KR20000017699A - A compisite by insulated paint a formation of paint substance for thermal insulation - Google Patents

A compisite by insulated paint a formation of paint substance for thermal insulation Download PDF

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KR20000017699A
KR20000017699A KR1019990024530A KR19990024530A KR20000017699A KR 20000017699 A KR20000017699 A KR 20000017699A KR 1019990024530 A KR1019990024530 A KR 1019990024530A KR 19990024530 A KR19990024530 A KR 19990024530A KR 20000017699 A KR20000017699 A KR 20000017699A
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weight
paint
voids
heat
emulsion
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KR100324305B1 (en
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정인수
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정인수
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    • H—ELECTRICITY
    • H04—ELECTRIC COMMUNICATION TECHNIQUE
    • H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N23/00—Cameras or camera modules comprising electronic image sensors; Control thereof
    • H04N23/50—Constructional details
    • H04N23/51—Housings
    • H—ELECTRICITY
    • H04—ELECTRIC COMMUNICATION TECHNIQUE
    • H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N23/00—Cameras or camera modules comprising electronic image sensors; Control thereof
    • H04N23/50—Constructional details
    • H04N23/55—Optical parts specially adapted for electronic image sensors; Mounting thereof
    • H—ELECTRICITY
    • H04—ELECTRIC COMMUNICATION TECHNIQUE
    • H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N23/00—Cameras or camera modules comprising electronic image sensors; Control thereof
    • H04N23/60—Control of cameras or camera modules
    • H—ELECTRICITY
    • H04—ELECTRIC COMMUNICATION TECHNIQUE
    • H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N7/00—Television systems
    • H04N7/18—Closed-circuit television [CCTV] systems, i.e. systems in which the video signal is not broadcast

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  • Engineering & Computer Science (AREA)
  • Multimedia (AREA)
  • Signal Processing (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

PURPOSE: A water soluble paint composition able to insulate heat consists of, as chief ingredients, emulsion resins of styrene-acryl copolymer which contains void therein to make heat-conductivity low and which has the excellent weatherproof and waterproof; an inorganic silicate compounds of hollowed form; the mica excellent in heat insulation, chemical resistance, and a rust proof. CONSTITUTION: A paint composition contains 5-40 wt.% of solid emulsion having voids therein during drying; 5-20 wt.% of inorganic silicates of a hollowed form having voids therein to be less heat-conductive; and 10-30 wt.% of mica which has good heat-insulation property.

Description

단열 도료 조성물{A compisite by insulated paint a formation of paint substance for thermal insulation}Insulation paint composition {A compisite by insulated paint a formation of paint substance for thermal insulation}

본 발명은 스티렌과 아크릴계 단량체를 공중합하여 유화시킨 에멀젼과 평균입경이 0.4∼0.5㎛의 미세입자로서 이 미세 입자 내부가 액상에서는 물로 채워져 있으나 건조되면서 물이 증발후 열전도도가 낮은 공기로 채워지는 특수에멀젼 수지를 병용하여 바인더로 사용하고 충진제로서는 고온에서 열처리한 초경량, 불활성의 무기질 미립중공체로서 열전도도가 아주 낮은 것과 판상의 입자 형상으로 인해 차단효과및 평활성의 효과를 주는 운모를 충진제로 사용한 단열 도료 조성물에 관한 것이다. 종래에는 포리스티렌 foam, 포리우레탄 foam, 유리섬유등의 재질을 단열재로 사용하여 왔는데 이것들은 시공시에 단열을 시키고자 하는 부위에 부착시키기 위한 frame이 필요할 뿐 아니라 두께도 두꺼워서 내외부 공간이 줄어드는 문제점과 단열시키고자 하는 부위의 형태가 복잡할 경우에는 시공하기가 어려운 단점도 있었다.The present invention is an emulsion in which styrene and an acrylic monomer are copolymerized to emulsify and fine particles having an average particle diameter of 0.4 to 0.5 μm. The inside of the fine particles is filled with water in a liquid phase, but dried and filled with air having low thermal conductivity after evaporation. Insulating emulsion resin is used as a binder, and as a filler, ultra-light, inert inorganic fine hollow body which is heat treated at high temperature, has a low thermal conductivity and mica which has blocking effect and smoothing effect due to plate-like particle shape. It relates to a coating composition. Conventionally, materials such as polystyrene foam, polyurethane foam, glass fiber, etc. have been used as insulation materials. These require not only a frame for attaching to the site to be insulated during construction, but also a thick thickness, which reduces the internal and external space. When the shape of the part to be insulated is complicated, there was a disadvantage that it is difficult to construct.

또한 종래의 단열도료는 내수성과 내알카리성이 약한 비닐 아세테이트계 에멀젼을 바인더로 하고 여러가지의 실리케이트 조성물을 혼합하여 제조한 단열도료가 일부사용되고 있었는데 폴리비닐아세테이트는 근본적으로 내알카리성이 약하기 때문에 콘크리트 조성물이 강알카리이면서 내부에 수분을 함유하고 있다는 점에 있어서 문제점이 있고 또 내부에 공기를 함유하고 있지 않은 실리케이트 조성물은 단열효과가 떨어지기 때문에 시공비가 많이 소요된다는 단점이 있을 뿐아니라 건조시에 균열이 생기는 단점도 있었다.In addition, the conventional heat insulating paint was used as a binder of a vinyl acetate emulsion having a weak water resistance and alkali resistance as a binder and a mixture of various silicate compositions were used. The problem is that the silicate composition which is alkaline and contains moisture and does not contain air has the disadvantage that it takes a lot of construction cost because of poor thermal insulation effect and cracks during drying. There was also.

본 발명은 상기와 같은 문제점을 해결하기 위해 사용한 수계 수지는 내수성과 내알카리성이 우수한 스티렌을 아크릴계 단량체와 공중합시킨 고분자량의 에멀젼수지 이면서 내부에 물을 함유하고 있어서 건조시에 물이 증발됨과 동시에 내부에 Void가 생겨 우수한 단열효과를 나타내는 특수에멀젼 수지를 바인더로 사용하였고 충진제로서는 무기질 실리케이트를 고온(약 1000℃)에서 특수 열처리하여 내부에 공기를 함유시켜서 만든 초경량, 불활성이면서 열전도도가 낮은 무기질을 사용하였고 또한 그 형상의 특성으로 인해 우수한 단열효과뿐만 아니라 치수안정성이 우수하며 균열방지 효과도 큰 운모를 사용하여 단열도료조성물을 제조하였다.According to the present invention, the aqueous resin used to solve the above problems is a high molecular weight emulsion resin obtained by copolymerizing styrene having excellent water resistance and alkali resistance with an acrylic monomer and containing water therein. As a binder, a special emulsion resin showing excellent heat insulation effect was formed as a binder. As a filler, an ultralight, inert, low thermal conductivity inorganic material made by specially heat-treating inorganic silicate at high temperature (about 1000 ° C) was used. In addition, due to the characteristics of the shape, as well as excellent thermal insulation effect, dimensional stability is excellent and the insulation coating composition was prepared using mica having a large crack prevention effect.

본 발명도료조성물의 에멀젼 수지는 스티렌을 아크릴계 단량체와 유화중합에 의한 공중합시에 고형분으로 10∼35중량％가 바람직하며 그 이상 첨가시는 내수성 내알카리성은 증가하지만 내후성측면에서 자외선에 의해 황변의 정도가 커지게 되고 Tg가 증가하며 도막형성 온도도 높아진다. 또, 건조후에 도막이 지나치게 취성을 가져 균열의 발생 가능성이 높고 각종 소재에 대한 부착성도 감소하게 된다. 아크릴 단량체는 부틸 아크리레이트, 2-에칠 헥실 아크리레이트, 에틸 아크리레이트 등과 같이 Tg가 낮고 유연한 단량체를 사용한 에멀젼 수지를 이용했으며 수지 고형분은 45∼55중량％가 적당하며 도료에 대한 수지 첨가량은 30∼45중량％가 적당하다. 백색 안료로서는 Rutile type의 TiO2를 사용하였는데 첨가량은 2∼5중량％이면 500㎛∼1200㎛의 건조도막두께에 충분한 은폐력을 나타낸다.The emulsion resin of the paint composition of the present invention is preferably 10 to 35% by weight as a solid content when copolymerizing styrene with an acrylic monomer, and the water resistance alkali resistance increases when added more, but the degree of yellowing due to ultraviolet rays in terms of weather resistance Increases, Tg increases, and the film forming temperature also increases. In addition, after drying, the coating film becomes excessively brittle, so that cracking is likely to occur, and adhesion to various materials is also reduced. The acrylic monomer used was an emulsion resin using a low Tg and flexible monomer such as butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, etc., and a suitable resin solid content of 45 to 55% by weight, and the amount of resin added to the paint 30-45 weight% of silver is suitable. As a white pigment, Rutile type TiO 2 was used, but when the addition amount is 2 to 5% by weight, a hiding power sufficient for a dry coating thickness of 500 µm to 1200 µm is obtained.

평활성와 소포제는 에틸렌 옥사이드 또는 프로필렌 옥사이드를 변성시킨 디메틸 폴리실록산을 주성분으로 되어 있으며 첨가량은 각각 0.1∼0.5중량％가 바람직하다. 첨가량이 과잉일 경우 표면장력에 의한 도막결함이 발생하거나 기포가 안정화되어 소포가 되지 않은 경우가 발생할 수도 있다.The smoothing agent and the antifoaming agent consist mainly of dimethyl polysiloxane obtained by modifying ethylene oxide or propylene oxide, and the amount of addition is preferably 0.1 to 0.5% by weight. If the added amount is excessive, coating defects may occur due to surface tension, or bubbles may not be formed due to stabilization of bubbles.

분산제는 노닐페놀에톡시레이트를 주성분으로 하는 비이온성 분산제를 사용했으며 그 첨가량은 0.2∼0.7중량％가 적당하다. 충진제의 침강 방지를 위해 사용한 증점제는 친수성과 소수성기를 동시에 가지고 있는 회합성 우레탄 증점제를 사용하였으며 첨가량은 1∼2중량％이다. 그 이상 첨가시는 도료가 지나치게 증점하여 paste상으로 되어 사용하기가 불편하다.The dispersing agent used the nonionic dispersing agent whose main component is nonyl phenol ethoxylate, The addition amount is suitable 0.2-0.7 weight%. The thickener used to prevent the sedimentation of the filler was an associative urethane thickener having both hydrophilic and hydrophobic groups. If it is added more, the paint thickens excessively and becomes a paste, which is inconvenient to use.

열전도도에 결정적인 역할을 하는 충진제로서는 중공체인 무기질실리케이트와 운모를 사용하였는데 무기질 실리케이트는 고온(약 1000℃)에서 특수열처리하여 내부에 void를 형성시켜 초경량화한것을 사용하였으며 이것은 건조시에 도막표면에 단열층을 형성시키는 장점이 있다.As a filler that plays a decisive role in thermal conductivity, inorganic silicate and mica, which are hollow bodies, were used.Inorganic silicate was used by special heat treatment at high temperature (about 1000 ℃) to form voids inside to make it ultra-light. There is an advantage of forming a heat insulating layer.

그 첨가량은 5∼15중량％이 적당하다. 과잉으로 첨가시에는 미세분말 입자의 겉보기 비중이 낮고 표면적이 커서 흡유량이 높기 때문에 도료의 점도가 지나치게 상승하여 도료를 사용하기가 여려운 단점이 생긴다. 또 소량 첨가시에는 단열효과가 급격히 감소하는 문제점이 있다.5-15 weight% is suitable for the addition amount. When added excessively, since the apparent specific gravity of the fine powder particles is low and the surface area is large, oil absorption is high, the viscosity of the paint is excessively increased, which makes it difficult to use the paint. In addition, when a small amount is added, there is a problem that the thermal insulation effect is sharply reduced.

운모의 경우 형상이 판상으로 도막내에 충진되게 되므로 열의 차단 효과와 치수 안정성이 뛰어나며 도장작업시에 평활성을 증진시켜 건조후에 미려한 외관을 부여하게 된다. 그 첨가량은 25∼35중량％를 사용하였다. 그외에 도료의 용기내에서의 저장안정성을 위해 PH조절용으로 3급아민을 0.1∼0.5중량％ 사용하였고 단열도료의 도막형성온도를 낮추기 위해 조용제를 1∼5중량％ 동결방지제로서 에칠렌그리콜을 1∼2중량％, 방부제를 0.1∼0.3중량％ 점도조절용으로 물을 8∼15중량％ 사용하였다.In the case of mica, the shape of the mica is filled in the coating film, so the heat blocking effect and dimensional stability are excellent, and smoothness is applied during the painting work to give a beautiful appearance after drying. The addition amount used 25-35 weight%. Besides, 0.1 ~ 0.5% by weight of tertiary amine was used for PH control for storage stability in the container of the paint, and 1 ~ 5% by weight of ethylene glycol was used as cryoprotectant to reduce the film formation temperature of the insulation paint. 8 to 15 weight% of water was used for the viscosity adjustment of -2 weight% and the preservative 0.1 to 0.3 weight%.

표1은 본 발명 도료의 일반적인 조성비를 나타내었다.Table 1 shows the general composition of the paint of the present invention.

원 료Raw material 조성비(단위 : 중량％)Composition ratio (unit: weight%) 에멀젼 수지Emulsion resin 30∼4530 to 45 백색안료White Pigment 3∼83 to 8 평활제Leveling agent 0.1∼0.50.1 to 0.5 소포제Antifoam 0.1∼0.50.1 to 0.5 분산제Dispersant 0.2∼0.70.2-0.7 증점제Thickener 1∼21 to 2 무기질실리케이트중공체Inorganic silicate hollow body 5∼155 to 15 운모mica 25∼3525 to 35 동결 방지제Cryoprotectants 1∼21 to 2 방부제antiseptic 0.1∼0.30.1-0.3 PH 조정제PH regulator 0.1∼0.50.1 to 0.5 조용제Solvent 1∼51 to 5 물water 8∼158 to 15 합 계Sum 100100

표2는 본 발명도료 조성물의 실시예1을 도시한 조성비를 나타내었다.Table 2 shows the composition ratio showing Example 1 of the coating composition of the present invention.

원 료Raw material 배합량(단위 : 중량％)Compounding amount (unit: weight%) 에멀젼 수지(1)Emulsion Resin (1) 3030 에멀젼 수지(2)Emulsion Resin (2) 1010 백색안료White Pigment 55 평활제Leveling agent 0.20.2 소포제Antifoam 0.20.2 분산제Dispersant 0.50.5 증점제Thickener 1.51.5 무기질실리케이트중공체Inorganic silicate hollow body 1313 운모mica 2121 동결 방지제Cryoprotectants 22 방부제antiseptic 0.10.1 PH 조정제PH regulator 0.20.2 조용제Solvent 22 물water 14.314.3 합 계Sum 100100

에멀젼 수지(1)은 Tg가 20℃ 도막형성온도가 30℃이고 고형분이 50중량％인 스티렌 아크릴 공중합체이고 에멀젼 수지(2)는 입자경이 0.4∼0.5㎛으로 고형분이 37∼38중량％이며 액상에서는 내부에 물로 채워져 있다가 건조 중에 물의 증발에 따라 내부에 void가 생기는 스티렌 아크릴 공중합체를 사용하였다.The emulsion resin (1) is a styrene acrylic copolymer having a Tg of 20 ° C., a film forming temperature of 30 ° C., and a solid content of 50% by weight. The emulsion resin (2) has a particle size of 0.4 to 0.5 μm, a solid content of 37 to 38% by weight, and a liquid phase. The styrene acryl copolymer was used in which the interior was filled with water and voids occurred as the water evaporated during drying.

백색안료는 Rutile type의 TiO2함량이 94％인 것을 사용하였으며 평활제와 소포제는 폴리에칠렌 옥사이드나 폴리프로필렌 옥사이드를 도입한 폴리디메칠 실록산을 주성분으로 하는 기존 상품을 이용하였다.The white pigment used was 94% of TiO 2 content of the rutile type, and the smoothing agent and the antifoaming agent used the existing product mainly composed of polydimethyl siloxane containing polyethylene oxide or polypropylene oxide.

분산제는 노닐페닐 에톡시레이트와 같은 비이온성 분산제를 사용하였으며 증점제는 회합성 우레탄 증점제를 사용하였다.The dispersant used a nonionic dispersant such as nonylphenyl ethoxylate and the thickener used an associative urethane thickener.

중공제인 무기질실리케이트는 평균입자가 40㎛ 비중이 0.32인것은 사용하였고, 운모는 평균입자가 42㎛ 비중이 2.72인것을 사용하였다.The inorganic silicate, which is a hollow agent, used 0.32 particles having an average particle size of 40 μm and mica used 2.72 particles having an average particle size of 42 μm.

동결 방지제는 에칠렌글리콜, PH 조정제는 3급아민류, 조용제는 부틸셀로솔브, 방부제는 기존 상품을 사용하였다.The cryoprotectant used ethylene glycol, the pH adjuster was tertiary amines, the crude solvent was butyl cellosolve, and the preservative was a conventional product.

실시예1의 조성비대로 도료를 제조했을시 도료점도가 stomer 점도계(Kreb unit)로 140KU 이상의 고점도여서 붓또는 로라 작업을 하기 위해서는 과량의 물로 희석이 필요하고 작업시에 붓 작업성이 나빠서 후도막을 올리기 위해서는 많은 회수의 공수가 필요한 단점이 발생하였다. 또한 물 희석량이 많으므로 수직도장작업시 흐름의 문제점이 발생되었다. 상기의 문제점을 개선하기 위하여 표3)과 같이 실시예2)의 조성비로 도료를 다시 제조하였다.When the paint is prepared according to the composition ratio of Example 1, the paint viscosity is high viscosity of 140 KU or more with a stomer viscosity unit, so dilution with excess water is required for brush or roller work, and the thick paint film is poor due to poor brush workability at the time of work. In order to raise the disadvantage that requires a large number of times of airlift. In addition, the amount of water dilution caused a problem of flow during the vertical coating work. In order to improve the above problems, the paint was prepared again at the composition ratio of Example 2) as shown in Table 3).

표3은 본 발명의 단열도료 실시예2의 조성비를 나타내었다.Table 3 shows the composition ratio of the heat insulating paint Example 2 of the present invention.

원 료Raw material 배 합 량(단위 : 중량％)Compounding amount (unit: weight%) 에멀젼 수지(1)Emulsion Resin (1) 3030 에멀젼 수지(2)Emulsion Resin (2) 1515 백색안료White Pigment 55 평활제Leveling agent 0.20.2 소포제Antifoam 0.20.2 분산제Dispersant 0.30.3 증점제Thickener 1.01.0 무기질실리케이트중공체Inorganic silicate hollow body 1010 운모mica 2222 동결 방지제Cryoprotectants 22 방부제antiseptic 0.40.4 조용제Solvent 22 물water 12.212.2 합 계Sum 100100

상기 단열도료 실시예1,2의 도막의 물성을 시험하기 위한 시험방법은 아래와 같다.The test method for testing the physical properties of the coating film of the insulating paint Examples 1 and 2 is as follows.

실온에서 붓으로 2∼3회에 걸쳐서 건조도막이 800∼1200㎛되게 한후 3일간 완전히 건조후에 시험하였다.After drying at 800 to 1200 占 퐉 over 2 to 3 times with a brush at room temperature, the test was performed after 3 days of complete drying.

도막광택은 독일BYK사의 광택기를 이용하여 입사각이 60°일때의 광택을 측정하였으며 내수성은 실온에서 수도물에 1주일간 침적 시킨뒤 도막의 외관에 부풀음이나 연화를 관찰하였다. 도막의 부착성은 KSM5981에 의해 몰타르, 철 등에 대한 부착성을 측정하였다.The gloss of the coating was measured by using a polisher of BYK in Germany at 60 ° angle of incidence. The water resistance was immersed in tap water at room temperature for 1 week, and then swelling and softening were observed on the appearance of the coating. The adhesion of the coating was measured by KSM5981 to mortar, iron and the like.

열전도도의 측정은 KSL9016에 의해 측정하였으며 시험한 결과를 표4)에 나타내었다.The thermal conductivity was measured by KSL9016 and the test results are shown in Table 4).

표4는 본 발명의 물성 시험 비교표를 나태내었다.Table 4 shows the comparison table of physical properties of the present invention.

시험항목 구분Test Item 실시 예1)Example 1 실시 예2)Example 2 도막두께Film thickness 800∼1,200㎛800 ~ 1,200㎛ 800∼1,200㎛800 ~ 1,200㎛ 건조시간(실온)Drying time (room temperature) 48시간48 hours 48시간48 hours 도막외관Coating appearance 불량Bad 양호Good 광택(60°)Glossy (60 °) 2％이하2% or less 3％이하3% or less 부착성Adhesion 몰타르Maltar 양호Good 양호Good 양호Good 양호Good 철iron 내수성Water resistance 양호Good 양호Good 열안정성(7일간)60℃ 8시간후 상온에서16시간 방치Thermal stability (7 days) left at room temperature for 16 hours after 8 hours at 60 ℃ 층분리Separation 양호Good 냉동안정성(7일간)-20℃ 8시간후 상온에서16시간 방치Frozen stability (7 days)-8 hours at -20 ℃ and left for 16 hours at room temperature Gel 상태Gel state 양호Good 열전도도(Kcal/m,h,℃)Thermal Conductivity (Kcal / m, h, ℃) 0.3500.350 0.1980.198

표4에 나타낸 시험 결과와 같이 본 발명도료는 외관이 미려하고 도막이 건조되면서 균열 발생이 없으며 내수성, 저장 안정성이 우수할뿐 아니라 도장작업성이 우수하고 특히 낮은 도막 두께로 열전도도가 낮아 단열효과가 뛰어나다.As shown in the test results shown in Table 4, the paint of the present invention is beautiful in appearance and has no cracks due to drying of the coating film, and has excellent water resistance and storage stability as well as excellent painting workability and low thermal conductivity due to low film thickness. outstanding.

이와 같이 본 발명 도료 조성물은 붓, 로라,스프레이등으로 건조도막이 800∼1200㎛ 정도로 도장하여 완전히 건조시킨뒤 그 위에 각종의 유색도료를 도장하면 미려한 색상의 외관을 나타낼수도 있다. 단지 내알카리성이 약한 도료를 본 도료 조성물에 도장하면은 건조, 부착등의 문제점을 유발시킬수도 있다.As described above, the paint composition of the present invention may exhibit a beautiful color appearance by coating a dry coating film with a brush, a roller, a spray, or the like at about 800 to 1200 μm and completely drying and then coating various colored paints thereon. Applying only a weak alkali resistant paint to the paint composition may cause problems such as drying and adhesion.

사용 용도로서는 건축물 창호부위, 일반 건축물 보수, 단열재및 보온재가 사용되는 철재및 기타 소재 등에 사용하면 경제성, 공간 활용 미려한 외관등의 면에서 우수한 성능을 발휘할 수 있다.As a use purpose, when it is used for building windows, general building repairs, steel and other materials where insulation and insulation materials are used, it can exhibit excellent performance in terms of economical efficiency and beautiful appearance.

Claims (4)

건조되면서 내부에 void를 가지는 에멀젼의 고형분을 5∼40중량％ 사용하면서 무기질 실리케이트를 사용한 도료 조성물Coating composition using inorganic silicate while using 5 to 40% by weight of solids of emulsion having voids while drying 제 1 항에 있어서,The method of claim 1, 건조되면서 내부에 void를 가지는 에멀젼의 고형분을 5∼40중량％ 사용하고, 내부에 열전도도가 낮은 void를 가지는 진공체의 무기질 실리케이트를 5∼20중량％ 함유하는 화합물A compound containing 5 to 40% by weight of solids of an emulsion having voids while drying, and 5 to 20% by weight of inorganic silicates of a vacuum body having voids having low thermal conductivity inside. 제 1 항에 있어서,The method of claim 1, 건조되면서 내부에 void를 가지는 에멀젼의 고형분을 5∼40중량％ 사용하고 단열효과와 치수안정성이 우수한 운모를 10∼30중량％ 사용한 도료 조성물.The coating composition which used 5-40 weight% of solids of the emulsion which has void inside, and used 10-30 weight% which is excellent in heat insulation effect and dimensional stability, while drying. 제 1 항, 제 2 항, 제 3 항을 모두 포함하는 도료 조성물로서,A coating composition comprising all of claims 1, 2, and 3, 건조되면서 내부에 void를 가지는 에멀젼의 고형분을 5∼40중량％ 사용하고 내부에 열전도도가 낮은 void를 가지는 진공체의 무기질 실리케이트를 5∼20중량％ 함유하고 단열효과와 치수안정성이 우수한 운모가 10∼30중량％ 함유한 도료 조성물.Mica contains 5 to 40% by weight of solids of the emulsion having voids inside and 5 to 20% by weight of inorganic silicates of vacuum bodies having voids with low thermal conductivity and has excellent thermal insulation and dimensional stability. Paint composition containing-30 weight%.
KR1019990024530A 1999-06-26 1999-06-26 A compisite by insulated paint a formation of paint substance for thermal insulation KR100324305B1 (en)

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KR20010000372A (en) * 2000-09-23 2001-01-05 임정기 WATERPRoof and ADIABATOR PAINT
KR100496509B1 (en) * 2002-11-21 2005-06-22 중앙방수기업주식회사 Complex waterproofing structure and method by penetrative silicate waterproofing agent and heat-protection, dew condensation-protection
KR100816085B1 (en) * 2001-12-29 2008-03-24 주식회사 케이씨씨 Anti-stain solar heat-shield insulating paint composition
KR100918085B1 (en) * 2009-02-16 2009-09-22 (주)비온디 Adiabatic paint composition for building structure and method for adiabatic construction by using the same
KR101065796B1 (en) * 2009-04-30 2011-09-19 (주)유창 Noninflammable coating materials and a manufacturing method thereof
CN102382520A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Vinyl-acrylic emulsion heat-insulation paint
CN102382534A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Acrylic resin heat-insulation paint
CN102382530A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Vinyl acrylic emulsion heat-insulation paint
CN102382531A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Phenylacetic emulsion-vinyl acetate/acrylic emulsion heat preservation coating
CN102382529A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Acetylated emulsion thermal insulation coating
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010000372A (en) * 2000-09-23 2001-01-05 임정기 WATERPRoof and ADIABATOR PAINT
KR100816085B1 (en) * 2001-12-29 2008-03-24 주식회사 케이씨씨 Anti-stain solar heat-shield insulating paint composition
KR100496509B1 (en) * 2002-11-21 2005-06-22 중앙방수기업주식회사 Complex waterproofing structure and method by penetrative silicate waterproofing agent and heat-protection, dew condensation-protection
KR100918085B1 (en) * 2009-02-16 2009-09-22 (주)비온디 Adiabatic paint composition for building structure and method for adiabatic construction by using the same
KR101065796B1 (en) * 2009-04-30 2011-09-19 (주)유창 Noninflammable coating materials and a manufacturing method thereof
CN102382520A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Vinyl-acrylic emulsion heat-insulation paint
CN102382534A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Acrylic resin heat-insulation paint
CN102382530A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Vinyl acrylic emulsion heat-insulation paint
CN102382531A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Phenylacetic emulsion-vinyl acetate/acrylic emulsion heat preservation coating
CN102382529A (en) * 2010-08-31 2012-03-21 苏州美亚美建筑涂料有限公司 Acetylated emulsion thermal insulation coating
EP3401375A1 (en) 2017-05-10 2018-11-14 Ekobokra Kajmar WASZUT Jolanta Method of manufacturing of the thermoactive acrylic paint

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