KR20010068142A - Apparatus for producing strong-acidic water and mild-basic water - Google Patents

Apparatus for producing strong-acidic water and mild-basic water Download PDF

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KR20010068142A
KR20010068142A KR1020010023103A KR20010023103A KR20010068142A KR 20010068142 A KR20010068142 A KR 20010068142A KR 1020010023103 A KR1020010023103 A KR 1020010023103A KR 20010023103 A KR20010023103 A KR 20010023103A KR 20010068142 A KR20010068142 A KR 20010068142A
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water
chamber
cathode chamber
line
weak alkaline
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KR100405144B1 (en
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황근우
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4618Supplying or removing reactants or electrolyte
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

PURPOSE: A production equipment of strong acidic water and weak alkaline water is provided, which can produce strong acidic water that is used for sterilizing water and can produce weak alkaline water that is sterilized by a sterilizer and is used as drinking water for human and anima. CONSTITUTION: The system comprises the followings: (i) an electrolytic cell (20) which is partitioned into a cathode chamber (26) that contains a cathode plate and an anode chamber (24) that contains an anode plate by a partition wall; (ii) a cathode chamber (26) into which raw water to which no electrolyte is added is fed for producing weak alkaline water and for sterilizing; (iii) an anode chamber (24) into which raw water to which electrolyte is added is fed for producing strong acidic water; (iv) an electrolyte supplying device for supplying electrolyte to raw water; (v) an anode chamber discharge line (44); (vi) a cathode chamber discharge line (46); and (vii) a sterilizing device(64).

Description

강산성수-약알칼리수 생성장치{APPARATUS FOR PRODUCING STRONG-ACIDIC WATER AND MILD-BASIC WATER}Strong acid water-alkaline water generator {APPARATUS FOR PRODUCING STRONG-ACIDIC WATER AND MILD-BASIC WATER}

본 발명은 원수를 전해하여 강산성수와 약알칼리수를 생성하는 강산성수-약알칼리수 생성장치에 관한 것으로서, 보다 상세하게는 양극실에 인입되는 원수에는 전해질을 가미하여 강산성수를 생성하고, 음극실에 인입되는 원수에는 전해질을 가미하지 않으므로써 약알칼리수를 생성하되, 음극실인입라인, 음극실, 음극실인출라인 중 어느하나 또는 둘 이상에 살균장치를 부착하여 약알칼리수가 살균되도록 하는 강산성수-약알칼리수 생성장치에 관한 것이다.The present invention relates to a strong acid water-weak alkaline water generating device that electrolyzes raw water to produce strong acidic water and weakly alkaline water, and more particularly, raw water introduced into the anode chamber is added to the electrolyte to generate strong acidic water, and raw water introduced into the cathode chamber. In the strong acidic water- weak alkaline water generating device to generate weak alkaline water without adding an electrolyte, but attaching a sterilizer to one or more of the cathode chamber inlet line, the cathode chamber, and the cathode chamber outlet line to sterilize the weak alkaline water. It is about.

대부분의 전해수 생성장치에 대한 연구는 주로 강산성수, 강알칼리수를 생성하는 장치에 관한 것이었다. 이러한 전해수 생성장치는 전해조 내에 격막을 가지고 있으며, 양극실과 음극실에 인입되는 원수에는 모두 전해질이 첨가되며, 전해조를 거쳐 강산성수와 강알카리수가 생성되도록 구성되어 있다.Most of the electrolyzed water generators have been studied for producing strong acidic water and strong alkaline water. The electrolyzed water generating apparatus has a diaphragm in the electrolytic cell, and the electrolyte is added to the raw water introduced into the anode chamber and the cathode chamber, and is configured to generate strong acidic water and strong alkaline water through the electrolytic cell.

이중 대한민국 공개특허 제1999-210292호(출원번호 10-1995-039266)에는 양극실과 음극실의 사이에 중간실을 위치시키고, 양극실과 음극실의 인입라인에 별도의 전해질 첨가장치를 두어 생성되는 양극수와 음극수의 pH에 따라 첨가되는 전해질의 양을 조절하는 기술이 개시되어 있다.In Korean Unexamined Patent Application Publication No. 1999-210292 (Application No. 10-1995-039266), an intermediate chamber is positioned between a cathode chamber and a cathode chamber, and a cathode is formed by placing a separate electrolyte adding device in the inlet line of the anode chamber and the cathode chamber. A technique for controlling the amount of electrolyte added according to the pH of water and cathodic water is disclosed.

그러나, 상기의 종래기술은 생성되는 양극수와 음극수의 pH를 일정하게 유지하기 위한 목적일 뿐이므로, 양극수와 음극수를 모두 사용할 수 있는 강산성수와 약알칼리수를 생성하기 위해서는 불필요한 제어를 하여야 하며, 또한 불필요한 중간실을 가지고 있으므로 전해조의 크기가 기존의 것보다 크고 복잡한 문제점이 있었다.However, the above-described prior art is only for the purpose of maintaining a constant pH of the positive and negative water to be produced, so that unnecessary control must be performed to generate strong acidic and weak alkaline water that can use both positive and negative water. In addition, since there is an unnecessary intermediate chamber, the size of the electrolyzer was larger and more complicated than the conventional one.

또한 음극실에서 생성되는 약알칼리수에 포함된 세균등을 살균할 수 있는 방법을 제공하지 못하였다.In addition, it could not provide a method for sterilizing bacteria contained in the weak alkaline water produced in the cathode chamber.

본 발명은 상기와 같은 종래기술의 문제점을 해결하기 위한 것으로, 양극실에 인입되는 원수에만 전해질을 첨가하고 전해하여 강산성수와 약알칼리수를 생성하되, 상기 약알칼리수에는 자외선살균기 또는 오존발생기 등의 살균장치를 장착한강산성수-약알칼리수 생성장치를 제공하는 것을 목적으로 한다.The present invention is to solve the problems of the prior art as described above, by adding an electrolyte only to the raw water introduced into the anode chamber and electrolytically to generate a strong acidic water and weak alkaline water, the weak alkaline water sterilization apparatus such as ultraviolet sterilizer or ozone generator An object of the present invention is to provide a strong acidic water- weak alkaline water generating device.

도1은 본 발명에 따른 일실시예의 장치 개념도.1 is a conceptual diagram of an apparatus according to an embodiment of the present invention.

도2는 본 발명에 따른 다른 실시예의 장치 개념도.2 is a device conceptual diagram of another embodiment according to the present invention;

도3a 및 도3b는 도1 및 도2의 장치에 역전압을 인가할 때의 전압의 변화도.3A and 3B are diagrams showing changes in voltage when a reverse voltage is applied to the apparatus of FIGS. 1 and 2;

*** 도면의 주요부분에 대한 부호설명 ****** Explanation of main parts of drawing ***

10. 원수탱크 12. 펌프 14. 필터10. Raw water tank 12. Pump 14. Filter

16. 혼합조 20. 전해조 22. 다단전해조16. Mixing tank 20. Electrolyzer 22. Multistage electrolytic bath

24. 양극실 26. 음극실 28. 제2양극실24. Anode chamber 26. Cathode chamber 28. Second anode chamber

30. 제2음극실 40. 양극실인입라인 42. 음극실인입라인30. Second cathode chamber 40. Anode chamber introduction line 42. Cathode chamber introduction line

44. 양극실배출라인 46. 음극실배출라인 48. 양극실연결라인44. Anode chamber discharge line 46. Anode chamber discharge line 48. Anode chamber connection line

50. 음극실연결라인 60. 전해질탱크 62. 전해질펌프50. Cathode chamber connection line 60. Electrolyte tank 62. Electrolyte pump

64. 살균장치 66. 기체제거장치 70. 저수조64. Sterilizers 66. Degassers 70. Reservoirs

72. 강산성수탱크 74. 약알칼리수탱크72. Strong acid water tank 74. Alkaline alkaline water tank

본 발명에 의한 강산성수-약알칼리수 생성장치는,Strongly acidic water- weak alkaline water generating apparatus according to the present invention,

원수를 전해하여 강산성수와 약알칼리수를 생성하는 강산성수-약알칼리수 생성장치에 있어서,In the strong acid-weak alkaline water generating device which electrolyzes raw water to generate strong acidic water and weak alkaline water,

양극판을 내포하는 양극실과, 음극판을 내포하는 음극실과, 상기 양극실과 음극실을 양분하는 격막을 포함하는 전해조와; 상기 양극실에 원수를 인입시키는 양극실인입라인과; 상기 음극실에 원수를 인입시키는 음극실인입라인과; 상기 양극실인입라인의 소정의 위치에 부착되어 원수에 전해질을 공급하는 전해질공급수단과; 상기 양극실로부터 전해된 강산성수를 인출시키는 양극실인출라인과; 상기 음극실로부터 약알칼리수를 인출시키는 음극실인출라인과; 상기 음극실인입라인, 음극실, 음극실인출라인 중 어느하나 또는 둘 이상에 내포되어 세균을 살균하는 살균장치;를 갖는다.An electrolytic cell including a positive electrode chamber containing a positive electrode plate, a negative electrode chamber containing a negative electrode plate, and a diaphragm dividing the positive electrode chamber and the negative electrode chamber; A cathode chamber inlet line for introducing raw water into the anode chamber; A cathode chamber inlet line for introducing raw water into the cathode chamber; Electrolyte supply means attached to a predetermined position of the anode chamber inlet line to supply electrolyte to raw water; A cathode chamber drawing line for drawing strong acidic water electrolyzed from the anode chamber; A cathode chamber drawing line for drawing the weak alkaline water from the cathode chamber; And a sterilization apparatus embedded in any one or two or more of the cathode chamber introduction line, the cathode chamber, and the cathode chamber drawing line to sterilize bacteria.

상기 양극실인입라인 중 상기 전해질공급수단이 부착된 지점과 상기 양극실 사이에는, 원수와 전해질이 잘 혼합되도록 공간을 제공하는 혼합조가 추가로 개재되기도 하며,Between the point where the electrolyte supply means is attached and the anode chamber of the anode chamber inlet line, a mixing tank for providing a space to mix the raw water and the electrolyte is further interposed,

상기 살균장치는 자외선발생기, 오존발생기, 가열기, 자외선발생기-산화티타늄에 의한 살균기 중 어느 하나 또는 둘 이상인 것을 특징으로 하기도 하며,The sterilizer is characterized in that any one or two or more of the UV generator, ozone generator, heater, UV generator-titanium oxide sterilizer,

상기 전해조와 상기 양극실인출라인 및 음극실인출라인 사이에는 적어도 하나이상의 다단전해조가 추가로 장착되며, 상기 전해조와 상기 다단전해조 사이에는 양극실연결라인과 음극실연결라인이 개재되며, 상기 음극실연결라인의 중간에는 저수조가 장착되기도 하며,At least one multi-stage electrolyzer is additionally installed between the electrolyzer and the anode chamber lead-out line and the cathode chamber lead-out line, and an anode chamber connection line and a cathode chamber connection line are interposed between the electrolyzer and the multistage electrolysis tank, and the cathode chamber In the middle of the connection line is a reservoir,

상기 저수조에는 기체제거장치가 추가로 부착되기도 하며,The reservoir may be additionally attached to the degassing device,

상기 전해조와 상기 저수조 사이에는 전해질공급수단이 추가로 개재되기도 한다.An electrolyte supply means may be further interposed between the electrolytic cell and the reservoir.

이하 실시예를 통하여 본 발명을 상세하게 설명한다. 그러나, 이들 실시예는 예시적인 목적일 뿐 본 발명이 이에 한정되는 것은 아니다.The present invention will be described in detail through the following examples. However, these examples are for illustrative purposes only and the present invention is not limited thereto.

[실시예1]Example 1

도1은 본 발명에 따른 일실시예의 장치 개념도이다.1 is a conceptual diagram of an apparatus according to an embodiment of the present invention.

도1을 살펴보면, 본 발명에 따른 강산성수-약알칼리수 생성장치는 원수탱크(10)와 펌프(12)와 필터(14)와 혼합조(16)와 전해조(20)와 양극실(24)과 음극실(26)과 양극실인입라인(40)과 음극실인입라인(42)과 양극실배출라인(44)과 음극실배출라인(46)과 전해질탱크(60)와 전해질펌프(62)와 살균장치(64)와 강산성수탱크(72)와 약알칼리수탱크(74)와 이들을 연결하는 배관(40, 42, 44, 46을 제외한 배관으로 도면부호 미표시) 및 상기 배관에 부착된 밸브들(미도시)로 구성된다.Referring to Figure 1, the strong acid water- weak alkaline water generating apparatus according to the present invention is a raw water tank 10, a pump 12, a filter 14, a mixing tank 16, an electrolytic cell 20, an anode chamber 24 and a cathode Seal 26, anode chamber introduction line 40, cathode chamber introduction line 42, anode chamber discharge line 44, cathode chamber discharge line 46, electrolyte tank 60, electrolyte pump 62 and sterilization Apparatus 64, strong acid water tank 72, weak alkaline water tank 74 and pipes connecting them (not shown, except for pipes 40, 42, 44, 46) and valves (not shown) attached to the pipes It consists of.

상기 원수탱크(10)는 전해를 하려는 물(원수)을 저장하는 탱크이다. 상기 원수는 수돗물, 담수, 해수, 지하수 등을 사용할 수 있다.The raw water tank 10 is a tank for storing the water (raw water) to be electrolyzed. The raw water may be used tap water, fresh water, sea water, ground water.

상기 펌프(12)는 상기 원수탱크(10)의 원수를 이송하는 장치이다. 상기 펌프(12)는 정량펌프인 것이 바람직하다.The pump 12 is a device for transferring the raw water of the raw water tank (10). The pump 12 is preferably a metering pump.

상기 펌프(12)를 통과한 원수는 필터(14)를 경유한다. 상기 필터(14)는 원수에 포함된 각종 이온이나 불순물들을 여과한다.The raw water passing through the pump 12 passes through the filter 14. The filter 14 filters various ions or impurities contained in raw water.

상기 필터(14)를 통과한 원수는 양극실인입라인(40)과 음극실인입라인(42)으로 각각 원수가 유입된다. 상기 양극실인입라인(40)에는 혼합조(16)가 중간에 설치되어 있으며, 상기 혼합조(16)에는 전해질탱크(60)와 전해질펌프(62)로 구성된 전해질첨가장치가 연결되어 전해질을 첨가한다. 상기 전해질첨가장치는 상기 혼합조(16) 직전의 양극실인입라인(40)에 연결될 수도 있다.The raw water passing through the filter 14 is introduced into the anode chamber introduction line 40 and the cathode chamber introduction line 42, respectively. The cathode chamber introduction line 40 is provided with a mixing tank 16 in the middle, and the mixing tank 16 is connected with an electrolyte adding device consisting of an electrolyte tank 60 and an electrolyte pump 62 to add electrolyte. do. The electrolyte adding device may be connected to the anode chamber inlet line 40 immediately before the mixing tank 16.

이하 강산성수 생성라인과 약알칼리수 생성라인인 분리하여 자세히 설명한다.Hereinafter, the strong acid water generation line and the weak alkaline water generation line will be described in detail.

(1) 강산성수 생성라인(1) strong acid water generation line

상기 필터(14)를 통과한 원수는 양극실인입라인(40)과 음극실인입라인(42) 두 곳으로 동시에 인입되어 각각 이동한다. 상기 양극실인입라인(40)에는 전해질탱크(60)와 전해질펌프(62)가 연결되며, 연결 부위에 혼합조(16)가 존재하여 전해질 및 원수가 상기 혼합조(16)로 유입되어 혼합된다. 상기 전해질탱크(60)에는 전해질, 즉 염화나트륨, 염화칼슘등의 전해질로 작용할 수 있는 용액이 저장된다.상기 전해질을 고체로 저장될 수도 있으나, 투입량의 정확도를 위하여 용액으로 저장되는 것이 바람직하다. 상기 전해질은 염산, 황산, 탄산, 질산 등의 무기산 또는 초산, 시트르산, 수산 등의 유기산을 사용할 수도 있다. 상기 무기산 또는 유기산을 사용하는 경우에는 보다 낮은 pH의 강산성수를 생성하기위해 사용할 때 유용하다.The raw water passing through the filter 14 is simultaneously introduced into the anode chamber inlet line 40 and the cathode chamber inlet line 42, respectively, and moves. An electrolyte tank 60 and an electrolyte pump 62 are connected to the anode chamber inlet line 40, and a mixing tank 16 exists at a connection portion, whereby electrolyte and raw water flow into the mixing tank 16 and are mixed. . The electrolyte tank 60 stores a solution capable of acting as an electrolyte, that is, an electrolyte such as sodium chloride or calcium chloride. The electrolyte may be stored as a solid, but is preferably stored as a solution for the accuracy of the dosage. The electrolyte may be an inorganic acid such as hydrochloric acid, sulfuric acid, carbonic acid, nitric acid, or an organic acid such as acetic acid, citric acid, or hydroxyl acid. In the case of using the inorganic acid or the organic acid, it is useful when used to generate strong acidic water of lower pH.

이와 같이 본 발명에서는 양극실인입라인(40)에만 전해질탱크(60)를 연결함으써 양극실(24)로 인입되는 원수에만 전해질이 가미되도록 한다.As described above, in the present invention, the electrolyte is added only to the raw water introduced into the anode chamber 24 by connecting the electrolyte tank 60 only to the anode chamber inlet line 40.

상기 양극실인입라인(40)은 양극실(24)의 하부와 연결되어 있다. 전해질이 혼합된 원수는 양극실(24)로 인입되어 전기분해된다. 상기 양극실(24)에서 전기분해된 전해수는 강산성을 띠고, 상기 전해수는 강산성수저장탱크(72)로 인입된다.The anode chamber inlet line 40 is connected to the lower portion of the anode chamber 24. The raw water mixed with the electrolyte is introduced into the anode chamber 24 to be electrolyzed. The electrolyzed water electrolyzed in the anode chamber 24 is strongly acidic, and the electrolyzed water is drawn into the strong acidic water storage tank 72.

(2) 약알카리성수 생성라인(2) weak alkaline water generation line

상기 필터(14)를 통과한 원수는 음극실인입라인(42)을 통해 음극실(26)의 하부로 인입된다. 양극실인입라인(40)과는 달리 전해질공급수단이 존재하지 않으며, 이로인해 음극실인입라인(42)에 혼합조(16)가 개재되지 않는다. 전해질이 가미되지 않은 원수는 음극실(26)로 인입되어 전기분해된다. 상기 음극실(26)에서 전기분해된 음극수는 약알카리성을 띠고, 상기 전해수는 약알칼리수저수탱크(74)로 인입된다.The raw water passing through the filter 14 is introduced into the lower portion of the cathode chamber 26 through the cathode chamber introduction line 42. Unlike the positive electrode chamber introduction line 40, there is no electrolyte supply means, and thus, the mixing tank 16 is not interposed in the negative electrode chamber introduction line 42. Raw water without electrolyte is introduced into the cathode chamber 26 to be electrolyzed. The cathode water electrolyzed in the cathode chamber 26 is weakly alkaline, and the electrolyzed water is introduced into the weak alkaline water storage tank 74.

이때, 원수가 증류수 같이 전해도가 없는 경우 음극실에 전해가 가능하도록 전해질, 즉 염화나트륨용액, 염화칼륨용액, 염화칼슘용액등을 소량 인입시킬수도 있다.In this case, when raw water does not have an electrolyte like distilled water, a small amount of electrolyte, ie, sodium chloride solution, potassium chloride solution, and calcium chloride solution, may be introduced to enable electrolysis in the cathode chamber.

상기의 약알칼리수에는 원수에 포함되어 있던 세균 등이 제거되지 않고 함유되어 있으므로 음용수로 사용하기 위해서는 살균을 해 주어야 한다. 이를 위해 상기 음극실인출라인(46)의 중간에 살균장치(64)를 설치하였다. 상기 살균장치(64)는 음극실인입라인(42), 음극실(26), 음극실인출라인(46), 약알칼리수탱크(72) 중 어느하나 또는 둘 이상에 장착할 수도 있다. 상기 살균장치(64)는 자외선발생기, 오존발생기, 가열기, 자외선발생기-산화티타늄에 의한 살균기 등을 비롯한 다양한 살균수단들 중 어느하나 또는 둘 이상을 사용할 수 있다.Since the weak alkaline water does not remove bacteria and the like contained in the raw water, it must be sterilized for use as drinking water. To this end, a sterilizer 64 was installed in the middle of the cathode chamber drawing line 46. The sterilizer 64 may be mounted on any one or two or more of the cathode chamber introduction line 42, the cathode chamber 26, the cathode chamber extraction line 46, and the weak alkaline water tank 72. The sterilization device 64 may use any one or two or more of various sterilization means, including a UV generator, an ozone generator, a heater, a UV generator-titanium oxide sterilizer, and the like.

또한, 본 발명에 따른 강산성수-약알칼리수 생성장치는, 펌프(12)와 필터(14)와 전해질탱크(60)와 전해질펌프(62)와 혼합조(16)와 전해조(20)와 이들을 연결하는 배관(도면부호 미표시) 및 상기 배관에 부착된 밸브 등에는 각종 센서(미도시)가 연결되며, 상기 센서에서 수집된 데이터를 이용하여 상기 펌프(12)와 전해질펌프(62)와 전해조(20) 및 각종 밸브등을 제어할 수 있는 제어부(미도시)를 갖는다.In addition, the strong acid water- weak alkaline water generating apparatus according to the present invention, the pump 12, the filter 14, the electrolyte tank 60, the electrolyte pump 62, the mixing tank 16 and the electrolytic cell 20 and connecting them Various sensors (not shown) are connected to a pipe (not shown) and a valve attached to the pipe, and the pump 12, the electrolyte pump 62, and the electrolyzer 20 are connected to each other using data collected from the sensor. And a controller (not shown) capable of controlling various valves and the like.

[실시예2]Example 2

도2는 본 발명에 따른 다른 실시예의 장치 개념도이다.2 is a device conceptual diagram of another embodiment according to the present invention.

도2를 살펴보면, 도2의 기본적인 구성은 도1과 같으나, 전해조(20)와 양극실배출라인(44)/음극실배출라인(46)의 사이에 양극실연결라인(48)/음극실연결라인 (50)과 기체제거장치(66)가 부착된 저수조(70)와 다단전해조(22)가 추가로 부착되는 점이 도1과 상이하다.Referring to FIG. 2, the basic configuration of FIG. 2 is the same as that of FIG. 1, but the anode chamber connection line 48 / the cathode chamber connection between the electrolytic cell 20 and the anode chamber discharge line 44 / cathode chamber discharge line 46 is shown. It is different from FIG. 1 in that the water tank 70 and the multistage electrolyzer 22 to which the line 50 and the gas removal apparatus 66 are attached are additionally attached.

이하 강산성수 생성라인과 약알칼리수 생성라인인 분리하여 자세히 설명한다.Hereinafter, the strong acid water generation line and the weak alkaline water generation line will be described in detail.

(1) 강산성수 생성라인(1) strong acid water generation line

전해조(20)에서 전해된 1차 강산성수는 양극실연결라인(48)을 거쳐 다단전해조(22)의 제2양극실(28)의 하부로 인입되고, 제2양극실(28)에서 한번 더 전해되어 2차 강산성수를 형성하며, 양극실인출라인(44)을 통과하여 강산성수저장탱크(72)로 인입된다.The primary strong acidic water electrolyzed in the electrolytic cell 20 is introduced into the lower portion of the second positive electrode chamber 28 of the multi-stage electrolytic bath 22 via the positive electrode chamber connecting line 48, and is electrolyzed once more in the second positive electrode chamber 28. It forms a secondary strong acidic water, and passes through the anode chamber lead-out line 44 is drawn into the strong acid water storage tank (72).

상기 양극실(24)로 인입되는 원수에는 도1과 마찬가지로 전해질이 가미되어 있으며, 이로인해 생성된 전해수가 강산성을 띠게 된다.The raw water introduced into the anode chamber 24 has an electrolyte added thereto as in FIG. 1, and thus the electrolyzed water produced is strongly acidic.

도면에 도시하지는 않았으나, 상기 양극실연결라인(48)에는 저수조(70)를 설치하고 상기 저수조에 전해질첨가장치가 추가로 연결할 수 있다. 전해질첨가장치를 추가로 연결하는 경우에는 pH가 더 낮은 2차 강산성수가 생성된다.Although not shown in the drawing, the cathode chamber connection line 48 may be provided with a reservoir 70 and an electrolyte addition device may be additionally connected to the reservoir. Further connection of the electrolyte addition device produces secondary strong acidic water with lower pH.

(2) 약알칼리수 생성라인(2) Alkaline water generation line

전해조(20)에서 전해된 1차 약알칼리수는 음극실연결라인(50)을 거쳐 다단전해조(22)의 제2음극실(30)의 하부로 인입되며, 상기 제2음극실(30)에서 한번 더 전해되어 2차 약알칼리수를 형성하며, 음극실인출라인(46)을 통과하여 약알칼리수저장탱크(74)로 인입된다.The first weak alkaline water electrolyzed in the electrolytic cell 20 is introduced into the lower portion of the second negative electrode chamber 30 of the multistage electrolytic bath 22 via the negative electrode chamber connecting line 50, and once in the second negative electrode chamber 30. It is further electrolyzed to form secondary weak alkaline water, and is introduced into the weak alkaline water storage tank 74 through the cathode chamber drawing line 46.

이때, 음극실(26)에서는 가스(주로 수소가스)가 생성되므로 다단전해조(22)의 전해를 원활하게 하기 위하여 음극실연결라인(50)에 저수조(70)를 설치하고, 상기 저수조(70)에 기체제거장치(66)를 부착하여 발생된 가스를 제거한다.At this time, since the gas (mainly hydrogen gas) is generated in the cathode chamber 26, in order to facilitate the electrolysis of the multistage electrolytic tank 22, a reservoir 70 is installed in the cathode chamber connection line 50, and the reservoir 70 The gas removal device 66 is attached to the gas to remove the generated gas.

[실시예3]Example 3

본 발명에 의한 강산성수-약알칼리수 생성장치에서 역전압을 인가할때는 정전압-역전압-정전압의 순으로 인가하는 통상의 역전압인가 방법으로 음극판에 부착되는 스케일을 제거할 수 있다. 역전압이 인가될 때에는 생성되는 전해수를 배수관으로 배출하도록 한다.When the reverse voltage is applied in the strongly acidic water-alkaline water generator according to the present invention, the scale attached to the negative electrode plate may be removed by a conventional reverse voltage applying method in the order of constant voltage, reverse voltage and constant voltage. When a reverse voltage is applied, the generated electrolyzed water is discharged to the drain pipe.

상기와 같은 종래의 방법을 사용하지 않고, 좀더 극판에 무리를 적게주는 방법을 강구할 수도 있다.Instead of using the conventional method as described above, it is possible to devise a method of less burden on the plate.

예를들면, 도3a 및 도3b에 도시된 방법으로 역전압을 인가할 수 있다. 도3a의 역전압 인가 방법을 사용하면 수직으로 전압이 떨어지는 값을 반으로 줄여 극판의 부하변동값을 줄일 수 있다. 또한, 도3b의 역전압 인가 방법을 사용하면 정전압의 절대값이 서서히 완만하게 떨어지게 하여 극판에 부담을 적게 줄 수 있다. 이때, 도3b에서 정전압의 절대값이 포물선을 그리면서 떨어질 수도 있다.For example, the reverse voltage can be applied by the method shown in FIGS. 3A and 3B. Using the reverse voltage applying method of FIG. 3A, the value of the load drop of the electrode plate can be reduced by reducing the value of the vertical voltage drop in half. In addition, when the reverse voltage application method of FIG. 3B is used, the absolute value of the constant voltage gradually decreases gradually, thereby reducing the burden on the electrode plate. At this time, the absolute value of the constant voltage in Figure 3b may drop while drawing a parabola.

실시예2에서 역전압을 인가할 때는 두개의 전해조를 역전압이 인가되는 것을 시간차를 두어 서로 다른 시간대에 둘 이상의 전해조에서 역전이 일어나도록 할 수 도 있다.When applying the reverse voltage in the second embodiment, the two electrolytic cells may be timed to apply the reverse voltage so that reversal occurs in two or more electrolyzers at different times.

종래의 방법을 사용하거나, 도3a 또는 도3b의 방법을 사용하는 모든 경우에 역전시(도3a 또는 도3b에서는 A부분)에는 다른 배출수라인(미도시)을 통하여 배출되도록 할 수도 있으나, 역전시에 양극수와 음극수의 유로를 변경시켜주는 장치를 전해조(20)와 양극실배출라인(44)/음극실배출라인(46)사이에 개재시켜 전해수의 낭비를 방지할 수도 있다. 실시예2에 이 방법을 적용하는 경우에는 양극실연결라인(48)에도 저수조(70) 및 기체제거장치(66)를 설치하는 것이 바람직하다.In all cases using the conventional method or using the method of FIG. 3A or 3B, the reverse display (part A in FIG. 3A or 3B) may be discharged through another discharge water line (not shown). An apparatus for changing the flow path between the positive and negative waters may be interposed between the electrolytic cell 20 and the positive electrode chamber discharge line 44 / cathode chamber discharge line 46 to prevent waste of electrolytic water. In the case of applying this method to the second embodiment, it is preferable to install the reservoir 70 and the gas removing device 66 in the anode chamber connecting line 48.

상기와 같은 구성을 바탕으로 전해수를 생성하면 양극수는 pH3이하의 강산성수이고, 음극수는 pH8.0~9.5의 약알칼리수가 생성된다,When electrolytic water is generated based on the above configuration, the positive water is a strong acidic water of pH3 or less, and the negative water is a weak alkaline water of pH 8.0 to 9.5.

이상과 같이 본 발명에 의하면, 양극실로는 전해질이 가미된 원수를 인입하여 강산성수가 생성되게 하고, 음극실로는 전해질이 가미되지 않은 원수를 인입하여 약알칼리수를 생성하되 살균장치로 살균처리를 하므로써, 강산성수는 살균대상물을 살균하는데 사용하고, 살균된 약알칼리수는 인간 또는 동물의 음용수 등으로 사용할 수 있으므로 전해된 양극수와 음극수를 낭비없이 사용할 수 있는 효과가 있다.As described above, according to the present invention, by introducing the raw water with the electrolyte added to the positive electrode chamber, strong acidic water is generated, and the negative electrode chamber is introduced with raw water without the electrolyte to generate weak alkaline water, but by sterilizing with a sterilizer, Strong acidic water is used to sterilize the sterilization target, and since the sterilized weak alkaline water can be used as drinking water for humans or animals, there is an effect that the used positive and negative water can be used without waste.

Claims (6)

원수를 전해하여 강산성수와 약알칼리수를 생성하는 강산성수-약알칼리수 생성장치에 있어서,In the strong acid-weak alkaline water generating device which electrolyzes raw water to generate strong acidic water and weak alkaline water, 양극판을 내포하는 양극실과, 음극판을 내포하는 음극실과, 상기 양극실과 음극실을 양분하는 격막을 포함하는 전해조와;An electrolytic cell including a positive electrode chamber containing a positive electrode plate, a negative electrode chamber containing a negative electrode plate, and a diaphragm dividing the positive electrode chamber and the negative electrode chamber; 상기 양극실에 원수를 인입시키는 양극실인입라인과;A cathode chamber inlet line for introducing raw water into the anode chamber; 상기 음극실에 원수를 인입시키는 음극실인입라인과;A cathode chamber inlet line for introducing raw water into the cathode chamber; 상기 양극실인입라인의 소정의 위치에 부착되어 원수에 전해질을 공급하는 전해질공급수단과;Electrolyte supply means attached to a predetermined position of the anode chamber inlet line to supply electrolyte to raw water; 상기 양극실로부터 전해된 강산성수를 인출시키는 양극실인출라인과;A cathode chamber drawing line for drawing strong acidic water electrolyzed from the anode chamber; 상기 음극실로부터 약알칼리수를 인출시키는 음극실인출라인과;A cathode chamber drawing line for drawing the weak alkaline water from the cathode chamber; 상기 음극실인입라인, 음극실, 음극실인출라인 중 어느하나 또는 둘 이상에 내포되어 세균을 살균하는 살균장치;를 갖는 강산성수-약알칼리수 생성장치.Strong acidic water- weak alkaline water generating device having a; sterilization apparatus embedded in any one or two or more of the cathode chamber introduction line, cathode chamber, cathode chamber extraction line to sterilize bacteria. 제 1 항에 있어서,The method of claim 1, 상기 양극실인입라인 중 상기 전해질공급수단이 부착된 지점과 상기 양극실 사이에는, 원수와 전해질이 잘 혼합되도록 공간을 제공하는 혼합조가 추가로 개재되는 강산성수-약알칼리수 생성장치.Strongly acidic water- weak alkaline water generating device between the point where the electrolyte supply means is attached and the anode chamber of the anode chamber inlet line, a mixing tank for providing a space for mixing the raw water and the electrolyte is further interposed. 제 1 항 또는 제 2 항에 있어서,The method according to claim 1 or 2, 상기 살균장치는 자외선발생기, 오존발생기, 가열기, 자외선발생기-산화티타늄에 의한 살균기 중 어느 하나 또는 둘 이상인 것을 특징으로 하는 강산성수-약알칼리수 생성장치.The sterilizing apparatus is a strong acidic water- weak alkaline water generator, characterized in that any one or two or more of a UV generator, ozone generator, heater, UV generator-titanium oxide sterilizer. 제 3 항에 있어서,The method of claim 3, wherein 상기 전해조와 상기 양극실인출라인 및 음극실인출라인 사이에는 적어도 하나이상의 다단전해조가 추가로 장착되며,At least one multistage electrolyzer is further installed between the electrolyzer and the anode chamber drawing line and the cathode chamber drawing line, 상기 전해조와 상기 다단전해조 사이에는 양극실연결라인과 음극실연결라인이 개재되며,An anode chamber connecting line and a cathode chamber connecting line are interposed between the electrolytic cell and the multistage electrolytic bath, 상기 음극실연결라인의 중간에는 저수조가 장착되는 강산성수-약알칼리수 생성장치.Strong acid water- weak alkaline water generating device is mounted in the middle of the cathode chamber connection line. 제 4 항에 있어서,The method of claim 4, wherein 상기 저수조에는 기체제거장치가 추가로 부착되는 강산성수-약알칼리수 생성장치.Strong acidic water- weak alkaline water generating device is further attached to the gas removal device in the reservoir. 제5항에 있어서,The method of claim 5, 상기 전해조와 상기 저수조 사이에는 전해질공급수단이 추가로 개재되는 강산성수-약알칼리수 생성장치.Strongly acidic water- weak alkaline water generating device further comprises an electrolyte supply means between the electrolytic cell and the reservoir.
KR10-2001-0023103A 2001-04-27 2001-04-27 Apparatus for producing strong-acidic water and mild-basic water KR100405144B1 (en)

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KR20030077910A (en) * 2002-03-27 2003-10-04 하이젠환경테크 (주) Highly concentrated electrolyte producing system and method thereof
KR20040049470A (en) * 2002-12-06 2004-06-12 이철호 Water sterilization device
KR100443296B1 (en) * 2002-04-10 2004-08-09 경원엔터프라이즈 주식회사 Apparatus and method for melting electrolyte for electric washing machine

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KR101550441B1 (en) * 2012-11-29 2015-09-04 주식회사 한국정품인증원 apparatus for water treatment using electrolysis sterilizinng water

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JPS6456188A (en) * 1987-03-11 1989-03-03 Tatsuo Okazaki Electrolyzer for water
JPH1157720A (en) * 1996-11-07 1999-03-02 Honda Motor Co Ltd Electrolytic functional water, its production method and device
KR100311911B1 (en) * 1998-05-23 2002-02-28 이규철 Apparatus for making drinking water and disinfected water simultaneously
KR19990078486A (en) * 1998-09-29 1999-11-05 박병인 Strong seawater generator
KR200240002Y1 (en) * 2001-04-18 2001-10-11 하이젠환경테크 (주) Apparatus creating electrolysed-water by multi-step and diaphram

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030077910A (en) * 2002-03-27 2003-10-04 하이젠환경테크 (주) Highly concentrated electrolyte producing system and method thereof
KR100443296B1 (en) * 2002-04-10 2004-08-09 경원엔터프라이즈 주식회사 Apparatus and method for melting electrolyte for electric washing machine
KR20040049470A (en) * 2002-12-06 2004-06-12 이철호 Water sterilization device

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