KR20010034343A - Smoking articles - Google Patents
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- KR20010034343A KR20010034343A KR1020007008078A KR20007008078A KR20010034343A KR 20010034343 A KR20010034343 A KR 20010034343A KR 1020007008078 A KR1020007008078 A KR 1020007008078A KR 20007008078 A KR20007008078 A KR 20007008078A KR 20010034343 A KR20010034343 A KR 20010034343A
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- tobacco
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- activated carbon
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/12—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
- Paper (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Seasonings (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
생담배 연기는, 특히 궐련을 예를 들면 재떨이에 두었을 때 비-흡연자가 불쾌하게 느낄 수 있고, 이의 감소가 바람직하다. 직접 마시는 연기의 변화는 흡연자의 물품에 대한 인식에 영향을 끼친다.The live tobacco smoke may be unpleasant to the non-smoker, in particular when the cigarette is placed in an ashtray, for example, the reduction of which is preferred. Changes in direct smoke affect the smoker's perception of the item.
본 발명은 흡연 물품의 연기를 변화시키기 위해 활성탄을 이용한다. 물론, 활성탄은 사실상 이의 탁월한 흡착성이 알려진 이후로, 흡연 물품에 및 다양한 목적을 위해 이용되어 왔다.The present invention utilizes activated carbon to change the smoke of smoking articles. Of course, activated carbon has been used in smoking articles and for a variety of purposes since virtually its excellent adsorption is known.
예를 들면, 필터의 다양한 탄소함량의 효과가 1964년 10월의 5th General Assembly of CORESTA, Vienna에서 제출된 보고서에서 Williams 등에 의해 조사되었고 Beitrage zur Tabakforschung, Vol. 3 part 3, pages 233-242로 재판되었다. 보고서는 상이한 구성의 필터 조각에 의한 직접 마시는 연기의 상이한 구성성분의 다양한 흡착성을 보여준다. 그러나 본 발명자는 담배 로드에 탄소를 배치하는 것; 즉 탄소가 필터에서의 상태와는 매우 상이한 상태에 놓이는 것에 관심이 있다.For example, the effects of various carbon contents in filters have been investigated by Williams et al. In a report submitted by the 5th General Assembly of CORESTA, Vienna, October 1964, and published in Beitrage zur Tabakforschung, Vol. Trial of 3 part 3, pages 233-242. The report shows the various adsorption properties of different components of direct drinking smoke by different pieces of filter pieces. However, the inventors have found that disposing carbon on tobacco rods; In other words, there is an interest in placing carbon in a state very different from that in the filter.
GB-A-1512352는 직접 마시는 연기에 영향을 끼치기 위해 담배 로드에 담배에 부착되는 탄소의 활성화된 다공성 입자의 사용을 보여준다. GB-A-1348580은 직접 마시는 연기에서 입자와 니코틴의 감소를 달성하는 궐련을 제조하기 위한 주요 물질로서 사용되는 활성탄을 함유하는 재구성된 담배 물질의 시트를 보여준다.GB-A-1512352 shows the use of activated porous particles of carbon attached to tobacco in tobacco rods to affect direct drinking smoke. GB-A-1348580 shows a sheet of reconstituted tobacco material containing activated carbon which is used as the main material for producing cigarettes which achieves a reduction of particles and nicotine in direct drinking smoke.
본 발명자가 현재 알고 있는 바로는, 생담배 연기의 감소가 목적인 상황에서 담배 로드에 탄소를 사용하는 유일한 특허 기술은 US-A-5092353(EP-A-378774)이다. 그러나 이 특허 기술에서의 목적은 매우 낮은 투과성(<10 CORESTA 단위)을 가지는 랩핑 페이퍼의 사용에 의해 생담배 연기를 감소시키는 것이다. 이것이 궐련이 자기-소화되도록 하는 경향을 보상하기 위해, 열분해된 알파-셀룰로오즈가 담배 로드에 존재한다.As far as the present inventors are aware, the only patented technology using carbon in tobacco rods in situations where the aim is to reduce live tobacco smoke is US-A-5092353 (EP-A-378774). However, the purpose of this patented technology is to reduce live tobacco smoke by the use of wrapping paper with very low permeability (<10 CORESTA units). To compensate for the tendency for cigarettes to self-extinguish, pyrolyzed alpha-cellulose is present in the tobacco rod.
이 열분해된 물질은 활성화 처리를 받지 않는다. 이것이 연기에 끼칠 수 있는 화학적 효과는 언급되지 않았고, 특정 예에서 열분해된 물질은, 비교적 낮은 표면적의 탄소를 부여하게 되는 면 린터이기 때문에 아마도 거의 또는 전혀 영향을 주지 않을 것이다.This pyrolyzed material is not subjected to activation treatment. No chemical effect this could have on the smoke is mentioned, and in certain instances the thermally decomposed material will probably have little or no effect since it is a cotton linter which gives a relatively low surface area of carbon.
본 발명은 궐련, 여송연 및 소형 엽궐련과 같은 흡연 물품에 관한 것이고, 흡연 물품으로부터 생담배 연기의 감소에 관련된 것이다. 생담배 연기는 물품이 탈 때 생성되지만 흡연자에 의해 빨아들여지지 않는 연기이다. 직접 마시는 연기는 흡연 물품이 흡연자에 의해 빨아들여질 때 생성되는 연기이다; 직접 마시는 연기와 생담배 연기의 화학적 성질은 상이하다.FIELD OF THE INVENTION The present invention relates to smoking articles, such as cigarettes, cigars and small cigars, and to the reduction of live tobacco smoke from smoking articles. Tobacco smoke is smoke that is produced when an item is burned but is not absorbed by the smoker. Direct drinking smoke is smoke generated when a smoking article is sucked by a smoker; The chemical properties of direct smoke and live tobacco smoke are different.
그러므로, 본 발명은 연기의 화학적 성질에 영향을 주는 활성탄을 담배 로드에 제공함으로써 이러한 모든 선행기술과 대조되고, 반면 낮은 투과성 페이퍼의 사용, 특히 <10 CORESTA의 페이퍼로 제한되지 않는다.Therefore, the present invention contrasts with all these prior art by providing the tobacco rod with activated carbon that affects the chemistry of the smoke, while not limited to the use of low permeability papers, in particular <10 CORESTA papers.
추가로, 본 발명은 흡연 물품의 더 순한 맛이 흡연자에 의해 직접 마시는 연기에서 인식되고, 동시에 물품 랩퍼의 광범위한 다공성에 걸쳐, 특히 물품의 자기-소화를 막기 위해 특별한 주의를 취할 필요가 없을 정도의 충분한 다공성으로 생담배 연기의 감소가 일어나도록 하는 방법으로 흡연 물품의 담배 로드에 재구성된 담배 시트내 특정 입자 형태로 활성탄의 첨가를 제공한다.In addition, the present invention recognizes that the milder taste of a smoking article is perceived in smoke that is consumed directly by the smoker, while at the same time taking no particular care to prevent the self-extinguishing of the article over the wide porosity of the article wrapper Sufficient porosity provides for the addition of activated carbon in the form of specific particles in the reconstituted tobacco sheet to the tobacco rod of the smoking article in such a way that a reduction in live tobacco smoke occurs.
추가로, 활성탄 입자는 바람직하게는 식물성 기원이어야 하는데, 그렇게 되면 이들이 연기로부터 (특히) 알데하이드의 견고한 흡착을 돕고 실제로 이러한 화합물과 킬레이트 결합을 할 수 있는, 미량의 금속을 함유하기 때문이다. 이들 화합물의 제거는 흡연시 물품의 순한 맛 인식을 향상시키는 데 특히 중요하다.In addition, the activated carbon particles should preferably be of vegetable origin, since they contain traces of metals that can help the solid adsorption of aldehydes (especially) from smoke and actually chelate these compounds. Removal of these compounds is particularly important for improving mild taste perception of articles in smoking.
그러나, 이와 동시에 활성탄은 감소하지 않으며 심지어는 연기의 특정 유익한 휘발성분을 증가시킬 수도 있다.At the same time, however, activated carbon does not decrease and may even increase certain beneficial volatiles in the smoke.
흡연 물품의 "석탄"이 용품을 따라 진행하기 때문에, 입자에 의해 흡착되는 연기 성분은 이러한 입자로부터 대체된다 하더라도 최소로 대체됨을 인식하는 것이 중요하다. 이들은 석탄에서 생성된 극고온(약 800℃ 까지)에 의해 탄소 입자 자체의 물질과 함께 옥사이드 기체로 파괴된다.As the "coal" of the smoking article progresses along the article, it is important to recognize that the smoke component adsorbed by the particles is minimally replaced, even if replaced by such particles. They break down into oxide gas together with the material of the carbon particles themselves by the extremely high temperatures (up to about 800 ° C.) produced from coal.
활성탄 입자를 함유하는 재구성된 담배 시트는 이러한 시트를 제조하는 통상적인 기술로 제조될 수 있고, 이런 기술은 통상적인 제지 기술과 유사하며, 이어서 시트는 담배 로드의 물질이 될 세단된 담배와의 혼입을 위해 세단될 것이다.Reconstituted tobacco sheets containing activated carbon particles can be made by conventional techniques for making such sheets, which techniques are similar to conventional papermaking techniques, and the sheets are then incorporated with shredded tobacco to be the material of tobacco rods. Will be sewed for.
그러나 본 발명의 중요한 적용은 "흡연자가 직접 마는" 담배 블렌드, 즉 포장하지 않고 시판되고 흡연자에 의해 궐련 페이퍼에 랩핑되는 것들일 것이다.An important application of the present invention, however, will be "smoker-directed" tobacco blends, ie those sold commercially without packaging and wrapped in cigarette paper by smokers.
그러므로 본 발명은 세단된 담배와 재구성된 담배 시트의 블렌드를 본 발명의 범위 내에 포함하고, 후자는 활성탄을 함유한다.The present invention therefore encompasses a blend of shredded tobacco and reconstituted tobacco sheets within the scope of the present invention, the latter containing activated carbon.
세단시든 또는 기계 또는 흡연자에 의한 추후 조작시든 간에 시트를 다루는 것은 탄소 입자의 손실을 초래할 수 있고 재구성된 담배 시트는 이 안에 입자의 보유를 돕기 위해 코팅되거나 사이징될 수 있고, 특히 입자 자체는 혼입되기 전에 미세-캡슐화될 수 있다. 후자는 입자 크기를 증가시켜 기계적인 이들의 보유와 크기의 균일성을 증가시키는 장점을 가지지만, 아마도 놀랍게도 이들의 활성에는 영향을 주지 않을 것이다.Handling the sheet, whether sedan or at a later operation by a machine or smoker, can result in the loss of carbon particles and the reconstituted tobacco sheet can be coated or sized to help retain the particles therein, in particular the particles themselves can be incorporated. Prior to micro-encapsulation. The latter has the advantage of increasing the particle size to increase mechanical retention and size uniformity, but perhaps surprisingly will not affect their activity.
실시예 1Example 1
궐련은 US 황색종과 Burley 담배의 혼합물로부터 제조되고, 말린 줄기를 잘라 담배를 팽창시키고, 공정처리하여 1인치 당 32 컷(cpi)으로 절단한다. 동등하게 절단되고 코코넛으로부터 37 ㎛의 평균 입자 크기와 0.5 ㎛ 내지 150 ㎛의 입자 크기 범위의 활성탄 입자 30%를 함유하는 재구성된 담배 시트 20%를 세단된 담배에 혼입한다. 대조 궐련은 활성탄 입자를 제외하고 동일하게 제조된다.Cigarettes are made from a mixture of US yellow species and Burley tobacco, cut dried stems, inflating tobacco, processing and cutting to 32 cuts per inch (cpi). 20% of the reconstituted tobacco sheet, equally cut and containing 30% of the activated carbon particles from the coconut with an average particle size of 37 μm and a particle size ranging from 0.5 μm to 150 μm, is incorporated into the shredded tobacco. Control cigarettes are prepared identically except activated carbon particles.
궐련은 길이 84 mm, 직경 7.9 mm이고 필터가 없다. 랩핑은 2% 칼륨 시트레이트 연소 증강제를 가진, 80 CORESTA 아마-기본 페이퍼이다.The cigarette is 84 mm long, 7.9 mm in diameter and without a filter. Lapping is 80 CORESTA flax-base paper, with 2% potassium citrate combustion enhancer.
궐련을 표준 흡연기에서 흡연시키고 직접 마시는 연기를 증기상과 반-휘발성분 함량에 대해 분석하여 결과를 표 1과 2에 나타내었다.Cigarettes were smoked in a standard smoker and direct smoke was analyzed for vapor phase and semi-volatile content and the results are shown in Tables 1 and 2.
표 1에서 보여지는 것처럼, 특정 알데하이드 및 케톤, 특히 아크롤레인과 부티르알데하이드의 선택적인 현저한 감소가 일어나고, 이들의 제거는 순한 맛을 위해 중요하다. 반면, 맛에 유익한 것으로 생각되는 특정 성분, 특히 리모넨은 표준에 비해서 실제로 증가했다.As shown in Table 1, a selective significant reduction of certain aldehydes and ketones, in particular acrolein and butyraldehyde, occurs and their removal is important for a mild taste. On the other hand, certain ingredients that are thought to be beneficial for taste, especially limonene, have actually increased compared to the standard.
덜 선택적이긴 하지만 유사한 감소가 표 2에서 보여진 것처럼 반-휘발성분에서도 나타난다.Although less selective, a similar reduction is seen for semi-volatiles as shown in Table 2.
실시예 2Example 2
궐련과 대조궐련은 실시예 1과 동일한 담배 블렌드와 재구성된 담배 시트를 이용해 제조되지만, 각각 25, 50, 80 및 180 CORESTA 단위 다공성의 페이퍼를 사용한다. 표 3에서 보여진 것처럼, 본 발명의 궐련과 대조궐련으로부터의 생담배 연기에서 반-휘발성분과 니코틴 함량 모두가 상당히 감소했다. 증가된 일산화탄소와 이산화탄소 생성은 담배 시트내 탄소 입자의 존재 때문인 것으로 생각된다.Cigarettes and control cigarettes were prepared using the same tobacco blend and reconstituted tobacco sheets as in Example 1, but using paper of 25, 50, 80 and 180 CORESTA unit porosity, respectively. As shown in Table 3, both the semi-volatile and nicotine contents were significantly reduced in the live tobacco smoke from the cigarettes of the present invention and the control cigarettes. Increased carbon monoxide and carbon dioxide production is believed to be due to the presence of carbon particles in the tobacco sheet.
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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GB9801797.3 | 1998-01-28 | ||
GBGB9801797.3A GB9801797D0 (en) | 1998-01-28 | 1998-01-28 | Smoking articles |
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KR20010034343A true KR20010034343A (en) | 2001-04-25 |
KR100597169B1 KR100597169B1 (en) | 2006-07-05 |
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KR1020007008078A KR100597169B1 (en) | 1998-01-28 | 1999-01-26 | Smoking articles |
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EP (1) | EP1051089B1 (en) |
JP (1) | JP4044731B2 (en) |
KR (1) | KR100597169B1 (en) |
CN (1) | CN1125604C (en) |
AT (1) | ATE239388T1 (en) |
AU (1) | AU747793B2 (en) |
BR (1) | BR9907722B1 (en) |
CA (1) | CA2317409C (en) |
DE (1) | DE69907632T2 (en) |
DK (1) | DK1051089T3 (en) |
ES (1) | ES2199543T3 (en) |
GB (1) | GB9801797D0 (en) |
HK (1) | HK1032721A1 (en) |
MY (1) | MY129320A (en) |
NO (1) | NO325593B1 (en) |
NZ (1) | NZ505480A (en) |
PT (1) | PT1051089E (en) |
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KR100879193B1 (en) | 2000-10-05 | 2009-01-16 | 니꼴라스 바스케비치 | Reduction of nitrosamines in tobacco and tobacco products |
EP1749599B1 (en) * | 2004-04-30 | 2015-09-09 | Hitachi Metals, Ltd. | Methods for producing raw material alloy for rare earth magnet, powder and sintered magnet |
US8616218B2 (en) | 2008-07-01 | 2013-12-31 | Kazuto Koshiishi | Tobacco filter |
JP5208041B2 (en) * | 2009-04-10 | 2013-06-12 | 和人 輿石 | Cigarette filter |
GB201100218D0 (en) * | 2011-01-07 | 2011-02-23 | British American Tobacco Co | Smoking article |
CN103099307A (en) * | 2012-11-13 | 2013-05-15 | 苏州谷力生物科技有限公司 | Preparation method of cigarette slice added with activated carbon |
CN103099304A (en) * | 2012-11-13 | 2013-05-15 | 苏州谷力生物科技有限公司 | Preparation method of iron-activated carbon cigarette slice |
CN103099306A (en) * | 2012-11-13 | 2013-05-15 | 苏州谷力生物科技有限公司 | Preparation method of activated carbon tobacco sheet |
US9220296B2 (en) | 2013-03-15 | 2015-12-29 | Safall Fall | Method of reducing tobacco-specific nitrosamines |
CN105377062A (en) * | 2013-07-19 | 2016-03-02 | 菲利普莫里斯生产公司 | Hydrophobic paper |
GB201412752D0 (en) | 2014-07-17 | 2014-09-03 | Nicoventures Holdings Ltd | Electronic vapour provision system |
CN105747264B (en) * | 2016-04-20 | 2020-11-20 | 贵州中烟工业有限责任公司 | Activated carbon-containing heating non-combustible tobacco substrate and preparation method and application thereof |
GB201908353D0 (en) * | 2019-06-11 | 2019-07-24 | Nicoventures Trading Ltd | A mouthpiece and an article for use in an aerosol provision system |
KR20240032921A (en) * | 2021-07-07 | 2024-03-12 | 필립모리스 프로덕츠 에스.에이. | Articles having a tubular aerosol-forming substrate |
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Publication number | Priority date | Publication date | Assignee | Title |
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GB1348580A (en) * | 1971-06-11 | 1974-03-20 | British American Tobacco Co | Reconstituted-tobacco smoking materials |
GB1512352A (en) | 1977-02-07 | 1978-06-01 | Imp Group Ltd | Additive for tobacco |
US4942888A (en) | 1989-01-18 | 1990-07-24 | R. J. Reynolds Tobacco Company | Cigarette |
US5092353A (en) | 1989-01-18 | 1992-03-03 | R. J. Reynolds Tobacco Company | Cigarette |
US5056537A (en) * | 1989-09-29 | 1991-10-15 | R. J. Reynolds Tobacco Company | Cigarette |
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1998
- 1998-01-28 GB GBGB9801797.3A patent/GB9801797D0/en not_active Ceased
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1999
- 1999-01-26 JP JP2000529143A patent/JP4044731B2/en not_active Expired - Fee Related
- 1999-01-26 WO PCT/GB1999/000260 patent/WO1999038396A1/en active IP Right Grant
- 1999-01-26 PT PT99903793T patent/PT1051089E/en unknown
- 1999-01-26 DE DE69907632T patent/DE69907632T2/en not_active Expired - Lifetime
- 1999-01-26 DK DK99903793T patent/DK1051089T3/en active
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- 1999-01-26 KR KR1020007008078A patent/KR100597169B1/en not_active IP Right Cessation
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- 1999-01-26 AT AT99903793T patent/ATE239388T1/en active
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- 1999-01-26 BR BRPI9907722-1A patent/BR9907722B1/en not_active IP Right Cessation
- 1999-01-26 AU AU24316/99A patent/AU747793B2/en not_active Ceased
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- 1999-01-28 ZA ZA9900675A patent/ZA99675B/en unknown
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2000
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DE69907632D1 (en) | 2003-06-12 |
ES2199543T3 (en) | 2004-02-16 |
CA2317409C (en) | 2004-07-20 |
KR100597169B1 (en) | 2006-07-05 |
NO20003357L (en) | 2000-09-26 |
EP1051089B1 (en) | 2003-05-07 |
JP2002501736A (en) | 2002-01-22 |
CA2317409A1 (en) | 1999-08-05 |
EP1051089A1 (en) | 2000-11-15 |
AU747793B2 (en) | 2002-05-23 |
AU2431699A (en) | 1999-08-16 |
ZA99675B (en) | 1999-07-28 |
ATE239388T1 (en) | 2003-05-15 |
NO325593B1 (en) | 2008-06-23 |
MY129320A (en) | 2007-03-30 |
DE69907632T2 (en) | 2004-04-08 |
NZ505480A (en) | 2003-01-31 |
PT1051089E (en) | 2003-08-29 |
HK1032721A1 (en) | 2001-08-03 |
JP4044731B2 (en) | 2008-02-06 |
DK1051089T3 (en) | 2003-09-01 |
WO1999038396A1 (en) | 1999-08-05 |
BR9907722B1 (en) | 2008-11-18 |
CN1289234A (en) | 2001-03-28 |
CN1125604C (en) | 2003-10-29 |
NO20003357D0 (en) | 2000-06-27 |
BR9907722A (en) | 2000-10-17 |
GB9801797D0 (en) | 1998-03-25 |
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