KR102621776B1 - Low Noise Asphalt Concrete Compositions Using Stylene Butadien Stylene and Constructing Methods Using Thereof - Google Patents
Low Noise Asphalt Concrete Compositions Using Stylene Butadien Stylene and Constructing Methods Using Thereof Download PDFInfo
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- KR102621776B1 KR102621776B1 KR1020230100688A KR20230100688A KR102621776B1 KR 102621776 B1 KR102621776 B1 KR 102621776B1 KR 1020230100688 A KR1020230100688 A KR 1020230100688A KR 20230100688 A KR20230100688 A KR 20230100688A KR 102621776 B1 KR102621776 B1 KR 102621776B1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/02—Cellulosic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
- C04B20/008—Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2676—Polystyrenes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/36—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/22—Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
- E01C11/224—Surface drainage of streets
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/262—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with fibrous material, e.g. asbestos; with animal or vegetal admixtures, e.g. leather, cork
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/265—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with rubber or synthetic resin, e.g. with rubber aggregate, with synthetic resin binder
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0082—Segregation-preventing agents; Sedimentation-preventing agents
Abstract
본 발명은 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부; 석유수지 1 내지 30중량부; 골재 800 내지 1,500중량부; 성능개선제 0.1 내지 10중량부; 나노세라믹 입자 0.1 내지 5중량부; 셀룰로오스 섬유 0.1 내지 2중량부; 상용화제 0.1 내지 5중량부; 안정제 1 내지 3중량부; 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물 및 이의 시공방법에 관한 것이다.
본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물은 내구성이 좋고, 소성변형, 노화 및/또는 박리가 쉽게 발생하지 않으면서도, 저비용으로 타설공정을 용이하게 수행할 수 있을 뿐만 아니라, 일반 아스팔트 콘크리트 조성물 보다 낮은 온도인 중온에서 타설 및/또는 포설이 가능하도록 하는 등의 효과가 있다.The present invention is based on 100 parts by weight of asphalt, 1 to 30 parts by weight of styrene butadiene styrene; 1 to 30 parts by weight of petroleum resin; 800 to 1,500 parts by weight of aggregate; 0.1 to 10 parts by weight of a performance improver; 0.1 to 5 parts by weight of nanoceramic particles; 0.1 to 2 parts by weight of cellulose fiber; 0.1 to 5 parts by weight of compatibilizer; 1 to 3 parts by weight of stabilizer; and a low-noise, drainable asphalt concrete composition containing 0.1 to 5 parts by weight of an anti-stripping agent and a construction method thereof.
The low-noise drainable asphalt concrete composition according to the present invention, specifically the low-noise drainable asphalt concrete composition containing SBS, is durable, does not easily cause plastic deformation, aging, and/or peeling, and easily performs the pouring process at low cost. In addition to being able to do so, it has the effect of enabling pouring and/or laying at a medium temperature, which is lower than that of general asphalt concrete compositions.
Description
본 발명은 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성 및 이의 시공방법에 관한 것으로서, 보다 상세하게는 SBS를 이용하여 저소음의 배수성을 갖도록 하는 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물 및 이의 시공방법에 관한 것이다.The present invention relates to a low-noise, drainable asphalt concrete composition containing SBS and a construction method thereof. More specifically, it relates to a low-noise, drainable asphalt concrete composition containing SBS that has low noise drainage using SBS and a construction method thereof. .
일반적으로 아스팔트는 유기화합물과 미량의 무기화합물 등이 포함된 수천 종 이상의 고분자 탄화수소(C-H)가 매우 복잡하게 구성된 흑색 또는 흑갈색 고체 또는 반고체의 열가소성 물질로서 가열하게 되면 서서히 액상으로 변화되는 특성을 갖는다.In general, asphalt is a black or dark brown solid or semi-solid thermoplastic material that is very complexly composed of thousands of types of polymer hydrocarbons (C-H) containing organic compounds and trace amounts of inorganic compounds, and has the characteristic of gradually changing into a liquid state when heated.
상기 아스팔트는 천연 아스팔트, 석유계 아스팔트 및 포장용 타르와 같은 종류로 나눠지며 스트레이트 아스팔트, 유화 아스팔트가 널리 알려져 있다. The asphalt is divided into types such as natural asphalt, petroleum-based asphalt, and paving tar, and straight asphalt and emulsified asphalt are widely known.
또한 상기 아스팔트는 점착성이 뛰어나고 광물질 재료와의 부착성이 우수하기 때문에 결합재료나 접착재료로 이용되며, 물에 용해되지 않고 불투수성이므로 방수재료로도 이용되며, 사용목적에 따라 점도를 변화시킬 수 있어 그 활용범위가 다양하고 도로 포장용, 방수용, 일반 공업용, 농업용 등의 다양한 용도로 사용되고 있다.In addition, the asphalt is used as a binding material or adhesive material because it has excellent adhesion and adhesion to mineral materials. It is also used as a waterproofing material because it does not dissolve in water and is impermeable. The viscosity can be changed depending on the purpose of use. Its application range is diverse and it is used for various purposes such as road paving, waterproofing, general industrial purposes, and agricultural purposes.
한편, 배수성 아스팔트 콘크리트 1950년대 영국에서 활주로의 수막현상을 방지하기 위해서 처음 시공되었고, 1980년대 배수성 아스팔트의 단점인 높은 공극률(개립 아스콘)에 의한 내구성을 향상시키기 위하여 일본에서 고점도 개질 아스팔트가 개발된 뒤, 그 단점을 보완하여 폭넓게 확대되었고, 2001년부터 일본의 모든 고속도로 및 일반도로에 특별한 사유가 없는 한 배수성 아스팔트를 의무적으로 사용하도록 하였다.Meanwhile, drainable asphalt concrete was first constructed in the 1950s in the UK to prevent hydroplaning on runways, and in the 1980s, high-viscosity modified asphalt was developed in Japan to improve durability due to the high porosity (open asphalt), a disadvantage of drainable asphalt. , it was expanded widely to compensate for its shortcomings, and since 2001, the use of drainable asphalt has been mandatory on all highways and general roads in Japan unless there are special reasons.
국내에는 1997년 경부 고속도로에 처음 시험포장된 이후로 1999년 건설교통부가 배수성 포장공법을 신기술 지정하여 점차 확대 적용하고 있으나, 아직까지 골재탈리, 소성변형, 포트홀 등 문제가 발생하여 기술적으로 보완이 절실한 실정이다.In Korea, since the first test pavement was installed on the Gyeongbu Expressway in 1997, the Ministry of Construction and Transportation designated the drainage pavement method as a new technology in 1999 and is gradually expanding its application. However, problems such as aggregate detachment, plastic deformation, and potholes still occur, and technological supplementation is urgently needed. This is the situation.
배수성 아스팔트는 공극율을 20%이상 형성시켜, 형성된 공극으로 우천시 우수가 투수되어 도로 표층으로 우수가 고이지 않도록 하는 것으로서, 일반 아스팔트 대비 주행 중 빗물의 비산이 작고, 물보라의 형성이 작아 주행시 시야 확보가 좋을 뿐만 아니라 수막현상이 작아 자동차의 노면 미끄럼 방지 효과가 크기 때문에 교통사고 방지효과가 크고, 형성된 공극으로 인해 주행시 발생되는 자동차 타이어와 노면 사이의 에어펌핑 현상에 의한 노면 마찰음을 흡수하기 때문에 기존의 도로대비 약 4 내지 8dB정도 소음을 줄일 수 있는 고기능 아스팔트이다.Drainable asphalt has a porosity of more than 20%, which allows rainwater to permeate during rainy weather through the formed pores and prevents rainwater from accumulating on the surface of the road. Compared to general asphalt, rainwater scatters less while driving, and the formation of spray is small, ensuring better visibility when driving. In addition, the effect of preventing traffic accidents is large because hydroplaning is small and the effect of preventing the car from slipping on the road surface is large, and the formed air gap absorbs road surface friction noise caused by the air pumping phenomenon between car tires and the road surface that occurs during driving, so it is better than existing roads. It is a high-performance asphalt that can reduce noise by about 4 to 8 dB.
그러나 배수성 아스팔트 콘크리트 구조역학적으로 높은 공극에 의한 골재간의 접촉면적이 작기 때문에 일반 아스팔트 콘크리트 대비 골재의 탈리가 쉽고 내구력이 작은 단점이 있다. However, due to the structural mechanics of drained asphalt concrete, the contact area between aggregates due to high voids is small, so the aggregates are easy to separate and have low durability compared to general asphalt concrete.
또한, 배수성 아스팔트 콘크리트는 기층 혹은 중간층에 빗물이 지하로의 투수에 의한 지반침하 현상을 방지하기 위하여 불투수화가 필수사항이며, 이에 텍코팅을 하여 불투수층을 형성한 뒤 그 위에 배수층을 포설한다.In addition, impervious asphalt concrete is essential to prevent ground subsidence caused by rainwater permeating into the basement in the base or middle layer, and a drainage layer is laid on top of this to form an impermeable layer by applying tectonic coating.
일반적으로 배수층은 공극율을 20% 이상 형성하도록 골재의 입경이 5mm 내지 13mm인 골재를 매트릭스구조 형성을 시키도록 골재 입자 최적분포로 선정하여 사용한다. 배수성 아스팔트 혼합물은 일반 아스팔트 혼합물에 비하여 아스팔트 코팅된 골재와 골재간의 공극이 크기 때문에 상대적으로 골재와 골재간의 접촉면적이 작아 동일한 접착력 혹은 응력을 갖는 아스팔트 혼합물을 사용할 경우 일반 아스팔트 혼합물에 비하여 결합제인 아스팔트 단위면적당 받은 에너지 부하량이 크기 때문에 쉽게 골재간의 결합이 떨어져 탈리 가능성이 매우 높다.In general, the drainage layer is used by selecting aggregate particles with an optimal distribution of aggregate particles to form a matrix structure with an aggregate particle size of 5 mm to 13 mm to form a porosity of 20% or more. Drainable asphalt mixtures have larger voids between the asphalt-coated aggregate and the aggregates compared to general asphalt mixtures, so the contact area between the aggregates is relatively small, so when using asphalt mixtures with the same adhesion or stress, the asphalt unit as a binder is used compared to general asphalt mixtures. Since the energy load received per area is large, the bond between aggregates easily breaks down and the possibility of detachment is very high.
따라서 배수성 아스팔트 혼합물의 경우 60℃에서의 점도가 200,000포이즈 이상을 요구하고 있음과 동시에 보다 강화된 물리적 강도를 요구하고 있다. Therefore, in the case of drainable asphalt mixtures, a viscosity of 200,000 poise or more at 60°C is required, and at the same time, more enhanced physical strength is required.
이와 같은 고응력성은 일반 아스팔트 혼합물의 점도가 60℃에서 3000 내지 5000포이즈임을 비교할 때 비교할 수 없을 정도의 높은 점도임을 알 수 있다.Such high stress can be seen as an incomparably high viscosity when comparing the viscosity of general asphalt mixtures of 3000 to 5000 poise at 60°C.
그러나 이러한 고점도 고응력의 배수성 아스팔트 혼합물은 공지의 시공온도인 125~135℃에서의 점도가 일반 아스팔트에 비하여 현저히 높기 때문에 다짐성 불량의 가능성이 높아 다짐 시공불량에 의한 소성변형 및 포트홀 발생 가능성이 높은 단점을 갖고 있어서, 고도의 시공온도 관리가 중요하며 많은 연구자들은 고점도 고응력을 갖으면서 일반 시공온도에서의 시공성 확보를 위한 연구가 과제로 되어있다.However, this high-viscosity, high-stress drainage asphalt mixture has a significantly higher viscosity at the known construction temperature of 125 to 135°C than general asphalt, so there is a high possibility of poor compaction, and there is a high possibility of plastic deformation and potholes due to poor compaction. Because it has disadvantages, high-level construction temperature management is important, and many researchers are tasked with researching how to secure constructability at general construction temperatures while maintaining high viscosity and high stress.
따라서 배수성 아스팔트 혼합물의 결합제인 아스팔트를 보다 높은 점결력을 갖도록 많은 연구를 거듭한 결과, 에스비알라텍스(SBR-Latex), 스타이렌-이소프렌-스타이렌(SIS), 스타이렌-부타디엔-스타이렌(이하 "SBS"라고 한다), 스타이렌-에틸렌-부타다이엔-스타이렌(SEBS), 초산비닐에틸렌(Ethylene Vinyl Acetate) 등등 합성고무를 개질제로 사용하여 아스팔트 조성물의 점도를 향상시키는 방법들은 이미 공지의 사실이며, 또한 폴리프로필렌 , 폴리에틸렌 등 합성수지를 사용하여 점도를 높이고 응력을 높이려는 많은 노력들을 해왔다.Therefore, as a result of extensive research to improve asphalt, which is a binder for drainable asphalt mixtures, with higher cohesive strength, SBR-Latex, styrene-isoprene-styrene (SIS), and styrene-butadiene-styrene ( Methods for improving the viscosity of asphalt compositions by using synthetic rubber as a modifier such as styrene-ethylene-butadiene-styrene (SEBS), Ethylene Vinyl Acetate, etc. are already known. This is true, and many efforts have been made to increase viscosity and stress by using synthetic resins such as polypropylene and polyethylene.
그 중에 경제성 측면에서 SBS 합성고무가 가장 범용적으로 사용되고 있으나, SBS는 아스팔트와 상용성이 좋지 않아서 열용해 혼합하여 방치 시 층분리가 발생하여 아스팔트 혼합물의 층간 품질 불균질성 때문에 현실적으로 포장체의 품질 불균질로 문제가 많은 것이 사실이다.Among them, SBS synthetic rubber is the most widely used in terms of economic efficiency, but SBS is not compatible with asphalt, so when it is mixed by heat and melted and left, layer separation occurs, and the quality of the pavement is realistically heterogeneous due to the quality heterogeneity between layers of the asphalt mixture. It is true that there are many problems with this.
특히, SBS는 아스팔트와 균질하게 열용융 혼합되려면 약 180℃이상에서 최소 5시간 이상 교반하면서 유지해야만 비교적 균질하게 열용융 혼합되기 때문에 공업적으로 개질 아스팔트 조성물은 프리믹스(Premixing Process)방식으로 아스팔트 제조사에서 직접 생산할 수밖에 없었다.In particular, in order to be homogeneously heat-melted and mixed with asphalt, SBS must be kept at a temperature above 180°C and stirred for at least 5 hours to be relatively homogeneously heat-melted and mixed. Therefore, industrially modified asphalt compositions are manufactured by asphalt manufacturers through a premixing process. I had no choice but to produce it myself.
따라서 지금까지도 개질 아스팔트 혼합물의 층간분리 방지 연구 및 성에너지 측면에서 열용융 혼합 공정 단축에 많은 심혈을 기울여 오고 있는 실정이다.Therefore, much effort has been put into researching the prevention of interlayer separation of modified asphalt mixtures and shortening the heat melt mixing process in terms of sexual energy.
대한민국 공고 특허 제10-0267575호에서는 개질 아스팔트 조성물의 층분리 안정화를 위해 층분리 안정제로 황화합물, 알카리메탈하이드록시드를 일정량 투입하는 내용에 관한 것이다. 이 같은 개질 아스팔트 조성물은 프리믹스 타입이기 때문에 이미 생산 공정에서 개질 특성이 확정되어 아스콘 공장으로 공급될 수밖에 없다. Republic of Korea Publication Patent No. 10-0267575 relates to adding a certain amount of sulfur compound and alkali metal hydroxide as a layer separation stabilizer to stabilize the layer separation of the modified asphalt composition. Because this modified asphalt composition is a premix type, its modification characteristics have already been confirmed in the production process and it is bound to be supplied to the asphalt plant.
따라서 아스콘 공장에서 다양한 등급(grade) 변화에 제약 요소가 될 뿐만 아니라, 저온 내구성이 낮은 문제 등이 있다.Therefore, not only is it a limiting factor in various grade changes in asphalt concrete factories, but there is also the problem of low low-temperature durability.
한편, 대한민국 공개 특허 젠10-2005-0074414호에서는 SBS에 점착성 부여수지 및 오일을 혼합한 고점도 배수성 아스팔트 개질제를 및 이를 함유한 아스팔트 혼합물을 제안하고 있다. 상기 개질제는 특허는 플랜트 믹스 방식의 개질제 제조특허로서 배수성 아스팔트 혼합물의 요구특성인 고응력(High Consistency)에 부합되도록 고점도 개질제로서의 특징을 갖으나, 높은 점도로 인한 공용 시공온도에서의 점도 또한 크기 때문에 시공 온도에 따른 민감성이 큰 단점이 있고, 시공 온도를 다소 높게 갖아야 되기 때문에 시공 온도를 조절하기가 곤란하여 포설 현장에서 실제로 시공 온도 저하에 따른 다짐불량으로 인한 구조 강도 발현에 곤란한 단점이 있다. Meanwhile, Republic of Korea Patent Publication No. Zen 10-2005-0074414 proposes a high-viscosity drainage asphalt modifier mixed with SBS and an adhesion-imparting resin and oil, and an asphalt mixture containing the same. The patent for the modifier is a patent for manufacturing a plant mix type modifier, and has the characteristics of a high viscosity modifier to meet the high stress (High Consistency) required for drainable asphalt mixtures. However, due to the high viscosity, the viscosity at common construction temperatures is also high. It has the disadvantage of being highly sensitive to construction temperature, and because the construction temperature must be somewhat high, it is difficult to control the construction temperature, making it difficult to develop structural strength due to poor compaction due to a decrease in construction temperature at the installation site.
따라서 칸타브로 손실률(%)이 공극율 20% 범위에서 11 내지 16%로 비산 발생의 우려가 있다.Therefore, there is a risk of scattering as the cantabro loss rate (%) is 11 to 16% in the porosity range of 20%.
본 발명은 전술한 문제점을 극복하기 위해 창출된 것으로서, 내구성이 좋고, 소성변형, 노화 및/또는 박리가 쉽게 발생하지 않으면서도 저소음의 배수성을 갖는 아스팔트 콘크리트 조성물을 제공한다.The present invention was created to overcome the above-described problems, and provides an asphalt concrete composition that is durable, does not easily cause plastic deformation, aging, and/or peeling, and has low noise and drainage properties.
본 발명은This invention
아스팔트 100중량부 기준으로,Based on 100 parts by weight of asphalt,
스티렌부타디엔스티렌 1 내지 30중량부;1 to 30 parts by weight of styrene butadiene styrene;
석유수지 1 내지 30중량부;1 to 30 parts by weight of petroleum resin;
골재 800 내지 1,500중량부;800 to 1,500 parts by weight of aggregate;
성능개선제 0.1 내지 10중량부;0.1 to 10 parts by weight of a performance improver;
나노세라믹 입자 0.1 내지 5중량부;0.1 to 5 parts by weight of nanoceramic particles;
셀룰로오스 섬유 0.1 내지 2중량부;0.1 to 2 parts by weight of cellulose fiber;
상용화제 0.1 내지 5중량부; 0.1 to 5 parts by weight of compatibilizer;
안정제 1 내지 3중량부; 및1 to 3 parts by weight of stabilizer; and
박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 제공한다.Provided is a low-noise, drainable asphalt concrete composition containing 0.1 to 5 parts by weight of an anti-stripping agent.
또한, 본 발명은In addition, the present invention
시공하고자 하는 대상면을 정리하는 정리단계;A cleaning step of organizing the surface to be constructed;
상기 정리단계가 종료된 대상면에 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부, 석유수지 1 내지 30중량부, 골재 800 내지 1,500중량부, 성능개선제 0.1 내지 10중량부, 나노세라믹 입자 0.1 내지 5중량부, 셀룰로오스 섬유 0.1 내지 2중량부, 상용화제 0.1 내지 5중량부, 안정제 1 내지 3중량부, 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 타설하는 타설단계;On the target surface where the cleaning step is completed, based on 100 parts by weight of asphalt, 1 to 30 parts by weight of styrene butadiene styrene, 1 to 30 parts by weight of petroleum resin, 800 to 1,500 parts by weight of aggregate, 0.1 to 10 parts by weight of performance improver, nanoceramic A pouring step of pouring a low-noise drainable asphalt concrete composition containing 0.1 to 5 parts by weight of particles, 0.1 to 2 parts by weight of cellulose fibers, 0.1 to 5 parts by weight of a compatibilizer, 1 to 3 parts by weight of a stabilizer, and 0.1 to 5 parts by weight of an anti-stripping agent. ;
상기 타설단계가 종료된 후 다지는 다짐단계; 및A compaction step of compaction after the pouring step is completed; and
상기 다짐단계가 종료된 후 양생하는 양생단계를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물의 시공방법을 제공한다.A method of constructing a low-noise, drainable asphalt concrete composition is provided, including a curing step of curing after the compaction step is completed.
본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물은 내구성이 좋고, 소성변형, 노화 및/또는 박리가 쉽게 발생하지 않으면서도 저소음의 배수성을 갖고, 저비용으로 타설공정을 용이하게 수행할 수 있도록 하는 등의 효과가 있다.The low-noise drainable asphalt concrete composition according to the present invention, specifically the low-noise drainable asphalt concrete composition containing SBS, has good durability, does not easily cause plastic deformation, aging, and/or peeling, has low noise drainage, and can be poured at low cost. It has the effect of making it easier to carry out the process.
이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.
한 가지 관점에서, 본 발명은 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부; 석유수지 1 내지 30중량부; 골재 800 내지 1,500중량부; 성능개선제 0.1 내지 10중량부; 나노세라믹 입자 0.1 내지 5중량부; 셀룰로오스 섬유 0.1 내지 2중량부; 상용화제 0.1 내지 5중량부; 안정제 1 내지 3중량부; 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 제공한다.In one aspect, the present invention provides 1 to 30 parts by weight of styrenebutadienestyrene, based on 100 parts by weight of asphalt; 1 to 30 parts by weight of petroleum resin; 800 to 1,500 parts by weight of aggregate; 0.1 to 10 parts by weight of a performance improver; 0.1 to 5 parts by weight of nanoceramic particles; 0.1 to 2 parts by weight of cellulose fiber; 0.1 to 5 parts by weight of compatibilizer; 1 to 3 parts by weight of stabilizer; and 0.1 to 5 parts by weight of an anti-stripping agent.
다른 관점에서, 본 발명은 시공하고자 하는 대상면을 정리하는 정리단계; 상기 정리단계가 종료된 대상면에 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부, 석유수지 1 내지 30중량부, 골재 800 내지 1,500중량부, 성능개선제 0.1 내지 10중량부, 나노세라믹 입자 0.1 내지 5중량부, 셀룰로오스 섬유 0.1 내지 2중량부, 상용화제 0.1 내지 5중량부, 안정제 1 내지 3중량부, 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 타설하는 타설단계; 상기 타설단계가 종료된 후 다지는 다짐단계; 및 상기 다짐단계가 종료된 후 양생하는 양생단계를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물의 시공방법을 제공한다.From another perspective, the present invention includes a cleaning step of organizing the surface to be constructed; On the target surface where the cleaning step is completed, based on 100 parts by weight of asphalt, 1 to 30 parts by weight of styrene butadiene styrene, 1 to 30 parts by weight of petroleum resin, 800 to 1,500 parts by weight of aggregate, 0.1 to 10 parts by weight of performance improver, nanoceramic A pouring step of pouring a low-noise drainable asphalt concrete composition containing 0.1 to 5 parts by weight of particles, 0.1 to 2 parts by weight of cellulose fibers, 0.1 to 5 parts by weight of a compatibilizer, 1 to 3 parts by weight of a stabilizer, and 0.1 to 5 parts by weight of an anti-stripping agent. ; A compaction step of compaction after the pouring step is completed; and a curing step of curing after the compaction step is completed. It provides a method of constructing a low-noise, drainable asphalt concrete composition.
본 발명에 따른 아스팔트는 당업계에서 통상적으로 사용되는 아스팔트라면 특별히 한정되지 않지만, 추천하기로는 스트레이트 아스팔트 등의 석유계 아스팔트를 사용할 수 있다.The asphalt according to the present invention is not particularly limited as long as it is an asphalt commonly used in the art, but it is recommended that petroleum-based asphalt such as straight asphalt can be used.
여기서, 상기 스트레이트 아스팔트(straight asphalt)는 석유 아스팔트로 원료를 건류 또는 증류한 잔류물을 정제한 통상의 아스팔트로, 특히 침입도가 60 내지 80인 것이 도로에 시공 시 용이성이 있어 더욱 좋다.Here, the straight asphalt is a normal asphalt obtained by refining the residue obtained by drying or distilling the raw material as petroleum asphalt. In particular, those with a penetration degree of 60 to 80 are better because they are easier to construct on roads.
본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 구성하는 아스팔트 외 나머지 성분의 함량은 아스팔트 100중량부 기준으로 한다.The content of the remaining components other than asphalt constituting the low-noise drainable asphalt concrete composition according to the present invention, specifically the low-noise drainable asphalt concrete composition containing SBS, is based on 100 parts by weight of asphalt.
본 발명에 따른 스티렌부타디엔스티렌(stylene butadien stylene; SBS)은 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성의 생성된 콘크리트의 박리를 억제하고, 균열을 감소시켜 포트홀을 방지할 뿐 아니라, 점결력을 제공하는 동시에 강도를 향상시킨다.Styrene butadiene styrene (SBS) according to the present invention inhibits peeling of concrete produced from a low-noise drainable asphalt concrete composition, specifically a low-noise drainable asphalt concrete composition containing SBS, and reduces cracks to prevent potholes. In addition, it provides cohesive force and improves strength at the same time.
바람직한 스티렌부타디엔스티렌은 신율이 320 내지 1,400%인 스티렌부타디엔스티렌을 사용하는 것이 좋고, 그 사용량은 아스팔트 100중량부 기준으로 1 내지 30중량부인 것을 추천한다.The preferred styrene butadiene styrene is styrene butadiene styrene with an elongation of 320 to 1,400%, and its usage is recommended to be 1 to 30 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 석유수지는 저소음 배수성 아스팔트 콘크리트 조성물에 고접착성 등을 제공하기 위한 것으로서, 이러한 목적을 위해 당업계에서 통상적으로 사용하는 석유수지, 바람직하게는 방향족 석유수지, 지방족 석유수지 또는 이들의 혼합물을 사용할 수 있고, 특히 바람직하게는 용융온도가 100℃ 이상이고, 침입도가 1/10mm이하, 140℃에서 점도(이하 140℃ 점도)가 50 내지 500cps인 석유수지가 적합하지만, 추천하기로는 용융온도가 110℃ 내지 140℃이고, 침입도가 0.5 내지 3, 140℃ 점도가 50 내지 300cps인 석유수지가 좋지만, 더욱 추천하기로는 점도가 100 내지 150cps인 지방족 C-5석유수지를 사용하는 것이 좋다.The petroleum resin according to the present invention is intended to provide high adhesion to a low-noise, drainable asphalt concrete composition, and for this purpose, a petroleum resin commonly used in the art, preferably an aromatic petroleum resin, an aliphatic petroleum resin, or any of these. A mixture can be used, and a petroleum resin having a melt temperature of 100°C or higher, a penetration of 1/10 mm or less, and a viscosity of 50 to 500 cps at 140°C (hereinafter referred to as 140°C viscosity) is particularly preferred, but it is recommended. A petroleum resin with a melting temperature of 110°C to 140°C, a penetration degree of 0.5 to 3, and a viscosity of 50 to 300cps at 140°C is preferred, but it is more recommended to use an aliphatic C-5 petroleum resin with a viscosity of 100 to 150cps. good night.
바람직한 석유수지의 사용량은 특별히 한정되는 것은 아니지만, 추천하기로는 아스팔트 100중량부 기준으로 1 내지 30중량부인 것이 좋다.The preferred amount of petroleum resin used is not particularly limited, but it is recommended to be 1 to 30 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 골재는 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성의 구성성분, 예를 들면, 아스팔트, 스티렌부타디엔스티렌, 석유수지 등에 의하여 뭉쳐져서 한 덩어리를 이룰 수 있는 건설용 광물질 재료이며, 화학적으로 안정하다.The aggregate according to the present invention is a low-noise drainable asphalt concrete composition, specifically, a low-noise drainable asphalt concrete composition containing SBS, such as asphalt, styrene-butadiene-styrene, petroleum resin, etc., which can be agglomerated to form a lump. It is a mineral material for construction and is chemically stable.
상기 골재는 화강암, 석회암, 모래, 자갈, 현무암, 오석, 바잘트, 버미큘라이트 또는 이들로부터 선택된 적어도 하나 이상의 혼합물, 또는 기타 이와 비슷한 재료를 지칭한다.The aggregate refers to granite, limestone, sand, gravel, basalt, rubble, bazalt, vermiculite, or a mixture of at least one or more selected from these, or other similar materials.
특정적으로, 상기 골재로서 약 13mm의 입경 및 약 0.7%의 흡수율을 갖는 염기성 맥암 및/또는 약 5mm의 입경 및 0.7%의 흡수율을 갖는 보크사이트를 더 포함할 수 있다.Specifically, the aggregate may further include basic vein rock with a particle size of about 13 mm and a water absorption of about 0.7% and/or bauxite with a particle size of about 5 mm and a water absorption of about 0.7%.
상기 골재는 크기에 따라 5mm미만의 것은 잔골재라 하고, 5mm이상의 것은 굵은 골재라 한다.Depending on the size of the aggregate, those smaller than 5 mm are called fine aggregates, and those larger than 5 mm are called coarse aggregates.
바람직한 골재의 사용량은 아스팔트 100중량부 기준으로 800 내지 1,500중량부인 것이 좋다.The preferred amount of aggregate used is 800 to 1,500 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 성능개선제는 당업계에서 통상적으로 사용되는 성능개선제, 특정적으로 아스팔트 성능개선제라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 아스팔트 100중량부 기준으로 0.1 내지 10중량부인 것이 바람직하다.The performance improving agent according to the present invention may be any performance improving agent commonly used in the art, specifically an asphalt performance improving agent, and the amount used is preferably 0.1 to 10 parts by weight based on 100 parts by weight of asphalt.
바람직한 성능개선제로는 성능개선제 전체 중량 기준으로 비닐아세테이트 모노머-파라핀오일 90 내지 99.5중량% 및 과산화벤조일 0.5 내지 10중량%를 포함하는 것이 좋다.Preferred performance improvers include 90 to 99.5% by weight of vinyl acetate monomer-paraffin oil and 0.5 to 10% by weight of benzoyl peroxide based on the total weight of the performance improver.
여기서, 상기 비닐아세테이트 모노머-파라핀오일은 비닐아세테이트 모노머 5 내지 25중량% 및 파라핀 오일 75 내지 95중량%가 혼합된 것을 사용하는 것이 바람직하다.Here, the vinyl acetate monomer-paraffin oil is preferably a mixture of 5 to 25% by weight of vinyl acetate monomer and 75 to 95% by weight of paraffin oil.
본 발명에 따른 나노세라믹 입자는 저소음 배수성 아스팔트 콘크리트 조성의 양생 중에 표면으로 부상하여 치밀하고 경도가 높은 표면을 형성하기 때문에, 내습성, 내구성, 내후성, 내충격성, 내약품성이 향상된다.The nanoceramic particles according to the present invention rise to the surface during curing of the low-noise drainable asphalt concrete composition to form a dense and high hardness surface, thereby improving moisture resistance, durability, weather resistance, impact resistance, and chemical resistance.
상기 나노세라믹 입자의 사용량은 아스팔트 100중량부 기준으로 0.1 내지 5중량부인 것이 좋다.The amount of nanoceramic particles used is preferably 0.1 to 5 parts by weight based on 100 parts by weight of asphalt.
바람직한 나노세라믹 입자는 실리콘카바이드, 알루미나, 실리카, 지르코니아-실리카, ZnO, TiO2 및/또는 CaCO3가 포함된다. Preferred nanoceramic particles include silicon carbide, alumina, silica, zirconia-silica, ZnO, TiO 2 and/or CaCO 3 .
이들 세라믹입자는 평균 입경이 나노 범위인 것이 바람직한데, 구체적으로 상기 실리콘카바이드의 평균 입경은 300 내지 500nm, 상기 알루미나의 평균 입경은 500 내지 1000nm, 상기 실리카의 평균 입경은 700 내지 1500nm, 상기 지르코니아-실리카의 평균 입경은 500 내지 1000nm, 상기 ZnO의 평균 입경은 500 내지 1000nm, 상기 TiO2의 평균 입경은 100 내지 300nm, 그리고 CaCO3의 평균 입경은 500 내지 1000nm인 것이 바람직하다.These ceramic particles preferably have an average particle size in the nano range. Specifically, the average particle size of the silicon carbide is 300 to 500 nm, the average particle size of the alumina is 500 to 1000 nm, the average particle size of the silica is 700 to 1500 nm, and the zirconia- It is preferable that the average particle diameter of silica is 500 to 1000 nm, the average particle diameter of ZnO is 500 to 1000 nm, the average particle diameter of TiO2 is 100 to 300 nm, and the average particle diameter of CaCO 3 is 500 to 1000 nm.
이 중에서도 실리콘카바이드는 천연광물로 존재하지 않으므로 인공적으로 합성하며, 고온에서의 화학적 안정성 및 내식성이 뛰어나고 높은 경도를 갖는다.Among these, silicon carbide does not exist as a natural mineral, so it is artificially synthesized, has excellent chemical stability and corrosion resistance at high temperatures, and has high hardness.
본 발명에 따른 셀룰로오스 섬유는 저소음 배수성 아스팔트 콘크리트 조성물로 형성된 교면의 종-횡 방향으로 가해지는 응력에 의한 인장력 및/또는 경량성 등을 제공하기 위한 것으로서, 이러한 목적을 갖는 셀룰로오스 섬유라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 천연 셀룰로오스 섬유를 사용하는 것이 좋고, 그 사용량은 아스팔트 100중량부 기준으로 0.1 내지 2중량부인 것이 좋다.The cellulose fiber according to the present invention is intended to provide tensile strength and/or lightness due to stress applied in the longitudinal-lateral direction of a bridge surface formed of a low-noise, drainable asphalt concrete composition. Any cellulose fiber having this purpose can be used. However, it is preferable to use natural cellulose fibers, and the amount used is 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 상용화제는 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물에 포함된 아스팔트 등과 성능개선제 등 간의 상용성을 증대시키기 위한 것이다.The compatibilizer according to the present invention is intended to increase compatibility between asphalt and performance improvers contained in low-noise drainable asphalt concrete compositions, specifically, low-noise drainable asphalt concrete compositions containing SBS.
바람직한 상용화제로는 폴리인산, 금속염 무기산류 또는 이들의 혼합물을 사용할 수 있고, 그 사용량은 아스팔트 100중량부 기준으로 0.1 내지 5중량부를 사용하는 것을 추천한다.Preferred compatibilizers include polyphosphoric acid, metal salt inorganic acids, or mixtures thereof, and it is recommended to use 0.1 to 5 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 안정제는 저소음 배수성 아스팔트 콘크리트 조성물을 자외선으로부터 보호하여 안정성을 제공하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 안정제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 아크릴 폴리올 수지, 무황변 폴리 우레아수지, 폴리이소시아네이트 또는 이들의 혼합물을 사용하는 것이 좋고, 그 사용량은 아스팔트 100중량부 기준으로 1 내지 3중량부인 것을 추천한다.The stabilizer according to the present invention is intended to provide stability to the low-noise drainable asphalt concrete composition by protecting it from ultraviolet rays. Any stabilizer common in the art for this purpose may be used, but preferably acrylic polyol resin, It is recommended to use yellowing polyurea resin, polyisocyanate, or a mixture thereof, and the amount used is recommended to be 1 to 3 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 박리방지제는 아스팔트 콘크리트 조성물, 특정적으로 저소음 배수성 아스팔트 콘크리트 조성물이 시공되는 시공면으로부터 용이하게 박리되는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 박리방지제라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 아스팔트 100중량부 기준으로 0.1 내지 5중량부인 것을 추천한다.The anti-stripping agent according to the present invention is used to prevent the asphalt concrete composition, specifically the low-noise drainable asphalt concrete composition, from easily peeling off from the construction surface on which it is constructed. Any conventional anti-stripping agent in the art for this purpose can be used. You may do so, and the recommended amount of use is 0.1 to 5 parts by weight based on 100 parts by weight of asphalt.
바람직한 박리방지제는 폴리인산계, 아민계, 또는 인산 에스테르계 박리방지제를 사용하는 것이 좋다.Preferred peeling inhibitors include polyphosphoric acid-based, amine-based, or phosphoric acid ester-based peeling inhibitors.
특정적으로, 상기 박리방지제는 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제; 산가가 10 ㎎KOH/g 이하이고, 총 아민가가 140 내지 400㎎HCl/g인 아민계 박리방지제일 수 있다.Specifically, the anti-peeling agent is a liquid type polyphosphoric acid-based anti-peeling agent having a specific gravity of 1.0 or more and a viscosity of 110 cPs at 60°C; It may be an amine-based peeling prevention agent with an acid value of 10 mgKOH/g or less and a total amine value of 140 to 400 mgHCl/g.
본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물은 하기의 특정 양태로 실시되는 부가물을 1종 또는 1종 이상 더 포함할 수 있다.The low-noise drainable asphalt concrete composition according to the present invention, specifically the low-noise drainable asphalt concrete composition containing SBS, may further include one or more types of additives implemented in the following specific embodiments.
특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 초기강도를 확보하고, 내마모성, 내식성 및 내화학성 등을 향상시키기 위하여 황산망간을 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In a specific embodiment, the low-noise drainable asphalt concrete composition according to the present invention, specifically the low-noise drainable asphalt concrete composition containing SBS, contains manganese sulfate as asphalt to secure the initial strength of the composition and improve wear resistance, corrosion resistance, chemical resistance, etc. It may further include 1 to 5 parts by weight based on 100 parts by weight.
다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내열성, 내마모성, 내약품성, 및/또는 경도 등을 향상시키기 위하여 방해석 분말을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있는데, 상기, 방해석은 순수한 물에는 녹지 않는 성질이 있으며, 산성환경에 대한 완충역할도 함께 할 수 있고, 바람직한 평균입도는 1 내지 5㎛ 이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of calcite powder based on 100 parts by weight of asphalt in order to improve the heat resistance, wear resistance, chemical resistance, and/or hardness of the composition. Calcite has the property of being insoluble in pure water and can also serve as a buffer in an acidic environment, and its preferred average particle size is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물이 신속히 경화를 진행하여도 크랙 및 탈락현상을 개선하고, 조성물의 가공성, 밀착력 및 안정성 등을 제공하기 위하여 폴리비닐리덴플로라이드수지를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention improves cracking and dropping phenomenon even when the composition cures quickly, and uses polyvinylidene fluoride resin to provide processability, adhesion, and stability of the composition. It may be further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 경도를 향상시키고 표면오염을 감소시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 3중량부의 트리메틸올프로판 트리아크릴레이트를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 0.1 to 3 parts by weight of trimethylolpropane triacrylate based on 100 parts by weight of asphalt in order to improve the hardness of the composition and reduce surface contamination. there is.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 분산성 향상 및 재료의 안정성과 작업성을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 5중량부의 폴리옥시에틸렌노닐페닐에테르를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further includes 0.1 to 5 parts by weight of polyoxyethylene nonylphenyl ether based on 100 parts by weight of asphalt in order to improve dispersibility and improve material stability and workability. can do.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내열성 및 내산성을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 2중량부의 니켈슬래그분말을 더 포함할 수 있는데, 상기 니켈슬래그분말은 니켈 제련과정에서 발생하는 산업부산물인 니켈슬래그를 분쇄한 것으로 상기 니켈슬래그 분말은 MgO 성분이 30 내지 35중량% 함유되어 있어, 이 성분은 열과 산에 대한 안정성을 가지므로 상기와 같은 효과를 얻을 수 있으며, 바람직한 니켈슬래그 분말의 평균입도는 1 내지 3㎛ 이다. In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 0.1 to 2 parts by weight of nickel slag powder based on 100 parts by weight of asphalt in order to improve the heat resistance and acid resistance of the composition. The nickel slag powder is made by pulverizing nickel slag, an industrial by-product generated during the nickel smelting process. The nickel slag powder contains 30 to 35% by weight of MgO, and this component has stability against heat and acid, thereby achieving the above effects. The average particle size of the preferred nickel slag powder is 1 to 3㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내열성, 탄성회복력, 및 내주름성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 3중량부의 디이소노닐프탈레이트(Di-Isononyl Phthalate, (DINP))를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 0.1 to 3 parts by weight of diisononyl phthalate (Di- Isononyl Phthalate, (DINP)) may be further included.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 항균성 및 산화방지 효과를 향상시키기 위하여 토코페릴아세테이트(tocopheryl acetate)를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include tocopheryl acetate in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt in order to improve the antibacterial and anti-oxidation effects of the composition. there is.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 박리 방지, 부착강도, 균열저항성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 2중량부의 다이머산(Dimer acid)을 더 포함 할 수 있는데, 상기 다이머산은 그 유래 및 형태가 크게 제한되지 않으나, 식물유 지방산의 이량체인 것이 바람직하고, 식물류 지방산은 올레익산, 리놀레익산, 스테아릭산 및 팔미틱산으로 이루어진 군에서 선택되는 1종 이상으로 구성될 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further contains 0.1 to 2 parts by weight of dimer acid based on 100 parts by weight of asphalt in order to prevent peeling, improve adhesion strength, crack resistance, etc. of the composition. The origin and form of the dimer acid are not greatly limited, but it is preferably a dimer of vegetable oil fatty acid, and the vegetable fatty acid is one selected from the group consisting of oleic acid, linoleic acid, stearic acid, and palmitic acid. It may consist of the above.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 초기 방청성을 향상시키고, 점탄성을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 1중량부의 소듐벤조에이트(sodium benzoate)를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further includes 0.1 to 1 part by weight of sodium benzoate based on 100 parts by weight of asphalt in order to improve the initial rust prevention of the composition and improve the viscoelasticity. can do.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 방수성, 내열성, 내염성 및 접착성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 아세틸레이티드라놀란을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further includes 1 to 10 parts by weight of acetylated dranolan based on 100 parts by weight of asphalt in order to improve the water resistance, heat resistance, salt resistance, and adhesiveness of the composition. can do.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 윤활성과 분산성을 향상시켜 균일한 배합과 작업성을 향상시키고, 균열저항성 및 강도을 향상시키기 위하여 스테아린산 알루미늄을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention improves uniform mixing and workability by improving the lubricity and dispersibility of the composition, and aluminum stearate is added to 100 parts by weight of asphalt to improve crack resistance and strength. It may further include 1 to 5 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내마모성, 내화성, 내수성 및 탈취성 등을 개선하기 위하여 세리사이트를 아스팔트 100중량부 기준으로 1 내지 5 중량부로 더 포함할 수 있는데, 상기 세리사이트는 단사정계에 속하는 광물질로서, 안정성, 윤활성, 보습성 등이 뛰어나므로 이를 저소음 배수성 아스팔트 콘크리트 조성물에 포함시키면 상기와 같은 효과를 갖게 된다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of sericite based on 100 parts by weight of asphalt in order to improve the wear resistance, fire resistance, water resistance, and deodorization of the composition. , The sericite is a mineral belonging to the monoclinic system and has excellent stability, lubricity, moisture retention, etc., so when it is included in a low-noise, drainable asphalt concrete composition, it has the above-mentioned effects.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 점도 및 재료분리 저항성을 개선하기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 세피올라이트를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of sepiolite based on 100 parts by weight of asphalt in order to improve the viscosity and material separation resistance of the composition.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 유연성, 신축성, 탄성, 및 자외선 저항성 등을 향상시키기 위하여 폴리트리메틸렌테레프탈레이트를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 1 to 5 parts by weight of polytrimethylene terephthalate based on 100 parts by weight of asphalt in order to improve the flexibility, elasticity, elasticity, and ultraviolet ray resistance of the composition. It can be included.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 강도, 침투력, 및 발수성 등을 향상시키기 위하여 3-메르캅토프로필트리메톡시실란을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 1 to 3 parts by weight of 3-mercaptopropyltrimethoxysilane based on 100 parts by weight of asphalt in order to improve the strength, penetration, and water repellency of the composition. More may be included.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 산패 발생 및 노화방지와 안정성 향상을 위하여 디부틸하이드록시톨루엔을 아스팔트 100중량부 기준으로 1 내지 3중량부 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of dibutylhydroxytoluene based on 100 parts by weight of asphalt to prevent rancidity and aging and improve stability of the composition. .
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 산화를 방지하고, 신속한 경화특성을 제공하여 재료분리 억제 및 재료손실을 효과적으로 방지하고, 습윤경화성능, 균열억제성능, 및 수축 저항성능을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 2중량부의 순지트(Shungite) 미분말을 더 포함할 수 있는데, 상기 순지트는 규산염과 플러렌이 주성분인 광물질로서 항산화 능력이 뛰어난 것으로 알려져 있는데 이를 아스팔트 콘크리트 조성물에 포함시키면 상기와 같은 효과를 얻을 수 있으며, 바람직한 순지트 미분말의 평균입도는 1 내지 5㎛ 이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention prevents oxidation of the composition, provides rapid curing characteristics, effectively prevents material separation and material loss, and has wet hardening performance, crack suppression performance, and shrinkage. In order to improve resistance performance, 0.1 to 2 parts by weight of shungite fine powder may be further included based on 100 parts by weight of asphalt. Shungite is a mineral whose main components are silicate and fullerene and is known to have excellent antioxidant ability. When included in a concrete composition, the above-mentioned effects can be obtained, and the average particle size of the preferred fine powder of Sunjit is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 부식억제 및 중성화 저항성, 유동성 등을 향상시키기 위하여 아노르싸이트 미분말을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있는데, 상기 아노르싸이트(회장석)는 석회가 풍부한 삼사정계 광물로서, 외부로 침투하는 염소이온에 의한 화합물과 반응하여 염소이온을 고정시켜 조성불 내부에 까지 염소이온이 도달하는 것을 억제함으로써 상기와 같은 효과를 발현시킬 수 있는데, 바람직한 아노르싸이트 미분말의 평균입도는 1 내지 5㎛ 이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of anorsite fine powder based on 100 parts by weight of asphalt in order to inhibit corrosion, neutralize resistance, and improve fluidity of the composition. The anorsite (ilesite) is a triclinic mineral rich in lime, which reacts with compounds caused by chlorine ions penetrating from the outside and fixes the chlorine ions, preventing the chlorine ions from reaching the inside of the composition. The same effect can be achieved, and the average particle size of the preferred anorsite fine powder is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 흡수성, 투과성 및 보습성을 향상시키기 위하여 스타치 포스페이트 에스테르를 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 0.1 to 2 parts by weight of starch phosphate ester based on 100 parts by weight of asphalt in order to improve the water absorption, permeability, and moisture retention of the composition.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 점도를 조절하고, 동결융해저항성 및 마모저항성을 개선하기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 수산화바륨티타네이트를 더 포함할 수 있는데, 상기 수산화바륨티타네이트는 펜탄올, 헥산올, 헵탄올, 옥탄올 및 이들의 혼합물로 이루어진 군에서 선택되는 1종 이상의 알코올에 바륨티타늄 복합알콕사이드를 0.01 내지 0.15 mol/ℓ 용해하여 얻어진 용액 40 내지 70 부피%와; 메틸에틸케톤 25 내지 45 부피%를 20 내지 60 ℃의 온도에서 혼합하여, 혼합용액을 제조하는 단계; 상기 혼합용액에 에탄올과 0.03 내지 0.30 mol/ℓ의 물을 혼합하되, 상기 에탄올과 물의 합이 5 내지 15 부피%가 되도록 혼합하여 반응용액을 제조하는 단계; 및 상기 반응용액을 상온에서 0.2 내지 1.5 시간동안 교반하면서 상기 반응용액 형성 초기에 핵생성된 수산화 바륨티타네이트 미립자 핵을 성장시키는 단계;를 포함하는 제조될 수 있으며 평균입경이 100 내지 800 nm인 것이 좋다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further contains 1 to 5 parts by weight of barium titanate based on 100 parts by weight of asphalt in order to control the viscosity of the composition and improve freeze-thaw resistance and wear resistance. It may include, wherein the barium titanate hydroxide is obtained by dissolving 0.01 to 0.15 mol/L of barium titanium complex alkoxide in one or more alcohols selected from the group consisting of pentanol, hexanol, heptanol, octanol, and mixtures thereof. 40 to 70% by volume of the resulting solution; Preparing a mixed solution by mixing 25 to 45% by volume of methyl ethyl ketone at a temperature of 20 to 60 ° C.; Preparing a reaction solution by mixing ethanol and 0.03 to 0.30 mol/l of water in the mixed solution so that the sum of the ethanol and water is 5 to 15% by volume; and growing the barium titanate hydroxide particulate nuclei nucleated at the beginning of the formation of the reaction solution while stirring the reaction solution at room temperature for 0.2 to 1.5 hours, and having an average particle diameter of 100 to 800 nm. good night.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 경량화 및 난연성을 개선하기 위하여 피브로퍼라이트(Fibroferrite) 미분말을 아스팔트 100중량부 기준으로 1 내지 3중량부더 포함할 수 있는데, 상기 피브로퍼라이트는 철분이 풍부한 삼방정계 광물로서, 바람직한 피브로퍼라이트 미분말의 평균입도는 1 내지 5㎛ 이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of Fibroferrite fine powder based on 100 parts by weight of asphalt in order to reduce the weight of the composition and improve flame retardancy. Fibroperite is a trigonal mineral rich in iron, and the average particle size of preferred fibroperite fine powder is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 균열저감 및 내마모성, 내염해성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 0.1 내지 3중량부의 질화갈륨(GaN) 미분말을 더 사용할 수 있는데, 바람직한 질화갈륨의 평균입도는 1 내지 5㎛이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further uses 0.1 to 3 parts by weight of gallium nitride (GaN) fine powder based on 100 parts by weight of asphalt in order to reduce cracking and improve wear resistance, salt resistance, etc. of the composition. The preferred average particle size of gallium nitride is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 부착강도, 내염해성, 중성화 저항성, 내열성, 자기보수성 등을 개선하기 위하여 알루미늄과 마그네슘이 풍부하고 흡착성이 강한 천연점토의 일종인 스멕타이트(smectite)를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention is a type of natural clay rich in aluminum and magnesium and with strong adsorption in order to improve the adhesion strength, salt resistance, neutralization resistance, heat resistance, and self-repairability of the composition. Smectite may be further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 초기 강도발현 향상을 위하여 호박산을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있는데, 상기 호박산은 다이카복시산으로, 사용시 온도 상승 시점이 빠르며, 온도 상승이 완만하게 이루어지다가 급격하게 올라가는 특성이 있어 초기 강도 발현에는 유리하다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of succinic acid based on 100 parts by weight of asphalt to improve initial strength development. The succinic acid is dicarboxylic acid, and when used, The temperature rises quickly, and the temperature rises slowly and then rapidly, making it advantageous for developing initial strength.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 강도, 내충격성, 내약품성을 향상시키기 위하여, 아스팔트 100중량부 기준으로 1 내지 3중량부의 폴리클로로트리플루오로에틸렌를 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of polychlorotrifluoroethylene based on 100 parts by weight of asphalt in order to improve the strength, impact resistance, and chemical resistance of the composition. You can.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 재료분리 및 재료손실을 방지하고, 시공성 및 분산성을 향상시키기 위하여 난각막 미분말을 아스팔트 100중량부 기준으로 1 내지 3중량부의 난각막 미분말을 더 포함할 수 있는데, 상기 난각막 미분말은 자외선을 조사한 것을 사용함으로써, 상기한 효과를 더욱 개선할 수 있고, 보다 구체적으로, 상기 난각막 미분말은 계란 껍질을 건조한 후, 상기 건조된 계란 껍질에서 난각막을 수득하는 단계; 상기 수득된 난각막을 1.5 내지 5배 중량의 1 내지 15 중량% 농도 유기산 수용액에 2 내지 8 시간 동안 침지시켜 산처리하는 단계; 상기 산처리가 완료된 난각막 침지액 100 중량부에 벤조산나트륨 0.1 내지 10 중량부를 혼합한 후, 수분함량 20 내지 35 %의 혼합반죽을 만드는 단계; 상기 혼합반죽을 자외선 조사장치에 넣고 자외선을 조사하는 단계; 및 상기 자외선 조사장치의 내부에서 자외선에 노출된 혼합반죽을 수분함량 15 % 이하로 건조한 후, 평균 입자 크기 200 내지 600 μm로 분쇄하는 단계를 포함하는 제조방법으로 제조되는 것을 바람직하게 사용할 수 있는데, 이때, 상기 계란 껍질의 건조는 70 내지 100 ℃에서 1 내지 4 시간 동안 수행될 수 있으며, 바람직한 난각막 미분말의 평균입도는 1 내지 5㎛이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 1 to 3 parts by weight of egg shell membrane fine powder based on 100 parts by weight of asphalt in order to prevent material separation and material loss of the composition and improve workability and dispersibility. It may further include fine powder, and the above effect can be further improved by using the egg shell membrane fine powder irradiated with ultraviolet rays. More specifically, the egg shell membrane fine powder is obtained from the egg shell membrane after drying the egg shell. Obtaining a; Acid treatment of the obtained eggshell membrane by immersing it in an aqueous solution of organic acid with a concentration of 1 to 15% by weight of 1.5 to 5 times the weight for 2 to 8 hours; Mixing 0.1 to 10 parts by weight of sodium benzoate with 100 parts by weight of the acid-treated eggshell membrane immersion liquid, and then making a mixed dough with a moisture content of 20 to 35%; Putting the mixed dough in an ultraviolet irradiation device and irradiating ultraviolet rays; and drying the mixed dough exposed to ultraviolet rays inside the ultraviolet irradiation device to a moisture content of 15% or less, and then grinding the mixed dough to an average particle size of 200 to 600 μm. At this time, drying of the eggshell may be performed at 70 to 100° C. for 1 to 4 hours, and the average particle size of the preferred egg shell membrane fine powder is 1 to 5 ㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 노화방지, 박리방지 및 균열 저항성 향상을 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 글루코노락톤(gluconolactone)을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of gluconolactone based on 100 parts by weight of asphalt to prevent aging, prevent peeling, and improve crack resistance of the composition. You can.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 산소의 접촉에 의한 화학반응을 억제 또는 차단시킴으로써 조성물이 산화반응에 의하여 분해되어 고유물성을 상실하는 것을 방지하기 위하여 디스테아릴 펜타에리트리톨 디포스페이트(Distearyl pentaerythritol diphosphite)를 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains distearyl pentaerythine to prevent the composition from being decomposed by an oxidation reaction and losing its intrinsic properties by suppressing or blocking the chemical reaction due to contact with oxygen. Distearyl pentaerythritol diphosphite may be further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 아스팔트 100중량부 기준으로 1 내지 10중량부의 구아검을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 10 parts by weight of guar gum based on 100 parts by weight of asphalt.
여기서, 상기 구아검은 수용성 고분자 물질인 천연수지로서, 수화반응에 의한 팽창 및 탈수에 의한 수축작용과, 조성물의 수화반응에 의한 고화시 팽창작용과의 상호작용으로 공극이 발생하며, 이러한 공극과 천연수지인 구아검 고유의 탄성력에 의해 충격흡수작용을 나타낼 수 있다.Here, the guar gum is a natural resin that is a water-soluble polymer material, and voids are generated due to the interaction between expansion due to hydration reaction, contraction due to dehydration, and expansion action when the composition solidifies due to hydration reaction, and these voids and natural Guar gum, a resin, can exhibit shock absorption due to its inherent elasticity.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 분산성 및 유동성을 일정시간 유지할 수 있도록 하기 위하여, 아스팔트 100중량부 기준으로 1 내지 5중량부의 이타코닉 산을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of itaconic acid based on 100 parts by weight of asphalt in order to maintain the dispersibility and fluidity of the composition for a certain period of time. there is.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성의 가소성 및 성형 가공성을 향상시키기 위하여, 에틸렌 비스 스테아마이드(ethylene bis stearamide)를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함할 수 있다.In another specific embodiment, in order to improve the plasticity and molding processability of the low-noise drainable asphalt concrete composition according to the present invention, ethylene bis stearamide may be further included in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt. there is.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물이 공기, 빛 및 수분에 노출될 때 산화되어 변색이 발생되어 외관을 해침은 물론, 조성물의 물리적인 특성의 급격한 저하를 방지하기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 적동석을 더 포함할 수 있는데, 상기 적동석은 황화구리 광물의 풍화에 의해 생성되는 2차 광물로서 구리 이온이 용출하기 쉽기 때문에, 용출된 구리 이온이 미생물이나 바이러스와 접촉함으로써 효소나 단백질과 결합해 활성을 저하시켜 미생물 및 바이러스의 대사 기능을 저하시키고, 용출된 구리 이온의 촉매 작용에 의해서 공기 중의 산소를 활성화하여, 미생물 및 바이러스의 유기물을 분해시키는 효과가 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention is oxidized and discolored when the composition is exposed to air, light, and moisture, thereby damaging the appearance as well as preventing rapid deterioration of the physical properties of the composition. To this end, it may further include 1 to 5 parts by weight of red copper ions based on 100 parts by weight of asphalt. Since the red copper ions are secondary minerals produced by weathering of copper sulfide minerals and are prone to eluted copper ions, the eluted copper ions are absorbed by microorganisms. When in contact with an enzyme or a virus, it binds to enzymes or proteins and reduces their activity, thereby lowering the metabolic function of microorganisms and viruses, and activating oxygen in the air through the catalytic action of eluted copper ions, which decomposes the organic matter of microorganisms and viruses. There is.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내마모성, 내화학성, 내알칼리성, 내오염성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 인산지르코늄을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of zirconium phosphate based on 100 parts by weight of asphalt in order to improve the wear resistance, chemical resistance, alkali resistance, contamination resistance, etc. of the composition. You can.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물에 항균작용을 부여하고 아스팔트 콘크리트 조성물에 포함된 중금속의 제거를 위하여, 카르복시메틸 키토산(carboxymethyl chitosan)을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있는데, 상기 카르복시메틸 키토산은 키토산 유도체로서 통상 게, 새우 등의 갑각류의 껍데기로부터 추출된다.In another specific embodiment, in order to impart an antibacterial effect to the low-noise, drainable asphalt concrete composition according to the present invention and to remove heavy metals contained in the asphalt concrete composition, carboxymethyl chitosan is added in an amount of 0.1 to 3 parts based on 100 parts by weight of asphalt. It may further be included in parts by weight. The carboxymethyl chitosan is a chitosan derivative and is usually extracted from the shells of crustaceans such as crabs and shrimp.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내산성 및 내화성을 개선하기 위하여 마그네사이트 미분말을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더포함할 수 있는데, 상기 마그네사이트는 탄산마그네슘으로 이루어진 삼방정계의 마그네슘 광물로서, 바람직한 마그네사이트 미분말의 평균입도는 1 내지 5㎛ 이다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of fine magnesite powder based on 100 parts by weight of asphalt in order to improve the acid resistance and fire resistance of the composition, and the magnesite is magnesium carbonate. It is a trigonal magnesium mineral composed of, and the average particle size of the preferred magnesite fine powder is 1 to 5㎛.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 혼합시 반응속도를 빠르게 하고, 접착 성능을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 2-브로모피리딘(2-bromopyridine)을 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 1 to 10 parts by weight of 2-bromopyridine (2) based on 100 parts by weight of asphalt in order to speed up the reaction rate when mixing the composition and improve adhesion performance. -bromopyridine) may be further included.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 내후성 및 흡착력을 증가시키고, 공기 중에 떠다니는 이산화탄소를 흡수하여 공기정화 작용 및 자외선을 안정적으로 흡수할 뿐만 아니라, 바인더 역할도 수행할 수 있도록 하기 위하여 아스팔트 100중량부 기준으로 규산나트륨과 규사가 1:1의 중량비율로 혼합된 규산나트륨 및 규사 혼합물을 1 내지 10중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention not only increases the weather resistance and adsorption capacity of the composition, absorbs carbon dioxide floating in the air, purifies the air and stably absorbs ultraviolet rays, but also acts as a binder. In order to do this, 1 to 10 parts by weight of a mixture of sodium silicate and silica sand mixed at a weight ratio of 1:1 may be further included based on 100 parts by weight of asphalt.
여기서, 상기 규산나트륨과 규사가 1:1의 중량비율로 혼합된 규산나트륨 및 규사 혼합물을 사용하는 것은, 규사가 바인더 역할을 수행하도록 하고, 규산나트륨은 세라믹 결합제로서 내후성 및 흡착력을 증가시키고, 공기 중에 떠다니는 이산화탄소를 흡수하여 공기정화 작용 및 자외선 파장영역 전체와 가시광선 파장 영역 전체에 걸쳐 흡수하는 효과적인 자외선 고무노화방지제 역할을 부여하게 하기 위함이다. Here, using a mixture of sodium silicate and silica sand in a weight ratio of 1:1 allows the silica sand to act as a binder, and sodium silicate acts as a ceramic binder to increase weather resistance and adsorption power, and to increase air absorption. This is to provide an air purifying effect by absorbing carbon dioxide floating in the air and an effective ultraviolet ray rubber anti-aging agent that absorbs the entire ultraviolet ray wavelength range and the entire visible ray wavelength range.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 초기 강도를 개선하고 균열발생을 억제하기 위하여 트리칼슘알루미네이트를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of tricalcium aluminate based on 100 parts by weight of asphalt in order to improve the initial strength of the composition and suppress the occurrence of cracks. .
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 부착력, 응집력 및 재료분리 방지성 등을 개선하고, 수축 저항성, 부착강도, 휨강도, 인장강도 및 압축강도 등의 물리적 성능을 향상시키기 위하여 아미노메틸폴리스티렌 수지를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention improves the adhesion, cohesion, and material separation prevention properties of the composition, and improves physical performance such as shrinkage resistance, adhesion strength, bending strength, tensile strength, and compressive strength. In order to achieve this, aminomethyl polystyrene resin may be further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 방부, 방오 및 항균성 등을 향상시키기 위하여 산화티탄을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 3 parts by weight of titanium oxide based on 100 parts by weight of asphalt in order to improve the antiseptic, antifouling, and antibacterial properties of the composition.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 강도, 내마모성, 균열저감효과 등을 개선하기 위하여 이황화 몰리브덴을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of molybdenum disulfide based on 100 parts by weight of asphalt in order to improve the strength, wear resistance, crack reduction effect, etc. of the composition.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 흡착력, 탈취, 내열성 등을 개선하기 위하여 근교린을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있는데, 상기 근교린은 굴폐각을 소성하여 얻어진 탄산칼슘을 주성분으로 하는 것으로, 생굴패각을 700 내지 900 ℃의 온도에서 1 내지 2시간 동안 소성 및 분쇄하고 수화 및 탄산화 반응시켜 제조한 것을 사용하여 상기한 효과를 더욱 향상시킬 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention may further include 1 to 5 parts by weight of periwinkle based on 100 parts by weight of asphalt in order to improve the adsorption capacity, deodorization, heat resistance, etc. of the composition. Lin is mainly composed of calcium carbonate obtained by calcining oyster shells. It is manufactured by calcining and pulverizing raw oyster shells at a temperature of 700 to 900°C for 1 to 2 hours, followed by hydration and carbonation reaction, to further achieve the above-mentioned effects. It can be improved.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 반응성을 개선하여 강도를 발현하고, 내오염성 및 재료분리 저항성을 향상시키기 위하여 메타인산 나트륨(sodium metaphosphate)를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention develops strength by improving the reactivity of the composition, and contains sodium metaphosphate based on 100 parts by weight of asphalt to improve contamination resistance and material separation resistance. It may be further included in an amount of 0.1 to 3 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 열적??화학적 안정성을 향상시켜 내화성을 개선하고 충진성을 향상시키기 위하여 규산알루미늄을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention contains 1 to 5 parts by weight of aluminum silicate based on 100 parts by weight of asphalt to improve fire resistance and fillability by improving the thermal and chemical stability of the composition. More may be included.
또 다른 특정 양태로서, 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물은 조성물의 강도를 개선하고 표면오염을 방지하기 위하여 산화제일구리(Cu2O)를 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있다.In another specific embodiment, the low-noise, drainable asphalt concrete composition according to the present invention further includes 0.1 to 2 parts by weight of cuprous oxide (Cu 2 O) based on 100 parts by weight of asphalt in order to improve the strength of the composition and prevent surface contamination. can do.
이와 같은 구성을 갖는 본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물, 특정적으로 SBS를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 이용한 시공방법을 설명하면 다음과 같다.A construction method using the low-noise, drainable asphalt concrete composition according to the present invention having the above-described structure, specifically the low-noise, drainable asphalt concrete composition containing SBS, will be described as follows.
본 발명에 따른 저소음 배수성 아스팔트 콘크리트 조성물을 이용한 시공방법은 시공하고자 하는 대상면을 정리하는 정리단계;The construction method using the low-noise, drainable asphalt concrete composition according to the present invention includes the steps of organizing the surface to be constructed;
상기 정리단계가 종료된 대상면에 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부, 석유수지 1 내지 30중량부, 골재 800 내지 1,500중량부, 성능개선제 0.1 내지 10중량부, 나노세라믹 입자 0.1 내지 5중량부, 셀룰로오스 섬유 0.1 내지 2중량부, 상용화제 0.1 내지 5중량부, 안정제 1 내지 3중량부, 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 타설하는 타설단계;On the target surface where the cleaning step is completed, based on 100 parts by weight of asphalt, 1 to 30 parts by weight of styrene butadiene styrene, 1 to 30 parts by weight of petroleum resin, 800 to 1,500 parts by weight of aggregate, 0.1 to 10 parts by weight of performance improver, nanoceramic A pouring step of pouring a low-noise drainable asphalt concrete composition containing 0.1 to 5 parts by weight of particles, 0.1 to 2 parts by weight of cellulose fibers, 0.1 to 5 parts by weight of a compatibilizer, 1 to 3 parts by weight of a stabilizer, and 0.1 to 5 parts by weight of an anti-stripping agent. ;
상기 타설단계가 종료된 후 다지는 다짐단계; 및A compaction step of compaction after the pouring step is completed; and
상기 다짐단계가 종료된 후 양생하는 양생단계를 포함한다.It includes a curing step of curing after the compaction step is completed.
이하에서 실시예를 통하여 본 발명을 구체적으로 설명하기로 한다. 그러나 하기의 실시예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로 이들 실시예에 의해 본 발명의 범위를 한정하는 것은 아니다.Hereinafter, the present invention will be described in detail through examples. However, the following examples are only for illustrating the present invention in detail and do not limit the scope of the present invention by these examples.
[실시예 1][Example 1]
침입도 70의 스트레이트 아스팔트 100g, 신율이 약 850%인 스티렌부타디엔스티렌 15g, 점도가 약 120cps인 지방족 C-5석유수지 15g, 평균입도가 약 1mm 내지 3mm의 모래와 약 5 내지 7mm의 자갈이 1:1의 중량비율로 혼합된 골재 1,100g, 비닐아세테이트 모노머-파라핀오일 95중량% 및 과산화벤조일 5중량%를 포함하는 성능개선제 5g, 평균입경이 약 400nm인 실리콘카바이드 3g, 천연 셀룰로오스 섬유 1g, 폴리인산 3g, 아크릴 폴리올 수지 2g, 및 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제 3g을 혼합하여 저소음 배수성 아스팔트 콘크리트 조성물을 제조하였다.100 g of straight asphalt with a penetration degree of 70, 15 g of styrene-butadiene-styrene with an elongation of about 850%, 15 g of aliphatic C-5 petroleum resin with a viscosity of about 120 cps, sand with an average particle size of about 1 mm to 3 mm and gravel with an average particle size of about 5 to 7 mm. :1,100g of aggregate mixed at a weight ratio of 1, 5g of performance improver containing 95% by weight of vinyl acetate monomer-paraffin oil and 5% by weight of benzoyl peroxide, 3g of silicon carbide with an average particle diameter of about 400nm, 1g of natural cellulose fiber, poly A low-noise, drainable asphalt concrete composition was prepared by mixing 3g of phosphoric acid, 2g of acrylic polyol resin, and 3g of a liquid type polyphosphoric acid-based anti-stripping agent with a specific gravity of 1.0 or more and a viscosity of 110 cPs at 60°C.
[실시예 2][Example 2]
실시예 1과 동일한 방법으로 실시하되, 황산망간 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of manganese sulfate was additionally added.
[실시예 3][Example 3]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 방해석 분말 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of calcite powder with an average particle size of 3 ㎛ was additionally added.
[실시예 4][Example 4]
실시예 1과 동일한 방법으로 실시하되, 폴리비닐리덴플로라이드수지 1g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 1 g of polyvinylidene fluoride resin was additionally added.
[실시예 5][Example 5]
실시예 1과 동일한 방법으로 실시하되, 트리메틸올프로판 트리아크릴레이트 1g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 1 g of trimethylolpropane triacrylate was additionally added.
[실시예 6][Example 6]
실시예 1과 동일한 방법으로 실시하되, 폴리옥시에틸렌노닐페닐에테르 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of polyoxyethylenenonylphenyl ether was additionally added.
[실시예 7][Example 7]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 2㎛인 니켈슬래그 분말 1g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 1 g of nickel slag powder with an average particle size of 2 μm was added.
[실시예 8][Example 8]
실시예 1과 동일한 방법으로 실시하되, 디이소노닐프탈레이트 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of diisononyl phthalate was additionally added.
[실시예 9][Example 9]
실시예 1과 동일한 방법으로 실시하되, 토코페릴아세테이트 1g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 1 g of tocopheryl acetate was additionally added.
[실시예 10][Example 10]
실시예 1과 동일한 방법으로 실시하되, 다이머산 1g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the additional addition of 1 g of dimer acid.
[실시예 11][Example 11]
실시예 1과 동일한 방법으로 실시하되, 소듐벤조에이트 0.5g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 0.5 g of sodium benzoate.
[실시예 12][Example 12]
실시예 1과 동일한 방법으로 실시하되, 아세틸레이티드라놀란 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of acetylated dranolan was added.
[실시예 13][Example 13]
실시예 1과 동일한 방법으로 실시하되, 스테아린산 알루미늄 2g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 2 g of aluminum stearate.
[실시예 14][Example 14]
실시예 1과 동일한 방법으로 실시하되, 세리사이트 2g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 2g of sericite.
[실시예 15][Example 15]
실시예 1과 동일한 방법으로 실시하되, 세피올라이트 3g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 3 g of sepiolite.
[실시예 16][Example 16]
실시예 1과 동일한 방법으로 실시하되, 폴리트리메틸렌테레프탈레이트 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of polytrimethylene terephthalate was additionally added.
[실시예 17][Example 17]
실시예 1과 동일한 방법으로 실시하되, 3-메르캅토프로필트리메톡시실란 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of 3-mercaptopropyltrimethoxysilane was additionally added.
[실시예 18][Example 18]
실시예 1과 동일한 방법으로 실시하되, 디부틸하이드록시톨루엔 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of dibutylhydroxytoluene was additionally added.
[실시예 19][Example 19]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 순지트 미분말 1g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 1 g of Sunjit fine powder with an average particle size of 3㎛.
[실시예 20][Example 20]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 아노르싸이트 미분말 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of anorsite fine powder with an average particle size of 3 ㎛ was additionally added.
[실시예 21][Example 21]
실시예 1과 동일한 방법으로 실시하되, 스타치 포스페이트 에스테르 1g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 1 g of starch phosphate ester.
[실시예 22][Example 22]
실시예 1과 동일한 방법으로 실시하되, 평균입경이 500 nm인 수산화바륨티타네이트 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of barium titanate with an average particle diameter of 500 nm was additionally added.
[실시예 23][Example 23]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 피프로퍼라이트 미분말 2g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, except that 2 g of pproperite fine powder with an average particle size of 3㎛ was added.
[실시예 24][Example 24]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 질화갈륨 미분말 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of gallium nitride fine powder with an average particle size of 3 μm was added.
[실시예 25][Example 25]
실시예 1과 동일한 방법으로 실시하되, 스멕타이트 2g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the additional addition of 2 g of smectite.
[실시예 26][Example 26]
실시예 1과 동일한 방법으로 실시하되, 호박산 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of succinic acid was additionally added.
[실시예 27][Example 27]
실시예 1과 동일한 방법으로 실시하되, 폴리클로로트리플루오로에틸렌 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of polychlorotrifluoroethylene was additionally added.
[실시예 28][Example 28]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 난각막 미분말 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of egg shell membrane fine powder with an average particle size of 3 μm was added.
[실시예 29][Example 29]
실시예 1과 동일한 방법으로 실시하되, 글루코노락톤 2g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 2 g of gluconolactone.
[실시예 30][Example 30]
실시예 1과 동일한 방법으로 실시하되, 디스테아릴 펜타에리트리톨 디포스페이트 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of distearyl pentaerythritol diphosphate was added.
[실시예 31][Example 31]
실시예 1과 동일한 방법으로 실시하되, 구아검 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of guar gum was added.
[실시예 32][Example 32]
실시예 1과 동일한 방법으로 실시하되, 이타코닉 산 3g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 3 g of itaconic acid.
[실시예 33][Example 33]
실시예 1과 동일한 방법으로 실시하되, 에틸렌 비스 스테아마이드 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of ethylene bisstamide was added.
[실시예 34][Example 34]
실시예 1과 동일한 방법으로 실시하되, 적동석 2g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 2 g of red copper stone.
[실시예 35][Example 35]
실시예 1과 동일한 방법으로 실시하되, 인산지르코늄 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of zirconium phosphate was added.
[실시예 36][Example 36]
실시예 1과 동일한 방법으로 실시하되, 카르복시메틸 키토산 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of carboxymethyl chitosan was added.
[실시예 37][Example 37]
실시예 1과 동일한 방법으로 실시하되, 평균입도가 3㎛인 마그네사이트 미분말 3g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 3 g of fine magnesite powder with an average particle size of 3 μm was added.
[실시예 38][Example 38]
실시예 1과 동일한 방법으로 실시하되, 2-브로모피리딘 5g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 5 g of 2-bromopyridine.
[실시예 39][Example 39]
실시예 1과 동일한 방법으로 실시하되, 규산나트륨과 규사가 1:1의 중량비율로 혼합된 규산나트륨 및 규사 혼합물 5g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, except that 5 g of a mixture of sodium silicate and silica sand mixed at a weight ratio of 1:1 was added.
[실시예 40][Example 40]
실시예 1과 동일한 방법으로 실시하되, 트리칼슘알루미네이트 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of tricalcium aluminate was added.
[실시예 41][Example 41]
실시예 1과 동일한 방법으로 실시하되, 아미노메틸폴리스티렌 수지 2g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the addition of 2 g of aminomethylpolystyrene resin.
[실시예 42][Example 42]
실시예 1과 동일한 방법으로 실시하되, 산화티탄 2g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 2 g of titanium oxide was added.
[실시예 43][Example 43]
실시예 1과 동일한 방법으로 실시하되, 이황화 몰리브덴 3g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 3 g of molybdenum disulfide.
[실시예 44][Example 44]
실시예 1과 동일한 방법으로 실시하되, 근교린 3g을 더 부가하여 실시하였다.This was carried out in the same manner as Example 1, but with the additional addition of 3 g of Gyeongyorin.
[실시예 45][Example 45]
실시예 1과 동일한 방법으로 실시하되, 메타인산 나트륨 2g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 2 g of sodium metaphosphate.
[실시예 46][Example 46]
실시예 1과 동일한 방법으로 실시하되, 규산알루미늄 2g을 더 부가하여 실시하였다.This was carried out in the same manner as in Example 1, but with the addition of 2 g of aluminum silicate.
[실시예 47][Example 47]
실시예 1과 동일한 방법으로 실시하되, 산화제일구리 1g을 더 부가하여 실시하였다.The same method as Example 1 was performed, except that 1 g of cuprous oxide was additionally added.
[실시예 48][Example 48]
실시예 1과 동일한 방법으로 실시하되, 실시예 2 내지 실시예 47에 따라 부가된 부가물을 모두 부가하여 실시하였다.This was carried out in the same manner as Example 1, except that all the additives added according to Examples 2 to 47 were added.
[실험][Experiment]
실시예들에 따라 제조된 조성물을 이용하여 약 60mm 두께의 아스팔트 콘크리트층을 제조한 후 공극률, 소음성, 간접인장강도, 변형강도, 회전점도(Rotational Viscosity) 등을 측정하였고, 약 60mm 두께의 아스팔트 콘크리트층을 제조하여 동적안정도를 측정하여 표 1로 나타냈다.After manufacturing an asphalt concrete layer with a thickness of about 60 mm using the composition prepared according to the examples, porosity, noise properties, indirect tensile strength, strain strength, rotational viscosity, etc. were measured, and asphalt with a thickness of about 60 mm was measured. The concrete layer was manufactured and the dynamic stability was measured and shown in Table 1.
여기서, 동적안정도는 소성변형 저항성 평가로 Kim Test에 의한 변형강도 시험과 시험을 통해 측정하고, 간접인강도는 균열 저항성을 평가하기 위해 진행되었다.Here, dynamic stability was measured through deformation strength tests and tests using the Kim Test to evaluate plastic deformation resistance, and indirect tensile strength was conducted to evaluate crack resistance.
(pass/mm)Dynamic stability
(pass/mm)
(ITS)Indirect tensile strength
(ITS)
(Mpa)strain strength
(Mpa)
표 1에 나타낸 바와 같이, 저소음 배수성 아스팔트 콘크리트 조성물을 사용한 실시예들의 공극률, 소음성, 동적안정도, 간접인장강도 및 변형강도가 좋고, 회전점도가 110 내지 130℃에서 적어도 1200 이상이었다.As shown in Table 1, the porosity, noise properties, dynamic stability, indirect tensile strength, and deformation strength of the examples using the low-noise drainage asphalt concrete composition were good, and the rotational viscosity was at least 1200 or more at 110 to 130 ° C.
이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.As described above, a person skilled in the art to which the present invention pertains will understand that the present invention can be implemented in other specific forms without changing its technical idea or essential features. Therefore, all embodiments described above should be understood as illustrative and not restrictive. The scope of the present invention should be construed as including all changes or modified forms derived from the meaning and scope of the claims described below and their equivalent concepts rather than the detailed description above.
Claims (5)
스티렌부타디엔스티렌 1 내지 30중량부;
석유수지 1 내지 30중량부;
골재 800 내지 1,500중량부;
성능개선제 0.1 내지 10중량부;
나노세라믹 입자 0.1 내지 5중량부;
셀룰로오스 섬유 0.1 내지 2중량부;
상용화제 0.1 내지 5중량부;
안정제 1 내지 3중량부; 및
박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물에,
황산망간을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
폴리비닐리덴플로라이드수지를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
디이소노닐프탈레이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고,
토코페릴아세테이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
피브로퍼라이트 미분말을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하고,
질화갈륨 미분말을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
스멕타이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고,
글루코노락톤을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며,
이타코닉 산을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
적동석을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며,
카르복시메틸 키토산을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고,
산화티탄을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하는 저소음 배수성 아스팔트 콘크리트 조성물.
Based on 100 parts by weight of asphalt,
1 to 30 parts by weight of styrene butadiene styrene;
1 to 30 parts by weight of petroleum resin;
800 to 1,500 parts by weight of aggregate;
0.1 to 10 parts by weight of a performance improver;
0.1 to 5 parts by weight of nanoceramic particles;
0.1 to 2 parts by weight of cellulose fiber;
0.1 to 5 parts by weight of compatibilizer;
1 to 3 parts by weight of stabilizer; and
A low-noise, drainable asphalt concrete composition containing 0.1 to 5 parts by weight of an anti-stripping agent,
Manganese sulfate is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt,
It further contains 0.1 to 3 parts by weight of polyvinylidene fluoride resin based on 100 parts by weight of asphalt,
It further contains 0.1 to 3 parts by weight of diisononyl phthalate based on 100 parts by weight of asphalt,
Tocopheryl acetate is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
Fibroperite fine powder is further included in an amount of 1 to 3 parts by weight based on 100 parts by weight of asphalt,
It further contains 0.1 to 3 parts by weight of gallium nitride fine powder based on 100 parts by weight of asphalt,
Smectite is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
It further contains 1 to 5 parts by weight of gluconolactone based on 100 parts by weight of asphalt,
Itaconic acid is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt,
Red copper stone is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt,
Carboxymethyl chitosan is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
A low-noise, drainable asphalt concrete composition further comprising 1 to 3 parts by weight of titanium oxide based on 100 parts by weight of asphalt.
상기 정리단계가 종료된 대상면에 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 1 내지 30중량부, 석유수지 1 내지 30중량부, 골재 800 내지 1,500중량부, 성능개선제 0.1 내지 10중량부, 나노세라믹 입자 0.1 내지 5중량부, 셀룰로오스 섬유 0.1 내지 2중량부, 상용화제 0.1 내지 5중량부, 안정제 1 내지 3중량부, 및 박리방지제 0.1 내지 5중량부를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물에, 황산망간을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 폴리비닐리덴플로라이드수지를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 디이소노닐프탈레이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고, 토코페릴아세테이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 피브로퍼라이트 미분말을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하고, 질화갈륨 미분말을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 스멕타이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고, 글루코노락톤을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며, 이타코닉 산을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 적동석을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며, 카르복시메틸 키토산을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고, 산화티탄을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하는 저소음 배수성 아스팔트 콘크리트 조성물을 타설하는 타설단계;
상기 타설단계가 종료된 후 다지는 다짐단계; 및
상기 다짐단계가 종료된 후 양생하는 양생단계를 포함하는 저소음 배수성 아스팔트 콘크리트 조성물의 시공방법.
A cleaning step of organizing the surface to be constructed;
On the target surface where the cleaning step is completed, based on 100 parts by weight of asphalt, 1 to 30 parts by weight of styrene butadiene styrene, 1 to 30 parts by weight of petroleum resin, 800 to 1,500 parts by weight of aggregate, 0.1 to 10 parts by weight of performance improver, nanoceramic Manganese sulfate is added to a low-noise drainable asphalt concrete composition containing 0.1 to 5 parts by weight of particles, 0.1 to 2 parts by weight of cellulose fibers, 0.1 to 5 parts by weight of a compatibilizer, 1 to 3 parts by weight of a stabilizer, and 0.1 to 5 parts by weight of an anti-stripping agent. It further contains 1 to 5 parts by weight based on 100 parts by weight of asphalt, polyvinylidene fluoride resin is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, and diisononyl phthalate is contained in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of asphalt. It further contains 3 parts by weight, tocopheryl acetate is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, and fibroperite fine powder is further included in an amount of 1 to 3 parts by weight based on 100 parts by weight of asphalt, and gallium nitride fine powder is added. It further contains 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, smectite is further included at 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, and gluconolactone is further included at 1 to 5 parts by weight based on 100 parts by weight of asphalt. , itaconic acid is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt, red copper stone is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt, and carboxymethyl chitosan is included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt. A pouring step of pouring a low-noise, drainable asphalt concrete composition further comprising 1 to 3 parts by weight of titanium oxide based on 100 parts by weight of asphalt;
A compaction step of compaction after the pouring step is completed; and
A construction method of a low-noise, drainable asphalt concrete composition comprising a curing step after the compaction step is completed.
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