KR19990068267A - Paris composition and its preparation method_ - Google Patents

Abstract

The present invention can effectively control pests belonging to the fly, such as flies by coating the surface of sucrose particles with a variety of attractants and extenders for attracting flies with insecticidal active ingredients having an insecticidal effect against flies, easy to use The present invention relates to a fly mouth composition and a method for producing the same.

The paralyzed composition according to the present invention is an insecticide selected from the group consisting of deltamethrin, dichlorbose, cypermethrin, imidacloprid, chlorfenapyr, chlorpyriphos, tetramethrin, permethrin or a mixture of two or more thereof. 1 to 10% by weight of active ingredient, 3 to 15% by weight of extender selected from the group consisting of pyrophyllite, white carbon or a mixture of two or more thereof, 0 to 5% by weight of malt sugar, salted and salted with salted seafood From 3% by weight to 0% by weight of glycol, 0-1% by weight of arthropods, in particular 0% to 1% by weight of pheromone in flies, and 0% to 2% by weight of the pesticide mixture on the surface of 60-95% by weight of sucrose particles Characterized in that made.

Therefore, according to the present invention, there is an effect of providing an extremely easy-to-use fly control composition which can effectively attract and control flies by coating insecticide active ingredients and attractants on the surface of sucrose particles.

Description

Paris composition and its preparation method

The present invention relates to a fly rescue composition and a method for producing the same. In more detail, the present invention can effectively control fly flies, especially flies, by coating the sucrose particles with a pesticide active ingredient having insecticidal effect against flies together with various attractants and extenders for attracting flies. A simple fly rescue composition and a method for producing the same.

Various studies have been carried out in the control of flies and pests, especially flies, and various types of products have been specified.

Japanese Patent Publication No. 94-802 describes a composition containing a sex pheromone of Paris, but this shows a great effect on the attraction of the fly, while the remedy effect is insufficient.

Insecticidal compositions based on the bases of trans Kris and mate alledrone and al-alledrone esters having activity against arthropod insects including flies (Korean Patent Publication No. 83-2677), active against arthropod insects Although there are aerosol insecticide compositions (Korean Patent Publication No. 85-1331) using a phosphorus pyredoid compound, they have a disadvantage in that the remedy effect is not sufficient for flies that are resistant to organophosphorus insecticides.

In addition, the fly medicines that have been developed and marketed as existing products have a disadvantage in that the remedy is less effective because most of them do not attract flies.

Therefore, there is a need for the development of an effective fly rescue composition that can solve this problem.

Disclosure of Invention An object of the present invention is to provide a fly control composition and a method of manufacturing the same, which have an excellent effect on attracting and controlling by coating a sucrose particle surface with an insecticidal active ingredient capable of killing flies and an attractant capable of attracting flies. .

Another object of the present invention is to provide a fly control composition and a method for producing the fly control which has a high control effect against flies that are resistant to organophosphorus insecticides.

The Parisian composition according to the present invention for achieving the above object is a delta mesrin, dichlorbose, cypermethrin, imidacloprid, chlorfenapyr, chlorpyriphos, tetramethrin, permethrin or a mixture of two or more thereof 1 to 10% by weight of the pesticidal active ingredient selected from the group consisting of, pyrophyllite, white carbon or a mixture of two or more thereof, 3 to 15% by weight, 0 to 5% by weight of malt, salted and salted 60-95% by weight sucrose particles of 0.5-3% by weight of fermented salted fish, 0-3% by weight of glycol, 0-1% by weight of pheromones of arthropods, especially flies, 0-2% by weight of pigments It is made by uniformly coating the surface.

In addition, the method for preparing fly mouth composition mule according to the present invention comprises: (1) a sample pretreatment step of mixing and grinding an insecticidal active ingredient and an extender; (2) a first coating step of coating a mixture of maltose, salted fish, sex pheromone and glycol on the surface of sucrose particles selected to a size of 0.5 to 5mm; (3) a secondary coating step of coating the mixture obtained by mixing the pigment with the mixture obtained in the sample pretreatment step on the surface of the particles obtained in the first coating step; And (4) a drying step of drying the coated particles in the secondary coating step at a temperature of 20 to 40 ℃.

Hereinafter, the present invention will be described in detail with reference to specific examples.

The paralyzed composition according to the present invention is an insecticide selected from the group consisting of deltamethrin, dichlorbose, cypermethrin, imidacloprid, chlorfenapyr, chlorpyriphos, tetramethrin, permethrin or a mixture of two or more thereof. 1 to 10% by weight of active ingredient, 3 to 15% by weight of extender selected from the group consisting of pyrophyllite, white carbon or a mixture of two or more thereof, 0 to 5% by weight of malt sugar, salted and salted with salted seafood From 3% by weight to 0% by weight of glycol, 0-1% by weight of arthropods, in particular 0% to 1% by weight of pheromone in flies, and 0% to 2% by weight of the pesticide mixture on the surface of 60-95% by weight of sucrose particles Characterized in that made.

The insecticidal active ingredient serves to show the insecticidal effect on the actual flies, and these are already commercially available ones that can be easily known and can be easily purchased and used by those skilled in the art. have. Insecticidal active ingredients in the present invention can be used both water-soluble, poorly water-soluble and non-water-soluble pesticidal active ingredients, which can be used without being significantly affected by physical and chemical properties such as formulation or solubility of the pesticidal active ingredient itself. As the insecticidal active ingredient, Deltamethrin (S) -α-cyano-3-phenoxy benzyl (1R, 3R) -3- (2,2-dibromo vinyl) -2,2-dimethylcyclopropane carboxylate ), Dichlorvos (2,2-dichloro vinyl dimethyl phosphate), Cypermethrin (RS)-α-cyano-3-phenoxy benzyl (1RS, 3RS; 1RS, 3SR)-3-(2 , 2 -dichloro vinyl) -2,2-dimethyl cyclopropane carboxylate), imidacloprid (1-(6-chloro-3-pyridyl methyl)-N-nitro imidazolidin-2-ylidene amine), Chlorfenapyr 4-bromo-2-(4-chloro phenyl)-1-ethoxy methyl-5-trifluoro methyl pyrrole-3-carbonitrile, Chlorpyrifos (O, O-3,5,6-trichloro-2- pyridyl phosphoro thioate), tetramethrin (cyclohex-1 -ene-1,2 -dicarboximido methyl (1RS, 3RS; 1RS, 3SR)-2,2-dimethyl-3-(2-methyl prop-1-enyl a) cyclopropane carboxylate), fur Permethrin (3-phenoxy benzyl (1RS, 3RS; 1RS, 3SR)-3-(2,2 -dichloro vinyl)-(2,2 -dimethyl cyclopropane carboxylate) or mixtures of two or more thereof May be used. When the pesticidal active ingredient is included in less than 1% by weight, there may be a problem that the absolute amount of the pesticidal active ingredient absorbed in the fly is not enough to expect a sufficient pesticidal effect, on the contrary more than 10% by weight Waste of the active ingredient is undesirable.

The extender adsorbs and powders the pesticidal active ingredient and functions as a material forming a surface with the other compositions as described above, and in particular, adjusts the composition ratio such as the pesticidal active ingredient, and controls the amount of the composition to enable a smooth coating, It can be understood that it can be suitably used for controlling the composition ratio of the whole composition, in particular for controlling the content of the pesticidal active ingredient. Therefore, it can be understood that the amount of use can also be appropriately added or reduced in consideration of the component ratio of the other components. As the extender, it is preferably easy to micronize, not reactive, inexpensive, and easy to supply raw materials. In particular, commercially available extenders such as pyrophyllite and white carbon may be used. The extender may preferably be used in the range of 3 to 15% by weight based on the amount of the pesticide active ingredient used.

The maltose increases the binding force of the insecticidal active ingredient and at the same time serves as an attractant to the fly, maltose, maltose syrup, syrup, powdered syrup, soybean syrup, or a mixture of two or more thereof, composed mainly of maltose. One selected from the group can be preferably used. If the maltose is more than 5% by weight may be a problem that the whole composition becomes too sticky and uncomfortable handling.

The salted fish refers to a common salted fish fermented by salting fish and shellfish, which is attracted to achieve an effective insecticidal effect on flies by its peculiar odor, and commercially available salted fish, salted fish or mixtures thereof One selected from the group consisting of can be preferably used. When the salted fish is contained in less than 0.5% by weight, there may be a problem that the attraction of the fly is reduced, when the salted fish exceeds 3% by weight may not be easy to coat the surface of the sucrose particles.

The glycol is for inhibiting the volatilization of volatile components such as salted fish and st. Pheromone of the composition in the drying step and the like in the preparation of the fly control composition according to the invention, preferably ethylene glycol, propylene glycol Selected from the group consisting of diethylene glycol, polyethylene glycol, or a mixture of two or more thereof, and may not be used depending on conditions, and in the case of more than 3% by weight, volatilization of these salted fish and sex pheromone of fly This may be extremely suppressed and there is a problem that the attraction effect of the fly is lowered.

The sex pheromone of the fly is a bio-secretory material of arthropods, in particular flies, typically can be used to purchase muscamon, etc., which are mass produced and distributed by synthesis. It does not need to exceed 1% by weight because it shows a sufficient attracting effect even in a very small amount, and may not be used by the use of salted fish because it only produces the attracting effect of flies.

The pigment is used to make it easy to identify the composition by distinguishing the composition to a specific color, and can be understood as those that can be purchased and used commercially as well, monoazo, diazo, phthalocyanine-based Commercial pigments may optionally be used, and the entire composition may be sufficiently colored in a predetermined color even by using less than 2% by weight.

The sucrose particles are granulated sucrose prepared by processing sugarcane or beet, which is composed mainly of sucrose (Sucrose) as a support agent and a attractant for attracting flies according to the present invention. Ordinarily selected from the group consisting of white sugar, brown sugar, double pairs, raw sugar, powdered sugar or a mixture of two or more thereof can be preferably used. Since the sucrose particles serve as a support, when used at less than 60% by weight, there may be a problem that other components are not sufficiently coated and isolated, and, in contrast, when more than 95% by weight, other effective ingredients There may be a problem that the proportion of filaments is relatively reduced, resulting in insufficient relief of flies.

In addition, the method for preparing fly mouth composition mule according to the present invention comprises: (1) a sample pretreatment step of mixing and grinding an insecticidal active ingredient and an extender; (2) a first coating step of coating a mixture of maltose, salted fish, sex pheromone and glycol on the surface of sucrose particles selected to a size of 0.5 to 5mm; (3) a secondary coating step of coating the mixture obtained by mixing the pigment with the mixture obtained in the sample pretreatment step on the surface of the particles obtained in the first coating step; And (4) a drying step of drying the coated particles in the secondary coating step at a temperature of 20 to 40 ℃.

In the sample pretreatment step, the insecticidal active ingredient is mixed with the extender, and adsorbed to the extender to facilitate powder separation. In the subsequent primary coating step, a mixture of maltose, salted fish and sex pheromone and glycol on the surface of the selected sucrose particles is added. After coating, the mixture obtained by mixing the pigment in the mixture obtained in the sample pretreatment step thereon may be secondly coated, and then, the coated particles may be dried at a temperature of 20 to 40 ° C. to prepare a predetermined fly mouth composition. .

In the preparation of the fly rescue composition according to the above-described procedure, since the mixture of maltose, salted fish, sex pheromone and glycol is first coated on the basis of the surface of sucrose particles, it can be controlled to slowly release salted fish and sex pheromone of fly. In addition, since the insecticidal active ingredient which substantially eliminates flies is coated thereon, flies attracted by the salted fish and sex pheromone and maltose of the fly secrete the digestive fluid in the epidermal layer of the fly control composition according to the present invention, and liquefy the composition. Inhalation of the insecticidal active ingredient constituting the epidermis in the fly control composition is immediately inhaled to enable effective control.

Hereinafter, preferred embodiments and comparative examples of the present invention will be described.

The following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.

Example 1

On a surface of 80 kg of sugar particles screened to 3 mm size, a mixture of 1.9 kg of crude syrup, 500 g of meat salt, 50 g of muscamon and 500 g of diethylene glycol was first coated, and then 5 kg of dichlorose was placed on top of 12 kg of sugar. The mixture which was premixed with pyrophyllite and pretreated and the mixture of 50 g of the pigment was recoated and dried at a temperature of 35 ° C. to obtain a fly control composition according to the present invention, and the insecticidal effect thereof was tested.

Insecticidal effect test on housefly was carried out by placing a bowl containing the obtained sample and a bowl containing sugar water in a frame made of mesh of 2m in width, length, and height of 2m each. And after 48 hours, the number of viable insects was counted, and the viability was investigated, and the results are shown in Table 1 below.

In addition, at the same time, for the comparison with the untreated, prepared a test bowl placed only a bowl containing sugar water and put 200 test insects raised indoors, counting the number of live insects after 24 hours and 48 hours, It investigated and the result is shown in following Table 1.

In addition, for the insecticidal effect test for flies resistant to organophosphorus insecticides, test specimens were replaced with flies having resistance to organophosphorus insecticides and tested in the same manner, and the results are shown in Table 2 below.

Example 2

On the surface of 89 kg of the double-particles screened to 3 mm size, 2.4 kg of starch syrup, 1 kg of fish sauce, 50 g of muscamon and 500 g of diethylene glycol were first coated, followed by 4.9 kg of 2.1 kg of imidacloprid. The mixture pre-mixed with pyrophyllite and the mixture of 50 g of the pretreated mixture were recoated and dried at a temperature of 35 ° C. to obtain a fly rescue composition according to the present invention, and the insecticidal effect thereof was carried out as described above. Test was carried out in the same manner as in Example 1, the results are shown in Table 1 and Table 2.

Example 3

On a surface of 85 kg of the double-particles screened to a size of 3 mm, a mixture of 1.9 kg of crude, 500 g of meat, 50 g of muscamon and 500 g of diethylene glycol was first coated, and then 4 kg of chlorfenapyr was placed on top of Recoating the mixture premixed with pyrophyllite and the mixture of 50 g of the pigment and dried at a temperature of 35 ° C. to obtain a fly rescue composition according to the present invention, and the insecticidal effect thereof Test was carried out in the same manner as 1, and the results are shown in Table 1 and Table 2.

Example 4

On the surface of 80 kg of double-particles screened to 3 mm size, 1.9 kg of starch syrup, 500 g of fish sauce, 50 g of muscamon and 500 g of diethylene glycol were firstly coated, and then 5 kg of chlorpyrifose was placed thereon. Recoating the mixture premixed with pyrophyllite and the mixture of 50 g of the pigment and dried at a temperature of 35 ° C. to obtain a fly rescue composition according to the present invention, and the insecticidal effect thereof Test was carried out in the same manner as 1, and the results are shown in Table 1 and Table 2.

Example 5

On a surface of 85 kg of the double-particles screened to 3 mm size, a mixture of 1.9 kg of fresh blue ginseng, 500 g of meat salt, 50 g of muscamon and 500 g of diethylene glycol was first coated, and then 5 kg of permethrin on top of 8 kg of Recoating the mixture premixed with pyrophyllite and the mixture of 50 g of the pigment and dried at a temperature of 35 ° C. to obtain a fly rescue composition according to the present invention, and the insecticidal effect thereof Test was carried out in the same manner as 1, and the results are shown in Table 1 and Table 2.

Comparative example

Using a domestic commercial fly mouth composition containing 1.1% by weight of the sample was tested in the same manner as in Example 1, the results are shown in Table 1 and Table 2.

Insecticidal effect test on housefly division 24 hours later 48 hours later Fresh water (mari) % Viability Fresh water (mari) % Viability Example 1 24 12.0 11 5.5 Example 2 20 10.0 10 5.0 Example 3 20 10.0 13 6.5 Example 4 23 11.5 12 6.0 Example 5 21 10.5 11 6.5 Comparative example 25 12.5 14 7.0 No treatment 200 100.0 196 98.0

Insecticidal test on flies resistant to organophosphorus pesticides division 24 hours later 48 hours later Fresh water (mari) % Viability Fresh water (mari) % Viability Example 1 23 11.5 13 6.5 Example 2 21 10.5 11 5.5 Example 3 28 14.0 13 6.5 Example 4 23 11.5 15 7.5 Example 5 30 15.0 22 11.0 Comparative example 43 21.5 30 15.0 No treatment 200 100.0 199 99.5

As a result of the synthesis of the above embodiments, it was confirmed that an excellent remedy effect can be obtained as compared with the conventional commercialized product as a comparative example, and in particular, an excellent remedy effect can be obtained even against flies resistant to organophosphorus insecticides. Could confirm. This showed a strong insecticidal effect against flies compared to no treatment, it was confirmed that the fly control composition according to the present invention is very excellent in the control of the fly.

Therefore, the present invention has an effect of providing an extremely easy-to-use fly control composition which can effectively control by attracting flies and pests, in particular flies, by coating the sucrose particles on the surface of the sucrose particles.

In addition, the fly rescue composition according to the present invention has the effect of providing a fly rescue composition showing an excellent control effect against flies having resistance to organophosphorus insecticides compared to other drugs.

In addition, according to the present invention has the effect of providing a method for producing a fly composition for easy manufacture and use using materials that can be easily purchased and used by those skilled in the art.

Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.

Claims (6)

1 to 10% by weight of an insecticidal active ingredient selected from the group consisting of deltamethrin, dichlorbose, cyspermethrin, imidacloprid, chlorfenapyr, chlorpyriphos, tetramethrin, permethrin or a mixture of two or more thereof, 3 to 15% by weight of a bulking agent selected from the group consisting of pyrophyllite, white carbon or a mixture of two or more thereof, 0 to 5% by weight of malt sugar, 0.5 to 3% by weight of salted and salted fish and salt, 0 to 3% of glycol 3% by weight, arthropods, in particular 0 to 1% by weight of the pheromone of the fly, 0 to 2% by weight of the pesticide mixture characterized in that the uniform coating on the surface of the sucrose particles of 60 to 95% by weight . The method of claim 1, And the extender is selected from the group consisting of pyrophyllite, white carbon or mixtures thereof. The method of claim 1, The fly control composition, characterized in that the maltose is selected from the group consisting of malt, maltose, syrup, powdered syrup, soybean syrup or a mixture of two or more thereof. The method of claim 1, Wherein said glycol is selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, polyethylene glycol, or a mixture of two or more thereof. The method of claim 1, The sucrose particles are granular sucrose prepared by processing sugarcane or beetroot composed of sucrose as a main component, and a group consisting of ordinary white sugar, brown sugar, double sugar, raw sugar, powdered sugar or a mixture of two or more thereof. The fly fly composition, characterized in that selected from. (1) a sample pretreatment step of mixing and grinding the pesticide active ingredient and the extender; (2) a first coating step of coating a mixture of maltose, salted fish, sex pheromone and glycol on the surface of sucrose particles selected to a size of 0.5 to 5mm; (3) a secondary coating step of coating the mixture obtained by mixing the pigment with the mixture obtained in the sample pretreatment step on the surface of the particles obtained in the first coating step; And (4) a drying step of drying the particles in which the coating is completed in the secondary coating step at a temperature of 20 to 40 ℃; manufacturing method of fly composition composition mule comprising the.