KR20000030261A - Photo titanium catalytic reactor treatment tank - Google Patents

Photo titanium catalytic reactor treatment tank Download PDF

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KR20000030261A
KR20000030261A KR1020000007423A KR20000007423A KR20000030261A KR 20000030261 A KR20000030261 A KR 20000030261A KR 1020000007423 A KR1020000007423 A KR 1020000007423A KR 20000007423 A KR20000007423 A KR 20000007423A KR 20000030261 A KR20000030261 A KR 20000030261A
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titanium
wastewater
photo
photoreactor
reaction tank
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KR1020000007423A
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Korean (ko)
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KR100343099B1 (en
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안석규
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안석규
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physical Water Treatments (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Catalysts (AREA)

Abstract

PURPOSE: A titanium photo reaction tank for waste water treatment is provided, which is characterized in that titanium tube and ultra violet rays are used for photo disintegrating waste water as a catalyst. CONSTITUTION: The method uses titanium oxide and ultra violet radiation. When electrode made of titanium dioxide semiconductor contacts with ultra violet rays or light, oxygen and hydrogen are generated. Properties of titanium dioxide are not changed by the reaction, and play a role of photo catalyst. Reaction tank using titanium device(4) which is made of titanium dioxide is installed with controlling device(3) of water level. Wastewater flows in the reaction tank through inlet(6), and outlet(5) for discharging sludge is provide. The capacity of the reaction tank can be adjusted according to property and quantity of waste water, and all the devices are operated using gear system automatically.

Description

폐수처리용 티타늄 광 반응조 {PHOTO TITANIUM CATALYTIC REACTOR TREATMENT TANK}Titanium photoreactor for wastewater treatment {PHOTO TITANIUM CATALYTIC REACTOR TREATMENT TANK}

본 발명은 심각하게 사회 문제화되고 있는 각종 오폐수 특히 쓰레기 침출수, 축산폐수, 분뇨, 공장폐수로 인하여 극심한 수질오염이 발생하여 범 국민적 환경운동으로 전개되는 바 본 발명인은 이를 해결하기 위하여 다년간 연구개발에 전념하여 폐수처리용 티타늄 광 반응기를 이용한 광 반응조를 개발하여 생활오수에서 고농도 폐수에 까지 저비용 고효율 효과로 처리할 수 있는 처리장치를 개발하여 환경문제 해소 및 수질보전으로 인류를 물 공해로부터 보호하기 위하여 본 발명을 하게 되었음.The present invention is developed as a nationwide environmental movement due to the severe water pollution caused by various wastewaters, especially leachate, livestock waste, manure, and factory wastewater, which are seriously social problems, and the present inventor is devoted to research and development for many years. Developed a photoreactor using titanium photoreactor for wastewater treatment and developed a treatment device that can treat wastewater to high concentration wastewater with low cost and high efficiency to solve environmental problems and protect humankind from water pollution by conserving water quality Invented.

본 발명은 폐수 처리 장치에 속한 것으로 폐수처리용 티타늄 광 반응기를 이용한 폐수처리용 티타늄 광 반응조로 각종 오폐수의 전처리 과정부터 완전 법정기준치 이하로 처리하며 특히 고농도 축산폐수의 경우 현재 전국에 시설 가동중인 처리장은 유입에서 방류까지 처리기간이 약15일 전후이나 본 발명한 반응조를 이용한 처리PROCESS를 채택하면 1시간30분내에 완전처리 되고 1조에 일일 5,000m³처리가 가능하며 또한 유입수 공급량과 그 처리량이 비례적으로 진행되도록 하여 처리된 수질이 매우 깨끗하게 여과 되어 지는 폐수처리장치에 관한 것이다. 일반적으로 발생하는 폐수는 생활오수, 축산폐수, 분뇨, 공업용폐수, 쓰레기 침출수 등으로 분류 할 수 있다.The present invention belongs to a wastewater treatment apparatus, which is a titanium photoreactor for wastewater treatment using a titanium photoreactor for wastewater treatment. The treatment period from inflow to discharge is about 15 days or when the treatment process using the reactor of the present invention is adopted, it can be completely processed within 1 hour and 30 minutes, and can handle 5,000 m³ per day in a tank. The present invention relates to a wastewater treatment apparatus in which the treated water quality is filtered very cleanly. Generally generated wastewater can be classified into domestic sewage, livestock wastewater, manure, industrial wastewater, and waste leachate.

상기와 같이 발생하는 폐수는 그 오염도가 매우 심각하여 범 국가적으로 해결하고자 하나 오염도가 매우 심각한 상태에 도달 그 심각도가 극도에 달하여 사회 문제화되어 있는 상태이며 특히 쓰레기 매립지 침출수, 공업용 폐수는 매우 심각한 실정이다.The wastewater generated as described above is very serious and is intended to be solved nationwide, but the pollution reaches a very serious condition, and the severity reaches an extremely serious social problem. Especially, landfill leachate and industrial wastewater are very serious. .

따라서 매립지 침출수, 공업용폐수 뿐만 아니라 축산폐수등은 자체적으로 여과 장치를 이용하여 처리하지만 투자비에 비하여 기준치에 미달하는 방류수가 종종 발생하고 있는 실정이다. 이는 각처리장에서 현재 실시하고 있는 처리장에는 생물학적방법, 화학적방법 자연정화법등을 보편적으로 적용하고 있으나 난분해성 물질을 처리함에는 부족함이 있을 뿐만 아니라 처리비용이 많이 투입됨에 비례하여 처리 효율이 저조한 상태이며 따라서 저렴한 운영비와 적은 공간에서 난분해성 물질을 처리하는 수 처리 공법이 절실히 요구되어 진다. 따라서 광 촉매를 이용한 폐수처리 문제를 해결하기 위하여 기술자와 과학자가 연구하여 실용화에 접근하려 하였으나 현실적인 수준에는 미흡한 상태였으나 본인은 이를 발전시켜 티타늄 광 반응기를 개발하고 이를 실용화 하는 폐수처리용 광 반응조를 발명하게 되었음.Therefore, landfill leachate, industrial wastewater, as well as livestock wastewater are treated by using a filtration device, but effluents often fall below the standard value compared to investment costs. The treatment plant currently implemented in each treatment plant generally applies biological methods, chemical methods, and natural purification methods, but it is not enough to treat hardly decomposable materials, and the treatment efficiency is low in proportion to the high processing cost. Therefore, there is an urgent need for a water treatment method for treating hardly decomposable materials in a low operating cost and a small space. Therefore, in order to solve the problem of wastewater treatment using photocatalyst, technicians and scientists tried to approach the practical use, but it was insufficient in practical level, but I developed the titanium photoreactor by developing it and invented the photoreactor for wastewater treatment that uses it. Was done.

따라서 본 발명은 이산화티타늄과 자외선을 이용한 것이며 광 촉매에 관한 것으로 이를 적용하여 물 등을 광분해 시키는 반응장치조이다. 이에 대해 광분해 반응에서는 이산화티타늄 반도체와 금속등을 전극으로 사용해 자외선 및 빛이 닿으면 산소와 수소가 발생한다. 이때 어느 정도 빛에서도 이산화티타늄은 변화하지 않고 광 촉매 역할을 하게 된다.Therefore, the present invention uses titanium dioxide and ultraviolet rays, and relates to a photocatalyst, which is a reaction apparatus tank for photolyzing water and the like by applying the same. On the other hand, in the photolysis reaction, when titanium dioxide semiconductor and metal are used as electrodes, oxygen and hydrogen are generated when ultraviolet rays and light reach. At this time, even in some light, titanium dioxide does not change and serves as a photocatalyst.

이산화티타늄(Tio2) 광 촉매 반응에서는 반응이 촉매 표면에서 일어나며 이산화티타늄 광 촉매는 산화 반응과 환원 반응이 광 촉매 표면에서 일어나지만 산화력이 매우 강하고 수 처리에 이용되는 염소나 오존의 산화력을 상화하며 극소수의 자외선 빛을 조사하여도 광 반응이 발생한다. 이를 수 처리에 이용함으로 수질 정화에 기여하게 되며, 광 촉매를 이용하여 수 처리를 하고자 할시 이산화티타늄분말을 탐지하는 방법이 하나의 주요 요점이 되어 왔으며 이 탐지된 이산화티타늄 회수에 기술적 문제가 되고 있으며 이 문제를 해결하기 위하여 탱크형광반응기(TANK TYPE PHOTO REACTOR), 이때는 광 수면의 최대 효과가 있으며, 또 관형반응기(PIPE TYPE PHOTO REACTOR)에 자외선의 투과율이 좋게 함으로 광 반응을 일으키게 하는 것과 활성탄(AC) 및 실리카켈 같은 흡착제에 이산화티타늄을 탐지시켜 고정 후 촉매반응을 일으키게 하는 장치 그 외 나선형 광반응기(SPIRAL TYPE PHOTO REACTOR) 이 밖에도 여러 가지 형태의 반응기가 고안되어 있으나 거의 실용화에는 못 미치며 실용화를 위해서는 반응효율과 가동비용 등 여러면에서 큰 규모가 필요하다. 이에 부응하여 다량의 고농도 현탁 폐수를 처리할 수 있는 폐수처리용 티타늄 광 반응조를 개발하게 되었다. 폐수를 광분해 할 수 있는 조(탱크)가 필요하게 되어 폐수를 뷴류하여 방류하고 스러지는 별도로 처리하는 폐수처리용 티타늄 광 반응조를 발명하게 되었음.In titanium dioxide (Tio2) photocatalytic reaction, the reaction takes place on the surface of the catalyst. Titanium dioxide photocatalyst has oxidation and reduction reactions on the surface of the photocatalyst, but the oxidation power is very strong and the oxidation power of chlorine or ozone used in water treatment is reduced. The light reaction occurs even when irradiated with ultraviolet light. It is used for water treatment, which contributes to the purification of water quality, and the method of detecting titanium dioxide powder when water treatment using photocatalyst has been one of the main points, and has become a technical problem in recovering the detected titanium dioxide. In order to solve this problem, TANK TYPE PHOTO REACTOR, in this case, has the maximum effect of light sleep, and it causes the light reaction to improve the transmittance of UV rays in the PIPE TYPE PHOTO REACTOR and activates the carbon. A device that detects titanium dioxide in an adsorbent such as silica gel and causes a catalytic reaction after fixation. In addition, a spiral type photoreactor (SPIRAL TYPE PHOTO REACTOR) has various types of reactors, but it is not practical for practical use. In many respects, such as reaction efficiency and running costs, they need to be large. In response, the company developed a titanium photoreactor for wastewater treatment capable of treating a large amount of high concentration suspended wastewater. A tank (tank) capable of photolyzing wastewater was needed, and the inventors invented a titanium photoreactor for wastewater treatment that separates and discharges wastewater and treats sewage separately.

도 1은 본 발명에 따른 폐수처리용 티타늄 광 반응조의 단면도1 is a cross-sectional view of the titanium photoreactor for wastewater treatment according to the present invention

도 2는 폐수처리용 티타늄 광 반응조의 외형을 나타낸 단면도Figure 2 is a cross-sectional view showing the appearance of the titanium photoreactor for wastewater treatment

도 3은 폐수처리용 티타늄 광 반응조의 폐수의 높이를 조절하는 수위조절기를 나타낸 것임.Figure 3 shows the water level regulator for adjusting the height of the wastewater of the titanium light reactor for wastewater treatment.

도 4는 폐수처리용 티타늄 광 반응조의 필수적 광 반응을 발생시키는 폐수처리용 티타늄 광 반응기를 타나낸 상세도임.4 is a detailed view showing a titanium light reactor for wastewater treatment generating an essential photoreaction of the wastewater treatment titanium light reactor.

도 5는 폐수처리용 티타늄 광 반응조의 부상 및 침전 스러지를 배출시키는 장치의 상세도임.Figure 5 is a detailed view of the device for discharging flotation and sedimentation of the titanium light reactor for wastewater treatment.

도 6는 폐수처리용 티타늄 광 반응조의 폐수 유입구를 나타낸 도임.6 is a view showing the wastewater inlet of the titanium light reactor for wastewater treatment.

도 7은 폐수처리용 티타늄 광 반응조의 처리수를 배출하는 배출구를 나타낸 것임.Figure 7 shows the outlet for discharging the treated water of the titanium light reactor for wastewater treatment.

다음 첨부 도면을 참고하여 본 발명을 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명의 폐수처리용 티타늄 광 반응조(도1)에 폐수를 저장하는 조 즉 폐수처리용 티타늄 광 반응조(도2) 중앙에 반응을 일으키게 하는 폐수처리용 티타늄 광 반응기(도4)를 취부하고 측면에 수위를 조절하는 수위조절기(도3)를 설치하며 폐수를 유입하기 위한 유입구(도6)를 설치하고 스러지를 배출하는 배출장치(도5)를 취부, 처리수를 배출하는 처리수 배출장치(도7)를 조합한 것으로 자동화 장치에 연결하여 연동으로 작동하게 하여 처리수를 얻은 장치.Mounting the wastewater treatment titanium photoreactor (FIG. 4) to cause the reaction in the center of the wastewater treatment titanium photoreactor (FIG. 1), namely the wastewater treatment titanium photoreactor (FIG. 2), and the side surface Install a water level regulator (Fig. 3) to adjust the water level in the installation of the inlet (Fig. 6) for inflow of wastewater, and equipped with a discharge device (Fig. 5) for discharging sludge, discharged treated water ( Fig. 7) is a device obtained by combining the automation device to operate in conjunction with the operation water obtained.

상기에서 서술한 바와 같이 본 발명에 따른 폐수처리용 광 반응조는 물을 광분해시켜 양질의 처리수를 만드는 조로서 처리할 폐수의 상태와 양에 따라 그 용량의 크기를 대,소로 제작하며 이때 모든 장치는 무인 운전이 용이 하도록 자동화 한다. 장점은 작은 부지에서 짧은 시간에 많은 폐수를 처리 할 수 있으며 하수처리장, 축산폐수처리장,쓰레기 침출수 처리장, 식음용수처리, 골프장폐수처리, 중수처리 등을 저렴한 운영비로 신속하게 양질의 처리수를 얻을 수 있음.As described above, the photoreactor for wastewater treatment according to the present invention is a tank for photodegrading water to produce high-quality treated water, and the size of the capacity is large and small according to the state and amount of wastewater to be treated. Automate to facilitate unmanned operation. The advantage is that it can treat a large amount of wastewater in a short time on a small site, and it is possible to obtain high-quality treated water quickly at low operating costs such as sewage treatment plant, livestock wastewater treatment plant, garbage leachate treatment plant, food and drinking water treatment, golf course wastewater treatment, and heavy water treatment. has exist.

Claims (1)

폐수처리용 티타늄 광 반응조(도1)는 폐수처리 용량에 적합한 조(도2)와 광 반응을 시키는 폐수처리용 티타늄 광 반응기를 취부(도4)와 폐수를 조내에 조절하는 수위조절기(도3)을 부착하고 폐수 유입구(도6)과 침전스러지 배출구(도5), 그리고 처리수 배출구(도7)를 조합하여 이루어진 폐수처리용 티타늄 광 반응조Titanium photoreactor for wastewater treatment (FIG. 1) is equipped with a tank (FIG. 2) suitable for wastewater treatment capacity and a water level regulator for controlling the wastewater treatment titanium photoreactor for photoreaction (FIG. 4) and wastewater in the tank (FIG. 3). Titanium photoreactor for wastewater treatment consisting of a combination of wastewater inlet (FIG. 6), sediment discharge outlet (FIG. 5), and treated water outlet (FIG. 7).
KR1020000007423A 2000-02-16 2000-02-16 Photo titannium catalytic reactor treatment tank KR100343099B1 (en)

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