KR20010017780A - A process for the production of cold plate roller and their roller using wasted fabric material - Google Patents

A process for the production of cold plate roller and their roller using wasted fabric material Download PDF

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Publication number
KR20010017780A
KR20010017780A KR1019990033448A KR19990033448A KR20010017780A KR 20010017780 A KR20010017780 A KR 20010017780A KR 1019990033448 A KR1019990033448 A KR 1019990033448A KR 19990033448 A KR19990033448 A KR 19990033448A KR 20010017780 A KR20010017780 A KR 20010017780A
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South Korea
Prior art keywords
rubber
roller
disc
fiber
resins
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KR1019990033448A
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Korean (ko)
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KR100364116B1 (en
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남향현
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남향현
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/0288Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/545Perforating, cutting or machining during or after moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0032Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2009/00Use of rubber derived from conjugated dienes, as moulding material
    • B29K2009/06SB polymers, i.e. butadiene-styrene polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/08Copolymers of ethylene
    • B29K2023/083EVA, i.e. ethylene vinyl acetate copolymer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/16EPM, i.e. ethylene-propylene copolymers; EPDM, i.e. ethylene-propylene-diene copolymers; EPT, i.e. ethylene-propylene terpolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/06Unsaturated polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • B29K2075/02Polyureas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2079/00Use of polymers having nitrogen, with or without oxygen or carbon only, in the main chain, not provided for in groups B29K2061/00 - B29K2077/00, as moulding material
    • B29K2079/08PI, i.e. polyimides or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26Scrap or recycled material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/772Articles characterised by their shape and not otherwise provided for
    • B29L2031/7728Disc-shaped

Abstract

PURPOSE: A production method for a roller is provided to save production costs by using waste fiber classified as a waste material and to produce the roller satisfying impact resistance, earthquake resistance, heat resistance, chemical resistance and so on. CONSTITUTION: Waste fiber is formed in a planar and nonwoven type of specific thickness by scutching the waste fiber. To have a desired shape of diameter for the planar and nonwoven type waste fiber, a disc is made up by using a die. The disc is soaked in a vacuum impregnation tub for a permeation treatment. Herein, the vacuum impregnation bath is mixed up with a thermosetting resin, a rubber and a vulcanizing agent. The disc is dried in a drier and deposited on a frame for a roller. In a state of depositing the disc, the disc is compressed horizontally. The disc is heated and hardened while keeping a compressed state. Then, the disc is finished in a desired shape by grinding the surface of the hardened disc.

Description

폐섬유를 이용한 냉연강판제철소용 롤러의 제조방법 및 그 롤러{A process for the production of cold plate roller and their roller using wasted fabric material}A process for the production of cold plate roller and their roller using wasted fabric material}

본 발명은 제철소의 냉연강판용 이송롤러의 제조방법 그리고 그 제조방법에 의하여 제조된 롤러에 관한 것이다. 특히 폐섬유를 원료로 기본골격을 구성한 다음 폐섬유의 공극부에 고무와 열경화성수지를 진공함침시켜 건조후, 이들을 일정한 형태로 적층하여 열경화시켜 주어 고무의 탄성과 열경화성 수지의 내구성이 함께 상승효과를 주어 내열성, 내약품성, 내충격성등을 함께 개선한 새로운 제철소용 롤러에 관한 것이다.The present invention relates to a method for producing a feed roller for a cold rolled steel sheet in a steel mill and a roller manufactured by the method. In particular, after constructing the basic skeleton from waste fiber as a raw material, vacuum impregnating rubber and thermosetting resin in the voids of the waste fiber and drying them, then laminating them in a certain form and thermosetting them so that the elasticity of the rubber and the durability of the thermosetting resin are synergistic. The present invention relates to a new steel mill roller that has improved heat resistance, chemical resistance, and impact resistance.

제철산업에서 압연강판을 일정한 형태로 권취하기 위하여 수백m 내지는 수Km에 이르는 강판의 이송이 필요하며 이 이송중에 강판이 부분적인 장력의 변화와 권취속도의 불일치로 부분적인 웨이브의 발생 또는 진동현상이 발생하여 이들을 흡수 제거하기위한 수단으로 진동흡수 콘트롤롤러와 탄성의 롤러가 병용되고 있는 것이다.In the steel industry, in order to wind up the rolled steel sheet in a certain form, it is necessary to transfer the steel sheet of several hundred meters to several kilometers. During this transfer, the steel sheet is partially waved or vibrated due to partial tension change and winding speed mismatch Vibration absorption control rollers and elastic rollers are used together as a means for generating and absorbing them.

제철용 롤러의 경우 대개 강재로 구성하는 경우 강판이 이송중 약간의 이송오차만 발생하여도 표면에 스트립이 발생하여 불량의 원인이 되며 심한 경우 기계전체를 중지한 채 보수하여야 하는 것이다. 즉, 인발거리가 수키로미터에 이르면 수십톤 내지 수백톤에 이르는 인발력이 작용하고 있으며 만일 좌우측일부에 속도차이가 발생하면 강한 파동이 발생하여 접촉면에 손상이 발생하고 불량의 발생원인이 되는 것이다. 이경우 현장에서 센서류를 다양한 위치에 설치하여 인발속도나 인발강도를 자동조절토록 하고 있다. 그러나 순간적으로 발생하는 미세한 변화를 전공정에 걸쳐 자동화하기 어렵고 자동화한다고 하여도 엄청난 설치비로 원가상승의 한 요인이 되므로 결국 작업자가 라인의 측면에 배치되어 진동의 발생을 미리미리 감지하도록 하는 육안에 의한 체크가 주요한 수단이 되고 있다.In the case of steel rollers, steel sheets are usually made of steel, even if only a slight conveyance error occurs during the transfer of steel strips to the surface, which can cause defects. That is, when the drawing distance reaches several kilometers, the drawing force of several tens of tons or hundreds of tons is acting. If a speed difference occurs in the left and right parts, a strong wave is generated, which causes damage to the contact surface and causes a defect. In this case, sensors are installed at various locations in the field to automatically adjust the drawing speed or drawing strength. However, it is difficult to automate minute changes that occur instantaneously throughout the entire process, and even if they are automated, they are a factor of cost increase due to the huge installation cost, so that the operator is placed on the side of the line to detect the occurrence of vibration in advance Checking is the main means.

그외에도 여러가지 산업현장에서 원료를 적재하여 이송하는 가운데 발생되는 부분적인 좌우불균형도 동일한 문제를 발생하고 있다.In addition, the partial left and right unbalance caused by loading and transporting raw materials in various industrial sites also causes the same problem.

또한 육안으로 첵크가 되었다하여도 고속진행하면서 권취되거나 이송하는 압연판의 순간적인 표면손상은 피할 수 없으며 작업자가 이같은 진동현상을 발견즉시 수정하고자 하여도 전체공정을 중단시킨 다음 전체적인 장력조정, 방향조정후 공정이 진행되므로 순간 순간 공정의 중단, 제품의 손상을 피할 수 없는 것이다.In addition, even if the shank is visually observed, instantaneous surface damage of the rolled plate that is wound or transported at high speed cannot be avoided, and even if the worker finds such a phenomenon immediately after stopping the whole process, after adjusting the overall tension and adjusting the direction As the process proceeds, interruption of the process and product damage are inevitable.

이같은 단점을 개선하고자 고무재를 원료로 한 롤러를 배치하여 진동과 왜곡현상을 고무의 탄성을 이용하여 흡수하도록 하고 있으나 강판과의 마찰로 짧게는 수일 길게는 수개월내에 교체하여 주어야 하므로 수십내지 수백kg에 달하는 롤러를 교체하려면 상당한 장비와 인력이 투입되어야 하며 동시에 공정이 중단되어야 하는 것이다.In order to improve the disadvantage, rubber and rubber rollers are placed to absorb vibration and distortion by using the elasticity of rubber. However, due to friction with steel sheet, it has to be replaced within a few months for a few days to hundreds of kg. Replacing these rollers requires significant equipment and manpower and at the same time stops the process.

본 발명의 부직포 고무적층형 롤러는 1997년 실용신안등록출원제 29373호에 개시되어있다. 이경우에 폐섬유가 아닌 원사를 이용하여 만든 부직포를 도너츠형태로 성형하여 탄성의 고무와 순차로 롤러프레임에 넣고 이것을 압축하면서 열처리하여 목적한 롤러를 제조하였다. 따라서 일단 부직포의 원가가 높고, 부직포와 고무층이 직접 닿는 부분은 그런대로 접착이 잘되어있으나 부직포의 중간부분은 접착이 되지 못한 비어있는 부분이 있어 탄성과 강도가 다른 곳과 다르게 되었다. 따라서 사용중 미충전된 부분을 중심으로 변성이 발생하여 사후 문제발생의 주요한 요인으로 작용하고 있는 것이다.The nonwoven rubber laminated roller of the present invention is disclosed in Utility Model Registration Application No. 29373 in 1997. In this case, a nonwoven fabric made of yarn, not waste fiber, was molded into a donut shape and placed in a roller frame in order with elastic rubber, followed by compression and heat treatment, thereby producing a desired roller. Therefore, once the cost of the nonwoven fabric is high, the part where the nonwoven fabric and the rubber layer directly contact is well adhered as it is, but the middle part of the nonwoven fabric has a hollow part that is not bonded, and thus the elasticity and strength are different from other places. Therefore, degeneration occurs around unfilled parts during use, which is a major factor in post-occurrence problems.

본 발명은 폐기물로 분류되는 폐섬유를 원료로 사용하여 생산원가를 낮추면서도 제철용롤러가 요구하는 내충격성, 내진성, 내약품성, 내열성등을 함께 충족하는 롤러를 제공하고자 개발된 것이다. 특히 폐섬유를 원료로 사용하고 고무와 열경화성 수지를 함께 병용하므로서 고무의 탄성과 열경화성 수지의 내화확성과 내열성등을 함께 발휘하도록 하여 상기한 문제점을 해소하고자 한다. 또한 롤러의 제작시 폐섬유를 부직포의 형태로 하여 수많은 공극을 형성토록 하고 이 공극내에 수지류와 고무의 침투를 보다 용이하게 하기 위하여 진공함침법을 병용하므로서 균일한 경화성물질 및 탄성물질이 침투토록하여 표면과 내부의 불균일성을 없애도록 하였다.The present invention was developed to provide a roller that satisfies the impact resistance, shock resistance, chemical resistance, heat resistance, etc. required by the steelmaking roller while using the waste fibers classified as waste as raw materials. In particular, by using waste fibers as a raw material and using a combination of rubber and thermosetting resin together to solve the above problems by showing the elasticity of the rubber and the fire resistance and heat resistance of the thermosetting resin. In addition, in the production of rollers, waste fibers are formed into non-woven fabrics to form numerous voids, and the vacuum impregnation method is used together to facilitate the penetration of resins and rubbers into the voids so that uniformly curable and elastic substances can penetrate. By removing the nonuniformity of the surface and inside.

도 1은 본 발명의 제조 공정도,1 is a manufacturing process diagram of the present invention,

도 2 는 본 발명의 디스크 원반의 사시도,2 is a perspective view of the disc disk of the present invention;

도 3 은 본 발명의 디스크원반을 함침조에 적재한 상태의 구성도,3 is a block diagram of a state where the disc disk of the present invention is loaded in an impregnation tank;

도 4 는 본 발명의 디스크원반을 건조하여 적층한 상태의 측면도,Figure 4 is a side view of the disk disk of the present invention dried and laminated;

도 5 는 본 발명의 디스크원반을 압축경화후 면처리 전후의 측면도임.Figure 5 is a side view of the disk disk of the present invention before and after surface curing after compression curing.

〈도면의 주요 부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>

1 : 롤러프레임 3 : 중앙공 10 : 디스크원반 15 : 섬유층DESCRIPTION OF SYMBOLS 1 Roller frame 3 Center hole 10 Disc disk 15 Fiber layer

30 : 혼합충전액 50 : 함침조 60 : 압축판 70 : 불규칙표면30: mixed filling liquid 50: impregnation tank 60: compression plate 70: irregular surface

본 발명은 폐섬유를 타면처리하여 내부에 공극이 많은 부직형태로 형성하고 일정한 두께와 공간을 갖는 판상형태로 구성하는 공정, 판상형태의 부직형태의 폐섬유에 원하는 형태의 직경을 갖도록 금형을 이용하여 디스크 원반을 만드는 공정, 만들어진 원판을 열경화성수지와 고무 그리고 가황제와 같은 첨가제를 배합한 진공함침조에 침지하여 침투처리하는 공정, 수지와 고무가 침투된 것을 건조기에서 건조처리하는 공정, 건조처리된 원반을 롤러용 프레임에 적층하는 공정, 적층된 상태에서 횡방향으로 압축하여 주는 공정, 압축이 된 상태를 유지하면서 가열경화하는 공정 그리고 경화된 것의 표면을 연삭 혹은 면삭처리하여 원하는 형태로 마감처리하는 공정으로 구성되어 있다.The present invention is a process to form a nonwoven form with a lot of voids by processing the other surface of the waste fiber and to form a plate-like shape having a predetermined thickness and space, using a mold to have a desired shape diameter to the plate-shaped nonwoven waste fiber. Process of making disc disc, process of immersing the made disc in vacuum impregnation tank containing additives such as thermosetting resin, rubber and vulcanizing agent, drying process of resin and rubber infiltration in dryer, drying process The process of laminating the disc to the roller frame, the process of compressing in the lateral direction in the stacked state, the process of heat curing while maintaining the compressed state, and the surface of the hardened thing to be finished by grinding or surface treatment to the desired shape. It consists of a process.

본 발명에서 사용하는 폐섬유는 천연섬유, 합성섬유 혹은 이들의 혼합섬유를 모두 포함하는 것이며 특별히 고무와 열경화성수지와의 관계에서 접합성이나 안정성에 문제가 있는 것이 아니면 모두 채용가능하나 가능한한 성분이 일정한 것으로 취합하여 사용하면 사용하는 수지와 고무의 특성에 따라 알맞게 사용할 수 있고 성형후에 강도, 내구성등이 예측가능하다.The waste fibers used in the present invention include all natural fibers, synthetic fibers, or mixed fibers thereof, and may be employed unless there is a problem in bonding or stability, especially in relation to rubber and thermosetting resin, but the components are as constant as possible. When used together, it can be appropriately used according to the characteristics of the resin and rubber used, and the strength and durability can be predicted after molding.

본 발명에서 사용할 수있는 고무는 단순한 천연고무외에도 SBR(스티렌부타디엔고무), CR(클로로프렌고무), IIR(부틸고무), EPDM, IR(이소프렌고무), BR(부타디엔러버), CSM(클로로술폰화폴리에틸렌), 우레탄고무, EVA 등이 모두 채용가능하다.The rubber that can be used in the present invention, in addition to simple natural rubber, SBR (styrene butadiene rubber), CR (chloroprene rubber), IIR (butyl rubber), EPDM, IR (isoprene rubber), BR (butadiene rubber), CSM (chlorosulfonated Polyethylene), urethane rubber, EVA and the like can all be employed.

본 발명에서 사용가능한 열경화성수지류는 페놀수지, 불포화폴리에스테르, 푸란수지, 우레아수지, 멜라민수지, 디아릴프탈레이트수지, 에폭시수지, 불소수지, 폴리이미드수지등이 선택가능하다. 이상의 수지와 고무는 필요로 하는 사용처에 따라 수지와 고무의 비율이 0.1∼1.5 : 1의 배합비(중량기준)가 적당하며, 수지의 강도를 높이면 상대적으로 고무의 배합비가 낮아져 탄성이 적어지는 반면 강도는 강화되는 특징이 있다.Thermosetting resins usable in the present invention may be selected from phenol resins, unsaturated polyesters, furan resins, urea resins, melamine resins, diaryl phthalate resins, epoxy resins, fluorine resins, polyimide resins, and the like. The ratio of resin to rubber is 0.1 ~ 1.5: 1 based on the required use of the resin and rubber. The ratio of resin to rubber is appropriate (by weight). The higher the strength of the resin, the lower the rubber compounding ratio and the less elasticity. Is characterized by being enhanced.

이하 본 발명의 제조공정을 첨부한 도면에 기초하여 구체적인 실시예를 통하여 설명한다.Hereinafter, the manufacturing process of the present invention will be described through specific embodiments based on the accompanying drawings.

본 발명의 롤러는 박판의 도너츠 형태를 이루는 부직형태의 섬유층에 고무와 열경화성수지를 침투시켜 충전층을 구성하여 이들을 롤러프레임에 중앙공이 끼워지도록 적층하여 준 다음 압축처리한 채 경화시킨 것이다. 경화처리된 것은 표면을 연마처리하여 마감처리하므로서 목적한 제철소용 롤러로 이용이 될 수 있는 것이다.The roller of the present invention forms a filling layer by infiltrating rubber and thermosetting resin into a nonwoven fiber layer forming a donut form of a thin plate, and stacking them so that a central hole is inserted into a roller frame, and then curing them while compressing. What is hardened can be used as a roller for the desired steelworks by polishing and finishing the surface.

본 발명은 도 1 에 도시하듯이 합성섬유 혹은 천연섬유 혹은 이들의 혼합섬유로 제작된 섬유중에서 폐기되어 버리는 폐섬유를 타면처리하여 직조상태를 해체한 판상의 부직포상태로 성형하는 공정,The present invention is a step of forming a nonwoven fabric of the disassembled woven state by treating the waste fibers discarded in the fibers made of synthetic fibers or natural fibers or mixed fibers thereof as shown in Figure 1,

부직상태로 된 폐섬유를 원형의 프레스금형을 이용하여 디스크원반형으로 절취하여 주는 디스크원반 제조공정,Disc disc manufacturing process that cuts non-woven waste fiber into disc disc using circular press mold,

절취된 원판을 일정한 양만큼 적층하여 열경화성 수지와 고무로 구성된 혼합충전액(30)으로 채워져 있는 폐쇄된 함침조(50)에 넣고 진공을 유지하여 섬유의 내부 공극으로 수지와 고무를 침투하는 공정,Stacking the cut discs in a predetermined amount and placing them in a closed impregnation tank 50 filled with a mixed filling liquid 30 composed of a thermosetting resin and rubber to maintain a vacuum to infiltrate the resin and rubber into the pores of the fiber;

수지와 고무가 충분히 침투되면 건조로에 넣고 건조처리하는 공정,When resin and rubber are sufficiently penetrated, it is put into a drying furnace and dried.

건조가 완료된 원판의 중앙공(3)을 이용하여 롤러프레임(1)에 차례로 적층하여 준 다음 횡방향에서 압축판(60)으로 압축하여 주는 공정,Laminating in order to the roller frame (1) by using the central hole (3) of the original disk is dried and then compressed into a compression plate 60 in the transverse direction,

고압압축이 된 상태를 유지하면서 고온의 경화조에 넣고 열경화처리하는 공정,Process to heat-cure into a high-temperature curing tank while maintaining the state of high-pressure compression,

열경화가 완료된 것의 표면을 선반이나 기타 장치를 이용하여 불규칙한 표면(70)을 연마하여 주는 표면마감공정으로 구성되어 있다.It is composed of a surface finishing process for polishing the irregular surface 70 by using a shelf or other device to the surface of the heat curing is completed.

본 발명에서 폐섬유를 타면처리하는 정도는 단위부피(㎥)당 180∼250Kg이 되도록 한다. 180이하로 처리하면 너무 많은 공극으로 인하여 섬유의 골격구조를 유지하기 어렵고, 250보다 많게 하면 수지와 고무의 첨가량이 적게되어 목적한 특성을 갖도록 조절하기 어렵게 된다.In the present invention, the degree of processing the other surface of the waste fiber is to be 180 ~ 250Kg per unit volume (㎥). If the treatment is less than 180 it is difficult to maintain the skeleton structure of the fiber due to too many voids, more than 250 it is difficult to control to have the desired properties because the addition amount of the resin and rubber is less.

본 발명에서 진공을 유지하는 함침조(50)는 섬유의 형태에 따라 다를 수 있으나 적어도 0.1기압이하를 유지하면서 상온에서 0.5내지 3시간 가량 함침처리한다.In the present invention, the impregnation tank 50 to maintain the vacuum may vary depending on the shape of the fiber, but the impregnation treatment for 0.5 to 3 hours at room temperature while maintaining at least 0.1 atm or less.

본 발명에서 함침처리에 사용된 열경화성 수지와 고무는 중량을 기준으로 0.1∼1.5 : 1.0 비율로 혼합하여 주며 소량의 가류제와 경화촉진제 그리고 혼합촉진제를 사용된 수지의 특성에 맞추어 첨가한다. 사용된 고무가 합성고무인 경우에는 열경화성 수지용 경화촉진제와 고무 경화촉진제를 동시에 사용할 수 있으며, 경화에 알맞는 것이라면 모두 사용가능하다.In the present invention, the thermosetting resin and rubber used in the impregnation treatment are mixed in a ratio of 0.1 to 1.5: 1.0 by weight, and a small amount of vulcanizing agent, curing accelerator, and mixing accelerator is added according to the characteristics of the resin used. When the rubber used is a synthetic rubber, a curing accelerator for thermosetting resin and a rubber curing accelerator may be used at the same time, and any rubber suitable for curing may be used.

본 발명에서 함침처리가 완료된 것은 건조로에 넣고 100℃미만의 온도의 열풍순환으로 건조처리하여준다. 건조의 온도가 너무 높으면 그대로 경화가 되므로 부분적인 온도불균일현상이 없도록 열풍을 순환처리하여 준다. 건조는 표면에 접촉시 액상의 수지류와 고무가 묻어나지 않을 정도이면 적당하다.Complete the impregnation treatment in the present invention is put into a drying furnace to be dried by hot air circulation at a temperature of less than 100 ℃. If the drying temperature is too high, it hardens as it is, and the hot air is circulated to avoid partial temperature unevenness. Drying is suitable as long as the liquid resins and rubbers do not adhere to the surface.

건조가 완료된 것은 중앙공(3)에 롤러프레임(1)이 끼워지도록 하여 적층처리한 다음 프레스기를 이용하여 롤러프레임의 축방향으로 좌우의 압축판(60)으로 압축처리하여 준다. 압축압력은 50∼50,000㎏/㎠이 되도록 한다. 압력은 사용되는 고무와 수지의 종류 그리고 사용된 폐섬유에 따라 고무의 사용량이 많을수록 압을 낮추고 폐섬유의 직경이나 탄성에 따라 선택하여야 한다. 50이하로 압축하면 내부 공극이 너무 벌어져 탄성은 있으나 쉽게 마모, 변형되어 버리며, 50,000이 넘게 압축하면 강도가 좋아져 내구성은 증가하나 탄성이 너무 낮아져 이송하는 판상의 철판이 손상되어 버리는 경향이 있고 롤러도 그 충격으로 파손되어 버린다.After the drying is completed, the roller frame 1 is inserted into the central hole 3 to be laminated, and then compressed using a press machine to the left and right compression plates 60 in the axial direction of the roller frame. Compression pressure is to be 50 ~ 50,000 kg / ㎠. Depending on the type of rubber and resin used and the waste fiber used, the pressure should be lowered according to the amount of rubber used and should be selected according to the diameter or elasticity of the waste fiber. When compressed to 50 or less, the internal voids become too wide and elastic, but they are easily worn and deformed. Compressing more than 50,000 increases strength and durability, but the elasticity is too low, which tends to damage the plate steel plate to be transported. It will be damaged by the shock.

압축이 완료된 것은 그대로 압축상태를 유지하면서 고온경화조(70)에 넣고 경화처리한다. 경화처리는 내부온도를 100∼180℃와 압력 4∼5㎏/㎠로 7∼12시간 처리하여 준다. 내부온도는 사용되는 수지와 고무의 경화에 알맞게 변경가능하다.Completion of the compression is put into a high-temperature curing tank 70 while maintaining the compression state as it is to be cured. The curing treatment is performed at an internal temperature of 100 to 180 ° C. and a pressure of 4 to 5 kg / cm 2 for 7 to 12 hours. The internal temperature can be changed to suit the curing of the resin and rubber used.

이상의 공정에 따라 제조된 실시예를 설명한다.The Example manufactured according to the above process is demonstrated.

실시예1.Example 1

면과 폴리에스터가 9:1로 혼합된 폐섬유를 약 200 g/㎥이 되도록 타면처리한 것을 프레스금형을 이용하여 두께 약 3mm의 도너츠형태로 절단하였다. 이 부직포를 일정한 숫자만큼 적층하여 적어도 0.1기압이하로 유지되는 함침조에 넣고 페놀수지와 NR고무가 1:1의 비로 혼합된 용액에 넣고 2시간 동안 혼합용액이 침투하도록 하였다. 함침이 완료된 도너츠형의 디스크 원반을 꺼내어 60∼70℃로 유지되는 열풍을 순환시켜줄 수 있는 건조로에 넣고 1시간 정도 건조 처리하였다. 건조가 완료된 것을 봉상의 롤러프레임에 중앙공이 끼워지도록 삽입하여 롤러프레임의 기리방향을 따라 적층하여 양단을 강판으로 마감시켜준다. 이어서 양단의 강판을 고압프레스로 약 20톤의 압을 주어 축방향압축처리하였다. 압축이 된 상태를 유지하면서 고온 경화조에 넣고 130℃의 온도와 약 4Kg/㎠의 압력을 가하면서 10시간가량 경화처리하였다. 경화가 완료된 것은 공지의 가공기를 이용하여 표면을 일정하게 다듬어 주면 목적한 롤러가 얻어진다. 생성된 제품의 물성은 표2와 같다.The waste fiber mixed with cotton and polyester 9: 1 was cut into a donut shape having a thickness of about 3 mm using a press mold. The nonwoven fabric was laminated by a certain number and placed in an impregnation tank maintained at least 0.1 atm or less in a solution in which the phenol resin and the NR rubber were mixed in a ratio of 1: 1 to allow the mixed solution to penetrate for 2 hours. The donut-shaped disk disk which has been impregnated was taken out and placed in a drying furnace capable of circulating hot air maintained at 60 to 70 ° C. and dried for about 1 hour. When the drying is completed, the center hole is inserted into the rod-shaped roller frame to be laminated along the direction of the roller frame to finish both ends with a steel sheet. Subsequently, the steel plates at both ends were subjected to axial compression by applying a pressure of about 20 tons using a high pressure press. The mixture was placed in a high temperature curing tank while maintaining a compressed state, and cured for about 10 hours while applying a temperature of 130 ° C. and a pressure of about 4 Kg / cm 2. When the hardening is completed, if the surface is trimmed uniformly using a well-known processing machine, the target roller will be obtained. Physical properties of the resulting product are shown in Table 2.

이하 다양한 재료와 조건에 의한 실시예를 다음의 표1로 정리하여 실시예를 설명한다.Hereinafter, the examples according to various materials and conditions will be described in Table 1 below.

* 상기한 실시예에서 내화학성이란 적어도 pH4이하의 산성과 pH10이상의 알카리성 약품에 롤러를 침지한 다음 100℃이상으로 가열하여 발생되는 변화의 유무를 기준으로 한다. 이상유무는 표면에 균열, 0.1mm이상의 핀홀발생이 전무이면 우수로 판정한다.* Chemical resistance in the above embodiment is based on the presence or absence of changes caused by immersing the roller in an alkaline chemical agent of at least pH 4 and less than pH 10 and then heating to 100 ℃ or more. Abnormality is judged to be excellent if there is no crack on the surface and no pinhole occurrence of 0.1 mm or more.

* 내열성은 130∼ 150℃의 온도에서 6개월이상 방치시 롤러표면의 탄화정도로 판단한다. 표면에 탄화가 발생하여 1㎠이상의 각질 분리현상이 발생시 불량으로 판단한다.* Heat resistance is judged as the degree of carbonization of the roller surface when left at the temperature of 130 ~ 150 ℃ for more than 6 months. When carbonization occurs on the surface and keratin separation phenomenon of 1cm2 or more occurs, it is judged to be defective.

* 가공성은 제조된 롤러를 그라인더, 마찰페이퍼 그리고 바이트로 가공시 표면의 1㎠이상의 입자 분리현상이 발생하거나 깊이 1mm이상의 홀이 발생하는 경우 불량으로 판단한다.* Machinability is judged to be defective when the manufactured roller is processed into grinder, friction paper, and bite when particle separation of more than 1cm 2 or hole of more than 1mm in depth occurs.

이상의 실시예에 나타나듯이 본발명의 제조공정에 의하여 제조된 롤러는 내화학성, 내열성 그리고 가공성에 있어 우수한 것으로 판명되었다.As shown in the above examples, the rollers produced by the manufacturing process of the present invention were found to be excellent in chemical resistance, heat resistance and processability.

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Claims (4)

합성섬유 혹은 천연섬유 혹은 이들의 혼합섬유로 제작된 섬유중에서 폐기되어 버리는 폐섬유를 ㎥당 180내지 250g이 되도록 타면처리하여 직조상태를 해체한 판상의 부직포상태로 성형하는 공정,A process of forming waste fibers discarded from synthetic fibers or natural fibers or mixed fibers thereof to form 180 to 250 g per m3 to form a nonwoven fabric in a disassembled woven state, 부직상태로 된 폐섬유를 원형의 프레스금형을 이용하여 중앙공이 있는 원형으로 절취하여 주는 디스크원반 제조공정,Disc disk manufacturing process that cuts non-woven waste fiber into a circle with a central hole by using a circular press mold, 절취된 원판을 일정한 양만큼 적층하여 열경화성 수지와 고무를 중량비를 기준으로 0.1내지1.5:1의 비율로 배합되어 있는 폐쇄된 함침조(50)에 넣고 0.1기압이하의 진공을 유지한 채 0.5내지 3시간 동안 섬유의 내부 공극으로 수지와 고무를 침투하는 공정,The cut discs were laminated in a predetermined amount, and the thermosetting resin and rubber were placed in a closed impregnation tank 50 having a ratio of 0.1 to 1.5: 1 based on the weight ratio, and maintained at a vacuum of 0.1 to 0.5 to 3 The process of penetrating resin and rubber into the inner voids of the fiber for a time, 수지와 고무가 충분히 침투되면 건조로에 넣고 60내지 80℃의 온도로 건조처리하는 공정,When the resin and rubber sufficiently infiltrate the process, it is put in a drying furnace and dried at a temperature of 60 to 80 ℃, 건조가 완료된 원판의 중앙공(3)을 이용하여 롤러프레임(1)에 차례로 적층하여 준 다음 횡방향에서 0.5내지 50톤/㎠의 압력으로 압축판(60)으로 중앙을 향하여 압축하여 주는 공정,Laminating in order to the roller frame (1) by using the central hole (3) of the original disk is dried and then compressed to the center with a compression plate 60 at a pressure of 0.5 to 50 tons / ㎠ in the transverse direction, 고압압축이 된 상태를 유지하면서 고온경화조에 넣고 110내지 130℃의 온도로 열경화처리하는 공정,Process of thermosetting at a temperature of 110 to 130 ° C. in a high temperature curing tank while maintaining a state of high pressure compression; 열경화가 완료된 것의 표면을 선반이나 기타 장치를 이용하여 불규칙한 표면(70)을 연마하여 주는 표면마감공정으로 구성된 내연강판제철소용 롤러의 제조방법.A method of manufacturing a roller for an internal-rolled steel sheet steel, comprising a surface finishing process for polishing an irregular surface 70 by using a lathe or other device on the surface of the thermal curing. 제 1 항에 있어서,The method of claim 1, 사용되는 열경화성 수지는 페놀수지, 불포화폴리에스테르, 푸란수지, 우레아수지, 멜라민수지, 디아릴프탈레이트수지, 에폭시수지, 불소수지, 폴리이미드수지중의 어느 한 가지 혹은 이들의 혼합물인 것을 특징으로 하는 내연강판제철소용 롤러의 제조방법.The thermosetting resin used is any one or a mixture of phenol resins, unsaturated polyesters, furan resins, urea resins, melamine resins, diaryl phthalate resins, epoxy resins, fluorine resins, and polyimide resins. Manufacturing method of roller for steel mill. 제 1 항에 있어서,The method of claim 1, 사용할 수 있는 고무는 단순한 천연고무외에도 SBR(스티렌부타디엔고무), CR(클로로프렌고무), IIR(부틸고무), EPDM, IR(이소프렌고무), BR(부타디엔러버), CSM(클로로술폰화폴리에틸렌), 우레탄고무,EVA 중의 어느 한 가지 혹은 이들의 혼합물인 것을 특징으로 하는 냉연강판제철소용 롤러의 제조방법.Rubber which can be used is SBR (styrene butadiene rubber), CR (chloroprene rubber), IIR (butyl rubber), EPDM, IR (isoprene rubber), BR (butadiene rubber), CSM (chlorosulfonated polyethylene) A method for producing a roller for cold rolled steel sheet, characterized in that any one of urethane rubber and EVA or a mixture thereof. 합성섬유 혹은 천연섬유 혹은 이들의 혼합섬유로 제작된 섬유중에서 폐기되어 버리는 폐섬유를 ㎥당 180내지 250Kg이 되도록 타면처리하여 판상형태의 부직포로 성형하여 중앙공(3)이 있는 원반형으로 절취하여 놓고, 절취된 디스크원반을 일정한 양만큼 적층하여 열경화성 수지와 고무를 중량비를 기준으로 0.1내지1.5:1의 비율로 배합되어 있는 폐쇄된 함침조(50)에 넣고 0.1기압이하의 진공을 유지한 채 0.5내지 3시간 동안 섬유의 내부 공극으로 수지와 고무를 침투하여 건조로에 넣고 60내지 80℃의 온도로 건조처리하여 얻어진 디스크원반을 준비하고,Waste fiber discarded from synthetic fiber or natural fiber or fiber made of mixed fiber is processed to be 180 ~ 250Kg per m3, molded into plate-shaped nonwoven fabric, cut into disc shape with central hole (3) Lay the disc disk cut in a certain amount, and put the thermosetting resin and rubber in the closed impregnation tank 50, which is mixed in a ratio of 0.1 to 1.5: 1 based on the weight ratio, and keeps the vacuum below 0.1 atm. Preparing a disk disc obtained by infiltrating the resin and rubber into the interior voids of the fiber for 3 to 3 hours and drying the mixture at a temperature of 60 to 80 ° C. 건조가 완료된 디스크원판의 중앙공(3)을 이용하여 롤러프레임(1)에 차례로 적층하여 준 다음 횡방향에서 0.5내지 50톤/㎠의 압력으로 압축판(60)로 양측에서 축방향압축하여 일체로 한 다음 고압압축이 된 상태를 유지하면서 고온경화조에 넣고 110내지 130℃의 온도로 열경화처리하여 얻어진 롤러의 표면을 연마하여 얻어진 냉연강판제철소용 롤러.Lay in the roller frame 1 by using the central hole (3) of the disk disk is dried, and then axial compression on both sides with the compression plate 60 at a pressure of 0.5 to 50 tons / ㎠ in the transverse direction The roller for cold rolled steelworks obtained by grinding the surface of the roller obtained by making it into the high temperature hardening tank, maintaining the high pressure compression, and thermosetting at the temperature of 110-130 degreeC.
KR10-1999-0033448A 1999-08-13 1999-08-13 A process for the production of cold plate roller and their roller using wasted fabric material KR100364116B1 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100346914B1 (en) * 1999-12-23 2002-08-13 조재권 A roller for producting rolled steel
KR100838601B1 (en) * 2008-01-02 2008-06-16 임채권 Manufacture method for noise prevention device equip transfer roller and thereof product
WO2011078730A1 (en) * 2009-12-21 2011-06-30 Shamaev Alexey Nikolaevich Video presentation method intended for prompting a change in the sound level of reproducing a vocal part
KR102046722B1 (en) * 2018-08-06 2019-11-19 신윤호 Fabrication method of fabric using recycled waste clothing and manufacturing method of chair seat
CN112279526A (en) * 2020-10-30 2021-01-29 娄底光华机械设备制造有限公司 Glass fiber soaks device for advanced materials

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2554215Y2 (en) * 1991-07-08 1997-11-17 日本バイリーン株式会社 Chemical resistant industrial roll
KR950000361A (en) * 1993-06-29 1995-01-03 윤종용 Manufacturing method of fiber reinforced plastic roller for metal surface treatment
KR0169407B1 (en) * 1995-12-02 1999-01-15 송화웅 Nonwoven fabric cloth roll for plates
KR200180215Y1 (en) * 1997-10-23 2000-08-01 남향현 Non woven cloth and elastic material laminated roller
JPH11129353A (en) * 1997-10-29 1999-05-18 Tokai Rubber Ind Ltd Method and equipment for manufacturing roll

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100346914B1 (en) * 1999-12-23 2002-08-13 조재권 A roller for producting rolled steel
KR100838601B1 (en) * 2008-01-02 2008-06-16 임채권 Manufacture method for noise prevention device equip transfer roller and thereof product
WO2011078730A1 (en) * 2009-12-21 2011-06-30 Shamaev Alexey Nikolaevich Video presentation method intended for prompting a change in the sound level of reproducing a vocal part
KR102046722B1 (en) * 2018-08-06 2019-11-19 신윤호 Fabrication method of fabric using recycled waste clothing and manufacturing method of chair seat
CN112279526A (en) * 2020-10-30 2021-01-29 娄底光华机械设备制造有限公司 Glass fiber soaks device for advanced materials

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