KR102612175B1 - Cup sleeve - Google Patents
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- KR102612175B1 KR102612175B1 KR1020210045131A KR20210045131A KR102612175B1 KR 102612175 B1 KR102612175 B1 KR 102612175B1 KR 1020210045131 A KR1020210045131 A KR 1020210045131A KR 20210045131 A KR20210045131 A KR 20210045131A KR 102612175 B1 KR102612175 B1 KR 102612175B1
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- South Korea
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- cup
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- sleeve
- sleeve body
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Images
Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G23/00—Other table equipment
- A47G23/02—Glass or bottle holders
- A47G23/0208—Glass or bottle holders for drinking-glasses, plastic cups, or the like
- A47G23/0216—Glass or bottle holders for drinking-glasses, plastic cups, or the like for one glass or cup
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
- C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Abstract
본 발명은 컵 슬리브에 관한 것으로, 더욱 상세하게는 컵이 수용되어 지지되는 중공부가 형성된 슬리브본체(100)를 포함하되, 상기 슬리브본체(100)는 종이(1), 상기 종이(1)에 라미네이팅된 바이오 플라스틱 필름(2), 및 상기 바이오 플라스틱 필름(2)에 형성된 항균 코팅층(3)을 포함하는 것을 특징으로 한다. 본 발명의 컵 슬리브에 의하면, 세균으로 인한 오염이 없어 위생적이고, 슬리브본체의 수분 차단성을 높여 사용시 불편함이 없으며, 우수한 단열성을 발휘하여 음료를 냉기 또는 온기를 장시간 유지할 수 있으며, 환경오염을 방지할 수 있다는 장점이 있다.The present invention relates to a cup sleeve, and more specifically, includes a sleeve body 100 formed with a hollow portion for receiving and supporting a cup, wherein the sleeve body 100 is made of paper (1) and laminated to the paper (1). It is characterized in that it includes a bioplastic film (2), and an antibacterial coating layer (3) formed on the bioplastic film (2). According to the cup sleeve of the present invention, it is hygienic because there is no contamination caused by bacteria, there is no inconvenience during use by increasing the moisture barrier of the sleeve body, and it exhibits excellent insulation properties to keep drinks cold or warm for a long time, preventing environmental pollution. It has the advantage of being preventable.
Description
본 발명은 컵 슬리브에 관한 것으로, 더욱 상세하게는 슬리브본체를 종이, 바이오 플라스틱 필름 및 항균 코팅층으로 구성함으로써, 세균으로 인한 오염이 없어 위생적이고, 슬리브본체가 물에 젖지 않아 사용시 불편함이 없으며, 환경오염을 방지할 수 있는 컵 슬리브에 관한 것이다.The present invention relates to a cup sleeve, and more specifically, the sleeve body is composed of paper, bioplastic film, and an antibacterial coating layer, so it is hygienic because there is no contamination caused by bacteria, and the sleeve body does not get wet, so there is no inconvenience during use. This is about a cup sleeve that can prevent environmental pollution.
일반적으로 뜨거운 커피나 음료를 수용하기 위하여 커피 전문점 등에서는 종이컵이 많이 사용된다. 이러한 종이컵은 대부분 두께가 상당히 얇은 종이를 성형하여 일회용으로 제작되고, 음료수를 담아 간편하게 음용한 후 버릴 수 있도록 되어 있다. 이러한 종이컵은 대부분 두께가 상당히 얇은 종이를 성형하여 일회용으로 제작되고, 음료수를 담아 간편하게 음용한 후 버릴 수 있도록 되어 있다.In general, paper cups are widely used in coffee shops to accommodate hot coffee or beverages. Most of these paper cups are made for disposable use by molding fairly thin paper, and are designed to be easily consumed after holding beverages and then discarded. Most of these paper cups are made for disposable use by molding fairly thin paper, and are designed to be easily consumed after holding beverages and then discarded.
이러한 종이컵에 뜨거운 음료를 담게 되면, 음료의 뜨거운 온도(약 80도 이상)가 종이컵을 통해 곧바로 사용자의 손에 전달되어 종이컵을 파지하기 어려울 수 있다. 또한, 종이컵에 담긴 뜨거운 음료가 마시기 적당한 온도로 식을 때까지 기다려야 하므로 많은 시간이 소모되게 된다. 따라서, 음료가 담긴 종이컵을 감싸도록 띠 형태로 형성되는 종이 재질의 컵 슬리브를 사용한다.When a hot beverage is placed in such a paper cup, the hot temperature of the beverage (approximately 80 degrees or more) is transmitted directly to the user's hand through the paper cup, making it difficult to hold the paper cup. Additionally, a lot of time is wasted because you have to wait for the hot beverage in the paper cup to cool to an appropriate temperature for drinking. Therefore, a cup sleeve made of paper, which is formed in a strip shape to surround a paper cup containing a beverage, is used.
또한, 차가운 음료를 수용하기 위해서는 대부분 얇은 플라스틱컵을 사용하는데, 이 역시 음료의 차가운 온도가 플라스틱컵을 통해 곧바로 사용자의 손에 전달되지 않도록 종이 재질의 컵 슬리브를 사용한다. Additionally, in order to accommodate cold drinks, most people use thin plastic cups, which also use paper cup sleeves to prevent the cold temperature of the drink from being transferred directly to the user's hands through the plastic cup.
이러한 컵 슬리브는 주로 골판지 형태로서 평상시에는 접혀진 상태에 있다가 사용시에는 중심부에 공간이 생기도록 펼쳐진 후 컵에 끼우는 제품이 주종을 이루고 있다.These cup sleeves are mainly in the form of cardboard and are usually folded, but when in use, they are unfolded to create a space in the center and then inserted into the cup.
그러나 이러한 종이 재질의 컵 슬리브는 판매자 또는 사용자가 계속해서 파지하게 되는 부분으로, 세균 및 바이러스에 의한 오염을 막을 수 없다는 문제가 있다. 아울러, 차가운 음료가 수용된 컵의 표면에 온도차에 의해 물방울이 맺히게 되면 종이 재질의 컵 슬리브가 이를 흡수하여 젖게 되므로, 쉽게 찢어지거나 사용자의 손에 물기가 묻게 되며, 종이 냄새가 손에 배게 되는 등의 사용상의 불편함이 있다.However, this cup sleeve made of paper is a part that is continuously held by sellers or users, and there is a problem in that it cannot prevent contamination by bacteria and viruses. In addition, when water droplets form on the surface of a cup containing a cold beverage due to a temperature difference, the paper cup sleeve absorbs it and becomes wet, which can easily tear or cause moisture to stick to the user's hands, leaving the smell of paper on the hands. There are inconveniences in use.
이를 해소하기 위하여 일부 매장에서는 종이 재질의 컵 슬리브에 플라스틱 필름층을 형성하여 사용하고 있다. 그러나 종이 재질에 플라스틱이 혼합되면, 자연상태에 버려진 후 분해가 되지 않아 심각한 환경오염을 초래하는 문제가 있다.To solve this problem, some stores are using a plastic film layer on paper cup sleeves. However, when plastic is mixed with paper material, there is a problem that it does not decompose after being discarded in nature, causing serious environmental pollution.
또한, 이러한 컵 슬리브는 파지시 사용자의 손을 열기 또는 냉기로부터 보호할 뿐, 단열성이 없어 커피 등의 음료가 쉽게 식는 단점이 있었다.In addition, these cup sleeves only protect the user's hands from heat or cold when gripped, but have a disadvantage in that beverages such as coffee easily cool down due to lack of insulation.
따라서, 본 발명의 목적은 상기한 종래의 컵 슬리브가 갖는 제반문제점을 해소하기 위한 것으로, 슬리브본체를 종이, 바이오 플라스틱 필름 및 항균 코팅층으로 구성함으로써, 세균으로 인한 오염이 없어 위생적이고, 슬리브본체가 물에 젖지 않아 사용시 불편함이 없으며, 환경오염을 방지할 수 있는 컵 슬리브를 제공하는 데 있다.Therefore, the purpose of the present invention is to solve the problems of the conventional cup sleeve described above. By composing the sleeve body with paper, bioplastic film, and an antibacterial coating layer, there is no contamination due to bacteria, so it is hygienic, and the sleeve body is hygienic. The goal is to provide a cup sleeve that does not get wet, so there is no inconvenience when using it and prevents environmental pollution.
본 발명의 다른 목적은 커피찌꺼기를 이용하여 단열층을 형성함으로써, 환경오염의 야기 없이 우수한 단열성을 발휘할 수 있도록 하는 컵 슬리브를 제공하는 데 있다.Another object of the present invention is to provide a cup sleeve that can exhibit excellent insulation properties without causing environmental pollution by forming an insulation layer using coffee grounds.
상기한 목적을 달성하기 위한 본 발명의 컵 슬리브는, 컵이 수용되어 지지되는 중공부가 형성된 슬리브본체를 포함하되, 상기 슬리브본체는 종이, 상기 종이에 라미네이팅된 바이오 플라스틱 필름, 및 상기 바이오 플라스틱 필름에 형성된 항균 코팅층을 포함하는 것을 특징으로 한다.The cup sleeve of the present invention for achieving the above object includes a sleeve body in which a hollow portion is formed to receive and support a cup, wherein the sleeve body is made of paper, a bioplastic film laminated to the paper, and the bioplastic film. It is characterized by comprising a formed antibacterial coating layer.
상기 바이오 플라스틱 필름은, 식물체 유래의 전분계 바이오매스, 식물체 유래의 셀룰로오스계 바이오매스 또는 이들 모두; 왁스; 계면활성제; 불가사리로부터 추출된 단백질; 순지트 파우더; 및 폴리에틸렌;을 포함하는 것을 특징으로 한다. The bioplastic film may include plant-derived starch-based biomass, plant-derived cellulose-based biomass, or both. wax; Surfactants; Protein extracted from starfish; shungite powder; and polyethylene.
상기 항균 코팅층은, 연 추출물 및 은행나무 추출물을 포함하는 것을 특징으로 한다. The antibacterial coating layer is characterized in that it contains lotus extract and ginkgo biloba extract.
상기 바이오 플라스틱 필름과 상기 항균 코팅층 사이에 단열층이 추가로 형성되되, 상기 단열층은 젤라틴, 카라기난, 커피찌꺼기 및 후코이단을 포함하는 것을 특징으로 한다.An insulating layer is additionally formed between the bioplastic film and the antibacterial coating layer, and the insulating layer includes gelatin, carrageenan, coffee grounds, and fucoidan.
본 발명의 컵 슬리브에 의하면, 세균으로 인한 오염이 없어 위생적이고, 슬리브본체의 수분 차단성을 높여 사용시 불편함이 없으며, 우수한 단열성을 발휘하여 음료의 냉기 또는 온기를 장시간 유지할 수 있으며, 환경오염을 방지할 수 있다는 장점이 있다.According to the cup sleeve of the present invention, it is hygienic because there is no contamination caused by bacteria, there is no inconvenience during use by increasing the moisture barrier of the sleeve body, and it exhibits excellent insulation properties to maintain the cold or warmth of the beverage for a long time, preventing environmental pollution. It has the advantage of being preventable.
도 1은 본 발명에 의한 컵 슬리브의 사용상태를 나타낸 사시도.
도 2는 본 발명에 의한 슬리브본체의 전개도.
도 3 내지 도 5는 본 발명에 의한 전개된 슬리브본체의 횡방향 단면도.Figure 1 is a perspective view showing the use state of the cup sleeve according to the present invention.
Figure 2 is an exploded view of the sleeve body according to the present invention.
3 to 5 are transverse cross-sectional views of the expanded sleeve body according to the present invention.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명의 가장 큰 특징은, 종이, 바이오 플라스틱 필름 및 항균 코팅층을 포함하여 슬리브본체를 구성함으로써, 환경오염을 야기하지 않으면서도 습기에 강해 사용에 불편함이 없으며, 항균성이 우수하여 세균의 오염을 방지할 수 있도록 하는 데 있다.The biggest feature of the present invention is that the sleeve body includes paper, bioplastic film, and an antibacterial coating layer, so it does not cause environmental pollution, is resistant to moisture, so there is no inconvenience in use, and has excellent antibacterial properties to prevent bacterial contamination. It's about being able to do it.
이를 위한 본 발명의 컵 슬리브는, 도 1 내지 도 5와 같이, 컵이 수용되어 지지되는 중공부가 형성된 슬리브본체(100)를 포함하되, 상기 슬리브본체(100)는 종이(1), 상기 종이(1)에 라미네이팅된 바이오 플라스틱 필름(2), 및 상기 바이오 플라스틱 필름(2)에 형성된 항균 코팅층(3)을 포함하는 것을 특징으로 한다.For this purpose, the cup sleeve of the present invention includes a
이하, 첨부된 도 1 내지 5를 참조하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the attached FIGS. 1 to 5.
먼저, 상기 슬리브본체(100)는 도 1, 2와 같이 컵이 수용되어 지지되는 중공부가 형성된 것으로, 전개시 일정한 폭을 가지는 띠로 이루어지며, 횡방향 양측 단부가 결합되어 중공부를 갖는 고리 형상을 형성하는 것이다. First, the
이때, 상기 슬리브본체(100)는 도 2와 같이, 전개시 횡방향 일측 단부에 형성된 접합부(110)를 포함할 수 있는바, 상기 접합부(110)가 타단에 접착되어 컵이 수용되어 지지되는 중공부가 형성되는 것이다. At this time, as shown in Figure 2, the
아울러, 상기 슬리브본체(100)는 부채꼴로 전개되는 형상으로 이루어질 수 있으며, 이에 따라 연장방향의 양측부가 결합되면 하부의 직경보다 상부의 직경이 더 크게 형성된 중공부가 형성될 수도 있는 것으로, 그 형상은 컵의 형상에 따라 다양한 형태로 변형될 수 있음은 당연하다. 즉, 상기 슬리브본체(100)의 형태, 접합부, 접합방법 등은 이 기술이 속하는 분야에서 이미 충분히 공지된 사항으로, 본 발명에서는 그 변형 실시를 제한하지 않는다.In addition, the
본 발명에서 상기 슬리브본체(100)는 도 3과 같이, 종이(1), 바이오 플라스틱(2) 및 항균 코팅층(3)으로 구성된다.In the present invention, the
먼저, 상기 종이(1)는 슬리브본체(100)에 삽입되는 컵(10)의 외주면과 맞닿는 면으로, 컵(10)의 외주면에 맺히는 물방울을 흡수함은 물론, 컵(10)으로부터 전달되는 열기나 냉기를 차단하는 역할을 한다. First, the paper 1 is a surface in contact with the outer peripheral surface of the
본 발명에서 상기 종이(1)는 도 3과 같이 평평한 형상일 수도 있지만, 도 4와 같이, 전체적으로 횡방향을 따라 주름이 잡힌 형상, 즉, 기재(11)에 골심지(12)가 형성된 골판지의 형상을 가질 수도 있다. 이러한 골판지의 형상을 가지면, 골심지(12)에 의해 형성된 공간부(13)는 슬리브에 삽입된 컵(10)으로부터 방출된 열기 또는 냉기를 수용한 상태에서 음료를 보온하거나 차가운 상태를 유지하는 기능을 하게되어, 컵(10)에 수용된 음료을 따뜻하거나 차갑게 유지시키는 역할을 한다.In the present invention, the paper 1 may have a flat shape as shown in Figure 3, but as shown in Figure 4, the shape is wrinkled along the overall transverse direction, that is, the shape of corrugated cardboard with a corrugated medium 12 formed on the base material 11. You can also have With this corrugated cardboard shape, the space 13 formed by the corrugated medium 12 has the function of keeping the beverage warm or cold while accommodating the heat or cold air emitted from the
본 발명에서 이러한 종이(1)의 형상은 선택사항으로, 그 형태를 제한하지 않음은 당연하다. In the present invention, the shape of the paper 1 is optional, and the shape is naturally not limited.
또한, 상기 종이(1)는 sc마닐라지, 모조지, 아트지 및 스노우지 중 어떠한 것이라도 사용 가능한바, 이를 제한하지 않으며, 그 두께 역시 제한하지 않는다. In addition, the paper 1 can be any of sc manila paper, vellum paper, art paper, and snow paper, and is not limited thereto, and its thickness is also not limited.
상기 종이(1)에 라미네이트되는 바이오 플라스틱 필름(2)은, 슬리브본체(100)의 강도를 개선하는 것은 물론, 종이(1)에 흡수된 수분의 전달을 차단시켜 사용자의 손에 수분이 전달되지 않도록 함으로써, 사용 편의성을 개선하는 역할을 한다. The bioplastic film 2 laminated to the paper 1 not only improves the strength of the
종래 이러한 기능을 위하여 일반 합성수지 필름을 사용하였는바, 이러한 합성수지 필름은 폐기시 환경오염을 야기한다는 단점이 있었다. 본 발명은 이러한 단점을 해소하기 위하여 바이오 플라스틱 필름(2)을 적용하는 것이다.Conventionally, general synthetic resin films were used for this function, but these synthetic resin films had the disadvantage of causing environmental pollution when disposed of. The present invention applies the bioplastic film (2) to solve these shortcomings.
상기 바이오 플라스틱 필름(2)은 바이오매스를 원료를 포함하는 합성수지를 의미하는 것으로, 대기 중의 탄소가 광합성에 의해 고정된 식물자원을 원료로 사용함으로써, 대기 중의 이산화탄소의 농도가 증가하는 것을 억제하고, 한정된 자원인 석유의 소비량을 줄일 수 있으며, 폐기 후에는 미생물에 의해 분해되기 때문에 친환경적이라는 장점이 있다. The bioplastic film 2 refers to a synthetic resin containing biomass as a raw material. By using plant resources in which carbon in the atmosphere is fixed through photosynthesis as a raw material, it suppresses the increase in the concentration of carbon dioxide in the atmosphere, It can reduce the consumption of petroleum, a limited resource, and has the advantage of being environmentally friendly because it is decomposed by microorganisms after disposal.
본 발명에서 상기 바이오 플라스틱 필름(2)은 바이오매스를 10~90중량%로 포함하는 것이라면 그 종류를 제한하지 않고 사용 가능하다. 다만, 그 생분해성, 물성 등을 고려할 때, 하기와 같이 구성함이 가장 바람직하다.In the present invention, the bioplastic film 2 can be used without limitation as long as it contains 10 to 90% by weight of biomass. However, considering its biodegradability, physical properties, etc., it is most preferable to configure it as follows.
즉, 상기 바이오 플라스틱 필름(2)은 식물체 유래의 전분계 바이오매스, 식물체 유래의 셀룰로오스계 바이오매스 또는 이들 모두; 왁스; 계면활성제; 불가사리로부터 추출된 단백질; 순지트 파우더; 및 폴리에틸렌;을 포함하는 것을 특징으로 한다. 더욱 구체적으로, 식물체 유래의 전분계 바이오매스, 식물체 유래의 셀룰로오스계 바이오매스 또는 이들 모두 10~70중량%; 왁스 5~10중량%; 계면활성제 0.5~5중량%; 불가사리로부터 추출된 단백질 0.5~5중량%; 순지트 파우더 0.5~5중량%; 및 잔량의 폴리에틸렌;을 포함하는 필름이다. 여기서, 상기와 같이 조성비를 제한하는 이유는 생분해성, 항균성, 기계적 물성 등을 모두 고려한 것이다.That is, the bioplastic film 2 may include plant-derived starch-based biomass, plant-derived cellulose-based biomass, or both. wax; Surfactants; Protein extracted from starfish; shungite powder; and polyethylene. More specifically, 10 to 70% by weight of plant-derived starch-based biomass, plant-derived cellulose-based biomass, or both; Wax 5-10% by weight; Surfactant 0.5-5% by weight; 0.5 to 5% by weight of protein extracted from starfish; 0.5-5% by weight of shungite powder; and a remaining amount of polyethylene. Here, the reason for limiting the composition ratio as described above is to take into account biodegradability, antibacterial properties, mechanical properties, etc.
상기 바이오매스로는 식물체 유래의 전분계 바이오매스, 식물체 유래의 셀룰로오스계 바이오매스 중 1종 이상, 가장 바람직하게는 2종 모두를 포함하는 것이다. 상기 식물체 유래의 전분계 바이오매스는, 구체적으로는, 옥수수 전분, 감자 전분, 고구마 전분, 카사바 전분, 이들의 변성 전분일 수 있고, 예를 들면, 산화전분, 양이온 전분, 크로스링키지 전분, 전분 에스테르, 이들의 결합물에서 선택되는 전분일 수 있고, 또는, 식물종자, 줄기, 뿌리, 잎을 분쇄한 가루로서, 예를 들면, 밀가루, 옥수수 가루, 쌀 가루, 찹쌀 가루, 감자 가루, 고구마 가루, 카사바가루, 이들의 결합물에서 선택되는 식물 가루일 수 있다. 또한, 식물체 유래의 셀룰로오스계 바이오매스는 구체적으로는, 나무섬유, 면섬유, 풀섬유, 갈대섬유, 대나무섬유, 이들의 변성물일 수 있고, 예를 들면, 카르복실메틸셀룰로오스, 카르복시에틸셀룰로오스, 셀룰로오스 에스테르, 셀룰로오스에테르, 및 그들의 결합물에서 선택될 수 있다.The biomass includes at least one type, most preferably both, of plant-derived starch-based biomass and plant-derived cellulose-based biomass. The starch-based biomass derived from the plant may be, specifically, corn starch, potato starch, sweet potato starch, cassava starch, and modified starches thereof, for example, oxidized starch, cationic starch, cross-linked starch, and starch ester. , may be a starch selected from a combination thereof, or may be a powder obtained by pulverizing plant seeds, stems, roots, and leaves, for example, wheat flour, corn flour, rice flour, glutinous rice flour, potato flour, sweet potato powder, It may be a plant flour selected from cassava flour or a combination thereof. In addition, plant-derived cellulosic biomass may specifically include wood fiber, cotton fiber, grass fiber, reed fiber, bamboo fiber, and modified products thereof, such as carboxymethyl cellulose, carboxyethyl cellulose, and cellulose ester. , cellulose ether, and combinations thereof.
상기 전분계 바이오매스는 수소 결합을 바탕으로 하여 입자 상을 이루고 있으며, 글루코스 단위에 붙어 있는 수산기로 인하여 수분 흡착성이 뛰어난 친수성의 물질이기에 수분의 자체함량이 10∼13%로 열을 가하여도 흐름성이 나타나지 않으며, 약 220℃ 범위에 탄화 현상 발생되며 고분자 간의 결합이 되지 않고, 빈약한 계면 접착력 때문에 기계적 물성이 떨어진다. 따라서 이의 해소를 위하여 셀룰로오스계 바이오매스를 함께 사용함으로써, 결합과 탄화현상을 방지하며, 알칼리에 강하고, 화학약품에 대한 저항성도 있고, 미생물에도 침식당하지 않는 기능을 추가할 수 있는 것이다. 따라서, 본 발명에서 상기 전분계 바이오매스와 셀룰로오스계 바이오매스는 10:1~5 중량비로 사용됨이 가장 바람직하다. 이때, 상기 바이오매스의 입자 크기는 제한하지 않는다.The starch-based biomass forms particles based on hydrogen bonds, and is a hydrophilic material with excellent moisture absorption due to the hydroxyl group attached to the glucose unit, so its moisture content is 10 to 13%, so it has flowability even when heated. does not appear, carbonization occurs in the range of about 220°C, bonding between polymers does not occur, and mechanical properties are poor due to poor interfacial adhesion. Therefore, by using cellulose-based biomass together to solve this problem, it is possible to add functions that prevent binding and carbonization, are strong against alkalis, are resistant to chemicals, and are not eroded by microorganisms. Therefore, in the present invention, it is most preferable that the starch-based biomass and cellulose-based biomass are used in a weight ratio of 10:1 to 5. At this time, the particle size of the biomass is not limited.
상기 왁스는 바이오매스와 폴리에틸렌을 연결해주는 역할을 하는 것으로, 파라핀 왁스, 유동 파라핀 왁스, 밀납, 몰다 왁스, 칸데릴라 왁스, 폴리에틸렌 왁스, 폴리프로필렌 왁스 중 선택되는 어느 하나 이상일 수 있으나, 이에 한정되지 않는다.The wax serves to connect biomass and polyethylene, and may be one or more selected from paraffin wax, liquid paraffin wax, beeswax, molda wax, candelilla wax, polyethylene wax, and polypropylene wax, but is not limited thereto. .
상기 계면활성제는 상기 바이오매스, 순지트 파우더 등을 폴리에틸렌과의 균일한 혼합을 위한 것으로, 스테아린산, 미리스트산, 팔미트산, 아라키드산, 올레인산, 리놀렌산 및 경화지방산과 같은 지방산, 글리세린, 부틸렌글리콜, 프로필렌 글리콜, 디프로필렌글리콜, 펜틸렌글리콜, 헥실렌글리콜, 폴리에틸렌글리콜 및 솔비톨과 같은 폴리올 계열 중에서 선택된 어느 하나 이상일 수 있으나 이에 한정하지 않는다.The surfactant is used to uniformly mix the biomass, shungite powder, etc. with polyethylene, and includes fatty acids such as stearic acid, myristic acid, palmitic acid, arachidic acid, oleic acid, linolenic acid, and hydrogenated fatty acids, glycerin, and butyl. It may be one or more selected from the polyol series such as lene glycol, propylene glycol, dipropylene glycol, pentylene glycol, hexylene glycol, polyethylene glycol, and sorbitol, but is not limited thereto.
상기 불가사리로부터 추출된 단백질은 바이오 플라스틱 필름(2)의 인장 강도를 좋게 하고, 생분해성을 높여주는 것은 물론, 항균성 역시 개선해주는 역할을 한다. 상기 불가사리로부터 단백질을 추출하는 방법은 종래 기술에 의하는 것으로, 그 실시를 제한하지 않는다.The protein extracted from the starfish improves the tensile strength of the bioplastic film (2), increases biodegradability, and also improves antibacterial properties. The method for extracting protein from the starfish is a conventional technique, and its practice is not limited.
상기 순지트(shungite) 파우더는, SiO2(규산염)과 C60(플러렌)을 주성분으로 하는 물질로 무기질 필러로 사용된다. 상기 순지트는 항산화 기능, 전자파 차단 기능, 오염물질의 정화 및 분해 기능, 그리고 살균 및 항균 기능이 있는 것으로, 슬리브본체(100)에 항균성을 부여한다. 아울러, 상기 순지트는 수분 차단성 역시 높여준다. 본 발명에서 상기 순지트 파우더로는 엘리트 순지트는 물론, 노멀 순지트 역시 사용 가능한 것으로, 그 종류를 제한하지 않으며, 그 입자 크기도 0.1~5㎛ 정도면 족하다.The shungite powder is a material containing SiO 2 (silicate) and C 60 (fullerene) as main components and is used as an inorganic filler. The sunjit has an antioxidant function, an electromagnetic wave blocking function, a purification and decomposition function of contaminants, and a sterilizing and antibacterial function, and provides antibacterial properties to the
그리고 상기 폴리에틸렌은 바이오 플라스틱 필름(2)의 주 수지로서, LDPE, HDPE 등 그 종류와 무관하게 사용 가능하다.And the polyethylene is the main resin of the bioplastic film (2), and can be used regardless of its type, such as LDPE or HDPE.
이러한 상기 바이오 플라스틱 필름(2)은 생분해성이 우수함은 물론, 항균성이 우수하고, 수분 차단성이 우수하며, 강도 등의 기계적 특성이 개선된다는 장점이 있다. The bioplastic film 2 has the advantage of excellent biodegradability, excellent antibacterial properties, excellent moisture barrier properties, and improved mechanical properties such as strength.
본 발명에서 상기 바이오 플라스틱 필름(2)은 그 두께가 10~300㎛일 수 있는바, 두께가 너무 두꺼울 경우 원가가 필요 이상 상승하므로 상기한 두께로 형성됨이 바람직하다.In the present invention, the bioplastic film 2 may have a thickness of 10 to 300㎛. If the thickness is too thick, the cost increases more than necessary, so it is preferable to form the bioplastic film 2 at the above-mentioned thickness.
상기 항균 코팅층(3)은 상기 바이오 플라스틱(2) 상에 코팅되어 형성되는 것으로, 슬라브본체(100)의 가장 외면에 위치하여 사용자의 손과 접촉되는 면이다. 즉, 사용자의 손과 직접 접촉되는 면으로 세균에 쉽게 노출되어 오염되는바, 상기 항균 코팅층(3)에 포함되는 연 추출물과 은행나무 추출물을 통해 항균성을 부여하는 것이다. The antibacterial coating layer 3 is formed by coating on the bioplastic 2, and is located on the outermost surface of the
더욱 구체적으로 상기 항균 코팅층(3)은 폴리우레탄 5~25중량%, 연 추출물 1~3중량%, 은행나무 추출물 1~3중량%, 침전방지제 0.5~15중량% 및 잔량의 에탄올을 포함하는 조성물을 상기 바이오 플라스틱 필름(2)에 그라비아 롤 인쇄 방식으로 도포하여 형성될 수 있다.More specifically, the antibacterial coating layer 3 is a composition containing 5 to 25% by weight of polyurethane, 1 to 3% by weight of lead extract, 1 to 3% by weight of ginkgo biloba extract, 0.5 to 15% by weight of anti-settling agent, and the remaining amount of ethanol. It can be formed by applying to the bioplastic film 2 using a gravure roll printing method.
이때, 상기 연 추출물은 연근, 연자육, 연자심, 연자방, 연잎, 연꽃 및 연줄기 중 1종 이상의 것을 용매로 추출하여 제조된 것으로, Alkaloids, Flavonoids, Steroids, Tannins, Glycosides, Polyphenols 등의 다양한 식품 화학물질(phytochemicals)를 함유하여, 우수한 항균성이 있음이 밝혀졌다.At this time, the lotus extract is manufactured by extracting one or more of lotus root, lotus root, lotus heart, lotus room, lotus leaf, lotus flower, and lotus stem with a solvent, and is used in various foods such as Alkaloids, Flavonoids, Steroids, Tannins, Glycosides, and Polyphenols. It was found that it contains phytochemicals and has excellent antibacterial properties.
상기 연 추출물은 더욱 구체적으로 연근, 연자육, 연자심, 연자방, 연잎, 연꽃 및 연줄기 중 1종 이상의 것을 20~30℃에서 1~3일간 건조하고, 이를 50~200mesh로 분쇄한 후, 이에 70~80%(v/v)의 에탄올 수용액 2~10중량배를 가하고, 30~85℃에서 2~24시간 추출한 후, 여과, 농축 및 건조하는 과정을 통해 제조할 수 있으나, 이를 반드시 제한하는 것은 아니며, 공지된 천연물로부터 추출물을 추출하는 방법 중 어떠한 방법이라도 적용 가능하다.The lotus extract is more specifically made by drying one or more of lotus root, lotus root, lotus heart, lotus room, lotus leaf, lotus flower and lotus stem at 20-30°C for 1-3 days, grinding it to 50-200 mesh, and then It can be manufactured by adding 2 to 10 times the weight of a 70 to 80% (v/v) ethanol aqueous solution, extracting at 30 to 85°C for 2 to 24 hours, and then filtering, concentrating and drying, but this must be limited. This does not mean that any method for extracting extracts from known natural products can be applied.
상기 은행나무 추출물은, 은행나무 열매, 은행잎 및 은행 줄기 중 1종 이상의 것을 용매로 추출하여 제조된 것으로, 플라보노이드 배당체와 테르펜류 화합물을 다량 포함하여 강력한 항균 효과를 발휘한다. 아울러, 상기 연 추출물과 더불어 사용될 경우, 그 항균성이 더욱 개선되어 슬리브의 세균, 바이러스 등에 의한 오염을 방지하는 것이다. The ginkgo extract is prepared by extracting one or more of ginkgo fruit, ginkgo leaves, and ginkgo stems with a solvent, and contains a large amount of flavonoid glycosides and terpene compounds, thereby exhibiting a strong antibacterial effect. In addition, when used together with the lotus extract, its antibacterial properties are further improved to prevent contamination of the sleeve by bacteria, viruses, etc.
상기 은행나무 추출물은 상기 연 추출물과 동일한 방법으로 제조될 수 있다.The ginkgo biloba extract can be prepared in the same way as the lotus extract.
상기 폴리우레탄은 예를 들어, 아크릴 변성 폴리우레탄이 사용될 수 있는데, 상기 아크릴 변성 폴리우레탄은 상기 조성물을 바이오 플라스틱 필름(2)에 부착하는 바인더로서 작용한다. 상기 아크릴 변성 폴리우레탄은 하기의 제조방법으로 제조된 아크릴 변성 폴리우레탄이 사용될 수 있으나, 이는 예시일 뿐 이 기술이 속하는 분야에서 공지된 제품을 사용하는 것도 가능함은 당연하다. The polyurethane may be, for example, an acrylic-modified polyurethane, and the acrylic-modified polyurethane acts as a binder to attach the composition to the bioplastic film 2. The acrylic-modified polyurethane may be an acrylic-modified polyurethane prepared by the following manufacturing method, but this is only an example and it is natural that products known in the field to which this technology belongs can be used.
먼저, 디이소시아네이트(Diisocyanate), 폴리올(Polyol) 및 유기용제(Organic Solvent)를 준비한 후 혼합하여 혼합액을 제조할 수 있는데, 상기 혼합액은 디이소시아네이트 1mol 및 폴리올 0.5~1.5mol의 비율로 준비되고, 상기 유기용제는 혼합액 전체 함량 중에서 60~70중량%로 포함되도록 할 수 있다. First, diisocyanate, polyol, and organic solvent can be prepared and then mixed to prepare a mixed solution. The mixed solution is prepared in a ratio of 1 mol of diisocyanate and 0.5 to 1.5 mol of polyol, and The organic solvent may be included in 60 to 70% by weight of the total mixed solution content.
상기 디이소시아네이트는 톨루엔 디이소시아네이트(Toluene diisocyanate(TDI)), 4,4'-디페닐메탄 디이소시아네이트(4,4'-Diphenylmethane diisocyanate(MDI)), 헥사메틸렌 디이소시아네이트(Hexamethylenediisocyanate(HDI)), 이소포론 디이소시아네이트(Isophorone diisocyanate(IPDI)) 및 4,4'-메틸렌비스(사이클로헥실 이소시아네이트)(4,4'-Methylenebis(cyclohexyl isocyanate)(HMDI)로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.The diisocyanate is toluene diisocyanate (TDI), 4,4'-Diphenylmethane diisocyanate (MDI), hexamethylenediisocyanate (HDI), iso Any one or more selected from the group consisting of Isophorone diisocyanate (IPDI) and 4,4'-Methylenebis(cyclohexyl isocyanate) (HMDI) may be used.
상기 폴리올은 폴리에테르 폴리올 또는 폴리에스테르 폴리올 중에서 선택된 어느 하나 이상이 사용될 수 있다.The polyol may be one or more selected from polyether polyol or polyester polyol.
상기 유기용제는 톨루엔(Toluene), 메틸에틸케톤(Methyl ethyl ketone), 에The organic solvent includes toluene, methyl ethyl ketone,
틸아세테이트(Ethyl acetate), 아세톤(Acetone) 및 디메틸포름아미드(Dimethylformamide)로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있Any one or more selected from the group consisting of ethyl acetate, acetone, and dimethylformamide may be used.
다. all.
다음으로, 상기 디이소시아네이트, 폴리올 및 유기용제로 이루어진 혼합액을 반응시켜 이소시아네이트 말단기를 가지는 폴리우레탄(Isocyanate terminated Polyurethane)을 제조할 수 있는데, 상기 반응은 83~88℃의 온도에서 3~5시간 동안 이루어질 수 있다.Next, the mixed solution consisting of the diisocyanate, polyol, and organic solvent can be reacted to produce polyurethane having an isocyanate terminal group (Isocyanate terminated polyurethane). The reaction is carried out at a temperature of 83 to 88 ° C. for 3 to 5 hours. It can be done.
그 다음으로, 상기 이소시아네이트 말단기를 가지를 폴리우레탄(Isocyanate terminated Polyurethane)에 하이드록시 그룹을 포함하는 모노머(Monomer(containing hydroxy group)) 0.1~0.5mol을 투입하면서 83~87℃의 온도 에서 2~4시간 동안 반응시켜 비닐 말단기를 가지는 폴리우레탄(Vinyl terminated polyurethane)을 제조할 수 있다. 상기 하이드록시 그룹을 포함하는 모노머(Monomer(containing hydroxy group)는 2-하이드록시에틸 메타크릴레이트(2-Hydroxyethyl methacrylate), 2-하이드록시프로필 메타크릴레이트(2-Hydroxypropyl methacrylate), 2-하히드록시에틸 아크릴레이트(2-Hydroxyethyl acrylate) 및 알릴알코올(Allyl alcohol로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.Next, 0.1 to 0.5 mol of a monomer (containing hydroxy group) containing a hydroxy group was added to the isocyanate terminated polyurethane, and the mixture was heated at a temperature of 83 to 87° C. Vinyl terminated polyurethane can be produced by reacting for 4 hours. Monomer (containing hydroxy group) is 2-Hydroxyethyl methacrylate, 2-Hydroxypropyl methacrylate, 2-Hydroxypropyl methacrylate Any one or more selected from the group consisting of 2-Hydroxyethyl acrylate and allyl alcohol may be used.
이어서, 상기 비닐 말단기를 가지는 폴리우레탄(Vinyl terminated Polyurethane)에 모노머를 투입하면서 75~80℃의 온도에서 1~3시간 동안 반응시켜 아크릴 변성 폴리우레탄을 제조할 수 있는데, 상기 비닐 말단기를 가지는 폴리우레탄 및 모노머는 각각 비닐말단기를 가지는 폴리우레탄 70~90중량% 및 모노머 10~30중량%의 중량 비율로 포함될 수 있다. 상기 모노머는 스티렌(Styrene), 메틸 메타크릴레이트(methyl methacrylate), 아크릴로니트릴(Acrylonitrile), 아크릴릭 애시드(Acrylic acid) 및 아크릴 모노머(Acrylic monomer)로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.Next, acrylic modified polyurethane can be prepared by adding a monomer to the vinyl terminated polyurethane and reacting at a temperature of 75 to 80°C for 1 to 3 hours. Polyurethane and monomer may be included in a weight ratio of 70 to 90% by weight of polyurethane having a vinyl terminal group and 10 to 30% by weight of monomer, respectively. The monomer may be any one or more selected from the group consisting of styrene, methyl methacrylate, acrylonitrile, acrylic acid, and acrylic monomer.
상기 침전방지제는 코팅 조성물을 구성하는 조성물의 침전을 방지하고 분산특성을 갖도록 하기 위하여 사용될 수있는데, 예를 들어, 상기 침전방지제로는 폴리에스터 폴리디메틸실록산 공중합체(Polyether-polydimethylsiloxane copolymer), 디메틸올 부타논산(DMBA), 디메틸올 프로피온산(DMPA), 메틸렌디에탄올아민 및 폴리에틸렌옥사이드유도체로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.The anti-settling agent may be used to prevent precipitation of the composition constituting the coating composition and to have dispersion characteristics. For example, the anti-settling agent includes polyester polydimethylsiloxane copolymer (Polyether-polydimethylsiloxane copolymer), dimethylol Any one or more selected from the group consisting of butanoic acid (DMBA), dimethylol propionic acid (DMPA), methylenediethanolamine, and polyethylene oxide derivatives may be used.
그리고 상기 에탄올은 용매로서 사용된다.And the ethanol is used as a solvent.
상기와 같이 구성되는 본 발명의 항균 코팅층(3)은 수분 차단성을 높여주면서도, 우수한 항균성을 발휘하는 것으로, 그 두께를 제한하지 않는다.The antibacterial coating layer 3 of the present invention configured as described above improves moisture barrier properties while exhibiting excellent antibacterial properties, and its thickness is not limited.
상기와 같이 구성된 본 발명의 컵 슬리브는, 우수한 수분 차단성, 항균성을 갖는바, 사용 편의성이 우수하다는 장점이 있다.The cup sleeve of the present invention configured as described above has excellent moisture barrier properties and antibacterial properties, and has the advantage of excellent ease of use.
한편, 본 발명의 일회용 컵 슬리브는, 도 5와 같이, 상기 바이오 플라스틱 필름(2)과 상기 항균 코팅층(3) 사이에 단열층(4)이 추가로 형성될 수 있다. 이는 슬리브본체(100)에 삽입되는 컵(10)에 수용된 음료의 열기나 냉기를 보호하기 위한 것으로, 따뜻한 음료나 차가운 음료를 보다 장시간 즐길 수 있도록 도움을 준다.Meanwhile, in the disposable cup sleeve of the present invention, as shown in FIG. 5, an insulating layer 4 may be additionally formed between the bioplastic film 2 and the antibacterial coating layer 3. This is to protect the heat or cold of the beverage contained in the
상기 단열층(4)은 환경오염을 야기하지 않으면서도, 단열성이 우수해야 하는데, 이를 위해 본 발명은 젤라틴, 카라기난, 커피찌꺼기 및 후코이단을 포함하여 단열층(4)을 구성한다.The insulating layer 4 must have excellent insulating properties while not causing environmental pollution. To this end, the present invention constitutes the insulating layer 4 including gelatin, carrageenan, coffee grounds, and fucoidan.
여기서, 상기 젤라틴은 3층 망상 구조를 형성하여 높은 수준의 단열성을 제공하며, 상기 카라기난은 상기 젤라틴에 의한 망상 구조를 지지하여 기밀성을 제공한다. 또한, 상기 후코이단은 상기 망상 구조 사이의 공극에 배치되어 공극을 메움으로써, 단열성을 좋게 하며, 항균성 역시 부여한다. Here, the gelatin forms a three-layer network structure to provide a high level of thermal insulation, and the carrageenan supports the network structure formed by the gelatin to provide airtightness. In addition, the fucoidan is disposed in the pores between the network structures to fill the pores, thereby improving thermal insulation and also providing antibacterial properties.
이때, 상기 커피찌꺼기는 로스팅된 원두로부터 커피를 추출하고 남은 잔여물을 함수량 0.1~3%로 건조하여 입도가 1~20㎛ 정도가 되도록 분쇄한 것을 의미하는바, 상기 커피찌꺼기에는 셀룰로오스가 다량 함유되어 우수한 단열성능을 갖는다. 아울러, 이러한 커피찌꺼기는 테이크 아웃 커피전문점 등에서 다량 발생하여 처치가 곤란한바, 이를 재활용하는 것은 물론, 폐기시 자연분해가 가능하여 환경오염을 야기하지 않는다는 장점이 있다.At this time, the coffee grounds refer to extracting coffee from roasted coffee beans, drying the remaining residue to a water content of 0.1 to 3%, and grinding it to a particle size of about 1 to 20㎛. The coffee grounds contain a large amount of cellulose. It has excellent insulation performance. In addition, such coffee grounds are difficult to dispose of as they are generated in large quantities at take-out coffee shops, etc., so they can be recycled and can be naturally decomposed when disposed of, so they have the advantage of not causing environmental pollution.
이때, 그 단열층(4)은 젤라틴 8~10중량%, 카라기난 8~10중량%, 커피찌꺼기 10~30중량%, 후코이단 5~10중량% 및 잔량의 물을 포함하는 조성물을 상기 바이오 플라스틱 필름(2)에 스핀 코팅, 바 코팅, 스프레이 코팅 등의 방법으로 도포한 후, 건조하여 형성할 수 있다. 여기서, 상기 건조방법은 제한하지 않는다.At this time, the insulation layer 4 is made of a composition containing 8 to 10% by weight of gelatin, 8 to 10% by weight of carrageenan, 10 to 30% by weight of coffee grounds, 5 to 10% by weight of fucoidan, and the remaining amount of water. 2) It can be formed by applying it using spin coating, bar coating, spray coating, etc. and then drying it. Here, the drying method is not limited.
본 발명에서 상기 단열층(4)의 두께는 제한하지 않는바, 20~300㎛ 정도일 수 있다.In the present invention, the thickness of the insulation layer 4 is not limited and may be about 20 to 300 μm.
아울러, 별도로 설명하지는 않았지만 각 층간의 접착을 위하여 별도의 접착제를 사용할 수도 있음은 당연하다. In addition, although not explained separately, it is natural that a separate adhesive may be used to bond each layer.
또한, 본 발명에 의한 슬라브는 슬라브본체(100) 외 다양한 구성을 더 포함할 수도 있는 것으로, 그 추가적인 실시를 제한하지 않는다. In addition, the slab according to the present invention may further include various configurations other than the
이하, 구체적인 실시예를 통해 본 발명을 상세히 설명한다. Hereinafter, the present invention will be described in detail through specific examples.
(실시예 1)(Example 1)
sc마닐라지를 준비한다. Prepare for SC Manila.
그리고 상기 sc마닐라지에 200㎛ 두께의 바이오 폴리에틸렌 필름 라미네이팅하였다.Then, a 200㎛ thick bio polyethylene film was laminated on the SC Manila paper.
이때, 상기 바이오 폴리에틸렌 필름은, 식물체 유래의 전분계 바이오매스(옥수수 가루)와 식물체 유래의 셀룰로오스계 바이오매스(카르복시에틸셀룰로오스)를 10:3 중량비로 혼합한 바이오매스 50중량%, 폴리에틸렌 왁스 5중량%, 글리세린 4중량%, 불가사리로부터 추출된 단백질 3중량%; 순지트 파우더 3중량%; 및 잔부의 HDPE로 구성된 조성물을 200℃에서 충분히 혼련하고, 이를 바이오 폴리에틸렌 필름으로 제조하여 라미네이팅하였다. 상기 바이오매스, 순지트 파우더, 불가사리로부터 추출된 단백질의 입자크기는 0.1~3㎛였다.At this time, the bio-polyethylene film is 50% by weight of biomass mixed with plant-derived starch-based biomass (corn flour) and plant-derived cellulose-based biomass (carboxyethylcellulose) in a 10:3 weight ratio, and 5% by weight of polyethylene wax. %, 4% by weight glycerin, 3% by weight protein extracted from starfish; 3% by weight of shungite powder; and the remainder of the composition consisting of HDPE were sufficiently kneaded at 200°C, and this was manufactured into a bio-polyethylene film and laminated. The particle size of the proteins extracted from the biomass, shungite powder, and starfish was 0.1 to 3 μm.
그리고 상기 불가사리로부터 추출된 단백질은 다음과 같이 제조하였다.And the protein extracted from the starfish was prepared as follows.
건조된 아무르 불가사리(Asterias amurensis)를 분쇄한 후 30mesh 체를 이용하여 선별하였다. 상기 선별된 불가사리 400g과 01M 수산화나트륨을 1:6(w/v) 비율로 혼합시킨 후 1시간 동안 교반하였다. 교반 후, 10,000 x g에서 20분 동안 원심분리하여 얻어진 침전물을 수돗물로 세척하였다. 세척 후, 05% 주석산을 첨가하여 1시간 동안 교반하였으며, 다시 10,000 x g에서 20분 동안 원심분리하여 침전물을 수돗물로 세척하였다. 세척 후, 1M 주석산으로 pH를 6으로 맞춘 후, 초음파 분쇄기를 사용하여 30분 동안 균질화한 후, 80℃에서 3시간 동안 교반하였다. 이를 다시 원심분리하여 상등액을 취한 후, 동결건조하여 단백질을 수득하였다.Dried Amur starfish (Asterias amurensis) was crushed and selected using a 30 mesh sieve. 400g of the selected starfish and 01M sodium hydroxide were mixed at a ratio of 1:6 (w/v) and stirred for 1 hour. After stirring, the precipitate obtained by centrifugation at 10,000 x g for 20 minutes was washed with tap water. After washing, 05% tartaric acid was added and stirred for 1 hour, centrifuged again at 10,000 x g for 20 minutes, and the precipitate was washed with tap water. After washing, the pH was adjusted to 6 with 1M tartaric acid, homogenized for 30 minutes using an ultrasonicator, and then stirred at 80°C for 3 hours. This was centrifuged again to obtain the supernatant, and then freeze-dried to obtain protein.
그리고 상기 라메네이트된 바이오 폴리에틸렌 필름에 항균 코팅 조성물을 도포한 후, 80℃의 열풍으로 건조하여 항균 코팅층을 형성하였다. 더욱 구체적으로 상기 항균 코팅층은, 아크릴 변성 폴리우레탄 10중량%, 연 추출물 2중량%, 은행나무 추출물 2중량%, 침전방지제(DMPA) 1중량% 및 잔량의 에탄올을 포함하는 코팅 조성물을 상기 바이오 폴리에틸렌 필름 표면에 그라비아 롤 인쇄 방식으로 도포한 후, 50~70m/h의 롤 속도, 17~18℃의 온도 및 3kgf/㎠의 롤 압력으로 가압하고, 22~23℃의 온도의 건조 챔버에서 15분 동안 건조함으로써, 그 두께가 30㎛인 항균 코팅층을 형성하였다.Then, the antibacterial coating composition was applied to the laminated bio-polyethylene film, and then dried with hot air at 80°C to form an antibacterial coating layer. More specifically, the antibacterial coating layer is a coating composition containing 10% by weight of acrylic modified polyurethane, 2% by weight of lead extract, 2% by weight of ginkgo biloba extract, 1% by weight of anti-settling agent (DMPA), and the remaining amount of ethanol. After being applied to the surface of the film using gravure roll printing, it is pressed at a roll speed of 50 to 70 m/h, a temperature of 17 to 18 ℃, and a roll pressure of 3 kgf/㎠, and dried in a drying chamber at a temperature of 22 to 23 ℃ for 15 minutes. By drying for a while, an antibacterial coating layer with a thickness of 30㎛ was formed.
상기 연 추출물은 연자육을 25℃에서 2일간 건조하고, 이를 100mesh로 분쇄한 후, 이에 70%(v/v)의 에탄올 수용액 5중량배를 가하고, 60℃에서 10시간 추출하고, 여과, 농축 및 건조하여 제조하였고, 은행나무 추출물은 은행나무의 잎을 25℃에서 2일간 건조하고, 이를 100mesh로 분쇄한 후, 이에 70%(v/v)의 에탄올 수용액 5중량배를 가하고, 60℃에서 10시간 추출하고, 여과, 농축 및 건조하여 제조하였다.The lotus extract was made by drying the lotus meat at 25°C for 2 days, grinding it to 100mesh, adding 5 times the weight of a 70% (v/v) ethanol aqueous solution, extracting at 60°C for 10 hours, filtering, concentrating, and It was prepared by drying. Ginkgo biloba extract was dried at 25°C for 2 days, ground to 100 mesh, then 5 times by weight of 70% (v/v) ethanol aqueous solution was added to it, and then dried for 10 days at 60°C. It was prepared by time extraction, filtration, concentration and drying.
(실시예 2)(Example 2)
실시예 1과 동일하게 실시하되, 상기 라메네이트된 바이오 폴리에틸렌 필름에 단열 조성물을 그라비아 롤 인쇄 방식으로 도포한 후, 50~70m/h의 롤 속도, 17~18℃의 온도 및 3kgf/㎠의 롤 압력으로 가압하고, 22~23℃의 온도의 건조 챔버에서 15분 동안 건조함으로써, 그 두께가 100㎛인 단열층을 형성하고, 상기 단열층 상에 항균 코팅층을 형성하였다.The same procedure as in Example 1 was carried out, except that the insulation composition was applied to the laminated bio-polyethylene film using a gravure roll printing method, followed by a roll speed of 50-70 m/h, a temperature of 17-18°C, and a roll of 3 kgf/cm2. By pressurizing and drying in a drying chamber at a temperature of 22 to 23° C. for 15 minutes, an insulating layer with a thickness of 100 μm was formed, and an antibacterial coating layer was formed on the insulating layer.
이때, 상기 단열 조성물로는 젤라틴 10중량%, 카라기난 10중량%, 커피찌꺼기(함수율 1%, 입도 1~20㎛) 20중량%, 후코이단 5중량% 및 잔량의 물을 혼합하여 사용하였다. At this time, the insulating composition used was a mixture of 10% by weight of gelatin, 10% by weight of carrageenan, 20% by weight of coffee grounds (moisture content: 1%, particle size: 1-20㎛), 5% by weight of fucoidan, and the remaining amount of water.
(시험예 1)(Test Example 1)
실시예 1 및 2의 항균성을 테스트 하였다. 그 결과는 하기 표 1과 같았다.The antibacterial properties of Examples 1 and 2 were tested. The results were as shown in Table 1 below.
표준필름: Stomacher® 400 POLY-BAG
시험조건: 시험균액을 (35±1)℃, 90% RH에서 24시간 정치 배양 후 균 수 측정
항균효과: 항균활성치 20 이상
사용공시균주: 균주1-Staphylococcus aureus ATCC 6538P
균주2-Escherichia coli ATCC 8739Test method: JIS Z 2801:2010, film adhesion method: number of bacteria/cm2, antibacterial activity log
Standard film: Stomacher® 400 POLY-BAG
Test conditions: Measure the number of bacteria after cultivating the test bacterial solution for 24 hours at (35±1)℃, 90% RH.
Antibacterial effect: Antibacterial activity value of 20 or more
Announced strain used: Strain 1-Staphylococcus aureus ATCC 6538P
Strain 2-Escherichia coli ATCC 8739
상기 표 1과 같이, 본 발명에 의한 실시예 1, 2는 항균 활성이 우수함을 확인할 수 있었다.As shown in Table 1 above, it was confirmed that Examples 1 and 2 according to the present invention had excellent antibacterial activity.
(시험예 2)(Test Example 2)
80℃의 아메리카노 200ml를 테이크 아웃용 컵 30개에 각각 담고, 컵 10개씩을 실시예 1, 2 및 대조군(시판되는 골판지 슬리브)의 슬리브에 삽입하였다. 그리고 이를 실온에서 30분간 방치한 후, 슬리브에 삽입된 테이크 아웃용 컵에 담긴 커피의 온도를 측정하고, 그 값을 각 슬리브 별로 평균내어 그 결과를 하기 표 2에 나타내었다. 200 ml of 80°C Americano was placed in 30 take-out cups, and 10 cups each were inserted into the sleeves of Examples 1 and 2 and the control group (commercially available cardboard sleeves). After leaving it at room temperature for 30 minutes, the temperature of the coffee contained in the take-out cup inserted into the sleeve was measured, the values were averaged for each sleeve, and the results are shown in Table 2 below.
상기 표 2에서와 같이, 본 발명에 의한 실시예 1, 2는 대조군에 비하여 컵에 담긴 아메리카노의 온도가 높음을 확인하였다. 따라서, 본 발명에 의한 컵 슬리브는 음료의 보온에 도움을 주는 것으로 판단되었다.As shown in Table 2, it was confirmed that the temperature of the Americano in the cup was higher in Examples 1 and 2 according to the present invention than in the control group. Therefore, it was determined that the cup sleeve according to the present invention helps keep drinks warm.
이상, 본 발명의 바람직한 일 실시예를 설명하였지만, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 일 실시예는 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.Although a preferred embodiment of the present invention has been described above, those skilled in the art will understand that the present invention can be implemented in other specific forms without changing the technical idea or essential features. You will be able to. Therefore, the embodiment described above should be understood in all respects as illustrative and not restrictive.
1: 종이 2: 바이오 플라스틱 필름
3: 항균 코팅층 4: 단열층
100: 슬리브본체 1: Paper 2: Bioplastic film
3: Antibacterial coating layer 4: Insulating layer
100: Sleeve body
Claims (4)
상기 슬리브본체(100)는 종이(1),
상기 종이(1)에 라미네이팅된 바이오 플라스틱 필름(2), 및
상기 바이오 플라스틱 필름(2)에 형성된 항균 코팅층(3)을 포함하며,
상기 바이오 플라스틱 필름(2)은,
식물체 유래의 전분계 바이오매스, 식물체 유래의 셀룰로오스계 바이오매스 또는 이들 모두 10~70중량%; 왁스 5~10중량%; 계면활성제 0.5~5중량%; 불가사리로부터 추출된 단백질 0.5~5중량%; 순지트 파우더 0.5~5중량%; 및 잔량의 폴리에틸렌;을 포함하는 것이고,
상기 항균 코팅층(3)은,
연 추출물 및 은행나무 추출물을 포함하는 것이며,
상기 바이오 플라스틱 필름(2)과 상기 항균 코팅층(3) 사이에 단열층(4)이 추가로 형성되되,
상기 단열층(4)은,
젤라틴, 카라기난, 커피찌꺼기 및 후코이단을 포함하는 것을 특징으로 하는 컵 슬리브.
It includes a sleeve body 100 formed with a hollow portion in which the cup is accommodated and supported,
The sleeve body 100 includes paper (1),
A bioplastic film (2) laminated on the paper (1), and
It includes an antibacterial coating layer (3) formed on the bioplastic film (2),
The bioplastic film (2) is,
10 to 70% by weight of plant-derived starch-based biomass, plant-derived cellulose-based biomass, or both; Wax 5-10% by weight; Surfactant 0.5-5% by weight; 0.5 to 5% by weight of protein extracted from starfish; 0.5-5% by weight of shungite powder; and a remaining amount of polyethylene,
The antibacterial coating layer (3) is,
Contains lotus extract and ginkgo biloba extract,
An insulating layer (4) is additionally formed between the bioplastic film (2) and the antibacterial coating layer (3),
The insulation layer (4) is,
A cup sleeve comprising gelatin, carrageenan, coffee grounds, and fucoidan.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000109045A (en) * | 1998-09-30 | 2000-04-18 | Jujo Central Kk | Heat insulation paper cup |
JP2012526006A (en) * | 2009-05-05 | 2012-10-25 | ミードウエストベコ・コーポレーション | Packaging material with enhanced thermal insulation performance |
KR102021295B1 (en) * | 2018-04-13 | 2019-09-16 | 김치곤 | Biodegradable sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof |
KR102203153B1 (en) * | 2019-03-15 | 2021-01-14 | 고의석 | Package for food using ginkgo biloba extracts and manufacturing method thereof |
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KR20110067477A (en) * | 2009-12-14 | 2011-06-22 | (주)맥스원테크놀로지 | Polymer compound for preparing eco friendly biodegradable plastics |
KR101901114B1 (en) | 2017-07-20 | 2018-09-21 | 김장훈 | cup holder using traditional korean paper contained with carbon |
KR20200059091A (en) | 2018-11-20 | 2020-05-28 | 김지선 | The waterless and thermoelectricity Cup Holder |
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JP2000109045A (en) * | 1998-09-30 | 2000-04-18 | Jujo Central Kk | Heat insulation paper cup |
JP2012526006A (en) * | 2009-05-05 | 2012-10-25 | ミードウエストベコ・コーポレーション | Packaging material with enhanced thermal insulation performance |
KR102021295B1 (en) * | 2018-04-13 | 2019-09-16 | 김치곤 | Biodegradable sheet having good maintenaance effect of multilaer food freshing and food tray product using thereof |
KR102203153B1 (en) * | 2019-03-15 | 2021-01-14 | 고의석 | Package for food using ginkgo biloba extracts and manufacturing method thereof |
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