KR20010068148A - A toothpaste having silver solution - Google Patents

A toothpaste having silver solution Download PDF

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KR20010068148A
KR20010068148A KR1020010023198A KR20010023198A KR20010068148A KR 20010068148 A KR20010068148 A KR 20010068148A KR 1020010023198 A KR1020010023198 A KR 1020010023198A KR 20010023198 A KR20010023198 A KR 20010023198A KR 20010068148 A KR20010068148 A KR 20010068148A
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silver
toothpaste
solution
colloidal
silver solution
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KR1020010023198A
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Korean (ko)
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김정일
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김정일
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/413Nanosized, i.e. having sizes below 100 nm

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE: Provided is a toothpaste containing colloidal silver which inflicts no harm on the health of people and shows effective anti-bacterial effects, and contributing to healthy teeth. CONSTITUTION: The toothpaste contains colloidal silver whose silver ions are dissolved in distilled water. Silver particles in the colloidal solution have the particle size of between 0.001μm and 0.02μm. And abrasives include dicalcium phosphate dihydrate, calcium carbonate etc. Binding agents are carboxy methyl cellulose sodium, carrageenan, xanthan gum, and polyacrylic acid and base. Wetting agents are selected form sorbitol solution, glycerin, polyethylene glycol, and propylene glycol. Alkyl sodium sulfate, anion surfactant, is used as a frothing agent.

Description

은용액 함유 치약{A toothpaste having silver solution}A toothpaste having silver solution

본 발명은 치약에 관한 것으로 특히 용액상태의 은용액을 크림상의 치약이나 액상의 치약에 첨가하여 인체에 무해하면서도 뛰어난 살균 및 항균효과를 제공하는 은용액 함유 치약에 관한 것이다.The present invention relates to toothpaste, and more particularly, to a silver solution-containing toothpaste which provides excellent sterilization and antibacterial effect while being harmless to human body by adding a solution-like silver solution to a toothpaste of a cream or liquid.

이러한 치약은 기제(基劑)와 습윤제·결합제·기포제·향료·색소 및 약효제 등이 조금씩 혼합되어 있다.Such toothpaste is mixed with a base, a humectant, a binder, a foaming agent, a flavoring agent, a pigment, and a medicinal agent little by little.

상기 기제(연마제)는 치약의 주된 용도인 치아의 기계적 청소를 위한 것으로 일정한 크기를 갖는 입자형태를 사용하되, 치아의 표면을 손상시키지 않도록 그 입자의 크기,경도 및 모양이 적당해야 한다. 또한 형태는 너무 예민하지 않아야 하며, 모스경도 3도 정도의 것이 적당하다.The base (polishing agent) is intended for the mechanical cleaning of the tooth, which is the main use of toothpaste, use a particle form having a certain size, the size, hardness and shape of the particle should be appropriate so as not to damage the surface of the tooth. Also, the shape should not be too sensitive, Mohs hardness 3 degrees is appropriate.

근래, 치약의 기능으로서 이러한 치아의 기계적 청소 외에도 구강내 청량감 제공이나, 치석제거도 요구되고 있으며, 특히 근래에는 구강 내의 세균 증식에 따른 각종 질환이 문제로 되고 있으며, 이에 따라 치약의 살균소독작용이 중요한 요소로 대두되고 있다.Recently, in addition to the mechanical cleaning of the teeth as a function of toothpaste, it is also required to provide a refreshing feeling in the oral cavity and removal of calculus. It is emerging as an important factor.

이러한 필요성으로 인하여 치약에 살균소독제를 첨가하는 경우가 많아지고 있으며, 이러한 살균소독제로는 파라히드록시벤조네이트, 클로르헥시딘, 히노키티올 및 프로타인 등이 일부 사용되고 있다.Due to this necessity, a disinfectant disinfectant is often added to toothpaste, and some of the disinfectant disinfectants include parahydroxybenzoate, chlorhexidine, hinokthiol, and protein.

그러나, 상기와 같은 살균소독제는 독성이 있고, 안정성에 있어서 문제가 있으며, 불쾌한 미각을 갖게 하므로 그 사용에 문제점이 많은 실정이다.However, such disinfectant disinfectant is toxic, there is a problem in stability, and has an unpleasant taste so there is a lot of problems in its use.

또한 이러한 종래의 치약에 사용되는 살균소독제는 반응성이 강하여 장기간 사용하기 곤란하다는 문제점이 있었다.In addition, the disinfectant disinfectant used in the conventional toothpaste has a problem that it is difficult to use for a long time due to the strong reactivity.

본 발명은 상기와 같은 종래의 치약이 갖고있는 문제점을 해결하기 위해서 안출한 것으로서, 특히 인체에 독성이 없으면서도 뛰어난 살균효과를 갖는 첨가물을 포함하여 기능성을 제고할 수 있는 치약의 제공을 그 목적으로 한다.The present invention has been made to solve the problems of the conventional toothpaste as described above, in particular, to provide a toothpaste that can enhance the functionality, including additives having excellent sterilization effect without being toxic to the human body. do.

이러한 목적은 은용액을 첨가하여 살균효과를 제고하면서도 인체에 무해한 본 발명에 의해서 달성될 수 있는 바, 이하 상세히 설명한다.This object can be achieved by the present invention harmless to the human body while improving the sterilization effect by adding a silver solution, will be described in detail below.

본 발명은 치약의 조성물 중에 인체에 유해성이 우려되는 기존의 살균제 대신 인체에 전혀 무해하면서도 뛰어난 살균효과를 갖는 은용액을 포함하도록 한 것이다.The present invention is intended to include a silver solution having excellent antiseptic effect while being completely harmless to the human body instead of the conventional fungicides that are harmful to the human body in the composition of the toothpaste.

요즘 건강에 대한 관심이 높아지면서 건강을 위한 은용액의 사용이 증대되고 있다. 상기 은용액은 은이온을 함유한 이온용액 또는 콜로이드형태의 용액으로서 은의 전기분해로써 생성한다.With increasing interest in health these days, the use of silver solutions for health is increasing. The silver solution is produced by the electrolysis of silver as an ionic solution or colloidal solution containing silver ions.

은(銀)은 옛부터 자연항생제로 사용하였으며, 수용액상태의 은용액을 만들어 음용하기도 하였다. 또한 근래에는 은의 항균효과가 밝혀지면서 다양한 실험과 함께 그 적용분야를 넓혀가고 있는 실정이다.Silver (銀) has been used as a natural antibiotic since ancient times, and made silver solution in the form of aqueous solution for drinking. In addition, as the antimicrobial effect of silver is revealed in recent years, the field of application is being expanded with various experiments.

은은 원소기호 Ag, 원자번호 47, 원자량 107.868, 녹는점 961.9℃, 끓는점 2212℃, 비중 10.49(20℃)로서 열과 전기의 전도성이 금속 중 최대이다.Silver has the element symbol Ag, atomic number 47, atomic weight 107.868, melting point 961.9 ° C, boiling point 2212 ° C, specific gravity 10.49 (20 ° C), and the conductivity of heat and electricity is the largest among metals.

이러한 은은 은이온에 의한 항균작용과 활성산소에 의한 항균작용으로 균의 물질대사를 방해하여 균을 질식시킨다는 학계의 보고가 있다. 이는 은이온의 전기적 부하가 병균의 생식기능을 제거하며, 세포구조를 파괴함에 따른 것으로 밝혀졌다.There is a report from the academic community that the silver suffocates the bacteria by interfering with the metabolism of the bacteria by the antibacterial action of silver ions and antibacterial action of free radicals. It was found that the electrical load of silver ions eliminates germ function and destroys cell structure.

또한 산화은(Ag2O)의 형태로 은에 결합하고 있는 산소는 은이온의 촉매작용에 의하여 부분적으로 활성산소로 전환하고, 활성산소는 강력한 살균작용을 한다.In addition, oxygen bound to silver in the form of silver oxide (Ag 2 O) is partially converted into active oxygen by the catalytic action of silver ions, and active oxygen has a strong sterilization effect.

또한 은이온은 쉽게 인체에 흡수되어 박테리아나 균류 등이 산소대사를 할 때 효소의 기능을 막으면서, 강력한 촉매역할을 하여 이들 병원체들을 살상하는 작용을 하는 것으로 알려져 있다.In addition, silver ions are easily absorbed by the human body to prevent the function of enzymes when bacteria and fungi metabolize oxygen, and are known to act as a powerful catalyst to kill these pathogens.

이러한 은이온 또는 은입자는 특히 인체에 해가 없다는 점에서 그 활용도가 증대될 것으로 기대된다.Such silver ions or silver particles are expected to increase their utilization, in particular because they are not harmful to the human body.

본 발명은 이러한 항균력을 갖는 은용액을 치약에 첨가하여 구강내의 항균작용을 증대시키도록 한 것이다.The present invention is to increase the antibacterial action in the oral cavity by adding a silver solution having such antimicrobial power to toothpaste.

치약에 첨가시키기 위해서 사용되는 은용액(silver solution)은 은이온 또는 은입자가 포함된 것이며, 은입자의 크기는 잇몸과 치아에 손상을 주지 않을 정도의 크기를 갖는 극미립자 형태의 것이 바람직 하며, 증류수와 같은 용매에 은이온(Ag+) 상태로만 포함된 은용액을 사용할 수 있으며, 또는 극미립자 형태의 은입자를 갖는 콜로이드용액형태의 은용액(은입자를 갖는 콜로이드용액은 은입자 외에도 은이온을 포함할 수 있는 것이며, 이와 같이 은입자와 은이온을 모두 포함하는 것 또한 통칭하여 은입자의 콜로이드용액 또는 콜로이드용액형태의 은용액 또는 은입자를 갖는 콜로이드용액이라 한다. 이하 같다.)을 사용할 수 있다.The silver solution used to add to the toothpaste is silver ions or silver particles, and the size of the silver particles is preferably in the form of micro particles having a size that does not damage the gums and teeth, A silver solution containing only silver ions (Ag + ) in a solvent such as distilled water may be used, or a colloidal solution in the form of a colloidal solution having silver particles in the form of microparticles. The silver particles and the silver ions are also collectively referred to as a colloidal solution of silver particles or a colloidal solution having silver particles or silver particles in the form of a colloidal solution. Can be.

상기 콜로이드용액형태의 은용액을 사용할 경우는 잇몸과 치아의 손상을 방지하기 위해 그 입자크기가 0.02㎛를 넘지 않도록 하는 것이 중요하다. 바람직하게는 0.001㎛~0.02㎛가 적당하다.When using the colloidal solution in the form of a silver solution, it is important that the particle size does not exceed 0.02㎛ in order to prevent damage to the gums and teeth. Preferably 0.001 micrometer-0.02 micrometer are suitable.

콜로이드용액 형태의 은용액(colloidal silver)은 혐수성(嫌水性)으로 전해질이 조금만 가해져도 침전되므로 증류수에 은을 전기분해하여 얻는다. 분해량에 따라 이온형태의 은용액 또는 콜로이드용액형태의 은용액을 얻을 수 있다.Colloidal silver in the form of a colloidal solution (colloidal silver) is hydrophobic (嫌 水性) is obtained by the electrolysis of silver in distilled water, because a small amount of electrolyte is precipitated. Depending on the amount of decomposition, silver solutions in the form of ions or silver solutions in the form of colloidal solutions can be obtained.

상기와 같은 은용액을 종래의 크림상의 치약 또는 액상의 치약에 첨가하여 사용할 수 있으며, 이 경우는 종래에 첨가되던 살균제 또는 항균제는 첨가하지 않는다.The silver solution as described above may be used in addition to a conventional toothpaste or a liquid toothpaste, in this case, conventionally added fungicides or antibacterial agents are not added.

일반적으로 크림형 치약을 구성하는 통상적인 조성물은 하기와 같다.In general, the conventional composition constituting the cream toothpaste is as follows.

먼저, 기제(연마제)로서 인산일수소칼슘, 함수실리카, 탄산칼슘, 함수알루미나등이 사용된다.First, calcium monohydrogen phosphate, hydrous silica, calcium carbonate, hydrous alumina and the like are used as the base (polishing agent).

이들 중의 하나 또는 다수개를 혼합하여 사용할 수 있다.One or more of these can be mixed and used.

또한 결합제로는 카르복시메틸셀룰로오스 나트륨, 카라기난, 잔탄검, 폴리아크릴산염 등이 일반적으로 많이 사용되며, 이들 중 어느 하나를 단독으로 첨가하거나 다종을 혼합하여 사용할 수 있다.In addition, as the binder, carboxymethyl cellulose sodium, carrageenan, xanthan gum, polyacrylate, and the like are generally used, and any one of them may be added alone or mixed.

습윤제로는 소르비톨액, 글리세린, 폴리에틸렌글리콜, 프로필렌글리콜 등의 다가알코올류를 단독 또는 혼합하여 사용할 수 있다.As the humectant, polyhydric alcohols such as sorbitol liquid, glycerin, polyethylene glycol, and propylene glycol can be used alone or in combination.

기포제로는 음이온계면활성제인 알킬황산나트륨이 대표적으로 사용되며, 비이온성 계면활성제도 많이 사용되고 있다.As the foaming agent, sodium alkyl sulfate, an anionic surfactant, is typically used, and nonionic surfactants are also widely used.

이 외에도 향료와 감미제가 첨가되며, 여기에 약효제를 첨가하기도 한다.In addition, flavors and sweeteners are added, and the drug may be added to it.

본 발명은 상기와 같은 조성물에 은용액(이온상의 은용액 또는 콜로이드상의 콜로이드용액)을 첨가하여 치약을 조성한 것이다.In the present invention, a toothpaste is prepared by adding a silver solution (an ionic silver solution or a colloidal colloidal solution) to the above composition.

상기와 같이 은용액을 첨가할 경우 별도의 방부제나 살균제를 첨가할 필요가 없다.When the silver solution is added as described above, there is no need to add a separate preservative or fungicide.

상기와 같은 치약은 통상적으로는 크림상의 치약으로 형성되지만 저점도의 액상의 치약에도 적용될 수 있다.Toothpaste is typically formed as a cream toothpaste, but can also be applied to low-viscosity liquid toothpaste.

상기에서와 같이 본 발명은 기존의 치약에 사용되는 방부제나 살균제 대신 은용액을 첨가함으로써, 인체에 전혀 해가 없으면서도 뛰어난 살균효과 및 항균효과를 제공하여, 구강의 청결과 위생에 크게 기여하게 된다.As described above, the present invention adds a silver solution instead of a preservative or a disinfectant used in the existing toothpaste, providing excellent sterilization and antimicrobial effects without any harm to the human body, thereby greatly contributing to the cleanliness and hygiene of the oral cavity. .

Claims (4)

기제(基劑)와 기포제를 포함하여서 조성된 치약에 있어서;Toothpaste comprising a base and a foaming agent; 은용액을 첨가하여 조성되는 것을 특징으로 하는 은용액 함유 치약.A silver solution-containing toothpaste, which is formed by adding a silver solution. 제1항에 있어서;The method of claim 1; 상기 은용액은 은이온이 증류수에 용해되어 있는 것을 특징으로 하는 은용액 함유 치약.The silver solution is a silver solution-containing toothpaste, characterized in that silver ions are dissolved in distilled water. 제1항에 있어서;The method of claim 1; 상기 은용액은 은입자의 콜로이드용액인 것을 특징으로 하는 은용액 함유 치약.The silver solution is a silver solution-containing toothpaste, characterized in that the colloidal solution of the silver particles. 제3항에 있어서;The method of claim 3; 상기 콜로이드용액에 포함된 은입자의 크기는 0.001㎛~0.02㎛인 것을 특징으로 하는 은용액 함유 치약.The silver solution-containing toothpaste, characterized in that the size of the silver particles contained in the colloidal solution is 0.001㎛ ~ 0.02㎛.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020068491A (en) * 2002-08-10 2002-08-27 배병철 Gel Silver Solution Toothpaste
CN111920758A (en) * 2020-09-23 2020-11-13 山东本真化妆品有限公司 A foamable oral care composition free of surfactants

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KR20020068491A (en) * 2002-08-10 2002-08-27 배병철 Gel Silver Solution Toothpaste
CN111920758A (en) * 2020-09-23 2020-11-13 山东本真化妆品有限公司 A foamable oral care composition free of surfactants
CN111920758B (en) * 2020-09-23 2022-10-14 山东本真化妆品有限公司 A foamable oral care composition free of surfactants

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