KR19980051202A - Manufacturing Method of Portland Cement Clinker Using Blast Furnace Slag, Steelmaking Slag and Limestone By-Products - Google Patents

Manufacturing Method of Portland Cement Clinker Using Blast Furnace Slag, Steelmaking Slag and Limestone By-Products Download PDF

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KR19980051202A
KR19980051202A KR1019960070076A KR19960070076A KR19980051202A KR 19980051202 A KR19980051202 A KR 19980051202A KR 1019960070076 A KR1019960070076 A KR 1019960070076A KR 19960070076 A KR19960070076 A KR 19960070076A KR 19980051202 A KR19980051202 A KR 19980051202A
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limestone
portland cement
cement clinker
slag
blast furnace
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KR1019960070076A
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Korean (ko)
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KR100270094B1 (en
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김형석
한기현
이현
이학봉
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김종진
포항종합제철 주식회사
신창식
재단법인 포항산업과학연구원
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Priority to KR1019960070076A priority Critical patent/KR100270094B1/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44—Burning; Melting
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/02—Portland cement
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/14—Cements containing slag
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/38—Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

본 발명은 고로슬래그, 제강슬래그 및 석회석 부산물을 이용한 포틀랜드 시멘트 클링커의 제조방법에 관한 것으로, 그 목적은 화학조성의 변학폭이 적은 고로슬래그, 제강슬래그 및 석회석 소성로 더스트를 포틀랜드 시멘트 클링커의 원료로 사용함으로서, 시멘트 클링커 제조공정상 원료투입의 관리를 용이하게하고, 시멘트 원료의90%이상을 차지하는 석회석의 사용량을 줄이고, 환경오염 물질을 저감시키고자 하는데 있다. 상기 목적을 달성하기 위한 본 발명은 포틀랜드 시멘트 클링커를 제조하는 방법에있어서, 단독 또는 복합으로 침가되는 석회석 소성로 더스트와 석회석 슬러리50∼55중량%,40-45중량%의 고로슬래그 및 5중량%이하의 제강슬래그를 혼합하여1350-1450℃의 온도범위에서 1시간 이상 소성하는 것으로 구성되는 고로슬래그, 제강슬래그 및 석회석 소성로 더스트를 이용한 포틀랜드 시멘트 클링커의 제조방법에관한 것을 그 요지로 한다.The present invention relates to a method for producing a portland cement clinker using blast furnace slag, steelmaking slag and limestone by-products, and an object thereof is to use blast furnace slag, steelmaking slag and limestone kiln dust with low chemical composition as a raw material of portland cement clinker. By doing so, it is easy to manage the input of raw materials in the cement clinker manufacturing process, to reduce the amount of limestone occupying 90% or more of the cement raw materials, and to reduce environmental pollutants. The present invention for achieving the above object in the method for producing a portland cement clinker, 50 to 55% by weight of limestone kiln dust and limestone slurry, immersed alone or in combination, 40 to 45% by weight of blast furnace slag and 5% by weight or less The present invention relates to a method for producing a Portland cement clinker using blast furnace slag, steelmaking slag and limestone kiln dust, which consist of mixing steelmaking slag at 1350-1450 ° C and firing it for at least 1 hour.

Description

고로슬래그, 제강슬래그 및 석회석 부산물을 이용한 포틀랜드 시멘트 클링커의 제조방법Manufacturing Method of Portland Cement Clinker Using Blast Furnace Slag, Steelmaking Slag and Limestone By-Products

본 발명은 포틀랜드 시멘트 클링커의 제조방법에 관한 것으로, 보다 상세하게는 제철소에서 발생하는 부산물인 고로슬래그, 제강슬래그 및 석회석 소성로 더스트를 활용하여 포틀랜드 시멘트 클링커를 제조하는 방법에 관한 것이다. 주성분으로 CaO, SiO2, A12O3, Fe2O3를 포함하며 무기물 결합재인 시멘트는 건축,토목용 졀합재의 대표적인 것으로, 이중에서 포틀랜드 시멘트는 가장 많이 생산되고 소비되는 시멘트이다. 일반적으로 시멘트는 원료를 소정의 배합비로 혼합하여 분쇄한 후 소성로에 투입하여 클링커를 만들고, 이것을 석고와 함께 혼합, 미분쇄하는 공정을 거쳐 제조된다. 포틀랜드 시멘트도 상기와 같은 공정을 거치는 것으로, 통상 하기표 1과 같은 화학성분을 갖는다.The present invention relates to a method for producing a portland cement clinker, and more particularly, to a method for manufacturing a portland cement clinker using blast furnace slag, steelmaking slag and limestone kiln dust, which are by-products generated in steel mills. Cement, which is composed of CaO, SiO 2 , A1 2 O 3 , Fe 2 O 3 as its main component and is an inorganic binder, is a representative of the composite material for building and civil engineering. Of these, Portland cement is the most produced and consumed cement. In general, the cement is prepared by mixing the raw materials in a predetermined compounding ratio, pulverizing and then putting them in a sintering furnace to make a clinker, mixing them with gypsum and pulverizing them. Portland cement is also subjected to the same process as above, and usually has the chemical composition shown in Table 1 below.

상기한 바와같이 시멘트는 석회, 실리카, 알루미나, 산화철 등 4가지 주 성분으로 구성된 소재이다. 따라서, 시멘트 원료로서의 조건은 4가지 주요성분을 함유하면서 분쇄 및 소성이 용이하고 성분변동이 적으면서 값싸게 구할 수 있어야 한다. 일반적으로 사용하는 성분별 가용원료는 석회질, 점토질, 규산질 및 산화철 원료등이 있다. 이중에서 시멘트 원료 중 약 90%를 차지하는 원료로서 석회석이 이용되고 있고, 시멘트 원료로서의 품위는 보통 CaC03기준으로 85% 정도이다. 석회질 원료에서 공급된 CaO 이외의 산성 산화물 성분인 SiO2, Al2O3, Fe2O3를 공급하는 원료로서 점토(Clay)와 guf암(Shale)등이 이용되고 있으며, 석회석 및 점토질 원료에서 충족되지 못한 SiO2와 Fe2O3를 공급하기 위해 규석, 규사 및 철광석, 제강슬래그등이 이용되고 있다. 이와같이 시멘트를 제조하기 위해서는 많은 원료들이 필요하며, 특히 주원료인 석회석은 많은 양의 공급이 필요한 실정이다. 또한, 상기 점토 등의 광물들은 산지마다 그 조성의 변화폭이 크다. 한편, 제철소에서 발생되는 부산물들은 다른 산업활동에 재사용되기도 하지만 많은양은 매립 등에 의해 처리되고 있는 실정이다. 이와같은 처리는 환경오염을 야기시키는 문점을 가지고 있다.As described above, cement is a material composed of four main components: lime, silica, alumina, and iron oxide. Therefore, the condition as a cement raw material should be able to be obtained inexpensively while containing four main components, easy to pulverize and fire, and have small component variations. Commonly available soluble raw materials for each ingredient include lime, clay, siliceous and iron oxide raw materials. Limestone is used as a raw material which occupies about 90% of cement raw materials, and the grade as cement raw material is about 85% based on CaC0 3 standard. An acidic oxide components other than the CaO feed from the calcareous materials SiO 2, Al 2 O 3, as a starting material for supplying the Fe 2 O 3 clay (Clay) and guf cancer (Shale) which is being used and so on, in the limestone and clay material To supply unsatisfied SiO 2 and Fe 2 O 3 , silica, silica and iron ore and steel slag are used. As such, many raw materials are needed to manufacture cement, and limestone, which is a main raw material, needs to be supplied in large amounts. In addition, minerals such as clay have a large variation in composition of each mountain area. On the other hand, by-products generated in steel mills are reused for other industrial activities, but a large amount is being disposed of by landfilling. Such treatment has the problem of causing environmental pollution.

본 발명은 포틀랜드 시멘트 클링커를 제조하기 위한 것으로, 본 발명은 화학조성의 변화폭이 적은 고로슬래그, 제강슬래그 및 석회석 소성로 더스트를 포틀랜드 시멘트 클링커의 원료로 사용함으로써, 시멘트 클링커 제조공정상 원료투입의 관리를 용이하게 하고, 시멘트 원료의 90%이상을 차지하는 석회석의 사용을 줄이고, 환경오염물질을 저감시키고자 하는데, 그 목적이 있다.The present invention is to manufacture a portland cement clinker, the present invention is easy to manage the input of raw materials in the cement clinker manufacturing process by using the blast furnace slag, steelmaking slag and limestone kiln dust as a raw material of the portland cement clinker with a small change in chemical composition The purpose is to reduce the use of limestone, which accounts for more than 90% of cement raw materials, and to reduce environmental pollutants.

도 1은 일반 포틀랜드 시멘트의 X선 회절분석 결과를 나타낸 그래프1 is a graph showing the results of X-ray diffraction analysis of general Portland cement

도 2 (a∼c)는 본 발명에 의해 제소한 시멘트 클링커의 X선 회절분석 결과를 나타낸 그래프Figure 2 (a to c) is a graph showing the results of X-ray diffraction analysis of the cement clinker filed by the present invention

본 발명은 포틀랜드 시멘트 클링커를 제조하는 방법에 있어서, 단독 또는 복합으로 첨가되는 석회석 소성로 더스트와 석회석슬러지 50-55중량%,40-45중량%의 고로 슬래그 및 5중량%이하의 제강슬래그를 혼합하여 1350-1450℃의 온도범위에서 1시간이상 소성하는 고로슬래그, 제강슬래그 및 석회석 부산물을 이용한 포틀랜드 시멘트 클링커의 제조방법에 관한 것이다. 이하, 본 발명을 보다 상세히 설명한다. 본 발명은 SiO2, 및 A12O3원으로 고로슬래그를 사용하고, Fe2O3및 CaO 원으로써 제강슬래그를 사용하고, 부족분의 CaO를 보충하기 위해 제철공정에서 발생하는 석회석부산물인 석회석 소성로 더스트 및 석회석슬러지 등을 활용하여 포틀랜드 시멘트 클링커를 제조하는 것이다. 본 발명에서는 SiO2및 A12O3의 주공급원으로 사용되는 고로슬래그를 40-45중량%의 함량으로 첨가한다. 상기 첨가범위를 벗어날 경우, 상기 SiO2및 A12O3의 함량이 포틀랜드 시멘트 클링커의 함량범위를 벗어나기 때문이다. 또한, 본 발명에서는 Fe2O 및 CaO의 주공급원으로 사용되는 제강슬래그를 5중량%이하의 함량으로 첨가한다. 상기 제강슬래그의 함량이 5중량%를 초과하면 Fe2O3의 함량이 포틀랜드 시멘트 클링커의 기준함량범위를 벗어나기 때문이다. 또한, 본 발명에서는 석회석 소성로 더스트와 석회석 슬리지를 단독 또는 복합첨가 하는데, 그 함량을 50∼55중량%로 한정한다. 상기 석회석소성로 더스트 및 석회석 슬러지는 CaO의 공급원으로써, 상기 고로 슬래그 및 제강슬래그에 의한 CaO의 공급을 보충해 주기 위한 것이다. 상기와 같은 함량으로 혼합된 원료는 1350-1450℃의 온도범위에서 1시간 이상 소성하는 과정을 거친다. 상기 소성온도가 1350℃미만인 경우에는 소결이 충분히 되지 않고,1450℃를 초과하는 경우에는 혼합된 원료들이 녹기 때문이다. 또한, 상기 소성을 1시간 미만으로 행하면 소결이 불충분하기 때문에 소성은 1시간이상 행한다. 이하, 실시예를 통하여 본 발명을 보다 상세히 설명한다.The present invention is a method for manufacturing a portland cement clinker, by mixing the limestone kiln dust and limestone sludge 50-55% by weight, 40-45% by weight of blast furnace slag and less than 5% by weight of steelmaking slag The present invention relates to a method for producing a Portland cement clinker using blast furnace slag, steelmaking slag and limestone by-products fired at a temperature range of 1350-1450 ° C. for at least 1 hour. Hereinafter, the present invention will be described in more detail. The present invention uses blast furnace slag as SiO 2 , and A1 2 O 3 source, using steelmaking slag as Fe 2 O 3 and CaO source, and limestone by-product which is a limestone by-product generated in steelmaking process to supplement the shortage of CaO. Portland cement clinker is manufactured using dust and limestone sludge. In the present invention, the blast furnace slag used as the main source of SiO 2 and A1 2 O 3 is added in an amount of 40 to 45% by weight. It is because the content of the SiO 2 and A1 2 O 3 is out of the content range of the Portland cement clinker. In addition, in the present invention, the steelmaking slag used as the main source of Fe 2 O and CaO is added in an amount of 5% by weight or less. If the content of the steelmaking slag exceeds 5% by weight because the content of Fe 2 O 3 is out of the standard content range of the Portland cement clinker. In addition, in the present invention, the limestone kiln dust and the limestone sludge are added alone or in combination, and the content thereof is limited to 50 to 55% by weight. The lime-calcinary furnace dust and limestone sludge are intended to supplement the supply of CaO by the blast furnace slag and steelmaking slag as a source of CaO. The raw materials mixed with the above content are subjected to baking for 1 hour or more in a temperature range of 1350-1450 ° C. If the firing temperature is less than 1350 ℃ sintering is not enough, if it exceeds 1450 ℃ mixed raw materials are melted. In addition, if the sintering is performed in less than 1 hour, the sintering is insufficient, so the firing is performed for 1 hour or more. Hereinafter, the present invention will be described in more detail with reference to Examples.

[실시예]EXAMPLE

하기표 2와 같은 성분을 함유하는 고로슬래그, 제강슬래그 및 석회석 소성로 더스트를 준비하였다. 준비된 원료들을 하기표 3과 같은 배합비로 배합한후 충분히 혼합하였다. 혼합후 1400℃에서 3시간 동안 소성하여 시멘트 클링커를 제조하였다.Blast furnace slag, steelmaking slag and limestone calcining furnace dust containing the components shown in Table 2 were prepared. The prepared raw materials were blended in a compounding ratio as shown in Table 3 and then sufficiently mixed. After mixing and baking for 3 hours at 1400 ℃ to prepare a cement clinker.

제조된 발명재(1-3)의 클링커를 분쇄하여 325mesh이하의 분말로 만든후, 포틀랜드시멘트 및 상기 분말에 대해 X선 회절분석을 실시하였다. 그리고, 포틀랜드 시멘트 분석결과를 도 1에 나타내었고, 발명재(1-3)의 분석결과를 도 2에 나타내었다. 도 2 의 (a)는 발명재(1),(b)는 발명재(2),(c)는발명재(3)의 분석결과이다. 도 1과도 2(a-c)에 나타난 바와같이, 제철소 부산물만으로 제조된 시멘트 클링커(발명재 1∼3)와 일반 포틀랜드 시멘트 구성광물상에 대한 X선회절피크는 거의 일치하며, 주 구성광물상은 알릿트, 베릿트, 세릿트, 알루민산 3칼슘임을 알 수있었다. 상기 발명재(1-3)의 화학성분 분석을 실시하고 그 결과를 하기표 4에 나타내였다.The clinker of the prepared inventive material (1-3) was pulverized to a powder of 325 mesh or less, and then subjected to X-ray diffraction analysis on the Portland cement and the powder. The Portland cement analysis results are shown in FIG. 1, and the analysis results of the inventive material (1-3) are shown in FIG. 2. (A) of FIG. 2 is invention material (1), (b) is invention material (2), (c) is analysis result of invention material (3). As shown in Figure 1 and 2 (ac), the X-ray diffraction peaks for the cement clinker (inventive materials 1 to 3) and the general Portland cement component mineral phase produced only by steel mill by-products, the main component mineral phase is Alt, It could be seen that it is berit, serit and tricalcium aluminate. The chemical composition analysis of the said invention material (1-3) was performed, and the result is shown in following Table 4.

상기 표 4에서 알수 있는 바와 같이, 본 발명에 의한 발명재(1-3)은 일반 포틀랜드 시멘트의 화학조성 범위 영역내에 포함되어 있였다.As can be seen from Table 4, the inventive material (1-3) according to the present invention was included in the chemical composition range of general Portland cement.

상기한 바와같이 본 발명에서는 시멘트 소성원료로서 제철소 폐기물만을 활용하여 포틀랜드 시멘트를 제조할수 있였으며, 본 발명이 실용화 될 경우 제철소 폐기물을대량 활용하여 환경부담을 줄일 수 있고 원료비용의 대폭절감, 시멘트 클링커 분말제품의 장거리 수송에 따른 물류비 개선, 석회석 자원의 사용량 저감 등의 효과가기대된다.As described above, in the present invention, Portland cement can be manufactured using only steel mill waste as a cement firing material, and when the present invention is put to practical use, it can reduce environmental burden by using large amount of steel mill waste and greatly reduce raw material cost, cement clinker. It is expected to improve logistics costs and reduce the use of limestone resources due to long-distance transportation of powder products.

Claims (1)

포틀랜드 시멘트 클링커를 제조하는 방법에 있어서, 단독 또는 복합으로 첨가되는 석회석 소성로더스트와 석회석 슬러리 50-55중량%, 40-45중량%의 고로 슬래그 및 5중량% 이하의 제강슬래그를 혼합하여 1350-1450℃의온도범위에서 1시간 이상 소성하는 것을 특징으로 하는 고로슬래그, 제강슬래그 및 석회석 소성로더스트를 이용한 포틀랜드 시멘트 클링커의 제조방법In the method for producing a Portland cement clinker, 1350-1450 by mixing 50-55% by weight of limestone baking furnace, 40-45% by weight of blast furnace slag and 5% by weight of steel slag added alone or in combination Process for producing Portland cement clinker using blast furnace slag, steelmaking slag and limestone firing furnace, characterized in that firing for more than 1 hour in the temperature range of ℃
KR1019960070076A 1996-12-23 1996-12-23 The method of portland cement clinker KR100270094B1 (en)

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KR100313709B1 (en) * 1999-09-03 2001-11-15 김형석 Process for producing cement clinker using ironworks slag
KR100609136B1 (en) * 2000-12-21 2006-08-04 재단법인 포항산업과학연구원 A method for manufacturing solidification brick
KR100896591B1 (en) * 2002-12-24 2009-05-07 주식회사 포스코 A method for manufacturing solidification brick
WO2009142349A1 (en) * 2008-05-21 2009-11-26 Hi-Dong Shin Inorganic cement clinker, its preparation and inorganic cement comprising the clinker

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KR101088183B1 (en) * 2009-03-11 2011-12-30 (주)세와비전 Synthetic method of portland cement by using the heat and elements of the fused blast furnace slag and portland cement manufactured with this
KR101111277B1 (en) * 2009-11-13 2012-03-13 한국지질자원연구원 Method for manufacturing portland cement using tailing of mineral dressing and portland cement manufactured with this
KR102528110B1 (en) 2022-11-28 2023-05-02 한국세라믹기술원 Clinker composition containing non-carbonate materials

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100313709B1 (en) * 1999-09-03 2001-11-15 김형석 Process for producing cement clinker using ironworks slag
KR100609136B1 (en) * 2000-12-21 2006-08-04 재단법인 포항산업과학연구원 A method for manufacturing solidification brick
KR100896591B1 (en) * 2002-12-24 2009-05-07 주식회사 포스코 A method for manufacturing solidification brick
WO2009142349A1 (en) * 2008-05-21 2009-11-26 Hi-Dong Shin Inorganic cement clinker, its preparation and inorganic cement comprising the clinker
KR100932590B1 (en) 2008-05-21 2009-12-21 신희동 Inorganic cement clinker using slag of high temperature molten state and its manufacturing method and inorganic cement containing the clinker

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