KR20000007733A - Antibiotic deodorized fibrous textile and production method and products thereby - Google Patents

Antibiotic deodorized fibrous textile and production method and products thereby Download PDF

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Publication number
KR20000007733A
KR20000007733A KR1019980027215A KR19980027215A KR20000007733A KR 20000007733 A KR20000007733 A KR 20000007733A KR 1019980027215 A KR1019980027215 A KR 1019980027215A KR 19980027215 A KR19980027215 A KR 19980027215A KR 20000007733 A KR20000007733 A KR 20000007733A
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South Korea
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fiber
antibacterial
deodorant
antimicrobial
antibiotic
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KR1019980027215A
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Korean (ko)
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이희명
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이희명
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42Oxides or hydroxides of copper, silver or gold
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear
    • D10B2501/021Hosiery; Panti-hose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments
    • D10B2501/043Footwear
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/04Floor or wall coverings; Carpets
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00Medical; Hygiene
    • D10B2509/02Bandages, dressings or absorbent pads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00Medical; Hygiene
    • D10B2509/02Bandages, dressings or absorbent pads
    • D10B2509/026Absorbent pads; Tampons; Laundry; Towels

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

PURPOSE: An antibiotic deodorized fibrous textile is provided to enable washing of many times and to endure high-temperature, harmless to human body and to the skin, to use as antibiotic deodorized insole, socks, underwear, carpet. CONSTITUTION: A production method of a fiber has the steps of: complex processing copper ion in polyacryliconitril which is the 1st group of acrylicic fiber; combining C23H25N2 radical group in the 3rd group different strong acid or polyacryliconitril; inputting acrylic fabric in oleic acid solution and inputting it in oleic acid to keep at the temperature of 40-60°C.

Description

항균 방취 섬유 직물 및 그 제조방법 및 이를 채용하는 용품 (An antibacterial and antistench fiber, and a method for producing of the fiber, and an article having the fiber)An antibacterial and antistench fiber, and a method for producing of the fiber, and an article having the fiber

본 발명은 일종의 항균 방취 섬유 직물 및 제조방법에 관한 것으로써, 특히 섬유의 성질을 개조 처리하여 응용한 방법이다.The present invention relates to a kind of antibacterial and deodorant fiber fabrics and a manufacturing method, in particular, a method applied by modifying the properties of the fiber.

일상 생활중에 사용하는 방직품에는 많은 미생물들이 있으며, 또 이로인해 많은 병균이 생겨나고 곰팡이가 형성되어 방직품의 위생상태를 악화시킨다.There are many microorganisms in the textiles used in daily life, and as a result, many germs are formed and molds are formed to deteriorate the sanitary condition of the textiles.

속내의, 양말, 구두깔창 등을 사용할 때 땀과 피부온도로 인해 미생물의 자생, 번식과 부패의 성장조건이 되므로 결과적으로 악취를 풍기게 된다. 고온에서 소독해낸 의료방직품은 비록 멸균은 했으나 사용할 때 빠른속도로 세균이 감염된다. 때문에 국내외에서는 항균 방취 방직품 연구에 관심을 갖어 왔었다.When using the inner, socks, shoe insoles, sweat and skin temperature due to the growth conditions of microbial growth, reproduction and decay, resulting in a bad smell. Medical textile products sterilized at high temperatures, although sterilized, rapidly infect bacteria when used. Therefore, at home and abroad, they have been interested in researching antibacterial and deodorant textiles.

일본(가공기술) VOL. 17 No. 7에서 보도한 내용에 따르면, 2개 동염과 유황화합물로 처리한 아크릴 섬유 제품은 금황색포도구균과 고초간균의 발육을 저지할 수 있다고 했다. 이후에 이와 유사한 보도가 있었으나 이후에 유화동을 복합시킨 아크릴의 일종은 금황색포도구균, 고초간균,대장간균,피부사상백선균등 4가지 종류에 살균능력이 어느정도 있다고 했다.Japan (processing technology) VOL. 17 No. According to a report reported in 7, acrylic fiber products treated with two copper salts and sulfur compounds can inhibit the growth of Staphylococcus aureus and Bacillus subtilis. There was a similar report afterwards, but there were four types of acrylic compounded with emulsified copper, and there were some kinds of bactericidal ability, such as golden yellow tarpaulin, Bacillus subtilis, Escherichia coli and dermatophytes.

본 발명의 목적은 항균범위를 확대하는 데 있으며 금황색포도구균(청민주),금황색포도구균(청내주), 백색포도구균, 백염주균,고초간균,대장간균,녹농간균,이질간균,장염간균,상한간균등 10여개 균 종류에 대한 항균방취 섬유 및 제조방법을 제공하는 데 있다.An object of the present invention is to expand the antimicrobial range, and the yellowish yellow Pogukyun (cheongjuju), Geumwangpopogi (cheongnaeju), whitepogugi, Bacillus bacillus, Bacillus subtilis, Escherichia coli, Pseudomonas aeruginosa, To provide antimicrobial deodorant fiber and manufacturing method for about 10 kinds of bacteria including enteritis bacillus, upper limit bacillus.

또한, 항균 방취 섬유직물을 채용한 양말,구두깔창,속내의 등의 일상용품을 제공하는 데 있다.In addition, to provide a daily necessities such as socks, soles, insoles employing antibacterial and deodorant textile fabrics.

본 발명의 기술요점은 화학반응을 통해 아크릴 섬유상에 동이온과 알카리성녹4 C23H25N2 +기단을 형성하여 섬유의 성질을 바꾸었다. 이중에 동이온과 아크릴의 복합은 아크릴중에 청기(-CN)을 실현시켰는데 그 반응등식은 다음과 같다.Technical point of the present invention is to change the properties of the fiber by forming a copper ion and alkaline rust 4 C 23 H 25 N 2 + base on the acrylic fiber through a chemical reaction. Among these, the complex of copper ions and acryl realized the fresh air (-CN) in acryl, and the reaction equation is as follows.

C23H25N2 +는 아크릴 섬유중 제3단체 황산 나트륨이나 또는 이강산 염화나트륨의 복합체이다. 이의 반응등식은 다음과 같다.C 23 H 25 N 2 + is a complex of tertiary sodium sulfate or sodium diacid chloride in acrylic fiber. Its reaction equation is as follows.

아크릴 섬유의 성질을 개량한 후의 구성등식은 다음과 같다.The structural equation after improving the property of acrylic fiber is as follows.

또는or

아크릴 섬유상에 동 이온과 C23H25N2기단이 생겨나고 이것은 세균의 살상작용을 하여 항균능력을 제고하고 따라서 원래의 아크릴 성질을 개량하여 항균방취작용을 한다. 그래서 항균 범위를 확대한다.Copper ions and C 23 H 25 N 2 bases are formed on the acrylic fiber, which kills bacteria and improves antimicrobial ability, thus improving the original acrylic property to perform antibacterial deodorization. So broaden the antimicrobial range.

본 발명의 제조방법은 다음과 같다.The production method of the present invention is as follows.

제1실시예First embodiment

아크릴:유산동:유대유산나트륨:알카리성녹4염료간의 배합비율은 1: (0.05-0.5):(0.01-0.1):(0.001-0.01)의 비율로 배합한다.The blending ratio of acrylic: copper lactate: sodium lactate: alkaline rust 4 dyes is compounded at the ratio of 1: (0.05-0.5) :( 0.01-0.1) :( 0.001-0.01).

먼저 상술한 배합 비율대로 유산동과 유대유산나트륨의 용액을 제조한다. 후에 아크릴 섬유를 넣는다. 투욕 비례조건은 1:(50-200), 온도는 40-80℃를 유지하고, 0.5-1시간후에 섬유나 직물을 꺼내 세탁하고 이후에 알카리성녹4를 다시넣고 Ph를 3-4로 조절하여 온도를 60-100℃를 유지한 후에 0.5-1시간후에 세탁하여 건조시킨다.First, a solution of copper lactate and sodium lactate is prepared in the above-described blending ratio. After that add acrylic fiber. The ratio of bathing ratio is 1: (50-200) and the temperature is maintained at 40-80 ℃. After 0.5-1 hour, the fibers or fabrics are taken out and washed. After that, the alkaline rust 4 is put again and the Ph is adjusted to 3-4. After keeping the temperature 60-100 ℃ washed after 0.5-1 hours to dry.

제2실시예Second embodiment

1그램의 아크릴 섬유(39수2겹)을 유산동 0.2그램과 유대유산나트륨0.1그램을 100리터에 넣어 1:(100-200)의 비율로 하고, 온도는 70-80℃를 유지시키고, 보온을 1시간 시킨후에 세탁하여 알카리성녹4를 0.15%를 넣은 후에 H。A。를 넣어 Ph를 3-4로 조절한다. 온도는 70-80℃에서 1시간 보온한 후에 세탁하여 건조한다.1 gram of acrylic fiber (39 layers 2 layers) is added 0.2 grams of lactic acid copper and 0.1 grams of sodium lactate in 100 liters at a ratio of 1: (100-200), the temperature is maintained at 70-80 ℃, keeping warm After washing for 1 hour, add 0.15% of alkaline rust 4, and then adjust Ph to 3-4 by adding H。A 。. The temperature is kept at 70-80 ° C. for 1 hour, followed by washing and drying.

제3실시예Third embodiment

1그램의 아크릴을 50리터의 용액에 유산동 0.2그램과 유대유산나트륨0.1그램과 기화나트륨 0.01용액중 용액비율을 1:(50-100)의 비율로 하고, 온도는 70-80℃에서 1시간 보온시킨후에 세탁하여 알카리성녹4를 0.15%를 넣은 후에 H。A。를 넣어 Ph를 3-4로 조절한다. 온도는 70-80℃에서 1시간 보온한 후에 세탁하여 건조한다.1 gram of acrylic is 50 liters of solution, 0.2 grams of copper lactate, 0.1 grams of sodium lactate and 0.01 g of sodium vaporization solution in a ratio of 1: (50-100), and the temperature is kept at 70-80 ° C. for 1 hour. After washing, put alkaline rust 4 into 0.15%, and then add H。A。 to adjust the pH to 3-4. The temperature is kept at 70-80 ° C. for 1 hour, followed by washing and drying.

제4실시예Fourth embodiment

1그램의 아크릴-면 혼방섬유(39수2합) 40%를 100리터에 유산동 0.1그램과 유대유산나트륨0.05그램을 1:(100-200)의 비율로 하고, 온도는 60-70℃에서 1시간 보온시킨후에 세탁하여 알카리성녹4를 0.1%와 H。A。를 넣어 Ph를 3-4로 조절하여 60-70℃에서 1시간 보온한 후에 세탁하여 건조한다.40% of 1 gram of acrylic-cotton blend fiber (39 water 2 go) is 100 liters, 0.1 gram of lactic acid copper and 0.05 grams of sodium lactate in a ratio of 1: (100-200), and the temperature is 1 at 60-70 ° C. After warming for a period of time, wash and put alkaline rust 4 0.1% and H。A。, adjust the pH to 3-4, keep warm at 60-70 ℃ for 1 hour, then wash and dry.

제5실시예Fifth Embodiment

1그램의 아크릴-면 혼방섬유 40%를 50리터에 유산동 0.1그램과 유대유산나트륨0.05그램과 기화나트륨 0.01그램의 용액중 1:(50-100)의 비율로 하고, 온도는 60-70℃에서 1시간 보온시킨후에 세탁하여 알카리성녹4를 0.1%를 넣은 후에 H。A。를 넣어 Ph를 3-4로 조절하여 60-70℃에서 1시간 보온한 후에 세탁하여 건조한다.40 grams of 1 gram of acrylic-cotton blend fiber is 50 liters in a ratio of 1: (50-100) in a solution of 0.1 grams of copper lactate, 0.05 grams of sodium lactate, and 0.01 grams of sodium vapor, and the temperature at 60-70 ° C. After warming for 1 hour, wash, add 0.1% of alkaline rust 4, add H。A。, adjust Ph to 3-4, warm at 60-70 ℃ for 1 hour, wash and dry.

본 발명의 응용범위는 넓으며 구두깔창,양말,내외의류,침상용품,부녀자위생용품, 병원용붕대 등을 항균방취제품으로 제조가 가능하고 실내장식직품,카페트등으로 사용이 가능하다.The scope of the present invention is wide and can be manufactured as an antibacterial deodorant products, such as shoe insoles, socks, clothing, bedding, women's hygiene products, hospital bandages, and can be used as interior decoration, carpets and the like.

첫째, 본 발명 항균 방취 섬유직물은 금황색포도구균(청민주),금황색포도구균(청내주),백색포도구균,백색염주균,고초간균,대장간균,녹농간균,이질간균,장염간균,상한간균 등의 넓은 범위에서 항균작용에 효과적이다.First, the present invention antimicrobial deodorant textile fabrics are yellowish yellow poults bacteria (cheongjuju), golden yellow poinsectium bacteria (Cheongnaeju), white poultry bacteria, white rot bacteria, Bacillus subtilis, E. coli bacilli, green bacillus bacilli, dysentery bacilli It is effective for antibacterial activity in a wide range such as capping bacillus.

둘째, 항균속도가 빠르다. 30분이내에 효과를 볼수 있다.Second, the antibacterial speed is fast. You can see the effect within 30 minutes.

셋째, 측정결과 본 발명은 인체에 무독성,무자극,무과민하다.Third, the measurement result The present invention is non-toxic, non-irritating, sensitive to the human body.

넷째, 이외에 세탁성이 우수하다. 60회 세탁, 1000회의 마찰에도 항균효과는 변함이 없고 130℃의 고온에서도 견디며 원가가 저렴하다.Fourth, the washability is excellent in addition. The antibacterial effect does not change even after 60 washings and 1000 frictions, and it can withstand high temperatures of 130 ℃ and the cost is low.

다섯째, 본 발명은 인간이 착용하거나, 식품공업,병원치료용 의료 부외품으로도 사용이가능하고, 기타 의료수단을 거치지 않고도 상처가 신속하게 치료될 수 있다. 여러차례 임상실험에서 이러한 점이 표명되었다.Fifth, the present invention can be worn by humans, can be used as a quasi-medical product for food industry, hospital treatment, and wounds can be quickly treated without going through other medical means. This has been demonstrated in several clinical trials.

Claims (12)

아크릴 섬유의 제1단체인 폴리 아크릴로니트릴에 동 이온을 복합처리하고, 제3단체 이강산 또는 폴리아크릴로니트릴에 C23H25N2 +기단에 복합시켜 다음과 같은 화학식중 어느 하나를 가지는 것을 특징으로 하는 항균 방취 섬유직물.The copper ions are mixed with polyacrylonitrile, which is the first group of acrylic fibers, and complexed with C 23 H 25 N 2 + base in a third group of yigangsan or polyacrylonitrile, having any one of the following formulas: Antibacterial and deodorant textile fabric characterized in that. 또는or 항균 방취 섬유직물의 제조방법에 있어서, 아크릴 섬유직물을 유산동에 넣었다가 유대 유산나트륨의 용액에 넣어 40-60℃의 온도로 유지시키는 것을 특징으로 하는 항균 방취 섬유직물의 제조방법.A method for producing an antimicrobial deodorant textile fabric, wherein the acrylic fiber fabric is placed in a copper lactate and then placed in a solution of sodium lactate, which is maintained at a temperature of 40 to 60 ° C. 제2항에 있어서, 제1차 처리한 섬유직물을 알카리성 녹4의 용액에 넣고 80-100℃에서 유지시키는 공정을 포함하여 된 것을 특징으로 하는 항균 방취 섬유직물의 제조방법.The method for producing an antibacterial and deodorizing textile fabric as claimed in claim 2, comprising the step of putting the first treated textile fabric in a solution of alkaline rust 4 and maintaining at 80-100 ° C. 제2항에 있어서, 상기 아크릴섬유:유산동:유대유산나트륨:알카리성녹4 염료의 배합비율이 1:(0.05-0.5):(0.01-0.1):(0.001-0.01)인 것을 특징으로 하는 항균 방취 섬유직물의 제조방법.The antimicrobial deodorizing agent according to claim 2, wherein the blending ratio of the acrylic fiber: copper lactate: sodium lactate: alkaline rust 4 dye is 1: (0.05-0.5): (0.01-0.1): (0.001-0.01). Method of manufacturing textile fabrics. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 신발깔창.Shoe insole, characterized in that made of the antibacterial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 양말.Socks, characterized in that made of the antibacterial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 속내의.Underwear, characterized in that made of the antibacterial deodorizing fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 침상용품.Needle-shaped article, characterized in that made of the antimicrobial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 실내장식용품.Upholstery article, characterized in that made of the antibacterial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 카페트.Carpet, characterized in that made of the antibacterial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 생리용품.Sanitary ware comprising the antimicrobial deodorant fiber of claim 1. 상기 청구항1의 항균 방취 섬유로 제조된 것을 특징으로 하는 병원용 붕대.Hospital bandages made of the antimicrobial deodorant fiber of claim 1.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100776225B1 (en) * 2000-06-19 2007-11-16 유니챰 가부시키가이샤 Sanitary shorts

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100776225B1 (en) * 2000-06-19 2007-11-16 유니챰 가부시키가이샤 Sanitary shorts

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