KR19980028580A - Rubber gloves with excellent antibacterial and cosmetic effects and preparation method thereof - Google Patents
Rubber gloves with excellent antibacterial and cosmetic effects and preparation method thereof Download PDFInfo
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- KR19980028580A KR19980028580A KR1019960047689A KR19960047689A KR19980028580A KR 19980028580 A KR19980028580 A KR 19980028580A KR 1019960047689 A KR1019960047689 A KR 1019960047689A KR 19960047689 A KR19960047689 A KR 19960047689A KR 19980028580 A KR19980028580 A KR 19980028580A
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- chitosan
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Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/08—Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0064—Producing wearing apparel
- B29D99/0067—Gloves
Abstract
본 발명은 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물이 첨가된 라텍스(Latex) 용액등의 원료수지액에 몰드(mold)를 디핑(dipping) 또는 코팅(coating)하여 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물이 균일하게 분포되거나 특정부위에만 분포되도륵 제조한 고무장갑 및 이의 제조방법에 관한 것으로, 고무장갑의 제조시 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물을 원료수지액에 대하여 각각 0.1∼2wt% 첨가하여 고무장갑을 제조하므로서 항균 및 미용효과가 우수하여 장기간 착용하더라도 피부질환의 유발이 없고, 착용감이 좋으며, 강도의 저하가 없는 고무장갑을 용이하게 얻을 수 있는 효과가 있다.The present invention dipping or coating a mold in a raw resin solution such as a chitosan or chitosan solution and seaweed powder or a latex solution to which the extract is added, thereby producing a chitosan or chitosan solution and seaweed powder or The present invention relates to a rubber glove prepared evenly or evenly distributed to a specific part of the extract, and to a method for manufacturing the rubber glove, wherein the chitosan or chitosan solution and seaweed powder or extract thereof is 0.1 to 2wt, respectively. Since the rubber gloves are manufactured by adding%, the antibacterial and cosmetic effects are excellent, and even when worn for a long time, there is no effect of causing skin diseases, a comfortable fit, and the rubber gloves without deterioration of strength are easily obtained.
Description
본 발명은 항균 및 미용효과가 우수한 고무장갑 및 이의 제조방법에 관한 것으로, 좀 더 구제적으로는 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물이 첨가된 라텍스(Latex) 용액등의 원료수지액에 몰드(mold)를 디핑(dipping) 또는 코팅(coating)하여 키트산 또는 키토산용액 및 해조류 분말또는 그 추출물이 균일하게 분포되거나 특정부위에만 분포되도록 제조한 고무장갑 및 이의 제조방법에 관한 것이다.코팅(coating)하여 성형한 다음, 건조하고 몰드에서 분리한 후, 후처리하여 제조된다.The present invention relates to a rubber glove excellent in antibacterial and cosmetic effects and a method for manufacturing the same, and more specifically, to a raw resin solution such as a latex (Latex) solution containing chitosan or chitosan solution and seaweed powder or extracts thereof. It relates to a rubber glove prepared by dipping or coating (mold) so that the kit acid or chitosan solution and the seaweed powder or its extracts are uniformly distributed or distributed only in specific areas. Molded, dried, separated from the mold, and then worked up.
한편, 키토산(chitosan)은 키틴을 탈아세틸화한 물질이며, β -(1→4)-2-아세트아미드-2-데옥시-D-글루코오즈 잔기의 비분자쇄로 구성된 것으로 셀룰로오즈와 유사한 구조를 가지고 있고, 무척추해양동물, 곤충 및 새우나 게등의 갑각류의 외골격에서 발견되고 있는 물질이며, 화장품의 흡습과 보수제, 의약품에서 항암제, 기능성 식품첨가물등으로 사용되고 있고, 그 사용용도가 급속도로 확산되고 있다.On the other hand, chitosan (chitosan) is a substance deacetylated chitin, composed of a non-molecular chain of β- (1 → 4) -2-acetamide-2-deoxy-D-glucose residue, similar to cellulose It is a substance found in the exoskeleton of crustaceans such as invertebrates, marine animals, insects, shrimps and crabs, and is used as a hygroscopic and repair agent for cosmetics, as an anticancer agent, and a functional food additive in medicines. have.
일반적으로 갑각류로 부터 얻어지는 키틴이 α-키틴이고, 무척추 해양동물로 부터 얻어지는 키틴이 β-키틴이다. 키틴은 물이나 다른 용제에 불용인 반면에 키토산은 여러가지 산성용매, 예를 들어 개미산이나 아세트산에 용해되므로 키틴보다 산업적으로 더욱 많이 응용되고 있다.In general, chitin obtained from crustaceans is α-chitin, and chitin obtained from invertebrate marine animals is β-chitin. Chitin is insoluble in water and other solvents, while chitosan is soluble in various acidic solvents, such as formic acid or acetic acid, so it is more industrially applied than chitin.
또한, 미역, 다시마등의 해조류는 예로부터 식용으로 널리 사용되어 왔지만, 요즈음에는 피부미용에도 탁월한 효과가 있는 것으로 알려지면서 화장품의 첨가제, 건강식품의 윈료 및 다이어트식품등으로 각광을 받고있다.In addition, seaweeds such as seaweed and kelp have been widely used for food for a long time, but nowadays, it is known to have an excellent effect on skin beauty, and has been spotlighted as an additive of cosmetics, a wintry of health food, and a diet food.
그러나, 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물의 용도개발이 미미한 실정이다.However, the development of the use of chitosan or chitosan solution and seaweed powder or its extract is insignificant.
따라서, 본 발명의 목적은 항균 및 미용효과가 우수하여 장기간 착용하더라도 피부질환의 유발이 없고, 착용시 촉감이 좋은 고무장갑을 제공하는 데 있다.Accordingly, an object of the present invention is to provide a rubber glove that is excellent in antibacterial and cosmetic effects and does not cause skin diseases even when worn for a long time, and feels well when worn.
도 1은 본 발명 고무장갑의 제조공정도이다.1 is a manufacturing process of the rubber glove of the present invention.
본 발명을 좀 더 구체적으로 설명하면 다음과 같다.원료수지액에 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물을 첨가하고, 이에 수세하고 염수처리하여 건조시킨 몰드를 디핑 또는 코팅하여 성형한 다음, 건조하고 몰드에서 분리한 후, 후처리하므로서 제조된다.키토산은 약산 또는 산성용액에는 용해되지만, 알칼리용액에서는 용해되지 않으며, 고무장갑 제조용 원료수지액은 알칼리 용액이므로 키토산이 용해되지 않아 키토산을 원료수지액에 혼합하기 위해서는 다음의 2가지 방법을 사용하여야 한다.The present invention will be described in more detail as follows. Chitosan or chitosan solution and seaweed powder or extracts thereof are added to the raw resin solution, and the mold is dried by washing with brine and dried by molding, then dried. The chitosan is dissolved in a weak acid or acidic solution, but not in an alkaline solution, and the chitosan for rubber gloves is an alkaline solution. The following two methods should be used for mixing.
일반적으로 고무장갑은 크게 두가지 방법으로 제조된다. 즉, 고무장갑 제조용 원료수지액에 몰드를 1회만 디핑 또는 코팅하여 제조되는 한겹제품과 2회에 걸쳐 디핑 또는 코팅하는 두겹제품으로 대별된다. 본 발명을 적용함에 있어서, 한겹제품의 경우에는 원료수지액에 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물을 첨가하므로서 용이하게 달성될 수 있고, 두겹 제품의 경우에는 손의 피부에 접촉되는 부분에만 키토산 또는 키토산용액 및 해조류 분말 또는 그추출물이 첨가되면 되므로 두번째 디핑 또는 코팅시 사용하는 원료수지액에만 키토산 또는 키토산용액 및 해조류 분말 또는 그추출물을 첨가하므로서 고무장갑의 강도를 최대한 유지하면서 항균효과 및 미용효과를 얻을 수 있었다.원료수지액에 요구되는 물성에 따라 여러가지 첨가제를 첨가할 수 있음은, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자이면 용이하게 유추가능하다.Generally, rubber gloves are manufactured in two ways. That is, it is roughly divided into a one-ply product manufactured by dipping or coating a mold only once in a raw material resin for manufacturing rubber gloves and a two-ply product that is dipped or coated twice. In applying the present invention, in the case of a one-ply product, it can be easily achieved by adding chitosan or chitosan solution and seaweed powder or extract thereof to the raw resin solution, and in the case of a double-ply product, only chitosan is in contact with the skin of the hand. Alternatively, chitosan solution and algae powder or its extracts may be added, so adding chitosan or chitosan solution and algae powder or its extract to the raw resin solution used for the second dipping or coating, maintains the strength of the rubber gloves to the maximum while maintaining antibacterial and cosmetic effects Various additives can be added according to the physical properties required for the raw material resin liquid, which can be easily inferred by those skilled in the art.
다음의 실시예 및 비교예는 본 발명을 좀 더 상세히 설명하는 것이지만, 본 발명의 범주를 한정하는 것은 아니다.The following examples and comparative examples illustrate the invention in more detail, but do not limit the scope of the invention.
손모양의 몰드를 수세하여 이물질을 제거한 다음, 염수로 재차 세척하고 건조하여 몰드를 준비한다.이었다.Hand molds were washed with water to remove foreign substances, and then washed again with brine and dried to prepare a mold.
키토산의 탈아세틸화도가 각각 90%, 65%인 것을 사용한 것을 제외하고 실시예 1과 동일한 방법으로 고무장갑을 제조하고, 항균성을 평가하여 그 결과를 표 1에 기재하였다. Rubber gloves were prepared in the same manner as in Example 1 except that the deacetylation degrees of chitosan were 90% and 65%, respectively, and the antibacterial properties were evaluated and the results are shown in Table 1.
(실시예 3)(Example 3)
키토산 또는 키토산용액 및 해조류 분말 또는 그추출물의 첨가량을 각각 0.5wt% 및 5wt%로 한 것올 제외하고는 실시예 3과 동일한 방법으로 고무장갑을 제조하고, 실시예 3과 동일한 방법으로 인장하중을 측정하여 그 결과를 표 2에 기재하였다.A rubber glove was prepared in the same manner as in Example 3, except that the amount of chitosan or chitosan solution and the algae powder or its extract was 0.5wt% and 5wt%, respectively, and the tensile load was measured in the same manner as in Example 3. The results are shown in Table 2.
표 2. 인장하중 Table 2. Tensile Load
상기 표 1 및 표 2로 부터 알 수 있는 바와 같이, 고무장갑에 첨가하는 키토산은 탈아세틸화도가 80%이상인 것이 항균효과에 있어서 바람직하며, 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물의 첨가량이 원료수지액에 대하여 5wt%이상인 경우에는 인장하중이 현저히 떨어져서 KSM6633의 규격이하가 되므로 바람직하지 못하였다.As can be seen from Table 1 and Table 2, the chitosan added to the rubber gloves is preferably deacetylation degree of 80% or more in the antibacterial effect, chitosan or chitosan solution and seaweed powder or the amount of the extract is added to the raw material In the case of 5wt% or more with respect to the resin solution, the tensile load was remarkably dropped, which was less than the specification of KSM6633.
고무장갑의 제조시 키토산 또는 키토산용액 및 해조류 분말 또는 그 추출물을 원료수지액에 대하여 0.1∼2wt% 첨가하여, 고무장갑을 제조하므로서 항균 및 미용효과가 우수하여 장기간 착용하더라도 피부질환의 유발이 없고 착용감이 좋으며, 강도의 저하가 없는 고무장갑을 용이하게 얻을 수 있는 효과가 있다.When manufacturing rubber gloves, 0.1 ~ 2wt% of chitosan or chitosan solution and seaweed powder or its extract is added to the raw resin solution.The rubber gloves are manufactured, so the antibacterial and cosmetic effects are excellent. This is good, and there is an effect that the rubber gloves can be easily obtained without a decrease in strength.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960047689A KR100186936B1 (en) | 1996-10-23 | 1996-10-23 | The superior rubber gloves for antibiotic and the effect of a beautiful face and the method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960047689A KR100186936B1 (en) | 1996-10-23 | 1996-10-23 | The superior rubber gloves for antibiotic and the effect of a beautiful face and the method thereof |
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| Publication Number | Publication Date |
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| KR19980028580A true KR19980028580A (en) | 1998-07-15 |
| KR100186936B1 KR100186936B1 (en) | 1999-05-01 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990037816A (en) * | 1999-01-27 | 1999-05-25 | 김정삼 | Rubber Gloves Containing Ground Loess |
| KR100429310B1 (en) * | 2001-05-21 | 2004-05-03 | 주식회사 마이다스 | manufacturing method for coating glove and thereby coating glove |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3546220B1 (en) * | 2003-10-30 | 2004-07-21 | 有限会社パンメディカ | Itching inflammation alleviating glove and method for producing the same |
| KR100665719B1 (en) | 2005-03-19 | 2007-01-09 | 이기율 | Method for produce of Rubber gloves contain Nano silver |
| KR20160120884A (en) | 2015-04-09 | 2016-10-19 | 주식회사 곰표산업 | Functional rubber gloves |
-
1996
- 1996-10-23 KR KR1019960047689A patent/KR100186936B1/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990037816A (en) * | 1999-01-27 | 1999-05-25 | 김정삼 | Rubber Gloves Containing Ground Loess |
| KR100429310B1 (en) * | 2001-05-21 | 2004-05-03 | 주식회사 마이다스 | manufacturing method for coating glove and thereby coating glove |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100186936B1 (en) | 1999-05-01 |
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