KR102636963B1 - Coating composition for tire - Google Patents

Coating composition for tire Download PDF

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KR102636963B1
KR102636963B1 KR1020230085663A KR20230085663A KR102636963B1 KR 102636963 B1 KR102636963 B1 KR 102636963B1 KR 1020230085663 A KR1020230085663 A KR 1020230085663A KR 20230085663 A KR20230085663 A KR 20230085663A KR 102636963 B1 KR102636963 B1 KR 102636963B1
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weight
parts
coating composition
tire
tires
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KR1020230085663A
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Korean (ko)
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정일모
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주식회사 제이두홀딩스
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

본 기술은 타이어의 내구성과 은폐력이 향상된 타이어용 코팅제 조성물에 관한 것으로, 더욱 상세하게는 타이어용 코팅제 조성물에 있어서, 상기 코팅제 100 중량부에 대하여, 용매제 61 중량부와, 비이온계열 계면활성제 3 중량부, 중합체 36 중량부가 혼합되도록 포함하는 것을 특징으로 한다.This technology relates to a coating composition for tires with improved durability and hiding power of tires. More specifically, the coating composition for tires includes 61 parts by weight of a solvent and 3 parts by weight of a nonionic surfactant based on 100 parts by weight of the coating agent. parts by weight, and 36 parts by weight of polymer are mixed.

Description

타이어용 코팅제 조성물{Coating composition for tire}Coating composition for tires {Coating composition for tire}

본 기술은 타이어의 내구성과 은폐력이 향상된 타이어용 코팅제 조성물에 관한 것이다.This technology relates to a coating composition for tires with improved tire durability and hiding power.

종래 타이어는 차량에 장착되어 사용되기 전까지 보관 기간이 증가하게 되면, 타이어에 포함되어 있는 산화방지제 및 왁스 성분 등의 첨가제가 타이어 표면부위로 이동하여 타이어의 외관 품질을 손상시킴으로써 상품성을 저하시키는 문제점이 있었다.As the storage period for conventional tires increases before being mounted on a vehicle and used, additives such as antioxidants and wax components contained in the tire move to the surface of the tire, damaging the exterior quality of the tire, thereby reducing marketability. there was.

전술한 문제점을 해결하기 위해 보관 중인 타이어 표면에는 코팅제를 코팅하여 보관하는데, 종래 타이어 코팅제는 고분자 물질 또는 왁스류를 바인더로 사용하고, 이러한 성분들을 용매에 녹인 유성 타입이 주로 사용되었다.In order to solve the above-mentioned problem, the surface of the tire being stored is coated with a coating agent. Conventional tire coating agents mainly use polymer substances or waxes as binders and are of the oil-based type in which these ingredients are dissolved in a solvent.

또한, 코팅제의 은폐력과 외관 향상을 위해 카본블랙 등을 충전재로 사용하고 있으나, 전술한 카본블랙은 바인더 성분의 함량보다 많은 과량을 첨가해야 우수한 은폐력이 얻어지고, 타이어 코팅제의 외관을 향상시킬 수 있는데, 카본블랙이 과량 첨가된 타이어 코팅제로 형성된 타이어 코팅막은 내구성이 취약한 문제점이 있었다.In addition, carbon black is used as a filler to improve the hiding power and appearance of the coating agent, but the carbon black described above must be added in excess of the content of the binder component to obtain excellent hiding power and improve the appearance of the tire coating agent. , Tire coating films formed from tire coatings containing excessive amounts of carbon black had a problem of poor durability.

국내등록특허 제1157121호(공고일: 2012. 6. 22.)Domestic registered patent No. 1157121 (announcement date: June 22, 2012) 국내공개특허 제2007-59150호(공개일: 2007. 6. 11.)Domestic Publication Patent No. 2007-59150 (Publication date: June 11, 2007) 국내등록특허 제934567호(공고일: 2009. 12. 30.)Domestic registered patent No. 934567 (announcement date: December 30, 2009) 국내등록특허 제781591호(공고일: 2007. 12. 3.)Domestic registered patent No. 781591 (announcement date: December 3, 2007)

상술한 종래의 문제점을 해결하기 위해 본 발명은 우수한 내구성, 은폐력 및 외관을 갖는 타이어 코팅제 조성물을 제공하고자 하는데 목적이 있다.In order to solve the above-described conventional problems, the purpose of the present invention is to provide a tire coating composition with excellent durability, hiding power, and appearance.

상기한 종래의 문제점을 해결하기 위한 과제의 해결 수단으로 본 발명에 따른 타이어용 코팅제 조성물은 타이어용 코팅제 조성물에 있어서, 상기 코팅제 100 중량부에 대하여, 용매제 61 중량부와, 비이온계열 계면활성제 3 중량부, 중합체 36 중량부가 혼합되도록 포함하는 것을 특징으로 한다.As a means of solving the problem of solving the above-described conventional problems, the coating composition for tires according to the present invention is a coating composition for tires, comprising 61 parts by weight of a solvent and a non-ionic surfactant based on 100 parts by weight of the coating agent. It is characterized in that 3 parts by weight and 36 parts by weight of polymer are mixed.

또한, 상기 용매제는 정제수 55 중량부, 벤조산 나트륨 1 중량부 및 에탄올 5 중량부가 혼합되는 것이 바람직하다.In addition, the solvent is preferably a mixture of 55 parts by weight of purified water, 1 part by weight of sodium benzoate, and 5 parts by weight of ethanol.

또한, 상기 비이온계열 계면활성제는 폴리에틸렌 글리콜 트리데실 에테르인 것이 바람직하다.Additionally, the nonionic surfactant is preferably polyethylene glycol tridecyl ether.

또한, 상기 중합체는 폴리다이메틸실록산 33 중량부, 데카메칠사이클로펜타실록산 1 중량부, 옥타메칠사이클로테트라실록산 1 중량부 및 실리콘 1 중량부를 혼합하되, 상기 중합체는 실리콘 이외에 트리메톡시메틸실란 터미네이티드 하이드록시 실록산인 것이 바람직하다.In addition, the polymer is a mixture of 33 parts by weight of polydimethylsiloxane, 1 part by weight of decamethylcyclopentasiloxane, 1 part by weight of octamethylcyclotetrasiloxane, and 1 part by weight of silicone, and the polymer is a mixture of trimethoxymethylsilane terminator in addition to silicone. Tid hydroxy siloxane is preferred.

본 발명에 따르면, 종래와는 차별적으로 우수한 내구성, 타이어 표면에 용이하게 도포되어 퍼질 수 있는 은폐력 및 외관을 갖는 타이어 코팅제 조성물을 제공할 수 있는 효과를 갖게 된다.According to the present invention, it is possible to provide a tire coating composition that has excellent durability, a hiding power that can be easily applied and spread on the tire surface, and an appearance that is different from the conventional one.

이하에서는 첨부된 도면을 참조하여 다양한 실시예를 보다 상세하게 설명한다. 본 명세서에 기재된 실시예는 다양하게 변형될 수 있다. 특정한 실시예가 도면에서 묘사되고 상세한 설명에서 자세하게 설명될 수 있다. 그러나 첨부된 도면에 개시된 특정한 실시예는 다양한 실시예를 쉽게 이해하도록 하기 위한 것일 뿐이다. 따라서 첨부된 도면에 개시된 특정 실시예에 의해 기술적 사상이 제한되는 것은 아니며, 발명의 사상 및 기술 범위에 포함되는 모든 균등물 또는 대체물을 포함하는 것으로 이해되어야 한다.Hereinafter, various embodiments will be described in more detail with reference to the attached drawings. The embodiments described herein may be modified in various ways. Specific embodiments may be depicted in the drawings and described in detail in the detailed description. However, the specific embodiments disclosed in the attached drawings are only intended to facilitate understanding of the various embodiments. Accordingly, the technical idea is not limited to the specific embodiments disclosed in the attached drawings, and should be understood to include all equivalents or substitutes included in the spirit and technical scope of the invention.

본 발명에 따른 타이어 코팅제를 획득하기 위한 조성물은 용매제, 계면활성제, 중합체 및 펄재료를 포함하여 이루어지고, 바람직하게는 상기 코팅제 100 중량부에 대하여, 상기 용매제 61 중량부와, 상기 계면활성제 3 중량부, 중합체 36 중량부 및 나노 단위의 입자를 갖는 분말 형태의 펄재료가 혼합된다.The composition for obtaining the tire coating agent according to the present invention includes a solvent, a surfactant, a polymer and a pearl material, preferably 61 parts by weight of the solvent and the surfactant based on 100 parts by weight of the coating agent. 3 parts by weight of polymer, 36 parts by weight of polymer and pearl material in powder form with nano-scale particles are mixed.

예컨대 용매제는 코팅제를 제조시 혼합 성능이 향상될 수 있게 사용되는 액상의 물질을 의미하고, 본 발명에서의 용매제는 정제수, 벤조산 나트륨 및 에탄올의 혼합으로 이루어질 수 있다.For example, a solvent refers to a liquid substance used to improve mixing performance when manufacturing a coating agent, and the solvent in the present invention may be a mixture of purified water, sodium benzoate, and ethanol.

여기서, 용매제의 바람직한 혼합은 정제수 55 중량부, 벤조산 나트륨 1 중량부 및 알코올계 분산매로서의 에탄올 5 중량부가 첨가되어 혼합될 수 있도록 한다.Here, the preferred mixture of solvents is to add and mix 55 parts by weight of purified water, 1 part by weight of sodium benzoate, and 5 parts by weight of ethanol as an alcohol-based dispersion medium.

벤조산 나트륨(Sodium benzoate)은 획득하고자 하는 코팅제에 대한 방부제의 기능은 물론, 다수의 조성물이 혼합되는 반응 과정에서 소모되거나 변하지 않으면서 반응 속도를 빠르게 만드는 촉진제의 기능을 함께 수행할 수 있도록 한다.Sodium benzoate not only functions as a preservative for the coating to be obtained, but also functions as an accelerator that speeds up the reaction rate without being consumed or changed during the reaction process in which multiple compositions are mixed.

또한, 계면활성제는 음이나 양이온의 계면활성제보다 비이온성 계면활성제를 사용하는 것이 바람직한데 그 이유는 상술한 용매제와 함께 희석율을 높일 수 있기 때문이다.In addition, it is preferable to use a nonionic surfactant rather than an anionic or cationic surfactant because the dilution rate can be increased with the above-mentioned solvent.

이를 위해, 본 발명에서의 비이온계 계면활성제는 폴리에틸렌 글리콜 트리데실 에테르를 사용할 수 있다.For this purpose, polyethylene glycol tridecyl ether can be used as the nonionic surfactant in the present invention.

물론, 필요에 따라 본 발명에서의 계면활성제는 음이나 양이온성의 계면활성제를 사용하는 것도 가능하고, 이를 위해 상기 계면활성제는 소디움도데실설포네이트 및 폴리에틸렌글리콜모노라우레이트 중 어느 하나를 사용할 수 있다.Of course, if necessary, the surfactant in the present invention may be an anionic or cationic surfactant. For this purpose, the surfactant may be either sodium dodecyl sulfonate or polyethylene glycol monolaurate.

또한, 중합체(polymer)는 본 발명에서 획득하고자 하는 코팅제를 구성하는 각각의 단위체를 다량체가 될 수 있도록 하기 위한 조성물이고, 본 발명에서의 상기 중합체는 폴리다이메틸실록산(Polydimethylsiloxane), 데카메칠사이클로펜타실록산(Decamethyl Cyclopentasiloxane), 옥타메칠사이클로테트라실록산(Octamethyl Cyclotetrasiloxane) 및 실리콘의 혼합으로 이루어진다.In addition, the polymer is a composition that allows each unit constituting the coating agent to be obtained in the present invention to become a multimer, and the polymer in the present invention is polydimethylsiloxane, decamethylcyclopenta It is composed of a mixture of siloxane (Decamethyl Cyclopentasiloxane), Octamethyl Cyclotetrasiloxane, and silicone.

이때, 상기한 중합체의 혼합은 폴리다이메틸실록산 33 중량부, 데카메칠사이클로펜타실록산 1 중량부, 옥타메칠사이클로테트라실록산 1 중량부 및 실리콘 1 중량부인 것이 바람직하다.At this time, the mixture of the above polymers is preferably 33 parts by weight of polydimethylsiloxane, 1 part by weight of decamethylcyclopentasiloxane, 1 part by weight of octamethylcyclotetrasiloxane, and 1 part by weight of silicon.

한편, 본 발명에서의 코팅제를 획득하기 위한 조성물에는 상기한 조성물 이외에 타이어에 대한 도포면의 보호성을 더 향상시키기 위하여 페닐살리실레이트(Phenyl Salicylate), 2,4-디히드록시벤조페논(dihydroxybenzophenone) 등의 자외선 방지제나 방청제, 타이어의 색과 유사한 블랙 계열의 착색제 등에서 선택된 1종 또는 2종 이상의 보조재와 함께 흑색 진주를 분말 형태로 가공한 펄재료를 함께 혼합하여 사용하는 것도 가능하다.Meanwhile, the composition for obtaining the coating agent in the present invention includes, in addition to the above composition, phenyl salicylate and 2,4-dihydroxybenzophenone to further improve the protection of the applied surface of the tire. It is also possible to mix and use a pearl material obtained by processing black pearls into powder form along with one or two or more auxiliary materials selected from ultraviolet ray inhibitors, rust preventives, and black colorants similar to the color of tires.

여기서, 보조재료는 코팅제 100 중량부에 대하여 5 중량부로 혼합되고, 펄재는 15 중량부로 포함될 수 있고, 이러한 보조재료와 펄재료의 혼합을 통해 타이어 본연의 색상이 뚜렷하게 노출되며, 펄재료의 혼합을 통해 외관이 수려한 타이어를 제공할 수 있는 장점을 갖게 된다.Here, the auxiliary material may be mixed at 5 parts by weight based on 100 parts by weight of the coating agent, and the pearl material may be included at 15 parts by weight. The natural color of the tire is clearly exposed through mixing of these auxiliary materials and the pearl material, and the mixing of the pearl materials This has the advantage of providing tires with a beautiful appearance.

전술한 바와 같이, 본 발명에 따른 타이어용 코팅제 조성물은 종래와는 차별적으로 우수한 내구성, 타이어 표면에 용이하게 도포되어 퍼질 수 있는 은폐력 및 외관을 갖는 타이어 코팅제 조성물을 제공할 수 있는 효과를 갖게 된다.As described above, the tire coating composition according to the present invention has the effect of providing a tire coating composition that has excellent durability, a hiding power that can be easily applied and spread on the tire surface, and an appearance that is different from the conventional one.

이상과 같이 본 발명에서는 구체적인 구성 요소 등과 같은 특정 사항들과 한정된 실시예 및 도면에 의해 설명되었으나 이는 본 발명의 보다 전반적인 이해를 돕기 위해서 제공된 것일 뿐, 본 발명은 상기의 실시예에 한정되는 것은 아니며, 본 발명이 속하는 분야에서 통상적인 지식을 가진 자라면 이러한 기재로부터 다양한 수정 및 변형이 가능하다.As described above, the present invention has been described with specific details such as specific components and limited embodiments and drawings, but this is only provided to facilitate a more general understanding of the present invention, and the present invention is not limited to the above embodiments. , those skilled in the art can make various modifications and variations from this description.

따라서, 본 발명의 사상은 설명된 실시예에 국한되어 정해져서는 아니 되며, 후술하는 특허청구범위뿐 아니라 이 특허청구범위와 균등하거나 등가적 변형이 있는 모든 것들은 본 발명 사상의 범주에 속한다고 할 것이다.Therefore, the spirit of the present invention should not be limited to the described embodiments, and the scope of the patent claims described below as well as all things that are equivalent or equivalent to the scope of the claims will be said to fall within the scope of the spirit of the present invention. .

Claims (4)

타이어용 코팅제 조성물에 있어서,
상기 타이어용 코팅제 조성물 100 중량부에 대하여,
용매제 61 중량부, 비이온계열 계면활성제 3 중량부, 중합체 36 중량부, 보조재료 5 중량부, 펄재료 15 중량부가 혼합되고,
상기 용매제 61 중량부에 대하여, 정제수 55 중량부, 벤조산 나트륨 1 중량부 및 에탄올 5 중량부가 혼합되고,
상기 비이온계열 계면활성제는 폴리에틸렌 글리콜 트리데실 에테르이고,
상기 중합체 36 중량부에 대하여, 폴리다이메틸실록산 33 중량부, 데카메틸사이클로펜타실록산 1 중량부, 옥타메틸사이클로테트라실록산 1 중량부와 함께 실리콘이나 트리메톡시메틸실란 터미네이티드 하이드록시 실록산 1 중량부를 혼합하고,
상기 보조재료는 타이어 도포면 보호성 향상을 위한 페닐살리실레이트, 2,4-디히드록시벤조페논인 방청제, 상기 펄재료는 검은색의 착색제이며,
상기 펄재료는 흑색 진주를 분말 형태로 혼합한 것을 특징으로 하는 타이어용 코팅제 조성물.
In the coating composition for tires,
With respect to 100 parts by weight of the coating composition for tires,
61 parts by weight of solvent, 3 parts by weight of nonionic surfactant, 36 parts by weight of polymer, 5 parts by weight of auxiliary material, and 15 parts by weight of pearl material are mixed,
With respect to 61 parts by weight of the solvent, 55 parts by weight of purified water, 1 part by weight of sodium benzoate, and 5 parts by weight of ethanol are mixed,
The nonionic surfactant is polyethylene glycol tridecyl ether,
For 36 parts by weight of the polymer, 33 parts by weight of polydimethylsiloxane, 1 part by weight of decamethylcyclopentasiloxane, 1 part by weight of octamethylcyclotetrasiloxane, and 1 part by weight of silicone or trimethoxymethylsilane terminated hydroxysiloxane. mixing wealth,
The auxiliary materials are phenyl salicylate and 2,4-dihydroxybenzophenone, a rust preventive to improve the protection of the tire coating surface, and the pearl material is a black colorant.
The pearl material is a coating composition for tires, characterized in that black pearls are mixed in powder form.
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KR20070059150A (en) 2004-09-21 2007-06-11 가부시키가이샤 윌슨 Tire coating agent
KR100781591B1 (en) 2006-12-20 2007-12-03 한국타이어 주식회사 Coating composition for tire
KR20090104276A (en) * 2008-03-31 2009-10-06 금호타이어 주식회사 Coating composition for tire
WO2010104326A2 (en) * 2009-03-10 2010-09-16 나오테크(주) Composition for coating a vehicle wiper blade, and vehicle wiper blade
KR20110128687A (en) * 2010-05-24 2011-11-30 주식회사 용진유화 Waterborne coating composition for tire

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050075767A (en) * 2002-11-08 2005-07-21 폴리머스 오스트레일리아 프로프라이어터리 리미티드 Process for the preparation of polyolefin nanocomposites
KR20070059150A (en) 2004-09-21 2007-06-11 가부시키가이샤 윌슨 Tire coating agent
KR100781591B1 (en) 2006-12-20 2007-12-03 한국타이어 주식회사 Coating composition for tire
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