KR20010037133A - Repellent Insecticide paint - Google Patents

Repellent Insecticide paint Download PDF

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Publication number
KR20010037133A
KR20010037133A KR1019990044471A KR19990044471A KR20010037133A KR 20010037133 A KR20010037133 A KR 20010037133A KR 1019990044471 A KR1019990044471 A KR 1019990044471A KR 19990044471 A KR19990044471 A KR 19990044471A KR 20010037133 A KR20010037133 A KR 20010037133A
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South Korea
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weight
repellent
paint
insecticide
insecticidal
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KR1019990044471A
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Korean (ko)
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장봉석
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안민동
국보제약 주식회사
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Priority to KR1019990044471A priority Critical patent/KR20010037133A/en
Publication of KR20010037133A publication Critical patent/KR20010037133A/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: Insecticidal or insect repellent paint containing pyrethroid and organic phosphorous insecticidal components and a repellent and using water as a solvent without volatile organic compounds is provided, which makes insects less resistant to insecticidal components, has synergistic and repellent effects, and also has friendly environment. CONSTITUTION: This insecticidal or insect repellent paint comprises 1 to 5% by weight of a pyrethroid insecticidal component, 1 to 15% by weight of an organic phosphorous insecticidal component, 1 to 5% by weight of a repellent component, 10 to 20% by weight of a surfactant, 50 to 80% by weight of water, 10 to 20% by weight of propyelene glycol and 10,000 to 20,000% by weight of paint. The paint has long lasting insecticidal effects by contact against various insects but is not harmful to human and warm-blooded animals.

Description

기피 및 살충 페인트{Repellent Insecticide paint}Repellent Insecticide paint

본 발명은 기피 및 살충페인트에 관한 것이다.The present invention relates to repellent and insecticide paints.

화학산업에 있어서 환경문제는 우리 모두가 해결하여야 할 과제로서 산업계는 이에 대한 준비작업을 꾸준히 진행해 왔다. 대기중으로 방출되고 있는 탄화수소의 양은 연 2000만톤으로 이중 18%인 350만톤은 도료에서 발생된다. 95년부터 휘발성 유기화합물(VOC)을 배출하는 시설에 대해 단계적으로 규제할 계획이며, 도장 작업시 가능한 한 유기용제의 사용을 억제하고 무기용제 사용을 적극 권장하고 있다.The environmental problem in the chemical industry is a challenge for all of us, and the industry has been constantly preparing for it. The amount of hydrocarbons released into the atmosphere is 20 million tons per year, of which 18%, or 3.5 million tons, comes from paints. In 1995, the company plans to phase-out facilities that emit volatile organic compounds (VOCs), and it is strongly recommended to limit the use of organic solvents and to use inorganic solvents when possible.

도료 산업계는 이에 대한 대책 마련을 위해 환경 대응형 도료인 저용제형 도료와 수계도료, 분체도료 및 특수경화형 도료 기술을 검토중에 있으며 자용차용 수계도료는 이미 상당한 기술수준에 도달하고 있다.The paint industry is considering low-solvent paints, water-based paints, powder paints, and special hardening paint technologies, which are environmentally compatible paints, and water-based paints for automobiles have already reached a considerable technical level.

미국, 일본, 독일, 영국, 네덜란드 및 유럽공동체(EEC) 국가들의 VOC 규제의 예를 보면, 1966년 미국 로스엔젤레스에서 규칙(Rule) 66이 발표된 이래 미국과 유럽에서 유기용제 배출에 대한 규제가 점점 강화되고 있다. 현재 미국과 유럽에서 자동차 도료 및 도장기술의 개발에 있어서 가장 중요한 모티브는 유기 용제 배출 규제 등의 환경보호 측면이다.Examples of VOC regulations in the United States, Japan, Germany, the United Kingdom, the Netherlands, and the European Community (EEC) states that since the release of Rule 66 in Los Angeles, the United States in 1966, regulations on organic solvent emissions in the United States and Europe have been It is getting stronger. At present, the most important motif in the development of automotive paint and coating technology in the United States and Europe is the environmental protection aspect such as the regulation of organic solvent emission.

도료 업계에서와 마찬가지로 살충제 업계에서도 세계적인 추세에 따라 휘발성 유기화합물의 사용을 억제하고자 꾸준히 연구 노력하고 있다. 그 결과 종래에는 휘발성 유기화합물인 탄화수소계 용제로 살충제를 제조 및 희석하여 해충을 퇴치하였으나 근래에는 휘발성 유기화합물을 사용하지 않고 물을 이용하여 살충제를 제조한 유형의 제품(EW, Emulsion in Water)을 개발하게 되었다. 휘발성 유기화합물을 사용하지 않고 물을 이용한 기피 및 살충페인트(이하, EW형 살충제로 표현.)의 개발은 인류 최대 문제인 자연환경 보호에 큰 노력이 될 것이다.As in the paint industry, the pesticide industry is constantly researching to suppress the use of volatile organic compounds in accordance with global trends. As a result, in the past, pesticides were prepared and diluted with hydrocarbon solvents, which are volatile organic compounds, in order to combat pests. However, in recent years, a type of product (EW, Emulsion in Water) prepared using pesticides without using volatile organic compounds is used. Developed. Avoiding volatile organic compounds and using water to avoid and develop insecticide paints (hereinafter referred to as EW type insecticides) will be a great effort to protect the natural environment, which is the biggest problem of humankind.

EW형 살충제의 또 하나의 장점은 약제가 물에 녹아 있어서 사용시 희석제로 물을 사용하므로 탄화수소계 용제에 희석하였을 때보다 훨씬 빨리 확산된다.Another advantage of the EW type insecticide is that the drug is dissolved in water and uses water as a diluent when used, so it spreads much faster than when diluted in a hydrocarbon solvent.

프랑스 특허 제 1050895호 및 2,593,821호에는 접촉에 의하여 살충 효력이 생기는 도료의 제조방법에 관하여 설명되어 있다.French Patent Nos. 1050895 and 2,593,821 describe a process for the preparation of paints in which the insecticidal effect is brought about by contact.

이들 특허에서 제조된 페인트의 살충작용은 건조후 조성 성분중 하나의 극성에 의하여 다공성의 얇은 막을 형성하고 이 다공을 통하여 살충성분이 염기의 표면장력효과에 따라 표면으로 이동하면서 나타나도록 설계되어 있다.The insecticidal action of the paints prepared in these patents is designed to form a porous thin film by the polarity of one of the compositional components after drying, and through this pore, the insecticidal components move to the surface according to the surface tension effect of the base.

또한, 이들 특허에서는 살충성분을 부탄올, 톨루엔, 크실렌(xylene), 이소부틸 아세테이트 및 테레빈유(terebenthin) 등과 같은 휘발성 유기 화합물을 사용하여 제조하고 있다.In addition, these patents produce pesticidal components using volatile organic compounds such as butanol, toluene, xylene, isobutyl acetate and terebenthin.

또한 동일 약제를 같은 대상 해충에 장기간 사용함으로써 약제에 대한 저항성(내성)이 생겨서 살충효과가 떨어질 수 있다.In addition, by using the same drug for the same target pests for a long time, resistance (drug resistance) to the drug may be generated and the insecticidal effect may be reduced.

본 발명은 위와 같은 문제점 및 개선요구를 감안하여 새로운 유형의 기피 및 살충페인트의 제조방법을 제공하고자 하는 것이다.The present invention is to provide a method of producing a new type of repellent and insecticide paint in view of the above problems and needs to improve.

본 발명자들은 이와 같은 휘발성 유기화합물을 사용하지 않고 살충성분을 물과 환경 친화적인 프로필렌글리콜을 사용하여 기피 및 살충페인트를 제조하였다.The present inventors prepared the repellent and insecticide paint using pesticide components using water and environmentally friendly propylene glycol without using such volatile organic compounds.

또한 본 발명의 기피 및 살충페인트는 살충성분에 내성이 생기는 문제를 해소하기 위하여 유기인계 살충성분과 피레스로이드계 살충성분 및 기피제를을 함께 사용함으로써 저항성을 없애고 또한 약효상승 효과와 기피효과도 얻을 수 있도록 하였다.In addition, the repellent and insecticide paint of the present invention can eliminate the resistance by using an organophosphorus insecticide component, a pyrethroid insecticide component and a repellent agent in order to solve the problem of resistance to the pesticidal components, and also increase the efficacy and repellent effect It was made.

따라서 본 발명은 피레스로이드계 살충성분과 유기인계 살충성분 및 기피제를 함유하고 휘발성 유기화합물을 사용하지 않고 물을 용제로 사용하는 새로운 유형의 기피 및 살충페인트를 제공한다.Therefore, the present invention provides a novel type of repellent and insecticide paint containing pyrethroid insecticide, organophosphorus insecticide and repellent and using water as a solvent without using volatile organic compounds.

본 발명의 기피 및 살충페인트는, 피레스로이드계 살충성분, 유기인계 살충성분, 물, 프로필렌글리콜 및 도료를 함유하며, 여기에 통상의 부형제, 보조제를 첨가하여 제조된다.The repellent and insecticide paints of the present invention contain pyrethroid insecticides, organophosphorus insecticides, water, propylene glycol and paints, and are prepared by adding conventional excipients and auxiliaries.

보다 바람직하게, 본 발명의 기피 및 살충페인트는 피레스로이드계 살충성분 1- 5중량%, 유기인계 살충성분 1-15중량%, 기피제 1-5중량%, 계면활성제 10-20중량%, 물 50-80중량%, 프로필렌글리콜 10-20중량% 및 도료 10000-20000중량%를 함유하며, 여기에 통상의 부형제 및 보조제를 첨가할 수 있다.More preferably, the repellent and insecticide paint of the present invention is 1-5% by weight of pyrethroid insecticides, 1-15% by weight of organophosphorus insecticides, 1-5% by weight of repellents, 10-20% by weight of surfactants, water 50 -80% by weight, 10-20% by weight of propylene glycol and 10000-20000% by weight of paint, and conventional excipients and auxiliaries can be added thereto.

본 발명의 기피 및 살충페인트에 있어서, 피레스로이드(Pyrethroides)계 살충성분은, 예를 들면, 델타메트린(Deltamethrin), 프탈로메트린(Phthalomethrin), 싸이할로트린(Cyhalothrin), 싸이플로트린(Cyfluthrin), 카데스린(Kadethrin), 에스바이오알레트린(Esbioallethrin)을 사용할 수 있다.In the repellent and insecticide paints of the present invention, the pyrethroides insecticide component is, for example, deltamethrin, Phthalomethrin, Cyhalothrin, Cyflothrin Cyfluthrin, Kadethrin, Esbioallethrin can be used.

유기인(Organophosphorous)계 살충성분은, 예를 들면, 클로르피리포스(Chlorpyrifos), 프로페탐포스(Propetamphos), 디클로로보스(Dichlorovos), 다이아지논(Diazinon)을 사용할 수 있다.The organophosphorous insecticide component may be, for example, chlorpyrifos, propetamphos, dichlorovos, or diazinon.

기피제(Repellent) 성분은 퍼메트린(Permethrin), 사이퍼메트린(Cypermethrin)등을 사용할 수 있다.Repellent ingredients include Permethrin and Cypermethrin.

계면활성제로는 비이온성 계면활성제인 폴리옥시 알킬렌알킬 에테르계 화합물, 폴리옥시 알킬렌알킬 페닐 에테르계 화합물, 폴리옥시 에틸렌 지방산 에스테르계 화합물, 다가 알코올 지방산 에스테르 화합물, 다가 알코올 지방산 에테르 화합물, 다가알콜 지방산 부분 에테르, 폴리옥시 에틸렌 폴리옥시 프로필렌 글리콜, 폴리옥시 에틸렌 다가 알코올 지방산 부분 에스테르 화합물등이 사용되며 필요하다면 양이온성 계면활성제, 음이온성 계면활성제, 양쪽성 계면활성제를 약간량씩 사용할 수 있다.As surfactant, polyoxy alkylene alkyl ether compound which is a nonionic surfactant, polyoxy alkylene alkyl phenyl ether compound, polyoxy ethylene fatty acid ester compound, polyhydric alcohol fatty acid ester compound, polyhydric alcohol fatty acid ether compound, polyhydric alcohol Fatty acid partial ethers, polyoxy ethylene polyoxy propylene glycol, polyoxy ethylene polyhydric alcohol fatty acid partial ester compounds and the like are used, and if necessary, cationic surfactants, anionic surfactants and amphoteric surfactants may be used in small amounts.

페인트 기제는 통상의 아크릴 수지(Acrylic resin)계성분을 사용하며, 여기에 부틸 히드록시 톨루엔(BHT), 부틸 히드록시 아니솔(BHA)등과 같은 산화방지제, 분산제, 안정화제, 점도조절제등을 첨가하여 통상의 방법으로 제조할 수 있다.The paint base uses a conventional acrylic resin-based component, and adds an antioxidant such as butyl hydroxy toluene (BHT) and butyl hydroxy anisole (BHA), a dispersant, a stabilizer, a viscosity modifier, and the like. It can be manufactured by a conventional method.

다음의 실시예로써 본 발명을 더욱 상세히 설명한다.The present invention is explained in more detail by the following examples.

실시예 1.Example 1.

델타메트린 1 - 5 gDeltamethrin 1-5 g

클로피리포스 1 - 5 gClopipulose 1-5 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

물 69 - 77 gWater 69-77 g

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

실시예 2Example 2

프탈로메트린 1 - 5 gPhthalomethrin 1-5 g

프로페탐포스 2 - 15 gPropetafoam 2-15 g

퍼메트린 1 - 5 gPermethrin 1-5 g

카데스린 0.1 - 0.5 gCatherin 0.1-0.5 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

물 58.4 - 75.9 gWater 58.4-75.9 g

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

실시예 3Example 3

델타메트린 1 - 5 gDeltamethrin 1-5 g

프로페탐포스 1 - 5 gPropetafoam 1-5 g

퍼메트린 1 - 5 gPermethrin 1-5 g

에스바이오알레트린 0.5 - 2 gEsbioaltrin 0.5-2 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

물 67 - 76.5 gWater 67-76.5 g

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

실시예 4Example 4

델타메트린 1 - 5 gDeltamethrin 1-5 g

프로페탐포스 5 - 15 gPropetafoam 5-15 g

싸이퍼메트린 1 - 5 gCypermethrin 1-5 g

카데스린 0.1 - 0.5 gCatherin 0.1-0.5 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

물 57.5 - 72.9 g57.5-72.9 g of water

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

실시예 5Example 5

델타메트린 1 - 5 gDeltamethrin 1-5 g

다이아지논 5 - 15 gDiazinon 5-15 g

싸이퍼메트린 1 - 5 gCypermethrin 1-5 g

카데스린 0.2 - 2 gCascaderin 0.2-2 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

트리코젠 0.1 - 1 gTricogen 0.1-1 g

물 56 - 72.7 g56-72.7 g of water

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

실시예 6Example 6

델타메트린 1 - 5 gDeltamethrin 1-5 g

클로르피리포스 2 - 6 gChlorpyriphos 2-6 g

싸이퍼메트린 1 - 5 gCypermethrin 1-5 g

카데스린 0.2 - 2 gCascaderin 0.2-2 g

프로필렌글리콜 15 g15 g of propylene glycol

계면활성제 6 g6 g of surfactant

트리코젠 0.1 - 1 gTricogen 0.1-1 g

물 65 - 75.7 g65-75.7 g of water

도료 18,000 g18,000 g of paint

상기의 성분을 통상의 도료에 희석하여 기피 및 살충페인트를 제조한다.The above components are diluted in conventional paints to prepare repellent and insecticide paints.

본 발명의 기피 및 살충페인트는 휘발성 유기화합물을 사용하지 않고 기피 및 살충제 성분에 물과 환경 친화적인 프로필렌글리콜을 사용함으로써, 환경오염의 문제를 해소하고, 또한, 피레스로이드계 살충성분과 유기인계 살충성분 및 기피제를 함께 함유하므로 살충성분에 대한 해충의 저항성 형성을 억제하며, 보다 상승된 살충작용 효과와 기피효과를 갖는다.The repellent and insecticide paint of the present invention eliminates the problem of environmental pollution by using water and environmentally friendly propylene glycol as a repellent and insecticide component without using volatile organic compounds, and also has a pyrethroid insecticide component and an organophosphorus insecticide. Containing both the ingredient and the repellent, it inhibits the formation of resistance of the pest to the pesticidal component, and has a more effective insecticidal and repellent effect.

Claims (3)

피레스로이드계 살충성분, 유기인계 살충성분, 기피제 성분, 계면할성제, 물, 프로필렌글리콜 및 도료를 함유하는 기피 및 살충 페인트.A repellent and insecticide paint containing pyrethroid insecticides, organophosphorus insecticides, repellents, surfactants, water, propylene glycol and paints. 제 1항에 있어서, 피레스로이드계 살충성분 1- 5중량%, 유기인계 살충성분 1-15중량%, 기피제 성분 1- 5중량%, 계면활성제 10-20중량%, 물 50-80중량%, 프로필렌글리콜 10-20중량% 및 도료 10000-20000중량%를 함유하는 기피 및 살충 페인트.According to claim 1, 1 to 5% by weight of pyrethroid insecticide components, 1 to 15% by weight organophosphorus insecticide components, 1 to 5% by weight repellent components, 10-20% by weight surfactant, 50-80% by weight water, Repellent and insecticidal paints containing 10-20% by weight of propylene glycol and 10000-20000% by weight of paint. 제 1항 또는 2항에 있어서, 피레스로이계 살충성분으로서 델타메트린, 프탈로메트린, 카데스린, 에스바이오알레트린에서 선택된 살충제를 사용하고, 유기인계 살충제로서 클로르피리포스, 프로페탐포스, 디클로로보스, 다이아지논에서 선택된 살충제를 사용하고, 기피제로 퍼메트린, 사이퍼메트린에서 선택된 기피제를 사용하여 제조된 기피 및 살충페인트.The insecticide selected from deltamethrin, phthalomemetrin, cardeslin, and esbioaltrin as a pyrethroid insecticidal component is used, and chlorpyrifos and propetafoam are used as organophosphorus insecticides. Repellent and insecticide paint prepared using pesticides selected from dichloroboss, diazinone, and repellents selected from permethrin and cypermethrin as repellents.
KR1019990044471A 1999-10-14 1999-10-14 Repellent Insecticide paint KR20010037133A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2397021A (en) * 2002-12-30 2004-07-14 Inst Medical Res Insecticidal Paint Composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2397021A (en) * 2002-12-30 2004-07-14 Inst Medical Res Insecticidal Paint Composition
GB2397021B (en) * 2002-12-30 2006-09-13 Inst Medical Res Insecticidal paint composition

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