KR20010057596A - a method for welding a duplex stainless steel - Google Patents

a method for welding a duplex stainless steel Download PDF

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Publication number
KR20010057596A
KR20010057596A KR1019990060662A KR19990060662A KR20010057596A KR 20010057596 A KR20010057596 A KR 20010057596A KR 1019990060662 A KR1019990060662 A KR 1019990060662A KR 19990060662 A KR19990060662 A KR 19990060662A KR 20010057596 A KR20010057596 A KR 20010057596A
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South Korea
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welding
stainless steel
gas
phase
duplex stainless
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KR1019990060662A
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Korean (ko)
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최두열
안상곤
손원근
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이구택
포항종합제철 주식회사
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Publication of KR20010057596A publication Critical patent/KR20010057596A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/02Iron or ferrous alloys
    • B23K2103/04Steel or steel alloys
    • B23K2103/05Stainless steel

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)

Abstract

PURPOSE: A method for welding a duplex stainless steel having an excellent welding performance is provided to improve the property of metals to weld without using any additional welding materials and carrying out any heat treatment after the welding. CONSTITUTION: In a method for welding a duplex stainless steel consisting of main components of Cr 20-30%, Ni 4-10%, Mo 1.5-5.0%, N 0.1-0.5%, and C 0.01-0.05%, and the rest of Fe and inevitable impurities, and having an excellent welding performance, a mixture gas of Ar or He gas as an inert gas and nitrogen gas 10-20% for increasing an austenite phase ratio is supplied for preventing oxidization of the surface and improving the welding performance of the stainless steel.

Description

용접성이 우수한 2상 스테인레스강의 용접 방법{a method for welding a duplex stainless steel}Welding method of two-phase stainless steel with excellent weldability {a method for welding a duplex stainless steel}

본 발명은 2상 스테인레스강의 용접방법에 관한 것으로, 화학 플랜트용 소재, 라인파이프 및 유정관 등에 이용되는 내식성이 우수한 2상 스테인레스강의 용접방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a welding method of two-phase stainless steel, and more particularly to a welding method of two-phase stainless steel excellent in corrosion resistance used in chemical plant materials, line pipes, oil well tubes, and the like.

일반적으로, 2상 스테인레스강은 페라이트상과 오스테나이트상이 대략 50:50의 비를 갖는 복합조직을 갖는 강으로, Cr, NI, Mo, N의 성분량을 제어를 통하여 염소이온 환경과 탄산가스 환경에서 우수한 내식성을 보이며, 오스테나이트계 및 페라이트계 스테인레스강에 비해 고강도인 것으로 알려져 있다. 이러한 내식성과 고강도 특성이 우수한 2상 스테인레스강을 용융 용접하면 델타 페라이트 단상에서 응고가 종료되며, 그후의 냉각과정에서 입계 및 입내로부터 Wudmantaten 구조의 오스테나이트상이 석출된 조직으로 된다. 이는 용접열 사이클이 가열, 냉각이 급속적으로 이루어지기 때문에 페라이트상으로부터의 오스테나이트상 석출은 평형상태에 도달하지 못해서 모재에 비해 페라이트상의 비율이 높게 된다. 이 때문에 기계적 성질 및 내식성의 열화를 초래하게 되는 문제가 있다.In general, two-phase stainless steel is a steel having a complex structure in which the ferrite phase and the austenite phase have a ratio of approximately 50:50, and are controlled in the chlorine ion environment and the carbon dioxide gas environment by controlling the amount of Cr, NI, Mo, and N. It shows excellent corrosion resistance and is known to be high strength compared to austenitic and ferritic stainless steels. When the two-phase stainless steel excellent in corrosion resistance and high strength properties is melt-welded, solidification is terminated in the delta ferrite single phase, and austenite phase of Wudmantaten structure is precipitated from grain boundaries and in the mouth during the subsequent cooling process. Since the welding heat cycle is rapidly heated and cooled, the austenite phase precipitation from the ferrite phase does not reach an equilibrium state, so that the ratio of the ferrite phase is higher than that of the base material. For this reason, there exists a problem which causes deterioration of mechanical property and corrosion resistance.

이러한 문제점으로 인하여 일반적으로 Ni함량이 높은 용접재료를 공급하거나 용접재료를 사용하지 않을 경우, 용접후 열처리를 통하여 용접금속의 페라이트상과 오스테나이트상의 상비율을 조절함으로써 용접 금속의 성질을 개선하고 있다.Due to these problems, in general, when a high Ni content welding material is supplied or a welding material is not used, the properties of the weld metal are improved by controlling the phase ratio of the ferrite phase and the austenite phase of the weld metal through heat treatment after welding. .

본 발명은 상기의 요망되는 과제를 해결하기 위하여 안출된 것으로서 2상 스테인레스강의 용접시 용접 재료를 사용하지 않으며, 또한 용접후 열처리를 하지 않으면서, 용접 금속의 성질을 개선시키는데 그 목적이 있다.SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object thereof is to improve the properties of a weld metal without using a welding material during welding of two-phase stainless steel and without performing heat treatment after welding.

본 발명은 상기 목적을 달성하기 위하여, Cr : 20∼30%, Ni : 4∼10%, Mo : 1.5∼5.0%, N : 0.1∼0.5%, C : 0.01∼0.05%을 포함하고, 잔부는 Fe 및 불가피한 불순물을 함유하는 2상 스테인레스강의 용접방법에 있어서, 불활성 기체인 Ar 또는 He 가스에 질소가스를 10∼20% 섞은 혼합가스를 보호가스로 공급하는 표면의 산화방지 및 용접성이 우수한 2상 스테인레스강의 용접방법을 제공한다.In order to achieve the above object, the present invention includes Cr: 20 to 30%, Ni: 4 to 10%, Mo: 1.5 to 5.0%, N: 0.1 to 0.5%, and C: 0.01 to 0.05%, and the balance is In the welding method of two-phase stainless steel containing Fe and unavoidable impurities, two-phase excellent in anti-oxidation and weldability of the surface supplying a mixed gas containing 10-20% of nitrogen gas to Ar or He gas, which is an inert gas, as a protective gas. Provides welding method of stainless steel.

이하, 본 발명을 설명한다.Hereinafter, the present invention will be described.

본 발명은 주성분으로 Cr : 20∼30%, Ni : 4∼10%, Mo : 1.5∼5.0%, N : 0.1∼0.5%, C : 0.01∼0.05%를 포함하고, 잔부는 Fe 및 불가피한 불순물을 함유하는 2상 스테인레스강을 용접할 때, 표면의 산화방지 및 용접성 개선을 목적으로 공급되는 보호가스로 불활성 기체인 Ar 또는 He 가스에 질소가스를 10∼20% 섞은 혼합가스를 사용하는 것을 특징으로 하는 2상 스테인레스강의 용접방법에 관한 것이다.The present invention contains Cr: 20-30%, Ni: 4-10%, Mo: 1.5-5.0%, N: 0.1-0.5%, C: 0.01-0.05%, and the balance includes Fe and unavoidable impurities. When welding two-phase stainless steel containing, it is used as a protective gas supplied for the purpose of preventing oxidation of the surface and improving weldability, using a mixed gas containing 10-20% of nitrogen gas in Ar or He gas, which is an inert gas. It relates to a welding method of two-phase stainless steel.

2상 스테인레스강의 용접시 보호가스로 질소가스를 혼합하여 공급한 이유는용접열에 의해 보호가스 중의 질소분자가 질소원자로 분해되어 용융금속으로 확산되어 들어감으로써 용접금속의 질소농도를 증가시켜 오스테나이트상의 비율을 높여주기 때문이다. 이것은 질소가 강력한 오스테나이트 형성원소이기 때문이다. 그러나 질소가스가 20%보다 많이 공급되면 용접금속에 기공이 발생하여 용접결함을 양성할 우려가 있으며, 반대로 그 양이 10%보다 작으면 용접금속 성질 개선에 큰 기여를 하지 못한다.The reason for supplying nitrogen gas as a protective gas during welding of two-phase stainless steel is that the nitrogen molecules in the protective gas are decomposed into nitrogen atoms and diffused into the molten metal by welding heat to increase the nitrogen concentration of the weld metal to increase the austenite phase ratio. Because it raises. This is because nitrogen is a strong austenite forming element. However, if more than 20% of nitrogen gas is supplied, there is a concern that porosity occurs in the weld metal to cultivate weld defects. On the contrary, if the amount of nitrogen gas is less than 10%, it does not contribute significantly to the improvement of the properties of the weld metal.

이하 본 발명의 실시예를 설명한다.Hereinafter, embodiments of the present invention will be described.

(실시예)(Example)

표 1에 나타낸 화학성분을 주성분으로 하는 두께 3mm의 2상 스테인레스강 판재에 대해서 아르곤 가스와 질소가스의 혼합가스를 보호가스로 공급하면서 플라즈마 아크 용접을 실시하였다. 이 때 질소가스의 함량을 0∼25%로 변화시켰다.Plasma arc welding was performed on a two-phase stainless steel sheet having a thickness of 3 mm having a chemical component shown in Table 1 while supplying a mixed gas of argon gas and nitrogen gas as a protective gas. At this time, the nitrogen gas content was changed to 0-25%.

표 2는 용접조건과 질소가스 함량에 따른 용접금속의 페라이트 함량과 180도 굽힘시험결과를 보여주는 것이다. 질소 함량이 0%, 5%일 때는 용접금속에서의 페라이트 함량이 각 각 64%, 61%로 모재의 53%로 보다 상당히 높았으며, 이로 인하여 굽힘시험에서도 균열이 발생하였다. 그러나 질소 함량이 10%인 경우는 페라이트 함량이 54%로 모재와 거의 동일하였으며, 굽힘시험에서도 양호한 결과를 보였다. 한편 질소함량이 25%인 경우의 페라이트 함량은 모재와 거의 동일하였지만 용접 금속에 기공이 다량 존재하였기 때문에 굽힘 특성이 불량하였다.Table 2 shows the ferrite content and 180 degree bending test results of weld metal according to welding conditions and nitrogen gas content. When the nitrogen content was 0% and 5%, the ferrite content of the weld metal was 64% and 61%, respectively, which was significantly higher than that of the base metal, which was 53% of the base metal. Thus, cracking occurred in the bending test. However, when the nitrogen content was 10%, the ferrite content was 54%, which was almost the same as that of the base material, and the bending test showed good results. On the other hand, the ferrite content in the case of nitrogen content of 25% was almost the same as the base material, but the bending characteristics were poor because a large amount of pores in the weld metal.

CC SiSi MnMn CrCr MoMo NiNi NN 0.020.02 0.520.52 1.121.12 22.522.5 3.243.24 5.655.65 0.1650.165

NoNo Ar+%N2Ar +% N2 페라이트(%)ferrite(%) 굽힙Bend 비고Remarks 1One 00 6464 불량Bad - 플라즈마 아크 용접용접전류 : 180A용접속도 : 0.9m/분-Plasma arc welding welding current: 180A Connection degree: 0.9m / min 22 55 6161 불량Bad 33 1010 5454 우수Great 44 2525 5050 불량Bad 모재Base material 5353

상술한 바와 같이, 본 발명에 의하면 표면의 산화방지 및 용접성 개선이 우수한 2상 스테인레스강의 용접방법을 제공한다.As described above, the present invention provides a welding method of two-phase stainless steel having excellent surface oxidation prevention and weldability improvement.

Claims (1)

Cr : 20∼30%, Ni : 4∼10%, Mo : 1.5∼5.0%, N : 0.1∼0.5%, C : 0.01∼0.05%을 포함하고, 잔부는 Fe 및 불가피한 불순물을 함유하는 2상 스테인레스강의 용접방법에 있어서, 불활성 기체인 Ar 또는 He 가스에 질소가스를 10∼20% 섞은 혼합가스를 보호가스로 공급하는 것을 특징으로 하는 표면의 산화방지 및 용접성이 우수한 2상 스테인레스강의 용접방법.2-phase stainless steel containing Cr: 20-30%, Ni: 4-10%, Mo: 1.5-5.0%, N: 0.1-0.5%, C: 0.01-0.05%, the balance being Fe and unavoidable impurities A welding method for steel, wherein the mixed gas containing 10 to 20% of nitrogen gas to Ar or He gas, which is an inert gas, is supplied as a protective gas.
KR1019990060662A 1999-12-22 1999-12-22 a method for welding a duplex stainless steel KR20010057596A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6793119B2 (en) * 2000-02-28 2004-09-21 Dsm Ip Assets B.V. Process for welding duplex steel
KR100805060B1 (en) * 2001-12-26 2008-02-20 주식회사 포스코 TIG WELDING METHOD TO IMPROVE PITTING CORROSION RESISTANCE OF 22%Cr DUPLEX STAINLESS STEEL WELDS
KR100908684B1 (en) * 2002-12-30 2009-07-22 주식회사 포스코 TIG welding method of super ferritic stainless steel
WO2012007664A1 (en) * 2010-07-13 2012-01-19 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hybrid arc/laser-welding method for aluminized steel parts using gammagenic elements and a gas containing less than 10 % of nitrogen or oxygen
CN107900494A (en) * 2017-11-03 2018-04-13 山西太钢不锈钢股份有限公司 A kind of S32750 super-duplex stainless steels flat cold-rolled sheet self-melting and welding method

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JPS61162271A (en) * 1985-01-08 1986-07-22 Sumitomo Metal Ind Ltd Penetration welding method
JPS62286676A (en) * 1986-06-03 1987-12-12 Sumitomo Metal Ind Ltd Welding method for two-phase stainless steel products
JPH10216942A (en) * 1997-01-31 1998-08-18 Sumitomo Metal Ind Ltd Consumable electrode type gas shielded metal arc welding method

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
JPS61162271A (en) * 1985-01-08 1986-07-22 Sumitomo Metal Ind Ltd Penetration welding method
JPS62286676A (en) * 1986-06-03 1987-12-12 Sumitomo Metal Ind Ltd Welding method for two-phase stainless steel products
JPH10216942A (en) * 1997-01-31 1998-08-18 Sumitomo Metal Ind Ltd Consumable electrode type gas shielded metal arc welding method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6793119B2 (en) * 2000-02-28 2004-09-21 Dsm Ip Assets B.V. Process for welding duplex steel
KR100805060B1 (en) * 2001-12-26 2008-02-20 주식회사 포스코 TIG WELDING METHOD TO IMPROVE PITTING CORROSION RESISTANCE OF 22%Cr DUPLEX STAINLESS STEEL WELDS
KR100908684B1 (en) * 2002-12-30 2009-07-22 주식회사 포스코 TIG welding method of super ferritic stainless steel
WO2012007664A1 (en) * 2010-07-13 2012-01-19 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hybrid arc/laser-welding method for aluminized steel parts using gammagenic elements and a gas containing less than 10 % of nitrogen or oxygen
FR2962673A1 (en) * 2010-07-13 2012-01-20 Air Liquide ARC / LASER HYBRID WELDING PROCESS OF ALUMINIZED STEEL PARTS WITH GAMAGENIC ELEMENTS
CN102985215A (en) * 2010-07-13 2013-03-20 乔治洛德方法研究和开发液化空气有限公司 Hybrid arc/laser-welding method for aluminized steel parts using gammagenic elements and a gas containing less than 10 % of nitrogen or oxygen
JP2013533807A (en) * 2010-07-13 2013-08-29 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード Hybrid arc / laser welding process for aluminized steel parts using gammagenic elements and a gas containing less than 10% nitrogen or oxygen
US9321132B2 (en) 2010-07-13 2016-04-26 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Hybrid arc/laser-welding method for aluminized steel parts using gammagenic elements and a gas containing less than 10% of nitrogen or oxygen
CN107900494A (en) * 2017-11-03 2018-04-13 山西太钢不锈钢股份有限公司 A kind of S32750 super-duplex stainless steels flat cold-rolled sheet self-melting and welding method

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