KR100343099B1 - Photo titannium catalytic reactor treatment tank - Google Patents

Photo titannium catalytic reactor treatment tank Download PDF

Info

Publication number
KR100343099B1
KR100343099B1 KR1020000007423A KR20000007423A KR100343099B1 KR 100343099 B1 KR100343099 B1 KR 100343099B1 KR 1020000007423 A KR1020000007423 A KR 1020000007423A KR 20000007423 A KR20000007423 A KR 20000007423A KR 100343099 B1 KR100343099 B1 KR 100343099B1
Authority
KR
South Korea
Prior art keywords
wastewater
titanium
water
photoreactor
wastewater treatment
Prior art date
Application number
KR1020000007423A
Other languages
Korean (ko)
Other versions
KR20000030261A (en
Inventor
안석규
Original Assignee
안석규
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 안석규 filed Critical 안석규
Priority to KR1020000007423A priority Critical patent/KR100343099B1/en
Publication of KR20000030261A publication Critical patent/KR20000030261A/en
Application granted granted Critical
Publication of KR100343099B1 publication Critical patent/KR100343099B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Physical Water Treatments (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 폐수처리용 티타늄 광 반응조로서 수(폐수)을 처리하기 위하여 처리 용량에 따라 그 크기를 대·소로 제작하고 반응조내에 수(폐수)를 투입하며 이때 수위 조절기를 부착하여 일정 수위를 유지하게 하고 유입수와 방류수를 비례 조절함과 수(폐수)처리를 위하여 조내에 폐수처리용 티타늄 광 반응기를 답지 고정하여 광 반응을 일으켜 폐수에 조사함으로 폐수가 분해작용을 하여 부유물질이 물위로 부상하고 슬러지는 조 하층부로 침전되므로 처리수를 조 중앙에 위치하게 하는 장치로서 부상, 침전된 슬러지를 분리 배출함과 동시 처리수는 방류관을 통하여 이송케하는 폐수처리용 티타늄 광 반응조를 제공하고자 하는 것이다.The present invention is a titanium light reaction tank for wastewater treatment to produce a large and small size according to the treatment capacity in order to treat the water (wastewater) and to put the water (wastewater) into the reaction tank and to maintain a constant water level by attaching a water level regulator And to control the inflow and discharge water, and to fix and fix the titanium photoreactor for wastewater treatment in the tank for water (wastewater) treatment. Since the sediment is deposited into the lower part of the tank, it is a device for placing the treated water in the center of the tank, and it is intended to provide a titanium photoreactor for wastewater treatment that separates and discharges the floated and precipitated sludge and simultaneously transmits the treated water through the discharge pipe.

Description

폐수처리용 티타늄 광 반응조 { PHOTO TITANNIUM CATALYTIC REACTOR TREATMENT TANK }Titanium Photoreactor for Wastewater Treatment {PHOTO TITANNIUM CATALYTIC REACTOR TREATMENT TANK}

본 발명은 폐수처리 장치에 속한 것으로, 폐수처리용 티타늄 광 반응기를 이용한 폐수처리용 티타늄 광 반응조로 각종 오폐수의 전처리 과정부터 완전 법정기준치 이하로 처리하여 특히 고농도 축산폐수의 경우 현재 전국에 시설되어 가동 중인 처리장은 유입에서 방류까지 처리기간이 약 15일 전후이나 본 발명한 반응조를 이용한 처리공정(PROCESS)를 채택하면 1시간 30분내에 완전 처리되고 1조에 일일 5,000㎥ 처리가 가능하며 또한 유입수 공급량과 그 처리량이 비례적으로 진행되도록 하여 처리된 수질이 매우 깨끗하게 여과되어지는 폐수처리 장치에 관한 것이다.일반적으로, 발생하는 폐수는 생활오수, 축산폐수, 분뇨, 공업용폐수, 쓰레기 침출수 등으로 분류 할 수 있다.The present invention belongs to the wastewater treatment apparatus, which is a titanium photoreactor for wastewater treatment using a titanium photoreactor for wastewater treatment, which is currently installed and operated nationwide, especially in the case of high concentration livestock wastewater, from the pretreatment process of various wastewater to below the full legal standard value. The treatment plant is about 15 days from the inflow to the discharge, but if the process using the reactor of the present invention (PROCESS) is adopted, it can be completely processed within 1 hour and 30 minutes, and can handle 5,000㎥ per day in one tank. The present invention relates to a wastewater treatment device in which the treated water is filtered in a very clean manner so that the throughput proceeds proportionally. have.

상기와 같이 발생하는 폐수는 그 오염도가 매우 심각하여 범 국가적으로 해결하고자 하나 오염도가 매우 심각한 상태에 도달 그 심각도가 극도에 달하여 사회 문제화되어 있는 상태이며 특히, 쓰레기 매립지 침출수, 공업용 폐수는 매우 심각한 실정이다.The wastewater generated as described above is very serious and is intended to be solved nationwide, but the pollution level reaches a very serious condition, and the severity reaches an extremely severe social problem. Particularly, the landfill leachate and industrial wastewater are very serious. to be.

더욱이 심각하게 사회 문제화되고 있는 각종 오폐수 특히 쓰레기 침출수, 축산폐수, 분뇨, 공장폐수로 인하여 극심한 수질오염이 발생하여 범 국민적 환경운동으로 전개되는 현실임을 감안하여 볼 때 매립지 침출수, 공업용폐수 뿐만 아니라 축산폐수 등은 자체적으로 여과 장치를 이용하여 처리하지만 투자비에 비하여 기준치에 미달하는 방류수가 종종 발생하고 있는 실정이여서 환경문제 해소 및 수질 보전으로 인류를 물 공해로부터 보호하는 것이 시급한 과제가 되었다.이는 각 처리장에서 현재 실시하고 있는 처리장에는 생물학적 정화처리방법, 화학적 정화처리방법, 자연정화처리방법 등을 보편적으로 적용하고 있으나 난 분해성 물질을 처리함에는 부족함이 있을 뿐만 아니라 처리비용이 많이 투입됨에 비례하여 처리 효율이 저조한 상태이며 따라서 저렴한 운영비와 적은 공간에서 난 분해성 물질을 처리하는 수 처리 공법이 절실히 요구되어 진다.Moreover, in view of the fact that extreme water pollution occurs due to various wastewaters, particularly leachate, livestock waste, manure, and factory wastewater, which are becoming serious social problems, landfill leachate, industrial wastewater, as well as industrial wastewater Although the back is processed by its own filtration device, effluents often fall below the standard value compared to the investment cost, so it is urgent to protect mankind from water pollution by solving environmental problems and preserving water quality. Currently, biological treatment, chemical purification, and natural purification methods are commonly applied to the treatment plant, but there is not enough to treat difficult decomposable materials, and the treatment efficiency is proportional to the high processing cost. In poor condition Therefore, there is an urgent need for a water treatment method for treating difficult degradable materials in a low operating cost and a small space.

따라서, 본 발명인은 이를 해결하기 위하여 다년간 연구개발에 전념하여 폐수처리용 티타늄 광 반응기를 이용한 광 반응조를 개발하여 생활오수에서 고농도 폐수에까지 저비용 고효율 광 효과로 처리할 수 있는 티타늄 광 반응기를 개발하고 이를 실용화하는 폐수처리용 광 반응조를 창안하게 되었다.본 발명의 목적은 이산화 티타늄과 자외선을 이용한 것이며, 광 촉매에 관한 것으로, 이를 적용하여 오염수, 물 등을 광분해 시키는 반응장치조를 제공하는데 있다.광분해 반응에서는 이산화 티타늄 반도체와 금속 등을 전극으로 사용해 자외선 및 빛이 닿으면 산소와 수소가 발생한다. 이때 어느 정도 빛에서도 이산화 티타늄은 변화하지 않고 광 촉매 역할을 하게 된다.Accordingly, the present inventors have devised a photoreactor using a titanium photoreactor for wastewater treatment by devoting to research and development for many years to solve this problem, and developed a titanium photoreactor that can be treated with low cost and high efficiency light effect from domestic wastewater to high concentration wastewater. The present invention has been made of a photoreaction tank for wastewater treatment. The object of the present invention is to use titanium dioxide and ultraviolet rays, and to provide a photocatalyst, and to provide a reaction apparatus tank for photodegrading contaminated water, water and the like by applying the same. In the photolysis reaction, oxygen and hydrogen are generated when ultraviolet rays and light come into contact with titanium dioxide semiconductor and metal as electrodes. At this time, titanium dioxide does not change even in some light and serves as a photocatalyst.

이산화티타늄(Tio2) 광 촉매 반응에서는 반응이 촉매 표면에서 일어나며 이산화티타늄 광촉매는 산화반응과 환원반응이 광 촉매 표면에서 일어나지만 산화력이 매우 강하여도 광 반응이 발생한다.이를 수 처리에 이용함으로 수질 정화에 기여하게 되며, 광촉매를 이용해서 수처리를 할 경우 이산화티타늄분말을 탐지하는 방법이 하나의 주요 요점이 되어 왔으며 이 탐지된 이산화티타늄 회수에 기술적 문제가 되고 있으며 이 문제를 해결하기 위하여 탱크형 광 반응기(TANK TYPE PHOTO REACTOR), 이때는 광 수면의 최대 효과가 있으며, 또 관형반응기(PIPE TYPE PHOTO REACTOR)에 자외선의 투과율이 좋게 함으로 광 반응을 일으키게 하는 것과 활성탄(AC)및 실리카겔 같은 흡착제에 이산화 티타늄을 탐지시켜 고정 후 촉매 반응을 하는 장치 그 외 나선형 광 반응기(SPIRAL TYPE PHOTO REACTOR) 이 밖에도 여러 가지 형태의 반응기가 고안되어 있으나 거의 실용화에는 못 미치며 실용화를 위해서는 반응효율과 가동비용 등 여러 면에서 큰 규모가 필요하다.이에 부응하여 다량의 고농도 현탁 폐수를 처리 할 수 있는 폐수처리용 티타늄 광 반응조를 개발하게 되었다. 폐수를 광분해 할 수 있는 조(탱크)가 필요하게 되어 폐수를 뷴류하여 방류하고 슬러지는 별도로 처리하는 폐수처리용 티타늄 광 반응 조를 창안하게 되었다.In the titanium dioxide photocatalytic reaction, the reaction takes place on the surface of the catalyst, and the titanium dioxide photocatalyst occurs in the photocatalytic oxidation and reduction reactions, but the photoreaction occurs even when the oxidation power is very strong. In the case of water treatment using a photocatalyst, a method of detecting titanium dioxide powder has been one of the main points, and it is a technical problem in recovering the detected titanium dioxide. (TANK TYPE PHOTO REACTOR) In this case, it has the maximum effect of light sleep, and it makes the photoreaction by making UV transmittance good in the PIPE TYPE PHOTO REACTOR and titanium dioxide in adsorbents such as activated carbon (AC) and silica gel. SPIRAL TYP In addition, various types of reactors have been devised, but they are far less practical and require large scale in terms of reaction efficiency and operating costs. Developed a titanium photoreactor for wastewater treatment. A tank (tank) capable of photolyzing the wastewater was needed to create a titanium photoreaction tank for wastewater treatment where the wastewater was discharged and discharged and the sludge was treated separately.

도 1은 본 발명에 따른 폐수처리용 티타늄 광 반응조를 개략적으로 도시한 단면도,1 is a cross-sectional view schematically showing a titanium photoreactor for wastewater treatment according to the present invention;

도 2는 본 발명에 따른 폐수처리용 티타늄 광 반응조의 외형을 나타낸 측면도,Figure 2 is a side view showing the appearance of the titanium photoreactor for wastewater treatment according to the present invention,

도 3은 본 발명에 따른 폐수처리용 티타늄 광 반응조의 폐수의 높이를 조절하는 수위조절기를 예시한 단면도,Figure 3 is a cross-sectional view illustrating a water level regulator for adjusting the height of the wastewater of the titanium photoreactor for wastewater treatment according to the present invention,

도 4는 본 발명에 따른 티타늄 광 반응조의 폐수처리용 반응기를 나타낸 단면도,4 is a cross-sectional view showing a reactor for wastewater treatment of a titanium photoreactor according to the present invention;

도 5는 본 발명에 따른 폐수처리용 티타늄 광 반응조의 부상 및 침전 슬러지를 배출장치의 단면도,5 is a cross-sectional view of the discharge device of the flotation and sedimentation sludge of the titanium photoreactor for wastewater treatment according to the present invention,

도 6은 본 발명에 따른 폐수처리용 티타늄 광 반응조의 폐수 유입구를 나타낸 단면도,6 is a cross-sectional view showing the wastewater inlet of the titanium light reactor for wastewater treatment according to the present invention;

도 7은 본 발명에 따른 폐수처리용 티타늄 광 반응조의 처리수를 배출하는 배출구를 나타낸 단면도이다.<도면의 주요부분에 대한 부호의 설명>① : 전선 ② : 폐수처리용 티타늄 광 반응기③ : 정화수 배출구 및 밸브 ④ : SS배출구 및 밸브⑤ : 폐수주입구 및 밸브 ⑥ : 부상SS배출구 및 밸브⑦ : 수위조절기Figure 7 is a cross-sectional view showing the discharge port for discharging the treated water of the wastewater treatment titanium light reaction tank according to the present invention. <Description of the reference numerals in the drawings> ①: Wire ②: Titanium photoreactor for wastewater treatment ③: Purified water Outlet and valve ④: SS outlet and valve ⑤: Waste water inlet and valve ⑥: Floating SS outlet and valve ⑦: Level controller

다음 첨부 도면을 참고하여 본 발명을 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명의 폐수처리용 티타늄 광 반응조(도1)에 폐수를 저장하여 폐수를 처리하는 조(도2) 중앙에 설치하고 광 반응을 발생시켜 각종 유기물질을 산화시키는 티타늄 광 반응기(②)을 취부하고 원수 유입을 조절하는 수위조절기(⑦)를 설치하여 유입구(도6)를 개폐하여 하여 수위조절을 할 수 있게 하였으며 처리수를 배출하는 배출장치(도7)를 조합한 것으로 운전은 전자동화로 연동으로 작동하게 하여 양질의 처리수를 얻는 폐수처리용 티타늄 광 반응조인 것이다.상기의 광반응공정에서 주요 역할을 하는 티타늄 광 반응기(②)의 구조와 작용을 설명하고자 한다.석영관 외부 표면에 이산화티타늄(Tio2)를 도포하고 석영관 내부에서 자외선을 조사함으로 수산화 라디칼(-OH Radical)로 변화되게 하여 난분해성 유기물질의 특성을 제거하고 색도도 제거하게 된다. 이때 접촉한 각종 유기물질은 산화되면서 탄산가스와 물로 분해시킨다.티타늄관(Ti)은 티타늄관 내부에 보빙관내에 칸탈선을 삽입하고 칸탈선에 전류를 흐르게 하면 칸탈선에서 열과 빛이 발생하면서 이 열과 빛이 외부 티타늄관으로 전도되면서 티타늄관이 열을 발생하고 이때 티타늄관 외부에 유기물질이 접촉하게 되면 접촉된 각종유기물질은 산화되면서 탄산가스와 물로 분해시킨다. 이때 티타늄관에서 발생하는 열은 폐수의 수온을 높임으로 각종 유기물질의 산화작용을 배가시키는 작용도 하게 된다.상기 이산화티타늄을 석영관에 도포하고 석영관내에서 자외선을 방사하는 장치와 티타늄관내에 보빙관과 칸탈선을 조합한 장치를 조합하여 구성한 폐수처리용 티타늄 광 반응기(②), 상기와 같은 역할을 하는 광 반응기(②)를 조 중앙에 취부하고 광 반응으로 산화되는 시간을 책정하여 유입수 조절을 하기 위한 수위조절기(⑦)를 취부하고 처리수를 배출하는 배출구를 두어 원하는 배출수의 기준으로 처리수를 얻고자하는 폐수처리 장치인 것이다.본 폐수처리용 티타늄 광 반응조를 이용하여 각종 폐수를 적용 처리한 결과 효율이 탁월하였으며 다양한 조건에서도 효과가 탁월하였음이 판명되었다.Installed in the center of the tank (Fig. 2) for storing wastewater in the wastewater treatment titanium photoreaction tank (Fig. 1) of the present invention and mounting a titanium photoreactor (②) for oxidizing various organic substances by generating a photoreaction Water level controller (⑦) to control the inflow of raw water to open and close the inlet (Fig. 6) to control the water level, and the combination of the discharge device (Fig. 7) to discharge the treated water. It is a titanium photoreactor for wastewater treatment that works by interlocking to obtain high quality treated water. The structure and operation of the titanium photoreactor (②) that plays a major role in the photoreaction process will be described. By applying titanium dioxide (Tio2) and irradiating ultraviolet rays inside the quartz tube, it is changed into hydroxyl radical (-OH Radical), which removes the characteristics of the hardly decomposable organic substance and removes the chromaticity. . At this time, the organic substances contacted are oxidized and decomposed into carbon dioxide gas and water.Titanium tube (Ti) is inserted into the bobbin tube in the inside of the titanium tube, and when the current flows through the canal wire, heat and light are generated from the canal wire. As heat and light are conducted to the external titanium tube, the titanium tube generates heat. At this time, when organic substances come into contact with the outside of the titanium tube, various organic substances are oxidized and decomposed into carbon dioxide and water. At this time, the heat generated from the titanium tube increases the water temperature of the waste water, thereby doubling the oxidation of various organic substances. The titanium dioxide is coated on the quartz tube and the ultraviolet rays are radiated from the quartz tube and the boring is performed in the titanium tube. Titanium photoreactor for wastewater treatment (②) consisting of a combination of pipe and canal wires (②) and photoreactor (②) with the same role as above are installed in the center of the tank and the inflow water is adjusted by setting the time to oxidize by the photoreaction. It is a wastewater treatment device that installs a water level controller (⑦) for the purpose and has a discharge port for discharging the treated water to obtain the treated water based on the desired discharged water. The treatment resulted in excellent efficiency and excellent effect under various conditions.

이상에서 설명한 바와 같이 본 발명에 따른 폐수처리용 광 반응조는 물을 광분해시켜 양질의 처리수를 만드는 조로서 처리할 폐수의 상태와 양에 따라 그 용량의 크기를 대·소로 제작하며 이때 모든 장치는 무인 운전이 용이하도록 자동화한다. 장점은 작은 부지에서 짧은 시간에 많은 폐수를 처리 할 수 있으며 하수처리장, 축산폐수처리장, 쓰레기 침출수 처리장, 식음용수처리, 골프폐수처리, 중수처리 등을 저렴한 운영비로 신속하게 양질의 처리수를 얻을 수 있다.As described above, the photoreactor for wastewater treatment according to the present invention is a tank for photodegrading water to produce high quality treated water, and the size of the capacity is large and small according to the state and amount of wastewater to be treated. Automate to facilitate unattended operation. The advantage is that it can treat a large amount of wastewater in a short time on a small site, and it is possible to get high-quality treated water quickly at low operating costs such as sewage treatment plant, livestock wastewater treatment plant, waste leachate treatment plant, food and drinking water treatment, golf wastewater treatment and heavy water treatment. have.

Claims (1)

폐수처리용 티타늄 광반응조에 있어서,In the titanium photoreactor for wastewater treatment, 폐수처리 용량에 따라 적절한 크기로 조절할 수 있는 광촉매 반응조(도2)내에 광 반응을 수행시키는 폐수처리용 티타늄 광 반응기(②)가 취부(도4)되고 폐수를 반응조 내에서 원하는 수위로 조절하는 수위조절기(⑦)을 부착하고 폐수 유입구(도6)와 침전슬러지 배출구(도5), 그리고 처리수 배출구(도7)를 조합하여 광반응을 수행하도록 이루어진 폐수처리용 티타늄 광 반응조.Titanium photoreactor for wastewater treatment (②), which performs photoreaction in a photocatalytic reactor (Fig. 2), which can be adjusted to an appropriate size according to the wastewater treatment capacity, is mounted (Fig. 4), and the level for controlling wastewater to the desired level in the reactor. Titanium photoreactor for wastewater treatment to attach a regulator (⑦) and to perform a photoreaction by combining the wastewater inlet (Fig. 6), sediment sludge outlet (Fig. 5), and the treated water outlet (Fig. 7).
KR1020000007423A 2000-02-16 2000-02-16 Photo titannium catalytic reactor treatment tank KR100343099B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020000007423A KR100343099B1 (en) 2000-02-16 2000-02-16 Photo titannium catalytic reactor treatment tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020000007423A KR100343099B1 (en) 2000-02-16 2000-02-16 Photo titannium catalytic reactor treatment tank

Publications (2)

Publication Number Publication Date
KR20000030261A KR20000030261A (en) 2000-06-05
KR100343099B1 true KR100343099B1 (en) 2002-07-05

Family

ID=19647137

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020000007423A KR100343099B1 (en) 2000-02-16 2000-02-16 Photo titannium catalytic reactor treatment tank

Country Status (1)

Country Link
KR (1) KR100343099B1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10244257A (en) * 1997-03-04 1998-09-14 Toshiba Lighting & Technol Corp Hot water sterilization device and constant circulation type bus unit device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10244257A (en) * 1997-03-04 1998-09-14 Toshiba Lighting & Technol Corp Hot water sterilization device and constant circulation type bus unit device

Also Published As

Publication number Publication date
KR20000030261A (en) 2000-06-05

Similar Documents

Publication Publication Date Title
CN101786756B (en) Process method for treating hardly-biodegradable organic wastewater
CN201770511U (en) Rotary disk photolytic reactor
Kang et al. Photocatalytic ozonation of organic pollutants in wastewater using a flowing through reactor
Oloibiri et al. Removal of organic matter and ammonium from landfill leachate through different scenarios: Operational cost evaluation in a full-scale case study of a Flemish landfill
CN104843917A (en) Device and method for purifying slightly-polluted waste water
CN102963956A (en) Method for processing high-concentration non-degradable organic wastewater in combination with titanium dioxide and ultraviolet radiation
KR101459376B1 (en) Water treatment apparatus having control system and water treatment process using thereof
CN104803444B (en) Advanced oxidation pollution control technology and device
Jiad et al. Petroleum refinery wastewater treatment using a novel combined electro-Fenton and photocatalytic process
CN204265477U (en) A kind of photochemical catalysis water treating equipment of light guide media supported catalyst
CN116589073A (en) In situ simultaneous production of O 3 And H 2 O 2 Advanced oxidation reactor and process
KR100343099B1 (en) Photo titannium catalytic reactor treatment tank
KR100454260B1 (en) Advanced water and wastewater treatment apparatus and method
CN1502562A (en) Continuous intelligent controlled photocatalytic water quality deep purifier
KR20010008265A (en) Energy saving photocatalysis water treatment system using solar light/UV/photocatalyst
CN211813791U (en) Organic waste water photocatalysis processing apparatus
CN213231883U (en) Device for treating wastewater based on physical adsorption coupling photo-Fenton oxidation technology
CN108751601A (en) A kind of agricultural breeding sewage-treatment plant and its processing method
CN212740858U (en) Ozone catalytic oxidation sewage advanced treatment system
KR100343100B1 (en) Photo titannium catalytic reactor treatment
CN110921890A (en) Organic waste water photocatalysis processing apparatus
EP2535315A1 (en) Method and arrangement for a water treatment
CN107487808A (en) A kind of photo-catalyst device
CN209292133U (en) A kind of combination unit for Wastewater from Organic Chemistry Laboratory processing
CN112591846A (en) MPUV advanced oxidation system for treating high-concentration and difficultly-degraded organic wastewater

Legal Events

Date Code Title Description
A201 Request for examination
G15R Request for early opening
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee