KR20010060651A - A TENSILE STRENGTH OF 780MPa GRADE HOT ROLLED STEEL SHEET FOR STRUCTURAL USE AND A METHOD FOR MANUFACTURING IT - Google Patents

A TENSILE STRENGTH OF 780MPa GRADE HOT ROLLED STEEL SHEET FOR STRUCTURAL USE AND A METHOD FOR MANUFACTURING IT Download PDF

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KR20010060651A
KR20010060651A KR1019990063057A KR19990063057A KR20010060651A KR 20010060651 A KR20010060651 A KR 20010060651A KR 1019990063057 A KR1019990063057 A KR 1019990063057A KR 19990063057 A KR19990063057 A KR 19990063057A KR 20010060651 A KR20010060651 A KR 20010060651A
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less
rolled steel
steel
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tensile strength
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KR100415672B1 (en
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조열래
박기종
설경식
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이구택
포항종합제철 주식회사
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

PURPOSE: Provided is a method for manufacturing hot rolled steel sheets having high tensile strength of 780MPa for the application to structural member such as automobile frame and deck, crane boom, etc. CONSTITUTION: The hot rolled steel sheet is manufactured by reheating a steel slab comprising C 0.06-0.10wt.%, Si 0.2wt.% or less, Mn 1.4-2.0wt.%, P 0.02wt.% or less, S 0.005wt.% or less, Al 0.010-0.050wt.%, Ti 0.050-0.15wt.%, Nb 0.020-0.040wt.%, Mo 0.1-0.3wt.%, N 60ppm or less, a balance of Fe, and other inevitable impurities; finish hot rolling the steel slab at an austenite temperature zone; cooling it to 550-640deg.C; and then coiling.

Description

인장강도 780MPa급 구조용 열연강판 및 그 제조방법{A TENSILE STRENGTH OF 780MPa GRADE HOT ROLLED STEEL SHEET FOR STRUCTURAL USE AND A METHOD FOR MANUFACTURING IT}Tensile strength 780MPA class hot rolled steel sheet and its manufacturing method {A TENSILE STRENGTH OF 780MPa GRADE HOT ROLLED STEEL SHEET FOR STRUCTURAL USE AND A METHOD FOR MANUFACTURING IT}

본 발명은 상용차의 프레임 및 데크, 특장차 크레인 붐(boom) 등의 구조용 강도부재로 적용되는 고강도 열연강판 및 그 제조방법에 관한 것으로서, 보다 상세하게는 강성분을 조정하고 열간압연 및 권취온도를 제어함으로써, 우수한 굽힘성과 용접특성을 갖는 인장강도 780 MPa급 구조용 열연강판 및 그 제조방법에 관한 것이다.The present invention relates to a high-strength hot-rolled steel sheet and a method for manufacturing the same, which are applied to structural strength members such as frames and decks of commercial vehicles, crane booms, and more specifically, to adjust steel components and to control hot rolling and winding temperatures. The present invention relates to a hot-rolled steel sheet having a tensile strength of 780 MPa class having excellent bendability and welding characteristics, and a method of manufacturing the same.

열연강판의 가공성은 굽힘성, 장출성 및 연신플랜지성 등으로 구분하고 있는데, 구조용 열연강판에서 주로 요구되는 성질은 굽힘성이며, 이는 주로 비금속 개재물 및 밴드상의 퍼얼라이트 조직에 영향을 받게 된다. 또한, 구조체 접합의 측면에 있어서 용접과 리벳팅을 고려할 수 있는데, 구조체로의 안정성을 확보하기 위해서는 용접부의 연화량이 가능한 작아야 한다.The workability of the hot rolled steel sheet is divided into bendability, elongation property and stretch flange property, and the main required property of structural hot rolled steel sheet is bendability, which is mainly affected by nonmetallic inclusions and band-like perlite structure. In addition, welding and riveting may be considered in terms of joining the structure. In order to secure stability to the structure, the softening amount of the weld portion should be as small as possible.

최근에 개발되는 인장강도 780 MPa급 이상의 고강도 열연강판의 제조방법들은 상기한 연성과 연신 플랜지성을 동시에 해결하고자 하기 보다는, 각각의 변형특성에 적합한 조직을 이용하는데, 그 예로서 다음의 기술들이 있다.Recently developed methods for producing high strength hot rolled steel sheets with a tensile strength of 780 MPa or more use a structure suitable for each deformation property, rather than simultaneously addressing the above-described ductility and stretching flange properties. Examples include the following techniques. .

즉, 일본특허 공개공보(소)61-15128호에 개시된 이상강(dual phase steel)은 석출강화형 열연강판에 비해, 강도-연신율 밸란스 특성이 우수하나 신장플랜지성은 베이나이트 단상강에 비하여 열위인 것으로 알려져 있다.That is, the dual phase steel disclosed in Japanese Patent Application Laid-Open No. 61-15128 has superior strength-elongation balance characteristics compared with precipitation-reinforced hot-rolled steel sheets, but its elongated flange property is superior to bainite single phase steel. It is known to be inferior.

일본특허 공개공보91-358007호에서는 종래의 이상강과는 달리 TiC 탄화물로 석출강화된 페라이트와 제 2상을 마르텐사이트로 조직제어함으로써, 연신율 및 피로특성이 우수한 저항복비형 고강도 열연강판의 제조가 가능한 것으로 제안하고 있다.In Japanese Patent Laid-Open Publication No. 91-358007, unlike the conventional ideal steel, by controlling the ferrite and the second phase precipitated and strengthened by TiC carbide with martensite, it is possible to manufacture a high-strength ratio type high strength hot rolled steel sheet having excellent elongation and fatigue characteristics. It is proposed.

일본특허 공개공보(평) 3-10049호에는 상기 이상강에 비해 더욱 고연성을 갖는 인장강도 780∼980MPa의 잔류 오스테나이트강이 제안되어 있는데, 이 잔류오스테나이트강은 인장강도-연신율 밸란스가 극히 우수하나 인장특성이 잔류오스테나이트량에 의하여 크게 좌우되기 때문에, 열연강판의 폭방향, 길이방향으로 균일한 재질을 얻기가 어려운 제조상의 단점을 가지고 있다.Japanese Patent Application Laid-Open No. 3-10049 proposes a retained austenite steel having a tensile strength of 780 to 980 MPa, which is more ductile than the above ideal steel. The residual austenite steel has a tensile strength-elongation balance of Although extremely excellent, the tensile properties are largely dependent on the amount of retained austenite, and thus, it is difficult to obtain a uniform material in the width direction and the length direction of the hot rolled steel sheet.

그러나, 상기한 이상강 또는 잔류오스테나이트강은 강도×연신율 발란스 측면에서는 대단히 우수하나, 열간압연후 페라이트의 조기석출을 위해 0.5∼2.5wt% 범위의 Si이 첨가되므로, 표면 산화스케일결함 발생가능성이 높으며, 성형단계에서 잔류오스테나이트가 마르텐사이트로 유기변태되는 과정에서 구성 상간의 경도차이가 증가하기 때문에, 기존의 페라이트-퍼얼라이트 조직강 혹은 페라이트 단상강에비해 신장플랜지성이 나쁘고 전단가공이 최종 가공면일 경우 굽힘성 역시 열위인 것으로 알려져 있다.However, the above ideal steel or residual austenite steel is very excellent in terms of strength × elongation balance, but since the Si is added in the range of 0.5 to 2.5 wt% for early deposition of ferrite after hot rolling, there is a possibility of occurrence of surface oxide scale defects. It is high, and the hardness difference between constituent phases increases in the process of organic transformation of retained austenite to martensite in the forming step, and thus has poor elongation flangeability compared to conventional ferrite-perlite tissue steel or ferrite single phase steel, and shear processing is final. Bendability is also known to be inferior in the case of machined surfaces.

한편, 강도×신장플랜지성 발란스 측면에서는 일본강관(NKK) 등에서 제안된 페라이트-베이나이트 복합조직강이 가장 우수한 것으로 알려져있다. 이 강은 열간압연후 런 아웃 테이블(run out table) 상에서 3단 제어냉각패턴을 적용하고 450∼500℃의 온도 범위에서 권취를 행하여 제조함으로써, 페라이트 기지와 제 2상간의 경도차가 작고, 입계 세멘타이트의 생성이 억제되어 강도×연신플랜지성 발란스가 우수하다. 그러나, 가공용 용도에서 비교적 낮은 값인 18% 전후의 연신율을 가지는 것이 단점으로 지적되고 있다.On the other hand, the ferrite-bainite composite tissue steel proposed by Nippon Steel Pipe Co., Ltd. (NKK) and the like is known to be the most excellent in terms of strength x extension flange balance. The steel is manufactured by applying a three-stage controlled cooling pattern on a run out table after hot rolling and winding in a temperature range of 450 to 500 ° C., so that the hardness difference between the ferrite matrix and the second phase is small and the grain boundary cement is produced. Tight formation is suppressed, and the strength x stretching flange balance is excellent. However, it is pointed out that having a elongation of about 18%, which is a relatively low value in processing applications, has a drawback.

이에, 본 발명자는 상기와 같은 문제점을 해결하기 위하여 연구와 실험을 거듭하고 그 결과에 근거하여 본 발명을 제안하게 된 것으로, 본 발명은 적정량의 망간, 티타늄, 니오븀 및 몰리브덴을 첨가하고 열간압연 및 권취온도를 적절히 제어함으로써, 높은 인장강도, 18% 이상의 연신율 및 우수한 굽힘성을 동시에 갖는 구조용 열연강판 및 그 제조방법을 제공하고자 하는데, 그 목적이 있다.Accordingly, the present inventors have repeatedly conducted research and experiments to solve the above problems and propose the present invention based on the results, and the present invention adds an appropriate amount of manganese, titanium, niobium and molybdenum, and hot rolls and By appropriately controlling the coiling temperature, it is an object of the present invention to provide a structural hot rolled steel sheet having a high tensile strength, an elongation of at least 18%, and excellent bendability, and a method of manufacturing the same.

본 발명은 중량%로 탄소 : 0.06∼0.10%, 실리콘 : 0.2% 이하, 망간 : 1.4∼2.0%, 인 : 0.02% 이하, 황 : 0.005% 이하, 알루미늄: 0.010∼0.050%, 티타늄: 0.050∼0.15%, 니오븀 : 0.020∼0.040%, 몰리브덴 : 0.1~0.3%, 질소 : 60ppm이하, 잔부 Fe 및 기타 불가피한 불순물을 함유하고, 페라이트 단상조직을 갖는 인장강도 780 MPa급 구조용 열연강판에 관한 것이다.In the present invention, carbon: 0.06 to 0.10%, silicon: 0.2% or less, manganese: 1.4 to 2.0%, phosphorus: 0.02% or less, sulfur: 0.005% or less, aluminum: 0.010 to 0.050%, titanium: 0.050 to 0.15 %, Niobium: 0.020% to 0.040%, molybdenum: 0.1% to 0.3%, nitrogen: 60 ppm or less, residual Fe and other unavoidable impurities, and a tensile strength 780 MPa class hot rolled steel sheet having a ferrite single phase structure.

또한, 본 발명은 중량%로 탄소 : 0.06∼0.10%, 실리콘 : 0.2% 이하, 망간 : 1.4∼2.0%, 인 : 0.02% 이하, 황 : 0.005% 이하, 알루미늄: 0.010∼0.050%, 티타늄: 0.050∼0.15%, 니오븀 : 0.020∼0.040%, 몰리브덴 : 0.1~0.3%, 질소 : 60ppm 이하, 잔부 Fe 및 기타 불가피한 불순물을 함유하는 강 슬라브를 재가열하고 오스테나이트온도역에서 마무리열간압연한 다음, 550~640℃의 온도범위까지 냉각하고 이 온도에서 권취하는 것을 특징으로 하는 인장강도 780 MPa급 구조용 열연강판의 제조방법에 관한 것이다.In the present invention, carbon: 0.06 to 0.10%, silicon: 0.2% or less, manganese: 1.4 to 2.0%, phosphorus: 0.02% or less, sulfur: 0.005% or less, aluminum: 0.010 to 0.050%, titanium: 0.050 ~ 0.15%, niobium: 0.020 to 0.040%, molybdenum: 0.1 to 0.3%, nitrogen: 60 ppm or less, reheat the steel slab containing residual Fe and other unavoidable impurities, and finish hot roll at the austenite temperature range, It relates to a method for producing a tensile strength 780 MPa class hot rolled steel sheet characterized by cooling to a temperature range of 640 ℃ and wound at this temperature.

이하, 본 발명에 대하여 상세히 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

상기 탄소(C)는 열연강판의 강도를 얻는데 기본적으로 필요한 원소인데, 본 발명강에서는 굽힘성을 열화시키는 퍼얼라이트조직의 생성억제, 즉 페라이트 단상조직화 및 입계 세멘타이트의 저감을 위하여 티타늄 및 니오븀 탄화물의 석출에 필요한 최소량으로 제어하기 위하여, 그 함량은 0.06∼0.10%로 제한하는 것이 바람직하다.The carbon (C) is basically an element necessary for obtaining the strength of the hot rolled steel sheet, and in the present invention steel, titanium and niobium carbides are used for inhibiting the formation of the ferrite structure, which deteriorates the bendability, that is, to reduce the ferrite single-phase organization and grain boundary cementite. In order to control to the minimum amount necessary for the precipitation of, the content is preferably limited to 0.06 to 0.10%.

상기 망간(Mn)은 고용강화에 유효한 원소로, 그 함량이 1.4% 미만인 경우에는 기대되는 강도가 얻어지지 않고, 2.0%를 초과하면 강도는 780MPa 이상이나 연신율이 급격히 감소된다. 즉, 망간 함유량이 증가하면 강의 소입성이 증가되어 베이나이트 단상화의 가능성이 높아지고, 티타늄 탄화물의 석출이 억제되어 강도가 오히려 저하되기 때문에, 그 함량은 1.4∼2.0%로 설정하는 것이 바람직하다.The manganese (Mn) is an effective element for solid solution strengthening. If the content is less than 1.4%, the expected strength is not obtained. If the content exceeds 2.0%, the strength is 780 MPa or more, but the elongation is drastically reduced. In other words, when the manganese content is increased, the hardenability of the steel is increased to increase the possibility of bainite single phase, the precipitation of titanium carbide is suppressed and the strength is lowered. Therefore, the content is preferably set to 1.4 to 2.0%.

상기 규소(Si)는 연성의 열화없이 강도를 상승시키는 고용강화원소이나, 열연강판 표면에 산화스케일 결함을 유발하므로, 본 발명에서는 유화물의 형상제어를 위하여 불가피하게 첨가되는 경우를 고려하여 그 함량을 0.20% 이하로 제한하는 것이 바람직하다. 실리콘이 상기 범위로 첨가되면, 양호한 표면성상을 얻을 수 있다.The silicon (Si) is a solid solution element that raises the strength without deterioration of ductility, but causes an oxide scale defect on the surface of the hot rolled steel sheet, in the present invention, the content of the silicon (Si) is inevitably added to control the shape of the emulsion. It is desirable to limit it to 0.20% or less. When silicon is added in the above range, good surface properties can be obtained.

상기 니오븀(Nb)은 열간압연동안 석출되거나 고용상태로 존재하면서 오스테나이트의 결정립 미세화에 기여할 뿐만 아니라 페라이트상의 석출강화에도 유효한 원소이다. 그러나, 그 첨가량이 과다하면 연속주조 슬라브의 제조과정에서 주편크랙을 생성시킬 가능성이 높아지기 때문에, 0.04% 이하로 규제하는 것이 바람직하다.The niobium (Nb) is an element that is effective in strengthening the precipitation of ferrite phase as well as contributing to the refinement of grains of austenite while being precipitated or being in solid solution during hot rolling. However, if the addition amount is excessive, the possibility of generating slag cracks during the manufacturing process of the continuous casting slab becomes high, so it is preferable to regulate it to 0.04% or less.

상기 티타늄(Ti)은 본 발명강에 있어 중요한 원소로, 열간압연후 냉각과정에서 페라이트 조직내 티타늄-니오비움 탄화물 또는 티타늄-니오븀-몰리브덴 복합탄화물로 석출하여 페라이트 기지의 강화에 기여하게 된다. 그 함량이 적으면 석출강화효과를 충분히 기대할 수 없으며, 반대로 그 함량이 0.15%를 초과하여도 무방하나 석출강화효과가 포화되기 때문에, 상기 티타늄의 첨가량은 0.05∼0.15%로 첨가하는 것이 바람직하다.The titanium (Ti) is an important element in the present invention steel, precipitates as titanium-niobium carbide or titanium-niobium-molybdenum composite carbide in the ferrite structure during the hot rolling process to contribute to the strengthening of the ferrite matrix. If the content is small, the precipitation strengthening effect cannot be sufficiently expected. On the contrary, the content may exceed 0.15%, but the precipitation strengthening effect is saturated. Therefore, the amount of titanium added is preferably added at 0.05 to 0.15%.

상기 몰리브덴(Mo)은 Mn과 더불어 강의 소입성을 증가시키는 동시에, 본 발명의 압연후 권취온도범위에서는 티타늄 및 니오븀과 더불어 석출강화에 기여하는 원소이다. 본 발명에서는 인장강도 780MPa급 열연강판의 강도수준과 용접성을 고려하여 0.1~0.3%로 첨가하는 것이 바람직하다. 만약, 그 함량이 0.3%를 초과하면 몰리브덴에 의한 소입성증가의 역기능인, 용접부 균열의 발생 가능성이 높아지게 된다.The molybdenum (Mo) is an element that increases the hardenability of the steel together with Mn, and contributes to precipitation strengthening together with titanium and niobium in the winding temperature range after rolling of the present invention. In the present invention, it is preferable to add the tensile strength of 780MPa grade hot rolled steel sheet in consideration of the strength level and weldability of 0.1 ~ 0.3%. If the content exceeds 0.3%, the likelihood of occurrence of weld cracking, which is a dysfunction of the increase in hardenability due to molybdenum, is increased.

본 발명에서는 상기와 같이 조성된 강 슬라브를 재가열한 후 열간압연하는데, 바람직하게는 Ar3이상인 840℃ 이상에서 마무리열간압연하고, 550~640℃의 온도범위에서 권취하는 것이 중요하다.In the present invention, the steel slab formed as described above is reheated and hot rolled. Preferably, it is important to finish hot roll at 840 ° C. or higher, which is Ar 3 or higher, and to wind the steel slab in a temperature range of 550 to 640 ° C.

즉, 종래 HSLA강의 제조에서는, 석출강화원소가 미세한 탄화물로 석출되면서 강도상승에 기여하도록 하기 위해, 열간압연후 600℃전후에서 권취하였는데, 본 발명도 기본적으로는 페라이트상에서의 탄화물을 석출시키는 것은 동일 개념이기 때문에, 상기 권취온도를 550~640℃범위로 설정하였다. 상기 온도가 이보다 낮으면 석출이 억제되고, 반대로 높으면 석출물크기는 조대화되어 인장강도가 저하되는 문제가 있다.That is, in the production of conventional HSLA steel, in order to contribute to the increase in strength while the precipitated reinforced element precipitates as fine carbide, it was wound around 600 ° C after hot rolling, but the present invention also basically deposits carbide on ferrite. Because of the concept, the winding temperature was set in the range of 550 ~ 640 ℃. If the temperature is lower than this, precipitation is suppressed. On the contrary, if the temperature is high, the precipitate size becomes coarse and the tensile strength is lowered.

이와 같은 본 발명의 열연강판은, 최종조직에서 티타늄-니오븀-몰리브덴 복합탄화물로 석출강화된 페라이트 단상조직을 갖고, 기계적성질에 있어서는 인장강도 780 MPa 이상, 항복강도 690 MPa 이상, 인장강도×연신율 발란스가 15000 MPa·% 이상의 우수한 특성을 제공할 수 있다.The hot rolled steel sheet of the present invention has a ferrite single phase structure precipitated and strengthened with titanium-niobium-molybdenum composite carbide in the final structure, and in mechanical properties, tensile strength of 780 MPa or more, yield strength of 690 MPa or more, tensile strength x elongation balance Can provide excellent characteristics of 15000 MPa ·% or more.

이하, 실시예를 통하여 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail through examples.

(실시예 )Example

하기 표1의 화학성분을 갖는 강 슬라브를 하기 표2의 조건으로 열간압연하여 냉각한 후 권취온도를 달리하여, 최종 판 두께가 3.2∼6.0mm인 열연강판을 제조하였다.The steel slab having the chemical composition of Table 1 was hot-rolled and cooled under the conditions of Table 2 below, and then the winding temperature was changed to prepare a hot rolled steel sheet having a final plate thickness of 3.2 to 6.0 mm.

그 후, 제조된 열연강판의 기계적성질을 측정하고, 그 결과를 하기 표2에 나타내었다.Thereafter, the mechanical properties of the manufactured hot rolled steel sheet were measured, and the results are shown in Table 2 below.

이 때, 인장강도는 압연방향에 대하여 수직인 방향으로 JIS 5호 인장시편을 제작한 후 상온에서 10mm/min의 속도로 인장하여 평가하였다.At this time, the tensile strength was evaluated by preparing a JIS No. 5 tensile test specimen in a direction perpendicular to the rolling direction and pulling at a speed of 10 mm / min at room temperature.

굽힘시험은 압연 직각방향의 35W×240L×t(mm) 크기의 시편의 버(burr) 발생부위를 굽힘부의 외측에 오도록하여 굽힘부 크랙이 발생되는 최소 반경을 측정하였다.In the bending test, a burr generation part of a specimen having a size of 35W × 240L × t (mm) in a right angle direction of rolling was placed outside the bend to measure the minimum radius at which the bend crack was generated.

강종Steel grade 화학성분(중량%)Chemical composition (% by weight) CC MnMn SiSi PP SS AlAl TiTi NbNb MoMo N(ppm)N (ppm) 종래강1Conventional Steel 1 0.0750.075 1.451.45 0.160.16 0.0090.009 0.0060.006 0.0430.043 0.0350.035 1414 종래강2Conventional Steel 2 0.0780.078 1.681.68 0.080.08 0.0130.013 0.0010.001 0.0310.031 0.1050.105 0.0330.033 4040 발명강Invention steel 0.0730.073 1.691.69 0.050.05 0.0170.017 0.0020.002 0.0340.034 0.0880.088 0.0300.030 0.200.20 3838 비교강1Comparative Steel 1 0.0740.074 1.651.65 0.100.10 0.0100.010 0.0050.005 0.0370.037 0.0820.082 0.0310.031 0.100.10 3636 비교강2Comparative Steel 2 0.0750.075 1.701.70 0.010.01 0.0100.010 0.0030.003 0.0320.032 0.0500.050 0.0300.030 0.220.22 4040

구분division 권취온도(℃)Winding temperature (℃) 두께(mm)Thickness (mm) 기계적성질Mechanical property 인장강도×연신율발란스(MPa×%)Tensile Strength × Elongation Balance (MPa ×%) 굽힘최소반경Bending radius 항복강도(MPa)Yield strength (MPa) 인장강도(MPa)Tensile Strength (MPa) 연신율(%)Elongation (%) 종래재1Conventional Materials 1 종래강1Conventional Steel 1 580580 3.63.6 510510 617617 2727 1665916659 1T1T 종래재2Conventional material 2 종래강2Conventional Steel 2 594594 1.01.0 657657 745745 2121 1564915649 종래재3Conventional Materials 3 585585 5.05.0 666666 735735 2121 1543515435 비교재1Comparative Material 1 발명강Invention steel 650650 5.05.0 627627 774774 2323 1780217802 발명재1Invention 1 620620 3.23.2 764764 833833 2121 1749317493 발명재2Invention 2 580580 4.54.5 735735 794794 2020 1588015880 비교재2Comparative Material 2 550550 4.04.0 666666 764764 1818 1375213752 비교재3Comparative Material 3 비교강1Comparative Steel 1 600600 696696 754754 1818 1375213752 비교재4Comparative Material 4 비교강2Comparative Steel 2 725725 774774 2121 1625416254

상기 표2에 나타난 바와 같이, 본 발명강으로 제조된 발명재(1),(2)는 모두 인장강도 780MPa이상, 연신율 18%이상, 인장강도×연신율 밸런스가 15000(MPa×%) 이상이고, 1t 굽힘에서도 균열이 발생되지 않는 조건을 동시에 만족하였다.As shown in Table 2, the invention materials (1), (2) made of the present invention steel is both 780MPa or more tensile strength, 18% or more elongation, tensile strength x elongation balance is 15000 (MPa x%) or more, Satisfies the condition that no crack occurs even in 1t bending.

반면에, 본 발명강의 성분범위를 모두 만족시키지 않는 종래강 및 비교강으로 제조된 종래재(1),(2) 및 비교재(3),(4)는 기계적 성질이 본 발명 수준에 도달하지 못하였다.On the other hand, conventional materials (1), (2) and comparative materials (3) and (4) made of conventional steel and comparative steel that do not satisfy all the component ranges of the present invention steel do not reach the level of the present invention. I could not.

발명강을 이용하지만 권취온도가 본 발명범위보다 높은 비교재(1)의 경우에는, 석출물들이 조대화되면서 석출강화효과가 저하되어 인장강도가 저하되었다. 또한, 발명강을 이용하지만 권취온도가 본 발명범위보다 낮은 비교재(2)의 경우에는, (Ti,Nb,Mo)C계 석출물의 석출이 억제되고 베이나이트 등의 저온변태조직이 생성되어 기계적 성질이 본 발명 수준에 미치지 못하였다.In the case of the comparative material (1) which uses the invention steel but the coiling temperature is higher than the scope of the present invention, as the precipitates coarsen, the precipitation strengthening effect is lowered and the tensile strength is lowered. In addition, in the case of the comparative material (2) which uses the invention steel but the winding temperature is lower than the range of the present invention, precipitation of (Ti, Nb, Mo) C-based precipitates is suppressed, and low-temperature transformation structures such as bainite are formed and mechanical The properties fell short of the present level.

한편, 상기 표2의 모든 시편들은 0.1%C 이하의 저탄소를 함유한 페라이트 단상조직강이기 때문에, 굽힘성이 대단히 우수하였다. 즉, 180°완전밀착 굽힘시험에서 균열은 발생되지 않았다.On the other hand, because all the specimens of Table 2 is a ferrite single-phase structure steel containing low carbon of less than 0.1% C, bendability was very excellent. That is, no crack was generated in the 180 ° complete close bending test.

상기한 바와 같이, 본 발명은 강성분을 조정하고 열간압연 및 권취온도를 제어함으로써, 티타늄-니오븀-몰리브덴 복합탄화물로 석출강화된 페라이트 단상조직강을 갖고 기계적 성질이 우수한 인장강도 780MPa급 열연강판을 제공할 수 있는 효과가 있는 것이다.As described above, the present invention provides a tensile strength 780MPa grade hot rolled steel sheet having excellent mechanical properties by adjusting the steel component and controlling the hot rolling and winding temperature, and having ferritic single phase structure steel precipitated and strengthened with titanium-niobium-molybdenum composite carbide. There is an effect that can be provided.

Claims (2)

중량%로 탄소 : 0.06∼0.10%, 실리콘 : 0.2% 이하, 망간 : 1.4∼2.0%, 인 : 0.02% 이하, 황 : 0.005% 이하, 알루미늄: 0.010∼0.050%, 티타늄: 0.050∼0.15%, 니오븀 : 0.020∼0.040%, 몰리브덴 : 0.1~0.3%, 질소 : 60ppm 이하, 잔부 Fe 및 기타 불가피한 불순물을 함유하고, 티타늄-니오븀-몰리브덴 복합탄화물로 석출강화된 페라이트 단상조직을 갖는 인장강도 780 MPa급 구조용 열연강판By weight%, carbon: 0.06 to 0.10%, silicon: 0.2% or less, manganese: 1.4 to 2.0%, phosphorus: 0.02% or less, sulfur: 0.005% or less, aluminum: 0.010 to 0.050%, titanium: 0.050 to 0.15%, niobium : 0.020 ~ 0.040%, Molybdenum: 0.1 ~ 0.3%, Nitrogen: 60ppm or less, Residual Fe and other unavoidable impurities. Hot rolled steel 중량%로 탄소 : 0.06∼0.10%, 실리콘 : 0.2% 이하, 망간 : 1.4∼2.0%, 인 : 0.02% 이하, 황 : 0.005% 이하, 알루미늄: 0.010∼0.050%, 티타늄: 0.050∼0.15%, 니오븀 : 0.020∼0.040%, 몰리브덴 : 0.1~0.3%, 질소 : 60ppm 이하, 잔부 Fe 및 기타 불가피한 불순물을 함유하는 강 슬라브를 재가열하고 오스테나이트온도역에서 마무리열간압연한 다음, 550~640℃의 온도범위까지 냉각하고 이 온도에서 권취하는 것을 특징으로 하는 인장강도 780 MPa급 구조용 열연강판의 제조방법By weight%, carbon: 0.06 to 0.10%, silicon: 0.2% or less, manganese: 1.4 to 2.0%, phosphorus: 0.02% or less, sulfur: 0.005% or less, aluminum: 0.010 to 0.050%, titanium: 0.050 to 0.15%, niobium : 0.020 ~ 0.040%, Molybdenum: 0.1 ~ 0.3%, Nitrogen: 60ppm or less, Re-heating steel slab containing remainder Fe and other unavoidable impurities, and finish hot rolling in austenite temperature range, then temperature range of 550 ~ 640 ℃ Method for producing a hot-rolled steel sheet for structural strength 780 MPa class, characterized in that cooled to and wound at this temperature
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Publication number Priority date Publication date Assignee Title
US7749338B2 (en) 2002-12-24 2010-07-06 Nippon Steel Corporation High burring, high strength steel sheet excellent in softening resistance of weld heat affected zone and method of production of same
KR100957937B1 (en) * 2002-12-27 2010-05-13 주식회사 포스코 Method for manufacturing thick hot-rolled steel sheets with tensile strength of 780MPa grade
KR101355744B1 (en) * 2012-09-27 2014-01-29 현대제철 주식회사 Front side member for car and method of manufacturing the same
CN103849811A (en) * 2014-03-31 2014-06-11 武汉钢铁(集团)公司 Low-brittleness 750MPa-level automobile beam steel and manufacturing method thereof
CN114107807A (en) * 2021-11-03 2022-03-01 邯郸钢铁集团有限责任公司 Low-cost light steel 650DB for suspension arm of truck-mounted crane and production method thereof

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