KR20000043777A - Mid-carbon steel excellent in quench and fine blanking workability and method of manufacturing the same - Google Patents

Mid-carbon steel excellent in quench and fine blanking workability and method of manufacturing the same Download PDF

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KR20000043777A
KR20000043777A KR1019980060198A KR19980060198A KR20000043777A KR 20000043777 A KR20000043777 A KR 20000043777A KR 1019980060198 A KR1019980060198 A KR 1019980060198A KR 19980060198 A KR19980060198 A KR 19980060198A KR 20000043777 A KR20000043777 A KR 20000043777A
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fine blanking
steel
hardness
less
heat treatment
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KR100376927B1 (en
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류재화
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이구택
포항종합제철 주식회사
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

PURPOSE: A method of manufacturing medium-carbon steel is provided to have fine blanking characteristic of low-carbon steel and to obtain quenching of high-carbon steel at the same time. CONSTITUTION: Steel consists of, by weight %: 0.15-0.35% of C, 0.1-0.5% of Si, 0.5-1.5% of Mn, 0.1-1.0% of Cr, not more than 0.005% of S, not more than 0.02% of P, 0.0005-0.005% of B, 2-7% of Ti/N, Fe and incidental impurities. The steel is hot-rolled at a temperature of 1240°C for 250 minutes or shorter and coiled at a temperature of 550-630°C to manufacture a hot-rolled steel plate. Finally, the manufactured steel plate is annealed.

Description

소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강 및 그 제조방법Medium carbon steel with excellent hardening heat treatment and fine blanking processability and its manufacturing method

본 발명은 자동차부품 및 기계부품 등에 사용되는 중탄소강대를 제조하기 위한 중탄소강 및 이를 이용한 제조방법에 관한 것으로 보다 상세하게는 소입열처리성이 높으면서도 파인블랭킹 가공성이 우수한 중탄소강대의 제조방법에 관한 것이다.The present invention relates to a medium carbon steel for manufacturing a medium carbon steel sheet used in automobile parts and mechanical parts, and more particularly, to a method for manufacturing a medium carbon steel sheet having high hardening heat treatment property and excellent fine blanking workability. will be.

근래에 와서 기계부품 및 자동차 부품의 많은 부분은 블랭킹가공을 통해 제조된다. 블랭킹가공이란 강판을 펀치와 다이사이에 넣고 펀치로 눌러 전단가공하는 것을 말한다. 블랭킹 종류는 일반적으로 일반블랭킹과 파인블랭킹으로 나눌 수 있는데 일반 블랭킹은 단순히 강판을 다이위에 놓고 펀치로 내리치면서 부품을 가공하는데 비해, 파인블랭킹은 블랭킹홀더로 강파을 움직이지 못하도록 고정하고 위의 펀치와 아래의 펀치로 재료를 동시에 잡고 서서히 밑으로 잡아 당기면서 부품을 가공하는 기술이다. 일반블랭킹으로 제조된 부품은 전단면이 30%이고, 파단면이 70%로서 블랭킹 단면이 좋지 못하고, 부품이 정밀하지 못하며, 또한 가공시 약간의 변형이 발생한다. 이에 반해 파인블랭킹으로 가공된 부품은 전단면이 100%이기 때문에 매우 미려한 블랭킹 단면을 가지며, 부품의 정밀도가 기계가공부품의 수준이며, 가공시에 변형이 전혀 발생하지 않는다. 또한 파인블랭킹은 일반블랭킹에 비해 2차가공을 필요로 하지 않기 때문에 생산공정을 생략할 수 잇고, 또한 기계가공과 유사한 정밀한 부품을 만들면서도 기계가공보다는 생산성이 매우 높기 때문에 최근에 와서 각광을 받고 있다.In recent years, much of mechanical parts and automobile parts are manufactured by blanking. Blanking processing refers to shearing a steel sheet between a punch and a die and pressing it with a punch. The blanking type is generally divided into general blanking and fine blanking. In general blanking, the parts are simply machined by placing the steel plate on the die and punching it down. It is a technology that processes parts while simultaneously grabbing the material with a punch and pulling it downward. Parts manufactured by general blanking have a shear surface of 30%, a fracture surface of 70%, a poor blanking cross section, an inaccurate component, and slight deformation during processing. On the other hand, the parts processed by fine blanking have a very beautiful blanking cross section because the shear surface is 100%, the precision of the parts is the level of the machined parts, and no deformation occurs at all. In addition, since fine blanking does not require secondary processing compared to general blanking, the production process can be omitted, and the production of precision parts similar to the machining can be omitted, but the productivity is much higher than machining. .

파인블랭킹은 일반블랭킹과 가공방식이 크게 다르기 때문에 파인블랭킹용으로 요구되는 소재의 특성도 다르다. 파인블랭킹 소재가 갖추어야 할 조건은 이방성이 없이 균일하고, 또한 연성이 커야 한다.Fine blanking differs from general blanking in that it is processed differently, so the characteristics of the material required for fine blanking are also different. The conditions for the fine blanking material should be uniform without anisotropy and large ductility.

파인블랭킹용 강판의 제조방법은 저탄소강에서 고탄소강에 이르기까지 여러 가지 종류가 있다. 일본공개특허공보(JP 58-104160 A)와 일본특허공보(JP 5-14784 B2)에 의하면 탄소함량이 비교적 낮은 저탄소강을 이용하여 파인블랭킹용 강판제조법을 제시하고 있으나 저탄속강은 경도가 낮고 연성이 우수하여 파인블랭킹성은 우수할 수 있으나 소입열처리성이 나쁘기 때문에 기계부품에서 많이 요구되는 부품 중심부까지 고경도와 고강도를 얻기가 힘들고, 또한 두꺼운 부품을 제조할수 없는 문제점이 있다.There are various kinds of methods for producing fine blanking steel sheet, from low carbon steel to high carbon steel. Japanese Laid-Open Patent Publications (JP 58-104160 A) and Japanese Patent Publications (JP 5-14784 B2) provide methods for manufacturing fine blanking steel sheets using low carbon steels with relatively low carbon contents, but low-carbon steels have low hardness and ductility. The fine blanking property may be excellent, but the hard quenching heat treatment is poor, so it is difficult to obtain high hardness and high strength from the mechanical parts to the required parts, and there is a problem in that thick parts cannot be manufactured.

소입열처리성을 향상시키고 열추리후 고강도를 얻기 위해 탄소함량을 높인 고탄소용 파인블랭킹용 강의 제조방법이 일본특허공보(JP 62-2008 B2)에 제시되고 있으나, 탄소함량이 높아지면 퍼얼라이트량이 많아 구상화소둔후에도 경도가 높고 연성이 낮아 부품의 파인블랭킹성이 저하될 뿐만 아니라 파인블랭킹 금형의 마모가 심해져서 금형을 자주 교체해야 하는 문제점이 있다.Japanese Patent Publication (JP 62-2008 B2) discloses a method for manufacturing high carbon fine blanking steel with high carbon content in order to improve the quenching heat treatment and to obtain high strength after heat inference. Even after spheroidizing annealing, the hardness and the ductility are low, so that the fine blanking property of the part is not only degraded, but the wear of the fine blanking mold is severe, which causes frequent mold replacement.

이에 본 발명자는 고탄소강의 높은 소입열처리성과 저탄소강의 우수한 파인블랭킹성을 동시에 가지는 강을 얻기 위해 연구와 실험을 거듭하고, 그 결과에 근거하여 본발명을 제안하게 된 것으로, 본 발명은 저탄소강과 고탄소강의 중간범위를 가진 중탄소강을 이용하여 개재물 및 미세조직을 조절하여 저탄소강 수준의 우수한 파인블랭킹 특성을 가지게 하고, 미량의 보론 및 Mn, Cr 등의 합금원소를 첨가하여 고탄소강의 수준의 우수한 소입열처리성을 가지게 함으로써 소입열처리성과 파인블랭킹성이 동시에 가지는 중탄소강대를 제조하는 방법을 제공하는데, 그 목적이 있다.Accordingly, the present inventors have repeatedly conducted studies and experiments to obtain a steel having both high quenching heat treatment of high carbon steel and excellent fine blanking property of low carbon steel, and proposed the present invention based on the results. The medium carbon steel having the middle range of carbon steel is used to control the inclusions and microstructures so that they have excellent fine blanking characteristics at low carbon steel levels, and the addition of trace amounts of boron and alloying elements such as Mn and Cr It is an object of the present invention to provide a method for producing a medium carbon steel strip having both quench heat treatment and fine blanking properties by having quench heat treatment.

본 발명은 상기 목적을 달성하기 위하여, 중량%로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.5-1.5%, Cr:0.1-1.0%, S:0.005%이하, P:0.02%이하, B: 0.0005 -0.005%, Ti/N : 2-7를 함유하고, 잔부 Fe 및 불가피한 불순물로 이루어지는 강재와, 상기 강재를 먼저, 가열온도 1240℃이하에서 가열시간을 250분이하로 하여 열간압연한 후, 권취온도를 550℃∼630℃로 하여 열연강판을 제조하고, 제조된 열연강판을 Ac1변태온도 이하에서 구상화소둔을 실시하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강대의 제조방법을 제공하는 것을 특징으로 한다.In order to achieve the above object, the present invention provides, by weight%, C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.5-1.5%, Cr: 0.1-1.0%, S: 0.005% or less, and P: 0.02% or less, B: 0.0005 -0.005%, Ti / N: 2-7, and the steel material consisting of the remaining Fe and unavoidable impurities, and the steel first, the heating time is 250 minutes or less at a heating temperature of 1240 ℃ or less After hot rolling, a hot rolled steel sheet is manufactured at a coiling temperature of 550 ° C. to 630 ° C., and a method for producing a medium carbon steel sheet having excellent hardening heat treatment and fine blanking workability is performed by spheroidizing annealing the prepared hot rolled steel at a transformation temperature below A c1. It characterized in that to provide.

또한, 본 발명은 중량%로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.4-1.5%, Cr: 0.1-1.0%, S:0.010%이하, P:0.02%이하, B:0.0005-0.005%, Ti/N : 2-7, Ca: 0.001 -0.01%를 함유하고, 잔부 Fe 및 불가피한 불순물로 이루어지는 강재와, 상가 강재를 먼저, 가열온도 1240℃이하에서 가열시간을 250분이하로 하여 열간압연한 후, 권취온도를 550℃∼630℃로 하여 열연강판을 제조하고, 제조된 열연강판을 Ac1변태온도 이하에서 구상화소둔을 실시하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강대의 제조방법을 제공한다.In addition, the present invention is in weight%, C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.4-1.5%, Cr: 0.1-1.0%, S: 0.010% or less, P: 0.02% or less, B : 0.0005-0.005%, Ti / N: 2-7, Ca: 0.001 -0.01%, and the steel material consisting of the balance Fe and unavoidable impurities, and the commercial steel, first, the heating time is 250 minutes at a heating temperature of 1240 ℃ or less After hot rolling, a hot-rolled steel sheet is manufactured at a coiling temperature of 550 ° C. to 630 ° C., and the annealed heat treatment and fine blanking workability are performed in which the prepared hot rolled steel sheet is spheroidized and annealed at a transformation temperature below A c1. It provides a manufacturing method.

이하, 본 발명에 대하여 더욱 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.

본 발명자는 중탄소강의 소입 열처리성 및 파인블랭킹성에 영향을 미치는 강중의 탄소, 보론, Mn, Cr, S, Ca의 작용 및 열간압연조건 및 구상화소둔 조건등의 제조조건을 연구한 겨로가 탄소, 보론, Mn, Cr, S, Ca를 적절히 함유시킨 강에서 소입열처리성과 파인블랭킹성이 우수한 강을 제조할 수 있음을 알았다.The present inventors have studied the working conditions of carbon, boron, Mn, Cr, S, Ca, and hot rolling conditions and spheroidizing annealing conditions in steel that affect the hardening heat treatment and fine blanking properties of medium carbon steel, It was found that steel having excellent quench heat treatment and fine blanking properties can be produced from steels containing boron, Mn, Cr, S, and Ca properly.

상기한 바와 같은 관점으로부터 출발한 본 발명을 중량비로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.5-1.5%, Cr:0.1-1.0%, S:0.005%이하, P:0.02%이하, B:0.0005-0.005%, Ti/N : 2~7를 함유하고, 잔부 Fe 및 불순물로 이루어지는 중탄소강,The present invention, starting from the above point of view, in a weight ratio of C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.5-1.5%, Cr: 0.1-1.0%, S: 0.005% or less, P: 0.02% or less, B: 0.0005-0.005%, Ti / N: Medium carbon steel containing 2-7, consisting of remainder Fe and impurities,

또는 중량비로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.4-1.5%, Cr:0.1-1.0%, S:0.010%이하, P:0.02%이하, B:0.0005-0.005%, Ti/N : 2~7, Ca : 0.001-0.01%를 함유하고, 잔부 Fe 및 불순물로 이루어지는 중탄소강에 관한 것이며,Or by weight ratio: C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.4-1.5%, Cr: 0.1-1.0%, S: 0.010% or less, P: 0.02% or less, B: 0.0005-0.005% , Ti / N: 2 to 7, Ca: 0.001-0.01%, and relates to a heavy carbon steel composed of balance Fe and impurities,

또한, 본 발명은 상기와 같은 조성의 강재를 가열온도 1240℃이하에서 가열시간을 250분이하로 하여 통상의 열간압연조건으로 열간압연한 후 권취온도를 550℃ ~ 630℃로 하여 열연강판을 제조한 후, 제조된 열연강판을 Acl변태온도이하에서 구상화소둔을 행하는 중탄소강대의 제조방법에 관한 것이다.In addition, the present invention hot-rolled steel sheet of the composition as described above hot-rolled at a heating temperature of 1240 ℃ or less at a heating time of 250 minutes or less and under the usual hot rolling conditions to produce a hot rolled steel sheet with a temperature of 550 ℃ ~ 630 ℃ Thereafter, the present invention relates to a method for producing a medium carbon steel sheet in which spheroidizing annealing of a manufactured hot rolled steel sheet is performed at an Acl transformation temperature or less.

이하, 본 발명강의 조성범위 한정이유에 대하여 설명한다.Hereinafter, the reason for limiting the composition range of the inventive steel will be described.

상기 C는 강의 경도를 높이는 가장 중요한 원소로써 0.15-0.35중량% (이하 간단히 "%"라고 한다.) 함유된다. 소입과 템퍼링열처리에 의해 기계부품에 필요한 경도 (HRC:30)를 얻기 위해서는 C이 적어도 0.15%이상 함유하는 것이 필요하다. 그러나 c량 너무 많으면 구상화 소둔후의 경도가 높아지고 연성이 감소하여 파인블랭킹성이 크게 떨어지므로 0.35%이하로 한다.C is 0.15-0.35% by weight (hereinafter referred to simply as "%") as the most important element for increasing the hardness of steel. In order to obtain the hardness (HRC: 30) required for the mechanical parts by hardening and tempering heat treatment, it is necessary to contain C at least 0.15%. However, if the amount of c is too high, the hardness after spheroidizing annealing becomes high and the ductility decreases, so the fine blanking property is greatly reduced.

상기 Si는 탈산제로서 아주 중요한 원소로써 0.1-0.5% 함유된다. Si량이 너무 적으면 탈산효과가 적으므로 0.1% 이상 함유시킨다. 그러나 Si량이 너무 많으면 재가열시 탈탄이 심하게 되고, 또한 적스케일이 발생하여 산세가 어려워 표면결함이 발생하기 쉽고 고용강화에 의해 경도가 높고 연성이 저하되므로 0.5%이하로 제한한다.Si is contained 0.1-0.5% as a very important element as a deoxidizer. If the amount of Si is too small, since there is little deoxidation effect, it contains 0.1% or more. However, if the amount of Si is too high, decarburization becomes severe during reheating, and red scale occurs, so that pickling is difficult, so that surface defects easily occur, and hardness is high due to solid solution strengthening and ductility is lowered, so it is limited to 0.5% or less.

상기 Mn은 소입성을 향상시키는 중요한 원소이며, 그 효과를 얻기 위해 0.5%이상 함유 시켜야 한다. 그러나 함유량이 증가하면 퍼얼라이트와 페라이트가 층상으로 분포하는 조직(이하 밴드조직이라 한다)이 발생하기 쉽고, 세멘타이트의 구상화를 억제하며, 경도를 높이고 연성을 저하시키기 때문에 상한을 1.5%로 한정하였다.Mn is an important element for improving the hardenability, and should be contained 0.5% or more to obtain the effect. However, when the content is increased, the structure in which the ferrite and ferrite are distributed in layers (hereinafter referred to as a band structure) is likely to occur, and the upper limit is limited to 1.5% because it suppresses spheroidization of cementite, increases hardness, and decreases ductility. .

상기 Cr은 Mn에 비해 고용강화 효과가 적고 밴드조직의 발달을 조장하지 않으면서 소입성을 향상시키는 유효한 원소이다. 본발명에서는 주로 밴드조직 발달을 억제하고 소입성을 향상시킬 목적으로 Cr을 첨가하였으며, 그 하한을 0.1%로 하였다. 그러나 Cr이 너무 많이 첨가되면 경도가 높아지고 연성이 저하되기 때문에 상한을 1.0%로 하였다.Cr is an effective element that has less solid solution strengthening effect than Mn and improves hardenability without promoting the development of band structure. In the present invention, Cr was added mainly to suppress band structure development and to improve hardenability, and the lower limit thereof was 0.1%. However, when Cr is added too much, the hardness becomes high and the ductility falls, so the upper limit was made 1.0%.

상기 S는 유화물을 형성하여 열간압연시 압연방향으로 길게 연신되어 강판의 이방성을 크게 하기 때문에 파인블랭성을 크게 저하시킨다. S량은 적으면 적을수록 좋지만 파인블랭킹성을 크게 저하시키지 않은 범위인 0.005%를 상한으로 설정하였다.S forms an emulsion and is elongated in the rolling direction during hot rolling to increase the anisotropy of the steel sheet, thereby greatly reducing the fine blanking property. The smaller the amount of S, the better. However, the upper limit was set at 0.005%, which is a range in which the fine blanking property is not significantly reduced.

상기 p는 세멘타이트를 안정화시켜 구상화를 방해하고, Mn과 함께 존재하여 편석되어 밴드조직을 조장하는 역할을 하기 때문에 상한을 0.02%로 설정하였다.The p was set to an upper limit of 0.02% because stabilization of cementite prevents spheroidization and is present together with Mn to segregate to promote band structure.

상기 B는 오스테나이트 결정립계에 편석되어 소입열처리시 퍼얼라이트의 생성을 억제하여 경화능을 향상시키는 중요한 원소로서, 최소 0.0005%이상이 함유되어야 경화능이 높아진다. 그러나, B가 0.005%이상 함유되면 경화능을 향상시키는 효과가 적고, 강중에 보론 질화물이나 보론 탄화물을 형성하여 연성을 오히려 낮추는 역할을 한다.The B is an important element that segregates at the austenite grain boundary and suppresses the production of pearlite during the hardening heat treatment, thereby improving the hardenability, and the hardenability is increased when the B content is contained at least 0.0005%. However, when B is contained in an amount of 0.005% or more, the effect of improving the hardenability is small, and boron nitride or boron carbide is formed in the steel, thereby lowering the ductility.

상기 Ti는 B가 산화물이나 질화물을 형성하여 경화능향상 효과를 저하시키는 것을 미리 방지하기 위해 첨가된다. B가 고용상태로 남아 경화능의 효과를 가지기 위해 Ti/N의 비가 최소 2이상이 되어야 하지만 Ti/N 비가 너무 높으면 티타늄 탄질화물이 형성 되어 기지의 경도가 높아지고 연성이 감소하므로 Ti/N비의 상한을 7로 하였다.The Ti is added in advance to prevent B from forming an oxide or nitride to lower the effect of improving hardenability. The ratio of Ti / N must be at least 2 to have the effect of hardenability. However, if the Ti / N ratio is too high, titanium carbonitride is formed, which increases the hardness of the matrix and decreases the ductility. The upper limit was set to seven.

상기 Ca는 유화물을 구상화시켜 재질의 이방성을 감소시키기 위해 첨가되었으며, Ca 첨가 효과를 얻기 위해서는 최소 0.001%이상은 함유해야 한다. 그러나 Ca가 너무 많으면 산화물계의 비금속개재물이 증가하여 연성을 저하시키기 때문에 Ca량을 0.1%이하로 한정한다. 한편 Ca가 첨가될 때에도 S량은 적을수록 좋지만 Ca가 존재할 때 S는 MnS보다 CaS로 먼저 석출하기 때문에 S가 재질이방성에 미치는 영향이 감소하게 된다. 따라서 Ca 첨가시에는 S량의 상한을 0.01%로 한정한다.The Ca was added to spheroidize the emulsion to reduce the anisotropy of the material, and at least 0.001% of Ca should be contained in order to obtain the Ca addition effect. However, if the amount of Ca is too high, the amount of Ca is limited to 0.1% or less because oxide-based nonmetallic inclusions increase to decrease ductility. On the other hand, even when Ca is added, the smaller the amount of S, the better. However, when Ca is present, S is precipitated as CaS rather than MnS, so the effect of S on material anisotropy is reduced. Therefore, when Ca is added, the upper limit of the amount of S is limited to 0.01%.

이하, 상기와 같은 성분의 강재를 이용하여 강대를 제조하는 방법에 대해서 설명한다.Hereinafter, the method of manufacturing a steel strip using the steel materials of the above components is demonstrated.

상기와 같은 조성의 중탄소강을 이용하여 강대를 제조하는 공정에 있어, 열간압연 공정에서는 표면탈탄 방지와 조직을 미세화시켜 밴드조직의 억제가 중요하다.In the process of manufacturing a steel strip using the medium carbon steel of the above composition, in the hot rolling process, it is important to prevent surface decarburization and to suppress the band structure by miniaturizing the structure.

상기 표면탈탄은 고탄소강의 소입성을 감소시켜 내마모성 및 내구성을 저해할 뿐만 아니라 열처리시에도 변형을 초래한다. 이를 방지하기 위해 재가열온도를 낮추고 시간을 줄여야 한다. 열연강판 두께의 1.0%이하 정도의 표면탈탄은 최종열처리재의 경도 및 변형에 큰 영향을 주지 않으므로, 이를 위해 가열온도는 1240℃이하, 가열시간은 250분 이하로 제한하였다.The surface decarburization reduces the hardenability of the high carbon steel to inhibit wear resistance and durability, as well as cause deformation during heat treatment. To prevent this, the reheat temperature should be lowered and the time saved. Surface decarburization of about 1.0% or less of the thickness of the hot-rolled steel sheet does not significantly affect the hardness and deformation of the final heat treatment material. For this purpose, the heating temperature is limited to 1240 ° C. or less, and the heating time is 250 minutes or less.

상기 조직미세화를 통한 밴드조직 억제는 구상화소둔성, 파인블랭킹성, 연성, 소입열처리성을 향상시키기 우해 중요하다. 즉, 조직이 미세하고 밴드조직이 억제될수록 구상화소둔시 세멘타이트의 구상화가 미세하고 조기에 이루어지며, 이에 따라 강도가 낮아지고 연성이 높아 파인블랭킹성이 향상되고, 소입열처리성도 향상된다. 열연강판에서 조직미세화는 권취온도에 가장 크게 좌우되는데, 권취온도가 높을수록 조직이 조대화 되고 밴드조직이 발달하여 구상화가 어려워진다. 그러나 권취온도가 너무 낮게되면 조직은 미세하지만 베이나이트가 생성되어 강도가 너무 높게 되며 구상화소둔후에도 경도가 높아 아 파인블랭킹금형의 마모가 크게 초래된다. 따라서 권취온도는 550℃~630℃로 제한하였는데, 630℃이상에서는 조대한 조직이 되고 밴드조직도 발달하며, 550℃이하에서는 베이나이트조직이 되면서 강도가 증가하고 구상화소둔후에도 경도가 높기 때문이다.Band tissue suppression through the tissue micronization is important for improving spheroidizing annealing, fine blanking, ductility, heat treatment heat treatment. That is, the finer the structure and the more the band structure is suppressed, the more spheroidization of cementite during spheroidization annealing is achieved, thereby improving the fine blanking property and lowering the heat-treatment heat treatment. In the hot rolled steel, the tissue micronization is most dependent on the coiling temperature. The higher the coiling temperature, the more coarse the tissue and the more difficult the spheroidization. However, if the coiling temperature is too low, the structure is fine, but bainite is formed, the strength is too high, and even after spheroidizing annealing, the hardness of the fine blanking mold is greatly caused. Therefore, the coiling temperature was limited to 550 ℃ ~ 630 ℃, because the coarse structure and the band structure is developed above 630 ℃, the bainite structure below 550 ℃ increases the strength and hardness after spheroidization annealing.

본 발명에서는 상기한 바와 같은 열간압연공정을 거쳐 얻어진 열연강판을 Acl변태온도 이하에서 구상화소둔을 행하고, 그 후에 얻어진 구사오하소둔강판을 이용하여 파인블랭킹가공을 행하고, 오스테나이트 변태가 일어나는 변태온도인 Ac3변태온도보다 30℃이상 높은 통상의 소입열처리 온도에서 통상의 시간동안 유지한 후 유냉을 통해 마르텐사이트조직을 얻은 후 최종제품에서 요구하는 경도로 템퍼링을 행하여 제품을 얻을 수 있다.In the present invention, the hot rolled steel sheet obtained through the hot rolling process as described above is subjected to spheroidizing annealing at or below A cl transformation temperature, and then subjected to fine blanking using the obtained Kusao-annealed steel sheet, and the transformation temperature at which austenite transformation occurs. The product can be obtained by maintaining the normal quenching heat treatment temperature higher than 30 ° C. above the phosphorus A c3 transformation temperature, then obtaining martensite structure through oil cooling and tempering to the hardness required for the final product.

상기 구상화소둔겅정에 있어 Acl변태온도이상에서 소둔을 행하면 구상화된 세멘타이트의 크기가 조대화되거나 또는 조대한 퍼얼라이트가 다시 생성되어 파인블랭킹성이 저하되거나 소입열처리성이 저하된다. 따라서 구상화소둔온도는 Acl변태온도 이하로 한다.Wherein the spheroidizing annealing in geongjeong the size of the cementite spheroidization annealing performed in the above A cl transformation temperature is coarsened or a coarse pearlite is regenerated fine blanking property may be degraded, or heat treatment quenching property is deteriorated. Therefore, the nodular annealing temperature is below the A cl transformation temperature.

상기 소입열처리의 온도 및 시간은 통상적인 조건을 적용할 수 있으며, 기계부품에 필요한 경도를 얻기 위해서는 Ac3변태온도의 30℃이상의 온도에서 세멘타이트가 충분히 고용되도록 유지한 다음 기름에 소입하고 최종제품의 경도를 얻기 위해 템퍼링을 행하는 것이 바람직하다.The temperature and time of the quenching heat treatment can be applied to the usual conditions, in order to obtain the hardness required for the machine parts, the cementite is kept sufficiently dissolved at a temperature of 30 ℃ or more of the A3 transformation temperature and then quenched in oil and the final product It is preferable to perform tempering to obtain a hardness of.

이하 실시예를 통해 본 발명을 보다 상세히 설명한다.The present invention will be described in more detail with reference to the following examples.

(실시예1)Example 1

표 1과 같은 성분을 갖는 강재들을 준비하였다. 강종 No.1-5는 본발명에서 규정하는 화학성분 범위내의 강이고, 강종 No.6-13은 본발명에서 비교를 위해 용해한 강이다.Steels having the components shown in Table 1 were prepared. Steel grade No. 1-5 is a steel within the chemical composition specified in the present invention, and steel grade No. 6-13 is a steel melted for comparison in the present invention.

열연강판의 표면탈탄을 억제하기 위한 재가열조건을 도출하기 위해 표 1의 발명강 1을 이용하여 가열온도를 1240℃로 일정하게 두고 가열시간을 220분, 250분, 280분으로 측정하고, 그 결과를 표 2에 나타내었다. 표 2에 나타난 바와 같이 가열시간이 길어짐에 따라 탈탄층의 깊이가 증가함을 알 수 있으며, 본 발명에서 목표로 하는 열연강판 두께의 1.0%범위 내에서의 탈탄층을 얻기 위한 가열조건은 가열온도 1240℃이하에서 250분 이하임을 알 수 있다.In order to derive the reheating condition to suppress the surface decarburization of the hot rolled steel sheet, using the invention steel 1 of Table 1, the heating temperature was constant at 1240 ° C. and the heating time was measured at 220 minutes, 250 minutes, and 280 minutes. Is shown in Table 2. As shown in Table 2, it can be seen that the depth of the decarburized layer increases as the heating time increases, and the heating conditions for obtaining the decarburized layer within 1.0% of the thickness of the hot-rolled steel sheet targeted by the present invention are the heating temperature. It can be seen that less than 250 minutes at 1240 ℃ or less.

(실시예2)Example 2

본실시예에서는 열간압연후 권취조건을 도출하기 위해 표 1의 발명강 1을 이용하여 가열온도를 1240℃로 일정하게 두고 가열시간을 230분으로 가열한 수 통상의 열간압연 조건인 850℃에서 두께 5.0㎜로 마무리 압연한 후 각각, 500℃, 600℃, 650℃에서 권취하여 두께 5.0㎜의 열연강판을 제조하였다. 상기 열연강판을 산세하고 비산화성 분위기에서 구상화소둔을 행하여 구상화소둔강판을 제조하였다. 구상화소둔은 통상의 조건인 Acl변태온도보다 낮은 710℃에서 10시간동안 행하였다. 이와같이 제조된 열연강판에 대해서는 경도를 측정하였고, 구상화강판에 대해서는 경도 및 파인블랭킹성을 측정하였다. 파인블랭킹성 측정방법은 파인블랭킹 프레스를 이용하여 두께 5.0㎜의 자동차도어 부품을 직접 제작하였으며, 제조된 제품으로부터 전단면이 90%이상이면 양호(◎ 표시), 전단면이 90%이하이면 보통 (○ 표시)으로 나타내었으며, 측정부품수는 각각 50개씩으로 하였다. 표 3에는 그 결과를 나타내었다. 표 3에 나타난 바와 같이 권취온도가 500℃인 경우에는 열연강판은 베이나이트 조직을 가지며 구상화소둔후에는 탄화물이 미세하게 분포하면서 파인블랭킹성은 우수하지만 경도가 너무 높아 금형의 수명이 짧아지는 문제가 있다. 발명조건인 권취온도가 600℃인 경우에는 열연강판에서 페라이트와 퍼얼라이트가 미세하게 분포하여 구상화소둔후에는 세멘타이트가 불균일하게 분포하여 경도는 낮지만 파인블랭킹성이 우수하지 못함을 알 수 있다. 따라서 본 발명에서 목표로 하는 금형수명도 길고 파인블랭킹성도 우수한 권취온도 범위는 550~630℃ 범위임을 알 수 있다.In this embodiment, in order to derive the coiling condition after hot rolling, the heating temperature was constant at 1240 ° C. using the inventive steel 1 shown in Table 1, and the heating time was heated at 230 minutes. After finishing-rolling to 5.0 mm, it wound up at 500 degreeC, 600 degreeC, and 650 degreeC, respectively, and produced the hot rolled steel plate of thickness 5.0mm. The hot rolled steel sheet was pickled and spheroidized annealing was performed in a non-oxidizing atmosphere to prepare a spheroidized annealing steel sheet. Spherical annealing was carried out for 10 hours at 710 ° C. lower than A cl transformation temperature, which is the normal condition. The hardness was measured for the hot rolled steel sheet thus prepared, and the hardness and the fine blanking property were measured for the spheroidized steel sheet. The method of measuring fine blanking property was manufactured by directly manufacturing automotive door parts with a thickness of 5.0mm by using a fine blanking press.If the shear surface is 90% or more from the manufactured product, it is good (marked ◎), and if the shear surface is 90% or less, ○) and the number of measurement parts was set to 50 pieces each. Table 3 shows the results. As shown in Table 3, when the coiling temperature is 500 ° C, the hot rolled steel sheet has a bainite structure, and after the spheroidizing annealing, carbides are finely distributed and excellent in fine blanking, but the hardness is too high, resulting in a shorter mold life. . When the coiling temperature of the invention condition is 600 ℃, ferrite and pearlite are finely distributed in the hot-rolled steel sheet, after spheroidizing annealing, the cementite is unevenly distributed, so that the hardness is low but the fine blanking property is not excellent. Therefore, it can be seen that the winding temperature range of the mold life aimed at the present invention and excellent fine blanking property is in the range of 550 ~ 630 ℃.

(실시예3)Example 3

다음은 표 1의 강종들을 이용하여 가열온도 1240℃에서 230분동안 가열한 후 통상의 열간압연조건인 850℃에서 두께 5.0㎜로 마무리 압연한 후 600℃에서 권취하였다. 권취된 열연판을 산세하고 비산화성 분위기에서 구상화소둔을 행하였다. 구상화소둔은 Ac1온도 이하인 710℃에서 10시간 행하였다. 구상화소둔강판을 이용하여 파인블랭킹 가공을 한 후 880℃에서 30분간 가열한 후 60℃ 온도의 기르멩 소입하였다. 구상화소둔 강판에 대해서는 경도 및 파인블랭킹성을 측정하였고, 소입강판에 대해서는 중심부의 경도를 측정하여 소입성을 평가하였다. 파인블랭킹성 평가 방법은 실시예 2에서 언급된 방법과 동일하다.Next, the steels of Table 1 were heated at a heating temperature of 1240 ° C. for 230 minutes, followed by finish rolling to a thickness of 5.0 mm at 850 ° C. under normal hot rolling conditions, and then wound at 600 ° C. The wound hot rolled sheet was pickled and spheroidized annealing was performed in a non-oxidizing atmosphere. Spherical annealing was performed at 710 degreeC which is A c1 temperature or less for 10 hours. The fine blanking process was performed using a spheroidized annealed steel sheet, followed by heating at 880 ° C. for 30 minutes, followed by ignition of 60 ° C. temperature. Hardness and fine blanking properties were measured for spherical annealed steel sheets, and hardenability of the hardened steel sheets was measured to evaluate hardenability. The fine blanking evaluation method is the same as the method mentioned in Example 2.

상기와 같이 측정된 결과를 각 합금원소의 특성을 알아보기 편리하도록 구분하여 표 4, 표 7에 나타내었다. 이때, 본발명에서 목표로하는 자동차 부품 및 기계부품의 구상화소둔후의 경도는 Hv 160이하이며, 파인블랭킹성은 전단면이 90%이상으로 우수해야하고, 소입후 400℃에서 1시간 템퍼링을 했을 때 경도가 Hv 300 이상이 되는 것이다. 이를 위해서는 중심부의 소입경도가 Hv 500 이상이 되어야 한다.The results measured as described above are shown in Table 4 and Table 7 to distinguish the characteristics of each alloy element for convenience. At this time, the hardness after spheroidizing annealing of automotive parts and mechanical parts targeted by the present invention is Hv 160 or less, and the fine blanking property should be excellent in shear surface of 90% or more, and when tempered at 400 ℃ for 1 hour after hardening Becomes Hv 300 or more. For this purpose, the hardening hardness of the core must be Hv 500 or more.

표 4는 탄소의 영향을 살펴본 것이다. 표 4에 나타난 바와 같이 탄소량이 0.1%일때는 파인블랭킹성은 양호하지만 소입경도가 목표로 하는 값보다 너무 낮고, 탄소량이 0.45%에서는 소입경도는 만족하지만 구상화소둔판 상태에서늬 경도가 너무 높아 파인 블랭킹성이 우수하지 못함을 알 수 있다. 따라서 목표로 하는 파인블랭킹성과 경도를 동시에 얻기 위해서는 탄소 범위가 0.15-0.35%가 적정함을 알 수 있다.Table 4 looks at the impact of carbon. As shown in Table 4, when the carbon content is 0.1%, the fine blanking property is good, but the particle size is too low than the target value, and when the carbon content is 0.45%, the particle size is satisfied, but the hardness is too high in the spheroidized annealing state. It can be seen that the castle is not excellent. Therefore, it can be seen that the carbon range of 0.15-0.35% is appropriate for simultaneously obtaining the target fine blanking properties and hardness.

표 5는 Cr의 영향을 살펴본 것이다. 표 5에 나타난 바와 같이 Cr량이 0.7%에서는 구상화소둔후의 경도 상승은 크게 높지 않고 파인브랭킹성도 양호하지만 Cr 량이 1.5%에서는 Cr이 세멘타이트의 구상화를 억제하기 때문에 구상화소둔 경도가 매우 높게 되고 파인브랭킹성도 저하됨을 알 수 있다.Table 5 looks at the effect of Cr. As shown in Table 5, when the Cr content is 0.7%, the hardness increase after the spheroidal annealing is not very high and the fine blanking property is good. However, when the Cr amount is 1.5%, the Cr suppresses the spheroidization of the cementite, the hardness of the spheroidizing annealing is very high and the pin is increased. It can be seen that the ranking property is also reduced.

표 6에는 B량 및 Ti량의 영향을 살펴본 것이다. 표 6에 나타난 바와 같이 B와 Ti은 구상화소둔성이나 파인블랭킹성에는 큰 영향을 미치지 않으나 B가 첨가되지 않으면 소입경도가 상당히 저하되는데, 이것은 B이 미량첨가 되어도 소입성을 크게 향상시키기 때문이다. 그리고 B는 첨가되어 있으나 Ti가 첨가도지 않으면 B이 주로 BN으로 석출하여 소입성 향상에는 크게 기여하지 않음을 알 수 있다. 즉, Ti 첨가의 목적은 Ti가 B보다 질소(N)에 대한 친화력이 크기 때문에 강중에 N이 BN을 생성하기에 앞서 TiN을 형성하여 B이 용질상태로 존재하게 함으로써 소입성을 향상시킨다.Table 6 looks at the effects of the amount of B and Ti. As shown in Table 6, B and Ti do not have a significant effect on spheroidizing annealing or fine blanking properties, but when B is not added, the particle size decreases considerably, since B is greatly improved even when B is added in a small amount. And when B is added but not Ti, B is mainly precipitated as BN, and it can be seen that it does not contribute significantly to the improvement of quenchability. In other words, the purpose of Ti addition is that Ti has greater affinity for nitrogen (N) than B, so that before forming N in the steel, B forms TiN so that B exists in the solute state, thereby improving the hardenability.

표 7은 S량 및 Ca량의 영향을 살펴본 것이다. 표 7에 나타난 바와 같이 Ca가 첨가되지 않은 경우에는 S가 0.004%일 때는 파인블랭킹성이 양호하나 S가 0.01%에서는 파인블랭킹성이 저하된다. 이것은 S는 Mn과 결합하여 MnS 개재물을 형성하는데, MnS 개재물은 연성이 커서 열간압연도중 쉽게 길게 연신되기 때문이다. 한편 Ca 가 첨가되는 경우에는 S량이 다소 많아도 파인블랭킹성이 개선되나 S가 너무 많으면 Ca를 첨가해도 연신되는 유화물량이 많아 파인블랭킹성이 저하된다. 따라서 파인블랭킹성을 확보하기 위해서는 S를 0.005%이하로 낮추는 것이 필요하지만 S를 0.005% 이하로 낮추지 못할 경우에는 Ca를 첨가하여 개재물을 구상화시킴으로써 파인블랭킹성을 개선할 수 있다. 그러나 Ca를 첨가하는 경우에도 S가 너무 많으면 파인블랭킹성이 저하되기 때문에 Ca를 첨가한 강에서도 S를 0.01%이하로 하여야 한다.Table 7 looks at the effects of S amount and Ca amount. As shown in Table 7, when Ca is not added, fine blanking property is good when S is 0.004%, but fine blanking property is decreased when S is 0.01%. This is because S combines with Mn to form MnS inclusions, because MnS inclusions are ductile and elongate easily during hot rolling. On the other hand, when Ca is added, the fine blanking property is improved even if the amount of S is slightly higher. However, when S is too large, the amount of emulsion that is stretched even when Ca is added increases the fine blanking property. Therefore, in order to secure the fine blanking property, it is necessary to lower S to 0.005% or less, but when S cannot be lowered to 0.005% or less, the fine blanking property can be improved by spheroidizing inclusions with Ca. However, even when Ca is added, too much S deteriorates the fine blanking property, so S must be 0.01% or less even in Ca-added steel.

화학성분 (wt%)Chemical composition (wt%) 비고Remarks CC SiSi MnMn CrCr SS PP BB TiTi NN CaCa 발명강Invention steel 1One 0.20.2 0.30.3 1.01.0 0.20.2 0.0040.004 0.0150.015 0.0020.002 0.020.02 0.0050.005 -- 기본basic 22 0.30.3 0.280.28 0.950.95 0.210.21 0.0030.003 0.0140.014 0.0020.002 0.0180.018 0.0080.008 -- C효과C effect 33 0.20.2 0.250.25 0.950.95 0.70.7 0.0030.003 0.0180.018 0.0020.002 0.0190.019 0.0050.005 -- Cr효과Cr effect 44 0.20.2 0.270.27 1.21.2 0.20.2 0.0030.003 0.0130.013 0.0040.004 0.0150.015 0.0040.004 -- B효과B effect 55 0.20.2 0.30.3 1.01.0 0.220.22 0.0080.008 0.0140.014 0.0020.002 0.0180.018 0.0040.004 0.0040.004 Ca효과Ca effect 비교강Comparative steel 66 0.10.1 0.20.2 0.90.9 0.20.2 0.0030.003 0.0150.015 0.0020.002 0.0150.015 0.0040.004 -- C효과C effect 77 0.480.48 0.210.21 1.01.0 0.20.2 0.0040.004 0.0150.015 0.0020.002 0.0160.016 0.0050.005 -- 88 0.20.2 0.250.25 2.02.0 0.20.2 0.0040.004 0.0160.016 0.0020.002 0.0180.018 0.0040.004 -- Mn효과Mn effect 99 0.20.2 0.20.2 1.01.0 1.51.5 0.0040.004 0.0150.015 0.0020.002 0.0170.017 0.0040.004 -- Cr효과Cr effect 1010 0.20.2 0.230.23 1.01.0 0.20.2 0.010.01 0.0150.015 0.0020.002 0.0160.016 0.0040.004 -- S효과S effect 1111 0.20.2 0.20.2 1.01.0 0.20.2 0.0150.015 0.0150.015 0.0020.002 0.0180.018 0.0050.005 0.0040.004 Ca효과Ca effect 1212 0.20.2 0.250.25 1.01.0 0.20.2 0.0040.004 0.0150.015 0.0020.002 00 0.0050.005 -- Ti효과Ti effect 1313 0.20.2 0.230.23 1.01.0 0.20.2 0.0040.004 0.0150.015 00 0.020.02 0.0040.004 -- B효과B effect

강종 No.1의 재가열조건에 따른 열연강판에서의 탈탄층 깊이(연강판 두께 : 5.0㎜)Decarburization layer depth in hot rolled steel sheet according to reheating condition of steel grade No.1 (mild steel sheet thickness: 5.0㎜) 재가열 조건Reheating conditions 탈탄층 깊이(㎛)Decarburized Layer Depth (㎛) 비 고Remarks 조건 1Condition 1 1240℃ × 220분1240 ℃ × 220 minutes 4545 발명조건Invention Condition 조건 2Condition 2 1240℃ × 250분1240 ° C × 250 minutes 5151 비교조건Comparative condition 조건 3Condition 3 1240℃ × 280분1240 ° C × 280 minutes 5858 비교조건Comparative condition 목 표goal 5050 강판두께 1.0%1.0% of steel plate thickness

하기 표 3은 강종 No.1의 권취온도에 따른 열연강판의 조직 및 경도와Table 3 shows the structure and hardness of the hot rolled steel sheet according to the coiling temperature of steel grade No. 1

구상화 소둔강판의 경도 및 파인블랭킹성 (강판두께 5.0㎜)을 나타낸다.Hardness and fine blanking property (steel plate thickness 5.0mm) of a spheroidized annealed steel sheet are shown.

권취온도(℃)Winding temperature (℃) 열연판경도(Hv)Hot Rolled Sheet Hardness (Hv) 열연판미세조직Hot Rolled Sheet Microstructure 구상화소둔판경도(Hv)Spherical hardened plate hardness (Hv) 구상화소둔판파인블랭킹성Spherical annealed plate fine blanking 비고Remarks 500500 230230 베이나이트Bainite 170170 ◎(★)◎ (★) 비교조건Comparative condition 600600 200200 페라이트-퍼얼라이트Ferrite-Perlite 150150 발명조건Invention Condition 650650 175175 밴드상 조직Band structure 135135 비교조건Comparative condition

◎ : 전단면이 90%이상 ○ : 전단면이 90%이하◎: Shear surface 90% or more ○: Shear surface 90% or less

★ : 경도가 높아 금령수명이 단축됨★: High hardness, shortened life span

탄소량이 구상화소둔경도, 파인블랭킹성, 소입경도 및 템퍼링경도에 미치는 영향 (강판두께 : 5.0㎜)Effect of Carbon Content on Spherical Annealing Hardness, Fine Blanking, Hardening Hardness and Tempering Hardness (Steel Thickness: 5.0㎜) C량(wt%)C amount (wt%) 구상화소둔후경도 (Hv)Hardness after spheroidization (Hv) 파인블랭킹성Fine Blanking 소입경도(Hv)Hardness Hardness (Hv) 템퍼링경도(Hv)Tempering Hardness (Hv) 강종Steel grade 발명예1Inventive Example 1 0.20.2 150150 510510 340340 발명강1Inventive Steel 1 발명예2Inventive Example 2 0.30.3 156156 550550 370370 발명강2Inventive Steel 2 비교예6Comparative Example 6 0.10.1 140140 400400 250250 비교강6Comparative Steel 6 비교예7Comparative Example 7 0.450.45 170170 600600 400400 비교강7Comparative Steel 7

◎ : 파인블랭킹성 양호, ○ : 보통◎: Fine blanking property is good, ○: Normal

표 5는 크롬량이 구상화소둔경도, 파인블랭킹성, 소입경도 및 템퍼링경도에 미치는 영향 (강판두께 : 5.0 ㎜)을 나타내다.Table 5 shows the effect (chromium thickness: 5.0 mm) on the amount of chromium on spheroidizing annealing, fine blanking, quenching and tempering.

Cr량(wt%)Cr amount (wt%) 구상화소둔후경도(Hv)Hardness after spheroidization (Hv) 파인블랭킹성Fine Blanking 소입경도(Hv)Hardness Hardness (Hv) 템퍼링경도(Hv)Tempering Hardness (Hv) 강종Steel grade 발명예1Inventive Example 1 0.20.2 150150 510510 340340 발명강1Inventive Steel 1 발명예3Inventive Example 3 0.70.7 155155 530530 360360 발명강3Invention Steel 3 비교예9Comparative Example 9 1.51.5 170170 560560 390390 비교강9Comparative Steel 9

◎ : 파인블랭킹성 양호, ○ : 보통◎: Fine blanking property is good, ○: Normal

보론 및 티타늄량이 구상화소둔경도, 파인블랭킹성, 소입경도 및 템퍼링경도에 미치는 영향 (강판두께 : 5.0 ㎜)Effect of Boron and Titanium on Spherical Annealing Hardness, Fine Blanking, Hardening Hardness and Tempering Hardness (Steel Thickness: 5.0 ㎜) B량(wt%)B amount (wt%) Ti량(wt%)Ti amount (wt%) 구상화소둔후 경도(Hv)Hardness after spheroidization (Hv) 파인블랭킹성Fine Blanking 소입경도(Hv)Hardness Hardness (Hv) 템퍼링경도(Hv)Tempering Hardness (Hv) 강종Steel grade 발명예1Inventive Example 1 0.0040.004 -- 150150 510510 340340 발명강1Inventive Steel 1 비교예10Comparative Example 10 0.010.01 -- 152152 515515 350350 발명강4Inventive Steel 4 발명예5Inventive Example 5 0.0080.008 0.0040.004 153153 505505 210210 비교강13Comparative Steel 13 비교예11Comparative Example 11 0.0150.015 0.0040.004 155155 511511 240240 비교강12Comparative Steel 12

◎ : 파인블랭킹성 양호, ○ : 보통◎: Fine blanking property is good, ○: Normal

S 및 Ca량이 구상화소둔경도, 파인블랭킹성, 소입 경도 및 템퍼링경도에 템퍼링경도에 미치는 영향 (강판두께 : 5.0 ㎜)Effect of S and Ca content on tempering hardness on spheroidizing annealing, fine blanking, quenching hardness and tempering hardness (steel thickness: 5.0 ㎜) S량(wt%)S amount (wt%) Ca량(wt%)Ca amount (wt%) 구상화소둔후 경도(Hv)Hardness after spheroidization (Hv) 파인블랭킹성Fine Blanking 소입경도(Hv)Hardness Hardness (Hv) 템퍼링경도(Hv)Tempering Hardness (Hv) 강종Steel grade 발명예1Inventive Example 1 0.0040.004 -- 150150 510510 340340 발명강1Inventive Steel 1 비교예10Comparative Example 10 0.010.01 -- 152152 515515 342342 비교강10Comparative Steel 10 발명예5Inventive Example 5 0.0080.008 0.0040.004 153153 505505 345345 발명강5Inventive Steel 5 비교예11Comparative Example 11 0.00150.0015 0.0040.004 155155 511511 343343 비교강11Comparative Steel 11

◎ : 파인블랭킹성 양호, ○ : 보통◎: Fine blanking property is good, ○: Normal

상술한 바와 같이, 본 발명에 의하면 저탄소강과 고탄소강의 중간범위의 탄소함량을 갖게 하고 개재물 및 미세조직의 제어를 통해 저탄소강 수준의 우수한 파인블랭킹을 성을 가지게 하고, 또한 미량의 보론 첨가 및 합금원소를 첨가하여 고탄소강 수준의 소입열처리성을 동시에 확보함을써 기계부품 및 자동차 부품의 안전성을 얻을 수 있고, 중탄소강대의 수요증가 및 수요가의 다양한 요구에 대응할 수 있는 효과가 제공된다.As described above, according to the present invention, it has an intermediate carbon content between low carbon steel and high carbon steel, and has excellent fine blanking at low carbon steel level through control of inclusions and microstructures, and also adds trace boron and alloys. By adding the element to secure the hardening heat treatment of high carbon steel at the same time, it is possible to obtain the safety of mechanical parts and automobile parts, and to provide the effect of increasing the demand for medium carbon steel strip and coping with various demands of the demand.

Claims (4)

중량%로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.5-1.5%, Cr:0.1-1.0%, S:0.005%이하, P:0.02%이하, B:0.0005-0.005%, Ti/N : 2-7를 함유하고, 잔부 Fe 및 불가피한 불순물로 이루어지는 것을 특징으로 하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강.By weight%, C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.5-1.5%, Cr: 0.1-1.0%, S: 0.005% or less, P: 0.02% or less, B: 0.0005-0.005% , Ti / N: A medium-carbon steel with excellent heat treatment heat treatment and fine blanking workability, characterized in that it comprises 2-7, the balance Fe and unavoidable impurities. 제 1항의 조성으로 이루어진 강재를 먼저, 가열온도 1240℃이하에서 가열시간을 250분이하로 하여 열간압연한 후, 권취온도를 550℃∼630℃로 하여 열연강판을 제조하고, 제조된 열연강판을 Ac1변태온도 이하에서 구상화소둔을 실시하는 것을 특징으로하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강대의 제조방법.The steel material having the composition of claim 1 is first hot-rolled at a heating temperature of 1240 ° C. or less with a heating time of 250 minutes or less, and then a hot rolled steel sheet is prepared at a winding temperature of 550 ° C. to 630 ° C. A method for producing a medium carbon steel sheet having excellent heat treatment heat treatment and fine blanking workability, characterized by performing spheroidizing annealing at a transformation temperature below c1 . 중량%로, C:0.15-0.35%, Si:0.1-0.5%, Mn:0.4-1.5%, Cr:0.1-1.0%, S:0.010%이하, P:0.02%이하, B:0.0005-0.005%, Ti/N : 2-7, Ca:0.001-0.01%를 함유하고, 잔부 Fe 및 불가피한 불순물로 이루어지는 것을 특징으로 하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강.By weight%, C: 0.15-0.35%, Si: 0.1-0.5%, Mn: 0.4-1.5%, Cr: 0.1-1.0%, S: 0.010% or less, P: 0.02% or less, B: 0.0005-0.005% , Ti / N: 2-7, Ca: 0.001-0.01%, heavy carbon steel with excellent heat treatment heat treatment and fine blanking workability, characterized in that consisting of the remaining Fe and unavoidable impurities. 제 3 항의 조성으로 이루어진 강재를 먼저, 가열온도 1240℃이하에서 가열시간을 250분이하로 하여 열간압연한 후, 권취온도를 550℃∼630℃로 하여 열연강판을 제조하고, 제조된 열연강판을 Ac1변태온도 이하에서 구상화소둔을 실시하는 것을 특징으로하는 소입열처리성과 파인블랭킹 가공성이 우수한 중탄소강대의 제조방법.The steel material having the composition of claim 3 is first hot-rolled at a heating temperature of 1240 ° C. or less with a heating time of 250 minutes or less, and then a hot rolled steel sheet is prepared with a winding temperature of 550 ° C. to 630 ° C. A method for producing a medium carbon steel sheet having excellent heat treatment heat treatment and fine blanking workability, characterized by performing spheroidizing annealing at a transformation temperature below c1 .
KR10-1998-0060198A 1998-12-29 1998-12-29 Manufacturing method of medium carbon steel and medium carbon steel with excellent hardening heat treatment and fine blanking workability KR100376927B1 (en)

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