KR102610628B1 - Granular antioxidant foaming cleansing composition containing high concentration of vitamins and method for preparing the same - Google Patents

Abstract

The present invention relates to a stabilized granular antioxidant foaming cleansing composition containing a high concentration of vitamin (Ascorbic Acid) by stabilizing vitamin (Ascorbic acid) with poor oxidation stability, and a method for manufacturing the same.
The present invention is to coat vitamin powder with ascorbic acid and at least one of metal soap or laurolylysine to stabilize it, and lipophilic fumed silica, and then coated vitamin powder, starch, surfactant and citric acid, and sodium bicarbonate as a foaming agent. A foamy cleansing composition with antioxidant effect is prepared using this method.
The creamy foam of the self-foaming cleansing granule of the present invention is a new concept product that is applied to the face like a pack and allowed to settle for 30 seconds to 1 minute to provide cleansing and antioxidant effects to the skin and then cleansed.

Description

Granular antioxidant foaming cleansing composition containing high concentration of vitamins and method for preparing the same}

The present invention relates to a stabilized granular antioxidant foaming cleansing composition containing a high concentration of vitamin (Ascorbic Acid) by stabilizing vitamin (Ascorbic acid) with poor oxidation stability, and a method for manufacturing the same. In detail, ascorbic acid and a method for stabilizing the same are provided. A foamable cleansing composition that has an antioxidant effect by coating vitamin powder with one or more of metal soap, laurolylysine, or lipophilic fumed silica, and using the coated vitamin powder, starch, surfactant, citric acid, and sodium bicarbonate as a foaming agent, and It relates to its manufacture.

Skin care is very important for modern people. In everyday life, the skin is exposed to various stresses every day due to the influence of the external environment. External factors such as fine dust, ultraviolet rays, stress, and irregular eating habits affect the skin, making it difficult to keep the skin healthy. Skin is one of the largest organs in our body, and healthy skin plays a big role in supporting a beautiful and happy life. Unhealthy skin can lead to a variety of skin problems, which can lead to loss of self-confidence or even serious psychological distress.

Therefore, modern people consider skin care important and spend a lot of time and money to maintain skin health in their daily lives. There are many ways to care for this type of skin, but the most basic is cleansing.

The present inventor seeks to provide a multi-function cleansing product containing vitamins capable of skin whitening and anti-aging. Pure vitamins are substances with powerful antioxidant properties. Pure vitamins have an excellent brightening effect by suppressing melanin production in the skin, and they are also ingredients that help promote skin elasticity by helping with collagen production. It also has excellent antioxidant properties and plays a role in protecting the skin from the external environment (moisture, air pollution, ultraviolet rays, etc.). Despite these many advantages, vitamin C has the disadvantage of being easily oxidized when exposed to air, heat, light, and water due to its poor oxidation stability.

Vitamin C, or ascorbic acid, is one of the water-soluble vitamins and is used as a coenzyme for collagen synthesis and intracellular energy metabolism, and is a powerful reducing agent with antioxidant properties.

The name 'Ascorb' or 'Ascorbate' is originally an abbreviation for 'anti-scorbutic' and can be translated as 'anti-scurvy factor.' This is a traditional name given before the existence of vitamins was fully studied, based on the hypothesis that sour fruits such as limes would contain substances (factors) that prevent scurvy. Today, it has been revealed that the reason vitamin C prevents scurvy is because it is an essential nutrient that participates in the synthesis of collagen and forms connective tissue.

Effervescent granules have been widely used in enzyme-containing dental compositions, contact lens cleaners, detergent powders, beverage sweetening tablets, chewable dentifrices, denture cleaners, surgical disinfectants, etc.

Film-coated effervescent granules are used to improve the stability of tablets and control the melting rate, and coating materials include polymers such as cellulose acetate phthalate or hydroxypropyl methylcellulose.

Conventionally, thermal melt extrusion and foamable formulations prepared by thermal melt extrusion are known as methods for producing pharmaceutical formulations. Conventional thermal melt extrusion methods generally require a temperature of 150°C or higher, enough to decompose the extruded material. Therefore, foamable compositions that are not heat stable could not be extruded by the heat melt method.

U.S. Patent No. 4,153,678 discloses effervescent tablets for additives in animal drinking water containing levamisole and vitamins or minerals as active ingredients, respectively, and U.S. Patent No. 3,667,929 discloses piperazic acid salts. It is known that foamable powder compositions coated with pulverized active ingredients such as copper sulfate, sodium nitrate, acidic substances, hydrophobic substances, or carbonates with slow melting substances are useful as additives for animal beverages or horticultural substances.

US Patent Publication No. 1,262,888 and US Patent Publication No. 4,753,792 disclose foamable toothpaste tablets designed to foam in a patient's mouth to provide a tooth cleansing action. And U.S. Patent Publication No. 5,178,878 discloses a foamable formulation that is mixed with applied microparticles to enable substantially immediate release of the pharmaceutical ingredient contained in the microparticles, wherein the microparticles contain a drug encapsulated in a protective material. The fine particles are then mixed with a blowing agent and the mixture is compressed into tablets.

U.S. Patent Publication No. 5,223,246 discloses a water-soluble foamable composition for beverage additives prepared by heat melting an active ingredient, an acid for foaming, a carbonate, and a water-soluble auxiliary with a melting point of 40°C or higher. The foamable composition is prepared by mixing the activator, acid, carbonate, and water-soluble auxiliary agent, heating the entire mixture to melt the auxiliary agent, and then stirring the mixture while cooling it at room temperature to form foamable particles.

As such, in the prior art, it was known to produce foamable granules by heat melt extrusion, but there was no foamable granule in the form of granules manufactured for cosmetic cleansing using starch and surfactant.

Additionally, the formulation of the conventional foaming cleansing composition was in the form of a tablet. In other words, there are general products made into tablets by compressing a mixture of carbonates (alkali) such as NaHCO₃ and Na₂CO₃, which generate CO₂, citric acid (acid), and a surfactant.

Also, there are products made into granule form by mixing surfactant and starch as a cosmetic detergent. However, cosmetic granule products do not foam and have to be wetted with water and rubbed with hands to generate foam.

Domestic Patent Publication No. 2003-0011819 (February 11, 2003)

In order to solve the above problems, the present invention is intended to provide a foaming cleanser for cosmetics that is convenient to use and has an effective antioxidant function using vitamins (ascorbic acid).

In addition, the present invention is to provide a granular antioxidant foaming cleansing composition with excellent foaming properties and antioxidant properties.

In addition, the present invention has an excellent cleaning effect and is intended for removing makeup or cleansing the face before applying makeup.

In order to manufacture a stabilized granular antioxidant foaming cleansing composition containing a high concentration of vitamin (Ascorbic Acid) of the present invention, it is necessary to secure the oxidation stability of the vitamin. Vitamins are very vulnerable to moisture, light or heat. In particular, it is affected by exposure to the air or moisture during the manufacturing process, and quickly discolors when mixed with additives for cleaning and foaming, which reduces marketability and also reduces antioxidant power.

To solve this problem, the present inventor treated the surface of vitamin powder to be hydrophobic to ensure water resistance. First, mix metal soap (Magnesium Myristate, Magnesium Stearate, Zinc Stearate, etc.), Lauroyl Lysine, Hydrophobic Fumed silica, Silicon Oil, etc. to ensure water resistance with ascorbic acid (Ascorbic acid) with a size of 10 to 100㎛. ) After coating the particles, starch, surfactant, sodium bicarbonate, citric acid, etc. are mixed to prepare a granular antioxidant foaming cleansing composition. During the coating, substances such as metallic soap and pure ascorbic acid pulverized to the above size are mixed in a high-speed rotating mixer and coated.

The granular antioxidant foaming cleansing composition is prepared by coating 100 parts by weight of vitamin C powder with 0.1 to 10 parts by weight of one or two or more of metal soap, lauroyl lysine, and lipophilic fumed silica to prepare coated vitamin C, An antioxidant foaming cleansing composition in the form of granules is prepared by mixing 10 to 30 parts by weight of the coating vitamin C, 10 to 40 parts by weight of starch, 20 to 40 parts by weight of surfactant, 10 to 30 parts by weight of sodium bicarbonate, and 3 to 10 parts by weight of citric acid. .

At this time, if the antioxidant foaming cleansing composition contains less than 10 parts by weight of coating vitamin C, the antioxidant effect may be reduced during a short cleaning time of less than 1 minute. On the other hand, if it contains more than 30 parts by weight, there is a problem that it may cause skin irritation.

In addition, when manufacturing coated vitamin C powder, if the content of the coating agent such as metallic soap is less than 0.1 parts by weight, it is insufficient to improve the stability of vitamin C, and if it contains more than 10 parts by weight, it reduces the feeling of use and inhibits the formation of bubbles.

When preparing the granular antioxidant foaming cleansing composition, the raw materials are mixed at room temperature, then water or ethanol is sprayed in a granulator to form granules of 0.1 to 2.0 mm in size, and then dried to produce foam.

The stabilized granular antioxidant foaming cleansing composition product containing high concentration of Vitamin C (Ascorbic Acid) of the present invention implements foaming cleansing granules for cosmetics and contains a high concentration of Vitamin C (more than 10%), so it can be used during cleansing at the same time. It is intended to provide the antioxidant effect of vitamins at the same time.

The creamy foam of the self-foaming cleansing granule of the present invention is a new concept product that is applied to the face like a pack and allowed to settle for 30 seconds to 1 minute to provide cleansing and antioxidant effects to the skin and then cleansed.

The present invention relates to a granular antioxidant foaming cleansing composition and a facial pack using the same, and is explained in detail using examples.

The granular antioxidant foaming cleansing composition of the present invention is prepared by coating with vitamin C. For convenience in explaining the invention, vitamin, vitamin C, and ascorbic acid are defined to have the same meaning.

In order to ensure the oxidation stability of vitamins in the present invention, the surface of vitamin C particles is coated with metal soap, laurolylysine, lipophilic fumed silica, or silicone oil.

Vitamin C is a substance with weak oxidation stability due to atmospheric moisture or light. Additionally, oxidation stability is easily damaged by surfactants, foaming agents, and other additives during the processing process. Accordingly, in the present invention, vitamin C is pulverized into particles of 10 to 100㎛ in size, and then hydrophobic (hydrophobic, lipophilic) substances such as metal soap (Magnesium Myristate, Magnesium Stearate, Zinc Stearate, etc.), Lauroyl Lysine, and Hydrophobic Fumed silica powder are used. Coating was performed on the vitamin particles. For powder coating of vitamin C, the powder is mixed in a mixer capable of high-speed rotation, then mixed at 1000 to 7000 rpm for 5 to 10 minutes to prepare a coating composition, and then stored for 4 weeks at a humidity of 80% and a temperature of 40°C to determine the degree of discoloration. Confirmed. Below are the results of comparing the oxidation stability of pure vitamin C powder and coated vitamin C powder through examples and comparative examples of the present invention.

Raw material Example 1 Example 2 Example 3 Example 4 Example 5 Ascorbic acid 97 99 99 99.9 95 Magnesium Myristate 3 Magnesium Steering One Zinc Stearate One Hydrophobic fumed silica 0.1 Lauroyl Lysine 5 Total 100 100 100 100 100

Raw material Example 6 Example 7 Example 8 Example 9 Comparative Example 1 Ascorbic acid 90 95 97 100 100 Magnesium Myristate 10 Magnesium Steering 5 Zinc Stearate 3 Hydrophobic fumed silica 0.5 Lauroyl Lysine Total 100 100 100 100 100

Example 1 Example 2 Example 3 Example 4 Example 5 1 week One One One One One 2 weeks One One One One One 3 weeks One One One 2 One 4 weeks One 2 2 2 One

Example 6 Example 7 Example 8 Example 9 Comparative Example 1 1 week One One One One One 2 weeks One One One One 2 3 weeks One One One One 3 4 weeks One One One 2 4

1: Stable without discoloration

2: Slight discoloration

3: Discoloration to yellow

4: Discoloration to brown

As a result of comparing the oxidation stability of the pure vitamin C powder and the coated vitamin C powder, it was confirmed that the oxidation stability of the coated vitamin powder of the coated example was improved.

The term “effervescence” used herein refers to the generation of gas and the release of bubbles when liquid is mixed with granules. At this time, the foaming cleansing composition in the form of granules is an effervescent granule, and the gas generation reaction is caused by a reaction between an alkaline component and an acidic component. In the present invention, a surfactant is used as an alkaline ingredient, and citric acid is used as an acidic ingredient.

Conventionally, a foaming acidic component is a source of protons and refers to a compound or substance that can react with an alkaline component to generate gas and cause bubbles to form in a solution containing them. Acidic components have a higher acid dissociation constant, that is, more than one acidic functional group, and include free acids, acid anhydrides, and organic acids in the salt state of acids.

Effervescent acidic ingredients that are solid at room temperature and have a pH of 4.5 or less when saturated with water at room temperature include tartaric acid, citric acid, maleic acid, fumaric acid, malic acid, adipic acid, succinic acid, lactic acid, and glycolic acid. , alpha hydroxy acids, ascorbic acid, amino acids, etc., and phosphoric acid or pyrophosphoric acid can be used.

Among the acidic components mentioned above, it is preferable to use one that has a relatively large acid dissociation constant (103 or more) and low hygroscopicity (critical humidity at 30°C is 40% RH or more). It is preferable that the acidic component can form a eutectic mixture with the binder.

Conventionally, the term “alkaline agent” refers to an alkaline compound that emits gases or causes a solution to bubble when exposed to an acidic agent or a proton source such as water. The alkaline component may be a carbon dioxide gas precursor, an oxygen gas precursor, or a chlorine dioxide precursor, and in the present invention, a surfactant is used.

When the alkaline reagent is a carbon dioxide precursor, carbonate, sesquicarbonate, and hydrogencarbonate salts of potassium, lithium, sodium, calcium, and ammonium, or L-lysine carbonate, arginine carbonate, sodium glycine carbonate, and sodium amino acid. Compounds such as carbonates may be used. When the alkaline reagent is an oxygen gas precursor, compounds such as anhydrous sodium perborate, effervescent perborate, sodium perborate monohydrate, sodium percarbonate and sodium dichloroisocyanurate can be used. When the alkaline component is a chlorine dioxide (ClO₂) precursor, compounds such as sodium hypochlorite and calcium hypochlorite can be used.

When the foaming component contains two components that can react with each other, for example, acid and alkaline, it is preferable to provide the acid and alkaline components in the same reaction equivalent ratio in order to completely react the two components.

By controlling the relative ratios of acidic:alkaline components, effervescent granules can be used to adjust the pH of their surroundings.

In the method of producing a granular antioxidant foaming cleansing composition, the composition is coated by coating 100 parts by weight of pure vitamin C powder with 0.1 to 10 parts by weight of one or two or more of metallic soap, lauroyl lysine, and lipophilic fumed silica. Manufactures vitamin C. When manufacturing coated vitamin C powder, if the content of the coating agent such as metallic soap is less than 0.1 parts by weight, it is insufficient to improve the oxidation stability of vitamin C, and if it is contained more than 10 parts by weight, it reduces the feeling of use and inhibits the formation of bubbles, so the coating agent It is undesirable to have too much content.

When preparing an antioxidant foaming cleansing composition using the above-mentioned coating vitamin C, 10 to 30 parts by weight of coating vitamin C is mixed to create an antioxidant foaming cleansing composition. At this time, if the content of coating vitamin C is less than 10 parts by weight, it is used for a short time of less than 1 minute. When washing, the antioxidant effect may decrease. On the other hand, if it contains more than 30 parts by weight, it may cause skin irritation.

Additionally, it is preferable to use 20 to 40 parts by weight of the surfactant. If the surfactant content is less than 20 parts by weight, the detergency and foaming power are reduced due to the low surfactant concentration. If the surfactant content is more than 40 parts by weight, the surfactant concentration is too high than necessary, which reduces hardness and changes the reaction effect.

Then, it is prepared in the form of granules by mixing 10 to 40 parts by weight of starch as a filling disintegrant, 10 to 30 parts by weight of sodium bicarbonate and 3 to 10 parts by weight of citric acid as a foaming agent. At this time, if the content of the foaming agent is too high or too low, it affects the foaming power and granule forming, so it is desirable to mix an appropriate amount.

The granular antioxidant foaming cleansing composition contains more than 10% by weight of vitamin C, so it supplies vitamin C to the skin, such as the face, at the same time as cleansing, and at the same time provides an antioxidant effect to the skin due to vitamin C.

In addition, the granular antioxidant foaming cleansing composition of the present invention is a self-foaming cleansing granule whose creamy foam swells 3 to 5 times and is applied to the entire face like soap foam to cleanse. At this time, the creamy foam that swells like soap foam is applied like a pack and kept for 30 seconds to 1 minute to provide cleansing and antioxidant effects to the skin and cleanse it.

The starch includes corn starch, wheat starch, rice starch, tapioca starch, potato starch or/and sweet potato starch.

Starch is a storage carbohydrate of plants and is classified into amylose and amylopectin according to the arrangement of glucose. Corn starch has a weak viscosity and is cloudy, but has a crumbly and chewy texture and a unique flavor, so it is used in puddings, pie fillings, and baking. In addition, it has excellent gel-forming ability, so it is used as a general thickening agent. It gels at a temperature of 62 to 80 degrees Celsius, and is often used as a substitute for potato starch. The amylose content is 21-28% and the amylopectin content is 72-79%.

Surfactant is a chemical substance that lowers the surface tension between interfaces and allows two or more substances to mix well.

Anionic surfactants are most commonly used because anions generated by dissociation in water are adsorbed to the surface of an aqueous solution, lowering the surface tension. The hydrophilic part consists of a carboxyl group, sulfuric acid, and phosphoric acid group, and these are neutralized with sodium, potassium, ammonium, and amine.

Alkylbenzene of alkylbenzene sulfonate (LAS: Linear Alkybenzene Sulfonate) was previously manufactured from propylene, but is currently manufactured from long-chain chloroalkane, and anhydrous sulfuric acid or sulfan is used in the sulfonation process.

α-Olefin Sulfonate (AOS: α-Olefin Sulfonate) is manufactured by sulfonation of α-olefin with about 15 carbons with anhydrous sulfuric acid and then treatment with sodium hydroxide.

Alkyl Ether Sulfate (AES) is manufactured by adding ethylene oxide to high-purity alcohol and then undergoing a sulfur oxidation process. It is a surfactant applied to liquid detergents and shampoos due to its excellent water solubility and cleaning power.

In addition, Alkyl Sulfate (AS) is manufactured through the sulfation process of higher alcohols, and can be processed into high-concentration powder form, so it is a surfactant used in toothpaste, etc.

In addition, Sodium Cocoyl Alaninate, Sodium Lauroyl Alaninate, and Potassium Cocoyl Alaninate are manufactured by attaching hydrophilic amino acid derivatives to higher alcohols or higher fatty acids. Alaninate), Sodium Cocoyl Glutamate, Potassium Cocoyl Glutamate, Sodium Lauroyl Glutamate, Sodium Cocoyl Glycinate, Potassium Cocoyl Glycinate There are Potassium Cocoyl Glycinate, Sodium Cocoyl Asperate, and Potassium Cocoyl Asperate, and Sodium Cocoyl Isethio is a natural vegetable surfactant derived from coconut. Sodium Cocoyl Isethionate (Nate), etc. may be used, but are not limited thereto.

Amphoteric surfactants are surfactants that are mainly used in personal care products and household cleaning products due to their low skin irritation. They are surfactants that dissociate in water and have an anionic, cationic, or nonionic form in aqueous solutions depending on pH. Representative examples include alkyl amine oxide (alkyl amine). Oxide, akyl betaine, Coco Amido Propyl Betaine, etc. can be used, but are not limited to these.

Cationic surfactants have the characteristic of coagulating particles by converting hydrophobic groups into positive ions in an aqueous solution, repelling ions of the same polarity and neutralizing ions of different polarity.

Alkyl ammonium type cationic surfactants are divided into tetraalkyl ammonium type and pyridinium type, and pyridinium type is generally synthesized by reaction of alkyl halide and pyridine.

Nonionic surfactants are surfactants that do not dissolve in water and have hydrophilic properties through hydrogen bonds with water through hydroxy groups or ethylene oxide groups.

Alcohol derivatives include polyhydroxy compounds such as glycerin, pentaerythritol, sorbitol, and sugar. Nonionic surfactants made of alcohol derivatives are odorless, non-toxic, and non-irritating and are used as food additives.

Sodium bicarbonate (NaHCO₃) of the present invention produces sodium bicarbonate (NaHCO₃) by supplying carbon dioxide-containing gas to a sodium hydroxide (NaOH) solution and reacting between sodium hydroxide and carbon dioxide. That is, when carbon dioxide-containing gas is supplied to a sodium hydroxide solution, sodium bicarbonate is produced through a reaction between the sodium hydroxide and carbon dioxide. Since the solubility of sodium bicarbonate is 96 g/L at 20°C, sodium bicarbonate is dissolved in the filtrate remaining as much as the solubility after recovering the precipitated sodium bicarbonate.

Sodium bicarbonate is produced through the reaction of sodium hydroxide and carbon dioxide, and the reaction formula for this sodium bicarbonate production reaction is shown in Equation 1 below.

Equation 1: NaOH + CO2 → NaHCO3

The granular antioxidant foaming cleansing composition is manufactured in granule form by mixing starch, surfactant, sodium bicarbonate, vitamin C, metallic soap, lauroyl lysine, lipophilic fumed silica, and citric acid.

At this time, the granular antioxidant foaming cleansing composition is coated by mixing 0.1 to 10 parts by weight of one or two types of metallic soap, lauroyl lysine, or lipophilic fumed silica with 100 parts by weight of pure vitamin C powder. When manufacturing coated vitamin C powder, if the content of a coating agent such as metallic soap is less than 0.1 parts by weight, it is insufficient to improve the oxidation stability of vitamin C. If it is more than 10 parts by weight, the content of the coating agent decreases the feeling of use and inhibits the formation of bubbles. Too much is not desirable.

10 to 30 parts by weight of the coated vitamin C, 10 to 40 parts by weight of starch, 20 to 40 parts by weight of surfactant, 10 to 30 parts by weight of sodium bicarbonate, and 3 to 10 parts by weight of citric acid are mixed and a granulator (Pelletizer) rotating at high speed is mixed. A granular cleansing foam is manufactured through this process.

At this time, the granular cleansing foaming agent is manufactured according to its size.

The oxidation stability of the granular foaming cleansing composition was compared through the following specific examples.

Granular foaming cleansing composition Raw material Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Comparative Example 2 Starch 30 20 10 20 27 29 20 Pure Ascorbic Acid 15 Coated ascorbic acid 10 20 30 15 17 20 Cocoyl Isethionate 10 15 15 20 10 20 Alkyl ether sulfate One 3 3 Cocoyl Alaninate 5 3 5 5 Cocoyl Glutamate 5 5 5 Cocoyl Glycinate 15 Cocoyl Asperate 5 10 5 Alkyl sulfate 4 15 5 5 Sodium bicarbonate 30 20 25 20 40 20 20 Citric Acid 10 10 5 5 10 3 5 Total 100 100 100 100 100 100 100

Comparison of oxidation stability (condition humidity 80%, temperature 45℃) Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Comparative Example 2 1 week One One One One One One 2 2 weeks One One One One One One 3 3 weeks One One 2 One One One 4 4 weeks One 2 2 One 2 2 4

1: Stable without discoloration

2: Slight discoloration

3: Discoloration to yellow

4: Discoloration to brown

The difference in oxidation stability between the granular foaming cleansing composition using the coated vitamin C of the above example and the pure vitamin C of Comparative Example 2 can be compared.

Next, the antioxidant power of granular foam cleansing was measured using the DPPH assay method described above.

Pure Ascorbic acid Example 13 Comparative Example 2 DPPH radical scavenging activity (%) 100 95.87±0.91 15.75±0.15

As a result of confirming the antioxidant activity of the granular foaming cleansing composition, it was confirmed that DPPH radical scavenging activity was significantly more effective than Comparative Example 2, and that Example 13 showed a very high level of antioxidant activity, equivalent to that of pure vitamin C. there is.

Claims (5)

In the antioxidant foaming cleansing composition containing coating vitamins,
The antioxidant foaming cleansing composition is made by mixing 10 to 30 parts by weight of coated vitamin C, 10 to 40 parts by weight of starch, 20 to 40 parts by weight of surfactant, 10 to 30 parts by weight of sodium bicarbonate, and 3 to 10 parts by weight of citric acid, then mixed with water or ethanol ( ethanol) is sprayed to form granules of 0.1 to 2.0 mm in size and then dried to produce foam.
The coated vitamin C is made by coating 100 parts by weight of vitamin C powder pulverized into particles of 10 to 100㎛ size with 0.1 to 10 parts by weight of one or two or more of metallic soap, lauroyl lysine, and lipophilic fumed silica. manufacturing,
When mixing and coating the vitamin C powder, the mixed powder is mixed at 1000 to 7000 rpm for 5 to 10 minutes to prepare a coating composition,
The starch is one of wheat starch, tapioca starch, or sweet potato starch.
Antioxidant foaming cleansing composition in granule form, characterized in that



delete delete delete According to paragraph 1,
Antioxidant foaming cleansing composition in the form of granules, characterized in that the surfactant uses one of an anionic surfactant, an amphoteric surfactant, a cationic surfactant, a nonionic surfactant, or an alcohol derivative.