, landfilling or incineration should be carried out. When the components are discharged and landfill is hardly decomposed, there was a problem causing environmental pollution.

또한, 동식물섬유를 사용하여 제조한 락의 경우에는 락이 유입되는 오,폐수에 의하여 락의 재료가 되는 동식물섬유가 분해되거나 변질되어 락으로서의 기능을 상실하는 경우가 많이 있을 뿐만 아니라 락을 자주 교환하여야 하므로 번거롭고 유지 비용이 많이 소요된다는 단점이 있었다.In addition, in the case of a rock manufactured using animal and plant fibers, the animal and plant fibers, which are the material of the rock, are decomposed or deteriorated by the wastewater and wastewater introduced therein. As a result, it was cumbersome and costly to maintain.

따라서, 본 발명의 목적은 상술한 종래 기술들의 문제점을 해결하기 위하여 안출된 것으로 천연의 식물 섬유를 사용하므로서 미생물과의 친화력이 뛰어나 유기물을 산화분해 및 환원시키는 미생물의 서식에 아주 적합하며, 폐기시에 환경 오염을 유발하지 않고, 수중에서의 풀림이나 처짐이 발생되지 않으며, 공극율이 크고, 미생물의 번식 및 활동력을 활성화시켜 보다 효율적인 오,폐수 처리가 가능하고, 분해되거나 변질될 위험이 거의 없어 장시간 사용할 수 있어 유지 비용이 저렴한오,폐수 정화용 식물성 섬유재 락을 제공하는데 있다.Accordingly, an object of the present invention is to solve the problems of the prior art described above, and by using natural plant fibers, it has excellent affinity with microorganisms and is well suited for the incubation of microorganisms that oxidatively decompose and reduce organic matters. It does not cause environmental pollution, does not cause loosening or sagging in the water, has a large porosity, activates the propagation and activity of microorganisms, enables more efficient wastewater treatment, and there is little risk of decomposition or deterioration. It is to provide a vegetable fiber lock for the purification of wastewater, which can be used at low cost.

본 발명의 다른 목적은 상기의 오,폐수 정화용 식물성 섬유재 락을 용이하게 제조할 수 있는 방법을 제공하는 데 있다.It is another object of the present invention to provide a method for easily manufacturing the above-mentioned wastewater purification plant fiber material lock.

상기 목적 뿐만 아니라 용이하게 표출되는 또 다른 목적들을 달성하기 위하여 본 발명에서는 락의 재료로서 전처리가 거의 필요없고 합성섬유와 같이 가느다란 섬유 형상을 갖는 코코넛의 껍질을 사용하되 코코넛 껍질을 건조하여 일정 길이로 절단한 후, 코코넛 껍질을 단위 면적당 0.5 ∼ 2㎏의 양으로 적층하고 압착한 다음, 이물질을 흡착하는 활성탄과, 원적외선을 방사하여 미생물의 활동력을 활성화하는 바이오 세라믹 및 상기 활성탄과 바이오 세라믹을 코코넛 껍질에 부착시키기 위한 접착제를 적당한 비율로 혼합한 것을 적층된 코코넛 껍질의 양면에 분무하여 골고루 분포되도록 하고 건조하여 락을 제조하므로서 천연의 식물 섬유 사용으로 인한 미생물과의 친화력이 뛰어나 유기물을 산화분해 및 환원시키는 미생물의 서식에 아주 적합하며, 폐기시에 환경 오염을 유발하지 않고, 수중에서의 풀림이나 처짐이 발생되지 않으며, 공극율이 크고, 미생물의 번식 및 활동력을 활성화시켜 보다 효율적인 오,폐수 처리가 가능하고, 분해되거나 변질될 위험이 거의 없어 장시간 사용할 수 있어 유지 비용이 저렴한 오,폐수 정화용 식물성 섬유재 락을 얻을 수가 있었다.In order to achieve the above objects as well as other objects that are easily expressed, the present invention uses a shell of coconut having a thin fiber shape, such as synthetic fiber, with little pretreatment as a material of the rock, but drying the coconut shell to a certain length. After cutting into pieces, coconut shells are laminated in an amount of 0.5 to 2 kg per unit area, compressed, and then activated carbon adsorbing foreign substances, bio-ceramic for activating the activity of microorganisms by radiating far infrared rays, and the activated carbon and bio-ceramic coconut Mixing the adhesive in a suitable proportion to the shell by spraying on both sides of the laminated coconut shell to be evenly distributed and dried to produce a rock, and has excellent affinity with microorganisms due to the use of natural plant fibers, oxidative decomposition and It is well suited for the habitat of reducing microorganisms, It does not cause environmental pollution at the time of disposal, does not cause loosening or sagging in the water, has a large porosity, activates the growth and activity of microorganisms, enables more efficient wastewater treatment, and almost no risk of decomposition or deterioration. It can be used for a long time, so it is possible to obtain a vegetable fiber lock for purification of wastewater and wastewater, which is inexpensive to maintain.

본 발명을 좀 더 구체적으로 설명하면 다음과 같다.The present invention is described in more detail as follows.

본 발명의 오,폐수 정화용 락은 1㎡당 코코넛 껍질을 0.5 ∼ 2㎏의 양으로 적층하고 압착한 다음, 접착제 40 ∼ 65중량%, 활성탄 20 ∼ 45중량%, 바이오 세라믹 15 ∼ 40중량%로 구성되는 혼합물이 코코넛 껍질 중량에 대하여 40 ∼ 50중량%가 되도록 압착된 코코넛 껍질의 양면에 분무하고 건조한 것으로 특징지워진다.The waste water purification lock of the present invention is laminated with a coconut shell per 1 m 2 in an amount of 0.5 to 2 kg and pressed, and then, 40 to 65% by weight of the adhesive, 20 to 45% by weight of activated carbon, and 15 to 40% by weight of the bio-ceramic. The resulting mixture is characterized as sprayed and dried on both sides of the pressed coconut shell to be 40-50% by weight relative to the coconut shell weight.

또한, 본 발명의 오,폐수 정화용 락의 제조방법은 코코넛 껍질을 정선하고, 건조한 후에 5 ∼ 10㎝의 크기로 절단하는 가공 단계; 코코넛 껍질을 1㎡당 0.5 ∼ 2㎏의 양으로 적층하는 단계; 적층이 완료된 후에 1㎡당 1,000 ∼ 5,000㎏의 압력으로 적층물을 압착하는 단계; 별도로 접착제 40 ∼ 65중량%, 활성탄 20 ∼ 45중량%, 바이오 세라믹 15 ∼ 40중량%로 구성되며, 전체 혼합물 중량에 대하여 10중량%의 희석제를 첨가한 혼합물을 제조하는 단계; 상기 혼합물이 코코넛 껍질 중량에 대하여 40 ∼ 50중량%이 되도록 압착된 코코넛 껍질 적층체의 양면에 골고루 분무하는 단계; 소정 시간 동안 자연 건조시키는 단계로 구성되는 것을 특징으로 한다.In addition, the manufacturing method of the rock for purification of wastewater of the present invention includes a processing step of selecting a coconut shell and cutting it to a size of 5 to 10 cm after drying; Stacking coconut shells in an amount of 0.5 to 2 kg per m 2; Compressing the laminate at a pressure of 1,000 to 5,000 kg per m 2 after lamination is completed; Separately preparing a mixture comprising 40 to 65% by weight of adhesive, 20 to 45% by weight of activated carbon, and 15 to 40% by weight of bio-ceramic and adding 10% by weight of diluent based on the total weight of the mixture; Spraying evenly on both sides of the compressed coconut shell laminate such that the mixture is 40-50% by weight relative to the weight of the coconut shell; It is characterized by consisting of a step of natural drying for a predetermined time.

본 발명에서 사용되는 코코넛 껍질은 코코야자나무 열매의 껍질이고, 코코넛은 단단한 갈색의 섬유질 껍질 안에 부드럽고 젤리같은 하얀 속이 들어있는 것으로 각종 요리에 사용되고 있지만 코코넛 껍질은 과열처리하여 활성탄소로 재활용되는 정도 이외에는 전혀 재활용이 이루어지지 않고, 활성탄소로 제조시에도 제조 원가가 많이 소요되어 거의 사용되지 않고 특수한 경우에만 사용되기 때문에 거의 전량이 폐기되고 있는 실정이다.Coconut husk used in the present invention is a coconut palm bark, and the coconut is a soft brown jelly in the soft brown fibrous husk is used in various dishes, but the coconut shell is superheated and recycled as activated carbon at all Since recycling is not performed and manufacturing of activated carbon requires a lot of manufacturing costs, almost all of the waste is discarded because it is rarely used but is used only in a special case.

그러나, 본 발명에서는 코코넛 껍질이 활성탄소로서의 우수한 효과를 가진다는 점에 착안하여 건조 후에 락으로 사용시 과열처리한 활성탄소 만큼의 효과는 아니지만 오,폐수 정화용 락으로의 사용에 적합하다는 사실을 발견하여 본 발명을 완성하였다.However, in view of the fact that the coconut shell has an excellent effect as activated carbon in the present invention, it was found that the shell is suitable for use as a wastewater purification lock, although it is not as effective as the overheated activated carbon when used as a lock after drying. The present invention has been completed.

특히, 합성섬유사로 제조된 락과 비교시 물이 우유빛과 같이 혼탁해지는 경우가 훨씬 적었으며, 물에서 냄새가 나는 경우도 현저히 감소할 뿐만 아니라 유기물이 물위에 떠 다니거나 수조에 거품이 생기는 현상의 발생 빈도가 현격히 감소되었는 바, 이는 코코넛 껍질 자체에서 여과 및 탈취 등의 작용이 이루어지는 것으로 추정된다.In particular, compared to the lock made of synthetic fiber yarn, water is much less turbid, like milky color, and the smell of water is significantly reduced, and organic matter floats on the water or bubbles occur in the tank. The incidence of P is significantly reduced, which is estimated to be the effect of filtration and deodorization on the coconut shell itself.

뿐만 아니라, 코코넛 껍질은 천연의 식물성 섬유이므로 미생물과의 친화력이 뛰어나 합성섬유로 이루어진 락과 비교시 미생물의 활성이 우수하였다.In addition, since coconut shell is a natural vegetable fiber, it has excellent affinity with microorganisms, and thus, the activity of microorganisms is excellent when compared to rock made of synthetic fibers.

먼저, 코코넛 껍질을 수거하여 섬유 형상이 아닌 각질 부분과 각종 이물질을제거하고, 완전히 자연 건조시킨 다음, 5 ∼ 10㎝의 크기로 절단한다. 그러나, 완전 건조된 코코넛 껍질은 단단하여 절단이 용이하지 못하므로 절단과 건조 공정은 바꾸어 행할 수도 있다.First, the coconut shell is collected to remove the keratinous portion and various foreign matters that are not fibrous, completely dried and then cut into a size of 5 to 10 cm. However, the completely dried coconut husk is hard and not easy to cut, so the cutting and drying process may be altered.

코코넛 껍질의 절단시 5㎝ 미만의 크기로 절단할 경우에는 코코넛 껍질을 적층체로 제조하기가 용이하지 못한 단점이 있고, 10㎝를 초과할 경우에는 미립자의 흡착이나 부유물의 여과 효율이 저하되는 문제점이 발생한다.When cutting the coconut shell to a size of less than 5cm it is not easy to manufacture a coconut shell into a laminate, if it exceeds 10cm there is a problem that the adsorption of fine particles or filtration efficiency of the suspended matter deteriorated Occurs.

절단된 코코넛 껍질을 1㎡당 0.5 ∼ 2㎏의 양으로 적층한다.The cut coconut shells are laminated in an amount of 0.5 to 2 kg per 1 m 2.

이 때 코코넛 껍질의 사용량이 1㎡당 0.5㎏ 미만일 경우에는 제조되는 적층체의 두께가 얇아 여과, 흡착, 미생물막의 형성 정도가 미약하여 전체적으로 오,폐수 정화 효율이 저하되며, 2㎏을 초과할 경우에는 초가 상승효과가 미약하여 경제적이지 못하다.At this time, if the amount of coconut shell used is less than 0.5 kg per 1㎡, the thickness of the laminate produced is thin, so that the degree of filtration, adsorption, and microbial film formation is weak, and the overall efficiency of wastewater purification is lowered. There is a weak initial price synergistic effect, which is not economical.

적층체를 1㎡당 1,000 ∼ 5,000㎏의 압력으로 압착한다.The laminate is pressed at a pressure of 1,000 to 5,000 kg per m 2.

별도로, 접착제 40 ∼ 65중량%, 활성탄 20 ∼ 45중량%, 바이오 세라믹 15 ∼ 40중량%로 구성되며, 전체 혼합물 중량에 대하여 10중량%의 희석제를 첨가한 혼합물을 제조한 후, 적층체의 양면에 코코넛 껍질 중량에 대하여 40 ∼ 50중량%가 되도록 분무한다.Separately, the adhesive was composed of 40 to 65% by weight, activated carbon 20 to 45% by weight, bio-ceramic 15 to 40% by weight, and after preparing a mixture in which 10% by weight of the diluent was added to the total mixture weight, both sides of the laminate were prepared. Spray to 40 to 50% by weight based on the weight of the coconut shell.

본 발명에서 접착제는 특별히 한정되는 것은 아니지만, 오공본드(주)의 701SP(제품명)을 사용하였다.Although the adhesive agent is not specifically limited in this invention, The 701SP (product name) of Ogong Bond Co., Ltd. was used.

접착제의 사용량은 활성탄, 바이오 세라믹 및 접착제로 구성되는 혼합물 전체 중량에 대하여 40 ∼ 65중량%를 사용하는 것이 바람직하며, 접착제의 사용량이 40중량% 미만일 경우에는 코코넛 껍질들의 접착이 용이하지 못하여 적층체로서의 제조가 어렵고, 65중량%를 초과할 경우에는 적층체의 공극율이 저하되어 여과율이 좋지 않으며, 상대적으로 활성탄, 바이오 세라믹의 사용량이 감소하여 탈취 효과가 저하되는 단점이 있다.The amount of the adhesive is preferably 40 to 65% by weight based on the total weight of the mixture composed of activated carbon, bio-ceramic and adhesive, and when the amount of the adhesive is less than 40% by weight, the adhesion of the coconut shells is not easy. It is difficult to manufacture as, and if it exceeds 65% by weight, the porosity of the laminate is lowered, the filtration rate is not good, and there is a disadvantage that the amount of activated carbon, bio-ceramic is relatively reduced and the deodorizing effect is lowered.

활성탄, 바이오 세라믹은 락에 흡착 및 부착되어 서식하는 미생물의 활동성과 번식을 활성화시킬 뿐만 아니라 탈취의 효과를 얻을 수 있도록 함과 동시에 코코넛 껍질의 부패나 변성을 방지하는 역할을 한다.Activated carbon and bio-ceramic are adsorbed and attached to the rock to activate the activity and reproduction of the inhabiting microorganisms as well as to obtain the effect of deodorization and serves to prevent the decay and degeneration of the coconut shell.

활성탄은 탄소로 구성된 물질(목재, 야자각, 갈탄, 역청탄 등의 탄화물)을 고도의 활성화에 의하여 미세공이 잘 발달되도록 한 것으로서 활성화 과정에서 발달된 무수한 미세공간의 통로로 연결된 넓은 내부 표면적을 갖게 되어 탈색, 탈취, 용제 회수 유해가스제거 등 다양한 용도로 사용되며, 본 발명에서는 유기물의 여과, 탈색, 탈취 등의 효과를 나타낸다.Activated carbon is a material that is made of carbon (carbide such as wood, coconut shell, lignite, bituminous coal) so that the micropores are well developed by high activation, and has a large internal surface area connected to the path of countless microspaces developed during the activation process. Used for various purposes such as decolorization, deodorization, removal of solvent recovery harmful gases, the present invention exhibits the effects of filtration, decolorization, deodorization of organic matter.

활성탄의 사용량은 접착제, 바이오 세라믹 및 활성탄으로 구성되는 혼합물 전체 중량에 대하여 20 ∼ 45중량%를 사용하는 것이 바람직하며, 활성탄의 사용량이 20중량% 미만일 경우에는 유기물의 여과, 탈색, 탈취 효과가 미약한 단점이 있고, 45%를 초과할 경우에는 락의 표면으로부터 활성탄이 탈리되는 경향이 높아 활성탄의 사용으로 인한 효과의 내구성이 저하되며, 활성탄 자체가 오염원으로 작용하는 등의 문제점이 있다.The amount of activated carbon is preferably used in an amount of 20 to 45% by weight based on the total weight of the mixture composed of the adhesive, the bio-ceramic and the activated carbon. When the amount of the activated carbon is less than 20% by weight, the effect of filtration, decolorization, and deodorization of organic matter is weak. One disadvantage is that if it exceeds 45%, the activated carbon is more likely to be detached from the surface of the lock, and thus the durability of the effect due to the use of activated carbon is lowered, and the activated carbon itself acts as a pollution source.

바이오 세라믹은 무기물질을 사용하는 산화물(Oxide), 질화물(Nitride), 탄화물(Carbide) 등의 재료로 일반적으로 금속재료, 유기재료에 비하여 내식성, 내열성, 내마모성 등이 매우 크며, 전자기적 기능, 기계적 기능, 광학적 기능, 생체적 기능 등의 다양한 기능을 갖고, 본 발명에서는 코코넛 껍질의 내식성을 향상시키고, 바이오 세라믹에서 방출되는 원적외선에 의하여 미생물의 활동과 번식을 활성화시키는 역할을 한다.Bio ceramics are inorganic materials such as oxides, nitrides, carbides, etc., and generally have much higher corrosion resistance, heat resistance, and abrasion resistance than metal materials and organic materials. It has a variety of functions, such as function, optical function, biological function, in the present invention improves the corrosion resistance of the coconut shell, and serves to activate the activity and reproduction of microorganisms by far-infrared rays emitted from the bio-ceramic.

바이오 세라믹의 사용량은 접착제, 활성탄 및 바이오 세라믹으로 구성되는 혼합물 전체 중량에 대하여 15 ∼ 40중량%를 사용하는 것이 바람직하며, 바이오 세라믹의 사용량이 15중량% 미만일 경우에는 코코넛 껍질의 내식성이 저하되고, 바이오 세라믹에서 방출되는 원적외선에 의한 미생물의 활동과 번식에 효과를 나타내지 못하는 단점이 있으며, 40%를 초과할 경우에는 첨가 상승 효과가 미약하여 경제적이지 못하고, 코코넛 껍질로부터 탈리되어 침전물을 형성할 수도 있다.The amount of the bio-ceramic is preferably used in an amount of 15 to 40% by weight based on the total weight of the mixture composed of the adhesive, the activated carbon, and the bio-ceramic. When the amount of the bio-ceramic is less than 15% by weight, the corrosion resistance of the coconut shell is deteriorated. There is a disadvantage in that it does not show an effect on the activity and reproduction of microorganisms by far-infrared rays emitted from bio-ceramic. If it exceeds 40%, the synergistic effect of addition is weak, and it is not economical, and it may detach from coconut shell and form a precipitate. .

접착제, 바이오 세라믹 및 활성탄의 혼합은 본 발명이 속하는 기술 분야에서 통상적으로 사용되는 희석제를 접착제, 바이오 세라믹 및 활성탄의 전체 중량에 대하여 10 ∼ 30% 첨가하여 혼합하며, 혼합 방법은 본 발명이 속하는 기술 분야에서 통상적으로 사용되는 방법들을 모두 사용할 수 있으나, 본 발명에서는 고형물 즉, 바이오 세라믹 및 활성탄을 먼저 교반기에 투입하여 균질하게 혼합시킨 다음, 희석제와 접착제를 투입하고 교반하여 혼합물을 제조한다.Mixing of the adhesive, bio-ceramic and activated carbon is a diluent commonly used in the technical field to which the present invention belongs, 10 to 30% of the total weight of the adhesive, bio-ceramic and activated carbon is added and mixed, and the mixing method is a technique to which the present invention belongs Although all methods commonly used in the art may be used, in the present invention, the solids, that is, the bio-ceramic and the activated carbon, are first mixed in a stirrer to homogeneously mix, and then a diluent and an adhesive are added and stirred to prepare a mixture.

상기와 같이 혼합물을 제조하여 코코넛 껍질 적층물의 양면에 분무한 다음, 2일간 자연건조시킴으로서 본 발명의 오,폐수 정화용 식물성 섬유재 락의 제조가 완료된다.By preparing a mixture as described above, sprayed on both sides of the coconut shell laminate, and then air-dried for two days to complete the manufacture of the vegetable fiber rock for purification of wastewater of the present invention.

상술한 바와 같이 본 발명에서는 본 발명에서는 락의 재료로서 전처리가 거의 필요없고 합성섬유와 같이 가느다란 섬유 형상을 갖는 코코넛의 껍질을 사용하되 코코넛 껍질을 건조하여 일정 길이로 절단한 후, 코코넛 껍질을 단위 면적당 0.5 ∼ 2㎏의 양으로 적층하고 압착한 다음, 이물질을 흡착하는 활성탄과, 원적외선을 방사하여 미생물의 활동력을 활성화하는 바이오 세라믹 및 상기 활성탄과 바이오 세라믹을 코코넛 껍질에 부착시키기 위한 접착제를 적당한 비율로 혼합한 것을 적층된 코코넛 껍질의 양면에 분무하여 골고루 분포되도록 하고 건조하여 락을 제조하므로서 천연의 식물 섬유 사용으로 인한 미생물과의 친화력이 뛰어나 유기물을 산화분해 및 환원시키는 미생물의 서식에 아주 적합하며, 폐기시에 환경 오염을 유발하지 않고, 수중에서의 풀림이나 처짐이 발생되지 않으며, 공극율이 크고, 미생물의 번식 및 활동력을 활성화시켜 보다 효율적인 오,폐수 처리가 가능하고, 분해되거나 변질될 위험이 거의 없어 장시간 사용할 수 있어 유지 비용이 저렴한 오,폐수 정화용 식물성 섬유재 락을 얻을 수가 있었다.As described above, in the present invention, pretreatment is hardly required as the material of the lock, and the coconut shell is dried after cutting to a certain length by drying the coconut shell using a thin shell of fiber having a thin fiber shape such as synthetic fibers. Laminated and compressed in an amount of 0.5 to 2 kg per unit area, and activated carbon that adsorbs foreign substances, bio-ceramic for activating microbial activity by radiating far infrared rays, and adhesive for attaching the activated carbon and bio-ceramic to coconut shell are suitable. It is very suitable for incubating microorganisms which oxidize and reduce organic matters because it has excellent affinity with microorganisms due to the use of natural plant fiber by spraying the mixture in proportion to the laminated coconut shells so that it is evenly distributed and dried to produce rock. Underwater, without causing environmental pollution during disposal It does not cause loosening or sagging, and has a high porosity, and enables more efficient waste and wastewater treatment by activating the propagation and activity of microorganisms, and it can be used for a long time because there is little risk of decomposition or deterioration. Vegetable fiber locks for wastewater purification were obtained.

Claims (2)

1㎡당 코코넛 껍질을 0.5 ∼ 2㎏의 양으로 적층하고 압착한 후, 접착제 40 ∼ 65중량%, 활성탄 20 ∼ 45중량%, 바이오 세라믹 15 ∼ 40중량%로 구성되는 혼합물이 코코넛 껍질 중량에 대하여 40 ∼ 50중량%가 되도록 압착된 적층체의 양면에 분무하고 자연 건조한 것을 특징으로 하는 오,폐수 정화용 식물성 섬유재 락.After laminating and pressing coconut shell per 1 m 2 in an amount of 0.5 to 2 kg, the mixture consisting of 40 to 65% by weight of adhesive, 20 to 45% by weight of activated carbon, and 15 to 40% by weight of bio-ceramic is based on the weight of coconut shell. A vegetable fiber material rock for purification of wastewater, characterized in that it is sprayed on both sides of the laminated body compressed to 40 to 50% by weight and dried naturally. 코코넛 껍질을 정선하고, 건조한 후에 5 ∼ 10㎝의 크기로 절단하는 가공 단계; 코코넛 껍질을 1㎡당 0.5 ∼ 2㎏의 양으로 적층하는 단계; 적층이 완료된 후에 1㎡당 1,000 ∼ 5,000㎏의 압력으로 적층물을 압착하는 단계; 별도로 접착제 40 ∼ 65중량%, 활성탄 20 ∼ 45중량%, 바이오 세라믹 15 ∼ 40중량%로 구성되며, 전체 혼합물 중량에 대하여 10중량%의 희석제를 첨가한 혼합물을 제조하는 단계; 상기 혼합물이 코코넛 껍질 중량에 대하여 40 ∼ 50중량%이 되도록 압착된 코코넛 껍질 적층체의 양면에 골고루 분무하는 단계; 2일 동안 자연 건조시키는 단계로 구성되는 것을 특징으로 하는 오,폐수 정화용 식물성 섬유재 락의 제조방법.Selecting a coconut shell and drying the cut to a size of 5 to 10 cm; Stacking coconut shells in an amount of 0.5 to 2 kg per m 2; Compressing the laminate at a pressure of 1,000 to 5,000 kg per m 2 after lamination is completed; Separately preparing a mixture comprising 40 to 65% by weight of adhesive, 20 to 45% by weight of activated carbon, and 15 to 40% by weight of bio-ceramic and adding 10% by weight of diluent based on the total weight of the mixture; Spraying evenly on both sides of the compressed coconut shell laminate such that the mixture is 40-50% by weight relative to the weight of the coconut shell; Method for producing a vegetable fiber rock for purification of waste water, characterized in that consisting of two steps of natural drying.
KR10-2001-0032312A 2001-06-09 2001-06-09 Lock of vegetable fiber for purification of the polluted water and waste water KR100403782B1 (en)

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KR100460748B1 (en) * 2001-12-27 2004-12-09 주식회사 대마 Absorbent Using By-product of Coir Fiber from Husk of Coconut Palm and Absorbing Method for Cohesive Waste Water Using the Same

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KR20010102871A (en) * 2001-09-12 2001-11-17 (주)삼원엔바이로 Media Made of Coconut Fibers for Microorganism for Treating Polluted or Waste Water and Method for Treating the Water using the same
KR100460748B1 (en) * 2001-12-27 2004-12-09 주식회사 대마 Absorbent Using By-product of Coir Fiber from Husk of Coconut Palm and Absorbing Method for Cohesive Waste Water Using the Same

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