KR20010032330A - Biodegradable cigarette filter - Google Patents
Biodegradable cigarette filter Download PDFInfo
- Publication number
- KR20010032330A KR20010032330A KR1020007005545A KR20007005545A KR20010032330A KR 20010032330 A KR20010032330 A KR 20010032330A KR 1020007005545 A KR1020007005545 A KR 1020007005545A KR 20007005545 A KR20007005545 A KR 20007005545A KR 20010032330 A KR20010032330 A KR 20010032330A
- Authority
- KR
- South Korea
- Prior art keywords
- filter
- tobacco
- condensate
- cigarette
- strand
- Prior art date
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 20
- 241000208125 Nicotiana Species 0.000 claims abstract description 28
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 28
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims abstract description 8
- 229960002715 nicotine Drugs 0.000 claims abstract description 8
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002678 cellulose Polymers 0.000 claims abstract description 7
- 239000001913 cellulose Substances 0.000 claims abstract description 7
- 230000035699 permeability Effects 0.000 claims abstract description 7
- 230000014759 maintenance of location Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 238000012856 packing Methods 0.000 claims abstract description 4
- 238000006065 biodegradation reaction Methods 0.000 abstract 1
- 238000009423 ventilation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 230000000007 visual effect Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 235000019613 sensory perceptions of taste Nutrition 0.000 description 2
- 230000035923 taste sensation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 206010016654 Fibrosis Diseases 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004761 fibrosis Effects 0.000 description 1
- -1 for example Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/043—Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Biological Depolymerization Polymers (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Nonwoven Fabrics (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Filtering Materials (AREA)
- Paper (AREA)
- Thermistors And Varistors (AREA)
Abstract
본 발명은 담배 종이로 둘러싸인 담배 스트랜드, ″에어-레이드″ 공법을 사용하여 제조된 셀룰로오스 플리스로부터 제조된 ″정상″ 수준의 보유성을 갖는 필터, 및 원주 방향으로 진행하는 필터 통기대를 갖는, 생분해성 필터를 갖는 필터 담배에 관한 것이다. 이는 다음과 같은 특징을 갖는다: 필터의 응축물 보유 수준은 40 내지 60 %이고; 셀룰로오스 플리스는 ″비크림프″된 것이며; 담배 스트랜드의 니코틴/응축물 스트랜드 산출비는 0.6 내지 0.9 (니코틴*10/응축물)이고; 담배 스트랜드의 담배 블렌드 패킹 밀도는 200 내지 250 ㎎/㎖이며; 담배-스트랜드 내인발성은 밀폐된 상태로 측정시, 45 내지 65 ㎜ 수 컬럼 압력 게이지이고; 담배의 공기 투과성은 20 내지 50 코레스타 단위이며; 필터 통기도는 15 내지 50 %에 달한다.The present invention relates to biodegradation, comprising tobacco strands surrounded by tobacco paper, filters having ″ normal ″ levels of retention made from cellulose fleece made using the ″ air-laid ″ process, and filter vents running circumferentially. It relates to a filter cigarette having a sex filter. It has the following characteristics: the condensate retention level of the filter is 40 to 60%; Cellulose fleece is ″ un crimped ″; Nicotine / condensate strand yield ratio of tobacco strands is 0.6 to 0.9 (nicotine * 10 / condensate); Tobacco blend packing density of tobacco strand is 200-250 mg / ml; Tobacco-strand resistance is 45-65 mm male column pressure gauge, measured in closed condition; The air permeability of tobacco is between 20 and 50 Coresta units; Filter ventilation is up to 15-50%.
Description
상기와 같은 필터 담배는 과거 수 차례 기재된 바 있다. 그러나, 생분해성 필터가 있는, 선행 기재된 모든 필터 담배의 단점은 연기의 맛에 대한 명백한 효과로 이는 기재된 상이한 재료에 의해 발생되며 이는 통상의 셀룰로오스 아세테이트 외의 재료로 제조되는 담배로서 항상 흡연자들에 의해 거절된다. 추가의 단점, 특히 생분해성 셀룰로오스로부터 제조된 필터의 단점은 또한 필터 말단의 외관에서의, 명확히 구분할 수 있는 차이이다. 과거에, 이는 생분해성 필터가 아세테이트 필터 시장에 대해 모노필터로서 수용될 수 없었음을 의미한다.Such filter cigarettes have been described several times in the past. However, the disadvantage of all previously described filter cigarettes with biodegradable filters is the apparent effect on the taste of the smoke, which is caused by the different materials described which are always rejected by smokers as cigarettes made from materials other than conventional cellulose acetate. do. A further disadvantage, in particular the disadvantage of filters made from biodegradable cellulose, is also a clearly distinguishable difference in the appearance of the filter ends. In the past, this meant that biodegradable filters could not be accepted as monofilters for the acetate filter market.
본 발명은 특허청구의 범위 제1항의 서론에 따르는 생분해성 필터에 관한 것이다.The present invention relates to a biodegradable filter according to the introduction of claim 1.
본 발명의 목적은 ″아세테이트-전형의″ 맛 감각과 ″아세테이트-전형의″ 시각적 외관을 제공하면서 공지된 필터 담배의 장점을 보유하는 언급된 종류의 필터 담배를 생산하는 것이다.It is an object of the present invention to produce a filter cigarette of the kind mentioned which retains the advantages of known filter cigarettes while providing ″ acetate-typical ″ taste sensation and ″ acetate-typical ″ visual appearance.
본 발명에 따라서, 상기 목적은 특허 청구의 범위의 특징부에 제시된 양태에 의해 성취된다.According to the invention, this object is achieved by the embodiments presented in the characterizing part of the claims.
적합한 형태는 종속항의 양태에 의해 정의된다.Suitable forms are defined by the aspects of the dependent claims.
본 발명으로 성취되는 이점은 특별한 셀룰로오스 물질의 선택 및 필수적인 인자, 즉 필터의 보유 특성, 담배 스트랜드의 니코틴/축합물 스트랜드 산출비, 담배 스트랜드의 담배 혼합물의 패킹 밀도, 담배 종이의 공기 투과성 및 최종적으로 한편으로는 맛 감각과 다른 한편으로는 시각적 매력을 최적화 시키는 전체적인 구조의 방향에서의 필터 통기성을 채택하여 특수 셀룰로오스 재료에 매치시킨 필터 담배 구조의 디자인에 있다. 필터 담배의 니코틴 산출량은 최대로 1 ㎎이며 축합물 산출량은 6 ㎎ 내지 12 ㎎이다.The advantages achieved with the present invention are the selection and essential factors of the particular cellulosic material, namely the retention properties of the filter, the nicotine / condensate strand yield of the tobacco strand, the packing density of the tobacco mixture of the tobacco strand, the air permeability of the tobacco paper and finally On the one hand it is in the design of the filter tobacco structure that matches the special cellulosic material by adopting the filter breathability in the direction of the overall structure to optimize the taste sense and on the other hand the visual appeal. The maximum yield of nicotine in filter tobacco is 1 mg and the condensate yield is 6 mg to 12 mg.
15 내지 50 %의 탐색-후 통기도는 포장 랩퍼와 랩핑시 통기대의 대응하는 디자인에 의해 확립될 수 있다.Post-search air permeability of 15-50% can be established by the corresponding design of the wrapper and the airbag during wrapping.
바람직한 양태에 따르면, 필터의 통기대는 마우스-측 말단으로부터 10 ㎜ 이상 떨어져있는 1 또는 2열의 홀로 이루어져 있으며; 이 홀은 최종 단계의 담배 상에서 레이져 조사 또는 기계적으로 제작될 수 있고, 가능한 작아야 하며 눈으로 볼 수 있을 정도로 커서는 안되며, 2개의 통기열에 15 내지 25개의 홀인 경우 양호한 결과가 수득된다.According to a preferred embodiment, the vent of the filter consists of one or two rows of holes at least 10 mm away from the mouth-side end; This hole can be laser irradiated or mechanically fabricated on the cigarette of the final stage, should be as small as possible and not large enough to be visible, and good results are obtained with 15 to 25 holes in two rows of vents.
놀랍게도, 아세테이트-전형의 맛 감각과 아세테이트-전형의 시각적 매력은 필터가 소위 ″에어-레이드″ 공법에 의해 탱글된 플리스로 가공된 셀룰로오스재로부터 제조되고, 이는 추가로 ″비크림프″ 가공되어 최종 필터가 되는 경우에만 수득될 수 있는 것으로 밝혀졌다. 이 공정에서, 에어-레이드 플리스의 면적 중량, 두께 및 폭의 적합한 조합은 목적하는 필터 내인발성, 따라서 보유도에 따라서 확립될 수 있다.Surprisingly, the taste taste of acetate-typical and the visual appeal of acetate-typical are made from cellulosic material in which the filter is processed into tangle fleece by the so-called ″ air-laid ″ process, which is further ″ non-crimp ″ processed to the final filter. It has been found that it can only be obtained if In this process, a suitable combination of area weight, thickness and width of the air-laid fleece can be established depending on the desired filter pullout resistance and thus retention.
예를 들어, US-PS 4,375,447에 기재된 바와 같은 에어-레이드 공법에서는, 제조된 셀룰로오스 섬유를 표준 종이 제조 공정에서와 같이 수중에 현탁시키지 않고, 쉬트 형성을 위하여 투과성 체에 통과시키는데, 체 위의 셀룰로오스 섬유는 비팅(beating)과 섬유화에 의해 정련되고, 서로 기계적으로 가교-결합되지만, 이들은 이들을 투과성 연속 체상으로 운반하는 공기의 스트림중으로 최대로 분리되어 통과되어 랜덤하게 쌓이게 된다. 이로써 거의 면솜과 유사한 볼륨감 있는 플리스가 수득되고 따라서 어떠한 기계적 강도 또는 섬유 결합도 증명되지 않는다. 기계적 결합 및 추가 가공에서 요구되는 필수적인 기계적 강도는 예를 들어, 폴리비닐 알코올, 폴리비닐 아세테이트, 중합체 전분, 덱스트린 또는 라텍스와 같은 결합제를 공기 스트림중에 첨가함으로써 수득된다. 상기 밀도(g/㎤)의 정도, 따라서 볼륨성 또는 두께는 이후의 칼렌더링(calendering)에 의해 정해진다. 면적 중량(g/㎡)은 체의 속도에 의해 또는 공기 스트림중으로 섬유를 도입시킴으로써 조정된다.For example, in the air-laid process as described in US Pat. No. 4,375,447, the prepared cellulose fibers are passed through a permeable sieve for sheet formation, without suspending in water as in standard paper making processes. The fibers are refined by beating and fibrosis and mechanically cross-linked with each other, but they are separated and passed through to a maximum in a stream of air that carries them onto a permeable continuous body and randomly stacked. This yields a voluminous fleece that is nearly cotton-like and therefore no mechanical strength or fiber bonds are demonstrated. The necessary mechanical strength required for mechanical bonding and further processing is obtained by adding a binder such as, for example, polyvinyl alcohol, polyvinyl acetate, polymer starch, dextrin or latex into the air stream. The degree of density (g / cm 3), and thus the volume or thickness, is determined by subsequent calendering. Area weight (g / m 2) is adjusted by the speed of the sieve or by introducing the fibers into the air stream.
본 발명은 다음 양태를 참고하여 더욱 상세하게 설명된다:The invention is explained in more detail with reference to the following aspects:
필터 담배는 담배 종이로 싸여 있는 담배 스트랜드와 담배 스트랜드에 연결되어 있는 필터를 갖는다. 담배 블렌드의 패킹 밀도는 200 내지 250 ㎎/㎖이다. 스트랜드의 내인발성은 밀폐된 상태에서 측정시 45 내지 65 ㎜ 수컬럼 압력 게이지이다.Filter tobacco has a tobacco strand wrapped with tobacco paper and a filter connected to the tobacco strand. The packing density of the tobacco blend is 200 to 250 mg / ml. The pullout resistance of the strand is a 45 to 65 mm male column pressure gauge as measured in the closed state.
담배 종이는 15 내지 50 코레스타 단위 범위의 낮거나 중간 정도의 공기 투과성을 갖는다. 담배 블렌드의 니코틴*10/응축물 스트랜드 산출비는 0.6 내지 0.9이다.Tobacco paper has a low or moderate air permeability ranging from 15 to 50 Coresta units. The nicotine * 10 / condensate strand yield ratio of the tobacco blend is between 0.6 and 0.9.
필터는 함께 폴딩된 ″비크림프″ 에어-레이드 플리스로 구성되어 있으며 다공성 랩핑 종이로 싸여 있다. 영역(zone)-다공성 커버 종이가 랩핑 종이를 둘러싸고 있으며 필터가 담배 스트랜드에 안착될 수 있도록 한다. 커버 종이의 다공성 영역의 공기 투과성은 목적하는 정도의 필터 통기성이 그 아래 있는 랩핑 종이와 관련하여 선택한다.The filter consists of a ″ non-crimp ″ air-laid fleece that is folded together and wrapped in a porous wrapping paper. Zone-porous cover paper surrounds the wrapping paper and allows the filter to seat on the tobacco strand. The air permeability of the porous area of the cover paper is selected in relation to the wrapping paper with the desired degree of filter breathability.
명시된 담배 스트랜드와 함께, 상기와 같은 필터를 시험한 결과, 응축물 산출량이 6 내지 12㎎이고 니코틴 산출량이 최대로 1㎎이었다. 장기간 경험한 흡연가에 대한 시험으로 상기와 같은 담배가 통상적으로 아세테이트 필터로 제조된 담배와 구별될 수 없는 것으로 밝혀졌다.Testing of such filters with the specified tobacco strands resulted in a condensate yield of 6-12 mg and a nicotine yield of at most 1 mg. Tests of smokers who have experienced long experiences have found that such cigarettes are indistinguishable from cigarettes typically made with acetate filters.
본 발명은 ″아세테이트-전형의″ 맛 감각과 ″아세테이트-전형의″ 시각적 외관을 제공하면서 공지된 필터 담배의 장점을 보유하는 언급된 종류의 필터 담배를 제공한다.The present invention provides a filter cigarette of the kind mentioned which retains the advantages of known filter cigarettes while providing ″ acetate-typical ″ taste sensation and ″ acetate-typical ″ visual appearance.
Claims (6)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19753193A DE19753193A1 (en) | 1997-11-21 | 1997-11-21 | Biologically degradable filter for cigarette |
DE19753193.8 | 1997-11-21 | ||
PCT/EP1998/007120 WO1999026497A1 (en) | 1997-11-21 | 1998-11-10 | Biodegradable cigarette filter |
Publications (1)
Publication Number | Publication Date |
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KR20010032330A true KR20010032330A (en) | 2001-04-16 |
Family
ID=7850356
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020007005545A KR20010032330A (en) | 1997-11-21 | 1998-11-10 | Biodegradable cigarette filter |
Country Status (27)
Country | Link |
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EP (1) | EP1032283B1 (en) |
JP (1) | JP2001523479A (en) |
KR (1) | KR20010032330A (en) |
CN (1) | CN1130135C (en) |
AT (1) | ATE225134T1 (en) |
AU (1) | AU1667699A (en) |
BG (1) | BG64611B1 (en) |
CZ (1) | CZ289363B6 (en) |
DE (2) | DE19753193A1 (en) |
DK (1) | DK1032283T3 (en) |
EA (1) | EA001997B1 (en) |
EE (1) | EE200000268A (en) |
ES (1) | ES2182382T3 (en) |
HK (1) | HK1034880A1 (en) |
HR (1) | HRP20000418A2 (en) |
HU (1) | HU225287B1 (en) |
ID (1) | ID25459A (en) |
NO (1) | NO309354B1 (en) |
OA (1) | OA11414A (en) |
PL (1) | PL187198B1 (en) |
PT (1) | PT1032283E (en) |
SK (1) | SK283275B6 (en) |
TR (1) | TR200001454T2 (en) |
TW (1) | TW533062B (en) |
UA (1) | UA56285C2 (en) |
WO (1) | WO1999026497A1 (en) |
YU (1) | YU49407B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003500008A (en) | 1999-02-26 | 2003-01-07 | レーンツマ シガレッテンファブリーケン ゲゼルシャフト ミット ベシュレンクテル ハフツング | Smokeable products |
CN100551283C (en) * | 2005-11-23 | 2009-10-21 | 云南烟草科学研究院 | A kind of cigarette with binary composite tip stick and preparation method thereof |
US7878210B2 (en) | 2007-06-04 | 2011-02-01 | Philip Morris Usa Inc. | Cellulose acetate fiber modification |
DE102009016148A1 (en) | 2009-04-03 | 2010-10-14 | Mcairlaid's Vliesstoffe Gmbh & Co. Kg | Filter material for cleaning air and gases |
CA2887696C (en) * | 2012-10-11 | 2021-07-06 | Schweitzer-Mauduit International, Inc. | Wrapper having reduced ignition proclivity characteristics |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US792913A (en) * | 1903-01-16 | 1905-06-20 | James J Mulconroy | Coupling device for rubber tubing, pipe, hose, &c. |
US4366826A (en) * | 1979-08-28 | 1983-01-04 | British-American Tobacco Company Limited | Smoke filtration |
US4375447A (en) * | 1979-12-21 | 1983-03-01 | Kimberly-Clark Corporation | Method for forming an air-laid web of dry fibers |
EP0745336A2 (en) * | 1995-05-31 | 1996-12-04 | Daicel Chemical Industries, Ltd. | Tobacco filters and a method of producing the same |
US5678577A (en) * | 1994-10-31 | 1997-10-21 | Daicel Chemical Industries, Ltd. | Tobacco filter material and a tobacco filter as produced using the same |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3625593A1 (en) * | 1986-07-29 | 1988-02-04 | Bat Cigarettenfab Gmbh | FILTER CIGARETTE |
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1997
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1998
- 1998-10-11 UA UA2000063573A patent/UA56285C2/en unknown
- 1998-11-10 EP EP98961155A patent/EP1032283B1/en not_active Expired - Lifetime
- 1998-11-10 EA EA200000549A patent/EA001997B1/en not_active IP Right Cessation
- 1998-11-10 CZ CZ20001829A patent/CZ289363B6/en not_active IP Right Cessation
- 1998-11-10 YU YU30900A patent/YU49407B/en unknown
- 1998-11-10 DK DK98961155T patent/DK1032283T3/en active
- 1998-11-10 PL PL98340593A patent/PL187198B1/en unknown
- 1998-11-10 KR KR1020007005545A patent/KR20010032330A/en active IP Right Grant
- 1998-11-10 HU HU0100392A patent/HU225287B1/en not_active IP Right Cessation
- 1998-11-10 AT AT98961155T patent/ATE225134T1/en active
- 1998-11-10 WO PCT/EP1998/007120 patent/WO1999026497A1/en active IP Right Grant
- 1998-11-10 CN CN98813219A patent/CN1130135C/en not_active Expired - Fee Related
- 1998-11-10 JP JP2000521714A patent/JP2001523479A/en active Pending
- 1998-11-10 ES ES98961155T patent/ES2182382T3/en not_active Expired - Lifetime
- 1998-11-10 EE EEP200000268A patent/EE200000268A/en unknown
- 1998-11-10 TR TR2000/01454T patent/TR200001454T2/en unknown
- 1998-11-10 AU AU16676/99A patent/AU1667699A/en not_active Abandoned
- 1998-11-10 PT PT98961155T patent/PT1032283E/en unknown
- 1998-11-10 DE DE59805850T patent/DE59805850D1/en not_active Expired - Lifetime
- 1998-11-10 SK SK742-2000A patent/SK283275B6/en not_active IP Right Cessation
- 1998-11-10 ID IDW20001196A patent/ID25459A/en unknown
- 1998-11-20 TW TW087119275A patent/TW533062B/en not_active IP Right Cessation
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2000
- 2000-05-16 NO NO20002516A patent/NO309354B1/en unknown
- 2000-05-19 OA OA1200000150A patent/OA11414A/en unknown
- 2000-06-20 BG BG104547A patent/BG64611B1/en unknown
- 2000-06-21 HR HR20000418A patent/HRP20000418A2/en not_active Application Discontinuation
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2001
- 2001-08-08 HK HK01105513A patent/HK1034880A1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US792913A (en) * | 1903-01-16 | 1905-06-20 | James J Mulconroy | Coupling device for rubber tubing, pipe, hose, &c. |
US4366826A (en) * | 1979-08-28 | 1983-01-04 | British-American Tobacco Company Limited | Smoke filtration |
US4375447A (en) * | 1979-12-21 | 1983-03-01 | Kimberly-Clark Corporation | Method for forming an air-laid web of dry fibers |
US5678577A (en) * | 1994-10-31 | 1997-10-21 | Daicel Chemical Industries, Ltd. | Tobacco filter material and a tobacco filter as produced using the same |
EP0745336A2 (en) * | 1995-05-31 | 1996-12-04 | Daicel Chemical Industries, Ltd. | Tobacco filters and a method of producing the same |
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